CN107107486B - Method for producing hybrid structural components for motor vehicles and corresponding hybrid structural components - Google Patents
Method for producing hybrid structural components for motor vehicles and corresponding hybrid structural components Download PDFInfo
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- B29C70/04—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
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- B29C70/882—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts characterised primarily by possessing specific properties, e.g. electrically conductive or locally reinforced partly or totally electrically conductive, e.g. for EMI shielding
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B62—LAND VEHICLES FOR TRAVELLING OTHERWISE THAN ON RAILS
- B62D—MOTOR VEHICLES; TRAILERS
- B62D29/00—Superstructures, understructures, or sub-units thereof, characterised by the material thereof
- B62D29/001—Superstructures, understructures, or sub-units thereof, characterised by the material thereof characterised by combining metal and synthetic material
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- Chemical & Material Sciences (AREA)
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Abstract
Description
技术领域technical field
本发明涉及用于生产机动车辆的混合结构部件的方法及相应的混合结构部件。The present invention relates to a method for producing a hybrid structural part for a motor vehicle and a corresponding hybrid structural part.
背景技术Background technique
术语混合结构部件是指由几种不同材料形成的结构部件,尤其是由金属材料和一种或更多种聚合物材料形成的结构部件。The term hybrid structural component refers to a structural component formed from several different materials, especially structural components formed from metallic materials and one or more polymeric materials.
机动车辆的某些结构构件特别在冲击期间受到应力,并且必须能够吸收一部分冲击能量以保持车辆结构的完整性。这种结构构件还必须足够坚固以经得住各种结构功能。例如在机动车中央支柱的情况下,在侧面碰撞期间,机动车中央支柱受到较高程度的应力并且还必须通过铰链保持后门并通过前门的闭合系统保持对前门的抵抗力。Certain structural components of a motor vehicle are particularly stressed during an impact and must be able to absorb a portion of the impact energy to maintain the structural integrity of the vehicle. Such structural members must also be strong enough to withstand various structural functions. In the case of a motor vehicle center pillar, for example, during a side impact, the motor vehicle center pillar is stressed to a high degree and must also hold the rear door by hinges and the front door resistance by the closing system of the front door.
此外,制造商正在使机动车辆结构变轻,以减少机动车辆结构的能量消耗。In addition, manufacturers are making motor vehicle structures lighter in order to reduce the energy consumption of motor vehicle structures.
由不同材料形成的所谓的混合结构是已知的,这些已知的混合结构通常由金属材料和聚合物材料形成。So-called hybrid structures formed from different materials are known, and these known hybrid structures are generally formed from metallic and polymeric materials.
文献DE3011336A1公开了一种通过粘合或压制来组装金属板和纤维增强聚合物材料而获得的轻质部件。所描述的方法生产出具有加强的外观的部件,但未提及所获得的部件的强度。Document DE3011336A1 discloses a lightweight component obtained by gluing or pressing to assemble sheet metal and fiber-reinforced polymer material. The described method produces parts with a reinforced appearance, but makes no mention of the strength of the parts obtained.
文献EP0370342A2描述了一种易于生产且具有良好的强度和刚度的轻质结构部件。该部件由下述中空件形成:该中空件在其腔内具有由注入的聚合物材料制成的一组肋。中空的该部件可以是金属的或者可以是通过热压制形成的纤维增强聚合物。所述一组肋通过交叉连接接合至中空部件。这种类型的连接具有使中空部件变弱的缺点。此外,通过不连续点的这种连接不允许中空部件和肋组以最佳方式组合工作并且阻碍重量的减小。Document EP0370342A2 describes a lightweight structural component that is easy to produce and has good strength and stiffness. The part is formed from a hollow piece having a set of ribs in its cavity made of injected polymer material. The hollow part may be metallic or may be a fiber reinforced polymer formed by hot pressing. The set of ribs is joined to the hollow member by a cross connection. This type of connection has the disadvantage of weakening the hollow part. Furthermore, this connection by means of discontinuities does not allow the hollow part and the rib set to work optimally in combination and hinders weight reduction.
文献EP1550604B1描述了一种用于生产混合结构部件的方法,其中,预先形成涂覆有热活化表面涂层的金属材料板,随后将热塑性材料施用至金属材料板的具有表面涂层的面。尽管这种类型的混合部件的强度适用于半结构部件,但是会证明这种类型的混合部件的强度不足以经受冲击,特别是对于机动车底盘的结构部件比如中央支柱、支柱A或C、纵向外侧梁、车顶横梁、冲击梁或任何其他车辆结构构件。Document EP1550604B1 describes a method for producing hybrid structural components, in which a sheet of metallic material coated with a heat-activated surface coating is preformed and a thermoplastic material is subsequently applied to the surface coated side of the sheet of metallic material. Although the strength of this type of hybrid component is suitable for semi-structural components, this type of hybrid component will prove insufficient to withstand impact, especially for structural components of motor vehicle chassis such as center pillars, pillars A or C, longitudinal Outboard beams, roof rails, impact beams or any other vehicle structural member.
文献DE 102009042272A1描述了一种结构部件,该结构部件具有放置在金属板上的由聚合物材料制成的加强层以及由施用至该加强层的热塑性材料制成的加强结构,并且该结构部件具有肋。金属板的边缘不被加强层或加强结构覆盖。Document DE 102009042272 A1 describes a structural component having a reinforcing layer made of polymer material placed on a metal sheet and a reinforcing structure made of thermoplastic material applied to the reinforcing layer, and the structural component has rib. The edges of the sheet metal are not covered by reinforcement layers or reinforcement structures.
