[go: up one dir, main page]

CN107043836A - A kind of method of blast furnace ironmaking - Google Patents

A kind of method of blast furnace ironmaking Download PDF

Info

Publication number
CN107043836A
CN107043836A CN201710251662.XA CN201710251662A CN107043836A CN 107043836 A CN107043836 A CN 107043836A CN 201710251662 A CN201710251662 A CN 201710251662A CN 107043836 A CN107043836 A CN 107043836A
Authority
CN
China
Prior art keywords
blast furnace
coke
powder
sefstromite
fluxing agent
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201710251662.XA
Other languages
Chinese (zh)
Inventor
王冰
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Individual
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Priority to CN201710251662.XA priority Critical patent/CN107043836A/en
Publication of CN107043836A publication Critical patent/CN107043836A/en
Pending legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21BMANUFACTURE OF IRON OR STEEL
    • C21B5/00Making pig-iron in the blast furnace
    • C21B5/008Composition or distribution of the charge
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21BMANUFACTURE OF IRON OR STEEL
    • C21B5/00Making pig-iron in the blast furnace
    • C21B5/007Conditions of the cokes or characterised by the cokes used
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21BMANUFACTURE OF IRON OR STEEL
    • C21B5/00Making pig-iron in the blast furnace
    • C21B5/02Making special pig-iron, e.g. by applying additives, e.g. oxides of other metals
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21BMANUFACTURE OF IRON OR STEEL
    • C21B5/00Making pig-iron in the blast furnace
    • C21B5/04Making slag of special composition

Landscapes

  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Manufacture And Refinement Of Metals (AREA)

Abstract

Smelted the invention discloses a kind of method of blast furnace ironmaking, including by furnace charge supplying blast furnace;The furnace charge includes sefstromite, fluxing agent, fuel, oxidisability powder and combustion adjuvant;The sefstromite includes vanadium-titanium magnitite sinter, vanadium-titanium pellet and lump ore;The fluxing agent includes one or more in lime stone, fluorite and manganese mineral powder;The fuel is made up of coke, nut coke and coal dust;The oxidation powder is Fe2O3;The combustion adjuvant is oxygen, and the sefstromite accounts for more than the 98% of the furnace charge gross weight, and the condition of smelting includes:Hot blast temperature in blast furnace is 1,200 1400 DEG C, and oxygen enrichment percentage is 4 10 volume %.Methods described can improve to slag fluidity, carry high-coal ratio and nut coke ratio, so as to reduce coke ratio, improve the usage factor of blast furnace.

