CN106626358A - Multi-material 3D printer and liquid matter accumulation 3D printing method - Google Patents
Multi-material 3D printer and liquid matter accumulation 3D printing method Download PDFInfo
- Publication number
- CN106626358A CN106626358A CN201611117769.7A CN201611117769A CN106626358A CN 106626358 A CN106626358 A CN 106626358A CN 201611117769 A CN201611117769 A CN 201611117769A CN 106626358 A CN106626358 A CN 106626358A
- Authority
- CN
- China
- Prior art keywords
- print head
- module
- printing
- axis
- printer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B33—ADDITIVE MANUFACTURING TECHNOLOGY
- B33Y—ADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3-D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3-D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING
- B33Y10/00—Processes of additive manufacturing
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B33—ADDITIVE MANUFACTURING TECHNOLOGY
- B33Y—ADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3-D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3-D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING
- B33Y30/00—Apparatus for additive manufacturing; Details thereof or accessories therefor
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B33—ADDITIVE MANUFACTURING TECHNOLOGY
- B33Y—ADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3-D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3-D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING
- B33Y50/00—Data acquisition or data processing for additive manufacturing
- B33Y50/02—Data acquisition or data processing for additive manufacturing for controlling or regulating additive manufacturing processes
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
Abstract
本发明公开了一种多材料3D打印机及液态物堆积3D打印方法,在3D打印机机架上安装打印头切换机构和打印头架,并设置多个打印头,每个打印头内放置不同的打印材料,同时在打印头架上安装物料后处理装置,对已打印的物料进行再加工。使用本发明所述技术方案可以先使用热塑性材料搭建具有复杂空间结构的容器,在构建容器的同时,将液态物填充在其中,从而精确控制液态物的空间构型。本发明所述的多材料3D打印机及液态物堆积打印方法将单材料3D打印技术拓展到多材料3D打印领域;多材料3D打印机运行可靠、精度高;在3D打印的同时可以对材料进行再加工;可以实现低粘度液态物的3D打印,具有良好的市场前景。
The invention discloses a multi-material 3D printer and a liquid object accumulation 3D printing method. A print head switching mechanism and a print head frame are installed on the 3D printer frame, and a plurality of print heads are arranged, and different print heads are placed in each print head. materials, and at the same time, a material post-processing device is installed on the print head frame to reprocess the printed materials. Using the technical solution of the present invention, thermoplastic materials can be used to build a container with a complex spatial structure, and liquids are filled in the container while the container is being constructed, thereby precisely controlling the spatial configuration of the liquid. The multi-material 3D printer and liquid object accumulation printing method described in the present invention expand the single-material 3D printing technology to the field of multi-material 3D printing; the multi-material 3D printer operates reliably and has high precision; materials can be reprocessed while 3D printing ; 3D printing of low-viscosity liquids can be realized, which has a good market prospect.
Description
技术领域technical field
本发明涉及3D打印领域,尤其涉及一种多材料3D打印机及液态物堆积打印方法,使用液态物堆积对多材料进行混合3D打印的技术。The present invention relates to the field of 3D printing, in particular to a multi-material 3D printer and a method for accumulating and printing liquid objects, which is a technique for mixing 3D printing of multi-materials by accumulating liquid objects.
背景技术Background technique
伴随工业制品精度的提高和个性化的发展,3D打印技术应运而生。相对于传统的模型构造技术而言,3D打印可以通过逐层打印完成立体结构的成型。因为单层的打印类似于二维的打印技术,所以这个技术被称为三维打印。该技术可以用来快速构建个性化的模型,包括精密的模型构建并将其转换成可输出的信号传递给3D打印机。3D打印过程中,通过软件设计确定打印出的性状,通过改变材料来确定结构的组成,通过挤压、激光或高温等物理条件的控制来确定最后的成型。它不仅可以快速打印出复杂的三维结构也可以满足个性化的需求。所以3D打印技术已经应用于众多领域。With the improvement of the precision of industrial products and the development of personalization, 3D printing technology has emerged as the times require. Compared with the traditional model construction technology, 3D printing can complete the three-dimensional structure by printing layer by layer. Because the printing of a single layer is similar to two-dimensional printing technology, this technology is called three-dimensional printing. The technology can be used to quickly build personalized models, including sophisticated model building and converting them into outputable signals for 3D printers. During the 3D printing process, the printed properties are determined by software design, the composition of the structure is determined by changing the material, and the final shape is determined by the control of physical conditions such as extrusion, laser or high temperature. It can not only quickly print complex 3D structures but also meet individual needs. Therefore, 3D printing technology has been applied in many fields.
目前常用的3D打印方法有光固化立体造型技术(stereo-lithography,SLA)、熔融沉积成型技术(fused deposition modeling,FDM)、选区激光烧结技术(selective lasersintering,SLS)、数字光处理技术(digital light processing,DLP)、三维印刷工艺(three dimensional printing,3DP)。无论哪种技术,所依据的原理都是先进行单层的固化、凝结、雕刻或成型,然后再进行另一层的制作,层层之间逐渐组合。Currently commonly used 3D printing methods include stereo-lithography (SLA), fused deposition modeling (FDM), selective laser sintering (SLS), and digital light processing (digital light). processing, DLP), three-dimensional printing (three dimensional printing, 3DP). No matter which technology is used, the principle is to solidify, condense, sculpt or shape a single layer first, and then make another layer, and the layers are gradually combined.
