CN106634721B - Acrylic ester aquosity hot melt latex solution of adhesion lining cloth and preparation method thereof - Google Patents
Acrylic ester aquosity hot melt latex solution of adhesion lining cloth and preparation method thereof Download PDFInfo
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- CN106634721B CN106634721B CN201510405901.3A CN201510405901A CN106634721B CN 106634721 B CN106634721 B CN 106634721B CN 201510405901 A CN201510405901 A CN 201510405901A CN 106634721 B CN106634721 B CN 106634721B
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Abstract
The present invention is used for the acrylic ester aquosity hot melt latex solution and preparation method of apparel binding fibre cloth.By AEO（Paregal O 25）1.5 2.5, lauryl sodium sulfate 0.5 1.5, acrylic acid 23, ethyl acrylate 75 80, styrene 45, vinyl acetate 15 18, methyl methacrylate 12 15, allyl methacrylate 1 1.5, methacrylic acid ethylidene-urea ethoxylated ester 34, ammonium persulfate 1 1.5, sodium hydrogensulfite 0.5 1, deionized water 120 150 are made.Its is water-based, environmentally friendly, and cost is low.
Description
Technical field
The present invention relates to a kind of acrylic ester aquosity hot melt latex solution and preparation method thereof, it is a kind of acrylic ester polymers
The emulsion of compound, used for apparel binding fibre cloth, lining cloth surface is directly coated with or is printed on, by the cohesive force of itself in heat
Lining cloth is adhered on garment material under pressure effect.
Background technology
Lining cloth can be woven fabric, looped fabric and non-fabrication cloth, and lining cloth has been generally divided into spinning lining and non-woven lining, for taking
The internal layer of dress, play a part of reinforcement, sizing.
Lining cloth and garment material, which are combined, just needs a kind of PUR.Traditional processing technology is first by adhesive
It is coated with or is printed on lining cloth, spray hot-melt adhesive powder afterwards, is then siphoned away unnecessary hot-melt adhesive powder by vacuum plant, finally
The lining cloth for being stained with hot-melt adhesive powder is dried, hot-melt adhesive powder by adhesives lining cloth one side, by lining cloth and institute during use
Need fabric to be bonded, melt hot-melt adhesive powder by temperature and pressure, lining cloth is bonded on garment material.
PUR principal item currently used for adhesion lining cloth is all kinds of heat such as polyethylene, polyamide, polyvinyl chloride, polyester
Melting powder, and the acrylic ester aquosity hot melt latex solution production technology for being used for lining cloth bonding yet there are no disclosure.
The content of the invention
It is an object of the invention to provide a kind of feature of environmental protection is good, adhesive fastness is high, resistance to dry-cleaning and washing, easy to use is used for
Acrylic ester aquosity hot melt latex solution of apparel binding fibre cloth and preparation method thereof.It is directly coated with or is printed on lining cloth surface,
Lining cloth is adhered on garment material under hot pressing function by the cohesive force of itself.
The present invention is used for the acrylic ester aquosity hot melt latex solution of apparel binding fibre cloth：
Raw material weight ratio is：AEO（Peregal O-25）1.5-2.5 lauryl sodium sulfate 0.5-
1.5, acrylic acid 2-3, ethyl acrylate 75-80, styrene 4-5, vinyl acetate 15-18, methyl methacrylate 12-15, first
Base allyl acrylate 1-1.5, methacrylic acid ethylidene-urea ethoxylated ester 3-4, ammonium persulfate 1-1.5, sodium hydrogensulfite
0.5-1, deionized water 120-150, the emulsion through emulsion polymerization；
Product index：
Outward appearance：White emulsion
It is ionic：It is cloudy
PH value： 7-8
Viscosity mPa.S： 100-500
Particle size range nm： 50-135
Average grain diameter nm： 80-90
Solid content %： 45±1
Wherein：Methacrylic acid ethylidene-urea ethoxylated ester creates Degussa Specialty Chemical to win（Shanghai）Co., Ltd produces
The W of MEEU 50.
