CN107109299A - 含有胺添加剂的洗衣液 - Google Patents
含有胺添加剂的洗衣液 Download PDFInfo
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- 150000001412 amines Chemical class 0.000 title claims abstract description 17
- 239000007788 liquid Substances 0.000 title claims abstract description 11
- 239000003599 detergent Substances 0.000 title description 20
- 239000000654 additive Substances 0.000 title description 2
- 230000000996 additive effect Effects 0.000 title description 2
- 239000000203 mixture Substances 0.000 claims abstract description 38
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 11
- -1 alkylbenzene sulfonate Chemical class 0.000 claims abstract description 4
- 125000002853 C1-C4 hydroxyalkyl group Chemical group 0.000 claims abstract description 3
- XLYOFNOQVPJJNP-DYCDLGHISA-N deuterium hydrogen oxide Chemical compound [2H]O XLYOFNOQVPJJNP-DYCDLGHISA-N 0.000 claims abstract description 3
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 5
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical class OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 4
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 4
- 150000003839 salts Chemical class 0.000 claims description 4
- 239000002253 acid Substances 0.000 claims description 3
- 125000006699 (C1-C3) hydroxyalkyl group Chemical group 0.000 claims description 2
- 125000001931 aliphatic group Chemical group 0.000 claims description 2
- 229910052751 metal Inorganic materials 0.000 claims description 2
- 239000002184 metal Substances 0.000 claims description 2
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- 239000003795 chemical substances by application Substances 0.000 description 6
- 102000004190 Enzymes Human genes 0.000 description 5
- 108090000790 Enzymes Proteins 0.000 description 5
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 4
- 238000012544 monitoring process Methods 0.000 description 4
- 239000002904 solvent Substances 0.000 description 4
- 238000005406 washing Methods 0.000 description 4
- KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 description 3
- 125000003118 aryl group Chemical group 0.000 description 3
- 229910052698 phosphorus Inorganic materials 0.000 description 3
- 239000011574 phosphorus Substances 0.000 description 3
- 210000002374 sebum Anatomy 0.000 description 3
- 239000002689 soil Substances 0.000 description 3
- 239000004094 surface-active agent Substances 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- 241001134446 Niveas Species 0.000 description 2
- 241000625836 Ochrolechia Species 0.000 description 2
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 2
- 125000000217 alkyl group Chemical group 0.000 description 2