经过对现有技术文献的检索发现,中国发明申请号:CN201410669660.9,公开号:CN104667344A,名称:《用于产生组织工程支架的3D打印技术》,该发明申请公开了组织工程支架的3D打印技术,其中有两个实施例,一是使用打印机将支架纤维的第一层打印至基本凝胶基材上,二是在经打印的第一层上设置第一凝胶层。该发明利用了3D打印技术在构造三维支架方面的优势。然而该发明中提出的打印方法近局限于组织工程支架的制备的应用,应用领域过于狭窄。而且,对于液态溶液,其中的处理方式是通过喷嘴喷射进行,所以仅能喷出液滴,如果需要更大剂量的溶液,那么该发明所述技术方案便不适用。After searching the existing technical literature, it was found that the Chinese invention application number: CN201410669660.9, publication number: CN104667344A, name: "3D printing technology for producing tissue engineering scaffolds", the invention application discloses the 3D printing of tissue engineering scaffolds technology, wherein there are two embodiments, one is to use a printer to print the first layer of scaffold fibers onto the basic gel substrate, and the other is to place the first gel layer on the printed first layer. The invention takes advantage of 3D printing technology in constructing three-dimensional scaffolds. However, the printing method proposed in this invention is limited to the preparation of tissue engineering scaffolds, and the application field is too narrow. And, for the liquid solution, the treatment mode wherein is to carry out by spraying through the nozzle, so only can spray liquid droplet, if need the solution of larger dosage, so the technical scheme of this invention just is not applicable.
另一中国发明申请号:CN201610122318.6,公开号:CN105643939A,名称:《硅胶3D打印机及硅胶产品打印方法》,其公开了一种硅胶的3D打印机和一种硅胶的3D打印方法。该发明主要通过一个带有加热装置的气压挤出筒三维打印硅胶产品,然而该发明对没有明确可供打印的硅胶原料的成分和具体加热温度,硅胶原料限定为一种具有剪切稀化特性的硅胶,因此该方法大大局限了可供3D打印的硅胶种类。事实上,硅橡胶在变成弹性体之前有一个生胶硫化的过程。按照硫化的温度不同,硅橡胶分热硫化型(HTV)和室温硫化型(RTV)。总而言之,生胶成分不同的硅胶,其硫化工艺完全不同,且聚合后的硅橡胶性能差异很大。一般,生胶呈胶状,流动性较好,如果能在3D打印的过程中也能进行较为快速的硫化再加工步骤,那么将大大拓宽可供3D打印的硅胶原料范围。Another Chinese invention application number: CN201610122318.6, publication number: CN105643939A, name: "Silicone 3D Printer and Silicone Product Printing Method", which discloses a silicone 3D printer and a silicone 3D printing method. This invention mainly uses a pneumatic extrusion cylinder with a heating device to 3D print silicone products. However, the invention does not specify the composition and specific heating temperature of the silicone raw material available for printing. The silicone raw material is limited to one with shear thinning properties. Silicone, so this method greatly limits the types of silicone available for 3D printing. In fact, silicone rubber has a raw rubber vulcanization process before it becomes an elastomer. According to the vulcanization temperature, silicone rubber is divided into heat vulcanization type (HTV) and room temperature vulcanization type (RTV). All in all, the vulcanization process of silica gel with different raw rubber components is completely different, and the performance of the polymerized silicone rubber varies greatly. Generally, raw rubber is gel-like and has good fluidity. If a relatively rapid vulcanization and reprocessing step can be performed during the 3D printing process, the range of silicone raw materials available for 3D printing will be greatly expanded.
目前无论使用什么原理的3D打印机,在打印一个模型的过程中,只能使用一种原材料进行打印。目前的3D打印机在打印出物料后,无法对物料进行再加工,导致部分种类的材料无法使用3D打印方法加工。低粘度液态物由于其流动性,很难形成稳定的空间结构。如果使用挤出法打印低粘度液态化合物/混合物,就无法精确控制液态物的形状,或者控制了液态物的初始形状,由于流动性最终形状无法保持。At present, no matter what principle of 3D printer is used, only one raw material can be used for printing in the process of printing a model. The current 3D printers cannot reprocess the materials after printing out the materials, resulting in the inability of some types of materials to be processed by 3D printing methods. Due to its fluidity, low-viscosity liquids are difficult to form a stable spatial structure. If extrusion is used to print low-viscosity liquid compounds/mixtures, the shape of the liquid cannot be precisely controlled, or the initial shape of the liquid is controlled, and the final shape cannot be maintained due to fluidity.
因此,本领域的技术人员致力于开发一种多材料3D打印机及液态物堆积打印方法,具有能够使用多种材料打印,能够使用低粘度液态物,能够对打印的物料进行再加工等特点。Therefore, those skilled in the art are devoting themselves to developing a multi-material 3D printer and a method for accumulating liquid objects, which have the characteristics of being able to use multiple materials for printing, being able to use low-viscosity liquid objects, and being able to reprocess printed materials.
发明内容Contents of the invention
有鉴于现有技术的上述缺陷,本发明所要解决的技术问题是如何能够使用多种材料打印,如何能够使用低粘度液态物打印以及如何能够对打印的物料进行再加工。In view of the above-mentioned defects of the prior art, the technical problems to be solved by the present invention are how to use various materials for printing, how to use low-viscosity liquid materials for printing and how to reprocess the printed materials.
为实现上述目的,本发明提供了一种多材料3D打印机,包括机架、载物台、单轴移动模块、打印头模块,其中,所述单轴移动模块包括X轴单轴移动模块、Y轴单轴移动模块、Z轴单轴移动模块;所述Y轴单轴移动模块安装在所述机架上,所述X轴单轴移动模块横跨安装在所述Y轴单轴移动模块和所述机架上,所述Z轴单轴移动模块垂直安装在所述机架上;所述打印头模块固定设置于所述X轴单轴移动模块上。To achieve the above object, the present invention provides a multi-material 3D printer, including a frame, a stage, a single-axis moving module, and a print head module, wherein the single-axis moving module includes an X-axis single-axis moving module, a Y axis single-axis movement module, Z-axis single-axis movement module; the Y-axis single-axis movement module is installed on the frame, and the X-axis single-axis movement module is installed across the Y-axis single-axis movement module and On the frame, the Z-axis single-axis moving module is vertically installed on the frame; the print head module is fixedly arranged on the X-axis single-axis moving module.