发明内容SUMMARY OF THE INVENTION
本发明旨在通过提出下述方法来克服这些缺陷:该方法为用于生产轻质且具有抵抗力、尤其是在冲击的情况下具有抵抗力的用于机动车辆的混合结构部件的方法。The present invention aims to overcome these drawbacks by proposing a method for producing hybrid structural components for motor vehicles that are lightweight and resistant, especially in the event of impacts.
关于此,本发明的目的涉及一种用于生产机动车辆的混合结构部件的方法,其特征在于,该方法包括以下步骤:In this regard, the object of the present invention relates to a method for producing a hybrid structural component for a motor vehicle, characterized in that the method comprises the following steps:
(a)成形金属材料板,(a) Sheets of formed metal material,
(b)提供复合材料板,该复合材料板包含浸入或嵌入聚合物基质、尤其是热塑性或热固性聚合物基质中的至少一个纤维层,所述纤维层选自单向纤维层和织造纤维层,(b) providing a composite sheet comprising at least one fibrous layer impregnated or embedded in a polymer matrix, especially a thermoplastic or thermosetting polymer matrix, the fibrous layer being selected from the group consisting of unidirectional fiber layers and woven fiber layers,
(c)在成形之前或成形之后在所述金属材料板的一个面上施用粘合材料层,或者在成形之前或成形之后在所述复合材料板的一个面上施用粘合材料层,(c) applying a layer of adhesive material on one side of the sheet of metallic material before or after forming, or applying a layer of adhesive material on one side of the sheet of composite material before or after forming,
(d)通过将所述复合材料板成形为所述金属材料板的形状并借助所述粘合材料层将复合材料板接合至金属材料板而形成混合构件,(d) forming a hybrid member by forming the composite material sheet into the shape of the metallic material sheet and joining the composite material sheet to the metallic material sheet by means of the adhesive material layer,
(e)通过使用聚合物材料(例如热塑性或热固性聚合物)对因此形成的混合构件的至少一部分进行二次成型(overmolding)以形成混合结构部件来生产硬化构件。(e) producing a hardened member by overmolding at least a portion of the thus formed hybrid member using a polymeric material, such as a thermoplastic or thermoset polymer, to form a hybrid structural component.
这种方法允许获得特别具有抵抗力的、尤其是对冲击具有抵抗力且轻质的混合结构部件。金属材料板提供良好的抗伸长率,并且在显著变形的情况下,复合材料板与金属材料板的形状进行匹配并且在增大组合件的冲击吸收能力同时使组合件的刚性和机械强度增大。最后,二次成型的聚合物材料使混合结构部件硬化及固结。This method allows to obtain particularly resistant, especially impact-resistant, and lightweight hybrid structural components. The metal sheet provides good resistance to elongation, and in the event of significant deformation, the composite sheet matches the shape of the metal sheet and increases the stiffness and mechanical strength of the assembly while increasing the impact absorption capacity of the assembly. big. Finally, the overmolded polymer material hardens and consolidates the hybrid structural component.
根据本发明,混合构件的成形步骤(d)实施成使得复合材料板部分地覆盖所述金属材料板的面,生产硬化构件的步骤(e)实施成使得聚合物材料至少部分地覆盖金属材料板的面的未被所述复合材料板覆盖的部分。According to the invention, the forming step (d) of the hybrid member is carried out such that the sheet of composite material partially covers the face of the sheet of metallic material, and the step (e) of producing the hardened member is carried out such that the polymer material at least partially covers the sheet of metallic material the portion of the face not covered by the composite sheet.
应当指出的是,步骤(a)和(b)可以按任何顺序进行;这些步骤可以颠倒。It should be noted that steps (a) and (b) can be performed in any order; the steps can be reversed.
步骤(a)step (a)
对于成形步骤(a),该步骤可以是冷或热加工步骤。金属材料板可以是金属板,该金属板的厚度例如为0.1mm至1.5mm、有利地为0.1mm至1mm、优选地为0.2mm至0.8mm。该金属材料板可以是铝、镁、钛或基于这些金属中的一种或更多种的合金,或者可以是铁基合金,例如钢或不锈钢。金属材料可以是可冷加工的材料、尤其是钢。For forming step (a), this step may be a cold or hot working step. The sheet of metallic material may be a sheet of metal having a thickness of, for example, 0.1 mm to 1.5 mm, advantageously 0.1 mm to 1 mm, preferably 0.2 mm to 0.8 mm. The sheet of metallic material may be aluminium, magnesium, titanium or an alloy based on one or more of these metals, or may be an iron based alloy such as steel or stainless steel. The metallic material may be a cold workable material, especially steel.
金属板优选地形成最终的混合结构部件的外部部分。由于该板是金属的,因此可以通过通常的焊接技术将该板组装在车身上,而不需要更改工厂组装线上当前存在的方法。The metal sheet preferably forms the outer part of the final hybrid structural component. Because the plate is metal, it can be assembled to the body by usual welding techniques without changing the methods currently existing on the factory assembly line.
