CN107190138A - A kind of method and device that manganese-silicon is prepared using poor ferrous manganese ore - Google Patents
A kind of method and device that manganese-silicon is prepared using poor ferrous manganese ore Download PDFInfo
- Publication number
- CN107190138A CN107190138A CN201710426482.0A CN201710426482A CN107190138A CN 107190138 A CN107190138 A CN 107190138A CN 201710426482 A CN201710426482 A CN 201710426482A CN 107190138 A CN107190138 A CN 107190138A
- Authority
- CN
- China
- Prior art keywords
- manganese
- silicon
- manganese ore
- poor
- ore
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 title claims abstract description 62
- 229910052748 manganese Inorganic materials 0.000 title claims abstract description 62
- 239000011572 manganese Substances 0.000 title claims abstract description 62
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 title claims abstract description 47
- PYLLWONICXJARP-UHFFFAOYSA-N manganese silicon Chemical compound [Si].[Mn] PYLLWONICXJARP-UHFFFAOYSA-N 0.000 title claims abstract description 25
- 238000000034 method Methods 0.000 title claims abstract description 22
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 41
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims abstract description 36
- 239000000567 combustion gas Substances 0.000 claims abstract description 25
- ODINCKMPIJJUCX-UHFFFAOYSA-N Calcium oxide Chemical compound [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 claims abstract description 21
- 239000000377 silicon dioxide Substances 0.000 claims abstract description 21
- 238000005453 pelletization Methods 0.000 claims abstract description 20
- 235000013312 flour Nutrition 0.000 claims abstract description 18
- 229910052742 iron Inorganic materials 0.000 claims abstract description 18
- 239000000292 calcium oxide Substances 0.000 claims abstract description 11
- 235000012255 calcium oxide Nutrition 0.000 claims abstract description 11
- 239000000463 material Substances 0.000 claims abstract description 8
- 238000010438 heat treatment Methods 0.000 claims abstract description 7
- 230000004044 response Effects 0.000 claims abstract description 5
- 238000007599 discharging Methods 0.000 claims description 16
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical group [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 8
- 229910052710 silicon Inorganic materials 0.000 claims description 8
- 239000010703 silicon Substances 0.000 claims description 8
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims description 4
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 4
- 229910021487 silica fume Inorganic materials 0.000 claims description 3
- 229910052593 corundum Inorganic materials 0.000 claims description 2
- 239000000395 magnesium oxide Substances 0.000 claims description 2
- 229910001845 yogo sapphire Inorganic materials 0.000 claims description 2
- 229910000616 Ferromanganese Inorganic materials 0.000 claims 1
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 claims 1
- DALUDRGQOYMVLD-UHFFFAOYSA-N iron manganese Chemical compound [Mn].[Fe] DALUDRGQOYMVLD-UHFFFAOYSA-N 0.000 claims 1
- 238000012545 processing Methods 0.000 abstract description 2
- 238000003723 Smelting Methods 0.000 description 9
- 238000002844 melting Methods 0.000 description 6
- 230000008018 melting Effects 0.000 description 6
- VASIZKWUTCETSD-UHFFFAOYSA-N manganese(II) oxide Inorganic materials [Mn]=O VASIZKWUTCETSD-UHFFFAOYSA-N 0.000 description 5
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 4
- 235000011941 Tilia x europaea Nutrition 0.000 description 4
- 229910045601 alloy Inorganic materials 0.000 description 4
- 239000000956 alloy Substances 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 4
- 239000004571 lime Substances 0.000 description 4
- 229920001296 polysiloxane Polymers 0.000 description 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 229910052500 inorganic mineral Inorganic materials 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 239000011707 mineral Substances 0.000 description 3
- 235000010755 mineral Nutrition 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 229910052760 oxygen Inorganic materials 0.000 description 3
- 239000001301 oxygen Substances 0.000 description 3
- 230000009467 reduction Effects 0.000 description 3
- 229910001021 Ferroalloy Inorganic materials 0.000 description 2
- 229910017028 MnSi Inorganic materials 0.000 description 2
- 229910000805 Pig iron Inorganic materials 0.000 description 2