- 230000004075 alteration Effects 0.000 description 2
- 150000001414 amino alcohols Chemical class 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- 230000004087 circulation Effects 0.000 description 2
- 239000006260 foam Substances 0.000 description 2
- 239000004519 grease Substances 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 239000001103 potassium chloride Substances 0.000 description 2
- 235000011164 potassium chloride Nutrition 0.000 description 2
- ULWHHBHJGPPBCO-UHFFFAOYSA-N propane-1,1-diol Chemical class CCC(O)O ULWHHBHJGPPBCO-UHFFFAOYSA-N 0.000 description 2
- 235000015067 sauces Nutrition 0.000 description 2
- 159000000000 sodium salts Chemical group 0.000 description 2
- LBLYYCQCTBFVLH-UHFFFAOYSA-N 2-Methylbenzenesulfonic acid Chemical compound CC1=CC=CC=C1S(O)(=O)=O LBLYYCQCTBFVLH-UHFFFAOYSA-N 0.000 description 1
- QJRVOJKLQNSNDB-UHFFFAOYSA-N 4-dodecan-3-ylbenzenesulfonic acid Chemical class CCCCCCCCCC(CC)C1=CC=C(S(O)(=O)=O)C=C1 QJRVOJKLQNSNDB-UHFFFAOYSA-N 0.000 description 1
- KZBUYRJDOAKODT-UHFFFAOYSA-N Chlorine Chemical compound ClCl KZBUYRJDOAKODT-UHFFFAOYSA-N 0.000 description 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
- 241000287828 Gallus gallus Species 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 241001331901 Mediterranea Species 0.000 description 1
- 240000007817 Olea europaea Species 0.000 description 1
- 241001284352 Terminalia buceras Species 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
- 239000012190 activator Substances 0.000 description 1
- 150000001335 aliphatic alkanes Chemical class 0.000 description 1
- 150000007933 aliphatic carboxylic acids Chemical class 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 239000003242 anti bacterial agent Substances 0.000 description 1
- 230000002421 anti-septic effect Effects 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- SRSXLGNVWSONIS-UHFFFAOYSA-M benzenesulfonate Chemical compound [O-]S(=O)(=O)C1=CC=CC=C1 SRSXLGNVWSONIS-UHFFFAOYSA-M 0.000 description 1
- 229940077388 benzenesulfonate Drugs 0.000 description 1
- 238000004061 bleaching Methods 0.000 description 1
- 230000000903 blocking effect Effects 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical class OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000012937 correction Methods 0.000 description 1
- 239000006071 cream Substances 0.000 description 1
- 238000005202 decontamination Methods 0.000 description 1
- 230000003588 decontaminative effect Effects 0.000 description 1
- 150000002009 diols Chemical class 0.000 description 1
- 238000004851 dishwashing Methods 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007717 exclusion Effects 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 235000015220 hamburgers Nutrition 0.000 description 1