步骤(b)step (b)
对于提供复合材料板的步骤(b),该板包含浸入或嵌入热塑性或热固性聚合物基质中的至少一个纤维层,所述纤维层选自单向纤维层和织造纤维层。因此,纤维层形成连续的加强部分,该加强部分在部件的整个长度或部分长度上或在部件的整个表面或部分表面上延伸。因此,一个或更多个这种类型的层的存在提高了混合结构部件的强度。For step (b) of providing a composite sheet, the sheet comprises at least one fiber layer selected from the group consisting of unidirectional fiber layers and woven fiber layers impregnated or embedded in a thermoplastic or thermoset polymer matrix. The fibrous layer thus forms a continuous reinforcement which extends over the entire or part of the length of the component or over the entire or part of the surface of the component. Thus, the presence of one or more layers of this type increases the strength of the hybrid structural component.
当复合材料板具有多层单向纤维时,所述多层单向纤维优选地全部在相同的方向上对齐。一般而言,单向纤维的方向选择成与要生产的部件的最大尺寸的方向平行。When the composite sheet has multiple layers of unidirectional fibers, the multiple layers of unidirectional fibers are preferably all aligned in the same direction. In general, the direction of the unidirectional fibers is chosen to be parallel to the direction of the largest dimension of the part to be produced.
在存在若干层织造纤维的情况下,纤维的主方向可以彼此相同或不同。Where there are several layers of woven fibers, the main directions of the fibers may be the same or different from each other.
有利地,织造纤维网的纤维或单向纤维可以沿着要生产的结构部件的最大尺寸的方向布置,以沿着部件的最大尺寸提高部件的强度。Advantageously, the fibers or unidirectional fibers of the woven web may be arranged in the direction of the largest dimension of the structural component to be produced to increase the strength of the component along the largest dimension of the component.
根据实施方案,复合材料板可以包含至少一个单向纤维层和至少一个织造纤维层。单向纤维提高混合结构部件在纤维方向上的刚度和抗应力性,同时织造纤维提高混合结构部件的抗冲击性。由此获得特别能够抵抗并吸收冲击的混合结构部件。According to embodiments, the composite panel may comprise at least one layer of unidirectional fibers and at least one layer of woven fibers. The unidirectional fibers increase the stiffness and stress resistance of the hybrid structural component in the fiber direction, while the woven fibers increase the impact resistance of the hybrid structural component. This results in a hybrid structural component that is particularly able to resist and absorb shocks.
有利地,步骤(b)中提供的复合材料板可以包含相同或不同的纤维的一个或更多个层,所述纤维选自玻璃纤维、碳纤维、玄武岩纤维、金属纤维和芳族聚酰胺纤维。Advantageously, the composite sheet provided in step (b) may comprise one or more layers of identical or different fibres selected from glass fibres, carbon fibres, basalt fibres, metal fibres and aramid fibres.
优选地,复合材料板可以包含至少一个单向碳纤维层和至少一个织造玻璃纤维层。Preferably, the composite panel may comprise at least one layer of unidirectional carbon fibers and at least one layer of woven glass fibers.
本发明不受特定数目的单向纤维层和/或织造纤维层的限制。层数例如可以根据期望的强度、尤其是断裂强度来选择,以及/或者可以根据期望的最大厚度来选择。复合材料板的厚度例如可以为3mm至6mm、有利地为3mm至5mm、优选地为4mm至5mm。The present invention is not limited to a particular number of unidirectional fiber layers and/or woven fiber layers. The number of layers can be selected, for example, according to the desired strength, in particular the breaking strength, and/or according to the desired maximum thickness. The thickness of the composite material sheet may for example be 3 mm to 6 mm, advantageously 3 mm to 5 mm, preferably 4 mm to 5 mm.
有利地,复合材料板可以包含交替的单向纤维层的叠层和织造纤维层的叠层。这些叠层可以包括2层至6层叠置的纤维。叠层有利地可以对称分布。例如,可以预见多达7个叠层或更多个叠层。例如,由2层至6层纤维构成的5个叠层。Advantageously, the composite panel may comprise alternating stacks of unidirectional fiber layers and woven fiber layers. These stacks may include 2 to 6 layers of fibers stacked. The stacks can advantageously be distributed symmetrically. For example, up to 7 stacks or more are envisioned. For example, 5 stacks consisting of 2 to 6 layers of fibers.
复合材料板的纤维含量可以是可变化的。例如,复合材料板的纤维含量为40重量%至85重量%、有利地为50%至85%、优选为55%至80%。The fiber content of the composite panels can be variable. For example, the fibre content of the composite sheet is from 40% to 85% by weight, advantageously from 50% to 85%, preferably from 55% to 80%.
复合材料板中存在的热塑性聚合物材料可以选自以下各种:脂族聚酰胺(PA)、聚邻苯二甲酰胺(PPA)、聚对苯二甲酸丁二醇酯(PBT)、聚对苯二甲酸乙二醇酯(PET)、聚碳酸酯(PC)、甚至聚丙烯以及这些聚合物材料的混合物。例如,可以使用聚酰胺66(PA66)或聚酰胺6(PA6)。The thermoplastic polymer material present in the composite panel may be selected from the following: aliphatic polyamide (PA), polyphthalamide (PPA), polybutylene terephthalate (PBT), polypara Ethylene phthalate (PET), polycarbonate (PC), and even polypropylene and blends of these polymer materials. For example, polyamide 66 (PA66) or polyamide 6 (PA6) can be used.
复合材料板中存在的热固性聚合物材料可以选自聚酯树脂、酯类乙烯基、环氧树脂、聚氨酯或这些聚合物材料的混合物。因此可以形成SMC(片状成型化合物)型产品。The thermoset polymeric material present in the composite panel may be selected from polyester resins, ester vinyls, epoxies, polyurethanes or mixtures of these polymeric materials. Thus, an SMC (Sheet Molding Compound) type product can be formed.