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 2
- XMWCXZJXESXBBY-UHFFFAOYSA-L manganese(ii) carbonate Chemical group [Mn+2].[O-]C([O-])=O XMWCXZJXESXBBY-UHFFFAOYSA-L 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 241000208340 Araliaceae Species 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- 235000005035 Panax pseudoginseng ssp. pseudoginseng Nutrition 0.000 description 1
- 235000003140 Panax quinquefolius Nutrition 0.000 description 1
- 229910000720 Silicomanganese Inorganic materials 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- 229910052681 coesite Inorganic materials 0.000 description 1
- 239000000571 coke Substances 0.000 description 1
- 229910052906 cristobalite Inorganic materials 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 238000010304 firing Methods 0.000 description 1
- 230000004907 flux Effects 0.000 description 1
- 235000008434 ginseng Nutrition 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000011656 manganese carbonate Substances 0.000 description 1
- 235000006748 manganese carbonate Nutrition 0.000 description 1
- 229940093474 manganese carbonate Drugs 0.000 description 1
- PPNAOCWZXJOHFK-UHFFFAOYSA-N manganese(2+);oxygen(2-) Chemical compound [O-2].[Mn+2] PPNAOCWZXJOHFK-UHFFFAOYSA-N 0.000 description 1
- 229910000016 manganese(II) carbonate Inorganic materials 0.000 description 1
- 238000005272 metallurgy Methods 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000011946 reduction process Methods 0.000 description 1
- 239000002893 slag Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 238000009628 steelmaking Methods 0.000 description 1
- 229910052682 stishovite Inorganic materials 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 229910052905 tridymite Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B1/00—Preliminary treatment of ores or scrap
- C22B1/14—Agglomerating; Briquetting; Binding; Granulating
- C22B1/24—Binding; Briquetting ; Granulating
- C22B1/2406—Binding; Briquetting ; Granulating pelletizing
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21B—MANUFACTURE OF IRON OR STEEL
- C21B13/00—Making spongy iron or liquid steel, by direct processes
- C21B13/006—Starting from ores containing non ferrous metallic oxides
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B1/00—Preliminary treatment of ores or scrap
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B47/00—Obtaining manganese
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B5/00—General methods of reducing to metals
- C22B5/02—Dry methods smelting of sulfides or formation of mattes
- C22B5/04—Dry methods smelting of sulfides or formation of mattes by aluminium, other metals or silicon
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C22/00—Alloys based on manganese
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Mechanical Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Life Sciences & Earth Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Geology (AREA)
- Manufacture And Refinement Of Metals (AREA)
Abstract
The invention discloses a kind of method for preparing manganese-silicon using poor ferrous manganese ore, comprise the steps of：Poor ferrous manganese ore is dried and crushed；Poor ferrous manganese ore after crushing mixes with silica flour and quick lime and mixed material pelletizing is formed into pelletizing；Pelletizing is distributed into heating response in molten point of stove of combustion gas and obtains silicomangan.The present invention also discloses a kind of device for performing the above method.The processing problem of low-grade ferrous manganese ore is solved by the use of the above method and device, realize low-grade ferrous manganese ore manganese and iron is separately recovered utilization.
Description
Technical field
The present invention relates to field of metallurgy, more particularly to a kind of method and device that manganese-silicon is prepared using poor ferrous manganese ore.
Background technology
The smelting to manganese-silicon has had for a long time and in-depth study both at home and abroad, and technologic improvement is favourable with improving
In every economic difficulty.The raising of technical indicator so reach it is energy-saving and improve product quality purpose.Manganese silicon to be made is closed
Golden smelting technique is further lifted to a new height, it is necessary to high energy consumption, product present in being smelted to current manganese-silicon
The problems such as quality is unstable further solves.
