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CN107099065A - A kind of football material and manufacture craft - Google Patents

A kind of football material and manufacture craft Download PDF

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Publication number
CN107099065A
CN107099065A CN201710449242.2A CN201710449242A CN107099065A CN 107099065 A CN107099065 A CN 107099065A CN 201710449242 A CN201710449242 A CN 201710449242A CN 107099065 A CN107099065 A CN 107099065A
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accounts
rubber
football
resin
superfine powder
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孟凡强
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Shaanxi University of Technology
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Shaanxi University of Technology
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L7/00Compositions of natural rubber
    • AHUMAN NECESSITIES
    • A63SPORTS; GAMES; AMUSEMENTS
    • A63BAPPARATUS FOR PHYSICAL TRAINING, GYMNASTICS, SWIMMING, CLIMBING, OR FENCING; BALL GAMES; TRAINING EQUIPMENT
    • A63B41/00Hollow inflatable balls
    • AHUMAN NECESSITIES
    • A63SPORTS; GAMES; AMUSEMENTS
    • A63BAPPARATUS FOR PHYSICAL TRAINING, GYMNASTICS, SWIMMING, CLIMBING, OR FENCING; BALL GAMES; TRAINING EQUIPMENT
    • A63B41/00Hollow inflatable balls
    • A63B41/02Bladders
    • AHUMAN NECESSITIES
    • A63SPORTS; GAMES; AMUSEMENTS
    • A63BAPPARATUS FOR PHYSICAL TRAINING, GYMNASTICS, SWIMMING, CLIMBING, OR FENCING; BALL GAMES; TRAINING EQUIPMENT
    • A63B41/00Hollow inflatable balls
    • A63B41/08Ball covers; Closures therefor
    • AHUMAN NECESSITIES
    • A63SPORTS; GAMES; AMUSEMENTS
    • A63BAPPARATUS FOR PHYSICAL TRAINING, GYMNASTICS, SWIMMING, CLIMBING, OR FENCING; BALL GAMES; TRAINING EQUIPMENT
    • A63B45/00Apparatus or methods for manufacturing balls
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L1/00Compositions of cellulose, modified cellulose or cellulose derivatives
    • C08L1/02Cellulose; Modified cellulose
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L11/00Compositions of homopolymers or copolymers of chloroprene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2227Oxides; Hydroxides of metals of aluminium
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2251Oxides; Hydroxides of metals of chromium
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/014Additives containing two or more different additives of the same subgroup in C08K
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Health & Medical Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Physical Education & Sports Medicine (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Synthetic Leather, Interior Materials Or Flexible Sheet Materials (AREA)

Abstract

本发明公开了一种足球材料及制作工艺,由竹纤维、碳纤维、白刚玉、丙烯酸树脂、氧化铝超微粉、氯丁橡胶、二甲苯、丁基橡胶、乙二醇单丁醚、三元乙丙橡胶、二甲基团聚硅氧烷、氧化铝超微粉、氧化铬、聚酰胺酸树脂、氟碳聚合物、四氟乙烯树脂、天然橡胶和二苯基甲烷二异氰酸酯组成。与现有技术相比,本发明的内胆和外层均采用多种材料合成,内胆具有高弹性和高韧性的特点,外层采用竹纤维和碳纤维提高韧性,采用白刚玉等增加耐磨性,提高足球的使用寿命,采用人工合成材料制成,环保,具有推广应用的价值。The invention discloses a football material and a manufacturing process, which is composed of bamboo fiber, carbon fiber, white corundum, acrylic resin, aluminum oxide superfine powder, neoprene rubber, xylene, butyl rubber, ethylene glycol monobutyl ether, ternary ethyl ether Composed of propylene rubber, dimethyl polysiloxane, alumina superfine powder, chromium oxide, polyamic acid resin, fluorocarbon polymer, tetrafluoroethylene resin, natural rubber and diphenylmethane diisocyanate. Compared with the prior art, the inner tank and the outer layer of the present invention are synthesized by various materials, the inner tank has the characteristics of high elasticity and high toughness, the outer layer adopts bamboo fiber and carbon fiber to improve toughness, and white corundum is used to increase wear resistance It is durable, improves the service life of the football, is made of artificial synthetic materials, is environmentally friendly, and has the value of popularization and application.

Description

一种足球材料及制作工艺A kind of football material and its manufacturing process

技术领域technical field

本发明涉及体育器材制作技术领域,尤其涉及一种足球材料及制作工艺。The invention relates to the technical field of sports equipment production, in particular to a football material and a production process.