The present invention is used for the acrylic ester aquosity PUR emulsion preparation method of apparel binding fibre cloth：
（1）By acrylic acid 2-3, ethyl acrylate 75-80, styrene 4-5, vinyl acetate 15-18, methyl methacrylate
12-15, allyl methacrylate 1-1.5, methacrylic acid ethylidene-urea ethoxylated ester 3-4 addition mixing kettles are sufficiently stirred mixed
Close；
（2）Deionized water 40-45, AEO are added in a kettle（Peregal O-25）0.5-1, fully
Stirring and dissolving；
（3）Ammonium persulfate 1-1.5 is dissolved to be well mixed with deionized water 8 ammonium persulfate aqueous solution is made；
（4）Sodium hydrogensulfite 0.5-1 is dissolved to be well mixed with deionized water 7 aqueous solution of sodium bisulfite is made；
（5）By deionized water 60-95, AEO（Peregal O-25）0.5-2, lauryl sodium sulfate
0.5-1.5 is added in pre-emulsification kettle, is sufficiently stirred dissolving；
（6）Mix monomer in mixing kettle is all added into pre-emulsification kettle, is sufficiently stirred emulsification, forms monomer emulsions；
（7）Temperature of reaction kettle is risen to 65-70 DEG C, starts the monomer emulsions being added dropwise in pre-emulsification kettle, and step is added dropwise simultaneously
Rapid 3）With step 4）Ammonium persulfate aqueous solution and aqueous solution of sodium bisulfite, control material is at the uniform velocity added dropwise, and in 3.5-4 hours
Inside synchronously drip, reaction temperature is controlled at 75-80 DEG C；
（8）Then reactor is warming up to 85-90 DEG C, after curing 30 minutes, cooled to 35-45 DEG C, detection contains admittedly
Amount, emulsion solid content is adjusted to 45 ± 1%, obtain product with deionized water.
Wherein：Methacrylic acid ethylidene-urea ethoxylated ester, it is to win wound Degussa Specialty Chemical（Shanghai）Co., Ltd goes out
The W of MEEU 50 of product；
The deionized water of emulsion solid content is adjusted not among the deionized water of raw material proportioning.
Solid content is measured according to method specified in the measure of GB/T 2793-1995 adhesive non-volatile contents.
Product of the present invention directly can be coated with or be printed on lining cloth surface, need to pass through bonding compared to other hot-melt adhesive powders
Agent is bonded in lining cloth surface, can simplify production technology, improves production efficiency, reduces production cost.
Product of the present invention is aqueous product, organic solvent need not be used in whole production engineering, with other PURs
The production process of powder is compared, more safety and environmental protection.
Product of the present invention need not be adhered on lining cloth by other adhesives by the cohesive force of itself when in use,
Reduce production process and bond medium, quality control is simpler, and product quality is more stable.
Product of the present invention is emulsion type products, can control to obtain the product of relatively low hot melting temperature, can some have compared with
Low temperature requirement under conditions of obtain more preferable application effect, and if conventional hot melt rubber powder hot melting temperature is too low, will store
During may produce adhesion and lose performance.
The present invention can improve the bond properties and washability of adhesive using methacrylic acid ethylidene-urea ethoxylated ester
Energy；The molecular weight of polymer can be improved using allyl methacrylate, while the branched structure of polymer can be increased, molten
More preferable fastness is realized in the transition process of warm solidification.And free formaldehyde is free of in product of the present invention, organic solvent-free and
VOC emission, the feature of environmental protection are fine.