进一步地,所述载物台的一端固定于所述Z轴单轴移动模块上,另一端固定在一花键上,滑动所述花键的导轨两端固定在所述机架上。Further, one end of the stage is fixed on the Z-axis single-axis moving module, the other end is fixed on a spline, and both ends of the guide rail sliding the spline are fixed on the frame.
进一步地,所述打印头模块包括打印头切换机构、打印头架和一个或多个打印头。Further, the print head module includes a print head switching mechanism, a print head frame and one or more print heads.
进一步地,所述打印头安装在所述打印头架上,所述打印头切换机构被配置为旋转所述打印头架;所述打印头架上设有固定孔或夹具,所述打印头被配置为通过所述固定孔或所述夹具固定。Further, the print head is installed on the print head frame, and the print head switching mechanism is configured to rotate the print head frame; the print head frame is provided with fixing holes or clamps, and the print head is configured to be fixed through the fixing hole or the clamp.
进一步地,所述打印头是喷出或挤出打印物料的装置,或者是对物料进行后处理加工的装置。Further, the printing head is a device for ejecting or extruding printing materials, or a device for post-processing materials.
进一步地,所述喷出或挤出打印物料的方式为电磁喷出式、压电喷出式、气压喷出式、活塞挤出式或螺旋挤出式中的一种;所述后处理加工的装置为激光器或喷风枪。Further, the way of ejecting or extruding printing materials is one of electromagnetic ejection, piezoelectric ejection, air pressure ejection, piston extrusion or spiral extrusion; the post-processing The preferred device is a laser or a blast gun.
进一步地,所述多材料3D打印机还包括上位控制系统和自动控制模块,所述上位控制系统被配置为以计算机为核心,对模型文件进行预处理,生成待打印模型的机加工代码信息,并通过数据线传输给所述自动控制模块;所述自动控制模块被配置为控制整个多材料3D打印机各机构的运动和数据采集。Further, the multi-material 3D printer also includes an upper control system and an automatic control module, the upper control system is configured to take the computer as the core, preprocess the model file, generate machining code information of the model to be printed, and The data is transmitted to the automatic control module through the data line; the automatic control module is configured to control the movement and data collection of the various mechanisms of the entire multi-material 3D printer.
进一步地,所述自动控制模块包括控制器、打印头模块运动控制模块、载物台运动控制模块、打印头切换机构控制模块和打印头控制模块。Further, the automatic control module includes a controller, a print head module motion control module, a stage motion control module, a print head switching mechanism control module and a print head control module.
进一步地,所述打印头模块运动控制模块被配置为根据所述上位控制系统生成的待打印模型的机加工代码信息,控制所述打印头模块在X轴和Y轴两个方向的移动位置、移动速度和移动加速度;所述打印头模块运动控制模块还包括位置传感器,所述位置传感器与所述控制器实时通信。Further, the print head module motion control module is configured to control the moving position of the print head module in the two directions of the X axis and the Y axis according to the machining code information of the model to be printed generated by the host control system, Moving speed and moving acceleration; the print head module motion control module also includes a position sensor, and the position sensor communicates with the controller in real time.
进一步地,所述载物台运动控制模块被配置为根据待打印模型所生成的机加工代码信息控制载物台在Z轴方向的移动位置、移动速度和移动加速度;所述载物台运动控制模块还包括位置传感器,所述位置传感器与所述控制器实时通信。Further, the motion control module of the stage is configured to control the moving position, speed and acceleration of the stage in the Z-axis direction according to the machining code information generated by the model to be printed; the motion control module of the stage The module also includes a position sensor in real-time communication with the controller.
进一步地,所述打印头切换机构控制模块被配置为根据待打印模型所需要的打印材料控制打印头切换机构运动,包括旋转打印头架,使所需要的打印头移动到工作位置;所述打印头切换机构控制模块还包括位置传感器,所述位置传感器与所述控制器实时通信。Further, the print head switching mechanism control module is configured to control the movement of the print head switching mechanism according to the printing materials required by the model to be printed, including rotating the print head frame to move the required print head to the working position; the printing The head switching mechanism control module also includes a position sensor in real-time communication with the controller.
进一步地,所述打印头控制模块被配置为采集传感器数据并控制打印头的执行器在需要的时刻的运动。Further, the print head control module is configured to collect sensor data and control the movement of the actuator of the print head at the desired moment.
进一步地,所述自动控制模块的数据通信方式采用Modbus协议下的RS485通讯总线。Further, the data communication mode of the automatic control module adopts the RS485 communication bus under the Modbus protocol.
本发明还提供了一种液态物堆积3D打印方法,包括以下步骤:The present invention also provides a liquid object accumulation 3D printing method, comprising the following steps:
S100、提供如权利要求1-13任意一种多材料3D打印机;S100, providing a multi-material 3D printer according to any one of claims 1-13;
S101、上位控制系统根据待打印模型的信息和用户的精度要求,首先将模型划分成若干层,然后根据材料和加工需要选择相对应的打印头,并规划此打印头对应的运动路径;S101. The upper control system first divides the model into several layers according to the information of the model to be printed and the accuracy requirements of the user, and then selects the corresponding print head according to the material and processing needs, and plans the corresponding movement path of the print head;
S102、自动控制模块根据上位控制系统生成的数据执行相应的动作,采集3D打印机上安装的传感器的测量数据。S102. The automatic control module executes corresponding actions according to the data generated by the host control system, and collects measurement data of sensors installed on the 3D printer.