背景技术Background technique

足球,有“世界第一运动”的美誉,是全球体育界最具影响力的单项体育运动。标准的足球比赛由两队各派10名球员与1名守门员,共11人,在长方形的草地球场上对抗、进攻。比赛目的是尽量将足球射入对方的球门内,每射入一球就可以得到一分,当比赛完毕后,得分最多的一队则胜出。如果在比赛规定时间内得分相同,则须看比赛章则而定,可以抽签、加时再赛或互射点球等形式比赛分高下。足球比赛中除了守门员可以在己方禁区内利用手部接触足球外,球场上每名球员只可以利用手以外的身体其他部分控制足球(开界外球例外)。现有技术中,足球大多不够耐磨,而且大多采用真皮皮革制作,不环保,因此,需要一种新材料诞生。Football, known as "the world's number one sport", is the most influential individual sport in the global sports world. A standard football match consists of two teams consisting of 10 players and 1 goalkeeper, a total of 11 people, fighting and attacking on a rectangular grass field. The purpose of the game is to shoot the football into the opponent's goal as much as possible. Every time a ball is scored, one point can be scored. When the game is over, the team with the most points wins. If the score is the same within the specified time of the game, it depends on the rules of the game, and the game can be divided in the form of drawing lots, overtime rematch or mutual penalty kicks. In football matches, except that the goalkeeper can use his hands to touch the football in his own penalty area, each player on the field can only use other parts of his body other than his hands to control the football (except for throw-ins). In the prior art, footballs are mostly not wear-resistant enough, and most of them are made of real leather, which is not environmentally friendly. Therefore, a new material needs to be born.

发明内容Contents of the invention

本发明的目的就在于为了解决上述问题而提供一种足球材料及制作工艺。The object of the present invention is to provide a football material and a manufacturing process in order to solve the above problems.

本发明通过以下技术方案来实现上述目的:The present invention achieves the above object through the following technical solutions:

本发明足球材料,由竹纤维、碳纤维、白刚玉、丙烯酸树脂、氧化铝超微粉、氯丁橡胶、二甲苯、丁基橡胶、乙二醇单丁醚、三元乙丙橡胶、二甲基团聚硅氧烷、氧化铝超微粉、氧化铬、聚酰胺酸树脂、氟碳聚合物、四氟乙烯树脂、天然橡胶和二苯基甲烷二异氰酸酯组成。The football material of the present invention is made of bamboo fiber, carbon fiber, white corundum, acrylic resin, aluminum oxide superfine powder, neoprene rubber, xylene, butyl rubber, ethylene glycol monobutyl ether, EPDM rubber, and dimethyl agglomeration It is composed of siloxane, alumina superfine powder, chromium oxide, polyamic acid resin, fluorocarbon polymer, tetrafluoroethylene resin, natural rubber and diphenylmethane diisocyanate.

具体地,按重量比,所述竹纤维占10%、所述碳纤维占15%、所述白刚玉占5%、所述丙烯酸树脂占5%、所述氧化铝超微粉占5%、所述氯丁橡胶占10%、所述二甲苯占2%、所述丁基橡胶占5%、所述乙二醇单丁醚占2%、所述三元乙丙橡胶占5%、所述二甲基团聚硅氧烷占2%、所述氧化铝超微粉占2%、所述氧化铬占2%、所述聚酰胺酸树脂占5%、所述氟碳聚合物占5%、所述四氟乙烯树脂占5%、所述天然橡胶占10%、所述二苯基甲烷二异氰酸酯占5%。Specifically, by weight, the bamboo fiber accounts for 10%, the carbon fiber accounts for 15%, the white corundum accounts for 5%, the acrylic resin accounts for 5%, the alumina superfine powder accounts for 5%, and the Chloroprene rubber accounts for 10%, the xylene accounts for 2%, the butyl rubber accounts for 5%, the ethylene glycol monobutyl ether accounts for 2%, the EPDM rubber accounts for 5%, and the butyl rubber accounts for 5%. Methyl polysiloxane accounts for 2%, the alumina superfine powder accounts for 2%, the chromium oxide accounts for 2%, the polyamic acid resin accounts for 5%, the fluorocarbon polymer accounts for 5%, and the The tetrafluoroethylene resin accounts for 5%, the natural rubber accounts for 10%, and the diphenylmethane diisocyanate accounts for 5%.

