CN1070421A - Rinsing drying brightener for tableware - Google Patents
Rinsing drying brightener for tableware Download PDFInfo
- Publication number
- CN1070421A CN1070421A CN 91106236 CN91106236A CN1070421A CN 1070421 A CN1070421 A CN 1070421A CN 91106236 CN91106236 CN 91106236 CN 91106236 A CN91106236 A CN 91106236A CN 1070421 A CN1070421 A CN 1070421A
- Authority
- CN
- China
- Prior art keywords
- tableware
- water
- alkyl
- purificant
- polyoxyethylene
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000001035 drying Methods 0.000 title abstract description 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 20
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 16
- -1 siloxanes Chemical class 0.000 claims abstract description 11
- 150000001875 compounds Chemical class 0.000 claims abstract description 8
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims abstract description 5
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 claims abstract description 5
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 claims abstract description 3
- 125000002467 phosphate group Chemical class [H]OP(=O)(O[H])O[*] 0.000 claims abstract 2
- 239000004094 surface-active agent Substances 0.000 claims description 6
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 4
- 239000013543 active substance Substances 0.000 claims description 4
- 239000000203 mixture Substances 0.000 claims description 4
- 229920001296 polysiloxane Polymers 0.000 claims description 4
- 238000002360 preparation method Methods 0.000 claims description 4
- 229910052708 sodium Inorganic materials 0.000 claims description 4
- 239000013530 defoamer Substances 0.000 claims description 3
- 239000008157 edible vegetable oil Substances 0.000 claims description 2
- RNMDNPCBIKJCQP-UHFFFAOYSA-N 5-nonyl-7-oxabicyclo[4.1.0]hepta-1,3,5-trien-2-ol Chemical compound C(CCCCCCCC)C1=C2C(=C(C=C1)O)O2 RNMDNPCBIKJCQP-UHFFFAOYSA-N 0.000 claims 1
- 235000009508 confectionery Nutrition 0.000 claims 1
- 239000003921 oil Substances 0.000 claims 1
- 239000002994 raw material Substances 0.000 claims 1
- BCKXLBQYZLBQEK-KVVVOXFISA-M Sodium oleate Chemical compound [Na+].CCCCCCCC\C=C/CCCCCCCC([O-])=O BCKXLBQYZLBQEK-KVVVOXFISA-M 0.000 abstract description 2
- 239000006260 foam Substances 0.000 description 13
- 238000005406 washing Methods 0.000 description 7
- 230000000694 effects Effects 0.000 description 4
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 230000035622 drinking Effects 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 150000003014 phosphoric acid esters Chemical class 0.000 description 2
- 229920000570 polyether Polymers 0.000 description 2
- 230000001737 promoting effect Effects 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- SNRUBQQJIBEYMU-UHFFFAOYSA-N Dodecane Natural products CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 1
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 239000004721 Polyphenylene oxide Substances 0.000 description 1
- ULUAUXLGCMPNKK-UHFFFAOYSA-N Sulfobutanedioic acid Chemical compound OC(=O)CC(C(O)=O)S(O)(=O)=O ULUAUXLGCMPNKK-UHFFFAOYSA-N 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 150000001335 aliphatic alkanes Chemical class 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- 150000004985 diamines Chemical class 0.000 description 1
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 1
- 238000004851 dishwashing Methods 0.000 description 1
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 239000003651 drinking water Substances 0.000 description 1
- 235000020188 drinking water Nutrition 0.000 description 1
- IDGUHHHQCWSQLU-UHFFFAOYSA-N ethanol;hydrate Chemical compound O.CCO IDGUHHHQCWSQLU-UHFFFAOYSA-N 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 206010016256 fatigue Diseases 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 238000011010 flushing procedure Methods 0.000 description 1
- 235000011194 food seasoning agent Nutrition 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 230000005764 inhibitory process Effects 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000002480 mineral oil Substances 0.000 description 1
- 235000010446 mineral oil Nutrition 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 125000001400 nonyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 229940049964 oleate Drugs 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 229920002545 silicone oil Polymers 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- PVGBHEUCHKGFQP-UHFFFAOYSA-N sodium;n-[5-amino-2-(4-aminophenyl)sulfonylphenyl]sulfonylacetamide Chemical compound [Na+].CC(=O)NS(=O)(=O)C1=CC(N)=CC=C1S(=O)(=O)C1=CC=C(N)C=C1 PVGBHEUCHKGFQP-UHFFFAOYSA-N 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 230000009967 tasteless effect Effects 0.000 description 1
- 230000001052 transient effect Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/373—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicones
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
Abstract
A kind of rinsing drying brightener for tableware, be formulated by aliphatic alcohol polyoxyvinethene phosphate salt, siloxanes, alkylphenol polyoxyethylene, sodium oleate, oxyethane propylene oxide block compound, second alcohol and water, 1～2min can be dry under rinsing tableware room temperature, tableware forms complete bright film, do not stay trace, light as new.
Description
The present invention relates to a kind of is main composition by tensio-active agent.
