CN1067214C - Herbicide for paddy fields and its preparing method - Google Patents
Herbicide for paddy fields and its preparing method Download PDFInfo
- Publication number
- CN1067214C CN1067214C CN96102448A CN96102448A CN1067214C CN 1067214 C CN1067214 C CN 1067214C CN 96102448 A CN96102448 A CN 96102448A CN 96102448 A CN96102448 A CN 96102448A CN 1067214 C CN1067214 C CN 1067214C
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- CN
- China
- Prior art keywords
- weeding
- paddy
- emulsion
- mixture
- weeds
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
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- 239000004009 herbicide Substances 0.000 title claims abstract description 25
- 230000002363 herbicidal effect Effects 0.000 title abstract description 5
- 238000000034 method Methods 0.000 title abstract description 5
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims abstract description 19
- 239000004202 carbamide Substances 0.000 claims abstract description 19
- 239000000839 emulsion Substances 0.000 claims abstract description 19
- 150000001875 compounds Chemical class 0.000 claims abstract description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 12
- PMNFTMSSBYQNTK-UHFFFAOYSA-N [Na].CC1=C(OCC(=O)O)C=CC(=C1)Cl Chemical compound [Na].CC1=C(OCC(=O)O)C=CC(=C1)Cl PMNFTMSSBYQNTK-UHFFFAOYSA-N 0.000 claims description 10
- 239000003125 aqueous solvent Substances 0.000 claims description 7
- -1 chloro propionyl Chemical group 0.000 claims description 4
- 229920000767 polyaniline Polymers 0.000 claims description 4
- 238000002360 preparation method Methods 0.000 claims description 2
- 238000003756 stirring Methods 0.000 claims description 2
- FBGYNJKXMKWETB-UHFFFAOYSA-N 2-(4-chloro-3-methylphenoxy)acetic acid Chemical compound CC1=CC(OCC(O)=O)=CC=C1Cl FBGYNJKXMKWETB-UHFFFAOYSA-N 0.000 claims 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims 1
- 239000005574 MCPA Substances 0.000 claims 1
- WHKUVVPPKQRRBV-UHFFFAOYSA-N Trasan Chemical compound CC1=CC(Cl)=CC=C1OCC(O)=O WHKUVVPPKQRRBV-UHFFFAOYSA-N 0.000 claims 1
- 229910052708 sodium Inorganic materials 0.000 claims 1
- 239000011734 sodium Substances 0.000 claims 1
- 241000196324 Embryophyta Species 0.000 abstract description 24
- 235000007164 Oryza sativa Nutrition 0.000 abstract description 15
- 235000009566 rice Nutrition 0.000 abstract description 13
- 240000007594 Oryza sativa Species 0.000 abstract description 11
- 230000000694 effects Effects 0.000 abstract description 10
- 238000009333 weeding Methods 0.000 abstract description 10
- 239000000203 mixture Substances 0.000 abstract description 9
- 241000234646 Cyperaceae Species 0.000 abstract description 3
- 241000209094 Oryza Species 0.000 abstract 4
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 abstract 1
- 239000000654 additive Substances 0.000 abstract 1
- 230000000996 additive effect Effects 0.000 abstract 1
- 230000018109 developmental process Effects 0.000 abstract 1
- LFULEKSKNZEWOE-UHFFFAOYSA-N propanil Chemical compound CCC(=O)NC1=CC=C(Cl)C(Cl)=C1 LFULEKSKNZEWOE-UHFFFAOYSA-N 0.000 abstract 1
- 230000008929 regeneration Effects 0.000 abstract 1
- 238000011069 regeneration method Methods 0.000 abstract 1
- STAPBGVGYWCRTF-UHFFFAOYSA-M sodium;2-(4-chloro-2-methylphenoxy)acetate Chemical compound [Na+].CC1=CC(Cl)=CC=C1OCC([O-])=O STAPBGVGYWCRTF-UHFFFAOYSA-M 0.000 abstract 1
- DPDMMXDBJGCCQC-UHFFFAOYSA-N [Na].[Cl] Chemical class [Na].[Cl] DPDMMXDBJGCCQC-UHFFFAOYSA-N 0.000 description 9
- 239000012752 auxiliary agent Substances 0.000 description 9
- 239000003814 drug Substances 0.000 description 4
- 230000008029 eradication Effects 0.000 description 4