Silicomangan is the important alloy of steel-making, and usage amount is maximum, is the important alloy for improving steel mechanics performance.China
Annual production ferroalloy is ten thousand tons about more than 3000, wherein 98% ferroalloy is using mineral hot furnace production, i.e., using mineral hot furnace by ore
Pyroreaction is heated to coke.Mineral hot furnace heating is that these raw materials are heated into high temperature by electrode, and need to be heated to 1600
More than DEG C, but these materials conductives and heat transfer efficiency are low, and heating process power consumption is big, firing rate is slow, and the production cycle is long.
The content of the invention
In order to solve the above-mentioned problems in the prior art, the present invention proposes one kind and prepares manganese silicon using poor ferrous manganese ore
The method and device of alloy, the present invention prepares manganese-silicon using poor ferrous manganese ore instead of high manganese ore, while solving industrial silica fume
Store up problem, make full use of silica flour characteristic carry out reduction melting.
The method that the present invention is used is as follows：
A kind of method for preparing manganese-silicon using poor ferrous manganese ore, is comprised the steps of：
Step one, poor ferrous manganese ore is dried and crushed；
Step 2, the poor ferrous manganese ore after being crushed in step one is mixed with silica flour and quick lime and by mixed material pelletizing
Form pelletizing；
Step 3, is distributed into heating response in molten point of stove of combustion gas by pelletizing and obtains silicomangan.
Further, the component of following mass fraction is contained in poor ferrous manganese ore：Manganese is 15-20%, and iron is 28-35%, oxygen
Change calcium is 2-4%, and magnesia is 0.5-1%, and silica is 13-16% and alundum (Al2O3) is 4-8%.
Further, poor ferrous manganese ore is dried to moisture in step one and is less than 1%, and be crushed to granularity and be less than
2mm。
Further, manganese is present in manganese carbonate form in ferrous manganese ore.
Further, in step 2 poor ferrous manganese ore, silica flour and quick lime according to mass ratio 100:(18-28):(20-38)
Mixed；Preferably, poor ferrous manganese ore, silica flour and Lime Quality ratio are 100:(23-26):(25-35).
Further, pelletizing diameter 10mm-15mm.
Further, silica flour is silicon ash and/or industrial silica fume.
Further, the temperature of molten point of stove of combustion gas is 1450-1550 DEG C, in molten point of stove of combustion gas, is contained in poor ferrous manganese ore
Manganese carbonate decompose generation MnO, MnO and SiO2Generation manganous silicate is combined first.When temperature is more than 1450 DEG C, in pelletizing
Silicon starts fusing, and quick lime plays a part of flux, SiO can be replaced under the high temperature conditions2Manganous oxide in MnO.Silicon
Ferriferous oxide can be reduced under the high temperature conditions, silicon can generate MnSi and oxygen with manganous oxide reaction, and oxygen exists
Atmosphere can be adjusted in molten point of stove of combustion gas, it is class oxidizing atmosphere to make the molten point stove of combustion gas, it is to avoid the volatilization loss of manganese.Si reduction iron
It is exothermic reaction, the molten point stove of now combustion gas can close burner, and molten bath is reacted by the heat of itself.In course of reaction
Middle iron is reduced first, and most iron sinks to burner hearth bottom first, in reduction process, and silicomanganese formation MnSi alloys are enriched to
Iron liquid upper strata, metallurgical slag floats over silicomangan upper strata.In order to avoid the volatilization of manganese, duration of heat control 30min-55min it
Between.Finally, manganese content 60-65%, silicone content 22-27% silicomangan can be obtained by melting, while iron can be obtained
The pig iron of content more than 95%.
Further, the mass percent of the silicon in silica flour is more than 90%.
Further, the heating response time in step 3 is 30-55min.