The mechanize dishwasher is all adopted in the washing of the tableware in large-scale eating house, restaurant, drinking utensils, glassware for drinking water (below be referred to as tableware), when washing, add washing composition usually, wash to finish and use flushing with clean water again, after treating that machine transmits automatically, then dry as using immediately with soft cloth, then place seasoning as not using immediately, need dry, bright in a word in use.Above way wash dining set or the globule is arranged or brightless, or the trace of water is arranged, and all not meeting the particularly the sort of whole day business of high-level requirement, the tableware that tableware need have enough to meet the need after fast restaurant, hotel need wash can very fast drying, do not stay the purificant of any trace after doing, to adapt to the business needs.Reported in literature is arranged; The purificant that a kind of aqueous solution that adds ethanol, Virahol is made can impel fast doing, but is not to still have foam, trace is arranged after doing, and is exactly scent of and undesirable.The rinsing liquid that European patent (Eur.P.Appl, EP59136) provides, its component are block compound, water and the alcohol that OP compound (oxyethane and alkylphenol reaction form), epoxy alkane and 2-list or diamine reaction form.For example: the OP-23 with 5%, the block compound that 41% oxyethane, propylene oxide and reacting ethylenediamine generate, the rinsing liquid that 15% ethanol and 39% water are formed can be low foam when rinsing, have the very fast draining of good wet performance also can urge to do.But the purificant of this few bubble is at the machine of washing of whole day running, and small amount of foam still can be tired out becomes thick foam layer.
The purpose of this invention is to provide a kind of by the kinds of surface promoting agent; The purificant that alcohol and water etc. are formed can not produce stable foam when rinsing, can do soon after washing, and does back tableware light as new.
Because the washing composition that uses during dishwashing detergent mostly is ionogenic surfactant, certain alkalescence is not only arranged to wash dirt, produces certain foam simultaneously to remove dirt.Yet this foam is difficult for removing, and stays a little and can stay the mottled trace of influence light when cleaning after doing on the tableware, thereby must remove.Froth breaking has two kinds of ways: the one, destroy foam, and use alcohols to get final product, but this is temporary transient; Another kind is the tensio-active agent that adds the very low non-ionic type of various HLB values, for example polyether surfactant, soap, polyoxyethylene glycol, sulfosuccinate, mineral oil, silicone oil etc.The present invention is according to these principles, and the salt of the polyethers of using organosilyl compound, being made by oxyethane and propylene oxide, the phosphoric acid ester of Soxylat A 25-7 etc. are as defoamer, and particularly silicoorganic compound can not only break bubble, but and the long term inhibition foam produce; OP type tensio-active agent is done the back good film-forming property increases the tableware luminance brightness; Ethanol also has broken bubble effect, but also has the effect of doing of urging.Purificant provided by the invention is made compositing formula:
(1) aliphatic alcohol polyoxyvinethene phosphate salt
Wherein R is C
10～C
20Alkyl, n=1～10.
M＝K、Na 0～10%
(2) silicone surfactant
R
2HSiO-（-SiHMeO-）n-SiHR
2
Wherein R is C
1～C
3Alkyl, n=1～15 0～3%
(3) bubble enemy (polyoxyethylene oxygen Ethylene Glycol ether Defoamer GPE) 15～30%
(4) alkylphenol polyoxyethylene (OP)
R-C
6H
4O-（-CH
2CH
2O-）n-H
Wherein R is C
5～C
18Alkyl, n=5～30 5～20%
(5) edible oil hydrochlorate RCOOM
Wherein R is C
15～C
18Alkyl M=Na, K 1～10%
(6) oxyethane propylene oxide block compound
H-（-OCH
2CH
2-）p-（-OCH
2CH
2CH
2-）m-O-（-CH
2CH
2O-）n-H
P=10～20 wherein, m=5～20, n=10-20 0～20%
(7) ethanol 5～20%
(8) water surplus
Only get a wherein part when above component is prepared as required, only need during preparation the stirring soluble in water of above component is formed.The purificant that so is made into is still a kind of concentrated solution, is made into 3～5% again during use; Or in washing machine, use concentrated solution, with the control of the distribution plate in the machine.Be at 70～90 ℃ of following continuous operation 0.5～2.0h during rinsing, be provided with stable foam in the machine, 1～2min can be dry under the air-tight state under the tableware taking-up room temperature.The tableware surface has the complete bright film of one deck, does not leave any trace, light as new.
Characteristics of the present invention are to use kinds of surface promoting agent and the formulated tableware purificant of ethanol water, compound method is easy, product is nontoxic, tasteless, when the rinsing tableware, do not produce stable foam, can work the effect of doing of urging, very fast drying after rinsing is intact, and can form complete bright film on the tableware surface, make tableware light as new.
Example 1
Press following formulated purificant:
1, silicone surfactant
Me
2HSiO-（-SiHMeO-）
10-SiHMe
20.01%
2, Nonyl pheno (10) ether 10%
3, the bubble enemy 20%
4, sodium oleate 5%
5, ethanol 10%
6, water surplus (about 55%)
Dishwasher is at 80 ℃ of following continuous operation 1h. of water temperature, and machine inner foam area only accounts for 1/6 of water-surface area, dies away after half a minute.Tableware sends out 45SeC to 1min10SeC inner drying under 25 ℃ of closed states, and the tableware smooth and bright surface can reach and urge dried brightness effect.
