CN106626858A - Quick-drying type thermal dye sublimation transfer film - Google Patents
Quick-drying type thermal dye sublimation transfer film Download PDFInfo
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- CN106626858A CN106626858A CN201611119930.4A CN201611119930A CN106626858A CN 106626858 A CN106626858 A CN 106626858A CN 201611119930 A CN201611119930 A CN 201611119930A CN 106626858 A CN106626858 A CN 106626858A
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- quick
- sublimation transfer
- ink
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- 238000000859 sublimation Methods 0.000 title claims abstract description 23
- 230000008022 sublimation Effects 0.000 title claims abstract description 23
- 238000001035 drying Methods 0.000 title abstract 4
- 239000011248 coating agent Substances 0.000 claims abstract description 24
- 238000000576 coating method Methods 0.000 claims abstract description 24
- 229920005989 resin Polymers 0.000 claims abstract description 24
- 239000011347 resin Substances 0.000 claims abstract description 24
- 239000000975 dye Substances 0.000 claims abstract description 22
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 18
- 150000004676 glycans Chemical class 0.000 claims abstract description 16
- 229920001282 polysaccharide Polymers 0.000 claims abstract description 16
- 239000005017 polysaccharide Substances 0.000 claims abstract description 16
- 229920002678 cellulose Polymers 0.000 claims abstract description 12
- 239000001913 cellulose Substances 0.000 claims abstract description 12
- 230000007797 corrosion Effects 0.000 claims abstract description 12
- 238000005260 corrosion Methods 0.000 claims abstract description 12
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 claims abstract description 10
- 239000005995 Aluminium silicate Substances 0.000 claims abstract description 10
- DKPFZGUDAPQIHT-UHFFFAOYSA-N Butyl acetate Natural products CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 claims abstract description 10
- 239000004372 Polyvinyl alcohol Substances 0.000 claims abstract description 10
- 229920002472 Starch Polymers 0.000 claims abstract description 10
- 239000003463 adsorbent Substances 0.000 claims abstract description 10
- 235000012211 aluminium silicate Nutrition 0.000 claims abstract description 10
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims abstract description 10
- 239000000986 disperse dye Substances 0.000 claims abstract description 10
- 239000000839 emulsion Substances 0.000 claims abstract description 10
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 claims abstract description 10
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims abstract description 10
- 229920002401 polyacrylamide Polymers 0.000 claims abstract description 10
- 229920002451 polyvinyl alcohol Polymers 0.000 claims abstract description 10
- 239000000661 sodium alginate Substances 0.000 claims abstract description 10
- 235000010413 sodium alginate Nutrition 0.000 claims abstract description 10
- 229940005550 sodium alginate Drugs 0.000 claims abstract description 10
- 239000008107 starch Substances 0.000 claims abstract description 10
- 235000019698 starch Nutrition 0.000 claims abstract description 10
- 239000004094 surface-active agent Substances 0.000 claims abstract description 10
- 239000002002 slurry Substances 0.000 claims abstract description 9
- 239000003755 preservative agent Substances 0.000 claims abstract description 6
- 230000002335 preservative effect Effects 0.000 claims abstract description 6
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims abstract description 5
- YTPLMLYBLZKORZ-UHFFFAOYSA-N Thiophene Chemical compound C=1C=CSC=1 YTPLMLYBLZKORZ-UHFFFAOYSA-N 0.000 claims description 22
