CN107057812A - 一种钢绞线专用防腐脂及其制备方法 - Google Patents
一种钢绞线专用防腐脂及其制备方法 Download PDFInfo
- Publication number
- CN107057812A CN107057812A CN201710267862.4A CN201710267862A CN107057812A CN 107057812 A CN107057812 A CN 107057812A CN 201710267862 A CN201710267862 A CN 201710267862A CN 107057812 A CN107057812 A CN 107057812A
- Authority
- CN
- China
- Prior art keywords
- corrosion
- steel strand
- strand wires
- fat
- special anti
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000005260 corrosion Methods 0.000 title claims abstract description 37
- 229910000831 Steel Inorganic materials 0.000 title claims abstract description 31
- 239000010959 steel Substances 0.000 title claims abstract description 31
- 238000002360 preparation method Methods 0.000 title claims abstract description 13
- WMFOQBRAJBCJND-UHFFFAOYSA-M Lithium hydroxide Chemical compound [Li+].[OH-] WMFOQBRAJBCJND-UHFFFAOYSA-M 0.000 claims abstract description 27
- 239000004519 grease Substances 0.000 claims abstract description 17
- 239000002480 mineral oil Substances 0.000 claims abstract description 16
- 235000010446 mineral oil Nutrition 0.000 claims abstract description 16
- 229920000193 polymethacrylate Polymers 0.000 claims abstract description 11
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 10
- 235000008733 Citrus aurantifolia Nutrition 0.000 claims abstract description 9
- 235000021355 Stearic acid Nutrition 0.000 claims abstract description 9
- 235000011941 Tilia x europaea Nutrition 0.000 claims abstract description 9
- 239000004571 lime Substances 0.000 claims abstract description 9
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims abstract description 9
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 claims abstract description 9
- 239000008117 stearic acid Substances 0.000 claims abstract description 9
- ULQISTXYYBZJSJ-UHFFFAOYSA-N 12-hydroxyoctadecanoic acid Chemical compound CCCCCCC(O)CCCCCCCCCCC(O)=O ULQISTXYYBZJSJ-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000003963 antioxidant agent Substances 0.000 claims abstract description 7
- 230000003078 antioxidant effect Effects 0.000 claims abstract description 7
- 239000013556 antirust agent Substances 0.000 claims abstract description 7
- 238000007127 saponification reaction Methods 0.000 claims abstract description 7
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 claims abstract description 6
- 239000004327 boric acid Substances 0.000 claims abstract description 6
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims description 11
- 229920002367 Polyisobutene Polymers 0.000 claims description 9
- 229910052788 barium Inorganic materials 0.000 claims description 8
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 claims description 8
- LPJSGMBEFCOVEO-UHFFFAOYSA-L [O-]P([O-])(O)=O.S.[Ba+2] Chemical compound [O-]P([O-])(O)=O.S.[Ba+2] LPJSGMBEFCOVEO-UHFFFAOYSA-L 0.000 claims description 7