- 239000003752 hydrotrope Substances 0.000 description 1
- 230000003165 hydrotropic effect Effects 0.000 description 1
- 238000005286 illumination Methods 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 239000012669 liquid formulation Substances 0.000 description 1
- 229910003002 lithium salt Inorganic materials 0.000 description 1
- 159000000002 lithium salts Chemical class 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- 239000010705 motor oil Substances 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- XOFYZVNMUHMLCC-ZPOLXVRWSA-N prednisone Chemical compound O=C1C=C[C@]2(C)[C@H]3C(=O)C[C@](C)([C@@](CC4)(O)C(=O)CO)[C@@H]4[C@@H]3CCC2=C1 XOFYZVNMUHMLCC-ZPOLXVRWSA-N 0.000 description 1
- 101150002764 purA gene Proteins 0.000 description 1
- 235000015170 shellfish Nutrition 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 235000012424 soybean oil Nutrition 0.000 description 1
- 239000003549 soybean oil Substances 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-N sulfonic acid Chemical compound OS(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-N 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2006—Monohydric alcohols
- C11D3/201—Monohydric alcohols linear
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2041—Dihydric alcohols
- C11D3/2044—Dihydric alcohols linear
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2086—Hydroxy carboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/30—Amines; Substituted amines ; Quaternized amines
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/04—Carboxylic acids or salts thereof
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
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- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
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- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Detergent Compositions (AREA)
Abstract
一种洗衣液组合物，其包含：(a)10wt％到30wt％的直链烷基苯磺酸盐；(b)4wt％到18wt％的直链醇乙氧基化物，和(c)2wt％到10wt％的胺，所述胺具有式(I)其中R1为C1‑C4烷基或C1‑C4羟基烷基；或式(II)其中R2是C1‑C4烷基且R3是C2‑C8烷基；或其组合；和(d)水。
Description
技术领域
本发明大体上涉及一种含有胺的洗衣液组合物。
背景技术
典型地，洗衣液组合物是使用氢氧化钠调节到碱性pH。在一些情况下，其它碱已经用于此目的。举例来说，美国专利第5,035,838号揭露了使用三乙醇胺中和洗涤剂组合物。然而，这个参考文献未揭露本发明的组合物，本发明的组合物提供了改进的性能。
发明内容
本发明涉及一种洗衣液组合物，其包含：(a)10wt％到30wt％的直链烷基苯磺酸盐；(b)4wt％到18wt％的直链醇乙氧基化物；(c)2wt％到10wt％的胺，所述胺具有式(I)
其中R1为C1-C4烷基或C1-C4羟基烷基；或式(II)
其中R2是C1-C4烷基且R3是C2-C8烷基；或其组合；和(d)水。
具体实施方式
除非另外指明，否则所有百分比均是重量百分比(wt％)，且所有温度均以℃为单位。除非另外说明，否则所有操作都在室温(20至25℃)下进行。如本文中所用，术语“柠檬酸盐”是指碱金属柠檬酸盐。优选的是，柠檬酸盐是钠盐、钾盐或锂盐；优选钠或钾盐；优选钠盐。柠檬酸盐的重量百分比是基于盐(包括金属离子)的实际重量。如本文中所用，术语“脂肪酸”是指具有十二到二十二个碳原子、优选十四到十八个碳原子的脂肪族羧酸。术语“无磷”是指组合物含有小于0.5wt％的磷(按元素磷计)，优选小于0.2wt％，优选小于0.1wt％，优选的是磷检测不到。洗涤剂组合物中的重量百分比是活性成分的百分比，即，排除可能存在于可商购的表面活性剂或其它成分中的任何水。
