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CN106833752A - The house refuse of three-stage technique cooperates with pyrolysis gasifying device and method with high-alkali coal - Google Patents

The house refuse of three-stage technique cooperates with pyrolysis gasifying device and method with high-alkali coal Download PDF

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CN106833752A
CN106833752A CN201710056568.9A CN201710056568A CN106833752A CN 106833752 A CN106833752 A CN 106833752A CN 201710056568 A CN201710056568 A CN 201710056568A CN 106833752 A CN106833752 A CN 106833752A
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pyrolysis
coal
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gas
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CN106833752B (en
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黄群星
胡斌航
池涌
严建华
李晓东
蒋旭光
马增益
王飞
陆胜勇
金余其
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Zhejiang University ZJU
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    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/58Production of combustible gases containing carbon monoxide from solid carbonaceous fuels combined with pre-distillation of the fuel
    • C10J3/60Processes
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/58Production of combustible gases containing carbon monoxide from solid carbonaceous fuels combined with pre-distillation of the fuel
    • C10J3/60Processes
    • C10J3/64Processes with decomposition of the distillation products
    • C10J3/66Processes with decomposition of the distillation products by introducing them into the gasification zone
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/72Other features
    • C10J3/82Gas withdrawal means
    • C10J3/84Gas withdrawal means with means for removing dust or tar from the gas
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00Details of gasification processes
    • C10J2300/09Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0913Carbonaceous raw material
    • C10J2300/093Coal
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00Details of gasification processes
    • C10J2300/09Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0913Carbonaceous raw material
    • C10J2300/0946Waste, e.g. MSW, tires, glass, tar sand, peat, paper, lignite, oil shale
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00Details of gasification processes
    • C10J2300/16Integration of gasification processes with another plant or parts within the plant
    • C10J2300/1603Integration of gasification processes with another plant or parts within the plant with gas treatment
    • C10J2300/1606Combustion processes

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Processing Of Solid Wastes (AREA)
  • Gasification And Melting Of Waste (AREA)

Abstract

本发明公开了一种三段式工艺的生活垃圾与高碱煤协同热解气化装置及方法。热解室、燃烧室和气化室依次连接而构成三段式生活垃圾与高碱煤协同热解处理环境,给料系统连接到热解室入口,热解室和气化室的灰渣回收口均设有灰渣收集装置,气化室经储气装置与热解室连接相通;生活垃圾物料由螺旋给料机输送入热解室,在往复式炉排上干燥并进行热解析出和挥发,挥发的热解气和焦油进入燃烧室,燃烧室在足量空气下完全燃烧,高碱煤进入气化室中心区域和燃烧生成的烟气接触反应,获得干净气化气并进入储气装置。本发明能够有效改善传统生活垃圾气化炉产生的合成气中含有大量焦油和氯化氢的问题,极大地提高了气化气的品质,有利于气化气的进一步利用。The invention discloses a three-stage process domestic garbage and high-alkali coal synergistic pyrolysis gasification device and method. The pyrolysis chamber, the combustion chamber and the gasification chamber are connected in sequence to form a three-stage synergistic pyrolysis treatment environment for domestic waste and high-alkali coal. There is an ash collection device, and the gasification chamber is connected to the pyrolysis chamber through the gas storage device; the domestic waste materials are transported into the pyrolysis chamber by the screw feeder, dried on the reciprocating grate, and thermally desorbed and volatilized. The volatilized pyrolysis gas and tar enter the combustion chamber, and the combustion chamber is completely combusted under sufficient air. The high-alkaline coal enters the central area of the gasification chamber and reacts with the flue gas generated by combustion to obtain clean gasification gas and enter the gas storage device. The invention can effectively improve the problem that a large amount of tar and hydrogen chloride are contained in the synthesis gas produced by the traditional domestic garbage gasification furnace, greatly improve the quality of the gasification gas, and is beneficial to the further utilization of the gasification gas.

Description

三段式工艺的生活垃圾与高碱煤协同热解气化装置及方法Cooperative pyrolysis gasification device and method for domestic waste and high-alkali coal in three-stage process

技术领域technical field

本发明涉及了一种生活垃圾处理装置和方法,尤其是涉及了一种三段式工艺的生活垃圾与高碱煤协同热解气化装置及方法。The invention relates to a domestic garbage treatment device and method, in particular to a three-stage process domestic garbage and high-alkali coal synergistic pyrolysis gasification device and method.

发明背景Background of the invention

垃圾处理是世界性难题,大量垃圾不仅占用了庞大宝贵的土地资源,而且对生态环境和人体健康产生了巨大的威胁。同时生活垃圾是一种“放错了地方的资源”,具有极大的开发价值,可以变废为宝。我国拥有巨大的城市生活垃圾资源,每年就有1.5亿吨左右的排放量,相当于2500万吨左右标煤,能源化处理利用率不足10%,能源化利用潜力较大。因此,对生活垃圾的无害化、资源化处理已经成为了当今废弃物处置的研究热点。在众多垃圾处置技术中,热处置技术因其在垃圾减量化和资源化方面的巨大优势而备受关注。其中,气化技术是指垃圾在较高的温度和一定压力下,与气化剂介质(如空气、水蒸气、二氧化碳等)发生部分氧化还原反应,生成含CO,CH4,H2的混合气的过程,气化气方便运输与存储,使得垃圾的利用价值得到了很大的提升。同时气化产气不仅可以用于燃烧发电、供热,也可以作为化工行业的原料,多途径、综合利用价值相对于焚烧等的热处理技术更高。气化过程发生的主要反应是:Garbage disposal is a worldwide problem. A large amount of garbage not only occupies huge and valuable land resources, but also poses a huge threat to the ecological environment and human health. At the same time, domestic garbage is a kind of "misplaced resources", which has great development value and can turn waste into treasure. my country has huge resources of municipal solid waste, with an annual discharge of about 150 million tons, which is equivalent to about 25 million tons of standard coal. The utilization rate of energy treatment is less than 10%, and the potential for energy utilization is relatively large. Therefore, the harmless and resourceful treatment of domestic waste has become a research hotspot in waste disposal today. Among many waste disposal technologies, heat treatment technology has attracted much attention because of its great advantages in waste reduction and resource utilization. Among them, the gasification technology refers to the partial redox reaction of garbage with the gasification agent medium (such as air, water vapor , carbon dioxide , etc.) at a relatively high temperature and a certain pressure to generate a mixed The process of gasification, gasification gas is convenient for transportation and storage, which greatly improves the utilization value of garbage. At the same time, gasification gas can not only be used for combustion power generation and heat supply, but also can be used as a raw material in the chemical industry. The multi-channel and comprehensive utilization value is higher than that of incineration and other heat treatment technologies. The main reactions that occur during gasification are:

C+CO2=2CO△H=+408kJ/molC+CO 2 =2CO△H=+408kJ/mol

2H2+O2=2H2O△H=+484kJ/mol2H 2 +O 2 =2H 2 O△H=+484kJ/mol

CH4+2O2=CO2+2H2O△H=+892kJ/molCH 4 +2O 2 =CO 2 +2H 2 O△H=+892kJ/mol

2CO+O2=2CO2△H=+566kJ/mol2CO+O 2 =2CO 2 △H=+566kJ/mol

CO2+O2=2CO△H=-162kJ/molCO 2 +O 2 =2CO△H=-162kJ/mol

H2O+C=CO+H2△H=-199kJ/molH 2 O+C=CO+H 2 △H=-199kJ/mol

CO+H2O=CO2+H2△H=-44kJ/molCO+H 2 O=CO 2 +H 2 △H=-44kJ/mol

但现有的单段式垃圾气化技术存在三个主要的问题,一个是产气热值低,目前国内采用固定床气化技术生产的气体热值在3-7MJ/m3左右,和煤、天然气等相比还有很大差距。如果将可燃气用作发电用则需要储存大量气体维持机组运行,这样就增加了投资和运行的成本;第二个是焦油问题严重,焦油容易和灰分、水粘结成块堵塞管道,对金属材质的设备和塑料管道有很强的腐蚀作用,焦油含量高就降低了气化效率和气体热值,在造成设备损害的同时又降低了经济性;第三个是垃圾成分相当复杂,相对于煤等传统能源来说,含有大量以PVC类高氯树脂为主要有机氯源的塑料和部分以NaCl为主要无机氯源的无机盐,因此在垃圾气化过程中,除了硫、氮氧化物之外,上述氯源还会导致污染物排放中含有大量HCl,氯化氢的排放会直接导致酸雨的形成,对水生生态系统造成破坏,而且氯化氢气体对气化炉的气化设备本体也有着很强的腐蚀作用,将会大大缩短气化炉的使用寿命,氯化氢还是生活垃圾气化过程中二噁英生成的来源,在生活垃圾高温气化中会产生一定量的飞灰,飞灰上含有大分子碳、不完全燃烧的碳粒和催化物质(主要是过渡态金属),这些物质会和烟气中的氯化氢经过气化、氯化以及缩合反应生成二噁英,其具有较强的半挥发性和持久性,对生物体造成不可逆的畸形,癌症和突变,对环境造成严重污染。However, there are three main problems in the existing single-stage garbage gasification technology. One is the low calorific value of the gas produced. , natural gas, etc., there is still a big gap. If combustible gas is used for power generation, it is necessary to store a large amount of gas to maintain the operation of the unit, which increases the cost of investment and operation; the second is that the problem of tar is serious, and tar is easy to bond with ash and water to block the pipeline and damage the metal. Equipment made of materials and plastic pipes have a strong corrosive effect, and high tar content reduces gasification efficiency and gas calorific value, causing equipment damage and reducing economic efficiency; the third is that the garbage composition is quite complex, compared to For traditional energy such as coal, it contains a large amount of plastics with PVC high-chlorine resin as the main source of organic chlorine and some inorganic salts with NaCl as the main source of inorganic chlorine. Therefore, in the process of garbage gasification, in addition to sulfur and nitrogen oxides In addition, the above-mentioned chlorine sources will also cause a large amount of HCl in the pollutant discharge, and the discharge of hydrogen chloride will directly lead to the formation of acid rain, causing damage to aquatic ecosystems, and hydrogen chloride gas also has a strong impact on the gasification equipment body of the gasifier. Corrosion will greatly shorten the service life of the gasifier. Hydrogen chloride is also the source of dioxins in the gasification process of domestic waste. A certain amount of fly ash will be produced in the high-temperature gasification of domestic waste. The fly ash contains macromolecules Carbon, incompletely burned carbon particles and catalytic substances (mainly transition state metals), these substances will react with hydrogen chloride in the flue gas to generate dioxins through gasification, chlorination and condensation reactions, which have strong semi-volatility and persistence, causing irreversible deformities to organisms, cancer and mutations, causing serious pollution to the environment.

发明内容Contents of the invention

为了解决上述生活垃圾单段式气化中会出现一系列问题,本发明提出了一种三段式工艺的生活垃圾与高碱煤协同热解气化装置及方法,以获得高热值,焦油、二噁英、氯化氢含量低的气化气。In order to solve a series of problems in the above-mentioned single-stage gasification of domestic waste, the present invention proposes a three-stage process of domestic waste and high-alkali coal synergistic pyrolysis gasification device and method to obtain high calorific value, tar, Gasification gas with low content of dioxin and hydrogen chloride.

本发明采用的技术方案是:The technical scheme adopted in the present invention is:

一、一种三段式工艺的生活垃圾与高碱煤协同热解气化装置:1. A three-stage process domestic waste and high-alkali coal synergistic pyrolysis gasification device:

装置包括热解室、燃烧室和气化室以及给料系统、灰渣收集装置和储气装置,热解室、燃烧室和气化室依次连接而构成三段式生活垃圾与高碱煤协同热解处理环境,热解室作为第一段,燃烧室作为第二段,气化室作为第三段;给料系统连接到热解室入口,热解室和气化室的灰渣回收口均设有灰渣收集装置,气化室经储气装置与热解室连接相通。The device includes a pyrolysis chamber, combustion chamber and gasification chamber as well as a feeding system, ash collection device and gas storage device. The pyrolysis chamber, combustion chamber and gasification chamber are connected in sequence to form a three-stage synergistic pyrolysis of domestic waste and high-alkali coal. Treatment environment, the pyrolysis chamber as the first stage, the combustion chamber as the second stage, and the gasification chamber as the third stage; the feeding system is connected to the inlet of the pyrolysis chamber, and the ash recovery ports of the pyrolysis chamber and gasification chamber are equipped with The ash collection device, the gasification chamber communicates with the pyrolysis chamber through the gas storage device.

所述的给料系统包括进料口、螺旋给料机和驱动电机,进料口设置在热解室入口侧,螺旋给料机安装于热解室前墙并位于进料口下方,驱动电机与螺旋给料机连接,驱动电机驱动螺旋给料机运行,从进料口置入的生活垃圾经螺旋给料机输送入热解室。The feeding system includes a feed inlet, a screw feeder and a drive motor, the feed inlet is arranged on the inlet side of the pyrolysis chamber, the screw feeder is installed on the front wall of the pyrolysis chamber and is located below the feed inlet, and the drive motor Connected with the screw feeder, the drive motor drives the screw feeder to run, and the domestic garbage placed from the feed port is transported into the pyrolysis chamber through the screw feeder.