Example 2
Press following formulated purificant:
1、Me
2HSiO-（-SiHMeO-）
10-SiHMe
20.01%
2, two dodecyl Soxylat A 25-7s (10) phosphoric acid ester 7.5%
3, the bubble enemy 28.0%
4、OP-10 15.0%
5, sodium oleate 2.5%
6, ethanol 15.0%
7, water surplus (being about 32.0%)
Rinsing tableware in dishwasher does not have the accumulation stable foam in 80 ℃ of water temperature continuous operation 1h., machine, 45SeC to 50SeC promptly does under 25 ℃ of following closed states of tableware taking-up.The plate surface filming is complete, and water tumbler, drinking utensils smooth finish are good, no watermark.
Claims (2)
1,, the invention is characterized in that the feed composition and the proportioning of preparation purificant is by tensio-active agent, alcohol, the formulated purificant of water:
(1) aliphatic alcohol polyoxyvinethene phosphate salt
Wherein R is C
10～C
20Alkyl, n=1～10.
M=K、Na 0～10%
(2) silicone surfactant
R
2HSiO-(-SiHMeO-)n-SiHR
2
Wherein R is C
1～C
3Alkyl, n=1～15 0～3%
(3) (polyoxyethylene oxygen ethene is sweet to steep the enemy
Oil ether Defoamer GPE) 15～30%
(4) alkylphenol polyoxyethylene (OP)
R-C
6H
4O-(-CH
2CH
2O-)n-H
Wherein R is C
5～C
18Alkyl, n=5～30 5～20%
(5) edible oil hydrochlorate RCOOM
Wherein R is C
15～C
18Alkyl M=Na, K 1～10%
(6) oxyethane propylene oxide block compound
H-(-OCH
2CH
2-)p-(-OCH
2CH
2CH
2-)m-O-(-CH
2CH
2O-)n-H
P=10～20 wherein, m=5～20, n=10-20 0～20%
(7) ethanol 5～20%
(8) water surplus
During preparation raw material at room temperature is dissolved in ethanol or the water, mixes and form.
2, the preparation of purificant as claimed in claim 1, the structure that is characterized as described silicone surfactant of the present invention is:
Me
2HSiO-（-SiHMeO-）n-SiHMe
2
N=8～12 wherein;
Described alkylphenol polyoxyethylene is a polyoxyethylene nonylphenol ether, and wherein n is 8～12.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 91106236 CN1070421A (en) | 1991-09-11 | 1991-09-11 | Rinsing drying brightener for tableware |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 91106236 CN1070421A (en) | 1991-09-11 | 1991-09-11 | Rinsing drying brightener for tableware |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1070421A true CN1070421A (en) | 1993-03-31 |
Family
ID=4907670
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 91106236 Pending CN1070421A (en) | 1991-09-11 | 1991-09-11 | Rinsing drying brightener for tableware |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1070421A (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1039822C (en) * | 1993-09-25 | 1998-09-16 | 山西省派尔保健日化厂 | Detergent for washing table ware containing isatis root |
| CN101508872B (en) * | 2009-03-11 | 2012-09-19 | 李汉辉 | Drier for bleaching of dish washing machine |
| CN101463229B (en) * | 2008-11-28 | 2012-10-03 | 江苏海迅实业集团股份有限公司 | Grinding agent for dental ceramic material |
| CN101189324B (en) * | 2005-05-04 | 2015-03-11 | 迪瓦西公司 | Warewashing system containing low levels of surfactant |
| CN112438675A (en) * | 2020-11-04 | 2021-03-05 | 华帝股份有限公司 | Intelligent throwing control method and system for dish brightening agent |
| CN115386437A (en) * | 2022-08-31 | 2022-11-25 | 中山百科清洁用品制造有限公司 | A special rinse agent for automatic dishwasher and preparation method thereof |
-
1991
- 1991-09-11 CN CN 91106236 patent/CN1070421A/en active Pending
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1039822C (en) * | 1993-09-25 | 1998-09-16 | 山西省派尔保健日化厂 | Detergent for washing table ware containing isatis root |
| CN101189324B (en) * | 2005-05-04 | 2015-03-11 | 迪瓦西公司 | Warewashing system containing low levels of surfactant |
| CN101463229B (en) * | 2008-11-28 | 2012-10-03 | 江苏海迅实业集团股份有限公司 | Grinding agent for dental ceramic material |
| CN101508872B (en) * | 2009-03-11 | 2012-09-19 | 李汉辉 | Drier for bleaching of dish washing machine |
| CN112438675A (en) * | 2020-11-04 | 2021-03-05 | 华帝股份有限公司 | Intelligent throwing control method and system for dish brightening agent |
| CN115386437A (en) * | 2022-08-31 | 2022-11-25 | 中山百科清洁用品制造有限公司 | A special rinse agent for automatic dishwasher and preparation method thereof |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C01 | Deemed withdrawal of patent application (patent law 1993) | ||
| WD01 | Invention patent application deemed withdrawn after publication |