CN107011736A - White marks ink and its manufacture method - Google Patents
White marks ink and its manufacture method Download PDFInfo
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- CN107011736A CN107011736A CN201710421267.1A CN201710421267A CN107011736A CN 107011736 A CN107011736 A CN 107011736A CN 201710421267 A CN201710421267 A CN 201710421267A CN 107011736 A CN107011736 A CN 107011736A
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- ink
- flocculant
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- 238000004519 manufacturing process Methods 0.000 title claims abstract description 14
- 238000000034 method Methods 0.000 title claims abstract description 12
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 84
- 239000004408 titanium dioxide Substances 0.000 claims abstract description 36
- 229920005989 resin Polymers 0.000 claims abstract description 27
- 239000011347 resin Substances 0.000 claims abstract description 27
- 239000002904 solvent Substances 0.000 claims abstract description 23
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 8
- 239000000758 substrate Substances 0.000 claims abstract description 8
- 239000000080 wetting agent Substances 0.000 claims abstract description 7
- 239000012046 mixed solvent Substances 0.000 claims abstract description 4
- 238000003756 stirring Methods 0.000 claims abstract description 4
- 235000010215 titanium dioxide Nutrition 0.000 claims description 40
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 33
- 238000009835 boiling Methods 0.000 claims description 16
- -1 alkyl phosphate Chemical compound 0.000 claims description 10
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 claims description 10
- 239000000203 mixture Substances 0.000 claims description 9
- 239000002245 particle Substances 0.000 claims description 9
- 229910019142 PO4 Inorganic materials 0.000 claims description 8
- 239000010452 phosphate Substances 0.000 claims description 8
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 claims description 5
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 claims description 5
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 5
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 claims description 5
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 claims description 4
- 240000000972 Agathis dammara Species 0.000 claims description 4
- 229920002871 Dammar gum Polymers 0.000 claims description 4
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 claims description 4
- 150000001408 amides Chemical class 0.000 claims description 4
- YAVVGPBYBUYPSR-UHFFFAOYSA-N benzene;oxygen Chemical compound [O].C1=CC=CC=C1 YAVVGPBYBUYPSR-UHFFFAOYSA-N 0.000 claims description 4
- ARXJGSRGQADJSQ-UHFFFAOYSA-N 1-methoxypropan-2-ol Chemical compound COCC(C)O ARXJGSRGQADJSQ-UHFFFAOYSA-N 0.000 claims description 3
- CUDYYMUUJHLCGZ-UHFFFAOYSA-N 2-(2-methoxypropoxy)propan-1-ol Chemical compound COC(C)COC(C)CO CUDYYMUUJHLCGZ-UHFFFAOYSA-N 0.000 claims description 3
- 239000004925 Acrylic resin Substances 0.000 claims description 3
- 229920000178 Acrylic resin Polymers 0.000 claims description 3
- 229920001807 Urea-formaldehyde Polymers 0.000 claims description 2
- 150000002148 esters Chemical class 0.000 claims description 2
- ODGAOXROABLFNM-UHFFFAOYSA-N polynoxylin Chemical compound O=C.NC(N)=O ODGAOXROABLFNM-UHFFFAOYSA-N 0.000 claims description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 2
- 239000004372 Polyvinyl alcohol Substances 0.000 claims 1
- 150000001299 aldehydes Chemical class 0.000 claims 1
- 229920002451 polyvinyl alcohol Polymers 0.000 claims 1
- 238000003860 storage Methods 0.000 abstract description 5
- 239000000463 material Substances 0.000 description 6
- 230000035699 permeability Effects 0.000 description 6
- 239000000843 powder Substances 0.000 description 4
- 239000000835 fiber Substances 0.000 description 3
- 238000005189 flocculation Methods 0.000 description 3
- 230000016615 flocculation Effects 0.000 description 3
- 229920002037 poly(vinyl butyral) polymer Polymers 0.000 description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
- QCDWFXQBSFUVSP-UHFFFAOYSA-N 2-phenoxyethanol Chemical compound OCCOC1=CC=CC=C1 QCDWFXQBSFUVSP-UHFFFAOYSA-N 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000000605 extraction Methods 0.000 description 2
- 230000005484 gravity Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- RCHKEJKUUXXBSM-UHFFFAOYSA-N n-benzyl-2-(3-formylindol-1-yl)acetamide Chemical compound C12=CC=CC=C2C(C=O)=CN1CC(=O)NCC1=CC=CC=C1 RCHKEJKUUXXBSM-UHFFFAOYSA-N 0.000 description 2
- 229960005323 phenoxyethanol Drugs 0.000 description 2
- 238000001556 precipitation Methods 0.000 description 2
- 239000000725 suspension Substances 0.000 description 2