Description

A kind of method of blast furnace ironmaking
Technical field
The invention belongs to technical field of blast furnace process, and in particular to a kind of method of blast furnace ironmaking.
Background technology
Blast furnace smelting iron method generally mainly includes:Sefstromite concentrate and common fine ore are sintered and produce sintering deposit, Pellet is produced with sefstromite concentrate and common iron concentrate pelletization, then sintering deposit, pellet and a small amount of lump ore are pressed necessarily Ratio, is added in blast furnace together with coke, while by Blast Furnace Injection coal dust and blasting air, makes coke and injection Coal dust burns, generation reducing gas (mainly CO and H2), and reducing gas removes vanadium titanium magnetic during rising in stove Oxygen in iron ore, reduction obtain iron, then dissolve drop onto cupola well realize slag, iron separation, so as to complete smelting process.
Wherein, blast furnace often smelts kilogram number of coke consumed in one ton of pig iron and represents that coke ratio is blast furnace ironmaking with coke ratio Main economic and technical indices, concentrated expression blast furnace ironmaking raw material, fuel, the level of equipment and technical operation, coke ratio more it is low just Represent that blast furnace working effect is better.At present, coke consumption is replaced using raising cheap fuel pulverized coal consumption, so that coke ratio is reduced, Improve the capacity factor of a blast furnace.A large amount of coal dusts are unburned during big discharge rate coal powder injection carries high-coal ratio, and a part is discharged with blast furnace gas Outside stove, another part is gathered in cupola well.Now, in cupola well unburned coal powder can be produced with the TiO2 reactions in slag substantial amounts of TiC, TiN and Ti (C, N), the titanium-containing compound of these new generations has higher fusing point, causes titanium slag to become sticky, be unfavorable for Slag sluicing system, and there is hearth accumulation phenomenon.
The content of the invention
Goal of the invention:The present invention is directed to deficiency of the prior art, proposes a kind of method of blast furnace ironmaking, and this method can change It is kind that high-coal ratio and nut coke ratio are carried to slag fluidity, so as to reduce coke ratio, improve the usage factor of blast furnace.
Technical scheme:A kind of method of blast furnace ironmaking of the present invention, methods described includes entering in furnace charge supplying blast furnace Row is smelted;The furnace charge includes sefstromite, fluxing agent, fuel, oxidisability powder and combustion adjuvant;The sefstromite includes vanadium Titanium sintering deposit, vanadium-titanium pellet and lump ore;The fluxing agent includes one or more in lime stone, fluorite and manganese mineral powder;It is described Fuel is made up of coke, nut coke and coal dust;The oxidation powder is Fe2O3;The combustion adjuvant is oxygen, and the sefstromite is accounted for More than the 98% of the furnace charge gross weight, the condition of smelting includes:Hot blast temperature in blast furnace is 1200-1400 DEG C, oxygen-enriched Rate is 4-10 volumes %.
Further, methods described also includes the nut coke being added in the sefstromite, is uniformly mixed to form ore deposit Rock layers;The coke and ore layer alternating cloth are entered into blast furnace, the alternate layer structure of ore layer and coke layer is formed.
Further, methods described also includes the fluxing agent, the oxidation powder with the combustion adjuvant with the coal dust Injection enters blast furnace.
Further, in terms of quality percentage, the sefstromite includes vanadium-titanium magnitite sinter 65%~80%, vanadium-titanium pellet 15%~25% and lump ore 2%~10%.
Further, in terms of quality percentage, the fluxing agent is 0 .5~5% of the coal dust amount;In terms of quality percentage, The fluxing agent includes lime stone 20~80%, fluorite 5~60% and manganese mineral powder 15%~60%.
Further, in terms of quality percentage, the oxidisability powder is 0 .8~6% of the coal dust amount.
Further, the nut coke granularity is 6~20mm.
Further, the coal powder size is 180~200 mesh.
Further, methods described also includes control 200~350kg/t of coke ratio, and nut coke is than 50~160kg/t, coal ratio 120~170kg/t.
Beneficial effect:The present invention is used as and helped using alkali flux lime stone, center fluxing agent fluorite and manganese mineral powder mixing Flux, reduction ironmaking fusing point, and improve slag fluidity;Combustion adjuvant is added as furnace charge, the coal powder ignition time can be shortened, by force Powdered coal burns, and improves the combustion rate of coal dust, reduces unburned coal powder content in stove, it is to avoid the TiO2 reduction in slag;Add oxygen Powder Fe2O3 is as furnace charge for the property changed, and can occur redox reaction with Low-valent Titanium (such as TiC, TiN and TiCN), by Low-valent Titanium Be oxidized to high price titanium, improve Performance of Slag, effectively reduce the viscosity of high-titanium blast furnace slag under the conditions of big coal injection, beneficial to titanium slag with Slag sluicing system.
Embodiment
With reference to specific embodiment, the invention will be further described:
Embodiment 1
A kind of method of blast furnace ironmaking, methods described includes being smelted in furnace charge supplying blast furnace;The furnace charge includes vanadium ferrotianium Ore deposit, fluxing agent, fuel, oxidisability powder and combustion adjuvant;The sefstromite includes vanadium-titanium magnitite sinter, vanadium-titanium pellet and block Ore deposit;The fluxing agent includes one or more in lime stone, fluorite and manganese mineral powder;The fuel is by coke, nut coke and coal dust group Into;The oxidation powder is Fe2O3;The combustion adjuvant is oxygen, and the nut coke is added in the sefstromite, uniform mixed Conjunction forms ore layer;The coke and ore layer alternating cloth are entered into blast furnace, the alternate of ore layer and coke layer is formed Layer structure, the fluxing agent, the oxidation powder enter blast furnace with the combustion adjuvant with the breeze blowing.The vanadium ferrotianium Ore deposit accounts for more than the 98% of the furnace charge gross weight, and the condition of smelting includes:Hot blast temperature in blast furnace is 1200 DEG C, oxygen enrichment percentage For 4 volume %.
