CN106752818A - A kind of manufacture craft of nano ATO transparent heat-insulating energy-saving glass coating - Google Patents
A kind of manufacture craft of nano ATO transparent heat-insulating energy-saving glass coating Download PDFInfo
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- CN106752818A CN106752818A CN201611130929.1A CN201611130929A CN106752818A CN 106752818 A CN106752818 A CN 106752818A CN 201611130929 A CN201611130929 A CN 201611130929A CN 106752818 A CN106752818 A CN 106752818A
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- 239000011521 glass Substances 0.000 title claims abstract description 43
- 239000011248 coating agent Substances 0.000 title claims abstract description 22
- 238000000576 coating method Methods 0.000 title claims abstract description 22
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 15
- 239000011347 resin Substances 0.000 claims abstract description 26
- 229920005989 resin Polymers 0.000 claims abstract description 26
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 25
- 239000002245 particle Substances 0.000 claims abstract description 23
- 239000000843 powder Substances 0.000 claims abstract description 18
- 238000000034 method Methods 0.000 claims abstract description 8
- 230000008569 process Effects 0.000 claims abstract description 6
- 238000012545 processing Methods 0.000 claims abstract description 6
- 239000002994 raw material Substances 0.000 claims abstract description 6
- 238000002156 mixing Methods 0.000 claims description 25
- 238000003756 stirring Methods 0.000 claims description 18
- VDGJOQCBCPGFFD-UHFFFAOYSA-N oxygen(2-) silicon(4+) titanium(4+) Chemical compound [Si+4].[O-2].[O-2].[Ti+4] VDGJOQCBCPGFFD-UHFFFAOYSA-N 0.000 claims description 17
- 239000011856 silicon-based particle Substances 0.000 claims description 17
- 239000000243 solution Substances 0.000 claims description 15
- 239000011259 mixed solution Substances 0.000 claims description 10
- 239000002002 slurry Substances 0.000 claims description 10
- 239000004814 polyurethane Substances 0.000 claims description 5
- 238000005507 spraying Methods 0.000 claims description 5
- 229920002635 polyurethane Polymers 0.000 claims description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract description 10
- 239000002105 nanoparticle Substances 0.000 abstract description 9
- 238000005516 engineering process Methods 0.000 abstract description 5
- 239000000377 silicon dioxide Substances 0.000 abstract description 5
- 238000000227 grinding Methods 0.000 abstract description 4
- 238000002310 reflectometry Methods 0.000 abstract description 3
- 238000010792 warming Methods 0.000 abstract description 3
- 239000012752 auxiliary agent Substances 0.000 abstract description 2
- 239000003795 chemical substances by application Substances 0.000 abstract description 2
- 239000002270 dispersing agent Substances 0.000 abstract description 2
- 239000004038 photonic crystal Substances 0.000 abstract description 2
- 230000000694 effects Effects 0.000 description 6
- 238000009413 insulation Methods 0.000 description 5
- 239000008187 granular material Substances 0.000 description 3
- 235000012239 silicon dioxide Nutrition 0.000 description 3
- 239000011162 core material Substances 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 238000004134 energy conservation Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 230000008676 import Effects 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 230000036651 mood Effects 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000005315 stained glass Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 description 1
- 229910001887 tin oxide Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K7/00—Use of ingredients characterised by shape
- C08K7/22—Expanded, porous or hollow particles
- C08K7/24—Expanded, porous or hollow particles inorganic
- C08K7/26—Silicon- containing compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/004—Reflecting paints; Signal paints
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2231—Oxides; Hydroxides of metals of tin
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses a kind of manufacture craft of nano ATO transparent heat-insulating energy-saving glass coating, comprise the following steps：Raw material prepares：Melt water treatment, mixed processing, particle treatment and dried process；The present invention by ATO powders it is soluble in water after be directly added into water-base resin.Cumbersome grinding and dispersing technology is eliminated, without adding the auxiliary agents such as dispersant and grinding aid and anti-settling agent.ATO is disperseed in water-base resin with atom form, aligned orderly, nano-particle is spherical monodisperse nano-particle soilless sticking, and similarity is high, particle diameter distribution is narrow, and nano-particle has used nanometer grade silica to do template and has been made into the performance that mesoporous form is shielded as winter to outdoor cold emission in production.Nano-particle can be arranged in photonic crystal form after coating is dried, therefore have reflectivity very high to infrared ray, can be reduced than external temperature using rear indoor temperature summer, and winter is then more warming.
