CN106691885A - Hair styling compositions comprising maltodextrin/NVP copolymer - Google Patents
Hair styling compositions comprising maltodextrin/NVP copolymer Download PDFInfo
- Publication number
- CN106691885A CN106691885A CN201510408869.4A CN201510408869A CN106691885A CN 106691885 A CN106691885 A CN 106691885A CN 201510408869 A CN201510408869 A CN 201510408869A CN 106691885 A CN106691885 A CN 106691885A
- Authority
- CN
- China
- Prior art keywords
- hair
- composition
- maltodextrin
- hair setting
- nvp
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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- 210000004209 hair Anatomy 0.000 title claims abstract description 101
- 239000000203 mixture Substances 0.000 title claims abstract description 100
- 229920001577 copolymer Polymers 0.000 title claims abstract description 38
- 239000005913 Maltodextrin Substances 0.000 title claims abstract description 28
- 229920002774 Maltodextrin Polymers 0.000 title claims abstract description 28
- 229940035034 maltodextrin Drugs 0.000 title claims abstract description 28
- 229920006317 cationic polymer Polymers 0.000 claims abstract description 11
- 238000000034 method Methods 0.000 claims abstract description 8
- 229920000642 polymer Polymers 0.000 claims description 19
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 14
- 239000003921 oil Substances 0.000 claims description 11
- 239000003795 chemical substances by application Substances 0.000 claims description 10
- 150000001875 compounds Chemical class 0.000 claims description 9
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- 238000002360 preparation method Methods 0.000 abstract description 6
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- 125000004432 carbon atom Chemical group C* 0.000 description 4
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- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 3
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- 239000008266 hair spray Substances 0.000 description 3
- 210000003128 head Anatomy 0.000 description 3
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- ULWHHBHJGPPBCO-UHFFFAOYSA-N propane-1,1-diol Chemical class CCC(O)O ULWHHBHJGPPBCO-UHFFFAOYSA-N 0.000 description 3
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- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Natural products CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 2
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- 229910019142 PO4 Inorganic materials 0.000 description 2
- OEYQBKYISMRWQB-UHFFFAOYSA-N Santal Chemical compound C=1C(OC)=CC(O)=C(C2=O)C=1OC=C2C1=CC=C(O)C(O)=C1 OEYQBKYISMRWQB-UHFFFAOYSA-N 0.000 description 2
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- POULHZVOKOAJMA-UHFFFAOYSA-M dodecanoate Chemical compound CCCCCCCCCCCC([O-])=O POULHZVOKOAJMA-UHFFFAOYSA-M 0.000 description 1
- PYBNTRWJKQJDRE-UHFFFAOYSA-L dodecanoate;tin(2+) Chemical compound [Sn+2].CCCCCCCCCCCC([O-])=O.CCCCCCCCCCCC([O-])=O PYBNTRWJKQJDRE-UHFFFAOYSA-L 0.000 description 1
- MOTZDAYCYVMXPC-UHFFFAOYSA-N dodecyl hydrogen sulfate Chemical compound CCCCCCCCCCCCOS(O)(=O)=O MOTZDAYCYVMXPC-UHFFFAOYSA-N 0.000 description 1
- 229940043264 dodecyl sulfate Drugs 0.000 description 1
- QVBODZPPYSSMEL-UHFFFAOYSA-N dodecyl sulfate;2-hydroxyethylazanium Chemical compound NCCO.CCCCCCCCCCCCOS(O)(=O)=O QVBODZPPYSSMEL-UHFFFAOYSA-N 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 239000000834 fixative Substances 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 1
- 208000010727 head pressing Diseases 0.000 description 1
- 229940051250 hexylene glycol Drugs 0.000 description 1
- 229920002674 hyaluronan Polymers 0.000 description 1
- 229960003160 hyaluronic acid Drugs 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- JNONJXMVMJSMTC-UHFFFAOYSA-N hydron;triethylazanium;sulfate Chemical compound OS(O)(=O)=O.CCN(CC)CC JNONJXMVMJSMTC-UHFFFAOYSA-N 0.000 description 1
- 125000001165 hydrophobic group Chemical group 0.000 description 1
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 1
- 230000003752 improving hair Effects 0.000 description 1
- 239000013067 intermediate product Substances 0.000 description 1
- 239000004310 lactic acid Substances 0.000 description 1
- 235000014655 lactic acid Nutrition 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 229940043348 myristyl alcohol Drugs 0.000 description 1
- GOQYKNQRPGWPLP-UHFFFAOYSA-N n-heptadecyl alcohol Natural products CCCCCCCCCCCCCCCCCO GOQYKNQRPGWPLP-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- 125000002811 oleoyl group Chemical group O=C([*])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])/C([H])=C([H])\C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 229940055577 oleyl alcohol Drugs 0.000 description 1