进一步地,所述步骤S101进一步包括以下步骤:Further, the step S101 further includes the following steps:
S101A、上位控制系统根据打印工艺要求,设计打印头的工作参数、设计打印头的进给率、设计启动打印头切换机构的时间和旋转角度。S101A. The host control system designs the working parameters of the printing head, the feeding rate of the printing head, the time and the rotation angle of starting the switching mechanism of the printing head according to the requirements of the printing process.
进一步地,所述步骤S102进一步包括以下步骤:Further, the step S102 further includes the following steps:
S102A、根据层片数据控制Z轴单轴移动模块驱动载物台至产品的各层对应位置;根据所需要的打印头数据驱动打印头切换机构旋转打印头架到指定角度,使得所需要的打印头到达工作位置;S102A. Control the Z-axis single-axis moving module to drive the stage to the corresponding position of each layer of the product according to the layer data; drive the print head switching mechanism to rotate the print head frame to the specified angle according to the required print head data, so that the required print The head reaches the working position;
S102B、当打印头就位后,根据所规划的运动控制信息控制X轴单轴移动模块和Y轴单轴移动模块驱动打印头模块到达指定的位置,同时控制打印头以所设计的方式执行物料喷出/挤出作业或者控制后处理加工装置对已经打印完的材料进行再加工;S102B. When the print head is in place, control the X-axis single-axis movement module and the Y-axis single-axis movement module to drive the print head module to the designated position according to the planned motion control information, and at the same time control the print head to execute the material in the designed way Jetting/extrusion operations or controlling post-processing processing devices to reprocess printed materials;
S102C、对下一个打印头重复驱动打印头切换机构运动、驱动X轴单轴移动模块和Y轴单轴移动模块运动、控制打印头执行物料喷出/挤出或再加工步骤;S102C, repeatedly driving the movement of the printing head switching mechanism for the next printing head, driving the movement of the X-axis single-axis moving module and the Y-axis single-axis moving module, and controlling the printing head to perform material ejection/extrusion or reprocessing steps;
S102D、对所有层都重复执行前述步骤。S102D. Repeat the foregoing steps for all layers.
进一步地,所述液态物是指熔融温度在50℃~400℃之间的热塑性材料。Further, the liquid substance refers to a thermoplastic material with a melting temperature between 50°C and 400°C.
进一步地,所述液态物是指液态化合物或液态混合物。Further, the liquid substance refers to a liquid compound or a liquid mixture.
本发明提供一种多材料3D打印机,实现多材料混合3D打印,从而实现更加自由的打印组合方式,扩充模型的原材料选择范围。本发明的打印机采用的基本打印方法是液态物堆积打印方法。The present invention provides a multi-material 3D printer, which realizes multi-material mixed 3D printing, thereby realizing a more free printing combination mode and expanding the selection range of raw materials for models. The basic printing method adopted by the printer of the present invention is a liquid accumulation printing method.
本发明提供的多材料3D打印机,包括机架、载物台、X轴单轴移动模块、Y轴单轴移动模块、Z轴单轴移动模块、打印头切换机构、打印头架、打印头、上位控制系统、自动控制模块。The multi-material 3D printer provided by the present invention includes a frame, an object stage, an X-axis single-axis moving module, a Y-axis single-axis moving module, a Z-axis single-axis moving module, a print head switching mechanism, a print head frame, a print head, Host control system, automatic control module.
所述Y轴单轴移动模块安装在机架上,可以沿Y轴方向运动,实现3D打印机打印头模块(打印头切换机构、打印头架和打印头的组合)Y轴方向的自由度。所述X轴单轴移动模块横跨安装在Y轴单轴移动模块和机架上,可以沿X轴方向运动,实现3D打印机打印头模块X轴方向的自由度。所述Z轴单轴移动模块安装在机架上,可以沿Z轴方向运动,实现3D打印机载物台Z轴方向的自由度。X轴,Y轴和Z轴三轴构成笛卡尔空间直角坐标系,给予打印头模块三个自由度。The Y-axis single-axis moving module is installed on the frame and can move along the Y-axis direction to realize the degree of freedom in the Y-axis direction of the 3D printer print head module (the combination of the print head switching mechanism, the print head frame and the print head). The X-axis single-axis moving module is installed across the Y-axis single-axis moving module and the frame, and can move along the X-axis direction to realize the degree of freedom of the 3D printer print head module in the X-axis direction. The Z-axis single-axis moving module is installed on the frame and can move along the Z-axis direction to realize the degree of freedom of the 3D printer stage in the Z-axis direction. The X-axis, Y-axis and Z-axis form a Cartesian space Cartesian coordinate system, giving the print head module three degrees of freedom.
所述载物台的一端固定于Z轴单轴移动模块上,另一端固定在一可以上下滑动的花键上,滑动花键的导轨两端固定在机架上。通过对载物台两端的固定,减少了挠度,提高了载物台的稳定性和Z轴移动精度。一般的3D打印机载物台设计方式为一端固定,当载物台自身较重或者打印模型较重时,所引起的挠度较大,造成打印精度和打印稳定性的下降。所述与机架连接的机构均通过凹槽与螺栓固定连接。One end of the stage is fixed on the Z-axis single-axis moving module, the other end is fixed on a spline that can slide up and down, and the two ends of the guide rail of the sliding spline are fixed on the frame. By fixing both ends of the stage, the deflection is reduced, and the stability of the stage and the movement precision of the Z axis are improved. The general 3D printer stage is designed to be fixed at one end. When the stage itself is heavy or the printed model is heavy, the resulting deflection is large, resulting in a decline in printing accuracy and printing stability. The mechanisms connected with the frame are fixedly connected with bolts through grooves.