In terms of quality percentage, the sefstromite includes vanadium-titanium magnitite sinter 65%, vanadium-titanium pellet 15% and lump ore 2%. In terms of quality percentage, the fluxing agent is 0 .5% of the coal dust amount;In terms of quality percentage, the fluxing agent includes lime stone 20%th, fluorite 5% and manganese mineral powder 15%.In terms of quality percentage, the oxidisability powder is 0 .8% of the coal dust amount.
The nut coke granularity is 6mm, and the coal powder size is 180 mesh.Methods described also includes control coke ratio 200kg/t, Nut coke compares 120kg/t than 50kg/t, coal.
Embodiment 2
A kind of method of blast furnace ironmaking, methods described includes being smelted in furnace charge supplying blast furnace;The furnace charge includes vanadium ferrotianium Ore deposit, fluxing agent, fuel, oxidisability powder and combustion adjuvant;The sefstromite includes vanadium-titanium magnitite sinter, vanadium-titanium pellet and block Ore deposit;The fluxing agent includes one or more in lime stone, fluorite and manganese mineral powder;The fuel is by coke, nut coke and coal dust group Into;The oxidation powder is Fe2O3;The combustion adjuvant is oxygen, and the nut coke is added in the sefstromite, uniform mixed Conjunction forms ore layer;The coke and ore layer alternating cloth are entered into blast furnace, the alternate of ore layer and coke layer is formed Layer structure, the fluxing agent, the oxidation powder enter blast furnace with the combustion adjuvant with the breeze blowing.The vanadium ferrotianium Ore deposit accounts for more than the 98% of the furnace charge gross weight, and the condition of smelting includes:Hot blast temperature in blast furnace is 1400 DEG C, oxygen enrichment percentage For 10 volume %.
In terms of quality percentage, the sefstromite includes vanadium-titanium magnitite sinter 80%, vanadium-titanium pellet 25% and lump ore 10%. In terms of quality percentage, the fluxing agent is the 5% of the coal dust amount;In terms of quality percentage, the fluxing agent includes lime stone 80%th, fluorite 60% and manganese mineral powder 60%.In terms of quality percentage, the oxidisability powder is the 6% of the coal dust amount.
The nut coke granularity is 20mm, and the coal powder size is 200 mesh.Methods described also includes control coke ratio 350kg/t, Nut coke compares 170kg/t than 160kg/t, coal.
Embodiment 3
A kind of method of blast furnace ironmaking, methods described includes being smelted in furnace charge supplying blast furnace;The furnace charge includes vanadium ferrotianium Ore deposit, fluxing agent, fuel, oxidisability powder and combustion adjuvant;The sefstromite includes vanadium-titanium magnitite sinter, vanadium-titanium pellet and block Ore deposit;The fluxing agent includes one or more in lime stone, fluorite and manganese mineral powder;The fuel is by coke, nut coke and coal dust group Into;The oxidation powder is Fe2O3;The combustion adjuvant is oxygen, and the nut coke is added in the sefstromite, uniform mixed Conjunction forms ore layer;The coke and ore layer alternating cloth are entered into blast furnace, the alternate of ore layer and coke layer is formed Layer structure, the fluxing agent, the oxidation powder enter blast furnace with the combustion adjuvant with the breeze blowing.The vanadium ferrotianium Ore deposit accounts for more than the 98% of the furnace charge gross weight, and the condition of smelting includes:Hot blast temperature in blast furnace is 1300 DEG C, oxygen enrichment percentage For 6 volume %.
In terms of quality percentage, the sefstromite includes vanadium-titanium magnitite sinter 70%, vanadium-titanium pellet 20% and lump ore 6%. In terms of quality percentage, the fluxing agent is the 3% of the coal dust amount;In terms of quality percentage, the fluxing agent includes lime stone 60%th, fluorite 30% and manganese mineral powder 40%.In terms of quality percentage, the oxidisability powder is the 3% of the coal dust amount.
The nut coke granularity is 10mm, and the coal powder size is 190 mesh.Methods described also includes control coke ratio 250kg/t, Nut coke compares 150kg/t than 100kg/t, coal.
The present invention is used as fluxing agent, reduction using alkali flux lime stone, center fluxing agent fluorite and manganese mineral powder mixing Fusing point is smelted iron, and improves slag fluidity;Combustion adjuvant is added as furnace charge, the coal powder ignition time can be shortened, strengthens coal dust firing , the combustion rate of coal dust is improved, unburned coal powder content in stove is reduced, it is to avoid the TiO2 reduction in slag;Add oxidisability powder Fe2O3 can occur redox reaction with Low-valent Titanium (such as TiC, TiN and TiCN), Low-valent Titanium is oxidized into height as furnace charge Valency titanium, improves Performance of Slag, the viscosity of high-titanium blast furnace slag under the conditions of big coal injection is effectively reduced, beneficial to titanium slag and slag sluicing system.
The above described is only a preferred embodiment of the present invention, any formal limitation not is made to the present invention, though So the present invention is disclosed above with preferred embodiment, but is not limited to the present invention, any to be familiar with this professional technology people Member, without departing from the scope of the present invention, when the technology contents using the disclosure above make a little change or modification For the equivalent embodiment of equivalent variations, as long as being the content without departing from technical solution of the present invention, the technical spirit according to the present invention Any simple modification, equivalent variations and the modification made to above example, in the range of still falling within technical solution of the present invention.