- 239000000843 powder Substances 0.000 claims description 22
- 239000004645 polyester resin Substances 0.000 claims description 18
- 229920001225 polyester resin Polymers 0.000 claims description 17
- -1 hydroxylmethyl Chemical group 0.000 claims description 15
- 239000006185 dispersion Substances 0.000 claims description 12
- 229930192474 thiophene Natural products 0.000 claims description 11
- XXLJGBGJDROPKW-UHFFFAOYSA-N antimony;oxotin Chemical compound [Sb].[Sn]=O XXLJGBGJDROPKW-UHFFFAOYSA-N 0.000 claims description 10
- 239000003112 inhibitor Substances 0.000 claims description 10
- SOQBVABWOPYFQZ-UHFFFAOYSA-N oxygen(2-);titanium(4+) Chemical compound [O-2].[O-2].[Ti+4] SOQBVABWOPYFQZ-UHFFFAOYSA-N 0.000 claims description 10
- 239000008367 deionised water Substances 0.000 claims description 9
- 229910021641 deionized water Inorganic materials 0.000 claims description 9
- 239000000463 material Substances 0.000 claims description 9
- 239000013530 defoamer Substances 0.000 claims description 8
- 229920001817 Agar Polymers 0.000 claims description 6
- 229920001503 Glucan Polymers 0.000 claims description 6
- 229920002527 Glycogen Polymers 0.000 claims description 6
- 235000010489 acacia gum Nutrition 0.000 claims description 6
- 239000001785 acacia senegal l. willd gum Substances 0.000 claims description 6
- 239000008272 agar Substances 0.000 claims description 6
- 229940096919 glycogen Drugs 0.000 claims description 6
- 239000000203 mixture Substances 0.000 claims description 6
- 239000002904 solvent Substances 0.000 claims description 6
- QQGISFDJEJMKIL-JAIQZWGSSA-N (5z)-5-[[3-(hydroxymethyl)thiophen-2-yl]methylidene]-10-methoxy-2,2,4-trimethyl-1h-chromeno[3,4-f]quinolin-9-ol Chemical group C1=CC=2NC(C)(C)C=C(C)C=2C2=C1C=1C(OC)=C(O)C=CC=1O\C2=C/C=1SC=CC=1CO QQGISFDJEJMKIL-JAIQZWGSSA-N 0.000 claims description 5
- 239000003795 chemical substances by application Substances 0.000 claims description 5
- 238000000926 separation method Methods 0.000 claims description 3
- DZPXBTZJEFYBBK-UHFFFAOYSA-N 1-(4,5-dihydroimidazol-1-yl)-4,5-dihydroimidazole Chemical compound C1=NCCN1N1C=NCC1 DZPXBTZJEFYBBK-UHFFFAOYSA-N 0.000 claims description 2
- KIUKXJAPPMFGSW-DNGZLQJQSA-N (2S,3S,4S,5R,6R)-6-[(2S,3R,4R,5S,6R)-3-Acetamido-2-[(2S,3S,4R,5R,6R)-6-[(2R,3R,4R,5S,6R)-3-acetamido-2,5-dihydroxy-6-(hydroxymethyl)oxan-4-yl]oxy-2-carboxy-4,5-dihydroxyoxan-3-yl]oxy-5-hydroxy-6-(hydroxymethyl)oxan-4-yl]oxy-3,4,5-trihydroxyoxane-2-carboxylic acid Chemical compound CC(=O)N[C@H]1[C@H](O)O[C@H](CO)[C@@H](O)[C@@H]1O[C@H]1[C@H](O)[C@@H](O)[C@H](O[C@H]2[C@@H]([C@@H](O[C@H]3[C@@H]([C@@H](O)[C@H](O)[C@H](O3)C(O)=O)O)[C@H](O)[C@@H](CO)O2)NC(C)=O)[C@@H](C(O)=O)O1 KIUKXJAPPMFGSW-DNGZLQJQSA-N 0.000 claims 1
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 claims 1
- 229940023476 agar Drugs 0.000 claims 1
- JSLMNNPQKHONFW-UHFFFAOYSA-N benzene naphthalene-1-carboxylic acid Chemical compound C1(=CC=CC2=CC=CC=C12)C(=O)O.C1=CC=CC=C1 JSLMNNPQKHONFW-UHFFFAOYSA-N 0.000 claims 1
- 239000008103 glucose Substances 0.000 claims 1
- 229920002674 hyaluronan Polymers 0.000 claims 1
- 229960003160 hyaluronic acid Drugs 0.000 claims 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims 1
- 238000010422 painting Methods 0.000 claims 1
- 150000003242 quaternary ammonium salts Chemical class 0.000 claims 1
- 229920003063 hydroxymethyl cellulose Polymers 0.000 abstract description 8
- 229940031574 hydroxymethyl cellulose Drugs 0.000 abstract description 8
- 238000007639 printing Methods 0.000 abstract description 6
- 239000000853 adhesive Substances 0.000 abstract description 3
- 230000001070 adhesive effect Effects 0.000 abstract description 3