Description
Technical field
The present invention relates to glass coating technical field, specially a kind of system of nano ATO transparent heat-insulating energy-saving glass coating
Make technique.
Background technology
It is a undisputable fact that global warming temperature raises this, while also bringing life to energy-conserving and environment-protective industry.Now
The usable floor area of the either high buildings and large mansions or tier building glass hot spoke of increasing and indoor summer for domestic construction
Penetrate and mainly come from glass（More than 60% can be accounted for）, what winter indoor radiating was also mainly distributed by glass.Although now
Outdoor wall country has been carried out pressure and has been incubated but glass industry country there is not appearance policy also at present, reason be it is domestic for
The research of this product is also at the early-stage, will appreciate that the enterprise of core technology seldom, the core material that most of enterprise uses
Dependence on import, its is expensive, causes finished product selling at exorbitant prices to be difficult to promote.If now with a kind of effect good product and valency
Lattice are again moderate so to believe that country will soon put into effect the policy for forcing glass heat-insulating.The maximum benefit of heat insulation glass is section
Energy emission reduction, summer can be greatly reduced the air conditioner refrigerating number of starts, and winter reduces heat and distributed to outdoor, while can also stop purple
Outside line is to human body and the aged deterioration of indoor article.Ripe heat insulation glass has following several .1. double glazings in the market,
Although double glazing is in winter than single-glass heat insulation effect will well still it can not keep out the infrared ray of sun in summer transmitting, institute
Do not served in summer with double glazing.2. Louis glass, Louis glass is a kind of coated glass, its performance very well, no matter
It is that summer or winter heat insulation effect are all fine, but because production Louis glass investment is huge, technical difficulty is strong, therefore causes
Its is expensive to make ordinary people be difficult to receive.3. stained glass, this kind of current glass curtain wall of glass is main to rise using more
Privacies attractive in appearance are acted on and do not play function of heat insulation, while it is indoor dimmed also to stop that certain visible ray makes, while to outdoor
Look and always feel the cloudy day, the mood for giving people brings unhappy.4. adhering film to glass, real effective adhering film to glass price is held high
Expensive, instead bad pad pasting has the opposite effect, so that pasting hotter and hotter, this car owners should have impression.
ATO（Antimony-doped tin oxide）Color is dusty blue powder, resistance to organic with the fast light of the alkaline-resisting of the acidproof of chemical resistance
Not the features such as solvent does not aoxidize the fire-retardant corrosion-and high-temp-resistants good mechanical stabilities of.ATO nano-particles are to visible ray（380 nanometers-
780 nanometers）The absorbability of wave band is extremely weak, so there is high transparency.
Method used on the market is to be directly dispersing in alcohol-soluble or water solubility by common ATO powders are polished at present
In resin, its drawback be grain size distribution width patterns for unformed disperse in resin mixed and disorderly particle diameter arrange mix because
This can only play a part of INFRARED ABSORPTION, that is to say, that even if glass while ATO heat-barrier materials serve stop infrared ray action
Glass than room temperature increase 10-20 degree thus form natural radiator it is secondary to indoor radiations heat energy so to room temperature lowering
Effect be not very big.Therefore, proposing a kind of manufacture craft of nano ATO transparent heat-insulating energy-saving glass coating.
The content of the invention
It is an object of the invention to provide a kind of manufacture craft of nano ATO transparent heat-insulating energy-saving glass coating, to solve
The problem proposed in above-mentioned background technology.