Claims (9)

1. a kind of method of blast furnace ironmaking, it is characterised in that methods described includes being smelted in furnace charge supplying blast furnace;The stove Material includes sefstromite, fluxing agent, fuel, oxidisability powder and combustion adjuvant;The sefstromite includes vanadium-titanium magnitite sinter, vanadium titanium Pellet and lump ore;The fluxing agent includes one or more in lime stone, fluorite and manganese mineral powder;The fuel is by coke, Jiao Fourth and coal dust composition;The oxidation powder is Fe2O3;The combustion adjuvant is oxygen, and the sefstromite accounts for the furnace charge gross weight More than the 98% of amount, the condition of smelting includes:Hot blast temperature in blast furnace is 1200-1400 DEG C, and oxygen enrichment percentage is 4-10 bodies Product %.
2. the method for blast furnace ironmaking according to claim 1, it is characterised in that methods described also includes adding the nut coke Into the sefstromite, ore layer is uniformly mixed to form;The coke and ore layer alternating cloth are entered into blast furnace, formed The alternate layer structure of ore layer and coke layer.
3. the method for blast furnace ironmaking according to claim 1, it is characterised in that methods described also includes the fluxing agent, institute State oxidation powder and enter blast furnace with the breeze blowing with the combustion adjuvant.
4. the method for blast furnace ironmaking according to claim 1, it is characterised in that in terms of quality percentage, the sefstromite bag Include vanadium-titanium magnitite sinter 65%~80%, vanadium-titanium pellet 15%~25% and lump ore 2%~10%.
5. the method for blast furnace ironmaking according to claim 1, it is characterised in that in terms of quality percentage, the fluxing agent is institute State 0 .5~5% of coal dust amount;In terms of quality percentage, the fluxing agent includes lime stone 20~80%, fluorite 5~60% and manganese Miberal powder 15%~60%.
6. the method for blast furnace ironmaking according to claim 1, it is characterised in that in terms of quality percentage, the oxidisability powder For 0 .8~6% of the coal dust amount.
7. the method for blast furnace ironmaking according to claim 1, it is characterised in that the nut coke granularity is 6~20mm.
8. the method for blast furnace ironmaking according to claim 1, it is characterised in that the coal powder size is 180~200 mesh.
9. the method for blast furnace ironmaking according to claim 1, it is characterised in that methods described also include control coke ratio 200~ 350kg/t, nut coke is than 50~160kg/t, and coal is than 120~170kg/t.
CN201710251662.XA 2017-04-18 2017-04-18 A kind of method of blast furnace ironmaking Pending CN107043836A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710251662.XA CN107043836A (en) 2017-04-18 2017-04-18 A kind of method of blast furnace ironmaking

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201710251662.XA CN107043836A (en) 2017-04-18 2017-04-18 A kind of method of blast furnace ironmaking

Publications (1)

Publication Number Publication Date
CN107043836A true CN107043836A (en) 2017-08-15

Family

ID=59545267

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201710251662.XA Pending CN107043836A (en) 2017-04-18 2017-04-18 A kind of method of blast furnace ironmaking

Country Status (1)

Country Link
CN (1) CN107043836A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108330238A (en) * 2018-02-27 2018-07-27 北京科技大学 A method of utilizing the smelting vanadium-titanium magnetite by blast furnace of superelevation oxygen-enriched air blast
CN108842016A (en) * 2018-08-21 2018-11-20 成渝钒钛科技有限公司 Improve the method that schreyerite smelts productivity
CN117487978A (en) * 2023-11-27 2024-02-02 山东钢铁集团永锋临港有限公司 A kind of blast furnace high-intensity smelting method