- DMBHHRLKUKUOEG-UHFFFAOYSA-N diphenylamine Chemical class C=1C=CC=CC=1NC1=CC=CC=C1 DMBHHRLKUKUOEG-UHFFFAOYSA-N 0.000 claims description 7
- 241000158728 Meliaceae Species 0.000 claims description 6
- ZTHYODDOHIVTJV-UHFFFAOYSA-N Propyl gallate Chemical compound CCCOC(=O)C1=CC(O)=C(O)C(O)=C1 ZTHYODDOHIVTJV-UHFFFAOYSA-N 0.000 claims description 4
- 238000007872 degassing Methods 0.000 claims description 4
- 238000010438 heat treatment Methods 0.000 claims description 4
- 230000035515 penetration Effects 0.000 claims description 4
- 238000010792 warming Methods 0.000 claims description 4
- 239000004255 Butylated hydroxyanisole Substances 0.000 claims description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 3
- 235000019282 butylated hydroxyanisole Nutrition 0.000 claims description 3
- CZBZUDVBLSSABA-UHFFFAOYSA-N butylated hydroxyanisole Chemical compound COC1=CC=C(O)C(C(C)(C)C)=C1.COC1=CC=C(O)C=C1C(C)(C)C CZBZUDVBLSSABA-UHFFFAOYSA-N 0.000 claims description 3
- 229940043253 butylated hydroxyanisole Drugs 0.000 claims description 3
- 229920001577 copolymer Polymers 0.000 claims description 3
- 239000003208 petroleum Substances 0.000 claims description 3
- 229910052708 sodium Inorganic materials 0.000 claims description 3
- 239000011734 sodium Substances 0.000 claims description 3
- WSFQLUVWDKCYSW-UHFFFAOYSA-M sodium;2-hydroxy-3-morpholin-4-ylpropane-1-sulfonate Chemical compound [Na+].[O-]S(=O)(=O)CC(O)CN1CCOCC1 WSFQLUVWDKCYSW-UHFFFAOYSA-M 0.000 claims description 3
- 239000000473 propyl gallate Substances 0.000 claims description 2
- 235000010388 propyl gallate Nutrition 0.000 claims description 2
- 229940075579 propyl gallate Drugs 0.000 claims description 2
- PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 claims 2
- 229940039407 aniline Drugs 0.000 claims 1
- -1 poly- Isobutene sulphur barium phosphate salt Chemical compound 0.000 claims 1
- 239000004575 stone Substances 0.000 claims 1
- 239000003921 oil Substances 0.000 abstract description 9
- 238000000034 method Methods 0.000 abstract description 8
- 239000000835 fiber Substances 0.000 abstract description 3
- 230000001050 lubricating effect Effects 0.000 abstract description 3
- 239000000344 soap Substances 0.000 abstract description 3
- 239000000084 colloidal system Substances 0.000 abstract description 2
- 239000010687 lubricating oil Substances 0.000 abstract description 2
- KIHBGTRZFAVZRV-UHFFFAOYSA-N 2-Hydroxyoctadecanoic acid Natural products CCCCCCCCCCCCCCCCC(O)C(O)=O KIHBGTRZFAVZRV-UHFFFAOYSA-N 0.000 abstract 1
- VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical compound CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- LNTHITQWFMADLM-UHFFFAOYSA-N gallic acid Chemical compound OC(=O)C1=CC(O)=C(O)C(O)=C1 LNTHITQWFMADLM-UHFFFAOYSA-N 0.000 description 2
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 229940074391 gallic acid Drugs 0.000 description 1
- 235000004515 gallic acid Nutrition 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
- C10M169/04—Mixtures of base-materials and additives