- 230000003647 oxidation Effects 0.000 abstract description 3
- 238000007254 oxidation reaction Methods 0.000 abstract description 3
- 238000002360 preparation method Methods 0.000 abstract description 3
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 abstract 3
- SWXVUIWOUIDPGS-UHFFFAOYSA-N diacetone alcohol Chemical compound CC(=O)CC(C)(C)O SWXVUIWOUIDPGS-UHFFFAOYSA-N 0.000 abstract 2
- 239000002518 antifoaming agent Substances 0.000 abstract 1
- 239000004200 microcrystalline wax Substances 0.000 abstract 1
- 235000019808 microcrystalline wax Nutrition 0.000 abstract 1
- 238000005192 partition Methods 0.000 abstract 1
- DLRVVLDZNNYCBX-UHFFFAOYSA-N Polydextrose Polymers OC1C(O)C(O)C(CO)OC1OCC1C(O)C(O)C(O)C(O)O1 DLRVVLDZNNYCBX-UHFFFAOYSA-N 0.000 description 10
- 238000010023 transfer printing Methods 0.000 description 9
- 238000000034 method Methods 0.000 description 8
- 229920000139 polyethylene terephthalate Polymers 0.000 description 6
- 239000005020 polyethylene terephthalate Substances 0.000 description 6
- 229920001100 Polydextrose Polymers 0.000 description 5
- 229920001807 Urea-formaldehyde Polymers 0.000 description 5
- 239000002253 acid Substances 0.000 description 5
- 239000004411 aluminium Substances 0.000 description 5
- 229910052782 aluminium Inorganic materials 0.000 description 5
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 5
- 230000000694 effects Effects 0.000 description 5
- 235000013856 polydextrose Nutrition 0.000 description 5
- 239000001259 polydextrose Substances 0.000 description 5
- 229940035035 polydextrose Drugs 0.000 description 5
- ODGAOXROABLFNM-UHFFFAOYSA-N polynoxylin Chemical compound O=C.NC(N)=O ODGAOXROABLFNM-UHFFFAOYSA-N 0.000 description 5
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 4
- 230000008859 change Effects 0.000 description 4
- 229910052760 oxygen Inorganic materials 0.000 description 4
- 239000001301 oxygen Substances 0.000 description 4
- 239000000835 fiber Substances 0.000 description 3
- 238000004043 dyeing Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000000704 physical effect Effects 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- HGWOWDFNMKCVLG-UHFFFAOYSA-N [O--].[O--].[Ti+4].[Ti+4] Chemical compound [O--].[O--].[Ti+4].[Ti+4] HGWOWDFNMKCVLG-UHFFFAOYSA-N 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 150000003863 ammonium salts Chemical class 0.000 description 1
- GVFOJDIFWSDNOY-UHFFFAOYSA-N antimony tin Chemical compound [Sn].[Sb] GVFOJDIFWSDNOY-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/26—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
- B41M5/40—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used characterised by the base backcoat, intermediate, or covering layers, e.g. for thermal transfer dye-donor or dye-receiver sheets; Heat, radiation filtering or absorbing means or layers; combined with other image registration layers or compositions; Special originals for reproduction by thermography
- B41M5/42—Intermediate, backcoat, or covering layers
- B41M5/44—Intermediate, backcoat, or covering layers characterised by the macromolecular compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/26—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
- B41M5/40—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used characterised by the base backcoat, intermediate, or covering layers, e.g. for thermal transfer dye-donor or dye-receiver sheets; Heat, radiation filtering or absorbing means or layers; combined with other image registration layers or compositions; Special originals for reproduction by thermography
- B41M5/42—Intermediate, backcoat, or covering layers
- B41M5/426—Intermediate, backcoat, or covering layers characterised by inorganic compounds, e.g. metals, metal salts, metal complexes