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102206718A (en) * 2010-03-29 2011-10-05 攀钢集团钢铁钒钛股份有限公司 Furnace charge for vanadium-titanium magnetite blast furnace smelting, and blast furnace smelting method
CN103820590A (en) * 2014-02-11 2014-05-28 东北大学 Ore and coke mixed blast furnace smelting method for vanadium-titanium magnetite ore
CN106191351A (en) * 2016-08-31 2016-12-07 云南德胜钢铁有限公司 A kind of method of blast furnace ironmaking
CN106282453A (en) * 2016-08-31 2017-01-04 云南德胜钢铁有限公司 A kind of method of sefstromite blast furnace process

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102206718A (en) * 2010-03-29 2011-10-05 攀钢集团钢铁钒钛股份有限公司 Furnace charge for vanadium-titanium magnetite blast furnace smelting, and blast furnace smelting method
CN103820590A (en) * 2014-02-11 2014-05-28 东北大学 Ore and coke mixed blast furnace smelting method for vanadium-titanium magnetite ore
CN106191351A (en) * 2016-08-31 2016-12-07 云南德胜钢铁有限公司 A kind of method of blast furnace ironmaking
CN106282453A (en) * 2016-08-31 2017-01-04 云南德胜钢铁有限公司 A kind of method of sefstromite blast furnace process

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108330238A (en) * 2018-02-27 2018-07-27 北京科技大学 A method of utilizing the smelting vanadium-titanium magnetite by blast furnace of superelevation oxygen-enriched air blast
CN108330238B (en) * 2018-02-27 2019-11-12 北京科技大学 A method for smelting vanadium-titanium magnetite using a blast furnace with ultra-high oxygen-enriched blast
CN108842016A (en) * 2018-08-21 2018-11-20 成渝钒钛科技有限公司 Improve the method that schreyerite smelts productivity
CN117487978A (en) * 2023-11-27 2024-02-02 山东钢铁集团永锋临港有限公司 A kind of blast furnace high-intensity smelting method

Similar Documents

Publication Publication Date Title
CN101775451B (en) Blast-furnace smelting method for vanadium titano-magnetite
CN101476002B (en) Blast furnace iron manufacturing process
CN101597661B (en) A method of smelting reduction ironmaking
CN107267749A (en) The method that the high vanadium vanadium titanium magnet ore concentrate mix containing chromium type of high-grade prepares sintering deposit
CN104862436B (en) A kind of large blast furnace banking distribution
CN107312899A (en) A kind of blast furnace smelting method of the high vanadium v-ti magnetite concentrate containing chromium type of high-grade
CN105838838B (en) Method for preparing pure steel by coal gas direct reduction one-step method
CN110305999B (en) A kind of metallized charge for processing blast furnace hearth accumulation and using method thereof
CN106191351A (en) A kind of method of blast furnace ironmaking
CN101215614A (en) Reducing chamber and heating chamber multilayer obturation alternation and fusion gasification combination metal smelting method
CN106011341B (en) The method that blast furnace process schreyerite carries high-coal ratio
CN104328242B (en) Method for making steel containing vanadium titanium high phosphorus hot metal
CN106119449B (en) A kind of blast furnace whole world group smelting process
CN106282453A (en) A kind of method of sefstromite blast furnace process
CN106086281A (en) The ironmaking of a kind of flash and the integrated apparatus of coal gas and method
CN107043836A (en) A kind of method of blast furnace ironmaking
CN108950111A (en) High-grade blast-furnace smelting method for vanadium titano-magnetite
CN101967530A (en) Method for reducing iron by smelting reduction in electrometallurgy
CN105463214A (en) Method for producing high-nickel iron by adopting low-grade laterite-nickel ores
CN104878148A (en) High reducing atmosphere rotary hearth furnace iron making method
CN113736992A (en) Limestone type fluxed pellet produced by adding fluorine-containing magnetite concentrate and preparation method thereof
CN109929957A (en) A kind of device and method of pre-reduced iron ore high melt production molten iron
JP2023152271A (en) Iron titanium composite coke for low carbon steelmaking and manufacturing method thereof
AU2008355447A1 (en) A method of iron smelting in blast furnace with high temperature coal gas
JPH0635604B2 (en) Blast furnace operation method

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication
RJ01 Rejection of invention patent application after publication

Application publication date: 20170815