所述的热解室内设置有往复式炉排、用于燃烧释放热量的燃烧器和炉排液压驱动装置,往复式炉排入口侧作为热解室的入口,往复式炉排出口侧上端与燃烧室连接相通,并在往复式炉排出口侧下端为出渣口,出渣口下方设置灰渣收集装置,往复式炉排连接炉排液压驱动装置,由炉排液压驱动装置驱动往复式炉排的炉排片进行往复运动;燃烧器位于往复式炉排上方,往复式炉排下方的热解室设有与储气装置出口连接相通的一次风口。The pyrolysis chamber is provided with a reciprocating grate, a burner for burning and releasing heat, and a grate hydraulic drive device. The chambers are connected, and the lower end of the reciprocating grate outlet side is a slag outlet, and an ash collecting device is installed under the slag outlet. The reciprocating grate is connected to the grate hydraulic drive device, and the reciprocating grate is driven by the grate hydraulic drive device. The grate pieces reciprocate; the burner is located above the reciprocating grate, and the pyrolysis chamber below the reciprocating grate is provided with a primary tuyere connected to the outlet of the gas storage device.

所述的燃烧室包括送风机和二次送风口,燃烧室呈倒“U”型结构,倒“U”型位于其中间段的入口侧设有二次送风口,送风机连接到二次送风口送入空气。The combustion chamber includes a blower and a secondary air supply port. The combustion chamber has an inverted "U"-shaped structure. The inverted "U" shape is located at the entrance side of its middle section and is provided with a secondary air supply port. The blower is connected to the secondary air supply port to deliver into the air.

所述的气化室包括煤分配器、储煤仓、旋转炉篦、合成气出口和储灰仓,气化室的底部设有旋转炉篦和储灰仓,旋转炉篦位于储灰仓上方,气化室的顶部安装有储煤仓和煤分配器,煤分配器位于储煤仓下方,高碱煤放置在储煤仓中,气化室的顶部侧壁设有与储气装置入口连接相通的合成气出口。The gasification chamber includes a coal distributor, a coal storage bin, a rotary grate, a synthesis gas outlet and an ash storage bin. The bottom of the gasification chamber is provided with a rotary grate and an ash storage bin, and the rotary grate is located above the ash storage bin. , the top of the gasification chamber is equipped with a coal storage bunker and a coal distributor, the coal distributor is located under the coal storage bunker, the high-alkali coal is placed in the coal storage bunker, and the top side wall of the gasification chamber is provided with a connection with the inlet of the gas storage device. Connected syngas outlet.

所述的储气装置包括储气罐、分压配气管路和减压阀,储气罐入口和气化室的合成气出口连接相通,储气罐经减压阀和分压配气管路连接,分压配气管路和所述热解室的一次风口连接相通。The gas storage device includes a gas storage tank, a pressure-dividing gas distribution pipeline and a pressure reducing valve. The inlet of the gas storage tank is connected to the synthesis gas outlet of the gasification chamber. The partial pressure gas distribution pipeline is connected to the primary air outlet of the pyrolysis chamber.

通过三段式生活垃圾与高碱煤的协同热解气化装置中第二段燃烧室的设计可以燃烧掉大部分生活垃圾热解产生的焦油,而且高碱煤中的碱金属氧化物和碱土金属氧化物都是一种效果较好的焦油催化裂解催化剂。在高温条件下可以催化裂解在第二段未完全燃烧的焦油,因此可以得到较为干净并且高热值的气化气。Through the design of the second-stage combustion chamber in the three-stage synergistic pyrolysis gasification device of domestic waste and high-alkali coal, most of the tar produced by the pyrolysis of domestic waste can be burned, and the alkali metal oxides and alkaline earth in the high-alkaline coal Metal oxides are good catalysts for tar catalytic cracking. Under high temperature conditions, the tar that is not completely burned in the second stage can be catalytically cracked, so a relatively clean gasification gas with high calorific value can be obtained.

二、一种三段式工艺的生活垃圾与高碱煤协同热解气化方法:2. A method of synergistic pyrolysis and gasification of domestic waste and high-alkali coal in a three-stage process:

1)从进料口置入的生活垃圾物料,驱动电机驱动螺旋给料机运行,生活垃圾物料由螺旋给料机输送入热解室;1) Household waste materials are put in from the feed port, the drive motor drives the screw feeder to run, and the house waste materials are transported into the pyrolysis chamber by the screw feeder;

2)输送入热解室的生活垃圾物料均匀地落在往复式炉排上,由炉排液压驱动装置驱动进行炉排片的往复运动,通过燃烧器燃烧加热,生活垃圾原料在往复式炉排上干燥并进行热解析出和挥发,挥发的热解气和焦油进入燃烧室,热解析出的残渣从出渣口排出到灰渣收集装置中;2) The domestic waste materials transported into the pyrolysis chamber fall evenly on the reciprocating grate, driven by the grate hydraulic drive device to reciprocate the grate pieces, and burn and heat through the burner, and the domestic waste raw materials are placed on the reciprocating grate Drying and pyrolysis and volatilization, the volatilized pyrolysis gas and tar enter the combustion chamber, and the pyrolysis residue is discharged from the slag outlet to the ash collection device;

3)从热解室输送来的热解气和焦油进入燃烧室,在送风机送入足量空气下进行完全燃烧,然后进入气化室;3) The pyrolysis gas and tar transported from the pyrolysis chamber enter the combustion chamber, and are completely combusted under the sufficient air supplied by the blower, and then enter the gasification chamber;

4)块状的高碱煤从气化室顶端进入,并通过气化室中心区域和燃烧室燃烧生成的烟气接触相发生反应,获得干净气化气;4) Blocky high-alkali coal enters from the top of the gasification chamber, and reacts with the flue gas generated by combustion in the central area of the gasification chamber to obtain clean gasification gas;

5)从气化室输出的干净气化气进入储气装置。5) The clean gasification gas output from the gasification chamber enters the gas storage device.

所述的储气装置的一部分气化气通过减压阀调节经由分压配气管路进行分配,经一次风口输送至热解室内,在热解室的燃烧器的启炉点火作用下完全燃烧释放出生活垃圾在热解室内热解所需的热量,用以提供生活垃圾原料在热解室的热解过程中需要的热量,另外一部分气化气输送至外部的气化气净化系统。Part of the gasification gas in the gas storage device is adjusted by the pressure reducing valve and distributed through the partial pressure gas distribution pipeline, transported to the pyrolysis chamber through the primary tuyere, and completely burned and released under the action of the burner in the pyrolysis chamber. The heat required for the pyrolysis of domestic waste in the pyrolysis chamber is used to provide the heat required for the pyrolysis process of domestic waste raw materials in the pyrolysis chamber, and the other part of the gasification gas is sent to the external gasification gas purification system.

