CN107050935A - A kind of special defoamer of power plant desulfurization - Google Patents
A kind of special defoamer of power plant desulfurization Download PDFInfo
- Publication number
- CN107050935A CN107050935A CN201611225215.9A CN201611225215A CN107050935A CN 107050935 A CN107050935 A CN 107050935A CN 201611225215 A CN201611225215 A CN 201611225215A CN 107050935 A CN107050935 A CN 107050935A
- Authority
- CN
- China
- Prior art keywords
- power plant
- product
- plant desulfurization
- present
- modified organic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000013530 defoamer Substances 0.000 title claims abstract description 12
- 238000006477 desulfuration reaction Methods 0.000 title claims abstract description 11
- 230000023556 desulfurization Effects 0.000 title claims abstract description 11
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims abstract description 15
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims abstract description 13
- 229910052710 silicon Inorganic materials 0.000 claims abstract description 13
- 239000010703 silicon Substances 0.000 claims abstract description 13
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 10
- 229920000570 polyether Polymers 0.000 claims abstract description 9
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 claims abstract description 5
- 239000002270 dispersing agent Substances 0.000 claims abstract description 5
- 230000002209 hydrophobic effect Effects 0.000 claims abstract description 5
- 239000003755 preservative agent Substances 0.000 claims abstract description 5
- 230000002335 preservative effect Effects 0.000 claims abstract description 5
- 239000000377 silicon dioxide Substances 0.000 claims abstract description 5
- LIVNPJMFVYWSIS-UHFFFAOYSA-N silicon monoxide Chemical class [Si-]#[O+] LIVNPJMFVYWSIS-UHFFFAOYSA-N 0.000 claims abstract description 5
- 229910052814 silicon oxide Inorganic materials 0.000 claims abstract description 5
- RCEAADKTGXTDOA-UHFFFAOYSA-N OS(O)(=O)=O.CCCCCCCCCCCC[Na] Chemical compound OS(O)(=O)=O.CCCCCCCCCCCC[Na] RCEAADKTGXTDOA-UHFFFAOYSA-N 0.000 claims description 4
- 230000000694 effects Effects 0.000 abstract description 4
- 230000002411 adverse Effects 0.000 abstract description 3
- 230000003254 anti-foaming effect Effects 0.000 abstract description 3
- 239000002518 antifoaming agent Substances 0.000 abstract description 3
- 239000000839 emulsion Substances 0.000 abstract description 3
- 238000007667 floating Methods 0.000 abstract description 3
- 239000012530 fluid Substances 0.000 abstract description 3
- 239000007788 liquid Substances 0.000 abstract description 3
- 231100000252 nontoxic Toxicity 0.000 abstract description 3
- 230000003000 nontoxic effect Effects 0.000 abstract description 3
- 239000003921 oil Substances 0.000 abstract description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 3
- YCSMVPSDJIOXGN-UHFFFAOYSA-N CCCCCCCCCCCC[Na] Chemical compound CCCCCCCCCCCC[Na] YCSMVPSDJIOXGN-UHFFFAOYSA-N 0.000 abstract 1
- 229910052938 sodium sulfate Inorganic materials 0.000 abstract 1
- 235000011152 sodium sulphate Nutrition 0.000 abstract 1
- 239000000463 material Substances 0.000 description 9
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 description 4
- 239000000126 substance Substances 0.000 description 3
- 239000006260 foam Substances 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 238000010248 power generation Methods 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
- 235000019738 Limestone Nutrition 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 230000003009 desulfurizing effect Effects 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000003546 flue gas Substances 0.000 description 1
- 239000002803 fossil fuel Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000010440 gypsum Substances 0.000 description 1
- 229910052602 gypsum Inorganic materials 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 239000006028 limestone Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- CCEKAJIANROZEO-UHFFFAOYSA-N sulfluramid Chemical group CCNS(=O)(=O)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F CCEKAJIANROZEO-UHFFFAOYSA-N 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D19/00—Degasification of liquids
- B01D19/02—Foam dispersion or prevention
- B01D19/04—Foam dispersion or prevention by addition of chemical substances
- B01D19/0404—Foam dispersion or prevention by addition of chemical substances characterised by the nature of the chemical substance
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D19/00—Degasification of liquids
- B01D19/02—Foam dispersion or prevention
- B01D19/04—Foam dispersion or prevention by addition of chemical substances
- B01D19/0404—Foam dispersion or prevention by addition of chemical substances characterised by the nature of the chemical substance
- B01D19/0409—Foam dispersion or prevention by addition of chemical substances characterised by the nature of the chemical substance compounds containing Si-atoms
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D19/00—Degasification of liquids
- B01D19/02—Foam dispersion or prevention
- B01D19/04—Foam dispersion or prevention by addition of chemical substances
- B01D19/0404—Foam dispersion or prevention by addition of chemical substances characterised by the nature of the chemical substance