复合材料板可以通过已知的方法生产,这些已知的方法比如为:在双带压机上可能在高压下通过压塑(例如通过压延)的RTM(树脂转印成型)方法、通过挤压成型或其他合适的方法例如聚合作用期间的单体浸渍方法。Composite panels can be produced by known methods such as: RTM (Resin Transfer Molding) methods, possibly by compression molding (eg by calendering) on a twin belt press, by extrusion Shaping or other suitable methods such as monomer impregnation during polymerization.
这种复合材料板为最终的混合结构部件提供较高的能量吸收能力,从而提高最终的混合结构部件对冲击的抵抗力。复合材料板在经受严重变形时同时具有多种失效模式,其中,每种失效模式都吸收能量。这些失效模式尤其是:This composite panel provides a higher energy absorption capacity for the final hybrid structural component, thereby increasing the impact resistance of the final hybrid structural component. Composite panels have multiple simultaneous failure modes when subjected to severe deformation, each of which absorbs energy. These failure modes are in particular:
-聚合物裂开,- the polymer cracks,
-纤维裂开,- fibers split,
-复合材料层之间分层(存在多个层时),- delamination between composite layers (when multiple layers are present),
-纤维与聚合物之间的内聚性损失,- loss of cohesion between fiber and polymer,
-纤维与聚合物之间的摩擦。- Friction between fiber and polymer.
步骤(c)step (c)
该步骤可以在成形步骤(a)之前或之后执行、优选地在成形步骤(a)之后进行,或者在步骤(b)之后执行。This step may be performed before or after the forming step (a), preferably after the forming step (a), or after the step (b).
粘合材料层可以是聚合物材料层、优选地与复合材料板的聚合物化学上相容,但这不是强制性的。The adhesive material layer may be a polymer material layer, preferably chemically compatible with the polymer of the composite panel, but this is not mandatory.
有利地,粘合材料在预定温度条件下能够将复合材料板接合至金属材料板。粘合材料被称为“可热活化的”,也称为“热熔”粘合剂。Advantageously, the adhesive material is capable of joining the composite sheet to the metallic sheet under predetermined temperature conditions. Adhesive materials are referred to as "heat-activatable", also known as "hot melt" adhesives.
例如,粘合材料是可热活化的的条件是复合材料板的热压印条件或二次成型材料的二次成型条件。For example, the conditions under which the adhesive material is heat activatable are the hot embossing conditions of the composite sheet or the overmolding conditions of the overmolded material.
粘合材料可以是可交联材料。对于这种类型的材料,随后的软化是不可能的、尤其是在暴露于预定温度下给定持续时间(有利的是暴露于复合材料板的热压印条件中的预定温度下给定持续时间或者暴露于生产线上的电泳循环和涂装中的预定温度下给定持续时间)时。这具有能够将复合材料板以足够的保持力至少部分地接合至金属材料板上的优点,以在限制或甚至阻止两个板相对于彼此移动的同时允许复合材料板经过机动车制造商的生产线上的所有加热步骤,这使得即使交联反应在制造商的加热过程期间结束,两个板也能够保持处于正确的几何位置。The binding material may be a crosslinkable material. Subsequent softening is not possible for this type of material, especially with exposure to a predetermined temperature for a given duration (advantageously exposure to a predetermined temperature in hot embossing conditions of a composite sheet) for a given duration Or when exposed to electrophoresis cycles on the production line and at predetermined temperatures in coating for a given duration). This has the advantage of being able to at least partially join the composite sheet to the metallic sheet with sufficient holding force to allow the composite sheet to pass through the motor vehicle manufacturer's production line while limiting or even preventing movement of the two sheets relative to each other This allows the two plates to remain in the correct geometrical position even if the cross-linking reaction ends during the manufacturer's heating process.
粘合材料也可以是非交联热熔材料。非交联热熔粘合材料可以选自共聚酯类或共聚酰胺类材料、或者聚烯烃类弹性体热塑性塑料。The adhesive material can also be a non-crosslinked hot melt material. The non-crosslinked hot melt adhesive material may be selected from copolyester-based or copolyamide-based materials, or polyolefin-based elastomeric thermoplastics.
可交联热熔粘合材料可以选自共聚酰胺类材料,可交联热熔粘合材料可能包含异氰酸酯、环氧化物或甚至聚烯烃。粘合剂型粘合材料在WO2010-136241A1和EP2435246A1中进行了描述。The cross-linkable hot-melt adhesive material may be selected from copolyamide type materials, which may comprise isocyanates, epoxies or even polyolefins. Adhesive-type adhesive materials are described in WO2010-136241A1 and EP2435246A1.
也可以想到提供其他类型的材料,只要这些材料能够进行热粘合,比如HCM(可热熔固化的)聚氨酯粘合剂或例如在CA 2321884C中描述的基于硅酮的材料,该列举不是限制性的。It is also conceivable to provide other types of materials, as long as these materials are capable of thermal bonding, such as HCM (hot melt curable) polyurethane adhesives or silicone based materials such as described in CA 2321884C, this listing not limiting of.