- 238000010998 test method Methods 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 235000014692 zinc oxide Nutrition 0.000 description 2
- 239000011787 zinc oxide Substances 0.000 description 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- 229910002012 Aerosil® Inorganic materials 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 239000004411 aluminium Substances 0.000 description 1
- 239000012296 anti-solvent Substances 0.000 description 1
- 239000000440 bentonite Substances 0.000 description 1
- 229910000278 bentonite Inorganic materials 0.000 description 1
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/16—Writing inks
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The white marks ink and its manufacture method of the present invention, white marks ink includes：Titanium dioxide, percentage by weight is 20~35%；Flocculant, including the first control flocculant and auxiliary control flocculant are controlled, first controls the percentage by weight of flocculant to be 5~15%, auxiliary controls the percentage by weight of flocculant to be the 10~15% of the weight percent content of the first control flocculant；Alcohol-soluble resin, percentage by weight is 8~15%；Substrate wetting agents, percentage by weight is 0.1~0.5%；Raise one's hat and prevent withered agent, percentage by weight is 0.1~0.5%；Solvent.The manufacture method of the present invention, the white marks ink for manufacturing the present invention, control flocculant is added in ink while stirring after should being diluted by mixed solvent.Technical scheme discloses a kind of using rolled core as storage medium, there is fine attachment fastness and the white marks ink of covering power on a variety of surfaces.
Description
Technical field
The present invention relates to the slurry for coloring, more particularly to a kind of white marks ink and its manufacture method.
Background technology
The conventional ink marked in dark colored surface is paint board pen ink, and the medium for storing this ink is typically aluminum pipe.Aluminium
It is a kind of metal material of highly energy-consuming, it is necessary to the amount out of ink of special Valve controlling ink in production practices, and ensures
The fluency of ink, ink needs to keep low viscosity, so as to cause titanium dioxide in ink to be precipitated in nib, and color is not during writing
It is homogeneous.If long-time is without titanium dioxide can form fine and close precipitation in nib, along with part is with molten caused by the error closed
Agent is volatilized, and will lose writing effect.And during painting pen use otherwise stop shaking up ink and pressing valve, also can to
Bring inconvenience in family.Also there is aqueous white marking pen on the market, but ink dried speed is too slow, it is impossible to reach satisfactory
Effect.
The content of the invention
It is an object of the invention to provide a kind of having good mobility, permeability and resistance to settling, the convenient height of writing
The white marks ink and its manufacture method of covering power.
The white marks ink of the present invention, including：
Titanium dioxide, percentage by weight is 20~35%；
Control flocculant, including the first control flocculant and auxiliary control flocculant, the weight of the first control flocculant
Percentage is 5~15%, and auxiliary controls the percentage by weight of flocculant to be the weight percent content of the first control flocculant
10~15%；
Alcohol-soluble resin, percentage by weight is 8~15%；
Substrate wetting agents, percentage by weight is 0.1~0.5%；
Raise one's hat and prevent withered agent, percentage by weight is 0.1~0.5%；
Solvent.
The white marks ink of the present invention, wherein, the solvent is the high boiling solvent of percentage by weight 1~5%, weight hundred
Divide the mixture than 10~25% medium-boiling solvents and the lower alcohol of surplus composition.
The white marks ink of the present invention, wherein, the titanium dioxide is rutile type titanium white or anatase thpe white powder, institute
The particle size range for stating titanium dioxide is 190nm~300nm, and the oil factor of the titanium dioxide is less than 25g.
The white marks ink of the present invention, wherein, described first controls flocculant to be rosin resin, the auxiliary control wadding
Solidifying agent is alkyl phosphate or aliphatic alcohol polyoxyvinethene phosphate, and the monoesters ratio of the auxiliary control flocculant is more than
70%.
The white marks ink of the present invention, wherein, the alcohol-soluble resin is polyvinyl butyral resin, aldehyde ketone resin, aldehyde
Resin, alcohol contain intermingle with urethane, alcohol and contain intermingle with amide resin, gum dammar or the molten acrylic resin of alcohol one kind therein.