Landscapes
- Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Laminated Bodies (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The invention discloses a quick-drying type thermal dye sublimation transfer film. The quick-drying type thermal dye sublimation transfer film comprises a film layer; a coating is arranged on the surface of the film layer and is an ink-absorbing coating; an anti-adhesion partition layer is arranged on the upper surface of the ink-absorbing coating; a water-removing layer is arranged between the film layer and the ink-absorbing coating; the coating comprises 5 to 30 parts of disperse dye slurry, 1 to 15 parts of resin, 1 to 15 parts of butyl etherified formaldehyde resin, 1 to 10 parts of butyl acetate, 1 to 10 parts of diacetone alcohol, 2 to 15 parts of hydroxymethyl cellulose, 2 to 15 parts of a surfactant, 1 to 10 parts of microcrystalline wax emulsion, 1 to 10 parts of aluminum oxide, 1 to 15 parts of polyacrylamide, 1 to 10 parts of polysaccharide derivatives, 1 to 15 parts of polyvinyl alcohol, 1 to 10 parts of a printing ink medium adsorbent, 1 to 12 parts of starch, 2 to 10 parts of preservative, 1 to 10 parts of a defoaming agent, 1 to 15 parts of cellulose, 1 to 15 parts of kaolin and 2 to 20 parts of sodium alginate. The quick-drying type thermal dye sublimation transfer film is simple in preparation process, and the prepared printing ink is high in corrosion resistance, wear resistance, oxidation resistance, water resistance and adhesive ability.
Description
Technical field
The present invention relates to thermal dye sublimation transfer printing technical field, specially a kind of quick-dry type thermal dye sublimation transfer film.
Background technology
Thermal dye sublimation transfer printing is a kind of water-free dyeing technique, with higher environmental protection effect, the high energy advocated current country
Consumption industry energy-saving reduces discharging improvement project and has important value, has become study hotspot at present.The principle of thermal dye sublimation transfer printing is in height
Under temperature (usually more than 220 DEG C), the disperse dyes on thermal dye sublimation transfer printing medium are sublimed up on chemical fiber plus material and directly by fabric
Fiber is fixed, and the chemical fiber plus material printed and dyed can be with Non-water washing.It is believed that thermal dye sublimation transfer printing technique, especially digital heat sublimation
Transfer printing process, is a kind of high in environmental protection and practical reliable technique, is hopeful to substitute traditional dyeing and finishing technique.
There is a problem of the PET thin slice melt-ofves under high temperature action due to existing thermal dye sublimation transfer film, in addition it is also necessary to protection by
The particularity for being transferred film of various physical property making exempts from damage, deformation and breakage, carries out moment thermal transfer, powerful adhesion
Printing effect is unstable under power, using existing heat transfer film, just cannot be in the different transfer printing body with particularity of physical property
Upper applicable thermal transfer printing product, using existing heat transfer film, it is necessary to can just be transferred to transfer printing body, nothing by HTHP
Method avoids being printed the problem of the damage in face, deformation and breakage.
The content of the invention
It is an object of the invention to provide a kind of quick-dry type thermal dye sublimation transfer film, to solve above-mentioned background technology in propose
Problem.