- C10M169/044—Mixtures of base-materials and additives the additives being a mixture of non-macromolecular and macromolecular compounds
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M145/00—Lubricating compositions characterised by the additive being a macromolecular compound containing oxygen
- C10M145/02—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C10M145/10—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a carboxyl radical, e.g. acrylate
- C10M145/12—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a carboxyl radical, e.g. acrylate monocarboxylic
- C10M145/14—Acrylate; Methacrylate
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M177/00—Special methods of preparation of lubricating compositions; Chemical modification by after-treatment of components or of the whole of a lubricating composition, not covered by other classes
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
- C10M2201/06—Metal compounds
- C10M2201/062—Oxides; Hydroxides; Carbonates or bicarbonates
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
- C10M2203/10—Petroleum or coal fractions, e.g. tars, solvents, bitumen
- C10M2203/1006—Petroleum or coal fractions, e.g. tars, solvents, bitumen used as base material
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
- C10M2205/02—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
- C10M2205/02—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers
- C10M2205/022—Ethene
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
- C10M2205/02—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers
- C10M2205/024—Propene
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/04—Ethers; Acetals; Ortho-esters; Ortho-carbonates
- C10M2207/046—Hydroxy ethers
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/10—Carboxylix acids; Neutral salts thereof
- C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
- C10M2207/125—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids
- C10M2207/126—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids monocarboxylic
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/10—Carboxylix acids; Neutral salts thereof
- C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
- C10M2207/125—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids
- C10M2207/128—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids containing hydroxy groups; Ethers thereof
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/10—Carboxylix acids; Neutral salts thereof
- C10M2207/16—Naphthenic acids
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/28—Esters
- C10M2207/284—Esters of aromatic monocarboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/02—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2209/08—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a carboxyl radical, e.g. acrylate type
- C10M2209/082—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a carboxyl radical, e.g. acrylate type monocarboxylic