所述步骤4)具体为:Described step 4) specifically is:

4.1)块状的高碱煤从气化室顶端通过闸斗进入储煤仓,再沿着气化炉向下移动至卸料斗落入煤分配器,煤分配器通过旋转驱动将块状高碱煤均匀分散开后并推动高碱煤落入气化室内;4.1) The lumpy high-alkali coal enters the coal storage bunker through the gate bucket from the top of the gasification chamber, and then moves down the gasifier to the unloading hopper and falls into the coal distributor. The coal distributor drives the lumpy high-alkali coal After the coal is evenly dispersed, the high-alkali coal is pushed into the gasification chamber;

4.2)高碱煤依次经气化室中心区域的干燥区、热解区、还原区和氧化区后落到旋转炉篦上,并在旋转炉篦上方形成堆高;4.2) The high-alkaline coal falls on the rotary grate after passing through the drying zone, pyrolysis zone, reduction zone and oxidation zone in the central area of the gasification chamber in sequence, and forms a pile height above the rotary grate;

4.3)燃烧室燃烧生成的烟气作为气化室的气化剂,从气化室底端进入到旋转炉篦下方,烟气向上流动并与块状高碱煤下落方向相反,使得块状高碱煤在下落过程中被向上流动的烟气烘干;4.3) The flue gas generated by combustion in the combustion chamber is used as the gasification agent of the gasification chamber, and enters below the rotary grate from the bottom of the gasification chamber. The soda coal is dried by the flue gas flowing upward during the falling process;

4.4)经过干燥区和热解区形成的煤焦在还原区高温条件下与作为气化剂的烟气发生气化反应后产生的干净气化气,干净气化气从合成气出口排出;气化反应未完全的煤焦接着在氧化区燃烧产生炉灰,炉灰经旋转炉篦落入储灰仓中,最后落入到灰渣收集装置。4.4) The coal coke formed in the drying zone and the pyrolysis zone undergoes a gasification reaction with flue gas as a gasification agent under high temperature conditions in the reduction zone to produce clean gasification gas, and the clean gasification gas is discharged from the synthesis gas outlet; The incomplete coal coke is then burned in the oxidation zone to produce ash, which falls into the ash storage bin through the rotating grate, and finally falls into the ash collection device.

本发明采用富含碱金属氧化物(主要是Na2O和K2O)和碱土金属氧化物(主要是CaO,Ca(OH)2和CaCO3)的高碱煤,高碱煤作为钙基吸收剂是一种高效的酸性气体吸收剂,对烟气中的氯化氢气体吸附效率可达95%以上,其在吸附过程中发生的主要反应是:The present invention uses high-alkali coal rich in alkali metal oxides (mainly Na 2 O and K 2 O) and alkaline earth metal oxides (mainly CaO, Ca(OH) 2 and CaCO 3 ), and the high-alkali coal is used as the calcium-based The absorbent is a high-efficiency acid gas absorbent, and the adsorption efficiency of hydrogen chloride gas in the flue gas can reach more than 95%. The main reaction that occurs during the adsorption process is:

CaCO3+HCl→CaCl2+H2O+CO2 CaCO 3 +HCl→CaCl 2 +H 2 O+CO 2

CaO+2HCl→CaCl2+H2OCaO+2HCl→ CaCl2 + H2O

CaCO3→CaO+CO2 CaCO 3 →CaO+CO 2

Ca(OH)2+HCl→CaCl2+H2OCa(OH) 2 +HCl→CaCl 2 +H 2 O

Ca(OH)2→CaO+H2OCa(OH) 2 →CaO+H 2 O

因此通过本发明三段式生活垃圾与高碱煤的协同热解气化能够有效改善传统单段式生活垃圾气化炉出来的合成气中含有大量氯化氢气体的缺陷,同时抑制了控制了氯源的供给,从而减少了烟气中的二噁英含量。Therefore, the synergistic pyrolysis gasification of the three-stage domestic waste and high-alkali coal of the present invention can effectively improve the defect that the synthesis gas from the traditional single-stage domestic waste gasifier contains a large amount of hydrogen chloride gas, and at the same time suppress and control the source of chlorine supply, thereby reducing the dioxin content in the flue gas.

从合成气出口排出的所述干净气化气组成为:H2 40%,CO 35%,CH4 10%,N210%,CO2 5%,温度在500~600℃范围内。The composition of the clean gasification gas discharged from the synthesis gas outlet is: H 2 40%, CO 35%, CH 4 10%, N 2 10%, CO 2 5%, and the temperature is in the range of 500-600°C.

生活垃圾中含有大量的无机氯和有机氯,其在气化过程中大部分都转化成了HCl,因此传统生活垃圾气化会导致气化气中含有大量氯化氢气体,从而限制合成气的进一步利用,而通过本发明方法利用高碱煤中富含碱土金属氧化物(主要是氧化碳,氢氧化钙,碳酸钙)的特点,它们是一种极佳的氯化氢吸附材料,小试结果表明高碱煤焦的碱土金属氧化物吸附效率可达95%以上,因此可以有效改善传统单段式生活垃圾气化炉出来的合成气中含有大量氯化氢气体的缺陷。同时,氯化氢是生活垃圾气化中二噁英生成的其中一种来源,其作为氯源的提供,会在气化过程中与飞灰中的大分子碳颗粒,不完全燃烧的碳粒和催化物质(主要是过渡态金属)发生氯化以及缩合反应生成二噁英。因此高碱煤焦将烟气中的氯化氢气体吸附生成稳定的氯化钙,可以有效减少烟气中二噁英的含量。Domestic waste contains a large amount of inorganic chlorine and organic chlorine, most of which are converted into HCl during the gasification process. Therefore, traditional domestic waste gasification will lead to a large amount of hydrogen chloride gas in the gasification gas, thereby limiting the further utilization of syngas , and utilize the characteristics that are rich in alkaline earth metal oxides (mainly carbon dioxide, calcium hydroxide, calcium carbonate) in the high-alkali coal by the inventive method, they are a kind of excellent hydrogen chloride adsorption material, and small test result shows that high-alkali The alkaline earth metal oxide adsorption efficiency of coal char can reach more than 95%, so it can effectively improve the defect that the synthesis gas from the traditional single-stage domestic waste gasifier contains a large amount of hydrogen chloride gas. At the same time, hydrogen chloride is one of the sources of dioxin generation in the gasification of domestic waste. As a source of chlorine, it will interact with macromolecular carbon particles in fly ash, incompletely burned carbon particles and catalysts during the gasification process. Substances (mainly transition metals) undergo chlorination and condensation reactions to form dioxins. Therefore, high-alkali coal char can absorb hydrogen chloride gas in flue gas to generate stable calcium chloride, which can effectively reduce the content of dioxin in flue gas.