- B01D19/0422—Foam dispersion or prevention by addition of chemical substances characterised by the nature of the chemical substance compounds containing S-atoms
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D19/00—Degasification of liquids
- B01D19/02—Foam dispersion or prevention
- B01D19/04—Foam dispersion or prevention by addition of chemical substances
- B01D19/0404—Foam dispersion or prevention by addition of chemical substances characterised by the nature of the chemical substance
- B01D19/0431—Foam dispersion or prevention by addition of chemical substances characterised by the nature of the chemical substance containing aromatic rings
- B01D19/0436—Foam dispersion or prevention by addition of chemical substances characterised by the nature of the chemical substance containing aromatic rings with substituted groups
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Toxicology (AREA)
- Dispersion Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Degasification And Air Bubble Elimination (AREA)
- Emulsifying, Dispersing, Foam-Producing Or Wetting Agents (AREA)
Abstract
The present invention discloses a kind of special defoamer of power plant desulfurization, by weight percentage, including：Modified organic silicon polyethers 20 40%；Organic siliconresin 10 30%；Polymethyl siloxane 5 15%；Hydrophobic silica 2 8%；Hydrophilic silicon oxides 2 8%；OP‑10 1‑3%；Lauryl sodium sulfate 2 4%；Sodium hydroxide 0.1 1%；Dispersant 0.5 1%；Preservative 0.01 0.03%.Wherein modified organic silicon pfpe molecule amount is 1,000 5000.The present invention is silicon polyethers emulsion type defoaming agent, with quick reduction gas-liquid surface tension force, and antifoaming speed is fast, and the suds time is long；Easily disperse in water, can be compatible well with fluid product, it is difficult the floating oil that is demulsified；Stability is high, and consumption is low；It is nontoxic, corrosion-free, without adverse side effect.Environmentally friendly class product, the excellent product performance, and it is cheap, it is a kind of cheap and good-quality tailored version product.
Description
Technical field
The present invention relates to defoamer field, more particularly to the special defoamer of power plant desulfurization.
Background technology
The discharge of sulfur dioxide is in addition to the natural phenomenas such as volcano eruption, most of burnings for coming from fossil fuel,
Because China generates electricity mainly by thermal power generation, based on coal, therefore the substantial amounts of sulfur dioxide that thermal power generation is produced is processed into
The maximum exhaust-gas treatment problem in power plant, typically using lime stone, gypsum wet flue gas desulfurizing, due to a large amount of during this
Using surfactant, a large amount of foams can be produced；
Therefore, prior art has yet to be improved and developed.
The content of the invention
In view of above-mentioned the deficiencies in the prior art, it is an object of the invention to provide a kind of special defoamer of power plant desulfurization, purport
The problem of a large amount of foams are produced in solving prior art sweetening process.
A kind of special defoamer of power plant desulfurization, wherein：By weight percentage, including：
Modified organic silicon polyethers 20-40%；
Organic siliconresin 10-25%；
Polymethyl siloxane 5-10%；
Hydrophobic silica 2-8%；
Hydrophilic silicon oxides 2-8%；
OP-10 1-3%；
Lauryl sodium sulfate 2-4%；
Sodium hydroxide 0.1-1%；
Dispersant 0.5-1%；
Preservative 0.01-0.03%.
Wherein modified organic silicon pfpe molecule amount is about 1000-5000.
Carry out above-mentioned each raw material under an inert atmosphere to be mixed and heated, to remove volatile materials.
Described volatile materials is unreacted material and accessory substance.
The present invention is silicon polyethers emulsion type defoaming agent, with quick reduction gas-liquid surface tension force, and antifoaming speed is fast, during suds
Between it is long；Easily disperse in water, can be compatible well with fluid product, it is difficult the floating oil that is demulsified；Stability is high, and consumption is low；Nontoxic,
It is corrosion-free, without adverse side effect.Environmentally friendly class product, the excellent product performance, and it is cheap, it is a kind of cheap and good-quality special
Type product.
Embodiment
The present invention provides a kind of special defoamer of power plant desulfurization, to make the purpose of the present invention, technical scheme and effect more
Clear, clear and definite, the present invention is described in more detail below.It should be appreciated that specific embodiment described herein is only used to
The present invention is explained, is not intended to limit the present invention.
Embodiment 1：
The special defoamer of a kind of power plant desulfurization provided by the present invention, by weight percentage, including：
Modified organic silicon polyethers 40%；
Organic siliconresin 28%；
Polymethyl siloxane 10%；
Hydrophobic silica 6%；
Hydrophilic silicon oxides 7%；
OP-10 3%；
Lauryl sodium sulfate 4%；
Sodium hydroxide 1%；
Dispersant 0.8%；
Preservative 0.2%.