The white marks ink of the present invention, wherein, the lower alcohol is the mixed of ethanol or normal propyl alcohol or ethanol and normal propyl alcohol
Compound.
The present invention white marks ink, wherein, the high boiling solvent be phenmethylol or Phenoxyethanol or benzene oxygen propyl alcohol,
The medium-boiling solvent is propylene glycol monomethyl ether or dipropylene glycol methyl ether or 3- methoxy methyl propionates.
The manufacture method of the white marks ink of the present invention, the white marks ink for manufacturing the present invention, the control
Flocculant by mixed solvent dilute after add while stirring in ink.
Technical scheme discloses a kind of using rolled core as storage medium, has fine attachment on a variety of surfaces
The white marks ink of fastness and covering power.The titanium dioxide nominal mean particle size that the present invention is used is 190nm~300nm, is passed through
Flocculation technique is controlled, makes the size controlling of titanium dioxide floccule body at 5~10 μm, the titanium dioxide floccule body has good flowing
Property, permeability and resistance to settling, so as to which conventional fiber nib and Asia makes every effort to overcome written extraction on the market at present, form pen
Head ink is not stratified, writes convenient high covering power mark ink.
Embodiment
The white marks ink of the present invention, including：
Titanium dioxide, percentage by weight is 20~35%, and particle size range is 190nm~300nm, and oil factor is less than 25g；
Control flocculant, including the first control flocculant and auxiliary control flocculant, the weight of the first control flocculant
Percentage is 5~15%, and auxiliary controls the percentage by weight of flocculant to be the weight percent content of the first control flocculant
10~15%；
Alcohol-soluble resin, percentage by weight is 8~15%, and it is that there is provided ink bulk flow for scattered suspension titanium dioxide that it, which is acted on,
Dynamic property, film forming skeleton and the adhesive force on writing base material；
Substrate wetting agents, percentage by weight is 0.1~0.5%；
Raise one's hat and prevent withered agent, percentage by weight is 0.1~0.5%；
Solvent, by the high boiling solvent of percentage by weight 1~5%, the medium-boiling solvent of percentage by weight 10~25% and
The mixture of the lower alcohol composition of surplus.
The white marks ink of the present invention, wherein, the titanium dioxide is rutile type titanium white or anatase thpe white powder, institute
The particle size range for stating titanium dioxide is 190nm~300nm, and the oil factor of the titanium dioxide is less than 25g.
The white marks ink of the present invention, wherein, described first controls flocculant to be rosin resin, the auxiliary control wadding
Solidifying agent is alkyl phosphate or aliphatic alcohol polyoxyvinethene phosphate, and the monoesters ratio of the auxiliary control flocculant is more than
70%.
The white marks ink of the present invention, wherein, the alcohol-soluble resin is polyvinyl butyral resin, aldehyde ketone resin, aldehyde
Resin, alcohol contain intermingle with urethane, alcohol and contain intermingle with amide resin, gum dammar or the molten acrylic resin of alcohol one kind therein.
The white marks ink of the present invention, wherein, the lower alcohol is the mixed of ethanol or normal propyl alcohol or ethanol and normal propyl alcohol
Compound.
The present invention white marks ink, wherein, the high boiling solvent be phenmethylol or Phenoxyethanol or benzene oxygen propyl alcohol,
Medium-boiling solvent is propylene glycol monomethyl ether or dipropylene glycol methyl ether or 3- methoxy methyl propionates.
The manufacture method of the white marks ink of the present invention, the white marks ink for manufacturing the present invention, the control
Flocculant is added in ink while stirring after should being diluted by mixed solvent.
Technical scheme discloses a kind of using rolled core as storage medium, has fine attachment on a variety of surfaces
The white marks ink of fastness and covering power.The titanium dioxide nominal mean particle size that the present invention is used is 190nm~300nm, is passed through
Flocculation technique is controlled, makes the size controlling of titanium dioxide floccule body at 5~10 μm, the titanium dioxide floccule body has good flowing
Property, permeability and resistance to settling, so as to which conventional fiber nib and Asia makes every effort to overcome written extraction on the market at present, form pen
Head ink is not stratified, writes convenient high covering power mark ink.
The present invention white marks ink titanium dioxide be high specific gravity Chinese white titanium dioxide, be rutile type titanium white or
Anatase thpe white powder, particle size range is 190nm~300nm, and oil factor is less than 25g.