生活垃圾气化过程中还会出现大量焦油,从而影响气化气品质,而通过三段式生活垃圾与高碱煤协同热解气化的工艺方法,生活垃圾原料在第一段热解过程中产生的焦油可以在第二段燃烧室得到充分燃烧,而放置在第三段气化室内的高碱煤富含碱金属氧化物(主要是Na2O和K2O)和碱土金属氧化物(主要是GaO和MgO),其是一种高效的焦油裂解催化剂,因此在第二段燃烧室未得到完全燃烧的焦油也可以在第三段气化室内在碱金属和碱土金属氧化物的催化作用下被催化裂解成轻质烃。A large amount of tar will also appear during the gasification process of domestic waste, which will affect the quality of gasification gas. Through the three-stage synergistic pyrolysis and gasification process of domestic waste and high-alkali coal, the raw materials of domestic waste will be The tar produced can be fully burned in the second-stage combustion chamber, while the high-alkali coal placed in the third-stage gasification chamber is rich in alkali metal oxides (mainly Na 2 O and K 2 O) and alkaline earth metal oxides ( Mainly GaO and MgO), which is an efficient tar cracking catalyst, so the tar that has not been completely burned in the second-stage combustion chamber can also be catalyzed by alkali metal and alkaline-earth metal oxides in the third-stage gasification chamber Under catalytic cracking into light hydrocarbons.

现有的生活垃圾气化技术还存在产气热值低的问题,目前国内采用固定床气化技术生产的合成气热值在3-7MJ/Nm3左右,和天然气的35.91MJ/Nm3相比还有很大差距。而通过三段式生活垃圾与高碱煤协同热解气化的工艺方法,由于设置了第二段燃烧室,并且增大了其流程,可以将生活垃圾在第一段热解产生的挥发分转化为气化剂稳定均匀地输送至第三段气化室,而在上吸式气化炉中富含碱金属和碱土金属氧化物的高碱煤焦可以有效吸附生活垃圾原料中无机氯和有机氯热转化形成的HCl,并且催化裂解第二段燃烧室未燃烧完全的焦油,从而可以有效改善气化设备的腐蚀问题,并且可以得到较为干净的合成气,极大地提高了气化气的热值。本发明通过实施试验表明采用三段式生活垃圾与高碱煤协同热解气化工艺可以使气化气的热值基本稳定在13.13-15.92MJ/Nm3The existing domestic waste gasification technology still has the problem of low calorific value of gas produced. At present, the calorific value of synthesis gas produced by fixed bed gasification technology in China is about 3-7MJ/Nm 3 , which is comparable to the 35.91MJ/Nm 3 of natural gas. There is still a big gap. However, through the three-stage synergistic pyrolysis and gasification process of domestic waste and high-alkali coal, since the second-stage combustion chamber is installed and its process is enlarged, the volatile matter produced by the first-stage pyrolysis of domestic waste can be It is converted into a gasification agent and transported to the third stage gasification chamber stably and evenly. In the updraft gasification furnace, the high-alkaline coal char rich in alkali metal and alkaline earth metal oxides can effectively absorb inorganic chlorine and The HCl formed by the thermal conversion of organic chlorine, and the catalytic cracking of the unburned tar in the second-stage combustion chamber can effectively improve the corrosion problem of the gasification equipment, and can obtain relatively clean syngas, which greatly improves the efficiency of the gasification gas. calorific value. The present invention proves that the calorific value of the gasification gas can be basically stabilized at 13.13-15.92MJ/Nm3 by adopting the three -stage synergistic pyrolysis gasification process of domestic garbage and high-alkali coal.

本发明具有如下技术特点:The present invention has the following technical characteristics:

本发明处理过程中,生活垃圾在第一段热解过程中产生的焦油会在第二段燃烧室完全燃烧,第二段未燃烧完全的焦油通过第三段富含碱金属氧化物和碱土金属氧化物的煤焦可以得到高效率的催化裂解。During the treatment process of the present invention, the tar produced in the first stage of pyrolysis of domestic waste will be completely burned in the second stage of the combustion chamber, and the unburned tar in the second stage will pass through the third stage rich in alkali metal oxides and alkaline earth metals. Oxides of coal char can be cracked with high efficiency catalytic cracking.

生活垃圾中含有大量无机氯和有机氯,本发明处理过程绝大多数的氯在第一段热解过程中转化成了HCl,而且在第二段的燃烧工况下也无法分解,但可以通过放置在第三段气化段富含碱土金属氧化物CaO的煤焦吸附作用下,去除95%以上的HCl,从而得到纯净的气化气。Household garbage contains a large amount of inorganic chlorine and organic chlorine. Most of the chlorine in the treatment process of the present invention is converted into HCl in the first stage of pyrolysis process, and it cannot be decomposed under the combustion conditions of the second stage, but can be passed through Placed in the third gasification section under the adsorption of coal char rich in alkaline earth metal oxide CaO, more than 95% of HCl is removed, thereby obtaining pure gasification gas.

本发明在第三段采用放置准东煤,准东煤是一种富含碱金属的高碱煤,而碱金属的碳酸盐、氧化物、氢氧化物和氯化物可以极大提高煤焦的反应活性,催化经第二段完全燃烧后的气体与第三段煤焦的气化反应。The present invention adopts placing Zhundong coal in the third section, Zhundong coal is a kind of high-alkali coal rich in alkali metals, and carbonates, oxides, hydroxides and chlorides of alkali metals can greatly improve the coal char The reactivity of the catalyst catalyzes the gasification reaction between the gas after the second stage of complete combustion and the third stage of coal char.

综合来说,本发明能够有效改善传统生活垃圾气化炉产生的合成气中含有大量焦油和氯化氢的问题,极大地提高了气化气的品质,有利于气化气的进一步利用。In summary, the present invention can effectively improve the problem of a large amount of tar and hydrogen chloride contained in the synthesis gas produced by the traditional domestic waste gasification furnace, greatly improve the quality of the gasification gas, and facilitate the further utilization of the gasification gas.

附图说明Description of drawings

图1为本发明装置的结构示意图。Fig. 1 is a structural schematic diagram of the device of the present invention.

图中:给料系统1,热解室2,燃烧室3,气化室4,灰渣收集装置5,储气装置6,进料口7、螺旋给料机8,驱动电机9,往复式炉排10,出渣口11,燃烧器12,一次风口13,炉排液压驱动装置14,送风机15,二次送风口16,煤分配器17储煤仓18,旋转炉篦19,合成气出口20,储灰仓21,储气罐22,分压配气管路23,减压阀24。In the figure: feeding system 1, pyrolysis chamber 2, combustion chamber 3, gasification chamber 4, ash collection device 5, gas storage device 6, feed inlet 7, screw feeder 8, drive motor 9, reciprocating Fire grate 10, slag outlet 11, burner 12, primary tuyere 13, grate hydraulic drive 14, blower 15, secondary air supply 16, coal distributor 17 coal storage bin 18, rotary grate 19, synthesis gas outlet 20, ash storage bin 21, gas storage tank 22, partial pressure gas distribution pipeline 23, pressure reducing valve 24.