For achieving the above object, the present invention provides following technical scheme：A kind of quick-dry type thermal dye sublimation transfer film, including film
Layer, the surface of the film layer is provided with coating, and the coating is ink-absorbed coated layer, and the upper surface of the ink-absorbed coated layer is provided with antiseized separation layer,
It is additionally provided between the film layer and ink-absorbed coated layer except water layer, except water layer is provided with, some spaces are empty, and the space hole is spherical voids
Hole, a diameter of 0.5～3 micron of space hole, the thickness of the film layer is 30-60 μm, and the thickness of the coating is 2.1-2.9 μ
M, the coating includes disperse dyes slurry 5-30 parts, resin 1-15 parts, butyl etherificate Lauxite 1-15 parts, butyl acetate 1-
10 parts, DAA 1-10 parts, hydroxymethyl cellulose 2-15 parts, surfactant 2-15 parts, crystallite wax emulsion 1-10 part, oxidation
Aluminium 1-10 parts, polyacrylamide 1-15 parts, polysaccharide derivates 1-10 parts, polyvinyl alcohol 1-15 parts, ink medium adsorbent 1-10
Part, starch 1-12 parts, preservative 2-10 parts, defoamer 1-10 parts, cellulose 1-15 parts, kaolin 1-15 parts, nanometer titanium dioxide
Titanium powder 4-10 part, superfine tin oxide antimony powder end 1-15 parts, sodium alginate 2-20 parts, deionized water 1-20 part, bi-imidazoline season
Ammonium salt corrosion inhibiter 4-8 parts and thiophene aqueous dispersions 1-20 parts.
Preferably, the material of the film layer is polyethylene terephthalate.
Preferably, the polysaccharide derivates include：Polydextrose, glucan, Arabic gum, agar, glycogen, hyalomitome
Acid.
Preferably, the resin is solvent type resin 1652, polyester resin ES-100, polyester resin ES-VB-220A or poly-
Ester resin W312.
Preferably, the preferred composition proportion of the coating is：20 parts of disperse dyes slurry, 8 parts of resin, butyl etherificate ureaformaldehyde
4 parts of resin, 5 parts of butyl acetate, 3 parts of DAA, 12 parts of hydroxymethyl cellulose, 2 parts of surfactant, 2 parts of crystallite wax emulsion,
5 parts of aluminum oxide, 1 part of polyacrylamide, 3 parts of polysaccharide derivates, 2 parts of polyvinyl alcohol, 8 parts of ink medium adsorbent, 6 parts of starch,
2 parts of preservative, 3 parts of defoamer, 4 parts of cellulose, 1 part of kaolin, 1 part of nano titanium dioxide powder, superfine tin oxide antimony powder end 2
Part, 2 parts of sodium alginate, 8 parts of deionized water, 4 parts of bi-imidazoline quaternary ammonium salt corrosion inhibitor and 5 parts of thiophene aqueous dispersions.
Compared with prior art, the invention has the beneficial effects as follows：
(1) preparation process is simple of the present invention, prepared thermal dye sublimation transfer film has good wearability, non-oxidizability, water-fast
Property and adhesive ability；
(2) increasing in the present invention has anticorrosive, and printing layer can be made to have good anticorrosive property；
(3) a certain proportion of nano titanium dioxide powder and superfine tin oxide antimony powder end are added with the present invention, can be made
Printing layer is more uniform, further increases transfer quality；
(4) the bi-imidazoline quaternary ammonium salt corrosion inhibitor and thiophene aqueous dispersions of present invention addition, can adjust printing layer
PH, while can also prevent in print procedure, coating stopped nozzles, affects transferring effect.
Specific embodiment
The technical scheme in the embodiment of the present invention is clearly and completely described below, it is clear that described embodiment
Only it is a part of embodiment of the invention, rather than the embodiment of whole.Based on the embodiment in the present invention, ordinary skill
The every other embodiment that personnel are obtained under the premise of creative work is not made, belongs to the scope of protection of the invention.