Embodiment
Embodiment 1
1) by acrylic acid 2.4, ethyl acrylate 76, styrene 4.5, vinyl acetate 15, methyl methacrylate 14, methyl
Allyl acrylate 1.2, methacrylic acid ethylidene-urea ethoxylated ester 3.7 add mixing kettle and are thoroughly mixed；
2) deionized water 42, AEO are added in a kettle（Peregal O-25）0.6, it is sufficiently stirred molten
Solution；
3) ammonium persulfate 1.2 is dissolved to be well mixed with deionized water 8 and ammonium persulfate aqueous solution is made；
4) sodium hydrogensulfite 0.6 is dissolved to be well mixed with deionized water 7 and aqueous solution of sodium bisulfite is made；
5) by deionized water 68, AEO（Peregal O-25）1.1st, lauryl sodium sulfate 1.4 adds
In pre-emulsification kettle, dissolving is sufficiently stirred；
6) mix monomer in mixing kettle is all added into pre-emulsification kettle, is sufficiently stirred emulsification, form monomer emulsions；
7) temperature of reaction kettle is risen to 66 DEG C, starts the monomer emulsions being added dropwise in pre-emulsification kettle, and step 3 is added dropwise simultaneously）
With step 4）Ammonium persulfate aqueous solution and aqueous solution of sodium bisulfite, control material is at the uniform velocity added dropwise, and time for adding is 3 hours 40
Minute, reaction temperature is controlled at 75-80 DEG C；
8) 85-90 DEG C and then by reactor is warming up to, after curing 30 minutes, is cooled to 35-45 DEG C, detection contains admittedly
Amount, emulsion solid content is adjusted to 45 ± 1%, obtain product with deionized water.
Embodiment 2
1) by acrylic acid 2.8, ethyl acrylate 79, styrene 4.1, vinyl acetate 16, methyl methacrylate 12, methyl
Allyl acrylate 1.3, methacrylic acid ethylidene-urea ethoxylated ester 3.1 add mixing kettle and are thoroughly mixed；
2) deionized water 45, AEO are added in a kettle（Peregal O-25）0.9, it is sufficiently stirred molten
Solution；
3) ammonium persulfate 1.4 is dissolved to be well mixed with deionized water 8 and ammonium persulfate aqueous solution is made；
4) sodium hydrogensulfite 0.8 is dissolved to be well mixed with deionized water 7 and aqueous solution of sodium bisulfite is made；
5) by deionized water 75, AEO（Peregal O-25）1.5th, lauryl sodium sulfate 0.6 adds
In pre-emulsification kettle, dissolving is sufficiently stirred；
6) mix monomer in mixing kettle is all added into pre-emulsification kettle, is sufficiently stirred emulsification, form monomer emulsions；
7) temperature of reaction kettle is risen to 68 DEG C, starts the monomer emulsions being added dropwise in pre-emulsification kettle, and step 3 is added dropwise simultaneously）
With step 4）Ammonium persulfate aqueous solution and aqueous solution of sodium bisulfite, control material is at the uniform velocity added dropwise, and time for adding is 3 hours 50
Minute, reaction temperature is controlled at 75-80 DEG C；
8) 85-90 DEG C and then by reactor is warming up to, after curing 30 minutes, is cooled to 35-45 DEG C, detection contains admittedly
Amount, emulsion solid content is adjusted to 45 ± 1%, obtain product with deionized water.
Embodiment 3
1) by acrylic acid 2.5, ethyl acrylate 77, styrene 4.6, vinyl acetate 17, methyl methacrylate 13, methyl
Allyl acrylate 1.3, methacrylic acid ethylidene-urea ethoxylated ester 3.9 add mixing kettle and are thoroughly mixed；
2) deionized water 44, AEO are added in a kettle（Peregal O-25）0.8, it is sufficiently stirred molten
Solution；
3) ammonium persulfate 1.3 is dissolved to be well mixed with deionized water 8 and ammonium persulfate aqueous solution is made；
4) sodium hydrogensulfite 0.7 is dissolved to be well mixed with deionized water 7 and aqueous solution of sodium bisulfite is made；
5) by deionized water 81, AEO（Peregal O-25）1.2nd, lauryl sodium sulfate 1 adds pre-
In emulsifying kettle, dissolving is sufficiently stirred；
6) mix monomer in mixing kettle is all added into pre-emulsification kettle, is sufficiently stirred emulsification, form monomer emulsions；
7) temperature of reaction kettle is risen to 69 DEG C, starts the monomer emulsions being added dropwise in pre-emulsification kettle, and step 3 is added dropwise simultaneously）
With step 4）Ammonium persulfate aqueous solution and aqueous solution of sodium bisulfite, control material is at the uniform velocity added dropwise, and time for adding is 3 hours 35
Minute, reaction temperature is controlled at 75-80 DEG C；
8) 85-90 DEG C and then by reactor is warming up to, after curing 30 minutes, is cooled to 35-45 DEG C, detection contains admittedly
Amount, emulsion solid content is adjusted to 45 ± 1%, obtain product with deionized water.