To achieve the above object, the present invention provides following technical scheme：A kind of nano ATO transparent heat-insulating energy-saving glass coating
Manufacture craft, comprise the following steps：
S1, raw material prepare：Water-soluble ATO powders, water-base resin, meso-porous titanium dioxide silicon particle；
S2, melt water treatment：Water-soluble ATO powders is soluble in water, while being stirred, mixing speed 240-260r/min is stirred
Time 60-75min is mixed, 50-60 DEG C of whipping temp obtains ATO solution after the completion of stirring, wherein water solubility ATO powder accountings 45-
55%, balance of water；
S3, mixed processing：Water-base resin is added to obtained ATO solution in S2, while being stirred again, mixing speed 300-
350r/min, 55-65 DEG C of whipping temp, mixing time 45-55min is obtained mixed solution, wherein ATO solution after the completion of stirring
Accounting 30-45%, balance of water-base resin；
S4, particle treatment：Meso-porous titanium dioxide silicon particle is added in the mixed solution obtained after being processed to S3, while be stirred,
Mixing speed 200-250r/min, 55-65 DEG C of whipping temp, mixing time 100-120min is obtained particle slurry after the completion of stirring
Body, wherein meso-porous titanium dioxide silicon particle accounting are 65-75%；
S5, dried process：Particle slurry after being processed in S4 is uniformly sprayed on glass surface by spraying equipment, coating thickness is
0.5-1mm, is spontaneously dried at normal temperatures, after being dried to by glass surface formed film.
Preferably, the water-base resin is aqueous polyurethane.
Preferably, the mesoporous rate of meso-porous titanium dioxide silicon particle is 65-75%, particle diameter 12-15nm.
Drawn by experiment, glass is as follows using the performance data after the coating：Visible light transmissivity：70% （Light splitting light
Degree meter）, infrared reflectivity：60%-70% （Spectrophotometer）, heat-insulated rate：50%-60% （Infrared heat tester）, hardness：
3H（Pencil hardometer）, service life：10 years（Artificial ageing）, with the outdoor temperature difference in summer room：7-15 degree energy-conservations 20%-30%.
Compared with prior art, the beneficial effects of the invention are as follows：The present invention by ATO powders it is soluble in water after be directly added into water
In property resin.Cumbersome grinding and dispersing technology is eliminated, without adding the auxiliary agents such as dispersant and grinding aid and anti-settling agent.
ATO is disperseed in water-base resin with atom form, aligned orderly, and nano-particle is spherical monodisperse nano-particle soilless sticking, and similarity is high, grain
Footpath narrowly distributing, nano-particle has used nanometer grade silica to do template and has been made into mesoporous form as winter in production
To the performance of outdoor cold emission shielding.Nano-particle can be arranged in photonic crystal form after coating is dried, therefore be had to infrared ray
Reflectivity very high, can be reduced using rear indoor temperature summer than external temperature, and winter is then more warming.
Specific embodiment
Illustrating in below in conjunction with the embodiment of the present invention, is carried out clearly to the technical scheme in the embodiment of the present invention
Chu, it is fully described by, it is clear that described embodiment is only a part of embodiment of the invention, rather than whole embodiments.
Based on the embodiment in the present invention, it is all that those of ordinary skill in the art are obtained under the premise of creative work is not made
Other embodiment, belongs to the scope of protection of the invention.
Embodiment 1
A kind of manufacture craft of nano ATO transparent heat-insulating energy-saving glass coating, comprises the following steps：
S1, raw material prepare：Water-soluble ATO powders, water-base resin, meso-porous titanium dioxide silicon particle, the water-base resin is aqueous poly-
Urethane, the mesoporous rate of meso-porous titanium dioxide silicon particle is 65%, particle diameter 12nm；
S2, melt water treatment：Water-soluble ATO powders is soluble in water, while being stirred, mixing speed 240r/min, during stirring
Between 60min, 50 DEG C of whipping temp obtains ATO solution after the completion of stirring, wherein water solubility ATO powders accounting 45%, balance of water；
S3, mixed processing：Water-base resin is added to obtained ATO solution in S2, while being stirred again, mixing speed
300r/min, 55 DEG C of whipping temp, mixing time 45min is obtained mixed solution, wherein ATO solution accounting after the completion of stirring
30%, balance of water-base resin；
S4, particle treatment：Meso-porous titanium dioxide silicon particle is added in the mixed solution obtained after being processed to S3, while be stirred,
Mixing speed 200r/min, 55 DEG C of whipping temp, mixing time 100min is obtained particle slurry, its intermediary hole after the completion of stirring
Silicon dioxide granule accounting is 65%；
S5, dried process：Particle slurry after being processed in S4 is uniformly sprayed on glass surface by spraying equipment, coating thickness is
0.5mm, is spontaneously dried at normal temperatures, after being dried to by glass surface formed film.