The modified organic silicon pfpe molecule amount is 3000.
The mixing and heating of component as described above are carried out under the space of inert gas, to remove volatile materials.
Described volatile materials is unreacted material and accessory substance.
Embodiment 2：
The special defoamer of a kind of power plant desulfurization provided by the present invention, by weight percentage, including：
Modified organic silicon polyethers 39%；
Organic siliconresin 26%；
Polymethyl siloxane 11%；
Hydrophobic silica 7%；
Hydrophilic silicon oxides 8%；
OP-10 3%；
Lauryl sodium sulfate 4%；
Sodium hydroxide 1%；
Dispersant 0.8%；
Preservative 0.2%.
Wherein modified organic silicon pfpe molecule amount is 3500.
The mixing and heating of each raw material as described above are carried out under an inert atmosphere, to remove volatile materials.
Described volatile materials is unreacted material and accessory substance.
The present invention is silicon polyethers emulsion type defoaming agent, with quick reduction gas-liquid surface tension force, and antifoaming speed is fast, during suds
Between it is long；Easily disperse in water, can be compatible well with fluid product, it is difficult the floating oil that is demulsified；Stability is high, and consumption is low；Nontoxic,
It is corrosion-free, without adverse side effect.Environmentally friendly class product, the excellent product performance, and it is cheap, it is a kind of cheap and good-quality special
Type product.
It should be appreciated that the application of the present invention is not limited to above-mentioned citing, for those of ordinary skills, can
To be improved or converted according to the above description, all these modifications and variations should all belong to the guarantor of appended claims of the present invention
Protect scope.
Claims (2)
1. a kind of special defoamer of power plant desulfurization, it is characterised in that：By weight percentage, including：
Modified organic silicon polyethers 20-40%；
Organic siliconresin 10-30%；
Polymethyl siloxane 5-15%；
Hydrophobic silica 2-8%；
Hydrophilic silicon oxides 2-8%；
OP-10 1-3%；
Lauryl sodium sulfate 2-4%；
Sodium hydroxide 0.1-1%；
Dispersant 0.5-1%；
Preservative 0.01-0.03%.
2. the special defoamer of a kind of power plant desulfurization according to claim 1, it is characterised in that：The modified organic silicon polyethers
Molecular weight is 1000-5000.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611225215.9A CN107050935A (en) | 2016-12-27 | 2016-12-27 | A kind of special defoamer of power plant desulfurization |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611225215.9A CN107050935A (en) | 2016-12-27 | 2016-12-27 | A kind of special defoamer of power plant desulfurization |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107050935A true CN107050935A (en) | 2017-08-18 |
Family
ID=59623761
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201611225215.9A Pending CN107050935A (en) | 2016-12-27 | 2016-12-27 | A kind of special defoamer of power plant desulfurization |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107050935A (en) |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20090093598A1 (en) * | 2006-09-01 | 2009-04-09 | Goldschmidt Gmbh | Use of Grafted Polyethersiloxane Copolymers for Improving the Low-Temperature Stability of Antifoams in Aqueous Dispersions |
| CN101632908A (en) * | 2009-08-19 | 2010-01-27 | 南京四新科技应用研究所有限公司 | Method for preparing defoaming agent composition |
| CN101652164A (en) * | 2006-10-10 | 2010-02-17 | 陶氏康宁公司 | Silicone foam control agent |
| CN102337031A (en) * | 2011-06-29 | 2012-02-01 | 南京四新科技应用研究所有限公司 | Organosilicon composition with low viscosity and its preparation method |
| CN102940982A (en) * | 2012-11-26 | 2013-02-27 | 西安道尔达化工有限公司 | High-efficiency defoaming agent for biological fermentation system and preparation process of high-efficiency defoaming agent |
-
2016
- 2016-12-27 CN CN201611225215.9A patent/CN107050935A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20090093598A1 (en) * | 2006-09-01 | 2009-04-09 | Goldschmidt Gmbh | Use of Grafted Polyethersiloxane Copolymers for Improving the Low-Temperature Stability of Antifoams in Aqueous Dispersions |
| CN101652164A (en) * | 2006-10-10 | 2010-02-17 | 陶氏康宁公司 | Silicone foam control agent |
| CN101632908A (en) * | 2009-08-19 | 2010-01-27 | 南京四新科技应用研究所有限公司 | Method for preparing defoaming agent composition |
| CN102337031A (en) * | 2011-06-29 | 2012-02-01 | 南京四新科技应用研究所有限公司 | Organosilicon composition with low viscosity and its preparation method |
| CN102940982A (en) * | 2012-11-26 | 2013-02-27 | 西安道尔达化工有限公司 | High-efficiency defoaming agent for biological fermentation system and preparation process of high-efficiency defoaming agent |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20170818 |