优选的是，具有式(I)的胺存在于洗衣液组合物中的量是至少3wt％；优选至少3.5wt％，优选至少4wt％，优选至少4.5wt％；优选不超过8wt％，优选不超过7wt％，优选不超过6.5wt％。
优选的是，R1是C1-C3烷基或C1-C3羟基烷基，优选C1-C2烷基或C1-C2羟基烷基；优选甲基、乙基或羟甲基。
优选的是，具有式(II)的胺存在于洗衣液组合物中的量是至少3.5wt％；优选至少4.5wt％，优选至少5wt％，优选至少5.5wt％，优选至少6wt％；优选不超过9.5wt％，优选不超过9wt％，优选不超过8.5wt％。
优选的是，R2是C1-C3烷基，优选甲基或乙基，优选乙基。优选的是，R3是C2-C6烷基，优选C3-C6烷基，优选C3-C5烷基，优选C4烷基，优选正丁基。
优选的是，胺在洗涤剂组合物中的总量是2.5wt％到9wt％，优选2.5wt％到8.5wt％，优选3wt％到8wt％。
优选的是，洗涤剂组合物包含至少5wt％的直链醇乙氧基化物，优选至少6wt％，优选至少7wt％；优选不超过17wt％，优选不超过16wt％，优选不超过15wt％。优选的是，直链醇乙氧基化物具有直链C6-C18烷基，优选C8-C16，优选C12-C15。烷基可以是不同烷基在指定范围内的混合基团。优选的是，直链醇乙氧基化物包含五到九个环氧乙烷聚合单元，优选六到八个，优选七个。
优选的是，洗涤剂组合物包含至少12wt％的直链烷基苯磺酸盐，优选至少13wt％，优选至少14wt％；优选不超过27wt％，优选不超过25wt％，优选不超过23wt％。优选的是，烷基苯磺酸盐具有C10-C14烷基。
优选的是，洗涤剂组合物包含1wt％到15wt％脂肪酸或其金属盐；优选至少3wt％，优选至少4wt％，优选至少5wt％；优选不超过13wt％，优选不超过12wt％，优选不超过11wt％。
优选的是，洗涤剂组合物包含0.5wt％到10wt％的柠檬酸盐，优选至少1wt％，优选至少1.5wt％；优选不超过8wt％，优选不超过6wt％，优选不超过5wt％。
优选的是，洗涤剂组合物包含1wt％到15wt％的醇和/或二醇溶剂，例如丙二醇和乙醇。优选的是，溶剂是丙二醇或乙醇。优选的是，洗涤剂组合物包含至少2wt％的溶剂，优选至少3wt％，优选至少4wt％；优选不超过12wt％，优选不超过10wt％，优选不超过9wt％。
优选的是，洗涤剂组合物包含30wt％到70wt％的水；优选至少35wt％，优选至少38wt％，优选至少41wt％，优选至少43wt％；优选不超过65wt％，优选不超过62wt％，优选不超过59wt％，优选不超过57wt％。
优选的是，洗涤剂组合物包含0.5wt％到10wt％水溶助溶剂或其盐，优选0.5wt％到6wt％，优选1wt％到5wt％。水溶增溶剂的优选实例是芳香族磺酸，优选甲苯磺酸。
洗涤剂组合物中的其它组分可以包括例如表面活性剂、氧气和/或氯气漂白剂、漂白剂活化剂、酶、泡沫抑制剂、颜料、芳香剂、抗细菌剂和填充剂。芳香剂、染料、泡沫抑制剂、酶和抗菌剂总计通常不超过组合物的5wt％。
优选的是，洗涤剂组合物具有7.5到10的pH，优选至少8，优选不超过9.5，优选不超过9。
洗涤剂组合物可以在任何典型的洗涤机中、在典型的操作条件下使用。洗涤过程中典型的水温优选20℃至85℃，优选25℃至70℃。按总液体在洗碗机中的百分比计的组合物典型浓度优选0.1wt％到1wt％，优选0.2wt％到0.7wt％。通过选择适当的产品形态和添加时间，组合物可以存在于预洗、主洗、倒数第二次冲洗、最后冲洗或这些循环的任何组合中。
优选的是，洗涤剂组合物基本上不含酶，即，其含有小于0.5wt％的酶，优选小于0.2wt％，优选小于0.1wt％，优选的是其含的酶检测不到。优选的是，洗涤剂组合物含有小于2wt％的胺氧化物表面活性剂，优选小于1wt％，优选小于0.5wt％，优选小于0.2wt％。优选的是，洗涤剂组合物基本上不含除式(I)和(II)胺之外的胺，即，这些其它胺存在的总量小于0.7wt％，优选小于0.5wt％，优选小于0.3wt％，优选小于0.2wt％。
实例
通过考虑初始清洁(去污)来研究陶氏高垢配制液(DOW High Duty Liquidformulation)中的氨基醇相对于传统中和剂(NaOH)中和各种污渍的益处(洗涤循环，30℃)。洗涤之前和洗涤之后测量每种污渍的色彩。
方案：
已经按以下配方添加各种氨基醇：
所用中和剂％(以便获得8.5的pH)：
测试所用的污渍监测剂如下：
污渍监测剂：得自测试材料中心(Center for Test Materials)-Ref MON DOW 7
| 污渍代码 | 污渍性质 |
| H078 | 唇膏#1 |
| H156 | 皮脂粉 |
| H038 | 褐色鞋油 |
| H150 | 大豆油/紫色染料 |
| H013 | 脏马达油 |
| H032 | 锈污 |
| H084 | 妮维雅(nivea visage)面霜 |
| H135 | 机械油脂 |
| H082 | 含有碳黑的贝伊皮脂(Sebum bey) |
| H066 | 特芙娜(tapenada)，黑橄榄 |
| H018 | 经研磨的土壤 |
| H134 | 汉堡油脂 |
| H126 | 含有紫色染料的Pura植物油 |
| H056 | 地中海酱(Sauce Mediterranea)，橄榄酱 |
| H162 | 烧烤鸡脂肪 |
| H145 | 网球场粘土 |
每台机器装载有：
1种污渍监测剂+1SBL(土壤压载载荷是8g)
60g洗涤剂
3.3kg压载载荷
自来水：TH，约18°F
在30℃进行的六轮不同循环(每轮循环使用新的污渍监测剂)已经进行(＝6次重复)
测量
土壤释放效应已经通过每种污渍的Delta E(ΔE)测量。
Delta E定义为未洗涤的污渍与已洗涤的污渍之间的色差(在L*a*b*色空间内)。
在洗涤之前及之后，通过使用Epson扫描软件的Epson Perfection 4490Photo扫描仪，在以下设置下测量每种污渍：
■专业模式.