具体实施方式detailed description

下面结合附图和实施例对本发明作进一步说明。The present invention will be further described below in conjunction with drawings and embodiments.

如图1所示,本发明的具体实施是包括热解室2、燃烧室3和气化室4以及给料系统1、灰渣收集装置5和储气装置6,热解室2、燃烧室3和气化室4依次连接而构成三段式生活垃圾与高碱煤协同热解处理环境,热解室2作为第一段,燃烧室3作为第二段,气化室4作为第三段;给料系统1连接到热解室2入口,热解室2和气化室4的灰渣回收口均设有灰渣收集装置5,气化室4经储气装置6与热解室2连接相通。As shown in Figure 1, the concrete implementation of the present invention is to comprise pyrolysis chamber 2, combustion chamber 3 and gasification chamber 4 and feeding system 1, ash collecting device 5 and gas storage device 6, pyrolysis chamber 2, combustion chamber 3 It is sequentially connected with the gasification chamber 4 to form a three-stage synergistic pyrolysis treatment environment for domestic waste and high-alkali coal. The pyrolysis chamber 2 is used as the first stage, the combustion chamber 3 is used as the second stage, and the gasification chamber 4 is used as the third stage; The material system 1 is connected to the entrance of the pyrolysis chamber 2, and the ash recovery ports of the pyrolysis chamber 2 and the gasification chamber 4 are provided with an ash collection device 5, and the gasification chamber 4 is connected to the pyrolysis chamber 2 through a gas storage device 6.

给料系统1主要由进料口7、螺旋给料机8和驱动电机9组成。进料口7安装于热解室2的前侧,便于进料,螺旋给料机8安装于热解室2前墙和进料口7下方,并且与进料口7紧密连接,从而保证生活垃圾物料能够稳定均匀地输送至第一段热解室2内进行干燥以及挥发分析出阶段。The feeding system 1 is mainly composed of a feeding port 7 , a screw feeder 8 and a driving motor 9 . The feed inlet 7 is installed on the front side of the pyrolysis chamber 2, which is convenient for feeding. The screw feeder 8 is installed on the front wall of the pyrolysis chamber 2 and below the feed inlet 7, and is closely connected with the feed inlet 7, thereby ensuring life Garbage materials can be stably and evenly transported to the first pyrolysis chamber 2 for drying and volatile analysis.

热解室2主要由往复式炉排10,出渣口11,燃烧器12,一次风口13和炉排液压驱动装置14构成,由螺旋给料机8输送至热解室2的生活垃圾物料均匀地落在往复式炉排10上,并由采用液压驱动的炉排液压驱动装置14驱动进行炉排片的往复运动,第三段气化室4出来的一部分气化气通过安装在往复式炉排10下方的一次风口13送入热解室2内,并在燃烧器12的启炉点火作用下完全燃烧释放出生活垃圾热解所需的热量。由此,生活垃圾原料在往复式炉排10上方干燥,并完全热解析出的挥发分进入第二段燃烧室3内,出渣口11位于热解室2后墙末端,生物垃圾原料经第一段完全热解后的残渣通过该出渣口11排出。从而保证生活垃圾原料第一段热解过程的连续稳定运行。The pyrolysis chamber 2 is mainly composed of a reciprocating fire grate 10, a slag outlet 11, a burner 12, a primary tuyere 13 and a fire grate hydraulic drive device 14. The ground falls on the reciprocating grate 10, and is driven by the hydraulically driven grate hydraulic drive device 14 to reciprocate the grate pieces. A part of the gasification gas from the third gasification chamber 4 passes through the reciprocating grate The primary tuyeres 13 below the 10 are sent into the pyrolysis chamber 2, and completely burnt under the action of the burner 12 to start and ignite to release the heat required for the pyrolysis of domestic waste. Thus, the domestic waste raw material is dried above the reciprocating fire grate 10, and the volatile matter that is completely pyrolyzed enters the second-stage combustion chamber 3. The slag outlet 11 is located at the end of the rear wall of the pyrolysis chamber 2. The residue after a period of complete pyrolysis is discharged through the slag outlet 11 . In this way, the continuous and stable operation of the first-stage pyrolysis process of domestic waste raw materials is ensured.

燃烧室3主要由送风机15和二次送风口16构成,燃烧室3总体呈倒“U”型分布,从而增大了烟道流程,送风机15布置在燃烧室3前墙一侧,由管道连接至安装于燃烧室3前墙的二次送风口16,送风机15通过二次送风口16给燃烧室3送入足量空气,使得由第一段热解室2出来的热解气和焦油到第二段燃烧室3能够基本完全燃烧。The combustion chamber 3 is mainly composed of a blower 15 and a secondary air supply port 16. The combustion chamber 3 is generally distributed in an inverted "U" shape, thereby increasing the flow of the flue. The blower 15 is arranged on the side of the front wall of the combustion chamber 3 and connected by pipes. To the secondary air supply port 16 installed on the front wall of the combustion chamber 3, the air blower 15 sends sufficient air to the combustion chamber 3 through the secondary air supply port 16, so that the pyrolysis gas and tar coming out of the first stage pyrolysis chamber 2 arrive at the The combustion chamber 3 of the second stage can burn substantially completely.