- XMLQWXUVTXCDDL-UHFFFAOYSA-N oleyl alcohol Natural products CCCCCCC=CCCCCCCCCCCO XMLQWXUVTXCDDL-UHFFFAOYSA-N 0.000 description 1
- 239000004006 olive oil Substances 0.000 description 1
- 235000008390 olive oil Nutrition 0.000 description 1
- 239000002540 palm oil Substances 0.000 description 1
- 229940101267 panthenol Drugs 0.000 description 1
- 235000020957 pantothenol Nutrition 0.000 description 1
- 239000011619 pantothenol Substances 0.000 description 1
- 239000000312 peanut oil Substances 0.000 description 1
- 239000002304 perfume Substances 0.000 description 1
- 150000003003 phosphines Chemical group 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229920000059 polyethylene glycol stearate Polymers 0.000 description 1
- 229940051841 polyoxyethylene ether Drugs 0.000 description 1
- 229920000056 polyoxyethylene ether Polymers 0.000 description 1
- 229920000136 polysorbate Polymers 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 239000001944 prunus armeniaca kernel oil Substances 0.000 description 1
- 125000001453 quaternary ammonium group Chemical group 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000006254 rheological additive Substances 0.000 description 1
- 239000010667 rosehip oil Substances 0.000 description 1
- 229940071089 sarcosinate Drugs 0.000 description 1
- 210000004761 scalp Anatomy 0.000 description 1
- 150000005619 secondary aliphatic amines Chemical class 0.000 description 1
- 230000035807 sensation Effects 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 229940083542 sodium Drugs 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 229940080272 sodium coco-sulfate Drugs 0.000 description 1
- 229940057950 sodium laureth sulfate Drugs 0.000 description 1
- 229940079862 sodium lauryl sarcosinate Drugs 0.000 description 1
- 235000019333 sodium laurylsulphate Nutrition 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- SXHLENDCVBIJFO-UHFFFAOYSA-M sodium;2-[2-(2-dodecoxyethoxy)ethoxy]ethyl sulfate Chemical compound [Na+].CCCCCCCCCCCCOCCOCCOCCOS([O-])(=O)=O SXHLENDCVBIJFO-UHFFFAOYSA-M 0.000 description 1
- ADWNFGORSPBALY-UHFFFAOYSA-M sodium;2-[dodecyl(methyl)amino]acetate Chemical compound [Na+].CCCCCCCCCCCCN(C)CC([O-])=O ADWNFGORSPBALY-UHFFFAOYSA-M 0.000 description 1
- MZSDGDXXBZSFTG-UHFFFAOYSA-M sodium;benzenesulfonate Chemical compound [Na+].[O-]S(=O)(=O)C1=CC=CC=C1 MZSDGDXXBZSFTG-UHFFFAOYSA-M 0.000 description 1
- 229940084106 spermaceti Drugs 0.000 description 1
- 239000012177 spermaceti Substances 0.000 description 1
- 238000010561 standard procedure Methods 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 229940012831 stearyl alcohol Drugs 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- OULAJFUGPPVRBK-UHFFFAOYSA-N tetratriacontyl alcohol Natural products CCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCO OULAJFUGPPVRBK-UHFFFAOYSA-N 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-O triethanolammonium Chemical compound OCC[NH+](CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-O 0.000 description 1
- 229940099259 vaseline Drugs 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
Landscapes
- Cosmetics (AREA)
Abstract
The invention discloses a hair styling composition, which comprises the following components: (1) maltodextrin/NVP copolymer; (2) a cationic polymer. The invention also relates to a method for styling hair by applying an effective amount of said hair styling composition and to the use of said hair styling composition for the preparation of a cosmetic product.
Description
Technical field
The present invention relates to a kind of hair setting composition, maltodextrin is included more particularly, to one kind
The hair setting composition of/NVP copolymers and anionic polymer.The hair setting composition tool
There is good hair fixing effect, and there can be the outward appearance clarified, good guarantor can be provided for hair
Wet, soft elastic and reconfigured performance.
Background technology
Hair fixing product (such as hair jelly, eruption water, hair cream, hair-cream or mousse etc.) is intended to side
Help the specific products form created personal hair style and temporarily keep a period of time in position.Existing skill
Typical hair setting composition is all based in suitable carrier mass (such as comprising gel shape in art
Into the aqueous or aqueous alcohol of agent) in hair fixing copolymer.However, these Hairstyling compositions is comprehensive
Close action effect still unsatisfactory, good moisturizing, soft elastic and again are particularly provided at the same time
Secondary mouldability aspect.