The invention also discloses a kind of device for performing the above method, including：
Dryer, dryer has charging aperture and discharging opening；
Disintegrating machine, disintegrating machine has charging aperture and discharging opening, and the discharging opening of dryer is connected with the charging aperture of disintegrating machine；
Batch mixer, batch mixer has is provided with one or more transmission above charging aperture and discharging opening, batch mixing machine inlet
Device, the material that one or more conveyers are used in the material for discharging discharge hole of crusher and conveyer top feed bin
It is sent in batch mixer；
Pelletizer, pelletizer has feeding mouth and discharging opening, and the outlet of batch mixer is connected with the entrance of pelletizer；
Molten point of stove of combustion gas, the molten point stove of combustion gas has charging aperture and a discharging opening, the charging aperture of molten point of stove of combustion gas and pelletizer
Discharging opening is connected.
Further, the feed bin above conveyer is silica flour feed bin and quick lime feed bin.
Further, the molten point furnace interior of combustion gas is provided with molten bath.
Further, the molten point stove of combustion gas is provided with burner.
Further, it is provided with agitating device in batch mixer.
Further, conveyer is conveyer belt.
By using above-mentioned technical proposal, following many beneficial effects are achieved：
(1) the processing problem of low-grade ferrous manganese ore is solved.
(2) reducing agent is done using silicon, can obtains being easier to obtain manganese-silicon.
(3) it is closed melting in smelting process to melt a point stove, while the speed of Si reduction iron and manganese, it is to avoid manganese
Volatilization loss.
(4) utilization is separately recovered by what molten point of one equipment of stove of combustion gas realized low-grade ferrous manganese ore manganese and iron.
Brief description of the drawings
The above-mentioned and/or additional aspect and advantage of the present invention will more in the description carried out to embodiment is combined with accompanying drawing
Plus substantially and be readily appreciated that, wherein：
Fig. 1 shows that the poor ferrous manganese ore of utilization according to embodiments of the present invention prepares the flow signal of the method for manganese-silicon
Figure.
Fig. 2 shows the schematic diagram of the device for preparing manganese-silicon according to embodiments of the present invention.
Embodiment
It should be appreciated that shown embodiments of the invention are merely illustrative in the exemplary embodiment.Although in this hair
Only a small number of embodiments are described in detail in bright, but those skilled in the art are readily appreciated that and depart from the present invention in not essence
In the case of the teaching of theme, a variety of modifications are feasible.Correspondingly, all such modifications should all be included in the present invention's
In the range of.Without departing from the spirit of the invention, design, operating condition and ginseng that can be to following exemplary embodiment
Number etc. makes others and replaces, changes, changes and delete.
Embodiment one
As shown in Figures 1 and 2, the ferrous manganese ore composition in the present embodiment is：Iron 28%, manganese 15%.At step S101, make
Ferrous manganese ore is dried to moisture with dryer 1 and is less than 1%, and below 2mm is crushed to using disintegrating machine 2.Then exist
Step 102 place, by dry and it is broken after ferrous manganese ore batch mixer 5 is sent to by conveyer, while by feed bin 3 and feed bin 4
In silica flour and quick lime be sent to batch mixer 5 also by conveyer.Wherein, ferrous manganese ore, silica flour and the life in batch mixer 5
Lime is according to 100:23:25 ratio mixing and the pelletizing formation pelletizing in pelletizer 6.At step S103, the pelletizing made
Put into molten point of stove 7 of combustion gas and carry out melting, the temperature control of molten point of stove of combustion gas is in 1480 ± 10 DEG C, smelting time 35min.Through
Manganese content 62% may finally be obtained by crossing smelting, and the manganese-silicon of silicone content 23.7% can also obtain the life of iron content 95.5%
Iron.