本发明足球制作工艺,包括以下步骤:Football production process of the present invention, comprises the following steps:

(1)将天然橡胶置于加热装置中升温至200-250度融化,依次添加聚酰胺酸树脂、氟碳聚合物、四氟乙烯树脂、二苯基甲烷二异氰酸酯,充分搅拌均匀,倒入模具中冷却制成足球内胆;(1) Put the natural rubber in a heating device to heat up to 200-250 degrees to melt, add polyamic acid resin, fluorocarbon polymer, tetrafluoroethylene resin, diphenylmethane diisocyanate in sequence, stir well, and pour into the mold Medium cooling to make football liner;

(2)将氯丁橡胶、丁基橡胶、三元乙丙橡胶均置入加热容器中升温至200-250度,搅拌混合均匀,再依次加入竹纤维、碳纤维、白刚玉、丙烯酸树脂、氧化铝超微粉、二甲苯、乙二醇单丁醚、二甲基团聚硅氧烷、氧化铝超微粉和氧化铬,倒入平坦容器中冷却制成合成类皮革;(2) Put chloroprene rubber, butyl rubber, and EPDM rubber into a heating container and heat up to 200-250 degrees, stir and mix evenly, then add bamboo fiber, carbon fiber, white corundum, acrylic resin, and alumina in sequence Ultrafine powder, xylene, ethylene glycol monobutyl ether, dimethyl agglomerated polysiloxane, aluminum oxide ultrafine powder and chromium oxide, pour into a flat container and cool to make synthetic leather;

(3)将步骤(2)的合成类皮革裁剪后采用缝制的方式将步骤(1)的内胆缝制包覆与内,即制得成品。(3) After cutting the synthetic leather in step (2), the liner of step (1) is sewn and covered with the inside by sewing to obtain the finished product.

本发明的有益效果在于:The beneficial effects of the present invention are:

本发明是一种足球材料及制作工艺,与现有技术相比,本发明的内胆和外层均采用多种材料合成,内胆具有高弹性和高韧性的特点,外层采用竹纤维和碳纤维提高韧性,采用白刚玉等增加耐磨性,提高足球的使用寿命,采用人工合成材料制成,环保,具有推广应用的价值。The present invention relates to a soccer ball material and its manufacturing process. Compared with the prior art, the inner tank and the outer layer of the present invention are synthesized by various materials, the inner tank has the characteristics of high elasticity and high toughness, and the outer layer is made of bamboo fiber and Carbon fiber improves toughness, white corundum is used to increase wear resistance, and the service life of football is improved. It is made of artificial synthetic materials, which is environmentally friendly and has the value of popularization and application.

具体实施方式detailed description

下面对本发明作进一步说明:The present invention will be further described below:

本发明足球材料,由竹纤维、碳纤维、白刚玉、丙烯酸树脂、氧化铝超微粉、氯丁橡胶、二甲苯、丁基橡胶、乙二醇单丁醚、三元乙丙橡胶、二甲基团聚硅氧烷、氧化铝超微粉、氧化铬、聚酰胺酸树脂、氟碳聚合物、四氟乙烯树脂、天然橡胶和二苯基甲烷二异氰酸酯组成。The football material of the present invention is made of bamboo fiber, carbon fiber, white corundum, acrylic resin, aluminum oxide superfine powder, neoprene rubber, xylene, butyl rubber, ethylene glycol monobutyl ether, EPDM rubber, and dimethyl agglomeration It is composed of siloxane, alumina superfine powder, chromium oxide, polyamic acid resin, fluorocarbon polymer, tetrafluoroethylene resin, natural rubber and diphenylmethane diisocyanate.

具体地,按重量比,所述竹纤维占10%、所述碳纤维占15%、所述白刚玉占5%、所述丙烯酸树脂占5%、所述氧化铝超微粉占5%、所述氯丁橡胶占10%、所述二甲苯占2%、所述丁基橡胶占5%、所述乙二醇单丁醚占2%、所述三元乙丙橡胶占5%、所述二甲基团聚硅氧烷占2%、所述氧化铝超微粉占2%、所述氧化铬占2%、所述聚酰胺酸树脂占5%、所述氟碳聚合物占5%、所述四氟乙烯树脂占5%、所述天然橡胶占10%、所述二苯基甲烷二异氰酸酯占5%。Specifically, by weight, the bamboo fiber accounts for 10%, the carbon fiber accounts for 15%, the white corundum accounts for 5%, the acrylic resin accounts for 5%, the alumina superfine powder accounts for 5%, and the Chloroprene rubber accounts for 10%, the xylene accounts for 2%, the butyl rubber accounts for 5%, the ethylene glycol monobutyl ether accounts for 2%, the EPDM rubber accounts for 5%, and the butyl rubber accounts for 5%. Methyl polysiloxane accounts for 2%, the alumina superfine powder accounts for 2%, the chromium oxide accounts for 2%, the polyamic acid resin accounts for 5%, the fluorocarbon polymer accounts for 5%, and the The tetrafluoroethylene resin accounts for 5%, the natural rubber accounts for 10%, and the diphenylmethane diisocyanate accounts for 5%.