The present invention provides a kind of technical scheme：A kind of dry type thermal dye sublimation transfer film, including film layer, the surface of the film layer is provided with
Coating, the coating is ink-absorbed coated layer, and the upper surface of the ink-absorbed coated layer is provided with antiseized separation layer, the film layer and ink-absorbed coated layer it
Between be additionally provided with except water layer, except water layer, to be provided with some spaces empty, and the space hole is spherical voids hole, a diameter of the 0.5 of space hole
～3 microns, the thickness of the film layer is 30-60 μm, and the thickness of the coating is 2.1-2.9 μm, and the coating includes dispersion dye
Slip material 5-30 parts, resin 1-15 parts, butyl etherificate Lauxite 1-15 parts, butyl acetate 1-10 parts, DAA 1-10 parts,
Hydroxymethyl cellulose 2-15 parts, surfactant 2-15 parts, crystallite wax emulsion 1-10 part, aluminum oxide 1-10 parts, polyacrylamide
1-15 parts, polysaccharide derivates 1-10 parts, polyvinyl alcohol 1-15 parts, ink medium adsorbent 1-10 parts, starch 1-12 parts, preservative
2-10 parts, defoamer 1-10 parts, cellulose 1-15 parts, kaolin 1-15 parts, nano titanium dioxide powder 4-10 parts, ultra-fine oxidation
Tin antimony powder end 1-15 parts, sodium alginate 2-20 parts, deionized water 1-20 part, bi-imidazoline quaternary ammonium salt corrosion inhibitor 4-8 parts and thiophene
Fen aqueous dispersions 1-20 parts.
Embodiment one：
In the present embodiment, the composition proportion of coating is：20 parts of disperse dyes slurry, 8 parts of resin, butyl etherificate ureaformaldehyde tree
4 parts of fat, 5 parts of butyl acetate, 3 parts of DAA, 12 parts of hydroxymethyl cellulose, 2 parts of surfactant, 2 parts of crystallite wax emulsion, oxygen
Change 5 parts of aluminium, 1 part of polyacrylamide, 3 parts of polysaccharide derivates, 2 parts of polyvinyl alcohol, 8 parts of ink medium adsorbent, 6 parts of starch, anti-
2 parts of rotten agent, 3 parts of defoamer, 4 parts of cellulose, 1 part of kaolin, 1 part of nano titanium dioxide powder, superfine tin oxide antimony powder end 2
Part, 2 parts of sodium alginate, 8 parts of deionized water, 4 parts of bi-imidazoline quaternary ammonium salt corrosion inhibitor and 5 parts of thiophene aqueous dispersions.
In the present embodiment, the material of the film layer is polyethylene terephthalate.
In the present embodiment, the polysaccharide derivates include：Polydextrose, glucan, Arabic gum, agar, glycogen, thoroughly
Bright matter acid.
In the present embodiment, the resin is solvent type resin 1652, polyester resin ES-100, polyester resin ES-VB-
220A or polyester resin W312.
Embodiment two：
In the present embodiment, the composition proportion of coating is：15 parts of disperse dyes slurry, 8 parts of resin, butyl etherificate ureaformaldehyde tree
4 parts of fat, 5 parts of butyl acetate, 3 parts of DAA, 15 parts of hydroxymethyl cellulose, 2 parts of surfactant, 2 parts of crystallite wax emulsion, oxygen
Change 5 parts of aluminium, 1 part of polyacrylamide, 3 parts of polysaccharide derivates, 2 parts of polyvinyl alcohol, 5 parts of ink medium adsorbent, 6 parts of starch, anti-
2 parts of rotten agent, 3 parts of defoamer, 4 parts of cellulose, 1 part of kaolin, 3 parts of nano titanium dioxide powder, superfine tin oxide antimony powder end 2
Part, 2 parts of sodium alginate, 8 parts of deionized water, 4 parts of bi-imidazoline quaternary ammonium salt corrosion inhibitor and 5 parts of thiophene aqueous dispersions.
In the present embodiment, the material of the film layer is polyethylene terephthalate.
In the present embodiment, the polysaccharide derivates include：Polydextrose, glucan, Arabic gum, agar, glycogen, thoroughly
Bright matter acid.
In the present embodiment, the resin is solvent type resin 1652, polyester resin ES-100, polyester resin ES-VB-
220A or polyester resin W312.