Embodiment 4
1) by acrylic acid 2.2, ethyl acrylate 80, styrene 4, vinyl acetate 18, methyl methacrylate 15, methyl-prop
Olefin(e) acid allyl ester 1.1, methacrylic acid ethylidene-urea ethoxylated ester 3.1 add mixing kettle and are thoroughly mixed；
2) deionized water 41, AEO are added in a kettle（Peregal O-25）1, it is sufficiently stirred molten
Solution；
3) ammonium persulfate 1.5 is dissolved to be well mixed with deionized water 8 and ammonium persulfate aqueous solution is made；
4) sodium hydrogensulfite 0.9 is dissolved to be well mixed with deionized water 7 and aqueous solution of sodium bisulfite is made；
5) by deionized water 69, AEO（Peregal O-25）1.2nd, lauryl sodium sulfate 0.7 adds
In pre-emulsification kettle, dissolving is sufficiently stirred；
6) mix monomer in mixing kettle is all added into pre-emulsification kettle, is sufficiently stirred emulsification, form monomer emulsions；
7) temperature of reaction kettle is risen to 67 DEG C, starts the monomer emulsions being added dropwise in pre-emulsification kettle, and step 3 is added dropwise simultaneously）
With step 4）Ammonium persulfate aqueous solution and aqueous solution of sodium bisulfite, control material is at the uniform velocity added dropwise, and time for adding is 3 hours 55
Minute, reaction temperature is controlled at 75-80 DEG C；
8) 85-90 DEG C and then by reactor is warming up to, after curing 30 minutes, is cooled to 35-45 DEG C, detection contains admittedly
Amount, emulsion solid content is adjusted to 45 ± 1%, obtain product with deionized water.
Experimental example：
The product that Example 1-4 is obtained, matched and printed as follows respectively.
100 parts of product of the present invention, 2.5 parts of PTF thickeners, stir, measurement viscosity is 3500 ± 500mPa.S.
Lining cloth specification：63D*63D, density 210T, the CM of breadth 150, grammes per square metre 52 are knitted from yarn（g/㎡）Plain weave wash silk
Spin.
Point-like stamp is carried out on lining cloth using circular screen printer, stamp is dried 2 minutes under the conditions of 120-130 DEG C.
Lining cloth is fitted in the cotton shuttle-woven fabric side that yarn knits 50*50, density 140*90, lining cloth upwardly, uses flatiron
Flatiron, flatiron temperature are 130-140 DEG C, are pressed 30 seconds.
Comparative example 1
EVA hot-melt adhesive powder
100 parts of taking adhesive, PTF thickeners 1.5, stir, and measurement viscosity is 2000 ± 200mPa.S.Using cylinder
Adhesive is imprinted on lining cloth by printing machine point-like stamp, EVA hot-melt adhesive powder is sprayed at into adhesive surface afterwards, then by true
Empty device siphons away unnecessary hot-melt adhesive powder, and the lining cloth for being stained with hot-melt adhesive powder is finally dried into 2 points under the conditions of 130-150 DEG C
Clock.
Lining cloth is fitted in the cotton shuttle-woven fabric side that yarn knits 50*50, density 140*90, lining cloth upwardly, uses flatiron
Flatiron, flatiron temperature are 130-140 DEG C, are pressed 30 seconds.
Comparative example 2
Polyurethane-hot melt rubber powder
100 parts of taking adhesive, PTF thickeners 1.5, stir, and measurement viscosity is 2000 ± 200mPa.S.Using cylinder
Adhesive is imprinted on lining cloth by printing machine point-like stamp, and polyurethane-hot melt rubber powder is sprayed at into adhesive surface, Ran Houtong afterwards
Cross vacuum plant to siphon away unnecessary hot-melt adhesive powder, the lining cloth for being stained with hot-melt adhesive powder is finally dried 2 under the conditions of 130-150 DEG C
Minute.