Embodiment two
As shown in Figures 1 and 2, the ferrous manganese ore composition in the present embodiment is：Iron 34%, manganese 20%.At step S101, make
Ferrous manganese ore is dried to moisture with dryer 1 and is less than 1%, and below 2mm is crushed to using disintegrating machine 2.Then exist
Step 102 place, by dry and it is broken after ferrous manganese ore batch mixer 5 is sent to by conveyer, while by feed bin 3 and feed bin 4
In silica flour and quick lime be sent to batch mixer 5 also by conveyer.Wherein, ferrous manganese ore, silica flour and the life in batch mixer 5
Lime is according to 100:25:30 ratio mixing and the pelletizing formation pelletizing in pelletizer 6.At step S103, the pelletizing made
Put into molten point of stove 7 of combustion gas and carry out melting, the temperature control of molten point of stove of combustion gas is in 1500 ± 10 DEG C, smelting time 40min.Through
Manganese content 63.8% may finally be obtained by crossing smelting, and the manganese-silicon of silicone content 25.6% can also obtain iron content 96.7%
The pig iron.
Embodiment three
As shown in Figures 1 and 2, the ferrous manganese ore composition in the present embodiment is：Iron 32%, manganese 19%.At step S101, make
Ferrous manganese ore is dried to moisture with dryer 1 and is less than 1%, and below 2mm is crushed to using disintegrating machine 2.Then exist
Step 102 place, by dry and it is broken after ferrous manganese ore batch mixer 5 is sent to by conveyer, while by feed bin 3 and feed bin 4
In silica flour and quick lime be sent to batch mixer 5 also by conveyer.Wherein, ferrous manganese ore, silica flour and the life in batch mixer 5
Lime is according to 100:26:33 ratio mixing and the pelletizing formation pelletizing in pelletizer 6.At step S103, the pelletizing made
Put into molten point of stove 7 of combustion gas and carry out melting, the temperature control of molten point of stove of combustion gas is in 1530 ± 10 DEG C, smelting time 50min.Through
Manganese content 62.2% may finally be obtained by crossing smelting, and the manganese-silicon of silicone content 27.3% can also obtain the life of iron content 97%
Iron.
These are only presently preferred embodiments of the present invention, not for limit the present invention practical range；If not departing from this
The spirit and scope of invention, modify or equivalent substitution to the present invention, all should cover the protection in the claims in the present invention
Among scope.
Claims (10)
1. a kind of method for preparing manganese-silicon using poor ferrous manganese ore, it is characterised in that comprise the steps of：
Step one, the poor ferrous manganese ore is dried and crushed；
Step 2, the poor ferrous manganese ore after being crushed in step one is mixed with silica flour and quick lime and mixed material pelletizing is formed
Pelletizing；
Step 3, is distributed into heating response in molten point of stove of combustion gas by the pelletizing and obtains silicomangan.
2. the method according to claim 1 for preparing manganese-silicon using poor ferrous manganese ore, it is characterised in that the poor ferromanganese
Contain the component of following mass fraction in ore deposit：Manganese is 15-20%, and iron is 28-35%, and calcium oxide is 2-4%, and magnesia is 0.5-
1%, silica is 13-16% and alundum (Al2O3) is 4-8%.
3. the method according to claim 1 for preparing manganese-silicon using poor ferrous manganese ore, it is characterised in that the step 2
In poor ferrous manganese ore, silica flour and quick lime according to mass ratio 100:(18-28):(20-38) is mixed.
4. the method according to claim 1 for preparing manganese-silicon using poor ferrous manganese ore, it is characterised in that the silica flour is
Silicon ash and/or industrial silica fume.
5. the method according to claim 1 for preparing manganese-silicon using poor ferrous manganese ore, it is characterised in that the combustion gas is melted
The temperature for dividing stove is 1450-1550 DEG C.
6. the method according to claim 1 for preparing manganese-silicon using poor ferrous manganese ore, it is characterised in that in the silica flour
The mass percent of silicon is more than 90%.
