CN106633897A - Formula of halogen-free flame-retardant aid - Google Patents
Formula of halogen-free flame-retardant aid Download PDFInfo
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- CN106633897A CN106633897A CN201611269093.3A CN201611269093A CN106633897A CN 106633897 A CN106633897 A CN 106633897A CN 201611269093 A CN201611269093 A CN 201611269093A CN 106633897 A CN106633897 A CN 106633897A
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- halogen
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- 239000003063 flame retardant Substances 0.000 title claims abstract description 27
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 title claims abstract description 20
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims abstract description 58
- 239000000843 powder Substances 0.000 claims abstract description 28
- 229910052698 phosphorus Inorganic materials 0.000 claims abstract description 16
- 239000011574 phosphorus Substances 0.000 claims abstract description 16
- 239000003094 microcapsule Substances 0.000 claims abstract description 15
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims abstract description 14
- 229920000877 Melamine resin Polymers 0.000 claims abstract description 14
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims abstract description 14
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 14
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 claims abstract description 14
- 239000011777 magnesium Substances 0.000 claims abstract description 14
- 229910052749 magnesium Inorganic materials 0.000 claims abstract description 14
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 claims abstract description 14
- 229920001296 polysiloxane Polymers 0.000 claims abstract description 14
- -1 phosphorus ester Chemical class 0.000 claims abstract description 13
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 12
- 229910002804 graphite Inorganic materials 0.000 claims abstract description 12
- 239000010439 graphite Substances 0.000 claims abstract description 12
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 claims abstract description 10
- 150000001875 compounds Chemical class 0.000 claims abstract 5
- 239000012752 auxiliary agent Substances 0.000 claims description 17
- 239000004411 aluminium Substances 0.000 claims description 13
- 229910021502 aluminium hydroxide Inorganic materials 0.000 claims description 13
- 230000000740 bleeding effect Effects 0.000 claims description 13
- 239000003795 chemical substances by application Substances 0.000 claims description 13
- PGFXOWRDDHCDTE-UHFFFAOYSA-N hexafluoropropylene oxide Chemical compound FC(F)(F)C1(F)OC1(F)F PGFXOWRDDHCDTE-UHFFFAOYSA-N 0.000 claims description 13
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 13
- 238000000034 method Methods 0.000 claims description 13
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims 2
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims 1
- 150000002148 esters Chemical class 0.000 claims 1
- 239000002341 toxic gas Substances 0.000 abstract description 3
- 230000007547 defect Effects 0.000 abstract description 2
- XYFCBTPGUUZFHI-UHFFFAOYSA-N Phosphine Chemical compound P XYFCBTPGUUZFHI-UHFFFAOYSA-N 0.000 abstract 2
- 238000000576 coating method Methods 0.000 abstract 2
- GGAUUQHSCNMCAU-ZXZARUISSA-N (2s,3r)-butane-1,2,3,4-tetracarboxylic acid Chemical compound OC(=O)C[C@H](C(O)=O)[C@H](C(O)=O)CC(O)=O GGAUUQHSCNMCAU-ZXZARUISSA-N 0.000 abstract 1
- 230000003647 oxidation Effects 0.000 abstract 1
- 238000007254 oxidation reaction Methods 0.000 abstract 1
- 239000000779 smoke Substances 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 description 5
- 235000019504 cigarettes Nutrition 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 150000001412 amines Chemical class 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- QGJOPFRUJISHPQ-UHFFFAOYSA-N Carbon disulfide Chemical compound S=C=S QGJOPFRUJISHPQ-UHFFFAOYSA-N 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- 239000000976 ink Substances 0.000 description 2
- 239000004575 stone Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 241000245026 Scoliopus bigelovii Species 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 235000012467 brownies Nutrition 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 230000001934 delay Effects 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 239000000686 essence Substances 0.000 description 1
- 238000004880 explosion Methods 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- 239000002574 poison Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 238000000859 sublimation Methods 0.000 description 1
- 230000008022 sublimation Effects 0.000 description 1
- 230000008016 vaporization Effects 0.000 description 1
- 238000009834 vaporization Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
- C08K13/06—Pretreated ingredients and ingredients covered by the main groups C08K3/00 - C08K7/00
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/08—Metals
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K7/00—Use of ingredients characterised by shape
- C08K7/22—Expanded, porous or hollow particles
- C08K7/24—Expanded, porous or hollow particles inorganic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K9/00—Use of pretreated ingredients
- C08K9/10—Encapsulated ingredients
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K2003/026—Phosphorus
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/08—Metals
- C08K2003/0812—Aluminium
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2227—Oxides; Hydroxides of metals of aluminium
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/22—Halogen free composition
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Fireproofing Substances (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention relates to a formula of a halogen-free flame-retardant aid. The formula comprises red phosphorus, aluminum hydroxide, expansible graphite, magnesium, aluminum, hydroxyl-functional organophosphorus oligomer, 1,2-BTCA (butanetetracarboxylic acid), melamine, silicone, a penetrant and nitrogen-containing organic phosphorus ester type compounds; microencapsulated red phosphorus is prepared from red phosphorus with a microcapsule coating process; the components are sufficiently mixed in parts by weight, and flame-retardant aid powder is prepared. The cost is low; microencapsulated red phosphorus is prepared from red phosphorus with the microcapsule coating process, overcomes inherent defects of red phosphorus and is efficient and low-smoke; no toxic gas is produced during processing, the dispersity, the physical and mechanical performance, the heat stability and the flame retardancy are improved, and severe consequences caused by oxidation of red phosphorus are effectively avoided.
Description
Technical field
The present invention relates to copper-clad plate manufacturing technology field, more particularly to the formula of halogen-free flameproof auxiliary agent.
Background technology
Fire-retardant science and technology is the needs in order to adapt to social safety production and live, and fire preventing occurs, and protects the people
Lives and properties and a science that grows up.Fire retardant is application of the flame-retarded technology in real life, and it is that one kind is used for
Improve the special auxiliary chemicals of flammable combustible material combustibility, in being widely used in the fire-retardant processing of all kinds of finishing materials.
Material after fire retardant processing, when being attacked by extraneous burning things which may cause a fire disaster, can effectively prevent, delays or terminate the biography of flame
Broadcast, so as to reach fire-retardant effect.
Fire retardant can be divided into following 4 class by the different criteria for classifying, halogenated flame retardant, phosphorus flame retardant, nitrogenated flame retardant,
Phosphorus-halogenated flame retardant.
In prior art, in copper coated plate manufacturing process, the flame retardant being frequently used is halogen-free flameproof auxiliary agent, is made now
Halogen-free flameproof auxiliary agent production cost is high, and flame retardant effect is poor, particularly the fire retardant containing red phosphorus, because red phosphorus is in sky
Oxidizable in gas, moisture absorption, easily causes dust explosion, transport difficult, the defect such as poor with macromolecular material intermiscibility, range of application
It is restricted.
The content of the invention
In view of this, it is necessary to provide a kind of low production cost, and it is difficult to make red phosphorus to aoxidize and have serious consequences
The formula of halogen-free flameproof auxiliary agent.
The present invention is achieved in that the formula of halogen-free flameproof auxiliary agent, includes according to parts by weight ratio：Red phosphorus 25 ~ 30
Part, 10 ~ 12 parts of aluminium hydroxide, 18 ~ 25 parts of expansile graphite, 2 ~ 6 parts of magnesium, 4 ~ 6 parts of aluminium, the electrodeless phosphorus oligomer HFPO for having hydroxyl
20 ~ 22 parts, 13 ~ 23 parts of 1,2- BTCAs BTCA, 6 ~ 12 parts of melamine, 3 ~ 10 parts of silicone, 5 ~ 15 parts of bleeding agent and contain
12 ~ 16 parts of nitrogen organophosphorus ester compound, the red phosphorus makes microencapsulated powder oil by microcapsule coated technique, will be upper
State each component to be sufficiently mixed according to parts by weight ratio, form flame retardant powder.
Further, include according to parts by weight ratio：25 parts of red phosphorus, 10 parts of aluminium hydroxide, 18 parts of expansile graphite, magnesium
2 parts, 4 parts of aluminium, electrodeless 20 parts of the phosphorus oligomer HFPO for having hydroxyl, 13 parts of 1,2- BTCAs BTCA, 6 parts of melamine,
12 parts of 3 parts of silicone, 5 parts of bleeding agent and nitrogenous organophosphorus ester compound, the red phosphorus is made by microcapsule coated technique
Microencapsulated powder oil, above-mentioned each component is sufficiently mixed according to parts by weight ratio, forms flame retardant powder.
Further, include according to parts by weight ratio：30 parts of red phosphorus, 12 parts of aluminium hydroxide, 25 parts of expansile graphite, magnesium
6 parts, 6 parts of aluminium, electrodeless 22 parts of the phosphorus oligomer HFPO for having hydroxyl, 23 parts of 1,2- BTCAs BTCA, 12 parts of melamine,
16 parts of 10 parts of silicone, 15 parts of bleeding agent and nitrogenous organophosphorus ester compound, the red phosphorus is by microcapsule coated technique, system
Into microencapsulated powder oil, above-mentioned each component is sufficiently mixed according to parts by weight ratio, is formed flame retardant powder.
Further, include according to parts by weight ratio：28 parts of red phosphorus, 11 parts of aluminium hydroxide, 22 parts of expansile graphite, magnesium
4 parts, 5 parts of aluminium, electrodeless 21 parts of the phosphorus oligomer HFPO for having hydroxyl, 18 parts of 1,2- BTCAs BTCA, 8 parts of melamine,
14 parts of 6 parts of silicone, 10 parts of bleeding agent and nitrogenous organophosphorus ester compound, the red phosphorus is by microcapsule coated technique, system
Into microencapsulated powder oil, above-mentioned each component is sufficiently mixed according to parts by weight ratio, is formed flame retardant powder.
The advantage of formula of the halogen-free flameproof auxiliary agent that the present invention is provided is：By by red phosphorus, aluminium hydroxide, dilatancy stone
Ink, magnesium, aluminium, electrodeless phosphorus oligomer HFPO, 1,2- BTCA BTCA for having hydroxyl, melamine, silicone, bleeding agent and
Nitrogenous organophosphorus ester compound be combined with each other made by halogen-free flameproof auxiliary agent, it is not only with low cost, and red phosphorus is adopted
Microcapsule coated technique, makes the red phosphorus become microencapsulated powder oil.Microencapsulated powder oil in addition to the drawbacks of overcoming red phosphorus and be intrinsic,
And with efficient, low cigarette, work in-process does not produce toxic gas, its dispersiveness, physics, mechanical performance, heat endurance and fire-retardant
Performance is improved and improves, and effectively prevent and is had serious consequences because red phosphorus is aoxidized.
Specific embodiment
In order that the objects, technical solutions and advantages of the present invention become more apparent, in conjunction with the embodiments, the present invention is carried out
Further describe.It should be appreciated that specific embodiment described herein is not used to limit only to explain the present invention
The present invention.
Embodiment one：
The formula of halogen-free flameproof auxiliary agent, includes according to parts by weight ratio：25 parts of red phosphorus, 10 parts of aluminium hydroxide, expansile graphite
18 parts, 2 parts of magnesium, 4 parts of aluminium, electrodeless 20 parts of the phosphorus oligomer HFPO, 13 parts of 1,2- BTCAs BTCA, the melamine that have hydroxyl
12 parts of 6 parts of amine, 3 parts of silicone, 5 parts of bleeding agent and nitrogenous organophosphorus ester compound, the red phosphorus passes through microcapsule coated work
Skill, makes microencapsulated powder oil, and above-mentioned each component is sufficiently mixed according to parts by weight ratio, forms flame retardant powder
End.
Embodiment two：
The formula of halogen-free flameproof auxiliary agent, includes according to parts by weight ratio：30 parts of red phosphorus, 12 parts of aluminium hydroxide, expansile graphite
25 parts, 6 parts of magnesium, 6 parts of aluminium, electrodeless 22 parts of the phosphorus oligomer HFPO, 23 parts of 1,2- BTCAs BTCA, the melamine that have hydroxyl
16 parts of 12 parts of amine, 10 parts of silicone, 15 parts of bleeding agent and nitrogenous organophosphorus ester compound, the red phosphorus passes through microcapsule coated
Technique, makes microencapsulated powder oil, and above-mentioned each component is sufficiently mixed according to parts by weight ratio, forms flame retardant powder
End.
Embodiment three：
The formula of halogen-free flameproof auxiliary agent, includes according to parts by weight ratio：28 parts of red phosphorus, 11 parts of aluminium hydroxide, expansile graphite
22 parts, 4 parts of magnesium, 5 parts of aluminium, electrodeless 21 parts of the phosphorus oligomer HFPO, 18 parts of 1,2- BTCAs BTCA, the melamine that have hydroxyl
14 parts of 8 parts of amine, 6 parts of silicone, 10 parts of bleeding agent and nitrogenous organophosphorus ester compound, the red phosphorus passes through microcapsule coated work
Skill, makes microencapsulated powder oil, and above-mentioned each component is sufficiently mixed according to parts by weight ratio, forms flame retardant powder
End.
The red phosphorus is located at the periodic table of elements the 15th, and symbol of element P, purplish red or slightly browny amorphous powder has
Gloss, density 2.34g/cm3, heating sublimation is heated to 590 DEG C of meltings under 4300 kPas of pressure, sublimates again then after vaporization
White phosphorus is obtained, water and CS2, ether, ammonia etc. is insoluble in, absolute ethyl alcohol is slightly soluble in, nontoxic odorlessness produces white cigarette during burning, cigarette has
Poison.Chemical activity is poorer than white phosphorus, and the phosphorus that do not light is stable at normal temperatures, difficult to react with oxygen, based on reproducibility.
The advantage of formula of the halogen-free flameproof auxiliary agent that the present invention is provided is：By by red phosphorus, aluminium hydroxide, dilatancy stone
Ink, magnesium, aluminium, electrodeless phosphorus oligomer HFPO, 1,2- BTCA BTCA for having hydroxyl, melamine, silicone, bleeding agent and
Nitrogenous organophosphorus ester compound be combined with each other made by halogen-free flameproof auxiliary agent, it is not only with low cost, and red phosphorus is adopted
Microcapsule coated technique, makes the red phosphorus become microencapsulated powder oil.Microencapsulated powder oil in addition to the drawbacks of overcoming red phosphorus and be intrinsic,
And with efficient, low cigarette, work in-process does not produce toxic gas, its dispersiveness, physics, mechanical performance, heat endurance and fire-retardant
Performance is improved and improves, and effectively prevent and is had serious consequences because red phosphorus is aoxidized.
Presently preferred embodiments of the present invention is the foregoing is only, not to limit the present invention, all essences in the present invention
Any modification, equivalent and improvement made within god and principle etc., should be included within the scope of the present invention.
Claims (4)
1. the formula of halogen-free flameproof auxiliary agent, it is characterised in that include according to parts by weight ratio：25 ~ 30 parts of red phosphorus, aluminium hydroxide
10 ~ 12 parts, 18 ~ 25 parts of expansile graphite, 2 ~ 6 parts of magnesium, 4 ~ 6 parts of aluminium, electrodeless 20 ~ 22 parts of the phosphorus oligomer HFPO for having hydroxyl, 1,
13 ~ 23 parts of 2- BTCAs BTCA, 6 ~ 12 parts of melamine, 3 ~ 10 parts of silicone, 5 ~ 15 parts of bleeding agent and nitrogenous organic phosphoric acid
12 ~ 16 parts of ester type compound, the red phosphorus makes microencapsulated powder oil by microcapsule coated technique, and above-mentioned each component is pressed
It is sufficiently mixed according to parts by weight ratio, is formed flame retardant powder.
2. the formula of halogen-free flameproof auxiliary agent according to claim 1, it is characterised in that include according to parts by weight ratio：
25 parts of red phosphorus, 10 parts of aluminium hydroxide, 18 parts of expansile graphite, 2 parts of magnesium, 4 parts of aluminium, the electrodeless phosphorus oligomer HFPO 20 that has hydroxyl
Part, 13 parts of 1,2- BTCAs BTCA, 6 parts of melamine, 3 parts of silicone, 5 parts of bleeding agent and nitrogenous organophosphorus compounds
12 parts of compound, the red phosphorus makes microencapsulated powder oil, by above-mentioned each component according to parts by weight by microcapsule coated technique
Ratio is sufficiently mixed, and forms flame retardant powder.
3. the formula of halogen-free flameproof auxiliary agent according to claim 1, it is characterised in that include according to parts by weight ratio：
30 parts of red phosphorus, 12 parts of aluminium hydroxide, 25 parts of expansile graphite, 6 parts of magnesium, 6 parts of aluminium, the electrodeless phosphorus oligomer HFPO 22 that has hydroxyl
Part, 23 parts of 1,2- BTCAs BTCA, 12 parts of melamine, 10 parts of silicone, 15 parts of bleeding agent and nitrogenous organophosphorus compounds
16 parts of compound, the red phosphorus makes microencapsulated powder oil, by above-mentioned each component according to weight portion by microcapsule coated technique
Number ratio is sufficiently mixed, and forms flame retardant powder.
4. the formula of halogen-free flameproof auxiliary agent according to claim 1, it is characterised in that include according to parts by weight ratio：
28 parts of red phosphorus, 11 parts of aluminium hydroxide, 22 parts of expansile graphite, 4 parts of magnesium, 5 parts of aluminium, the electrodeless phosphorus oligomer HFPO 21 that has hydroxyl
Part, 18 parts of 1,2- BTCAs BTCA, 8 parts of melamine, 6 parts of silicone, 10 parts of bleeding agent and nitrogenous organophosphorus compounds
14 parts of compound, the red phosphorus makes microencapsulated powder oil, by above-mentioned each component according to parts by weight by microcapsule coated technique
Ratio is sufficiently mixed, and forms flame retardant powder.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201611269093.3A CN106633897A (en) | 2016-12-31 | 2016-12-31 | Formula of halogen-free flame-retardant aid |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN108546320A (en) * | 2018-04-12 | 2018-09-18 | 安徽皖东树脂科技有限公司 | The preparation method of phenolic resin |
| WO2020224182A1 (en) * | 2019-05-09 | 2020-11-12 | 王金琪 | Environment-friendly flame-retardant plastic master batch capable of preventing from blooming and precipitation and preparation method therefor |
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| CN103450503A (en) * | 2013-08-28 | 2013-12-18 | 瓮福（集团）有限责任公司 | Composite phosphorus-nitrogen flame retardant |
| CN105199182A (en) * | 2015-10-28 | 2015-12-30 | 辽宁石油化工大学 | Polyolefin flame retardant |
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2016
- 2016-12-31 CN CN201611269093.3A patent/CN106633897A/en active Pending
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102477169A (en) * | 2010-11-30 | 2012-05-30 | 比亚迪股份有限公司 | Flame retardant composition and thermoplastic elastomer composite material containing same |
| CN103450503A (en) * | 2013-08-28 | 2013-12-18 | 瓮福（集团）有限责任公司 | Composite phosphorus-nitrogen flame retardant |
| CN105199182A (en) * | 2015-10-28 | 2015-12-30 | 辽宁石油化工大学 | Polyolefin flame retardant |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108546320A (en) * | 2018-04-12 | 2018-09-18 | 安徽皖东树脂科技有限公司 | The preparation method of phenolic resin |
| CN108546320B (en) * | 2018-04-12 | 2019-07-26 | 安徽皖东树脂科技有限公司 | The preparation method of phenolic resin |
| WO2020224182A1 (en) * | 2019-05-09 | 2020-11-12 | 王金琪 | Environment-friendly flame-retardant plastic master batch capable of preventing from blooming and precipitation and preparation method therefor |
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