Lining cloth is fitted in the cotton shuttle-woven fabric side that yarn knits 50*50, density 140*90, lining cloth upwardly, uses flatiron
Flatiron, flatiron temperature are 130-140 DEG C, are pressed 30 seconds.
Comparative example 3
Polyamide hot-melt adhesive powder
100 parts of taking adhesive, PTF thickeners 1.5, stir, and measurement viscosity is 2000 ± 200mPa.S.Using cylinder
Adhesive is imprinted on lining cloth by printing machine point-like stamp, and polyamide hot-melt adhesive powder is sprayed at into adhesive surface, Ran Houtong afterwards
Cross vacuum plant to siphon away unnecessary hot-melt adhesive powder, the lining cloth for being stained with hot-melt adhesive powder is finally dried 2 under the conditions of 130-150 DEG C
Minute.
Lining cloth is fitted in the cotton shuttle-woven fabric side that yarn knits 50*50, density 140*90, lining cloth upwardly, uses flatiron
Flatiron, flatiron temperature are 130-140 DEG C, are pressed 30 seconds.
Performance comparison.
| Product | Washability（Washing 10 times） | Tearing brute force（Kg） | Hot melting temperature |
| Embodiment 1 | Slight foaming | ≥1.8 | ≥100℃ |
| Embodiment 2 | Slight foaming | ≥1.8 | ≥100℃ |
| Embodiment 3 | Slight foaming | ≥1.8 | ≥100℃ |
| Embodiment 4 | Slight foaming | ≥1.8 | ≥100℃ |
| EVA hot-melt adhesive powder | Severe blister | ≥1.8 | ≥120℃ |
| Polyurethane-hot melt rubber powder | Well, it is non-foaming | ≥1.8 | ≥120℃ |
| Polyamide hot-melt adhesive powder | Slight foaming | ≥1.9 | ≥130℃ |
Washability test is according to standard GB/T/T8629-2001 Textile Tests home washings and drying program.
Tearing brute force test is according to national standard BG/T3917.2-2009 textile fabric tear properties Part II：
Trousers shape sample（The test of single seam tearing brute force）
Product of the present invention is sufficiently close to from application performance with conventional hot melt rubber powder, can meet the requirement of lining cloth,
But production technology more simplifies, and production efficiency is higher, and production cost is lower, in use, its hot melting temperature is relatively low, more suitable for wanting
Seek the product of lower temperature.
Claims (3)
1. the acrylic ester aquosity hot melt latex solution of adhesion lining cloth, it is characterized in that：
Raw material weight ratio is：AEO peregal O-25 is 1.5-2.5, lauryl sodium sulfate 0.5-1.5,
Acrylic acid 2-3, ethyl acrylate 75-80, styrene 4-5, vinyl acetate 15-18, methyl methacrylate 12-15, methyl-prop
Olefin(e) acid allyl ester 1-1.5, methacrylic acid ethylidene-urea ethoxylated ester 3-4, ammonium persulfate 1-1.5, sodium hydrogensulfite 0.5-1,
Deionized water 120-150, the emulsion through emulsion polymerization；
Product index：
Outward appearance：White emulsion
It is ionic：It is cloudy
PH value： 7-8
Viscosity mPa.S： ≤500
Particle size range nm： 50-135
Average grain diameter nm： 80-90
Solid content %： 45±1
Wherein：Methacrylic acid ethylidene-urea ethoxylated ester is to win wound Degussa Specialty Chemical（Shanghai）What Co., Ltd produced
MEEU 50 W。
2. the acrylic ester aquosity PUR emulsion preparation method of adhesion lining cloth, it is characterized in that：
Raw material is by weight ratio：
1) by acrylic acid 2-3, ethyl acrylate 75-80, styrene 4-5, vinyl acetate 15-18, methyl methacrylate 12-
15, allyl methacrylate 1-1.5, methacrylic acid ethylidene-urea ethoxylated ester 3-4 add mixing kettle and are thoroughly mixed；
2) addition deionized water 40-45, AEO peregal O-25 are 0.5-1 in a kettle, are fully stirred
Mix dissolving；