本发明足球制作工艺,包括以下步骤:Football production process of the present invention, comprises the following steps:

(1)将天然橡胶置于加热装置中升温至200-250度融化,依次添加聚酰胺酸树脂、氟碳聚合物、四氟乙烯树脂、二苯基甲烷二异氰酸酯,充分搅拌均匀,倒入模具中冷却制成足球内胆;(1) Put the natural rubber in a heating device to heat up to 200-250 degrees to melt, add polyamic acid resin, fluorocarbon polymer, tetrafluoroethylene resin, diphenylmethane diisocyanate in sequence, stir well, and pour into the mold Medium cooling to make football liner;

(2)将氯丁橡胶、丁基橡胶、三元乙丙橡胶均置入加热容器中升温至200-250度,搅拌混合均匀,再依次加入竹纤维、碳纤维、白刚玉、丙烯酸树脂、氧化铝超微粉、二甲苯、乙二醇单丁醚、二甲基团聚硅氧烷、氧化铝超微粉和氧化铬,倒入平坦容器中冷却制成合成类皮革;(2) Put chloroprene rubber, butyl rubber, and EPDM rubber into a heating container and heat up to 200-250 degrees, stir and mix evenly, then add bamboo fiber, carbon fiber, white corundum, acrylic resin, and alumina in sequence Ultrafine powder, xylene, ethylene glycol monobutyl ether, dimethyl agglomerated polysiloxane, aluminum oxide ultrafine powder and chromium oxide, pour into a flat container and cool to make synthetic leather;

(3)将步骤(2)的合成类皮革裁剪后采用缝制的方式将步骤(1)的内胆缝制包覆与内,即制得成品。(3) After cutting the synthetic leather in step (2), the liner of step (1) is sewn and covered with the inside by sewing to obtain the finished product.

以上显示和描述了本发明的基本原理和主要特征及本发明的优点。本行业的技术人员应该了解,本发明不受上述实施例的限制,上述实施例和说明书中描述的只是说明本发明的原理,在不脱离本发明精神和范围的前提下,本发明还会有各种变化和改进,这些变化和改进都落入要求保护的本发明范围内。本发明要求保护范围由所附的权利要求书及其等效物界定 。The basic principles and main features of the present invention and the advantages of the present invention have been shown and described above. Those skilled in the industry should understand that the present invention is not limited by the above-mentioned embodiments. What are described in the above-mentioned embodiments and the description only illustrate the principle of the present invention. Without departing from the spirit and scope of the present invention, the present invention will also have Variations and improvements all fall within the scope of the claimed invention. The protection scope of the present invention is defined by the appended claims and their equivalents.

Claims (3)