例如,可以使用以下材料:For example, the following materials can be used:
-可交联热熔粘合材料:X1333-P1、HCM555、Lohmann和 - Crosslinkable Hot Melt Adhesive Materials: X1333-P1, HCM555, Lohmann and
-非交联热熔粘合材料:EMSCE20、EMSCT100和391。-Non-crosslinked hot melt adhesive material: EMS CE20, EMS CT100 and 391.
步骤(d)step (d)
在混合构件的成形步骤(d)中,复合材料板可以在被施用至金属材料板之前成形,并且使用粘合材料层将复合材料板附接至金属材料板。然而,这种成形步骤有利地与接合步骤同时执行,以使得便于零件的生产并缩短制造时间。In forming step (d) of the hybrid member, the composite material sheet may be formed before being applied to the metallic material sheet, and the composite material sheet is attached to the metallic material sheet using a layer of adhesive material. However, this forming step is advantageously performed at the same time as the joining step, so as to facilitate the production of the parts and shorten the manufacturing time.
执行该步骤(d),使得复合材料板将所述金属材料板的面部分地覆盖。This step (d) is performed so that the composite material sheet partially covers the face of the metallic material sheet.
成形尤其可以通过热压印执行、优选地直接对金属材料板执行。Shaping can be carried out in particular by hot embossing, preferably directly on the sheet of metallic material.
复合材料板借助粘合材料层在预定条件下接合至金属材料板,该预定条件尤其包括温度、压力和可能的持续时间。The composite material sheet is joined to the metallic material sheet by means of a layer of adhesive material under predetermined conditions, which include, inter alia, temperature, pressure and possible duration.
有利地,这些预定的温度条件与复合材料板的热压印条件相对应,复合材料板的热压印条件可以根据复合材料板的组成而变化。Advantageously, these predetermined temperature conditions correspond to thermal embossing conditions of the composite sheet, which may vary depending on the composition of the composite sheet.
有利地,混合构件的成型步骤(d)可以是在有效的温度和压力条件下将所述复合材料板热压印(也称为热压)在所述金属材料板上以使所述复合材料板成形的步骤,粘合材料层定位在复合材料板与金属材料板之间,所述粘合材料在热压印条件下能够将复合材料板接合至金属材料板。Advantageously, the forming step (d) of the hybrid member may be hot embossing (also referred to as hot pressing) the composite material sheet on the metal material sheet under effective temperature and pressure conditions to make the composite material sheet. In the step of forming the sheet, a layer of adhesive material is positioned between the sheet of composite material and the sheet of metallic material, the adhesive material capable of joining the sheet of composite material to the sheet of metallic material under hot embossing conditions.
这尤其允许对于步骤(d)和(e)使用相同的工具,随后例如通过注塑成型或压塑成型来执行步骤(e)。在通过压塑执行步骤(e)的情况下,该步骤可以与步骤(d)同时进行。This allows, inter alia, to use the same tool for steps (d) and (e), after which step (e) is carried out, eg by injection moulding or compression moulding. In the case where step (e) is performed by compression molding, this step may be performed simultaneously with step (d).
例如,可以按照以下方式执行热压印。将复合材料板在热压印操作之前加热到足够的温度以使其软化,例如加热到等于或大于复合材料板的聚合物的熔化温度的温度。随后将软化的复合材料板放置在压印模具中、金属材料板上。一旦模具闭合,就在有效压力下对复合材料板执行压印操作,以使复合材料板成形。例如,施加的压力可以为80巴至170巴、优选地为100巴至150巴。在施加压力时,模具可以可选地保持在70℃至160℃,优选地80℃至140℃的温度。For example, thermal embossing can be performed in the following manner. The composite sheet is heated to a temperature sufficient to soften it prior to the hot embossing operation, eg, to a temperature equal to or greater than the melting temperature of the polymers of the composite sheet. The softened composite sheet is then placed in an embossing mold, a sheet of metallic material. Once the mold is closed, an embossing operation is performed on the composite sheet under effective pressure to shape the composite sheet. For example, the applied pressure may be 80 to 170 bar, preferably 100 to 150 bar. The mould may optionally be maintained at a temperature of 70°C to 160°C, preferably 80°C to 140°C while the pressure is being applied.
在提供复合材料板的步骤中或在压印步骤结束时,有利地可以考虑给出从复合材料板回收磨碎料并通过对所述板进行切割来实现的步骤,或者给出从复合材料板回收磨碎料并在模具闭合时和/或压印操作期间通过对所述网或失效部件(不合格品)进行切割来实现的步骤。这些磨碎料可以在步骤(e)中被研磨并被有利地重新使用。During the step of providing the composite sheet or at the end of the embossing step, it may advantageously be envisaged to give a step of recovering the ground stock from the composite sheet and to achieve it by cutting said sheet, or to give a step from the composite sheet The step of recovering the ground stock and effecting it by cutting the web or failed parts (defects) when the die is closed and/or during the stamping operation. These grounds can be ground in step (e) and advantageously reused.
步骤(e)step (e)
对于步骤(e),涉及硬化构件的生产,该步骤使用热塑性或热固性聚合物材料对在步骤(d)中形成的混合构件的至少一部分实施二次成型。该步骤尤其通过增大混合部件的惯性来加强混合部件。For step (e), which involves the production of a hardened member, this step overmolding at least a portion of the hybrid member formed in step (d) using a thermoplastic or thermosetting polymer material. This step strengthens the mixing element in particular by increasing the inertia of the mixing element.