7. the method according to claim 1 for preparing manganese-silicon using poor ferrous manganese ore, it is characterised in that the step 3
In the heating response time be 30-55min.
8. the method according to claim 1 for preparing manganese-silicon using poor ferrous manganese ore, it is characterised in that the step one
Middle dry the poor ferrous manganese ore to moisture is less than 1%.
9. a kind of poor ferrous manganese ore of utilization implemented any one of claim 1-8 prepares the device of the method for manganese-silicon,
Characterized in that, described device includes：
Dryer, the dryer has charging aperture and discharging opening；
Disintegrating machine, the disintegrating machine has charging aperture and discharging opening, the charging of the discharging opening of the dryer and the disintegrating machine
Mouth is connected；
Batch mixer, the batch mixer has charging aperture and discharging opening, and the batch mixing machine inlet top is provided with one or more
Conveyer, one or more of conveyers are used for the material and the conveyer for discharging the discharge hole of crusher
Material in the feed bin of top is sent in the batch mixer；
Pelletizer, the pelletizer has feeding mouth and discharging opening, the outlet of the batch mixer and the entrance phase of the pelletizer
Even；
Molten point of stove of combustion gas, the molten point stove of the combustion gas has charging aperture and a discharging opening, the charging aperture of molten point of stove of the combustion gas with it is described
The discharging opening of pelletizer is connected.
10. device according to claim 9, it is characterised in that the molten point furnace interior of the combustion gas is provided with molten bath.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710426482.0A CN107190138A (en) | 2017-06-08 | 2017-06-08 | A kind of method and device that manganese-silicon is prepared using poor ferrous manganese ore |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710426482.0A CN107190138A (en) | 2017-06-08 | 2017-06-08 | A kind of method and device that manganese-silicon is prepared using poor ferrous manganese ore |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107190138A true CN107190138A (en) | 2017-09-22 |
Family
ID=59877804
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710426482.0A Pending CN107190138A (en) | 2017-06-08 | 2017-06-08 | A kind of method and device that manganese-silicon is prepared using poor ferrous manganese ore |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107190138A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114015873A (en) * | 2021-09-18 | 2022-02-08 | 昆明理工大学 | A method for preparing manganese-silicon alloy from lithium ore and enriching lithium |
| CN115161498A (en) * | 2022-08-19 | 2022-10-11 | 宁夏森源重工设备有限公司 | Process for producing manganese metal by large-scale submerged arc furnace |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1912159A (en) * | 2006-08-17 | 2007-02-14 | 偏关县晋电化工有限责任公司 | Production method of silicomangan of sintering powder by rotary kiln and hot filling in ore-smelting electric furnace |
| CN102766715A (en) * | 2012-07-27 | 2012-11-07 | 胡长春 | Slag-free production process of ilmenite |
| CN103695596A (en) * | 2013-12-05 | 2014-04-02 | 广西敏诚矿业有限公司 | Recycling method for producing silicomanganese alloy and medium and low carbon ferromanganese |
| CN106086275A (en) * | 2016-08-05 | 2016-11-09 | 江苏省冶金设计院有限公司 | Point stove and the method carrying out metallurgy with it are melted in a kind of combustion gas with blowing device |
| CN106319232A (en) * | 2016-08-18 | 2017-01-11 | 江苏省冶金设计院有限公司 | Method and system for processing zinc volatilization kiln slag |
| CN206986249U (en) * | 2017-06-08 | 2018-02-09 | 江苏省冶金设计院有限公司 | A kind of device that manganese-silicon is prepared using poor ferrous manganese ore |
-
2017