■文件类型：反射
■文件来源：文件表格
■自动曝光类型：光照
■图像类型：48位色彩
■扫描品质：最佳
■分辨率：400dpi
■无色彩校正
■防UV 400nm
接着，使用软件Image J 1.4.3.67版(获自因特网的自由软件)，使用提供L*a*b*色空间内的色彩信息的宏指令，分析每种污渍的色彩。
结景(6轮不同循环的平均值，30℃)
Delta E定义为未洗涤的污渍与已洗涤的污渍之间的色差(在L*a*b*色空间内)。
结果列表于下方。
Delta E
标准差
Claims (9)
1.一种洗衣液组合物，其包含：(a)10wt％到30wt％的直链烷基苯磺酸盐；(b)4wt％到18wt％的直链醇乙氧基化物，和(c)2wt％到10wt％的胺，所述胺具有式(I)
其中R1为C1-C4烷基或C1-C4羟基烷基；或式(II)
其中R2是C1-C4烷基且R3是C2-C8烷基；或其组合；和(d)水。
2.根据权利要求1所述的组合物，其中R1是C1-C3烷基或C1-C3羟基烷基。
3.根据权利要求2所述的组合物，其中R2是C1-C3烷基且R3是C2-C6烷基。
4.根据权利要求3所述的组合物，其包含30wt％到70wt％的水。
5.根据权利要求4所述的组合物，其包含1wt％到15wt％脂肪酸或其金属盐。
6.根据权利要求5所述的组合物，其中R1是甲基、乙基或羟甲基。
7.根据权利要求6所述的组合物，其中R2是甲基或乙基且R3是C3-C5烷基。
8.根据权利要求1所述的组合物，其中所述胺具有式(I)。
9.根据权利要求1所述的组合物，其中所述胺具有式(II)。
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP14290319.4 | 2014-10-22 | ||
| EP14290319 | 2014-10-22 | ||
| PCT/US2015/056607 WO2016064967A1 (en) | 2014-10-22 | 2015-10-21 | Liquid laundry detergent containing amine additives |
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| CN107109299A true CN107109299A (zh) | 2017-08-29 |
| CN107109299B CN107109299B (zh) | 2020-06-05 |
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| CN201580053658.1A Active CN107109299B (zh) | 2014-10-22 | 2015-10-21 | 含有胺添加剂的洗衣液 |
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| Country | Link |
|---|---|
| US (1) | US20170335239A1 (zh) |
| EP (1) | EP3209757B1 (zh) |
| JP (1) | JP6630354B2 (zh) |
| CN (1) | CN107109299B (zh) |
| AU (1) | AU2015335977B2 (zh) |
| BR (1) | BR112017007537A2 (zh) |
| WO (1) | WO2016064967A1 (zh) |
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| US4079078A (en) * | 1974-06-21 | 1978-03-14 | The Procter & Gamble Company | Liquid detergent compositions |
| CN88103546A (zh) * | 1987-06-10 | 1988-12-28 | 阿尔布赖特-威尔逊公司 | 液体洗涤组合物 |
| US5035838A (en) * | 1989-10-24 | 1991-07-30 | Shell Oil Company | Nonionic surfactant based liquid detergent formulation containing an alkenyl or alkyl carboxysulfonate component |
| WO2000020545A1 (en) * | 1998-10-06 | 2000-04-13 | Unilever Plc | Hard surface cleaning bar |
| CN1332786A (zh) * | 1998-11-06 | 2002-01-23 | 宝洁公司 | 含las的水性、液体洗衣用洗涤剂组合物的亲水指数 |
| CN1806039A (zh) * | 2003-06-16 | 2006-07-19 | 荷兰联合利华有限公司 | 洗涤剂组合物 |
| CN101981171A (zh) * | 2008-04-07 | 2011-02-23 | 埃科莱布有限公司 | 超浓缩液体脱脂剂组合物 |
| CN103221525A (zh) * | 2010-11-16 | 2013-07-24 | 陶氏环球技术有限责任公司 | 包含低voc、低气味烷醇胺的硬质表质面清洁剂 |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0100125B1 (en) * | 1982-07-27 | 1988-12-07 | THE PROCTER & GAMBLE COMPANY | Liquid detergent compositions comprising coacervate mixture of alkylcellulose and carboxymethylcellulose and method for preparing them |