- 230000001586 eradicative effect Effects 0.000 description 4
- 244000025254 Cannabis sativa Species 0.000 description 3
- 230000000857 drug effect Effects 0.000 description 3
- DCKVNWZUADLDEH-UHFFFAOYSA-N sec-butyl acetate Chemical compound CCC(C)OC(C)=O DCKVNWZUADLDEH-UHFFFAOYSA-N 0.000 description 3
- YZHUMGUJCQRKBT-UHFFFAOYSA-M sodium chlorate Chemical class [Na+].[O-]Cl(=O)=O YZHUMGUJCQRKBT-UHFFFAOYSA-M 0.000 description 3
- 239000007921 spray Substances 0.000 description 3
- 238000005507 spraying Methods 0.000 description 3
- 235000013339 cereals Nutrition 0.000 description 2
- 239000012467 final product Substances 0.000 description 2
- 238000012856 packing Methods 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- UZGKAASZIMOAMU-UHFFFAOYSA-N 124177-85-1 Chemical compound NP(=O)=O UZGKAASZIMOAMU-UHFFFAOYSA-N 0.000 description 1
- 235000017166 Bambusa arundinacea Nutrition 0.000 description 1
- 235000017491 Bambusa tulda Nutrition 0.000 description 1
- 244000150195 Cyperus longus Species 0.000 description 1
- 235000018109 Cyperus longus Nutrition 0.000 description 1
- 241000254158 Lampyridae Species 0.000 description 1
- 241000169076 Monochoria korsakowii Species 0.000 description 1
- 240000002853 Nelumbo nucifera Species 0.000 description 1
- 235000006508 Nelumbo nucifera Nutrition 0.000 description 1
- 235000006510 Nelumbo pentapetala Nutrition 0.000 description 1
- 240000008881 Oenanthe javanica Species 0.000 description 1
- 235000000365 Oenanthe javanica Nutrition 0.000 description 1
- 240000000275 Persicaria hydropiper Species 0.000 description 1
- 235000017337 Persicaria hydropiper Nutrition 0.000 description 1
- 244000082204 Phyllostachys viridis Species 0.000 description 1
- 235000015334 Phyllostachys viridis Nutrition 0.000 description 1
- 235000013559 Schnittsellerie Nutrition 0.000 description 1
- 244000143231 Scirpus validus Species 0.000 description 1
- 235000008573 Scirpus validus Nutrition 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 239000011425 bamboo Substances 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 238000005538 encapsulation Methods 0.000 description 1
- 239000003337 fertilizer Substances 0.000 description 1
- 239000005556 hormone Substances 0.000 description 1
- 229940088597 hormone Drugs 0.000 description 1
- 230000032696 parturition Effects 0.000 description 1
- 230000035790 physiological processes and functions Effects 0.000 description 1
- 230000000284 resting effect Effects 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 235000014347 soups Nutrition 0.000 description 1
- 230000001018 virulence Effects 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The present invention relates to a weeding mixture for paddy rice fields, upland rice fields and other similar situations and a method for preparing the mixture. The weeding mixture is prepared in a way that a propanil emulsible solution is mixed with a saline solution of MCPA-sodium to obtain an emulsion, and urea as an additive is added to the emulsion to obtain a compound rice field herbicide product during application. The weeding mixture has good weeding effects on various weeds of rice fields, the weeding effects can be taken in three days, and the weeds die down after seven days and have no regeneration capacity. The weeding mixture has specially good effects on cyperaceae weeds and broad-leaved weeds; because of high security, the weeding mixture can not influence the growth, the development, the tiller and the ear bearing of the crops of paddy rice after being used in any period in any dosage; the present invention has the advantages of convenient use, flexibility, labor saving, money saving, economy and practicability.