气化室4主要由煤分配器17储煤仓18,旋转炉篦19,合成气出口20和储灰仓21组成。气化室4主要采用的是一套上吸式气化炉,块状的高碱煤储放置储煤仓18中,储煤仓18则安装在气化室4的顶部,一定大小的高碱煤块通过闸斗进入储煤仓18沿着气化炉向下移动至卸料斗落入煤分配器17,煤分配器17安装于储煤仓18下方,通过旋转驱动使得块状高碱煤均匀分散开后,落入气化炉内的块状高碱煤依次经过干燥区,热解区,还原区和氧化区,被旋转炉篦19支撑,在旋转炉篦19上方形成一定的堆高,旋转炉篦19安装在气化炉下方,经第二段燃烧室燃烧生成的烟气主要成分是CO2和水蒸气,以及少量的氧气作为第三段气化室4的气化剂从旋转炉篦19下方进入,与块状高碱煤流动方向相反,块状高碱煤在下落过程中被向上流动的烟气烘干。经过干燥区和热解区形成的高碱煤焦在还原区高温条件下与气化剂发生一系列气化反应后产生的干净气化气从合成气出口20排出,合成气出口20安装在煤分配器17一侧气化炉墙上,排出的气化气组成基本为:H2 40%,CO 35%,CH4 10%,N2 10%,CO2 5%,温度大概在500~600℃范围内。通过气化区的未气化完全的煤焦在氧化区燃烧产生的炉灰,经旋转炉篦19落入灰闸排至安装在气化炉底部的储灰仓21。从而保证了第三段气化室4的连续稳定运行。The gasification chamber 4 is mainly composed of a coal distributor 17, a coal storage bin 18, a rotary grate 19, a synthesis gas outlet 20 and an ash storage bin 21. The gasification chamber 4 mainly adopts a set of updraft gasification furnace. The massive high-alkali coal storage is placed in the coal storage bin 18, and the coal storage bin 18 is installed on the top of the gasification chamber 4. A certain size of high-alkali coal The coal block enters the coal storage bunker 18 through the lock bucket and moves down along the gasifier to the unloading hopper and falls into the coal distributor 17. The coal distributor 17 is installed under the coal storage bin 18, and the lumpy high-alkali coal is evenly distributed through the rotation drive. After being dispersed, the massive high-alkali coal falling into the gasifier passes through the drying zone, pyrolysis zone, reduction zone and oxidation zone in sequence, and is supported by the rotary grate 19, forming a certain pile height above the rotary grate 19, The rotary grate 19 is installed under the gasification furnace, and the main components of the flue gas generated by combustion in the second-stage combustion chamber are CO 2 and water vapor, and a small amount of oxygen is used as the gasification agent in the third-stage gasification chamber 4 from the rotary furnace. Enter below the grate 19, opposite to the flow direction of the blocky high-alkali coal, the blocky high-alkali coal is dried by the flue gas flowing upwards during the falling process. The high-alkaline coal coke formed in the drying zone and the pyrolysis zone undergoes a series of gasification reactions with the gasification agent under high temperature conditions in the reduction zone, and the clean gasification gas produced is discharged from the synthesis gas outlet 20. The synthesis gas outlet 20 is installed at the coal On the wall of the gasifier on the side of the distributor 17, the composition of the discharged gasification gas is basically: H 2 40%, CO 35%, CH 4 10%, N 2 10%, CO 2 5%, and the temperature is about 500-600 ℃ range. The ash produced by the combustion of incompletely gasified char that passes through the gasification zone in the oxidation zone falls through the rotating grate 19 into the ash gate to the ash storage bin 21 installed at the bottom of the gasifier. Therefore, the continuous and stable operation of the gasification chamber 4 in the third stage is ensured.

储气装置6主要由储气罐22,分压配气管路23和减压阀24构成,储气罐22与第三段气化室4内的合成气出口20相连,储存第三段上吸式气化炉出来的干净合成气,其中有一部分合成气通过减压阀24的调节从分压配气管路23输送至第一段热解室2内,提供生活垃圾原料在第一段热解过程中需要的热量。另外一部分则直接输送至气化气净化系统,从而保证了整个三段式系统的循环稳定运行。The gas storage device 6 is mainly composed of a gas storage tank 22, a pressure-dividing gas distribution pipeline 23 and a pressure reducing valve 24. The gas storage tank 22 is connected with the synthesis gas outlet 20 in the third-stage gasification chamber 4, and stores the third-stage upper suction The clean syngas from the type gasifier, part of which is transported from the partial pressure gas distribution pipeline 23 to the first-stage pyrolysis chamber 2 through the regulation of the pressure-reducing valve 24, provides domestic waste raw materials for the first-stage pyrolysis heat required in the process. The other part is directly sent to the gasification gas purification system, thus ensuring the stable operation of the entire three-stage system.

由此可见,本发明采用三段式复合结构,生活垃圾由螺旋给料机输送至第一段热解室内的往复炉排上,其热解所需热量来源于第三段气化室出来的一部分合成气完全燃烧释放出来,完全热解后产生的挥发分通过第二段燃烧室内送风机的空气供给使得大部分的热解气和焦油都燃烧完全。第三段采用的上吸式气化炉下方炉篦上形成了块状高碱煤的一定堆高保证足够的气化停留时间,协同还原第二段的燃烧产物生成以H2和CO为主的气化气,同时利用高碱煤中富含碱金属和碱土金属的特点,可以有效地减少HCl在烟气排放中的含量,HCl去除效率达到95%以上,起到固定气化气中氯的作用,也切断了氯源的供给,所以可以有效减少烟气中二噁英的排放,同时高碱煤中的碱金属和碱土金属氧化物都是一种高效的焦油催化裂解催化剂,可以有效催化裂解在第二段燃烧室未完全燃尽的焦油。小试实验结果表明第三段气化室出来的气化气中焦油含量为73mg/m3,已经符合直接进入内燃机燃烧发电的进气标准(100mg/m3)。It can be seen that the present invention adopts a three-stage composite structure, and the domestic waste is transported to the reciprocating fire grate in the first stage pyrolysis chamber by the screw feeder, and the heat required for its pyrolysis comes from the gasification chamber in the third stage. A part of the syngas is completely combusted and released, and the volatile matter produced after complete pyrolysis is supplied by the air blower in the second-stage combustion chamber so that most of the pyrolysis gas and tar are completely combusted. The grate below the updraft gasifier used in the third stage forms a certain pile height of massive high-alkali coal to ensure sufficient gasification residence time, and the combustion products of the second stage of synergistic reduction are mainly H2 and CO At the same time, the high-alkaline coal is rich in alkali metals and alkaline earth metals, which can effectively reduce the content of HCl in the flue gas emission. The removal efficiency of HCl can reach more than 95%, and it can fix the chlorine in the gasification gas. It also cuts off the supply of chlorine sources, so it can effectively reduce the emission of dioxins in the flue gas. At the same time, the alkali metal and alkaline earth metal oxides in high-alkali coal are a kind of efficient tar catalytic cracking catalyst, which can effectively Catalytic cracking of tar that is not completely burned in the second stage combustion chamber. The results of the small test show that the tar content in the gasification gas from the third stage gasification chamber is 73mg/m 3 , which meets the intake standard (100mg/m 3 ) for direct combustion into the internal combustion engine for power generation.

Claims (10)