It is well known that being used for hair setting composition using conventional polymer, these polymer include day
Right colloid and resin, and synthesis source polymer.It is known for use as the city of forming hair or setting agent
Sell polymer including PVP, PVP/vinyl acetate copolymer with
And acrylate/hydroxy ester acrylate copolymer (Rohm and Haas).Other examples are propylene
Acid ester copolymer (Balance CR, Akzo；Luviflex Soft, Luvimer 100P and Luvimer
Pro55, by BASF sell), AMP- acrylate/allyl methacrylate copolymer (FixateTM
G-100, Lubrizol Advanced Materials, Inc.) (the Fixate of polyacrylate -14TMPlus,
Lubrizol Advanced Materials, Inc.) and the cross-linked polymer of polyacrylate -2 (FixateTM
Superhold, Lubrizol Advanced Materials, Inc.).For example, U.S. of Gehman et al.
State's patent 4,196,190 discloses acrylic compounds hairspray.However, conventional fixative polymers
One of shortcoming is that they significant thickening generally can not be provided under actual concentration or contribution is aobvious
The rheological equationm of state of work.
In addition, conventional hairspray polymer is often incompatible with rheological modifiers or gel,
Viscosity is caused to be damaged, gel products clarity is not good enough, texture attribute is unsatisfactory and shears thinning stream
The loss of denaturation.
The United States Patent (USP) 3,726,288 of Nowak et al. is attempted being used for hair using acrylate polymer
The crosslinking of setting agent and thickener, but, although the product realizes thickening, but hair fixing performance
Difference bends guarantor (at 72 degrees Fahrenheits (about 22 degrees Celsius)) and under 90% relative humidity after 0.5 hour
Holdup is less than 50%.
Therefore, further improved hair setting composition is stilled need in the prior art, and it can be hair
Good moisturizing, soft elastic and mouldability again are provided.
The content of the invention
Except as otherwise noted, all percentages otherwise used herein are with the gross weight meter of composition,
All of ratio is weight ratio.
The all components used in the present invention should be that skin is acceptable, i.e., when the skin with people is in contact
Shi Buhui causes unsuitable toxicity, incompatibility, unstability and allergic reaction etc..
Term " hair setting composition " used herein refers to be intended to the combination for personal nursing
Thing, its hair fixing effect needed for it being provided to object.
In the present invention, " hair fixing product " or " hairspray " refer to for hair fixing or
The personal care composition of moulding, it can be such as form such as spray, mousse, pomade and hair jelly.
" personal nursing " is related to be applied topically to the composition of people's (not being ingested).Preferably, described
People's care composition is acceptable beauty." beauty is acceptable " refers to be generally used for personal nursing group
The long hair of compound, and be intended to emphasize in the presence of with the amount for generally being found in personal care composition
Virose material is not considered component of the invention.
Herein, " polymer " or " copolymer " is term well known to those skilled in the art, can
Enter FW Billmeyer JR to exist《Polymer science textbook》(Textbook of Polymer
Science it is by the product of smaller chemical repeat unit) defined in (second edition, 1971)
The bigger molecule of composition.
The molecular weight of polymer can be measured by standard method, for example with SEC
(SEC).Herein, prepared by being polymerized alone or be polymerized jointly with other monomers by certain monomer
Polymer includes the monomer as polymerized unit.
There is good shape keeping ability it is an object of the present invention to provide one kind, it is possible to provide good moisturizing,
The hair setting composition of soft elastic and reconfigured performance.
The present inventor in research process it was unexpectedly found that, by maltodextrin/NVP (N- vinyl
Pyrrolidones) copolymer be selected from anionic polymer, cationic polymer, amphoteric ion polymer
Or the combination of polymers of its mixture is used, it is possible to achieve above-mentioned purpose.
Therefore, in a first aspect, the invention provides a kind of hair setting composition, it includes following
Component is composed of the following components：
(1) maltodextrin/NVP (NVP) of composition gross weight 0.1% to 10% is accounted for
Copolymer；
(2) cationic polymer of composition gross weight 0.1% to 5% is accounted for；With
(3) optional carrier.
Surprisingly, it was found that maltodextrin/NVP copolymers have with the combination of cationic polymer
There is good compatibility, be capable of achieving good sizing and shape-retaining ability energy, good guarantor can be particularly provided
Wet, soft elastic and reconfigured performance.
In one aspect of the invention, the maltodextrin/NVP copolymers account for hair fixing group of the present invention
The 0.1% to 8% of compound gross weight, preferably 0.2% to 8%, 0.2% to 7%, 0.2% to 6%, more
It is preferred that 0.2% to 5%, even more preferably 0.3% to 5%.
Maltodextrin of the invention/NVP copolymers preferably have following formula：
100,000-150, between 000 dalton, wherein m is whole between 800 to 1800 to its molecular weight
Number, n is the integer between 500 to 1200.At preferred aspect, the molecular weight of the copolymer
Between 120,000-140,000 dalton.At another preferred aspect, wheat in the polymer
The weight ratio for about 1: 1 of bud dextrin and NVP component units.
At a preferred aspect, the molecular weight of maltodextrin of the invention/NVP copolymers preferably exists
Between 100,000-150,000 dalton.Inventors have surprisingly discovered that, the wheat in above range
Bud dextrin/NVP copolymers, can bring superior technique effect, particularly good moisturizing,
Soft elastic and reconfigured aspect of performance, and also can have the transparent appearance of clarification.
In one aspect, hair setting composition of the invention includes the maltodextrin/NVP copolymers
And cationic polymer, or be made from it.
At a preferred aspect, the cationic polymer is selected from polyquaternium -4, polyquaternium -11
And its mixture.
In another aspect, hair setting composition of the invention includes maltodextrin/NVP (N- second
Vinyl pyrrolidone) copolymer, cationic polymer, and carrier.At a preferred aspect,
The carrier is liquid-carrier；It is highly preferred that the carrier is selected from water, C1-C6Alkanol and its mixing
Thing.The C1-C6Alkanol is in particular selected from ethanol, propyl alcohol, isopropanol, butanol or its mixture.Or
Person, the carrier page can be the mixture of water and alcohol.Particularly preferred liquid-carrier is selected from water, second
Alcohol, isopropanol, normal propyl alcohol, glycerine and propane diols or its combination.Specification is needed, the present invention
Carrier may include to play the material of solvent or diluent functions.
Additionally, as needed, hair setting composition of the invention can also comprising selected from it is following at least
A kind of component or its combination：Essence, preservative, solubilizer, thickener, surfactant, neutralization
Agent, NMF, essential oil, vitamin, pearling agent and dyestuff.
In another aspect of the present invention, there is provided a kind of to make the method for hair fixing, including to head
Hair applies the hair setting composition of the invention described above of effective dose.
In another aspect of the present invention, there is provided hair setting composition of the invention is in preparation
Purposes in people's care product.The product can be for example transparent hair jelly, eruption water, hair cream, hair
The form such as breast or mousse.
Specific embodiment
Described further below and demonstration embodiment within the scope of the present invention.Provide these specific realities
The mode of applying is intended merely to the purpose for illustrating rather than limitation of the present invention, because this can not departed from
The spirit and scope of invention carry out many changes and adjustment to them.Unless otherwise indicated, it is all to enumerate
Content, concentration be all w/w percentage.
In one aspect of the invention, there is provided a kind of hair setting composition, it includes following components
Or it is composed of the following components：
(1) maltodextrin/NVP (NVP) of composition gross weight 0.1% to 10% is accounted for
Copolymer；
(2) cationic polymer of composition gross weight 0.1% to 5% is accounted for；With
(3) optional carrier.
Maltodextrin/NVP copolymers in the present invention are one kind by making NVP
(NVP) hybridized polymer for being reacted with maltodextrin and being generated, outward appearance that it can show clear,
Suitable rheological characteristic and good stability.The copolymer except contributing to the improvement of shaping performance,
Also there is the natural sex and security in low production cost and source.However, the copolymer is used alone
Effect as hair setting composition is not still highly satisfactory.
The present inventor is had found by studying, by the maltodextrin of proper proportion/NVP copolymers and appropriate ratio
The cationic polymer of example is combined, and can well realize good sizing and shape-retaining ability energy, special
It is not that good moisturizing, soft elastic and reconfigured performance can be provided, and product is on the whole with outer
The advantage of the aspects such as sight, cost, security and compatibility.
In the present composition, maltodextrin/NVP copolymers account for hair setting composition gross weight of the present invention
0.1% to 8%, preferably 0.2% to 8%, 0.2% to 7%, 0.2% to 6%, more preferably 0.2%
To 5%, even more preferably 0.3% to 5%.
Preferably, the maltodextrin/NVP copolymers have formula：
100,000-150, between 000 dalton, wherein m is whole between 800 to 1800 to its molecular weight
Number, n is the integer between 500 to 1200.At preferred aspect, the molecular weight of the copolymer
Between 120,000-140,000 dalton.At another preferred aspect, malt in the polymer
The weight ratio for about 1: 1 of dextrin and NVP component units.
It is particularly preferred that maltodextrin of the invention/NVP copolymers particularly above formula copolymer has
Molecular weight between 100,000-150,000 dalton.
Positive ions polymer in the present composition be selected from polyquaternium -4, polyquaternium -11 and its
Mixture.Wherein, (hydroxyethyl cellulose is total to polyquaternium -4 with dimethyl diallyl ammonium chloride
Polymers) and (quaternary ammonium of vinyl pyrrolidone and decil methyl acrylate of polyquaternium -11
Change copolymer) it is as known in the art.
Composition of the invention preferably also includes carrier.It is solvent or diluent that the carrier can be played
Those materials of function, preferably liquid-carrier；It is highly preferred that the carrier is selected from water, C1-C6
Alkanol and its mixture.The C1-C6Alkanol in particular selected from ethanol, propyl alcohol, isopropanol, butanol or
Its mixture.Or, the carrier can also be the mixture of water and alcohol.Particularly preferred liquid is carried
Body is selected from water, ethanol, isopropanol, normal propyl alcohol, glycerine and propane diols or its combination.
In addition to the components described above, hair setting composition of the invention can also be included optionally as needed
Selected from following at least one component or its combination：Essence, preservative, solubilizer, surfactant,
Thickener, nertralizer, NMF, antistatic additive, oils, vitamin, pearling agent and dyestuff.When
So, it should be appreciated by those skilled in the art that the selection of these optional components and content should not be to the present invention
The effect of composition is adversely affected, and these components and its amount can be carried out according to being actually needed for product
Appropriate selection, and be added in composition of the invention.
On above-mentioned optional components, it is specifically originated and selects component as described below.
Surfactant
Can be selected from anionic surface for the surfactant in hair setting composition of the invention
One kind or its any combination in activating agent, zwitterionic surfactant and nonionic surfactant.
The surfactant can bring cleaning action and frothing capacity for composition.
Anionic surfactant component not only includes common anion surfactant, is additionally included in
It is the zwitterionic surfactant of the coupling part of anionic property under the pH of composition, or they
Combination.The example of the anion surfactant suitable for composition of the invention includes but does not limit
In sulfate, sulfonate, sarcosinate and sarcosine derivative.Preferred anion surfactant
It is poly alkyl alcohol ether sulfate and aliphatic alcohol sulfate.Non-limiting example is Texapon Special, coconut palm
Oil base ammonium sulfate, lauryl potassium sulfate, cocoyl potassium sulfate, NaLS, dodecyl sulphur
Sour sodium, ammonium lauryl sulfate, sodium cocosulfate, lauryl sulfate monoethanolamine, cocoyl sulphur
Sour MEA, lauryl sulfate diethanolamine, triethanolamine lauryl sulfate, lauryl sulfate three
Ethamine and its mixture, particularly preferably Texapon Special, NaLS, lauryl gather
Oxygen ethene ether ammonium sulfate, laureth ammonium sulfate, sodium laureth sulfate,
Laureth potassium sulfate, laureth diethanolamine, lauryl polyoxy
Vinethene sulfate, laureth sulfuric acid triethanolamine, lauryl polyoxyethylene
Ether sulfuric acid triethylamine and its mixture.The example of the anion surfactant of sulfonate includes such as ten
Trialkyl benzene sulfonic acid sodium salt, neopelex, lauryl sulfosuccinates etc..Methyl amimoacetic acid and
The example of sarcosine derivative includes sodium lauryl sarcosinate, cocoyl sarcosine, cocoyl sarcosine
And its mixture.
Amphoteric surfactant suitable for hair setting composition of the invention is known in this field
, those materials that can be used in skin nursing, as described in following patent document：United States Patent (USP)
5,104,646, United States Patent (USP) 5,106,609.These amphoteric surfactantes include secondary aliphatic amine and uncle
The surfactant of amine derivative, wherein the aliphatic group can be the group of straight or branched,
And in the aliphatic group can contain about 8-18 carbon atom, another can be comprising one kind
Anionic hydrophilic group such as carboxyl, sulfonic acid with, sulfate radical, phosphate radical or phosphonate radical.Suitable for this
The amphoteric surfactant of invention is also included as the derivative of aliphatic quaternary ammonium, quaternary phosphines and season sulfonium compound
The surfactant of thing, one of aliphatic group contains about 8-18 carbon atom, and another can be wrapped
Containing a kind of anionic hydrophilic group such as carboxyl, sulfonic acid with, sulfate radical, phosphate radical or phosphonate radical.It is excellent
Choosing is betaines zwitterionic compound, including alkyl betaine, sulfobetaines, acylamino-
Alkyl betaine, amidosulfo betaines, hydroxyl sulfo betaine and its mixture, especially coconut palm
Oleoyl amidopropyl betaine, Cocamidopropyl hydroxyl sulfo betaine, coco dimethyl carboxylic first
Base glycine betaine, coco dimethyl sulfopropyl betaine, stearyl dimethyl sulfopropyl glycine betaine.
Nonionic surfactant suitable for hair setting composition of the invention is known in this field
, such as the compound with hydrophobic group and hydrogen atoms, such as APEO of alkyl phenol,
AEO, span classes, tween classes etc..Particularly preferred nonionic surfactant
It is hydrogenated castor oils, particularly Cremophor RH40.
Thickener
The thickener that can be used in hair setting composition of the invention is generally used for the present invention with effective dose
Hair setting composition in so that bulk property is suitable to product purpose.The specific non-limit of thickener
Qualitative example includes sodium chloride, sodium sulphate and its mixture.
NMF
The NMF that can be formulated into hair setting composition of the invention can be used to promote water tariff collection to exist
The surface region of hair and scalp, it includes singly being not limited to polyhydroxy-alcohol, for example butanediol, hexylene glycol,
Glycerine, propane diols, sorbierite etc.；Lactic acid and lactate include its sodium salt or ammonium salt；Hyaluronic Acid；Hydroxyl
Acetic acid；Sugar and starch；Vaseline；Natural oil；Panthenol；And wax etc..
Nertralizer
The nertralizer that can be used in hair setting composition of the invention may be selected from NaOH, hydroxide
Potassium, ammonium hydroxide, triethanol ammonium, aminomethyl propanol, double isopropanolamines and triisopropanolamine.
Antistatic additive
The optional antistatic additive that can be used is the cationic surfactant of such as water-insoluble,
Its concentration is usually the 0.1% to about 5% of composition weight.Such antistatic additive should fail to understand development
Ring the performance and benefit of the present composition.Suitably antistatic additive is specific non-limiting
Example is three spermaceti methyl ammoniums.
Oils
Hair setting composition of the invention can contain oily substance.The oily substance can increase
Hair elasticity, helps to prevent hairs break, jag, and can to a certain extent improve hair color
Pool.The oily substance includes but is not limited to vegetable oil, animal oil, mineral oil and synthesis oils
(higher fatty acids fat) etc., preferably vegetable oil, mineral oil and artificial oil, particularly preferred vegetable oil.
Vegetable oil includes essential oil and expressed oi.Expressed oi is often referred to from vegetable seeds, fruit etc.
Oil, such as SIMMONDSIA CHINENSIS SEED OIL, Sweet Almond Oil, grape-kernel oil, rose hip oil, olive oil, cocounut oil,
Castor oil, peanut oil, apricot kernel oil etc.；Flower, fruit, leaf of the plants essential oil typical from plant
Deng the height extract at position, it is generally volatile oil, for example, changed from fish pelargonium, lavender, fan
The essential oil of the plants such as perfume, santal, grape fruit, lavender, rose, bergamot.
Pearling agent
The pearling agent that can be used in hair setting composition of the invention includes pearly-lustre as known in the art
Agent, such as hard fat compounds of group.The hard fat compounds of group is preferably with about
14 to 30 fatty alcohols of carbon atom, even more preferably about 16 to about 22 fat of carbon atom
Fat alcohol；The aliphatic compound may also include fatty acid ester in addition to fatty alcohol.These aliphatic
The instantiation of compound includes：Laruyl alcohol, stearyl alcohol, docosyl alcohol, palmityl alcohol, cetanol,
Myristyl alcohol, oleyl alcohol, cetostearyl alcohol；Mono laurate glycol ester, Tego-stearate,
Single behenic acid glycol ester, tin dilaurate glycol ester, double glycol stearates, two behenic acid second
Diol ester, mono laurate macrogol ester, monostearate macrogol ester, single behenyl acid polyethylene glycol
Ester, tin dilaurate macrogol ester, double stearic acid macrogol esters, two behenic acid macrogol esters,
Lauric monoethanolamide, stearic acid monoethanolamide, behenic acid but glycollic amide, glycerol stearate
Ester, Compritol 888 ATO and glycerol-1,3-dipalmitate；And their mixture.Its content can be
The 1% to 10% of composition gross weight, preferably 2% to 8%, more preferably 3% to 7%.
In another aspect of the present invention, there is provided a kind of to make the method for hair fixing, including to head
Hair applies the hair setting composition of the invention of effective dose.
In another aspect of the present invention, there is provided hair setting composition of the invention is in preparation
Purposes in people's care product.Hair setting composition of the invention can be used separately as finished product,
Can also be used to prepare personal care product as intermediate products, the personal care product is included for example
The forms such as transparent hair jelly, eruption water, hair cream, hair-cream or mousse.
Production method
Hair setting composition of the invention can by it is any known or other be effectively adapted to provide for
Prepared by the technology of hair setting composition, on condition that resulting composition is provided as described herein
Performance.The method of composition of the invention is prepared including in conventional preparation, mixing and soda acid
And technology.Specifically, showing for hair setting composition of the invention is given by following examples
Example property preparation method(by taking the preparation of Hairstyling composition in embodiment I-XIV as an example)。
Prepare：
1. appropriate water, ethanol and cationic polymer are added in retort, stirred；
2., to maltodextrin/NVP copolymers are added in said mixture, stir 10 minutes；
3. the other components such as glycerine, D-pantothenyl aleohol, essence, preservative are added, is stirred.
The composition of the hair setting composition of embodiment of the present invention I-XVI is shown in Table 1.Wherein, embodiment
II, IV, VI, VIII, X, XII, XIV and XVI are not comprising maltodextrin/NVP copolymers
But the negative control composition comprising anionic polymer；Embodiment III, VII, XI and XV are bags
Negative control composition containing maltodextrin/NVP copolymers but not comprising anionic polymer..
The composition of the hair setting composition of the embodiment I-XVI of table 1
Effect assessment
Evaluation method：
Sensory evaluation is carried out for the effect of embodiment, the method for sensory evaluation is：It is trained special
Industry tester carries out half a head comparative evaluation to 5 testees.Standards of grading use ten point system, 1
Worst, 10 points best, and the higher the better for fraction.
Evaluation criterion：
Sprayability：Feel whether pump head pressing easy degree is uniform with spraying
8-9 points：Pressing is very easy to, and sprays very uniform；6-7 points：Pressing is easier, and spraying is less
Uniformly；4-5 points：Pressing is less susceptible to, and sprays uneven；2-3 points：Pressing is difficult, and sprays very uneven
It is even；0-1 points：By motionless.
It is tack-free：While moulding, the viscosity between hair and hand is felt
8-9 points：Without viscous sense, 6-7 points：Slightly glue sense, negligible viscous sense；4-5 points：Compare
Strong viscous sense；2-3 points：Very strong viscous sense；0-1 points：Very strong viscous sense.
Non-greasy：While moulding, the greasy degree on hair is felt
8-9 points：Without greasy feeling；6-7 points：It is more oily, negligible oil；4-5 points：Oil
Part is heavier；2-3 points：It is very greasy；0-1 points：It is very greasy.
Moisturizing：Feel the wettability of hair
8-9 points：Moisture is very sufficient, moistens very much；6-7 points：Moisture is general, compares moistening；4-5 points：
It is more dry, slightly sensation of dryness；2-3 points：It is very dry and astringent；0-1 points：It is very dry and astringent.
Gloss：Observe the glossy degree of hair.
8-9 points：Hair gloss is bright；6-7 points：Hair gloss is brighter；4-5 points：Hair gloss one
As；2-3 points：Hair gloss is dim；0-1 points：Hair is completely matt.
Dry hair sizing hardness：With middle finger, forefinger and thumb feel the power that hair bends
8-9 points：Very strong hardness；6-7 points：It is harder；4-5 points：Hardness is general, there is soft feeling；
2-3 points：It is relatively soft, do not have hardness；0-1 points：It is very soft, there is no hardness.
Curling is not at random：That observes hai roll flies away degree
8-9 points：Hai roll is remained intact；6-7 points：Hai roll keeps preferable；4-5 points：Hai roll keeps one
As, locally have and scatter；2-3 points：Hai roll major part is scattered；0-1 points：Hai roll scatters completely.
Soft elastic：Hai roll is pinched up and down feels resilience
8-9 points：Elastic very good, flexible；6-7 points：It is elastic preferable, the general 4-5 of toughness points：It is more stiff
Firmly, it is nonelastic；2-3 points：It is very stiff；0-1 points：It is very stiff.
Gloss：Observe the glossy degree of hair.
8-9 points：Hair gloss is bright；6-7 points：Hair gloss is brighter；4-5 points：Hair gloss one
As；2-3 points：Hair gloss is dim；0-1 points：Hair is completely matt.
Sizing hardness (after 4 hours)：With middle finger, forefinger and thumb feel the power that hair bends
8-9 points：Very strong hardness；6-7 points：It is harder；4-5 points：Hardness is general, there is soft feeling；
2-3 points：It is relatively soft, do not have hardness；0-1 points：It is very soft, there is no hardness.
Crimp (after 4 hours) not at random：Observation hai roll flies away degree
8-9 points：Hai roll is remained intact；6-7 points：Hai roll keeps preferable；4-5 points：Hai roll keeps
Typically, locally have and scatter；2-3 points：Hai roll scatters；0-1 points：Hai roll scatters completely.
It is reconfigured：Reconfigured ability after water spray
8-9 points：It is easy to moulding；6-7 points：It is easier moulding；4-5 points：It is not easy moulding；
2-3 points：Extremely difficult moulding；0-1 points：Can not be reconfigured.
Evaluation result
The evaluation result of embodiment of the present invention I-XVI refers to table 2 below.
As can be seen from the above results, it is of the invention to gather comprising maltodextrin/NVP copolymers and cation
The hair setting composition of the combination of compound is combined with the control not comprising maltodextrin/NVP copolymers
Thing is compared, and shows the improvement in moisturizing, soft elastic and the aspect performance such as reconfigured.
Claims (10)
1. a kind of hair setting composition, it includes following components or composed of the following components：
(1) maltodextrin/NVP (NVP) of composition gross weight 0.1% to 10% is accounted for
Copolymer；
(2) cationic polymer of composition gross weight 0.1% to 5% is accounted for；With
(3) optional carrier.
2. hair setting composition according to claim 1, wherein the maltodextrin/NVP copolymerization
Thing accounts for the 0.1% to 8% of composition gross weight, preferably 0.2% to 8%, more preferably 0.2% to 5%.
3. according to the hair setting composition of claim 1 or 2, wherein the maltodextrin/NVP
Copolymer has formula：
100,000-150, between 000 dalton, wherein m is whole between 800 to 1800 to its molecular weight
Number, n is the integer between 500 to 1200.
4. hair setting composition as claimed in one of claims 1-3, wherein in the polymer
The weight ratio for about 1: 1 of maltodextrin and NVP component units.
5. according to the hair setting composition of any one of preceding claims, wherein the cation is poly-
Compound is selected from polyquaternium -4, polyquaternium -11 and its mixture.
6. according to the hair setting composition of any one of preceding claims, wherein the carrier is liquid
Body carrier, it is selected from water, C1-C6Alkanol and its mixture.
7. according to the hair setting composition of any one of preceding claims, wherein the composition is also
Comprising selected from following at least one component or its combination：Essence, preservative, solubilizer, thickener,
Surfactant, nertralizer, NMF, oils, vitamin, pearling agent and dyestuff.
8. it is a kind of to make the method for hair fixing, including to hair apply such as claim 1 of effective dose to
Any one of 7 defined hair setting compositions.
9. the hair setting composition of any one of claim 1 to 7 is in personal care product is prepared
Purposes.
10. the purposes of claim 9, wherein the product be transparent hair jelly, eruption water, hair cream,
The form of hair-cream or mousse.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510408869.4A CN106691885A (en) | 2015-07-13 | 2015-07-13 | Hair styling compositions comprising maltodextrin/NVP copolymer |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510408869.4A CN106691885A (en) | 2015-07-13 | 2015-07-13 | Hair styling compositions comprising maltodextrin/NVP copolymer |
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| CN106691885A true CN106691885A (en) | 2017-05-24 |
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| CN201510408869.4A Pending CN106691885A (en) | 2015-07-13 | 2015-07-13 | Hair styling compositions comprising maltodextrin/NVP copolymer |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2581566A (en) * | 2018-12-18 | 2020-08-26 | Henkel Ag & Co Kgaa | Composition and method for temporarily reshaping keratinous fibres |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102549034A (en) * | 2009-07-31 | 2012-07-04 | 阿克佐诺贝尔股份有限公司 | Hybrid copolymer compositions for personal care applications |
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2015
- 2015-07-13 CN CN201510408869.4A patent/CN106691885A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102549034A (en) * | 2009-07-31 | 2012-07-04 | 阿克佐诺贝尔股份有限公司 | Hybrid copolymer compositions for personal care applications |
Non-Patent Citations (1)
| Title |
|---|
| LAURIE J. MARSHALL 等: "Unique Styling Products Via Maltodextrin/VP", 《获取网址: HTTPS://WWW.HAPPI.COM/CONTENTS/VIEW_FEATURES/2012-11-06/UNIQUE-STYLING-PRODUCTS-VIA-MALTODEXTRINVP》 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2581566A (en) * | 2018-12-18 | 2020-08-26 | Henkel Ag & Co Kgaa | Composition and method for temporarily reshaping keratinous fibres |
| GB2581566B (en) * | 2018-12-18 | 2021-04-21 | Henkel Ag & Co Kgaa | Composition and method for temporarily reshaping keratinous fibres |
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