Titanium dioxide has a wide range of applications as best Chinese white is had now been found that in terms of writing material.Titanium dioxide
Proportion is very high, and nib is out of ink rapid when viscosity is low, but titanium dioxide under gravity can be in written rapid subsidence, and nib is down
When, written lower area titanium dioxide enrichment, written upper area titanium dioxide is rare, occurs that so-called one side is deep when writing again
Shallow negative and positive phenomenon on one side.
By adding thickener, such as polyamide wax, Tissuemat E, rilanit special, bentonite, aerosil,
The anti-settling performance improvement of titanium dioxide, but because high viscosity causes ink flow and permeability drastically to decline, ink is difficult to lead to
Cross capillarity and reach nib, thus marking pen loses writing use value.
Technical scheme improves control flocculation technique, and rosin resin is the first control flocculant, with alkyl phosphorus
Flocculant aid supplemented by acid esters or aliphatic alcohol polyethenoxy phosphate, makes the titanium white powder particles that initial size is 190nm~300nm wad a quilt with cotton
It is titanium dioxide floccule body that apparent particle diameter is 5~10 μm to coagulate.The floccule body relative density is greatly reduced compared with titanium dioxide, while in pen
Head has good resistance to settling energy, and has excellent mobility, permeability.Control the percentage by weight of flocculant for 0.5~
1%.
The titanium dioxide that the present invention is used is Du Pont R706 or Australia Ke Meiji CR-828,834 or Sha Haliben RDI-S or henry
This graceful TR81,92.
The resin of the present invention is alcohol-soluble resin, its main function be scattered suspension titanium dioxide there is provided ink flow,
Film forming skeleton and the adhesive force on writing base material.The resin of the present invention can be low viscosity polyvinyl butyral resin, aldehyde
Ketone resin, urea formaldehyde, low viscosity alcohol contain intermingle with urethane, low viscosity alcohol and contain intermingle with amide resin, gum dammar, the molten acrylic acid of low viscosity alcohol
Resin etc..The percentage by weight of resin is 8~15%.
To increase the mobility of ink, the present invention also added substrate wetting agents, and substrate wetting agents are U.S.'s aerochemistry
465 or 485, the percentage by weight of substrate wetting agents is 0.1~0.5%.
In order to increase the performance of raising one's hat of ink, technical scheme also added additive of raising one's hat.
The solvent of technical scheme is the mixture of lower alcohol, medium-boiling solvent and high boiling solvent.This hair
The solvent of bright technical scheme is molten by the mid-boiling point of the high boiling solvent of percentage by weight 1~5%, percentage by weight 10~25
The lower alcohol composition of agent and surplus.
The specific embodiment contrast form of technical scheme is as follows, and the content of material in embodiment is weight hundred
Divide in ratio, bracket for supply of material producer.
Embodiment contrast one
Embodiment contrast two
Embodiment contrast test method：
1. ink system pen, is utilized respectively examples detailed above one, example two, comparison example one, the ink of comparison example two and makes
Marking pen, the parts of marking pen include ink storage rolled core, high porosity fiber nib, acrylic nib and plastic casing,
Ink storage rolled core ink ink reservoir volume is 4g；
2. base material is write, black or dark woven bag or polybag；
3. method of testing, under room temperature situation respectively by the nib of above-mentioned four kinds of marking pens upward, written level, written court
It is lower to place one month, then write in above-mentioned writing substrate surface, the change of observation stitching and covering power.
Test result shows：
Instant ability out of ink, four kinds of marking pens are all out of question, and stitching is all very full, and feel is smooth；
Attachment fastness：Example one and example two are substantially more more advantageous than comparison example one, comparison example two；
The marking pen of example one and the marking pen of example two, nib upward, level, down afterwards writing color keep substantially not
Become, and the marking pen head of the marking pen of comparison example one, comparison example two is write after light such as water, written horizontal positioned afterwards upward
There is typical negative and positive phenomenon, and rear color burn is many down for nib, not smooth withered phenomenon out of ink occurs.
The ink that can be seen that technical scheme from above-mentioned test result have good mobility, permeability and
Resistance to settling, writes convenient and high covering power.Rosin, phosphate is added to can be very good to improve antisolvent precipitation of the titanium dioxide in nib
Performance.