Description
The present invention relates to a kind of mixture of water, dryland paddy and other similar applications weeding and the method for preparing it.
At present, be used for the goods of paddy field weeding, mainly contain i.e. 2 first, the 4 chlorine sodium salts of 2-methyl-4-chlorophenoxyacetic acid sodium, 2.4D butyl ester and careless jinx etc.2 first, 4 chlorine sodium salts are about in the of 80% to the eradicative rate of weeds in paddy field; 2.4D butyl ester, eradicative rate are about in the of 75%; And they all can not use in morning, the mid-term of weed growth, otherwise, can influence paddy rice growth, grow and tiller, do the later stage more and remedy usefulness.The grass jinx, eradicative rate is about in the of 65%, is suitable for the early stage sealing usefulness of doing, the intermediary and later stages are weak effect then, though but blade of grass can withered and yellow demutation soon.Consumption that the more important thing is them is difficult to grasp, in case the amount conference causes the paddy rice Miao Buchang that contracts, not earing of autumn; Consumption is little weeds are dead or wake up from death, and are serious even cause uncultivated or the underproduction; For this reason, the artificial weeding of often having to be aided with increases heavy manual labor, causes the manpower waste in man-hour.Integrate, the weak point of this several herbicides mainly is: eradicative rate is lower, can not dig up the roots substantially; Safety in utilization is poor.
The objective of the invention is to avoid weak point of the prior art, and good, safe in utilization, the reliable herbicides for use in paddy goods of a kind of property killed are provided and produce the method for this weed killer herbicide.
Can take following technical scheme to realize purpose.It is made mainly by containing 20%3, and the Stam F-34 missible oil of 4-two chloro propionyl polyaniline and 56% 2-methyl-4-chlorophenoxyacetic acid sodium, aqueous solvent are mixed into emulsion, during use, add the compound herbicides for use in paddy goods of urea auxiliary agent.
The best approach of preparation herbicides for use in paddy is:
1, produce mixed emulsion:
A, at 25 °～30 ℃, 2-methyl-4-chlorophenoxyacetic acid sodium is water-soluble, to fully dissolving.The consumption of common solvent water is 1.5～3 times of 2 first, 4 chlorine sodium salts, can dissolve fully, and what of solvent do not have influence to drug effect.Make the 2-methyl-4-chlorophenoxyacetic acid sodium water solution;
Under b, the uniform temp, Stam F-34 missible oil mixes with the 2-methyl-4-chlorophenoxyacetic acid sodium water solution, stirs, and makes mixed emulsion.
Packing mixed emulsion, standby.This emulsion resting period is grown, when layering occurring and having small amount of crystalline to separate out, gets final product with before rocking evenly, and drug effect is not had influence.
2, backup urea auxiliary agent is promptly pressed the Packing Unit of mixed emulsion, corresponding encapsulation aid, standby in addition.According to circumstances, the urea auxiliary agent also can be provided for oneself by the user, at this moment, should make clear and definite usage, consumption explanation in operation instructions.
Be described in further detail in conjunction with the content of embodiment the technical program.