Embodiment three：
In the present embodiment, the composition proportion of coating is：16 parts of disperse dyes slurry, 5 parts of resin, butyl etherificate ureaformaldehyde tree
6 parts of fat, 5 parts of butyl acetate, 3 parts of DAA, 12 parts of hydroxymethyl cellulose, 2 parts of surfactant, 2 parts of crystallite wax emulsion, oxygen
Change 4 parts of aluminium, 4 parts of polyacrylamide, 3 parts of polysaccharide derivates, 3 parts of polyvinyl alcohol, 8 parts of ink medium adsorbent, 6 parts of starch, anti-
2 parts of rotten agent, 3 parts of defoamer, 6 parts of cellulose, 1 part of kaolin, 1 part of nano titanium dioxide powder, superfine tin oxide antimony powder end 2
Part, 2 parts of sodium alginate, 10 parts of deionized water, 4 parts of bi-imidazoline quaternary ammonium salt corrosion inhibitor and 5 parts of thiophene aqueous dispersions.
In the present embodiment, the material of the film layer is polyethylene terephthalate.
In the present embodiment, the polysaccharide derivates include：Polydextrose, glucan, Arabic gum, agar, glycogen, thoroughly
Bright matter acid.
In the present embodiment, the resin is solvent type resin 1652, polyester resin ES-100, polyester resin ES-VB-
220A or polyester resin W312.
Example IV：
In the present embodiment, the composition proportion of coating is：25 parts of disperse dyes slurry, 8 parts of resin, butyl etherificate ureaformaldehyde tree
6 parts of fat, 5 parts of butyl acetate, 5 parts of DAA, 10 parts of hydroxymethyl cellulose, 2 parts of surfactant, 2 parts of crystallite wax emulsion, oxygen
Change 5 parts of aluminium, 3 parts of polyacrylamide, 3 parts of polysaccharide derivates, 2 parts of polyvinyl alcohol, 8 parts of ink medium adsorbent, 6 parts of starch, anti-
2 parts of rotten agent, 3 parts of defoamer, 4 parts of cellulose, 3 parts of kaolin, 1 part of nano titanium dioxide powder, superfine tin oxide antimony powder end 2
Part, 2 parts of sodium alginate, 8 parts of deionized water, 4 parts of bi-imidazoline quaternary ammonium salt corrosion inhibitor and 5 parts of thiophene aqueous dispersions.
In the present embodiment, the material of the film layer is polyethylene terephthalate.
In the present embodiment, the polysaccharide derivates include：Polydextrose, glucan, Arabic gum, agar, glycogen, thoroughly
Bright matter acid.
In the present embodiment, the resin is solvent type resin 1652, polyester resin ES-100, polyester resin ES-VB-
220A or polyester resin W312.
Preparation process is simple of the present invention, prepared thermal dye sublimation transfer film have good anti-corrosive properties, wearability, non-oxidizability,
Resistance to water and adhesive ability；Add anticorrosive in the present invention, can make ink that there is good anticorrosive property, additionally, of the invention
In be added with a certain proportion of nano titanium dioxide powder and superfine tin oxide antimony powder end, coating can be made more uniform, moreover it is possible to
The antistatic effect of ink is improved, transfer quality is improve；The bi-imidazoline quaternary ammonium salt corrosion inhibitor and thiophene of present invention addition
Aqueous dispersions, can adjust the PH of ink, while can also prevent in print procedure, clogged with ink nozzle, affect transferring effect.
Although an embodiment of the present invention has been shown and described, for the ordinary skill in the art, can be with
Understanding can carry out various changes, modification, replacement to these embodiments without departing from the principles and spirit of the present invention
And modification, the scope of the present invention be defined by the appended.