Embodiment 2
A kind of manufacture craft of nano ATO transparent heat-insulating energy-saving glass coating, comprises the following steps：
S1, raw material prepare：Water-soluble ATO powders, water-base resin, meso-porous titanium dioxide silicon particle, the water-base resin is aqueous poly-
Urethane, the mesoporous rate of meso-porous titanium dioxide silicon particle is 75%, particle diameter 15nm；
S2, melt water treatment：Water-soluble ATO powders is soluble in water, while being stirred, mixing speed 260r/min, during stirring
Between 75min, 60 DEG C of whipping temp obtains ATO solution after the completion of stirring, wherein water solubility ATO powders accounting 55%, balance of water；
S3, mixed processing：Water-base resin is added to obtained ATO solution in S2, while being stirred again, mixing speed
350r/min, 65 DEG C of whipping temp, mixing time 55min is obtained mixed solution, wherein ATO solution accounting after the completion of stirring
45%, balance of water-base resin；
S4, particle treatment：Meso-porous titanium dioxide silicon particle is added in the mixed solution obtained after being processed to S3, while be stirred,
Mixing speed 250r/min, 65 DEG C of whipping temp, mixing time 120min is obtained particle slurry, its intermediary hole after the completion of stirring
Silicon dioxide granule accounting is 75%；
S5, dried process：Particle slurry after being processed in S4 is uniformly sprayed on glass surface by spraying equipment, coating thickness is
1mm, is spontaneously dried at normal temperatures, after being dried to by glass surface formed film.
Embodiment 3
A kind of manufacture craft of nano ATO transparent heat-insulating energy-saving glass coating, comprises the following steps：
S1, raw material prepare：Water-soluble ATO powders, water-base resin, meso-porous titanium dioxide silicon particle, the water-base resin is aqueous poly-
Urethane, the mesoporous rate of meso-porous titanium dioxide silicon particle is 67%, particle diameter 14nm；
S2, melt water treatment：Water-soluble ATO powders is soluble in water, while being stirred, mixing speed 245r/min, during stirring
Between 65min, 55 DEG C of whipping temp obtains ATO solution after the completion of stirring, wherein water solubility ATO powders accounting 46%, balance of water；
S3, mixed processing：Water-base resin is added to obtained ATO solution in S2, while being stirred again, mixing speed
312r/min, 56 DEG C of whipping temp, mixing time 47min is obtained mixed solution, wherein ATO solution accounting after the completion of stirring
35%, balance of water-base resin；
S4, particle treatment：Meso-porous titanium dioxide silicon particle is added in the mixed solution obtained after being processed to S3, while be stirred,
Mixing speed 222r/min, 56 DEG C of whipping temp, mixing time 110min is obtained particle slurry, its intermediary hole after the completion of stirring
Silicon dioxide granule accounting is 67%；
S5, dried process：Particle slurry after being processed in S4 is uniformly sprayed on glass surface by spraying equipment, coating thickness is
0.6mm, is spontaneously dried at normal temperatures, after being dried to by glass surface formed film.
Although an embodiment of the present invention has been shown and described, for the ordinary skill in the art, can be with
Understanding can carry out various changes, modification, replacement to these embodiments without departing from the principles and spirit of the present invention
And modification, the scope of the present invention be defined by the appended.
Claims (3)
1. a kind of manufacture craft of nano ATO transparent heat-insulating energy-saving glass coating, it is characterised in that：Comprise the following steps：
S1, raw material prepare：Water-soluble ATO powders, water-base resin, meso-porous titanium dioxide silicon particle；
S2, melt water treatment：Water-soluble ATO powders is soluble in water, while being stirred, mixing speed 240-260r/min is stirred
Time 60-75min is mixed, 50-60 DEG C of whipping temp obtains ATO solution after the completion of stirring, wherein water solubility ATO powder accountings 45-
55%, balance of water；
S3, mixed processing：Water-base resin is added to obtained ATO solution in S2, while being stirred again, mixing speed 300-
350r/min, 55-65 DEG C of whipping temp, mixing time 45-55min is obtained mixed solution, wherein ATO solution after the completion of stirring
Accounting 30-45%, balance of water-base resin；
S4, particle treatment：Meso-porous titanium dioxide silicon particle is added in the mixed solution obtained after being processed to S3, while be stirred,
Mixing speed 200-250r/min, 55-65 DEG C of whipping temp, mixing time 100-120min is obtained particle slurry after the completion of stirring
Body, wherein meso-porous titanium dioxide silicon particle accounting are 65-75%；
S5, dried process：Particle slurry after being processed in S4 is uniformly sprayed on glass surface by spraying equipment, coating thickness is
0.5-1mm, is spontaneously dried at normal temperatures, after being dried to by glass surface formed film.