实施步骤(e),由此聚合物材料至少部分地覆盖金属材料板的面的未被所述复合材料板覆盖的部分。Step (e) is carried out whereby the polymeric material at least partially covers the portion of the face of the sheet of metallic material that is not covered by the sheet of composite material.
热塑性或热固性聚合物材料可以与形成步骤(b)中提供的复合材料板的一部分的聚合物材料相同或不同。The thermoplastic or thermoset polymeric material may be the same or different from the polymeric material forming part of the composite panel provided in step (b).
该步骤可以以与步骤(d)的工具不同的工具来执行。This step may be performed with a different tool than that of step (d).
优选地,步骤(e)以与步骤(d)中使用的工具相同的工具来执行、尤其是当步骤(d)通过热压印执行时,这降低了制造成本。步骤(e)可以是注塑成型或压塑成型步骤。Preferably, step (e) is performed with the same tool as used in step (d), especially when step (d) is performed by hot embossing, which reduces manufacturing costs. Step (e) may be an injection molding or compression molding step.
有利地,所形成的硬化构件是加强肋,这些加强肋可选地基本垂直于复合材料板延伸,即在该板的表面上延伸。Advantageously, the stiffening members formed are reinforcing ribs, which optionally extend substantially perpendicular to the composite sheet, ie over the surface of the sheet.
尤其,当金属材料板具有凹部时,这些硬化构件有利地布置在凹部内以加强组合件。特别地,在冲击的情况下,硬化构件的存在限制凹部在冲击下的较大程度的张开或闭合。尤其在支柱的情况下,硬化构件在保持凹部部段的边缘间隔的同时,对凹部的较大程度的张开或闭合以及支柱的高度上的曲率或横向上的曲率进行限制。In particular, when the sheet of metallic material has recesses, these stiffening members are advantageously arranged within the recesses to strengthen the assembly. In particular, in the event of an impact, the presence of the stiffening member limits the opening or closing of the recess to a greater extent under impact. Especially in the case of struts, the stiffening members limit the greater opening or closing of the recesses and the curvature in height or in the lateral direction of the struts while maintaining the edge spacing of the recessed sections.
有利地,在二次成型之前聚合物材料可以被添加有任意放置的纤维以获得更坚固的硬化构件。这些纤维可以与步骤(b)的复合材料板中存在的纤维相同或不同。这些纤维可以是碳纤维、玻璃纤维、玄武岩纤维、金属纤维或聚合物纤维,尤其是芳族聚酰胺纤维。Advantageously, the polymer material can be added with randomly placed fibers prior to overmolding to obtain a stronger stiffened member. These fibers may or may not be the same as the fibers present in the composite sheet of step (b). These fibers can be carbon fibers, glass fibers, basalt fibers, metal fibers or polymer fibers, especially aramid fibers.
有利地,所添加的纤维与复合材料板中存在的一种或更多种纤维是相同的类型。Advantageously, the fibers added are of the same type as the one or more fibers present in the composite panel.
特别地,聚合物材料可以包含:来自复合材料板的、以及来自步骤(d)或步骤(b)的磨碎料;可能补充的聚合物、尤其是复合材料板的复合材料中存在的聚合物或化学上相容的其他聚合物。In particular, the polymeric material may comprise: ground stock from the composite sheet, and from step (d) or step (b); possibly supplementary polymers, especially polymers present in the composite material of the composite sheet or other polymers that are chemically compatible.
这降低了混合部件的总生产成本。This reduces the overall production cost of the hybrid component.
本发明还涉及可以通过实施根据本发明的方法而获得的用于机动车辆的混合结构部件,该混合结构部件包括:The invention also relates to a hybrid structural component for a motor vehicle obtainable by implementing the method according to the invention, the hybrid structural component comprising:
-金属材料板、尤其是成形的金属材料板,- sheets of metallic material, especially shaped sheets of metallic material,
-复合材料板、尤其是成形的复合材料板,该复合材料板至少部分地覆盖所述金属材料板的面,复合材料板包含浸入或嵌入聚合物基质中的至少一个纤维层,所述纤维层选自单向纤维层和织造纤维层,- a composite sheet, in particular a shaped composite sheet, which at least partially covers the face of the metal sheet, the composite sheet comprising at least one fibre layer immersed or embedded in a polymer matrix, said fibre layer selected from unidirectional fiber layers and woven fiber layers,
-聚合物材料,该聚合物材料尤其是模制的,该聚合物材料至少部分地覆盖所述金属材料板的至少部分地覆盖有复合材料板的面,该聚合物材料可选地形成肋。- a polymeric material, in particular moulded, which at least partially covers the face of the sheet of metallic material which is at least partially covered with the sheet of composite material, optionally forming ribs.
这种混合结构部件特别地对冲击具有抵抗力、尤其是在基本垂直于金属板和复合材料板的冲击的情况下。Such hybrid structural components are particularly resistant to impacts, especially in the case of impacts substantially perpendicular to the metal and composite panels.
金属材料板、复合材料板和聚合物材料的组成可以如参照根据本发明的方法所描述的那样。The composition of the sheet of metallic material, the sheet of composite material and the polymeric material may be as described with reference to the method according to the invention.
该混合结构部件可以形成结构支柱。该结构支柱尤其可以是位于车辆的两个门之间的中央结构支柱、或者是前或后结构支柱。该结构支柱也可以是纵向外侧梁、甚至车顶横梁、冲击梁或车辆的任何其他结构构件。The hybrid structural components may form structural struts. The structural strut may in particular be a central structural strut between two doors of the vehicle, or a front or rear structural strut. The structural struts can also be longitudinal outboard beams, or even roof rails, impact beams or any other structural member of the vehicle.