1.一种足球材料,其特征在于:由竹纤维、碳纤维、白刚玉、丙烯酸树脂、氧化铝超微粉、氯丁橡胶、二甲苯、丁基橡胶、乙二醇单丁醚、三元乙丙橡胶、二甲基团聚硅氧烷、氧化铝超微粉、氧化铬、聚酰胺酸树脂、氟碳聚合物、四氟乙烯树脂、天然橡胶和二苯基甲烷二异氰酸酯组成。1. A football material, characterized in that: by bamboo fiber, carbon fiber, white corundum, acrylic resin, aluminum oxide superfine powder, neoprene, xylene, butyl rubber, ethylene glycol monobutyl ether, ethylene propylene diene Composed of rubber, dimethyl polysiloxane, alumina superfine powder, chromium oxide, polyamic acid resin, fluorocarbon polymer, tetrafluoroethylene resin, natural rubber and diphenylmethane diisocyanate. 2.根据权利要求1所述的足球材料,其特征在于:按重量比,所述竹纤维占10%、所述碳纤维占15%、所述白刚玉占5%、所述丙烯酸树脂占5%、所述氧化铝超微粉占5%、所述氯丁橡胶占10%、所述二甲苯占2%、所述丁基橡胶占5%、所述乙二醇单丁醚占2%、所述三元乙丙橡胶占5%、所述二甲基团聚硅氧烷占2%、所述氧化铝超微粉占2%、所述氧化铬占2%、所述聚酰胺酸树脂占5%、所述氟碳聚合物占5%、所述四氟乙烯树脂占5%、所述天然橡胶占10%、所述二苯基甲烷二异氰酸酯占5%。2. The football material according to claim 1, characterized in that: by weight, the bamboo fiber accounts for 10%, the carbon fiber accounts for 15%, the white corundum accounts for 5%, and the acrylic resin accounts for 5% , the alumina superfine powder accounts for 5%, the chloroprene rubber accounts for 10%, the xylene accounts for 2%, the butyl rubber accounts for 5%, the ethylene glycol monobutyl ether accounts for 2%, and the The EPDM rubber accounts for 5%, the dimethyl agglomerated polysiloxane accounts for 2%, the alumina superfine powder accounts for 2%, the chromium oxide accounts for 2%, and the polyamic acid resin accounts for 5%. , the fluorocarbon polymer accounts for 5%, the tetrafluoroethylene resin accounts for 5%, the natural rubber accounts for 10%, and the diphenylmethane diisocyanate accounts for 5%. 3.一种足球制作工艺,其特征在于,包括以下步骤:3. A football manufacturing process, characterized in that, comprising the following steps: (1)将天然橡胶置于加热装置中升温至200-250度融化,依次添加聚酰胺酸树脂、氟碳聚合物、四氟乙烯树脂、二苯基甲烷二异氰酸酯,充分搅拌均匀,倒入模具中冷却制成足球内胆;(1) Put the natural rubber in a heating device to heat up to 200-250 degrees to melt, add polyamic acid resin, fluorocarbon polymer, tetrafluoroethylene resin, diphenylmethane diisocyanate in sequence, stir well, and pour into the mold Medium cooling to make football liner; (2)将氯丁橡胶、丁基橡胶、三元乙丙橡胶均置入加热容器中升温至200-250度,搅拌混合均匀,再依次加入竹纤维、碳纤维、白刚玉、丙烯酸树脂、氧化铝超微粉、二甲苯、乙二醇单丁醚、二甲基团聚硅氧烷、氧化铝超微粉和氧化铬,倒入平坦容器中冷却制成合成类皮革;(2) Put chloroprene rubber, butyl rubber, and EPDM rubber into a heating container and heat up to 200-250 degrees, stir and mix evenly, then add bamboo fiber, carbon fiber, white corundum, acrylic resin, and alumina in sequence Ultrafine powder, xylene, ethylene glycol monobutyl ether, dimethyl agglomerated polysiloxane, aluminum oxide ultrafine powder and chromium oxide, pour into a flat container and cool to make synthetic leather; (3)将步骤(2)的合成类皮革裁剪后采用缝制的方式将步骤(1)的内胆缝制包覆与内,即制得成品。(3) After cutting the synthetic leather in step (2), the liner of step (1) is sewn and covered with the inside by sewing to obtain the finished product.
CN201710449242.2A 2017-06-14 2017-06-14 A kind of football material and manufacture craft Pending CN107099065A (en)

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CN108003484A (en) * 2017-12-11 2018-05-08 定远县杰仕达体育用品有限公司 A kind of basketball liner elastomeric material
CN108084620A (en) * 2017-12-11 2018-05-29 安徽省定远县劲牛球业有限公司 A kind of vollyball lightweight combined material
CN108129710A (en) * 2018-01-30 2018-06-08 山东工商学院 A kind of basketball wearing coat material preparation method
CN108148395A (en) * 2017-12-11 2018-06-12 定远县杰仕达体育用品有限公司 A kind of basketball leather
CN108499051A (en) * 2018-04-09 2018-09-07 商洛学院 A kind of vollyball manufacture craft

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108003484A (en) * 2017-12-11 2018-05-08 定远县杰仕达体育用品有限公司 A kind of basketball liner elastomeric material
CN108084620A (en) * 2017-12-11 2018-05-29 安徽省定远县劲牛球业有限公司 A kind of vollyball lightweight combined material
CN108148395A (en) * 2017-12-11 2018-06-12 定远县杰仕达体育用品有限公司 A kind of basketball leather
CN108129710A (en) * 2018-01-30 2018-06-08 山东工商学院 A kind of basketball wearing coat material preparation method
CN108499051A (en) * 2018-04-09 2018-09-07 商洛学院 A kind of vollyball manufacture craft

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