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant Compositions
- C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
- C10M2215/06—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to carbon atoms of six-membered aromatic rings
- C10M2215/064—Di- and triaryl amines
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/04—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions containing sulfur-to-oxygen bonds, i.e. sulfones, sulfoxides
- C10M2219/044—Sulfonic acids, Derivatives thereof, e.g. neutral salts
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2225/00—Organic macromolecular compounds containing phosphorus as ingredients in lubricant compositions
- C10M2225/04—Organic macromolecular compounds containing phosphorus as ingredients in lubricant compositions obtained by phosphorisation of macromolecualr compounds not containing phosphorus in the monomers
- C10M2225/041—Hydrocarbon polymers
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2010/00—Metal present as such or in compounds
- C10N2010/02—Groups 1 or 11
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2010/00—Metal present as such or in compounds
- C10N2010/04—Groups 2 or 12
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/12—Inhibition of corrosion, e.g. anti-rust agents or anti-corrosives
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/32—Wires, ropes or cables lubricants
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2050/00—Form in which the lubricant is applied to the material being lubricated
- C10N2050/10—Form in which the lubricant is applied to the material being lubricated semi-solid; greasy
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Lubricants (AREA)
Abstract
本发明公开一种钢绞线专用防腐脂，其组成为：12‑羟基硬脂酸5％～10％w；工业硬脂酸1％～3％w；氢氧化锂3％～5％w；熟石灰0.5％～1％w；水8％～13％w；650SN矿物油70％～75％w；粘度指数改进剂0.5％～1％w；清净剂0.5％～1％w；防锈剂0.5％～1％w；抗氧化剂0.5％～1％w。本发明还公开了上述润滑油的制备方法，该防腐脂的制备方法，主要在皂化过程中加入硼酸提高了润滑脂的胶体安定性，并且调和过程中加入聚甲基丙烯酸酯使填充油能牢牢的包在皂纤维中，可以大幅改善防腐脂的钢网分油率，解决目前钢绞线防腐脂析油严重，达到对钢绞线的有效保护。
Description
技术领域
本发明涉及防腐材料技术领域，尤其涉及一种能够长时间的有效保护钢绞线的钢绞线专用防腐脂及其制备方法。
背景技术
钢绞线在日常生活中的应用已相当普遍，然而它的腐蚀却一直是一个令人头疼的问题。钢绞线腐蚀的要害处不仅在于本身的损失，更严重的是制品结构损坏所造成的损失大到无法估量。一般的金属防腐材料都只是涂刷或附着在金属表面，起到隔离作用，经不起成年累月的自然破坏，保护时间很短。
目前，防腐脂基本都是按照锂基脂或者复合锂基脂的配方和方法进行生产的，该方法所制备的产品，钢网分油基本都在10％或者5％以内，钢网分油率没有达到很低的水平。但是这种高压导线很容易因为电流过大而使温度攀升至很高，这种情况下，按照目前技术制备的防腐脂析油问题严重，其结果会导致防腐脂对导线的保护作用急剧下降，进而影响了导线的整体使用寿命。
钢网分油率成为钢绞线能否有效保护的瓶颈问题。因此，需要针对这种关键技术难题进行全面优化，确保高空导线能得到长时间的有效保护。
发明内容
为了克服现有钢绞线防腐脂的制备方法的不足之处，本发明提供了一种针对防腐脂析油严重、对钢绞线进行长期有效保护的钢绞线专用防腐脂及其制备方法。
一种钢绞线专用防腐脂，其组成为：12-羟基硬脂酸5％～10％w；工业硬脂酸1％～3％w；氢氧化锂3％～5％w；熟石灰0.5％～1％w；水8％～13％w；650SN矿物油70％～75％w；粘度指数改进剂0.5％～1％w；清净剂0.5％～1％w；防锈剂0.5％～1％w；抗氧化剂0.5％～1％w。
进一步改进的是，所述的粘度指数改进剂可以是聚甲基丙烯酸酯或乙烯丙烯共聚物或聚异丁烯。
进一步改进的是，所述的清净剂可以是聚异丁烯硫磷酸钡盐。
进一步改进的是，所述的防锈剂可以是石油磺酸钡或石油磺酸钠或环烷酸锌。
进一步改进的是，所述的抗氧剂可以是二苯胺或丁基羟基茴香醚或没食子酸丙酯。
一种钢绞线专用防腐脂的制备方法，其步骤如下：
a.将650SN矿物油充入添加有硼酸的皂化釜，并升温到55～75℃；
b.然后加入12-羟基硬脂酸，工业硬脂酸，氢氧化锂，熟石灰，水，添加完后起压、恒压、卸压，再温度升高至150～190℃之间，加入650SN矿物油100～500L，继续升温至220～248℃进行急冷混合并转入调和釜中，进行循环剪切；