根据本发明,复合材料板部分地覆盖所述金属材料板的一个面,随后聚合物材料至少部分地覆盖该面的未被所述复合材料板覆盖的部分。这在不会影响部件的抗冲击性的情况下限制了复合材料板的磨碎料的生产并且覆盖了金属材料板的留空的表面。According to the invention, a sheet of composite material partially covers one face of the sheet of metallic material, and then the polymer material at least partially covers the part of that face that is not covered by the sheet of composite material. This limits the production of ground stock of the composite sheet and covers the voided surfaces of the metal sheet without affecting the impact resistance of the part.
有利地,金属材料板的留下未被覆盖的部分或这些部分中的一些可以是用于将混合部件紧固至另一结构部件的部分,其中,特别是通过焊接将混合部件紧固至另一结构部件。这些部分例如是混合结构部件的边缘部分。如此实现的两个件之间的附接可以用于硬化混合部件,例如通过形成封闭的横截面来硬化混合部件;如此实现的两个件之间的附接也可以用于将混合部件接合至机动车辆的车体的另外已经预组装的金属部件:例如,在中央混合支柱的情况下,金属材料板的留下未被覆盖的一部分可以在上部部分焊接至车顶横梁或车顶侧梁并且在下部部分焊接至外侧梁或金属门槛板。Advantageously, the portion of the sheet of metallic material that is left uncovered, or some of these portions, may be the portion used to fasten the hybrid element to another structural element, wherein the hybrid element is fastened to the other structural element, in particular by welding. a structural component. These parts are, for example, edge parts of hybrid structural components. The attachment between the two pieces so achieved can be used to harden the mixing element, for example by forming a closed cross-section; the attachment between the two pieces so achieved can also be used to join the mixing element to Additional already pre-assembled metal parts of the body of a motor vehicle: for example, in the case of a central hybrid strut, the part of the sheet of metal material that is left uncovered can be welded in the upper part to the roof rails or roof side rails and Welded to outboard beams or metal rocker plates in the lower part.
有利地,金属材料板的至少一个边缘可以具有既不被复合材料板覆盖也不被聚合物材料覆盖的预定的紧固区域,所述预定的紧固区域尤其是被焊接,所述预定的紧固区域被覆盖有聚合物材料的区域隔开。该布置限制了金属材料板的边缘上的惯性裂开,并且因此防止了金属材料板在这些区域中大范围地断裂或变形。Advantageously, at least one edge of the sheet of metallic material may have a predetermined fastening area which is not covered neither by the sheet of composite material nor by the polymeric material, said predetermined area of fastening being in particular welded, said predetermined fastening area. The solid regions are separated by regions covered with polymer material. This arrangement limits inertial cracking on the edges of the sheet of metallic material and thus prevents extensive fracture or deformation of the sheet of metallic material in these areas.
在这种情况下,有利的是预见到结构部件的被金属材料板的边缘附接的边缘具有凹部。凹部之间的区域意在与金属材料板的紧固区域接触,凹部意在与金属材料板的涂覆有聚合物材料的区域接触。这加强了所组装的边缘。In this case, it is advantageous to foresee that the edge of the structural component to which the edge of the sheet of metal material is attached has a recess. The areas between the recesses are intended to be in contact with the fastening areas of the sheet of metallic material, the recesses are intended to be in contact with the areas of the sheet of metallic material coated with the polymer material. This strengthens the assembled edge.
当然,结构部件的意在被紧固至混合部件的若干边缘均可以具有凹部。Of course, several edges of the structural component that are intended to be fastened to the mixing component may each have recesses.
有利地,这些凹部成形为补偿金属材料板的边缘的与覆盖有聚合物材料的区域的存在相关联的额外厚度。Advantageously, these recesses are shaped to compensate for the extra thickness of the edge of the sheet of metallic material associated with the presence of areas covered with polymer material.
本发明还涉及组装至尤其是金属结构部件的根据本发明的混合结构部件的组合件。The invention also relates to an assembly of hybrid structural components according to the invention assembled to, in particular, metallic structural components.
附图说明Description of drawings
现在将参照以下非限制性的图来描述本发明:The invention will now be described with reference to the following non-limiting figures:
-图1是根据本发明的混合结构部件的实施方案的分解立体图,- Figure 1 is an exploded perspective view of an embodiment of a hybrid structural component according to the invention,
-图2是根据另一实施方案的混合结构部件的局部立体图、是该部件的凹形侧部的视图,- Figure 2 is a partial perspective view of a hybrid structural component according to another embodiment, a view of the concave side of the component,
-图3a是组装至结构部件的在图2中示出的部件的横向横截面;图3b是组装至结构部件的在图2中示出的部件的边缘的纵向横截面。- Figure 3a is a transverse cross-section of the part shown in Figure 2 assembled to a structural part; Figure 3b is a longitudinal cross-section of the edge of the part shown in Figure 2 assembled to a structural part.