在本发明所述的多材料3D打印机中,所述打印头模块包括:打印头切换机构、打印头架和打印头。其固定设置于X轴单轴移动模块上。In the multi-material 3D printer of the present invention, the print head module includes: a print head switching mechanism, a print head frame and a print head. It is fixedly arranged on the X-axis single-axis moving module.
在本发明所述的多材料3D打印机中,所述打印头切换机构由一台步进电机驱动,电机轴通过皮带轮带动打印头架旋转。In the multi-material 3D printer of the present invention, the print head switching mechanism is driven by a stepping motor, and the motor shaft drives the print head frame to rotate through a pulley.
在本发明所述的多材料3D打印机中,所述打印头架上可以安装多个打印头,使用打印头切换机构旋转打印头架,从而切换工作打印头。打印头架上有固定孔位,可以通过夹具固定打印头。In the multi-material 3D printer of the present invention, multiple print heads can be installed on the print head frame, and the print head switch mechanism is used to rotate the print head frame to switch the working print heads. There are fixed holes on the print head frame, and the print head can be fixed by a clamp.
在本发明所述的多材料3D打印机中,所述的不同打印头内可根据打印需要放置不同/相同的打印材料,从而实现多材料的3D打印。针对所打印的材料的特性需要使用基于不同原理或者特殊规格的打印头。In the multi-material 3D printer of the present invention, different/same printing materials can be placed in the different printing heads according to printing requirements, so as to realize multi-material 3D printing. The characteristics of the material to be printed require the use of print heads based on different principles or special specifications.
优选地,所述的打印头不仅限于是喷出/挤出物料的装置,也可以是一种对物料进行后处理加工的装置。Preferably, the printing head is not limited to a device for ejecting/extruding materials, but also a device for post-processing materials.
在本发明所述的多材料3D打印机中,所述上位控制系统以计算机为核心,可对模型文件进行预处理,生成待打印模型的机加工代码信息,通过数据线传输给自动控制模块。In the multi-material 3D printer of the present invention, the host control system takes a computer as the core, and can preprocess the model file to generate machining code information of the model to be printed, and transmit it to the automatic control module through the data line.
在本发明所述的多材料3D打印机中,所述自动控制模块用于系统性地控制整个多材料3D打印机各机构的运动和采集数据。根据控制对象进行分类,整个自动控制模块分为五个个子模块:控制器、打印头模块运动控制模块、载物台运动控制模块、打印头切换机构控制模块和打印头控制模块。其中,所述控制器作为整个自动控制模块的核心,对所有数据进行运算处理,并与所有控制对象通讯连接。所述打印头模块运动控制模块根据上位控制系统生成的待打印模型的机加工代码信息,控制打印头模块在X轴和Y轴两个方向的移动位置、移动速度和移动加速度;同时,该控制模块中还包含位置传感器与控制器实时通信从而提高运动控制的精确度。所述载物台运动控制模块根据待打印模型所生成的加工代码信息控制载物台在Z轴方向的移动位置、移动速度和移动加速度;同时,该控制模块中也包含位置传感器与控制器实时通信从而提高运动控制的精确度。所述打印头切换机构控制模块根据待打印模型所需要的打印材料控制打印头切换机构运动,从而旋转打印头架,使所需要的打印头移动到工作位置;同时,该控制模块中也包含位置传感器与控制器实时通信从而提高打印头的位置精确度。所述打印头控制模块用于控制打印头,控制方式取决于打印头的种类,这里的打印头喷出/挤出物料的例子包括但不限于电磁喷出式、压电喷出式、气压喷出式、活塞挤出式、螺旋挤出式;如果需要对物料进行后处理,这里的打印头的例子包括但不仅限于紫外线激光器、红外线激光器、强力喷风枪。无论采取那种方式,所述打印头控制模块采集相关传感器数据(如果有的情况下)并控制打印头的执行器在需要的时刻的运动。In the multi-material 3D printer of the present invention, the automatic control module is used to systematically control the movement and collect data of each mechanism of the entire multi-material 3D printer. Classified according to the control objects, the entire automatic control module is divided into five sub-modules: controller, print head module motion control module, stage motion control module, print head switching mechanism control module and print head control module. Wherein, the controller, as the core of the entire automatic control module, performs operations on all data and communicates with all control objects. The print head module motion control module controls the moving position, moving speed and moving acceleration of the printing head module in the two directions of the X axis and the Y axis according to the machining code information of the model to be printed generated by the host control system; at the same time, the control The module also includes a position sensor to communicate with the controller in real time to improve the accuracy of motion control. The movement control module of the stage controls the moving position, moving speed and moving acceleration of the carrying stage in the Z-axis direction according to the processing code information generated by the model to be printed; meanwhile, the control module also includes a position sensor and a real-time communication to improve the accuracy of motion control. The print head switching mechanism control module controls the movement of the print head switching mechanism according to the printing materials required by the model to be printed, thereby rotating the print head frame and moving the required print head to the working position; at the same time, the control module also includes position The sensor communicates with the controller in real time to improve the positional accuracy of the print head. The print head control module is used to control the print head, and the control method depends on the type of the print head. Examples of materials ejected/extruded by the print head include but are not limited to electromagnetic ejection, piezoelectric ejection, air pressure ejection, etc. Extrusion type, piston extrusion type, screw extrusion type; if post-processing of materials is required, examples of print heads here include but not limited to ultraviolet lasers, infrared lasers, powerful air spray guns. Either way, the printhead control module collects relevant sensor data (if any) and controls the movement of the printhead's actuators at the desired moment.
优选地,本发明所述的自动控制模块的数据通信方式采用Modbus协议下的RS485通讯总线。Preferably, the data communication mode of the automatic control module of the present invention adopts the RS485 communication bus under the Modbus protocol.