Claims (5)
1. a kind of quick-dry type thermal dye sublimation transfer film, it is characterised in that：Including film layer, the surface of the film layer is provided with coating, the painting
Layer is ink-absorbed coated layer, and the upper surface of the ink-absorbed coated layer is provided with antiseized separation layer, is additionally provided between the film layer and ink-absorbed coated layer and removes
Water layer, except water layer, to be provided with some spaces empty, and the space hole is spherical voids hole, a diameter of 0.5～3 micron of space hole, institute
The thickness for stating film layer is 30-60 μm, and the thickness of the coating is 2.1-2.9 μm, and the coating includes disperse dyes slurry 5-30
Part, resin 1-15 parts, butyl etherificate Lauxite 1-15 parts, butyl acetate 1-10 parts, DAA 1-10 parts, hydroxylmethyl cellulose
Plain 2-15 parts, surfactant 2-15 parts, crystallite wax emulsion 1-10 part, aluminum oxide 1-10 parts, polyacrylamide 1-15 parts, polysaccharide
Derivative 1-10 parts, polyvinyl alcohol 1-15 parts, ink medium adsorbent 1-10 parts, starch 1-12 parts, preservative 2-10 parts, froth breaking
Agent 1-10 parts, cellulose 1-15 parts, kaolin 1-15 parts, nano titanium dioxide powder 4-10 parts, superfine tin oxide antimony powder end 1-
15 parts, sodium alginate 2-20 parts, deionized water 1-20 part, bi-imidazoline quaternary ammonium salt corrosion inhibitor 4-8 parts and thiophene aqueous dispersions
1-20 parts.
2. quick-dry type thermal dye sublimation transfer film according to claim 1, it is characterised in that：The material of the film layer is for poly- to benzene
Naphthalate.
3. quick-dry type thermal dye sublimation transfer film according to claim 1, it is characterised in that：The polysaccharide derivates include：It is poly-
Glucose, glucan, Arabic gum, agar, glycogen, hyaluronic acid.
4. quick-dry type thermal dye sublimation transfer film according to claim 1, it is characterised in that：The resin is solvent type resin
1652nd, polyester resin ES-100, polyester resin ES-VB-220A or polyester resin W312.
5. quick-dry type thermal dye sublimation transfer film according to claim 1, it is characterised in that：The preferred composition proportion of the coating
For：20 parts of disperse dyes slurry, 8 parts of resin, butyl 4 parts of Lauxite of etherificate, 5 parts of butyl acetate, 3 parts of DAA, hydroxyl first
12 parts of base cellulose, 2 parts of surfactant, 2 parts of crystallite wax emulsion, 5 parts of aluminum oxide, 1 part of polyacrylamide, polysaccharide derivates 3
Part, 2 parts of polyvinyl alcohol, 8 parts of ink medium adsorbent, 6 parts of starch, 2 parts of preservative, 3 parts of defoamer, 4 parts of cellulose, kaolin
1 part, 1 part of nano titanium dioxide powder, superfine tin oxide antimony powder end 2 parts, 2 parts of sodium alginate, 8 parts of deionized water, bi-imidazoline
5 parts of 4 parts of quaternary ammonium salt corrosion inhibitor and thiophene aqueous dispersions.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611119930.4A CN106626858A (en) | 2016-12-08 | 2016-12-08 | Quick-drying type thermal dye sublimation transfer film |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611119930.4A CN106626858A (en) | 2016-12-08 | 2016-12-08 | Quick-drying type thermal dye sublimation transfer film |
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| CN106626858A true CN106626858A (en) | 2017-05-10 |
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ID=58819971
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| CN201611119930.4A Pending CN106626858A (en) | 2016-12-08 | 2016-12-08 | Quick-drying type thermal dye sublimation transfer film |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN111087862A (en) * | 2019-12-31 | 2020-05-01 | 苏州吉谷新材料有限公司 | Thermal sublimation changes printing paper with thermal sublimation coating |
| CN116638881A (en) * | 2023-05-11 | 2023-08-25 | 江阴市全佳数码科技有限公司 | Quick-drying type thermal sublimation transfer paper and manufacturing method thereof |
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| CN111087862A (en) * | 2019-12-31 | 2020-05-01 | 苏州吉谷新材料有限公司 | Thermal sublimation changes printing paper with thermal sublimation coating |
| CN116638881A (en) * | 2023-05-11 | 2023-08-25 | 江阴市全佳数码科技有限公司 | Quick-drying type thermal sublimation transfer paper and manufacturing method thereof |
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Application publication date: 20170510 |