| US4560492A (en) * | 1984-11-02 | 1985-12-24 | The Procter & Gamble Company | Laundry detergent composition with enhanced stain removal |
| US9879204B2 (en) * | 2010-03-17 | 2018-01-30 | Method Products, Pbc | Liquid cleaning compositions with lower freezing point |
| JP5727032B2 (ja) * | 2010-12-17 | 2015-06-03 | ザ プロクター アンド ギャンブルカンパニー | 両性ポリカルボキシレートポリマーを有する洗浄組成物 |
| WO2012161979A1 (en) * | 2011-05-20 | 2012-11-29 | Dow Global Technologies Llc | Method of promoting soil release from fabrics |
-
2015
- 2015-10-21 AU AU2015335977A patent/AU2015335977B2/en not_active Ceased
- 2015-10-21 US US15/520,890 patent/US20170335239A1/en not_active Abandoned
- 2015-10-21 BR BR112017007537-7A patent/BR112017007537A2/pt not_active Application Discontinuation
- 2015-10-21 CN CN201580053658.1A patent/CN107109299B/zh active Active
- 2015-10-21 EP EP15787840.6A patent/EP3209757B1/en active Active
- 2015-10-21 WO PCT/US2015/056607 patent/WO2016064967A1/en not_active Ceased
- 2015-10-21 JP JP2017518429A patent/JP6630354B2/ja active Active
Patent Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4079078A (en) * | 1974-06-21 | 1978-03-14 | The Procter & Gamble Company | Liquid detergent compositions |
| CN88103546A (zh) * | 1987-06-10 | 1988-12-28 | 阿尔布赖特-威尔逊公司 | 液体洗涤组合物 |
| US5035838A (en) * | 1989-10-24 | 1991-07-30 | Shell Oil Company | Nonionic surfactant based liquid detergent formulation containing an alkenyl or alkyl carboxysulfonate component |
| WO2000020545A1 (en) * | 1998-10-06 | 2000-04-13 | Unilever Plc | Hard surface cleaning bar |
| CN1332786A (zh) * | 1998-11-06 | 2002-01-23 | 宝洁公司 | 含las的水性、液体洗衣用洗涤剂组合物的亲水指数 |
| CN1806039A (zh) * | 2003-06-16 | 2006-07-19 | 荷兰联合利华有限公司 | 洗涤剂组合物 |
| CN101981171A (zh) * | 2008-04-07 | 2011-02-23 | 埃科莱布有限公司 | 超浓缩液体脱脂剂组合物 |
| CN103221525A (zh) * | 2010-11-16 | 2013-07-24 | 陶氏环球技术有限责任公司 | 包含低voc、低气味烷醇胺的硬质表质面清洁剂 |
Also Published As
| Publication number | Publication date |
|---|---|
| CN107109299B (zh) | 2020-06-05 |
| WO2016064967A1 (en) | 2016-04-28 |
| AU2015335977A1 (en) | 2017-05-18 |
| AU2015335977B2 (en) | 2019-05-30 |
| BR112017007537A2 (pt) | 2018-01-30 |
| JP2017531713A (ja) | 2017-10-26 |
| EP3209757A1 (en) | 2017-08-30 |
| EP3209757B1 (en) | 2018-08-15 |
| JP6630354B2 (ja) | 2020-01-15 |
| US20170335239A1 (en) | 2017-11-23 |
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