本发明还提供了一种液态物堆积打印方法,这里的液态物是指两种打印材料:热塑性材料,熔融温度在45℃~400℃之间;以及,液态化合物/液态混合物(包括:浊液,溶液,胶体)。该打印方法包括以下步骤:The present invention also provides a method for accumulating and printing liquid objects, where the liquid objects refer to two types of printing materials: thermoplastic materials with a melting temperature between 45°C and 400°C; and liquid compounds/liquid mixtures (including: turbid liquid , solution, colloid). The printing method includes the following steps:
S101,上位控制系统根据待打印模型的信息和用户的精度要求,首先将模型划分成若干层,然后依据工艺要求设计打印路径:根据材料和加工需要选择相对应的打印头,并规划此打印头对应的运动路径。最后将生成的数据传输给自动控制模块;S101, the host control system first divides the model into several layers according to the information of the model to be printed and the accuracy requirements of the user, and then designs the printing path according to the process requirements: select the corresponding print head according to the material and processing needs, and plan the print head corresponding movement path. Finally, the generated data is transmitted to the automatic control module;
S102,自动控制模块根据上位控制系统生成的数据执行相应的动作。首先,根据层片数据控制Z轴单轴移动模块驱动载物台至产品的各层对应位置;根据所需要的打印头数据驱动打印头切换机构旋转打印头架到指定角度,使得所需要的打印头到达工作位置;当打印头就位后,根据所规划的运动控制信息(位置、速度和加速度)控制X轴单轴移动模块和Y轴单轴移动模块驱动打印头模块到达指定的位置,同时控制打印头以所设计的方式执行物料喷出/挤出作业或者控制后处理装置对已经打印完的材料进行再加工;对下一个打印头重复驱动打印头切换机构运动、驱动X轴单轴移动模块和Y轴单轴移动模块运动、控制打印头执行物料喷出/挤出或再加工三个步骤,从而完成对该层的打印;对所有层都重复执行前述步骤,从而完成该产品的打印。S102, the automatic control module executes corresponding actions according to the data generated by the host control system. First, control the Z-axis single-axis moving module to drive the stage to the corresponding position of each layer of the product according to the layer data; drive the print head switching mechanism to rotate the print head frame to the specified angle according to the required print head data, so that the required print The head reaches the working position; when the print head is in place, control the X-axis single-axis movement module and the Y-axis single-axis movement module to drive the print head module to the specified position according to the planned motion control information (position, speed and acceleration), and at the same time Control the print head to execute material ejection/extrusion in the designed way or control the post-processing device to reprocess the printed material; repeatedly drive the movement of the print head switching mechanism for the next print head, and drive the X-axis single-axis movement Module and Y-axis single-axis movement Module movement, control of the print head to perform material ejection/extrusion or reprocessing three steps to complete the printing of this layer; repeat the above steps for all layers to complete the printing of this product .
在本发明所述的液态物堆积打印方法中,在所述步骤S101中,还包括以下步骤:In the method for accumulating and printing liquid objects according to the present invention, in the step S101, the following steps are further included:
上位控制系统根据打印工艺要求(待打印材料的加工特性),设计打印头的工作参数;The upper control system designs the working parameters of the print head according to the printing process requirements (processing characteristics of the material to be printed);
上位控制系统根据打印工艺要求(物料的粗细),设计打印头的进给率;The upper control system designs the feed rate of the print head according to the printing process requirements (material thickness);
上位控制系统根据打印工艺要求(何时应当选择何种打印头工作),设计启动打印头切换机构的时间和旋转角度。The host control system designs the time and rotation angle for starting the print head switching mechanism according to the printing process requirements (when and which print head should be selected to work).
在本发明所述的液态物堆积打印方法中,在所述步骤S102中,还包括以下步骤:In the method for accumulating and printing liquid objects according to the present invention, in the step S102, the following steps are further included:
采集3D打印机上安装的各类传感器的测量数据,包括XYZ三轴的位置传感器、打印头切换机构的位置传感器和打印头上安装的各类传感器。Collect the measurement data of various sensors installed on the 3D printer, including the XYZ three-axis position sensor, the position sensor of the print head switching mechanism, and various sensors installed on the print head.
基于本发明所提出的多材料3D打印机和液态物堆积打印方法,可以进行如下打印操作,以突破目前3D打印技术遇到的两大瓶颈:Based on the multi-material 3D printer and liquid accumulation printing method proposed by the present invention, the following printing operations can be performed to break through the two major bottlenecks encountered by the current 3D printing technology:
其一,通过先使用热塑性材料打印出具有复杂空间结构的容器,在每一层容器构造完成后,将低粘度液态物填充在其中,之后逐层如此,层层叠加,从而精确控制低粘度液态物的空间构型。First, by using thermoplastic materials to print out a container with a complex spatial structure, after the construction of each layer of container is completed, the low-viscosity liquid is filled in it, and then layer by layer, layer by layer, so as to precisely control the low-viscosity liquid The spatial configuration of objects.
其二,通过在打印头架上设置材料后处理打印头,在每一层需要后处理的材料打印完后,将打印头架切换到后处理打印头上,对材料进行进一步加工,从而解决3D材料打印过程中的后处理难题,有效拓宽可打印3D打印材料的种类。Second, by setting the material post-processing print head on the print head frame, after each layer of material that needs post-processing is printed, the print head frame is switched to the post-processing print head to further process the material, thereby solving the problem of 3D printing. The post-processing problems in the material printing process effectively broaden the types of 3D printing materials that can be printed.
本发明所述的多材料3D打印机及液态物堆积打印方法将单材料3D打印技术拓展到多材料3D打印领域;多材料3D打印机运行可靠、精度高;在3D打印的同时可以对材料进行再加工;可以实现低粘度液态物的3D打印。The multi-material 3D printer and liquid object accumulation printing method described in the present invention expand the single-material 3D printing technology to the field of multi-material 3D printing; the multi-material 3D printer operates reliably and has high precision; materials can be reprocessed while 3D printing ; 3D printing of low-viscosity liquids can be realized.