1. a kind of house refuse of three-stage technique cooperates with pyrolysis gasifying device with high-alkali coal, it is characterised in that:
Including pyrolysis chamber (2), combustion chamber (3) and vaporizer (4) and feeding system (1), ash collection device (5) and gas storage dress Put (6), pyrolysis chamber (2), combustion chamber (3) and vaporizer (4) are sequentially connected and constitute three-stage house refuse and cooperateed with high-alkali coal Pyrolysis processing environment, feeding system (1) is connected to pyrolysis chamber (2) entrance, the lime-ash recovery port of pyrolysis chamber (2) and vaporizer (4) Ash collection device (5) is equipped with, vaporizer (4) is connected with pyrolysis chamber (2) through caisson (6) and communicates.
2. a kind of house refuse of the three-stage technique according to claims 1 cooperates with pyrolysis gasifying device with high-alkali coal, It is characterized in that:Described feeding system (1) includes charging aperture (7), screw(-type) feeder (8) and motor (9), charging aperture (7) pyrolysis chamber (2) entrance side is arranged on, screw(-type) feeder (8) is installed on pyrolysis chamber's (2) front wall and is located at charging aperture (7) lower section, Motor (9) is connected with screw(-type) feeder (8), and motor (9) drives screw(-type) feeder (8) operation, is put from charging aperture (7) The house refuse for entering is conveyed into pyrolysis chamber (2) through screw(-type) feeder (8).
3. a kind of house refuse of the three-stage technique according to claims 1 cooperates with pyrolysis gasifying device with high-alkali coal, It is characterized in that:Reciprocating fire grate (10), the burner (12) for combustion heat release amount are provided with described pyrolysis chamber (2) With fire grate fluid pressure drive device (14), reciprocating fire grate (10) entrance side as pyrolysis chamber (2) entrance, reciprocating fire grate (10) Outlet side upper end is connected with combustion chamber (3) and communicates, and is slag notch (11), slag notch in reciprocating fire grate (10) outlet side lower end (11) lower section sets ash collection device (5), and reciprocating fire grate (10) connects fire grate fluid pressure drive device (14), by fire grate hydraulic pressure Drive device (14) drives the fire grate segment of reciprocating fire grate (10) to move back and forth;Burner (12) is positioned at reciprocating fire grate (10) top, the pyrolysis chamber (2) below reciprocating fire grate (10) is provided with the primary air nozzle for being connected with caisson (6) outlet and being communicated (13)。
4. a kind of house refuse of the three-stage technique according to claims 1 cooperates with pyrolysis gasifying device with high-alkali coal, It is characterized in that:Described combustion chamber (3) includes pressure fan (15) and secondary blast mouthful (16), and combustion chamber (3) are in inverse u shape knot Structure, the entrance side of section is provided with secondary blast mouthful (16) between inverse u shape is located therein, and pressure fan (15) is connected to secondary blast mouthful (16) air is sent into.
5. a kind of house refuse of the three-stage technique according to claims 1 cooperates with pyrolysis gasifying device with high-alkali coal, It is characterized in that:Described vaporizer (4) includes coal distributor (17), coal store (18), revolving grate (19), syngas outlet (20) and ash-storing bin (21), the bottom of vaporizer (4) is provided with revolving grate (19) and ash-storing bin (21), and revolving grate (19) is located at Ash-storing bin (21) top, is provided with coal store (18) and coal distributor (17) at the top of vaporizer (4), coal distributor (17) is located at Coal store (18) lower section, high-alkali coal is placed in coal store (18), and the top sidewall of vaporizer (4) is provided with and caisson (6) The syngas outlet (20) that entrance connection is communicated.
6. a kind of house refuse of the three-stage technique according to claims 1 cooperates with pyrolysis gasifying device with high-alkali coal, It is characterized in that:Described caisson (6) includes air accumulator (22), partial pressure distribution pipeline (23) and pressure-reducing valve (24), gas storage Syngas outlet (20) connection of tank (22) entrance and vaporizer (4) is communicated, and air accumulator (22) is matched somebody with somebody through pressure-reducing valve (24) and partial pressure Air pipe (23) is connected, and primary air nozzle (13) connection of partial pressure distribution pipeline (23) and the pyrolysis chamber (2) is communicated.
7. the house refuse for being applied to a kind of three-stage technique of any described devices of claims 1-6 cooperates with heat with high-alkali coal Solution gasification process, it is characterised in that comprise the following steps:
1) house refuse material is inserted from charging aperture (7), motor (9) drives screw(-type) feeder (8) operation, house refuse thing Material is conveyed into pyrolysis chamber (2) by screw(-type) feeder (8);
2) it is conveyed into the house refuse material of pyrolysis chamber (2) equably to fall on reciprocating fire grate (10), by fire grate hydraulic-driven Device (14) drives the reciprocating motion for carrying out fire grate segment, and by burner (12) combustion heating, house refuse raw material is reciprocating Dry and carry out Thermal desorption to go out and volatilize on fire grate (10), the pyrolysis gas and tar of volatilization enter combustion chamber (3), what pyrolysis was separated out Residue is discharged in ash collection device (5) from slag notch (11);
3) pyrolysis gas and tar for coming from pyrolysis chamber (2) conveying enter combustion chamber (3), under pressure fan (15) feeding enough air Burnt completely, the flue gas after burning enters vaporizer (4);
4) block high-alkali coal enters from vaporizer (4) top, and is generated by vaporizer (4) central area and combustion chambers burn Smoke contacts react, obtain clean gasification gas;
5) the clean gasification gas from vaporizer (4) output enters caisson (6).
8. a kind of house refuse of the three-stage technique according to claims 7 cooperates with pyrolysis gasification method with high-alkali coal, It is characterized in that:The part gasification gas of described caisson (6) is adjusted via partial pressure distribution pipeline by pressure-reducing valve (24) (23) it is allocated, is delivered in pyrolysis chamber (2) through primary air nozzle (13), the burner (12) in pyrolysis chamber (2) opens stove point Burning discharges house refuse in the heat needed for pyrolysis in pyrolysis chamber (2) completely under fire action, is used to provide house refuse original The heat that material needs in the pyrolytic process of pyrolysis chamber, another part gasification gas is delivered to the gasification gas cleaning system of outside.
9. a kind of house refuse of the three-stage technique according to claims 7 cooperates with pyrolysis gasification method with high-alkali coal, It is characterized in that:The step 4) it is specially:
4.1) block high-alkali coal enters coal store (18) from vaporizer (4) top by lock bucket, further along gasification furnace to moving down Move to dump skip and fall into coal distributor (17), coal distributor (17) by rotation driving by block high-alkali coal is dispersed open after simultaneously High-alkali coal is promoted to fall into vaporizer (4);
4.2) high-alkali coal falls rotation after the dry section of vaporizer (4) central area, pyrolysis zone, reducing zone and zoneofoxidation successively On fire grate (19), and it is high to form heap in revolving grate (19) top;
4.3) flue gas of combustion chambers burn generation enters into revolving burner as the gasifying agent of vaporizer (4) from vaporizer (4) bottom Comb below (19), flue gas is flowed up and opposite with block high-alkali coal falling direction so that block high-alkali coal is in dropping process The flue gas drying for being flowed up;
4.4) coal tar formed by dry section and pyrolysis zone occurs under the hot conditions of reducing zone with the flue gas as gasifying agent The clean gasification gas produced after gasification reaction, clean gasification gas is discharged from syngas outlet (20);The incomplete coal of gasification reaction It is burnt then to produce ashes, the rotated fire grate of ashes (19) to fall into ash-storing bin (21) in zoneofoxidation burning, finally drop into lime-ash Collection device (5).
10. a kind of house refuse of the three-stage technique according to claims 7 cooperates with pyrolysis gasification method with high-alkali coal, It is characterized in that:It is from the described clean gasification gas composition of syngas outlet (20) discharge:H240%, CO 35%, CH4 10%, N210%, CO25%, temperature is in the range of 500~600 DEG C.
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