具体实施方式Detailed ways
图1示出了机动车辆的中央结构支柱10,中央结构支柱10包括:Figure 1 shows a central structural pillar 10 of a motor vehicle comprising:
-成形的金属材料板12,- formed sheet metal material 12,
-成形的复合材料板14,- Formed
-模制的聚合物材料16,模制的聚合物材料16至少部分地覆盖覆盖有复合材料板14的覆盖金属材料板1进,聚合物材料16可选地形成肋18。- a moulded polymer material 16 which at least partially covers the covering metal material sheet 1 covered with the
金属材料板12呈中空部件的形式并且具有凹形的内表面12a和凸形的外表面12b。The metal material plate 12 is in the form of a hollow member and has a concave
复合材料板14覆盖金属材料板12的面12a。该复合材料板14含有浸入或嵌入聚合物基质中的若干层纤维。The
应当指出的是,本发明不限于金属材料板12的其上施用有复合材料板14的面12a的特定形状,该面12a可以是凸形的面或其他面。It should be noted that the present invention is not limited to the particular shape of the
聚合物材料16在此处形成一组肋18,所述一组肋18有利地在板12和14的凹部内延伸并且部分地覆盖两个板12、14的边缘。The polymer material 16 here forms a set of
例如,混合中央支柱10包括:For example, the hybrid center strut 10 includes:
-厚度为0.67mm的钢板10,- Steel plate 10 with a thickness of 0.67mm,
-含有55%至80%重量的单向碳纤维和织造玻璃纤维的厚度为4.35mm的聚酰胺66基复合材料板,以及- 4.35mm thick polyamide 66-based composite panels containing 55% to 80% by weight of unidirectional carbon fibers and woven glass fibers, and
-含有50%重量的切碎玻璃纤维的由聚酰胺66制成的厚度可在2mm至4.5mm变化的热塑性材料,- thermoplastic material made of polyamide 66 with a thickness of 2mm to 4.5mm, containing 50% by weight of chopped glass fibers,
混合中央支柱10相对于全钢支柱轻了30%,但具有相同的冲击性能(例如通过模拟进行检测)。The hybrid center strut 10 is 30% lighter than an all-steel strut, but has the same impact performance (eg, as tested by simulation).
图2和图3a、图3b部分地示出了根据另一实施方案的混合结构部件110。在该实施方案中,混合结构部件110同样包括成形的金属材料板112、成形的复合材料板114和部分地覆盖金属材料板112的模制的聚合物材料116。从图2和图3b中可以看出,聚合物材料116形成肋118。Figures 2 and 3a, 3b partially illustrate a hybrid
如在前述实施方案中的那样,金属材料板112呈中空部件的形式并且具有凹形的内表面112a和凸形的外表面112b。As in the previous embodiments, the
在该实施方案中,应当指出的是,金属材料板112未被复合材料板114完全覆盖、尤其是在金属材料板112的纵向边缘113a和113b处。这些纵向边缘113a、113b具有与以聚合物材料116覆盖的区域122交替的紧固区域120。紧固区域120既不被复合材料板114覆盖也不被聚合物材料116覆盖,从而允许紧固区域120被紧固至结构部件,尤其是通过焊接至金属结构部件来紧固紧固区域120。In this embodiment, it should be noted that the sheet of
此外,应当指出的是,金属材料板112的不是紧固区域120且不被复合材料板114覆盖的部分覆盖有聚合物材料116,如可以在图3a(图的左侧部分)中更具体地看出的。换句话说,在该实施方案中,在横向横截面中,金属材料板112的不附接至结构部件的每个部分均被复合材料板114或聚合物材料116覆盖。在未示出的另一实施方案中,可以存在金属材料板112的不附接至结构部件且不被任何其他材料覆盖的部分。Furthermore, it should be noted that the portion of the sheet of
横截面3a和横截面3b中部分地示出了金属结构部件124。为了与混合结构部件110更好地组装,该部件124的边缘具有中空区域或凹部125,中空区域或凹部125定位成与覆盖有聚合物材料116的区域122相对,并且中空区域或凹部125设计成补偿由于这些区域122的存在而导致的边缘113a的过大厚度。The metal
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| FR1463218 | 2014-12-23 | ||
| PCT/FR2015/053669 WO2016102859A1 (en) | 2014-12-23 | 2015-12-21 | Method for producing a hybrid-structure part of a motor vehicle and corresponding hybrid-structure part |
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2015
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- 2015-12-21 CN CN201580069959.3A patent/CN107107486B/en active Active
- 2015-12-21 WO PCT/FR2015/053669 patent/WO2016102859A1/en active Application Filing
- 2015-12-21 EP EP15823697.6A patent/EP3237268B1/en active Active
- 2015-12-21 JP JP2017529022A patent/JP6637045B2/en active Active
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Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102149592A (en) * | 2008-09-08 | 2011-08-10 | 雷诺股份公司 | Arrangements for draining water from the roof of a motor vehicle |
| DE102009042272A1 (en) * | 2009-09-22 | 2011-03-31 | Dr. Ing. H.C. F. Porsche Aktiengesellschaft | lightweight component |
Also Published As
| Publication number | Publication date |
|---|---|
| JP6637045B2 (en) | 2020-01-29 |
| WO2016102859A1 (en) | 2016-06-30 |
| EP3237268A1 (en) | 2017-11-01 |
| US20170327157A1 (en) | 2017-11-16 |
| KR102362595B1 (en) | 2022-02-14 |
| CN107107486A (en) | 2017-08-29 |
| FR3030356A1 (en) | 2016-06-24 |
| KR20170098264A (en) | 2017-08-29 |
| JP2018504304A (en) | 2018-02-15 |
| FR3030356B1 (en) | 2019-04-05 |
| US10472002B2 (en) | 2019-11-12 |
| EP3237268B1 (en) | 2019-06-19 |
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