以下将结合附图对本发明的构思、具体结构及产生的技术效果作进一步说明,以充分地了解本发明的目的、特征和效果。The idea, specific structure and technical effects of the present invention will be further described below in conjunction with the accompanying drawings, so as to fully understand the purpose, features and effects of the present invention.
附图说明Description of drawings
图1是本发明的一个较佳实施例的多材料3D打印机立体结构示意图;Fig. 1 is a schematic diagram of the three-dimensional structure of a multi-material 3D printer according to a preferred embodiment of the present invention;
图2是本发明液态物堆积打印方法的第一实施例中PCL材料的加工示意图;Fig. 2 is a schematic diagram of the processing of PCL materials in the first embodiment of the liquid object accumulation printing method of the present invention;
图3是本发明液态物堆积打印方法的第一实施例中水凝胶材料的加工示意图;Fig. 3 is a schematic diagram of the processing of the hydrogel material in the first embodiment of the liquid object accumulation printing method of the present invention;
图4是本发明液态物堆积打印方法的第一实施例中培养混合液的加工示意图;Fig. 4 is a schematic diagram of the processing of the culture mixture in the first embodiment of the liquid object accumulation printing method of the present invention;
图5是本发明液态物堆积打印方法的第二实施例中硅胶支撑材料的打印示意图;Fig. 5 is a schematic diagram of the printing of the silica gel support material in the second embodiment of the liquid object accumulation printing method of the present invention;
图6是本发明液态物堆积打印方法的第二实施例中硅胶材料的打印示意图;Fig. 6 is a schematic diagram of the printing of the silica gel material in the second embodiment of the liquid object accumulation printing method of the present invention;
图7是本发明液态物堆积打印方法的第二实施例中紫外线发射器的加工示意图;Fig. 7 is a schematic diagram of the processing of the ultraviolet emitter in the second embodiment of the liquid object accumulation printing method of the present invention;
图8是本发明液态物堆积打印方法的第二实施例中除去支撑材料后的打印成品。Fig. 8 is the printed product after removing the support material in the second embodiment of the liquid object accumulation printing method of the present invention.
具体实施方式detailed description
以下各实施例的说明是参考附加的图式,用以例示本发明可用以实施的特定实施例。本发明所提到的方向用语,例如[上][下][前][后][左][右][内][外][侧面]等,仅是参考附加图式的方向。因此,使用的方向用语是用以说明及理解本发明,而非用以限制本发明。The following descriptions of the various embodiments refer to the accompanying drawings to illustrate specific embodiments in which the present invention can be practiced. The directional terms mentioned in the present invention, such as [top] [bottom] [front] [back] [left] [right] [inside] [outside] [side], etc., are only referring to the directions of the attached drawings. Therefore, the directional terms used are used to illustrate and understand the present invention, but not to limit the present invention.
如图1所示,本发明优选实施例的多材料3D打印机,包括机架109、载物台107、X轴单轴移动模块102、Y轴单轴移动模块103、Z轴单轴移动模块101、打印头切换机构105、打印头切换机构的动力源104、打印头架106、打印头110和111和112、上位控制系统(未示出)、自动控制模块(未示出)。X轴单轴移动模块102、Y轴单轴移动模块103和Z轴单轴移动模块传动部件采用丝纹螺杆,用步进电机驱动,移动精度达到0.1mm,整个设备结构精简可靠,打印精度高。Y轴单轴移动模块103安装在机架109上,实现3D打印机打印头模块(打印头切换机构105、打印头架106和打印头110的组合)Y轴方向的自由度。打印头模块包括固定设置于X轴单轴移动模块102上,打印头切换机构105由一台步进电机104驱动,电机轴通过皮带轮带动打印头106架旋转。X轴单轴移动模块102横跨安装在Y轴单轴移动模块103和机架109上,实现3D打印机打印头模块X轴方向的自由度。所述Z轴单轴移动模块101安装在机架109上,实现3D打印机载物台107在Z轴方向的自由度。X轴,Y轴和Z轴三轴构成笛卡尔空间直角坐标系,给予打印头模块三个自由度。载物台107的一端固定于Z轴单轴移动模块101上,另一端固定在一可以上下滑动的花键108上,滑动花键108的导轨两端固定在机架109上。通过对载物台107两端的固定,减少了挠度,提高了载物台107的稳定性和Z轴移动精度。As shown in Figure 1, the multi-material 3D printer of the preferred embodiment of the present invention includes a frame 109, an object stage 107, an X-axis single-axis movement module 102, a Y-axis single-axis movement module 103, and a Z-axis single-axis movement module 101 , the print head switching mechanism 105, the power source 104 of the print head switching mechanism, the print head frame 106, the print heads 110 and 111 and 112, the host control system (not shown), the automatic control module (not shown). X-axis single-axis moving module 102, Y-axis single-axis moving module 103, and Z-axis single-axis moving module transmission parts adopt threaded screws, driven by stepping motors, and the moving accuracy reaches 0.1mm. The whole equipment structure is simple and reliable, and the printing accuracy is high. . The Y-axis single-axis moving module 103 is installed on the frame 109 to realize the degree of freedom in the Y-axis direction of the 3D printer print head module (the combination of the print head switching mechanism 105, the print head frame 106 and the print head 110). The print head module includes a fixed X-axis single-axis moving module 102, the print head switching mechanism 105 is driven by a stepping motor 104, and the motor shaft drives the print head 106 to rotate through a pulley. The X-axis single-axis moving module 102 is installed across the Y-axis single-axis moving module 103 and the frame 109 to realize the degree of freedom of the 3D printer print head module in the X-axis direction. The Z-axis single-axis movement module 101 is installed on the frame 109 to realize the degree of freedom of the 3D printer stage 107 in the Z-axis direction. The X-axis, Y-axis and Z-axis form a Cartesian space Cartesian coordinate system, giving the print head module three degrees of freedom. One end of the stage 107 is fixed on the Z-axis single-axis moving module 101 , the other end is fixed on a spline 108 that can slide up and down, and the two ends of the guide rail of the sliding spline 108 are fixed on the frame 109 . By fixing both ends of the object stage 107, the deflection is reduced, and the stability of the object stage 107 and the Z-axis movement precision are improved.