In this herbicides for use in paddy, used various raw materials contain 20%3, the Stam F-34 missible oil of 4-two chloro propionyl polyaniline, and 56% 2-methyl-4-chlorophenoxyacetic acid sodium and urea (containing phosphoamide＞46%) all adopt commercial articles can satisfy performance requirement.Selectivity is tagged because this weed killer herbicide belongs to, hormone, mixed type medicament are conducted in interior suction, after spraying, it can suppress the growth of weeds, destroys the growing point of weeds, the leaf of plant, stem, root all can absorb, more obvious to the sub-plant performance of double leaf, after soup is transported to site of action, destroy the physiological function of plant, weeds are subjected to medicine after a few hours, promptly stop growing, stem chap, brittle failure after several days, general 3～7 days can obviously take effect; And medicament does not belong to a virulence difference together to gramineous plants, and the paddy rice body contains the aryl amide hydrolase, and this medicament is decomposed, and loses activity, so harmless to the rice standing grain.Cooperating urea in use mainly is to impel plant to absorb quickly, is decomposed quickly in the rice body, destroys growing point in weeds quickly, impels as early as possible to rot, can demutation; After urea also can be avoided spraying certain hour, by weathering, lose drug effect too quickly.Through repetition test, the consumption proportion of each raw material can take the circumstances into consideration, grasp flexibly in the herbicides for use in paddy, as long as it is 2 first, 4 chlorine sodium salts are water-soluble, be mixed into emulsion with Stam F-34 missible oil again, during use, add people's urea auxiliary agent, spray after converting water, weeds in paddy field all there is result of use preferably, though excessive one times of dose, to paddy rice safety too; This compound weed killer herbicide has better effects to the sedge family and the broad-leaf weeds of water, dryland paddy.
Note, urea can only be spraying before with addition of, as when converting water, adding mixed emulsion and urea.Ten million can not mix system, standby simultaneously with Stam F-34 missible oil, 2 first, 4 chlorine sodium-salt aqueous solutions, otherwise can decompose and lose effectiveness.
During use,, convert water 18Kg～25Kg, can spray one mu of rice field with this herbicides for use in paddy (contain and mix emulsion and urea) 0.4～0.5Kg.Converting the water yield can grasp flexibly, with guarantee evenly to spray in this area, topped getting final product.
In the herbicides for use in paddy, if their consumption, by weight:
20%3, the Stam F-34 missible oil 2～3 of 4-two chloro propionyl polyaniline
56% 2-methyl-4-chlorophenoxyacetic acid sodium 1
Aqueous solvent 1.5～3
Auxiliary agent urea 2.5～5 o'clock, its result of use is better.
Embodiment 1, herbicides for use in paddy, by weight:
Be mixed into emulsion by Stam F-34 missible oil 2.5 and 2 first, 4 chlorine sodium salts 1, aqueous solvent 1.5; During use, add urea auxiliary agent 5.Its weed eradication rate is 99%.
Embodiment 2, herbicides for use in paddy, by weight:
Be mixed into emulsion by Stam F-34 missible oil 2 and 2 first, 4 chlorine sodium salts 1, aqueous solvent 3; During use, add urea auxiliary agent 2.5.Its weed eradication rate is 93%.
Embodiment 3: herbicides for use in paddy, by weight:
Be mixed into emulsion by Stam F-34 missible oil 3 and 2 first, 4 chlorine sodium salts 1, aqueous solvent 1.5; During use, add urea auxiliary agent 4.Its weed eradication rate is 99%.
Embodiment 4: herbicides for use in paddy, by weight:
Be mixed into emulsion by Stam F-34 missible oil 2.25 and 2 first, 4 chlorine sodium salts 1, aqueous solvent 2; During use, add urea auxiliary agent 5.And interpolation 2.4D butyl ester 0.25.Its weed eradication rate is 99%.
The relative prior art of the technical program has following advantage and effect:
1, the property killed is good: water, upland rice various weeds live, that transplant the field are all had kill preferably effect Really, took effect in three days, withered after seven days, do not have the anti-ability of giving birth to; Cyperaceae and broad-leaf weeds are had special efficacy, As can making Herba Cyperi Glomerati, difformed galingale herb, Jing Sansuo, flat bar bamboo trunk grass, Scirpus tabernaemontani, firefly Lin and arrowhead class, Chinese celery, polygonum flaccidum, rhizoma alismatis, Monochoria korsakowii, wild lotus etc. once dig up the roots.