- 2017-06-08 CN CN201710426482.0A patent/CN107190138A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1912159A (en) * | 2006-08-17 | 2007-02-14 | 偏关县晋电化工有限责任公司 | Production method of silicomangan of sintering powder by rotary kiln and hot filling in ore-smelting electric furnace |
| CN102766715A (en) * | 2012-07-27 | 2012-11-07 | 胡长春 | Slag-free production process of ilmenite |
| CN103695596A (en) * | 2013-12-05 | 2014-04-02 | 广西敏诚矿业有限公司 | Recycling method for producing silicomanganese alloy and medium and low carbon ferromanganese |
| CN106086275A (en) * | 2016-08-05 | 2016-11-09 | 江苏省冶金设计院有限公司 | Point stove and the method carrying out metallurgy with it are melted in a kind of combustion gas with blowing device |
| CN106319232A (en) * | 2016-08-18 | 2017-01-11 | 江苏省冶金设计院有限公司 | Method and system for processing zinc volatilization kiln slag |
| CN206986249U (en) * | 2017-06-08 | 2018-02-09 | 江苏省冶金设计院有限公司 | A kind of device that manganese-silicon is prepared using poor ferrous manganese ore |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114015873A (en) * | 2021-09-18 | 2022-02-08 | 昆明理工大学 | A method for preparing manganese-silicon alloy from lithium ore and enriching lithium |
| CN115161498A (en) * | 2022-08-19 | 2022-10-11 | 宁夏森源重工设备有限公司 | Process for producing manganese metal by large-scale submerged arc furnace |
| CN115161498B (en) * | 2022-08-19 | 2024-04-12 | 宁夏森源重工设备有限公司 | Production process for producing manganese metal by large submerged arc furnace |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| KR102134202B1 (en) | Vortex Stirring Method | |
| CN105256152B (en) | The method of quick reduction melting Ti-containing slag | |
| JP7382036B2 (en) | Continuous smelting reduction iron manufacturing method | |
| CN105525055B (en) | A kind of control method of converter less-slag melting carbon period splash | |
| CN101538629A (en) | Process and device for smelting chromium irons and chromium-containing molten iron by using chromium ore powder | |
| CN105624438B (en) | A kind of method using poor manganese slag refining ferromanganese alloy | |
| CN103952571A (en) | One-step copper smelting technology and device thereof | |
| CN105838838B (en) | Method for preparing pure steel by coal gas direct reduction one-step method | |
| CN106086608B (en) | A kind of method that low-carbon manganese-silicon is produced using carbon manganese slag | |
| CN107699701A (en) | By the method containing zinc and the mixing slag recovery valuable component of iron | |
| CN101886231B (en) | Method for manufacturing nickel iron alloy | |
| CN103627846B (en) | The method of molybdenum oxide DIRECT ALLOYING steel-making | |
| CN106435310B (en) | A kind of technique with grate ferrosilicon process refining manganese silico-aluminum | |
| CN102409126B (en) | Integrated reduction ironmaking furnace and integrated reduction ironmaking process | |
| CN107190188A (en) | A kind of utilization Mn-rich slag prepares the method and device of manganese-silicon | |
| Fruehan | New steelmaking processes: drivers, requirements and potential impact | |
| CN107190138A (en) | A kind of method and device that manganese-silicon is prepared using poor ferrous manganese ore | |
| CN206986249U (en) | A kind of device that manganese-silicon is prepared using poor ferrous manganese ore | |
| CN115636607A (en) | Method and system for cooperatively treating high-iron red mud and electrolytic manganese slag | |
| CN110438352A (en) | A kind of method of rare earth yield in raising rare earth ferrosilicon alloy | |
| CN108977621A (en) | A kind of smelting process of high carbon ferro-chrome | |
| CN105087841A (en) | Spontaneous combustion reduction method iron making process | |
| CN107858530A (en) | A kind of antimony sulfide ore oxygen-enriched smelting method | |
| CN103667738A (en) | Oxygen-enriched side-blowing dual-area bath smelting furnace and method for smelting copper matte by using copper-containing complex material | |
| CN206986264U (en) | A kind of device that manganese-silicon is prepared using Mn-rich slag |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination |