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CN106636779A - Wear-resisting aluminum alloy material and preparation method thereof - Google Patents

Wear-resisting aluminum alloy material and preparation method thereof Download PDF

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Publication number
CN106636779A
CN106636779A CN201611247418.8A CN201611247418A CN106636779A CN 106636779 A CN106636779 A CN 106636779A CN 201611247418 A CN201611247418 A CN 201611247418A CN 106636779 A CN106636779 A CN 106636779A
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China
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wear
alloy material
melting
aluminium alloy
magnesium
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CN201611247418.8A
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不公告发明人
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Henan Times Cloud Communication Technology Co Ltd
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Henan Times Cloud Communication Technology Co Ltd
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Priority to CN201611247418.8A priority Critical patent/CN106636779A/en
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    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C1/00Making non-ferrous alloys
    • C22C1/02Making non-ferrous alloys by melting
    • C22C1/026Alloys based on aluminium
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C21/00Alloys based on aluminium

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Refinement Of Pig-Iron, Manufacture Of Cast Iron, And Steel Manufacture Other Than In Revolving Furnaces (AREA)

Abstract

The invention discloses a wear-resisting aluminum alloy material and a preparation method thereof. The wear-resisting aluminum alloy material is prepared by smelting the following alloy elements in percentage by mass: 8.55-9.12% of Fe, 6.49-6.82% of Mg, 1.54-1.78% of W, 0.25-0.61% of Mg, 0.13-0.17% of B and Al in balancing amount. The preparation method comprises the following steps: according to elements that are required to be smelted to prepare an aluminum-aluminum alloy material, preheating pure metal powder containing the elements to 200 DEG C, then placing the pure metal powder in a resistance furnace to smelt the pure metal powder at the smelting temperature of 920-980 DEG C for 51 min, transferring the smelted pure metal powder into a medium-frequency induction heating furnace to refine the smelted pure metal powder at the refining temperature of 1,354-1,367 DEG C, and removing slag after refining; and finally, pouring the smelted pure metal powder into a mould that is preheated to 320-360 DEG C, and performing demoulding to obtain the wear-resisting aluminum alloy material. The wear-resisting aluminum alloy material prepared according to the method is improved in wear resistance, is superior to high-Fe steel, wolfram steel and cast aluminum in comprehensive performance and has an extremely high performance-price ratio.

Description

A kind of wear-resistant aluminium alloy material and preparation method thereof
Technical field
The present invention relates to technical field of metal, specifically a kind of wear-resistant aluminium alloy material and preparation method thereof.
Background technology
Existing metal material destruction has three kinds of forms:That is fracture, corrosion and abrasion.Although material weares and teares not as other two The form of kind, seldom causes the catastrophic harm of metal works, but its economic loss for causing is quite surprising.According to statistics, The economic loss caused by abrasion, dollar/year of the U.S. about 50,000,000,000, German about 30,000,000,000 marks/year.China is every year because abrasion is caused Ball mills consume nearly 2,000,000 tons, and ball mill and various lining board of crusher consume nearly 500,000 tons, and roll consumption is nearly 600,000 tons, Various engineering excavation machines and loader bucket tooth, various Wearproof transfer pipings, various grinder hammerheads and jaw, various creeper treads disappear Consumption is also above 500,000 tons.In all kinds of abrasions, abrasive wear occupies an important position again, account in galling total amount 50% with On, abrasion is many industrial department generally existings such as metallurgy, mine, machinery, electric power, coal, oil, traffic, military project and becomes Cause a major reason of equipment failure or material damage, be also one of problem for causing economic loss most.Therefore, study With Development of Novel high-abrasive material, to reduce galling, there is important meaning to national economy.
The content of the invention
It is an object of the invention to provide a kind of wear-resistant aluminium alloy material and preparation method thereof, to solve above-mentioned background technology The problem of middle proposition.
For achieving the above object, the present invention provides following technical scheme:
A kind of wear-resistant aluminium alloy material, is formed by the alloying element melting of following mass percent:Ferrum 8.55-9.12%, magnesium 6.49-6.82%, tungsten 1.54-1.78%, magnesium 0.25-0.61%, boron 0.13-0.17%, balance of aluminum.
As further scheme of the invention:The wear-resistant aluminium alloy material, by the alloying element of following mass percent Melting is formed:Ferrum 8.79-9.03%, magnesium 6.66-6.80%, tungsten 1.63-1.75%, magnesium 0.46-0.57%, boron 0.13-0.17%, it is remaining Measure as aluminum.
As further scheme of the invention:The wear-resistant aluminium alloy material, by the alloying element of following mass percent Melting is formed:Ferrum 8.86%, magnesium 6.74%, tungsten 1.70%, magnesium 0.52%, boron 0.16%, balance of aluminum.
A kind of preparation method of wear-resistant aluminium alloy material, concretely comprises the following steps:
According to the element of melting needed for aluminum aluminum alloy materials, subsequently the pure metal powder containing each element is carried out being preheating to 200 DEG C, being subsequently placed in resistance furnace carries out melting, and smelting temperature is 920-980 DEG C, and smelting time is 51min, is transferred to after melting Medium Frequency Induction Heating Furnace refine, refining temperature is 1354-1367 DEG C, carries out dragging for slag after refine;Finally it is poured into and is preheated to 320- In 360 DEG C of mould, obtain final product after the demoulding.
As further scheme of the invention:Smelting temperature is 950 DEG C in concrete steps.
As further scheme of the invention:Refining temperature is 1363 DEG C in concrete steps.
As further scheme of the invention:Finally it is poured in concrete steps and is preheated in 340 DEG C of mould.
Compared with prior art, the invention has the beneficial effects as follows:
Heretofore described wear-resistant aluminium alloy material, is formed by the alloying element melting of following mass percent:Ferrum 8.55- 9.12%th, magnesium 6.49-6.82%, tungsten 1.54-1.78%, magnesium 0.25-0.61%, boron 0.13-0.17%, balance of aluminum;Preparation method is such as Under, according to the element of melting needed for aluminum aluminum alloy materials, subsequently the pure metal powder containing each element is carried out being preheating to 200 DEG C, being subsequently placed in resistance furnace carries out melting, and smelting temperature is 920-980 DEG C, and smelting time is 51min, is transferred to after melting Medium Frequency Induction Heating Furnace refine, refining temperature is 1354-1367 DEG C, carries out dragging for slag after refine;Finally it is poured into and is preheated to 320- In 360 DEG C of mould, obtain final product after the demoulding.Wear-resistant aluminium alloy material prepared by the present invention, improves Wear Resistance, and its is comprehensive Conventional high ferro steel, wolfram steel and cast aluminium can be better than, with the high ratio of performance to price.
Specific embodiment
The technical scheme of this patent is described in more detail with reference to specific embodiment.
Embodiment 1
A kind of wear-resistant aluminium alloy material, is formed by the alloying element melting of following mass percent:Ferrum 8.55%, magnesium 6.49%, tungsten 1.54%th, magnesium 0.25%, boron 0.13%, balance of aluminum.
A kind of preparation method of wear-resistant aluminium alloy material, concretely comprises the following steps:
According to the element of melting needed for aluminum aluminum alloy materials, subsequently the pure metal powder containing each element is carried out being preheating to 200 DEG C, being subsequently placed in resistance furnace carries out melting, and smelting temperature is 920 DEG C, and smelting time is 51min, and intermediate frequency is transferred to after melting Induction heater refine, refining temperature is 1354 DEG C, carries out dragging for slag after refine;Finally it is poured into and is preheated in 320 DEG C of mould, Obtain final product after the demoulding.
Embodiment 2
A kind of wear-resistant aluminium alloy material, is formed by the alloying element melting of following mass percent:Ferrum 8.79%, magnesium 6.66%, tungsten 1.63%th, magnesium 0.46%, boron 0.13%, balance of aluminum.
A kind of preparation method of wear-resistant aluminium alloy material, concretely comprises the following steps:
According to the element of melting needed for aluminum aluminum alloy materials, subsequently the pure metal powder containing each element is carried out being preheating to 200 DEG C, being subsequently placed in resistance furnace carries out melting, and smelting temperature is 920 DEG C, and smelting time is 51min, and intermediate frequency is transferred to after melting Induction heater refine, refining temperature is 1354 DEG C, carries out dragging for slag after refine;Finally it is poured into and is preheated in 320 DEG C of mould, Obtain final product after the demoulding.
Embodiment 3
A kind of wear-resistant aluminium alloy material, is formed by the alloying element melting of following mass percent:Ferrum 8.86%, magnesium 6.74%, tungsten 1.70%th, magnesium 0.52%, boron 0.16%, balance of aluminum.
A kind of preparation method of wear-resistant aluminium alloy material, concretely comprises the following steps:
According to the element of melting needed for aluminum aluminum alloy materials, subsequently the pure metal powder containing each element is carried out being preheating to 200 DEG C, being subsequently placed in resistance furnace carries out melting, and smelting temperature is 950 DEG C, and smelting time is 51min, and intermediate frequency is transferred to after melting Induction heater refine, refining temperature is 1363 DEG C, carries out dragging for slag after refine;Finally it is poured into and is preheated in 340 DEG C of mould, Obtain final product after the demoulding.
Embodiment 4
A kind of wear-resistant aluminium alloy material, is formed by the alloying element melting of following mass percent:Ferrum 9.03%, magnesium 6.80%, tungsten 1.75%th, magnesium 0.57%, boron 0.17%, balance of aluminum.
A kind of preparation method of wear-resistant aluminium alloy material, concretely comprises the following steps:
According to the element of melting needed for aluminum aluminum alloy materials, subsequently the pure metal powder containing each element is carried out being preheating to 200 DEG C, being subsequently placed in resistance furnace carries out melting, and smelting temperature is 980 DEG C, and smelting time is 51min, and intermediate frequency is transferred to after melting Induction heater refine, refining temperature is 1367 DEG C, carries out dragging for slag after refine;Finally it is poured into and is preheated in 360 DEG C of mould, Obtain final product after the demoulding.
Embodiment 5
A kind of wear-resistant aluminium alloy material, is formed by the alloying element melting of following mass percent:Ferrum 9.12%, magnesium 6.82%, tungsten 1.78%th, magnesium 0.61%, boron 0.17%, balance of aluminum.
A kind of preparation method of wear-resistant aluminium alloy material, concretely comprises the following steps:
According to the element of melting needed for aluminum aluminum alloy materials, subsequently the pure metal powder containing each element is carried out being preheating to 200 DEG C, being subsequently placed in resistance furnace carries out melting, and smelting temperature is 980 DEG C, and smelting time is 51min, and intermediate frequency is transferred to after melting Induction heater refine, refining temperature is 1367 DEG C, carries out dragging for slag after refine;Finally it is poured into and is preheated in 360 DEG C of mould, Obtain final product after the demoulding.
Comparative example 1
A kind of wear-resistant aluminium alloy material, is formed by the alloying element melting of following mass percent:Ferrum 8.86%, magnesium 6.74%, tungsten 1.70%, balance of aluminum.
A kind of preparation method of wear-resistant aluminium alloy material, concretely comprises the following steps:
According to the element of melting needed for aluminum aluminum alloy materials, subsequently the pure metal powder containing each element is carried out being preheating to 200 DEG C, being subsequently placed in resistance furnace carries out melting, and smelting temperature is 950 DEG C, and smelting time is 51min, and intermediate frequency is transferred to after melting Induction heater refine, refining temperature is 1363 DEG C, carries out dragging for slag after refine;Finally it is poured into and is preheated in 340 DEG C of mould, Obtain final product after the demoulding.
Comparative example 2
A kind of wear-resistant aluminium alloy material, is formed by the alloying element melting of following mass percent:Ferrum 8.86%, magnesium 0.52%, boron 0.16%, balance of aluminum.
A kind of preparation method of wear-resistant aluminium alloy material, concretely comprises the following steps:
According to the element of melting needed for aluminum aluminum alloy materials, subsequently the pure metal powder containing each element is carried out being preheating to 200 DEG C, being subsequently placed in resistance furnace carries out melting, and smelting temperature is 950 DEG C, and smelting time is 51min, and intermediate frequency is transferred to after melting Induction heater refine, refining temperature is 1363 DEG C, carries out dragging for slag after refine;Finally it is poured into and is preheated in 340 DEG C of mould, Obtain final product after the demoulding.
Comparative example 3
A kind of wear-resistant aluminium alloy material, is formed by the alloying element melting of following mass percent:Magnesium 6.74%, tungsten 1.70%, magnesium 0.52%th, boron 0.16%, balance of aluminum.
A kind of preparation method of wear-resistant aluminium alloy material, concretely comprises the following steps:
According to the element of melting needed for aluminum aluminum alloy materials, subsequently the pure metal powder containing each element is carried out being preheating to 200 DEG C, being subsequently placed in resistance furnace carries out melting, and smelting temperature is 950 DEG C, and smelting time is 51min, and intermediate frequency is transferred to after melting Induction heater refine, refining temperature is 1363 DEG C, carries out dragging for slag after refine;Finally it is poured into and is preheated in 340 DEG C of mould, Obtain final product after the demoulding.
Comparative example 4
Chinese patent " a kind of composite abrasion-proof inner plate, manufacture its antifriction alloy and the method that manufactures it "(Disclosure/notification number: CN 104249504B), comprise the steps:1) dispensing, prepares the dispensing of antifriction alloy, the weight hundred of composition in antifriction alloy Divide ratio as follows:Cr (14-15.8) W%, C (2.0-3.2) W%, Si (0.3-1.2) W%, Mn (0.3-0.8) W%, S (0- 0.015) W%, P (0-0.015) W%, Mo (0.2-2.0) W%, Ni (0-1.0) W%, Cu (0.3-1.2) W%, Re (0.2- 0.4) W%, balance of Fe;2) stove melting is entered, antifriction alloy and high-ductility steel separate melting:1500 DEG C of first stove melting antifriction alloy Come out of the stove, enter A casting ladles;1700 DEG C of second stove melting high-ductility steel is come out of the stove, and enters B casting ladles;3) molten steel casting, first pours on antifriction alloy molten steel Note to die cavity, then by high-ductility steel pouring molten steel to die cavity:31) suitable mold is got out, A casting ladles stand, to be cooled To after 1400 DEG C, poured into a mould to die cavity by lower floor's casting system, to theoretical level -1cm;32) 1-3 minutes, die cavity cast are cooled down Body surface temperature is cooled to 1200 ± 30 DEG C, and B casting ladles are poured into theoretical level by upper strata casting system;33) A casting ladles are mended Pour, until being full of whole rising head;34) rising head covering and heat insulating agent time delay feeding;4) cast(ing) surface is processed, spruing, cleaning Undesirable root, overlap, burr;5) heat treating castings, are quenched, temper:51) quenching liquid is allocated;52) foundry goods dispersion shove charge, Stage long-time 12-20 hour is warming up between 900-1000 DEG C;53) insulation is come out of the stove for more than 6 hours, is stood in still air After 5 minutes, quench in the quenching liquid for stirring, compressed air is stirred more than 5 hours;54) treat foundry goods be cooled to 500 DEG C with Under, then stand and continue cool in air room temperature, enter stove and be tempered 150-250 DEG C of time 3-6 hour;55) it is cooled to after coming out of the stove often Temperature.
Comparative example 5
Chinese patent " a kind of nano combined antifriction alloy and its preparation technology for abrasion-resistant stee "(Disclosure/notification number:CN 104264029A), the antifriction alloy is by nano ceramics powder, metal powder material is compound is prepared from.The antifriction alloy gross weight of preparation Measure as 5000g, various material rates are:Nano ceramics powder gross weight 1000g, wherein WC:TiC:SiC:CeO:The ratio of YO For 1:0.1:0.2:0.2:0.1, behind four weight sums be 375g;Remaining is nanometer WC powder material.Ratio in metal powder material To reduce aluminium powder:Magnesium-chromium composite powder:Aluminium powder, iron powder, magnesium powder=1:0.5:0.025(0.01+0.01+0.005);Wherein aluminum, Ferrum, magnesium powder material weight sum are 65.57g;Reduction aluminium powder 2622.95g, magnesium-chromium powder 1311.48g.Preparation technology is in the steps below Carry out:" PVB+ dehydrated alcohol " colloidal solution is configured first;By design proportion weigh nanometer scale ceramicses powder WC, TiC, SiC, CeO and YO, individual particle state is dispersed into after mixing with dehydrated alcohol with ultrasound wave, and per 100g powders dehydrated alcohol 180ml is added, Then it is poured in the agitator for having added " PVB+ dehydrated alcohol glues " in advance and is slowly stirred,(Rotating speed less than 120 turns/ min);Other metal powder materials are subsequently adding, then blender rotating speed is transferred to into 300 turns/more than min, stirred 12 hours.Slip is existed Dry, ball milling and screening, the powder being uniformly mixed under vacuum condition;By powder pressing into base substrate.The base substrate is placed in general Oxidation processes are done in energization stove, i.e., base substrate is heated to into 450 DEG C in the case where there are air conditionses, be incubated 250min, make those metals Grain surface forms a layer thickness for nano level oxide-film.Sintering is completed under nitrogen protective condition, in 1200 DEG C of sintering, is protected Temperature 100 minutes.Bulk alloy is made by powder, as antifriction alloy finished product using crushing and ball milling method after terminating.
In sum, the aluminum alloy materials for being prepared by the preparation of embodiment of the present invention 1-5 and comparative example 1-5 are according to GB/T 1817- 1995 standards are tested;Aluminum alloy materials prepared by embodiment of the present invention 1-5, when granule is moved, linear velocity is less than 20m/s, Particle diameter is less than 1mm, and wearability is 10-15 times of high violent steel, is 8-9 times of wolfram steel, and diameter 400mm corundum wheels, Rotating speed is 3000r/min, contact pressure under conditions of 50KN, its rub proofness is less than 0.0021~0.0078mm3/ h, with rigid body Adhesion strength is more than 80MPa, and shearing strength is more than 40MPa;And aluminum alloy materials prepared by comparative example 1-5, in diameter 400mm corundum wheels, rotating speed be 3000r/min, contact pressure under conditions of 50KN, its rub proofness is 0.017~ 0.048mm3/ h, is 31-64MPa with rigid body adhesion strength, and shearing strength is 15-26MPa.
The better embodiment of this patent is explained in detail above, but this patent is not limited to above-mentioned embodiment party Formula, in the ken that one skilled in the relevant art possesses, can be with the premise of without departing from this patent objective Make a variety of changes.