3) ammonium persulfate 1-1.5 is dissolved to be well mixed with deionized water 8 and ammonium persulfate aqueous solution is made；
4) sodium hydrogensulfite 0.5-1 is dissolved to be well mixed with deionized water 7 and aqueous solution of sodium bisulfite is made；
5) it is 0.5-2, lauryl sodium sulfate 0.5- by deionized water 60-95, AEO peregal O-25
1.5 add in pre-emulsification kettle, are sufficiently stirred dissolving；
6) mix monomer in mixing kettle is all added into pre-emulsification kettle, is sufficiently stirred emulsification, form monomer emulsions；
7) temperature of reaction kettle is risen to 65-70 DEG C, starts the monomer emulsions being added dropwise in pre-emulsification kettle, and step 3 is added dropwise simultaneously）With
Step 4）Ammonium persulfate aqueous solution and aqueous solution of sodium bisulfite, control material is at the uniform velocity added dropwise, and synchronous within 3.5-4 hours
Drip, reaction temperature is controlled at 75-80 DEG C；
8) 85-90 DEG C and then by reactor is warming up to, after curing 30 minutes, is cooled to 35-45 DEG C, detects solid content, is used
Deionized water adjusts emulsion solid content to 45 ± 1%, obtains product；
Wherein：Methacrylic acid ethylidene-urea ethoxylated ester is to win wound Degussa Specialty Chemical（Shanghai）What Co., Ltd produced
MEEU 50 W。
3. the acrylic ester aquosity for apparel binding fibre cloth that claim 2 methods described obtains heats latex solution.
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| CN201510405901.3A CN106634721B (en) | 2015-07-13 | 2015-07-13 | Acrylic ester aquosity hot melt latex solution of adhesion lining cloth and preparation method thereof |
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|---|---|---|---|
| CN201510405901.3A CN106634721B (en) | 2015-07-13 | 2015-07-13 | Acrylic ester aquosity hot melt latex solution of adhesion lining cloth and preparation method thereof |
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| CN110669447B (en) * | 2019-09-26 | 2023-10-03 | 江苏晶华新材料科技有限公司 | Acrylic pressure-sensitive adhesive PVC decorative film and preparation method thereof |
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|---|---|---|---|---|
| CN1393500A (en) * | 2001-06-27 | 2003-01-29 | 大赛璐·赫斯株式会社 | Hot melt composition and viscous lining cloth using composition |
| CN102391823A (en) * | 2011-08-12 | 2012-03-28 | 江苏三泰轻工科技有限公司 | Farinose and epruinose mixed slurry assistant for melt adhesive padding cloth |
| CN103102848A (en) * | 2012-11-08 | 2013-05-15 | 吴江市钱氏纺织有限公司 | Clothing lining-cloth hot melt adhesive and preparation method thereof |
| CN103215825A (en) * | 2013-05-04 | 2013-07-24 | 辽宁恒星精细化工有限公司 | Printing adhesive of stone paper wallpaper and preparation method of printing adhesive |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20080055899A (en) * | 2005-09-08 | 2008-06-19 | 사이텍 설패이스 스페셜티즈, 에스.에이. | Polymer and composition |
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|---|---|---|---|---|
| CN1393500A (en) * | 2001-06-27 | 2003-01-29 | 大赛璐·赫斯株式会社 | Hot melt composition and viscous lining cloth using composition |
| CN102391823A (en) * | 2011-08-12 | 2012-03-28 | 江苏三泰轻工科技有限公司 | Farinose and epruinose mixed slurry assistant for melt adhesive padding cloth |
| CN103102848A (en) * | 2012-11-08 | 2013-05-15 | 吴江市钱氏纺织有限公司 | Clothing lining-cloth hot melt adhesive and preparation method thereof |
| CN103215825A (en) * | 2013-05-04 | 2013-07-24 | 辽宁恒星精细化工有限公司 | Printing adhesive of stone paper wallpaper and preparation method of printing adhesive |
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