c.加入聚甲基丙烯酸酯，聚异丁烯硫磷酸钡盐，石油磺酸钡，二苯胺，通过调整650SN矿物油的量得到锥入度为220-295的防腐脂，符合要求后，均质，脱气。
本发明的有益效果是：本钢绞线专用防腐脂的制备方法，主要在皂化过程中加入硼酸提高了润滑脂的胶体安定性，并且调和过程中加入聚甲基丙烯酸酯使填充油能牢牢的包在皂纤维中，可以大幅改善防腐脂的钢网分油率，解决目前钢绞线防腐脂析油严重，达到对钢绞线的有效保护。
具体实施方式
下面将结合本发明实施例，对本发明实施例中的技术方案进行清楚、完整地描述，显然，所描述的实施例仅仅是本发明的一部分实施例，而不是全部的实施例，基于本发明中的实施例，本领域普通技术人员在没有做出创造性劳动前提下所获得的所有其他实施例，都属于本发明保护的范围。
实施例1
一种钢绞线专用防腐脂，其组成为：12-羟基硬脂酸5％～10％w；工业硬脂酸1％～3％w；氢氧化锂3％～5％w；熟石灰0.5％～1％w；水8％～13％w；650SN矿物油70％～75％w；粘度指数改进剂0.5％～1％w；清净剂0.5％～1％w；防锈剂0.5％～1％w；抗氧化剂0.5％～1％w。
进一步改进的是，粘度指数改进剂可以是聚甲基丙烯酸酯或乙烯丙烯共聚物或聚异丁烯。
进一步改进的是，清净剂可以是聚异丁烯硫磷酸钡盐。
进一步改进的是，防锈剂可以是石油磺酸钡或石油磺酸钠或环烷酸锌。
进一步改进的是，抗氧剂可以是二苯胺或丁基羟基茴香醚或没食子酸丙酯。
一种钢绞线专用防腐脂的制备方法，其步骤如下：
a.将650SN矿物油充入添加有硼酸的皂化釜，并升温到55～75℃；
b.然后加入12-羟基硬脂酸，工业硬脂酸，氢氧化锂，熟石灰，水，添加完后起压、恒压、卸压，再温度升高至150～190℃之间，加入650SN矿物油100～500L，继续升温至220～248℃进行急冷混合并转入调和釜中，进行循环剪切；
c.加入聚甲基丙烯酸酯，聚异丁烯硫磷酸钡盐，石油磺酸钡，二苯胺，通过调整650SN矿物油的量得到锥入度为220-295的润滑油，符合要求后，均质，脱气。
实施例2
一种钢绞线专用防腐脂，其组成为：12-羟基硬脂酸8％w，工业硬脂酸2w，氢氧化锂4％w，熟石灰0.5％w，水10％w，聚甲基丙烯酸酯0.5％w，聚异丁烯硫磷酸钡盐0.5％w，石油磺酸钡0.5％w，二苯胺0.5％w和650SN73.5％w。
一种钢绞线专用防腐脂的制备方法，其步骤如下：将650SN矿物油充入皂化釜，并升温到65℃；然后加入12-羟基硬脂酸，工业硬脂酸，氢氧化锂，熟石灰，水，添加完后起压、恒压、卸压，再温度升高至150～190℃之间，加入650SN矿物油100～500L，继续升温至220进行急冷混合并转入调和釜中，进行循环剪切；加入聚甲基丙烯酸酯，聚异丁烯硫磷酸钡盐，石油磺酸钡，二苯胺，通过调整650SN矿物油的量得到锥入度为220-295的防腐脂，符合要求后，均质，脱气。
本钢绞线专用防腐脂的制备方法，主要在皂化过程中加入硼酸提高了润滑脂的胶体安定性，并且调和过程中加入聚甲基丙烯酸酯使填充油能牢牢的包在皂纤维中，可以大幅改善防腐脂的钢网分油率，解决目前钢绞线防腐脂析油严重，达到对钢绞线的有效保护。
尽管参照前述实施例对本发明进行了详细的说明，对于本领域的技术人员来说，其依然可以对前述各实施例所记载的技术方案进行修改，或者对其中部分技术特征进行等同替换，凡在本发明的精神和原则之内，所作的任何修改、等同替换、改进等，均应包含在本发明的保护范围之内。
Claims (6)
1.一种钢绞线专用防腐脂，其组成为：12-羟基硬脂酸5％～10％w；工业硬脂酸1％～3％w；氢氧化锂3％～5％w；熟石灰0.5％～1％w；水8％～13％w；650SN矿物油70％～75％w；粘度指数改进剂0.5％～1％w；清净剂0.5％～1％w；防锈剂0.5％～1％w；抗氧化剂0.5％～1％w。
2.根据权利要求1所述的一种钢绞线专用防腐脂，其特征在于：所述的粘度指数改进剂可以是聚甲基丙烯酸酯或乙烯丙烯共聚物或聚异丁烯。
3.根据权利要求1所述的一种钢绞线专用防腐脂，其特征在于：所述的清净剂可以是聚异丁烯硫磷酸钡盐。
4.根据权利要求1所述的一种钢绞线专用防腐脂，其特征在于：所述的防锈剂可以是石油磺酸钡或石油磺酸钠或环烷酸锌。
5.根据权利要求1所述的一种钢绞线专用防腐脂，其特征在于：所述的抗氧剂可以是二苯胺或丁基羟基茴香醚或没食子酸丙酯。
6.一种钢绞线专用防腐脂的制备方法，其步骤如下：
a. 将650SN矿物油充入添加有硼酸的皂化釜，并升温到55～75℃；
b. 然后加入12-羟基硬脂酸，工业硬脂酸，氢氧化锂，熟石灰，水，添加完后起压、恒压、卸压，再温度升高至150～190℃之间，加入650SN矿物油100～500L，继续升温至220～248℃进行急冷混合并转入调和釜中，进行循环剪切；
c. 加入聚甲基丙烯酸酯，聚异丁烯硫磷酸钡盐，石油磺酸钡，二苯胺，通过调整650SN矿物油的量得到锥入度为220-295的防腐脂，符合要求后，均质，脱气。
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710267862.4A CN107057812A (zh) | 2017-04-22 | 2017-04-22 | 一种钢绞线专用防腐脂及其制备方法 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710267862.4A CN107057812A (zh) | 2017-04-22 | 2017-04-22 | 一种钢绞线专用防腐脂及其制备方法 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107057812A true CN107057812A (zh) | 2017-08-18 |
Family
ID=59603457
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710267862.4A Pending CN107057812A (zh) | 2017-04-22 | 2017-04-22 | 一种钢绞线专用防腐脂及其制备方法 |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107057812A (zh) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107760427A (zh) * | 2017-11-16 | 2018-03-06 | 郑州市欧普士科技有限公司 | 一种极低分油率架空导线防腐脂及其制备方法 |
| CN107794108A (zh) * | 2017-11-16 | 2018-03-13 | 郑州市欧普士科技有限公司 | 一种圆线同心绞架空导线导电防腐脂及其制备方法 |
| CN108795546A (zh) * | 2018-07-26 | 2018-11-13 | 郑州市欧普士科技有限公司 | 一种可降解型割草机专用润滑脂及其制备方法 |