2, security is good: when phase dispenser in office, dose size, to the growth of rice crop, growth, Tiller, booting all do not have impact, can impel on the contrary that rice seedling is dark green to be sent out prosperous.
3, easy to use, flexible, save both labour and money, economical and practical, use at the weed growth animated period, Remarkably productive, concentrate, if use in advance, then can reduce weeds and the seedlings of cereal crops strive fertilizer; 0.07 hectare is only spent several Yuan just can solve big problem.
Claims (2)
1. compound herbicides for use in paddy is characterized in that: by weight, it is by containing 20%3, and 2-methyl-4-chlorophenoxyacetic acid sodium 1, the aqueous solvent 1.5～3 of the Stam F-34 missible oil 2～3,56% of 4-two chloro propionyl polyaniline are mixed into emulsion; During use, add the compound herbicides for use in paddy that people's urea is made again.
2, a kind of preparation method of compound herbicides for use in paddy as claimed in claim 1 is characterized in that,
(1), produce mixed emulsion:
A, at 25 °～30 ℃, 56%2-methyl-4-chlorophenoxyacetic acid sodium is water-soluble, to fully dissolving, makes the 2-methyl-4-chlorophenoxyacetic acid sodium water solution;
Under b, the uniform temp, 20% Stam F-34 missible oil mixes with the 2-methyl-4-chlorophenoxyacetic acid sodium water solution, stirs, and makes mixed emulsion;
(2), the backup urea, other packages spare;
(3), when using, the emulsion of (1) is mixed with urea, make compound herbicides for use in paddy.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN96102448A CN1067214C (en) | 1996-03-07 | 1996-03-07 | Herbicide for paddy fields and its preparing method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN96102448A CN1067214C (en) | 1996-03-07 | 1996-03-07 | Herbicide for paddy fields and its preparing method |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1140015A CN1140015A (en) | 1997-01-15 |
| CN1067214C true CN1067214C (en) | 2001-06-20 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN96102448A Expired - Fee Related CN1067214C (en) | 1996-03-07 | 1996-03-07 | Herbicide for paddy fields and its preparing method |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1067214C (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103027036B (en) * | 2013-01-16 | 2014-12-10 | 山东潍坊润丰化工股份有限公司 | Phytocidal composite containing methoxone salt and propanil and applications thereof |
| CN107006469A (en) * | 2017-04-25 | 2017-08-04 | 浙江中山化工集团股份有限公司 | A kind of herbicide composition for paddy fields |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN85106327A (en) * | 1985-08-10 | 1986-11-26 | 化学工业部沈阳化工研究院 | A new method for the synthesis of metalaxyl from methyl N-(2,6-xylyl)alanine |
| CN87100152A (en) * | 1986-01-10 | 1987-08-12 | Fmc有限公司 | The compound of weeding |
-
1996
- 1996-03-07 CN CN96102448A patent/CN1067214C/en not_active Expired - Fee Related
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN85106327A (en) * | 1985-08-10 | 1986-11-26 | 化学工业部沈阳化工研究院 | A new method for the synthesis of metalaxyl from methyl N-(2,6-xylyl)alanine |
| CN87100152A (en) * | 1986-01-10 | 1987-08-12 | Fmc有限公司 | The compound of weeding |
Non-Patent Citations (4)
| Title |
|---|
| 农用化学品 1995.1.1 化工出版社 * |
| 国外农药品种手册一 1980.1.1 化学工业产，农药情报中心站 * |
| 国外农药品种手册一 1980.1.1 化学工业产，农药情报中心站;农用化学品 1995.1.1 化工出版社;新编农药手册 1989.10.1 农业出版社 * |
| 新编农药手册 1989.10.1 农业出版社 * |
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| Publication number | Publication date |
|---|---|
| CN1140015A (en) | 1997-01-15 |
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