2. a kind of manufacture craft of nano ATO transparent heat-insulating energy-saving glass coating according to claim 1, its feature exists
In：The water-base resin is aqueous polyurethane.
3. a kind of manufacture craft of nano ATO transparent heat-insulating energy-saving glass coating according to claim 1, its feature exists
In：The mesoporous rate of meso-porous titanium dioxide silicon particle is 65-75%, particle diameter 12-15nm.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611130929.1A CN106752818A (en) | 2016-12-09 | 2016-12-09 | A kind of manufacture craft of nano ATO transparent heat-insulating energy-saving glass coating |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611130929.1A CN106752818A (en) | 2016-12-09 | 2016-12-09 | A kind of manufacture craft of nano ATO transparent heat-insulating energy-saving glass coating |
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| Publication Number | Publication Date |
|---|---|
| CN106752818A true CN106752818A (en) | 2017-05-31 |
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| CN201611130929.1A Pending CN106752818A (en) | 2016-12-09 | 2016-12-09 | A kind of manufacture craft of nano ATO transparent heat-insulating energy-saving glass coating |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107267000A (en) * | 2017-06-23 | 2017-10-20 | 广州特种承压设备检测研究院 | A kind of nanometer heat isolation paint preparation method |
| WO2018103063A1 (en) * | 2016-12-09 | 2018-06-14 | 苏州蓝锐纳米科技有限公司 | Nano ato transparent thermal-insulation and energy-saving glass coating manufacturing process |
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| CN102911591A (en) * | 2011-08-04 | 2013-02-06 | 中国人民解放军装甲兵工程学院 | Transparent thermal insulation coating with nano porous auxiliary and preparation method thereof |
| CN103436127A (en) * | 2013-09-06 | 2013-12-11 | 深圳市文浩建材科技有限公司 | Transparent, hydrophobic and heat-insulating coating material for glass and preparation method thereof |
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| CN104230177A (en) * | 2013-06-18 | 2014-12-24 | 南京工业大学 | Preparation method of nano ATO aqueous slurry |
| JP2015034198A (en) * | 2013-08-07 | 2015-02-19 | 旭化成株式会社 | Heat insulating composition, heat-insulating member and heat-insulating coating film |
| CN104893604A (en) * | 2015-04-21 | 2015-09-09 | 浙江省能源与核技术应用研究院 | Transparent thermal-insulation window film |
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|---|---|---|---|---|
| CN101514083A (en) * | 2009-02-16 | 2009-08-26 | 陈楚伟 | Method for preparing low-emission thermal insulation film for laminated glass |
| CN102911591A (en) * | 2011-08-04 | 2013-02-06 | 中国人民解放军装甲兵工程学院 | Transparent thermal insulation coating with nano porous auxiliary and preparation method thereof |
| CN104230177A (en) * | 2013-06-18 | 2014-12-24 | 南京工业大学 | Preparation method of nano ATO aqueous slurry |
| JP2015034198A (en) * | 2013-08-07 | 2015-02-19 | 旭化成株式会社 | Heat insulating composition, heat-insulating member and heat-insulating coating film |
| CN103436127A (en) * | 2013-09-06 | 2013-12-11 | 深圳市文浩建材科技有限公司 | Transparent, hydrophobic and heat-insulating coating material for glass and preparation method thereof |
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| CN104151970B (en) * | 2014-08-15 | 2016-09-14 | 肇庆千江高新材料科技股份公司 | Hydrate colour transparent heat insulating dope and preparation method and using method |
| CN104893604A (en) * | 2015-04-21 | 2015-09-09 | 浙江省能源与核技术应用研究院 | Transparent thermal-insulation window film |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2018103063A1 (en) * | 2016-12-09 | 2018-06-14 | 苏州蓝锐纳米科技有限公司 | Nano ato transparent thermal-insulation and energy-saving glass coating manufacturing process |
| CN107267000A (en) * | 2017-06-23 | 2017-10-20 | 广州特种承压设备检测研究院 | A kind of nanometer heat isolation paint preparation method |
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