| CN110527581A (zh) * | 2019-09-23 | 2019-12-03 | 上海鸿辉光通科技股份有限公司 | 一种架空导线用高温防腐脂及其制备方法 |
| CN111269743A (zh) * | 2020-03-17 | 2020-06-12 | 郑州市欧普士科技有限公司 | 一种耐磨耐高温润滑脂及其制备方法和应用 |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101479374A (zh) * | 2006-05-31 | 2009-07-08 | 国际壳牌研究有限公司 | 制备皂浓缩物、润滑组合物和它们的组合的方法和装置 |
| CN102585977A (zh) * | 2011-12-26 | 2012-07-18 | 中国人民解放军91872部队 | 一种钢丝绳维护保养脂及其制作方法 |
| CN104152218A (zh) * | 2014-08-20 | 2014-11-19 | 安庆市中天石油化工有限公司 | 一种专用于压延机的润滑脂及其制备方法 |
| CN104449983A (zh) * | 2014-10-25 | 2015-03-25 | 中国石油化工股份有限公司 | 一种锂复合钙润滑脂组合物及制备方法 |
| CN104804809A (zh) * | 2015-04-28 | 2015-07-29 | 天津市金海利油脂有限公司 | 一种用于钢芯铝绞线防护的润滑脂及其制备方法 |
-
2017
- 2017-04-22 CN CN201710267862.4A patent/CN107057812A/zh active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101479374A (zh) * | 2006-05-31 | 2009-07-08 | 国际壳牌研究有限公司 | 制备皂浓缩物、润滑组合物和它们的组合的方法和装置 |
| CN102585977A (zh) * | 2011-12-26 | 2012-07-18 | 中国人民解放军91872部队 | 一种钢丝绳维护保养脂及其制作方法 |
| CN104152218A (zh) * | 2014-08-20 | 2014-11-19 | 安庆市中天石油化工有限公司 | 一种专用于压延机的润滑脂及其制备方法 |
| CN104449983A (zh) * | 2014-10-25 | 2015-03-25 | 中国石油化工股份有限公司 | 一种锂复合钙润滑脂组合物及制备方法 |
| CN104804809A (zh) * | 2015-04-28 | 2015-07-29 | 天津市金海利油脂有限公司 | 一种用于钢芯铝绞线防护的润滑脂及其制备方法 |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107760427A (zh) * | 2017-11-16 | 2018-03-06 | 郑州市欧普士科技有限公司 | 一种极低分油率架空导线防腐脂及其制备方法 |
| CN107794108A (zh) * | 2017-11-16 | 2018-03-13 | 郑州市欧普士科技有限公司 | 一种圆线同心绞架空导线导电防腐脂及其制备方法 |
| CN108795546A (zh) * | 2018-07-26 | 2018-11-13 | 郑州市欧普士科技有限公司 | 一种可降解型割草机专用润滑脂及其制备方法 |
| CN110527581A (zh) * | 2019-09-23 | 2019-12-03 | 上海鸿辉光通科技股份有限公司 | 一种架空导线用高温防腐脂及其制备方法 |
| CN110527581B (zh) * | 2019-09-23 | 2021-09-14 | 上海鸿辉光通科技股份有限公司 | 一种架空导线用高温防腐脂及其制备方法 |
| CN111269743A (zh) * | 2020-03-17 | 2020-06-12 | 郑州市欧普士科技有限公司 | 一种耐磨耐高温润滑脂及其制备方法和应用 |
| CN111269743B (zh) * | 2020-03-17 | 2022-06-28 | 郑州市欧普士科技有限公司 | 一种耐磨耐高温润滑脂及其制备方法和应用 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN107057812A (zh) | 一种钢绞线专用防腐脂及其制备方法 | |
| CN102618371A (zh) | 高滴点钢丝绳脂及其制备方法 | |
| CN103897780B (zh) | 钢丝绳抗氧耐磨表面防护脂 | |
| WO2017059677A1 (zh) | 一种长效钢丝绳麻芯脂 | |
| JP2014520927A5 (zh) | ||
| CN108531280A (zh) | 一种钢绞线专用防腐脂 | |
| CN103351918A (zh) | 一种水性拉丝润滑剂及其制备方法 | |
| CN100543098C (zh) | 油套管螺纹密封脂 | |
| CN1257964C (zh) | 烃基润滑脂组合物 | |
| CN106221879A (zh) | 一种加强型润滑油 | |
| CN105296116A (zh) | 环境友好蓖麻基导电润滑脂的组合物 | |
| CN104449971A (zh) | 一种环保型防锈油 | |
| CN103666666A (zh) | 一种钢丝绳润滑脂组合物 | |
| CN108517250A (zh) | 抗氧化铜拉丝油 | |
| CN107164027A (zh) | 轨道螺栓防锈润滑脂组合物及制备工艺 | |
| CN107903991A (zh) | 一种抗磨液压油及其制备方法 | |
| CN103965990B (zh) | 一种改善二烷基二硫代磷酸锌与基础油相容性的方法 | |
| CN105543856A (zh) | 一种油溶性缓蚀剂 | |
| CN106221860A (zh) | 一种含石墨添加剂的润滑油 | |
| CN106675700A (zh) | 铁路轨道防锈润滑脂及其制备方法 | |
| CN106929125A (zh) | 一种润滑脂组合物 | |
| CN101988004A (zh) | 一种润滑脂防锈防腐添加剂 | |
| CN105238504A (zh) | 一种耐高温钢丝绳表面防护润滑脂 | |
| CN107760427A (zh) | 一种极低分油率架空导线防腐脂及其制备方法 | |
| CN111073740A (zh) | 一种长效钢丝绳麻芯脂 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20170818 |