Described above is only the preferred embodiment of the present invention, it is noted that for the ordinary skill people of the art
For member, under the premise without departing from the principles of the invention, some improvements and modifications can also be made, these improvements and modifications also should
It is considered as protection scope of the present invention.
Claims (8)
1. a kind of white marks ink, it is characterised in that including：
Titanium dioxide, percentage by weight is 20~35%；
Control flocculant, including the first control flocculant and auxiliary control flocculant, the weight percent of the first control flocculant
Than for 5~15%, auxiliary control the percentage by weight of flocculant for the first weight percent content for controlling flocculant 10~
15%；
Alcohol-soluble resin, percentage by weight is 8~15%；
Substrate wetting agents, percentage by weight is 0.1~0.5%；
Raise one's hat and prevent withered agent, percentage by weight is 0.1~0.5%；
Solvent.
2. white marks ink as claimed in claim 1, it is characterised in that the solvent is the height boiling of percentage by weight 1~5%
The mixture of the lower alcohol composition of point solvent, the medium-boiling solvent of percentage by weight 10~25% and surplus.
3. white marks ink as claimed in claim 1, it is characterised in that the titanium dioxide is rutile type titanium white or sharp
Titanium-type titanium dioxide, the particle size range of the titanium dioxide is 190nm~300nm, and the oil factor of the titanium dioxide is less than 25g.
4. white marks ink as claimed in claim 1, it is characterised in that described first controls flocculant to be rosin resin,
The auxiliary controls flocculant to be alkyl phosphate or aliphatic alcohol polyoxyvinethene phosphate, and the auxiliary controls the list of flocculant
Ester ratio is more than 70%.
5. white marks ink as claimed in claim 1, it is characterised in that the alcohol-soluble resin is polyvinyl alcohol contracting fourth
Aldehyde, aldehyde ketone resin, urea formaldehyde, alcohol contain intermingle with urethane, alcohol and contain intermingle with amide resin, gum dammar or the molten acrylic resin of alcohol therein one
Kind.
6. white marks ink as claimed in claim 2, it is characterised in that the lower alcohol is ethanol or normal propyl alcohol or ethanol
With the mixture of normal propyl alcohol.
7. white marks ink as claimed in claim 2, it is characterised in that the high boiling solvent is phenmethylol or benzene oxygen second
Alcohol or benzene oxygen propyl alcohol, the medium-boiling solvent are propylene glycol monomethyl ether or dipropylene glycol methyl ether or 3- methoxy methyl propionates.
8. a kind of manufacture method of white marks ink, for manufacturing the white marks ink as described in claim any one of 1-7
Water, it is characterised in that the control flocculant by mixed solvent dilute after add while stirring in ink.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710421267.1A CN107011736A (en) | 2017-06-07 | 2017-06-07 | White marks ink and its manufacture method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710421267.1A CN107011736A (en) | 2017-06-07 | 2017-06-07 | White marks ink and its manufacture method |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107011736A true CN107011736A (en) | 2017-08-04 |
Family
ID=59452265
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710421267.1A Pending CN107011736A (en) | 2017-06-07 | 2017-06-07 | White marks ink and its manufacture method |
Country Status (1)
| Country | Link |
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| CN (1) | CN107011736A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108774428A (en) * | 2018-06-13 | 2018-11-09 | 上海纳诺微新材料科技有限公司 | Marking pen, mark composition for ink and preparation method thereof |
| CN109836887A (en) * | 2019-02-26 | 2019-06-04 | 上海晨光文具股份有限公司 | A kind of strong adhesion mark ink, preparation method and strong adhesion marking pen |
| CN111117353A (en) * | 2019-12-26 | 2020-05-08 | 苏州雄鹰笔墨新材料有限公司 | Low-volatility pigment type marking ink |
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| 李孟，张倩: "《给水处理原理》", 31 December 2013, 武汉理工大学出版社 * |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN108774428A (en) * | 2018-06-13 | 2018-11-09 | 上海纳诺微新材料科技有限公司 | Marking pen, mark composition for ink and preparation method thereof |
| CN109836887A (en) * | 2019-02-26 | 2019-06-04 | 上海晨光文具股份有限公司 | A kind of strong adhesion mark ink, preparation method and strong adhesion marking pen |
| CN111117353A (en) * | 2019-12-26 | 2020-05-08 | 苏州雄鹰笔墨新材料有限公司 | Low-volatility pigment type marking ink |
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