Claims (7)

1. a kind of wear-resistant aluminium alloy material, it is characterised in that formed by the alloying element melting of following mass percent:Ferrum 8.55-9.12%, magnesium 6.49-6.82%, tungsten 1.54-1.78%, magnesium 0.25-0.61%, boron 0.13-0.17%, balance of aluminum.
2. wear-resistant aluminium alloy material according to claim 1, it is characterised in that the wear-resistant aluminium alloy material, by following The alloying element melting of mass percent is formed:Ferrum 8.79-9.03%, magnesium 6.66-6.80%, tungsten 1.63-1.75%, magnesium 0.46- 0.57%th, boron 0.13-0.17%, balance of aluminum.
3. wear-resistant aluminium alloy material according to claim 1, it is characterised in that the wear-resistant aluminium alloy material, by following The alloying element melting of mass percent is formed:Ferrum 8.86%, magnesium 6.74%, tungsten 1.70%, magnesium 0.52%, boron 0.16%, it is balance of Aluminum.
4. a kind of preparation method of the wear-resistant aluminium alloy material as described in claim 1-3 is arbitrary, it is characterised in that concrete steps For:
According to the element of melting needed for aluminum aluminum alloy materials, subsequently the pure metal powder containing each element is carried out being preheating to 200 DEG C, being subsequently placed in resistance furnace carries out melting, and smelting temperature is 920-980 DEG C, and smelting time is 51min, is transferred to after melting Medium Frequency Induction Heating Furnace refine, refining temperature is 1354-1367 DEG C, carries out dragging for slag after refine;Finally it is poured into and is preheated to 320- In 360 DEG C of mould, obtain final product after the demoulding.
5. the preparation method of wear-resistant aluminium alloy material according to claim 4, it is characterised in that melting temperature in concrete steps Spend for 950 DEG C.
6. the preparation method of wear-resistant aluminium alloy material according to claim 4, it is characterised in that refine temperature in concrete steps Spend for 1363 DEG C.
7. the preparation method of wear-resistant aluminium alloy material according to claim 4, it is characterised in that finally pour in concrete steps Note and be preheated in 340 DEG C of mould.
CN201611247418.8A 2016-12-29 2016-12-29 Wear-resisting aluminum alloy material and preparation method thereof Pending CN106636779A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN116083757A (en) * 2022-12-13 2023-05-09 中铝郑州有色金属研究院有限公司 Crust breaking hammer and preparation method thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN116083757A (en) * 2022-12-13 2023-05-09 中铝郑州有色金属研究院有限公司 Crust breaking hammer and preparation method thereof

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