在本实施例中,打印头架106上安装了三个打印头110、111和112,使用打印头切换机构105旋转打印头架106,从而切换工作打印头。打印头架106上有固定孔位,通过内六角螺丝固定打印头。如图1所示,打印头112是FDM式的打印头,所用打印材料为PCL线材;打印头111是电机驱动的活塞挤出式打印头,所用打印材料是包埋了活细胞的水凝胶;打印头110是气压喷出式的打印头(气压调整模块未示出),所用打印材料是包含了生化环境调节剂和营养物质的培养基。不同材料和不同原理的打印头共同实现了多材料的3D打印。这三个打印头将采用液态物堆积打印方法打印,也构成了液态物堆积打印方法的第一实施例。如果打印头112采用FDM式打印头,所用材料改为3DSystems公司的InfinityTMRinse-Away水溶性支撑材料;打印头111采用气压挤出式的打印头,打印材料用含光引发剂的液态硅胶;打印头110改为紫外线发射器,那么采用液态物堆积打印方法打印就构成了液态物堆积打印方法的第二实施例。In this embodiment, three printheads 110 , 111 and 112 are installed on the printhead frame 106 , and the printhead switching mechanism 105 is used to rotate the printhead frame 106 to switch the working printheads. There are fixing holes on the print head frame 106, and the print head is fixed by hexagon socket head screws. As shown in Figure 1, the print head 112 is an FDM print head, and the printing material used is a PCL wire; the print head 111 is a motor-driven piston extrusion print head, and the printing material used is a hydrogel embedded with living cells ; The print head 110 is an air pressure ejection type print head (the air pressure adjustment module is not shown), and the printing material used is a medium containing biochemical environment regulators and nutrients. Print heads with different materials and different principles jointly realize multi-material 3D printing. These three print heads will use the liquid object accumulation printing method to print, and also constitute the first embodiment of the liquid object accumulation printing method. If the print head 112 adopts an FDM print head, the material used is changed to the Infinity TM Rinse-Away water-soluble support material of 3DSystems; the print head 111 adopts a pneumatic extrusion print head, and the printing material is liquid silica gel containing a photoinitiator; If the print head 110 is changed to an ultraviolet emitter, then printing by using the liquid accumulation printing method constitutes the second embodiment of the liquid accumulation printing method.
上位控制系统(未示出)以计算机为核心,可对模型文件进行预处理,生成待打印模型的机加工代码信息,通过数据线传输给自动控制模块(未示出)。The host control system (not shown) takes the computer as the core, and can preprocess the model file to generate the machining code information of the model to be printed, and transmit it to the automatic control module (not shown) through the data line.
其中,自动控制模块(未示出)可以系统性地控制整个多材料3D打印机各机构的运动和采集数据。根据控制对象进行分类,整个自动控制模块分为五个个子模块:控制器、打印头模块运动控制模块、载物台运动控制模块、打印头切换机构控制模块和打印头控制模块。控制器作为整个自动控制模块的核心,对所有数据进行运算处理,并与所有控制对象通讯连接。打印头模块运动控制模块根据上位控制系统生成的待打印模型的机加工代码信息,控制X轴单轴移动模块102和Y轴单轴移动模块103上的电机,驱动模块中的丝杠运动从而带动打印头模块105、106、110、111、112在X轴和Y轴两个方向的移动位置、移动速度和移动加速度;同时,该控制模块中还会采集X轴单轴移动模块102和Y轴单轴移动模块103上的位置传感器的数据,并与控制器实时通信从而提高运动控制的精确度。载物台运动控制模块根据待打印模型所生成的加工代码信息,控制Z轴单轴移动模块101上的电机,驱动模块中的丝杠运动,从而控制载物台107在Z轴方向的移动位置、移动速度和移动加速度;同时,该控制模块中还会采集Z轴单轴移动模块101上的位置传感器的数据,并与控制器实时通信从而提高运动控制的精确度。打印头切换机构控制模块根据待打印模型所需要的打印材料控制打印头切换机构105的动力源104电机转动,用皮带轮带动一根与打印头架106连接的轴转动,从而旋转打印头架106,使所需要的打印头110或111或112转动到工作位置,这里的轴与固定在支架上的轴承相连接;同时,在打印头架106上装有位置传感器,与控制器实时通信从而采集打印头架106的旋转位置信息,提高打印头的位置精确度。Wherein, the automatic control module (not shown) can systematically control the movement and collect data of each mechanism of the entire multi-material 3D printer. Classified according to the control objects, the entire automatic control module is divided into five sub-modules: controller, print head module motion control module, stage motion control module, print head switching mechanism control module and print head control module. As the core of the entire automatic control module, the controller performs operations on all data and communicates with all control objects. The print head module motion control module controls the motors on the X-axis single-axis moving module 102 and the Y-axis single-axis moving module 103 according to the machining code information of the model to be printed generated by the upper control system, and drives the lead screw in the module to move to drive The moving positions, moving speeds and moving accelerations of the print head modules 105, 106, 110, 111, and 112 in the two directions of the X-axis and the Y-axis; at the same time, the control module also collects the X-axis single-axis moving module 102 and the Y-axis The data of the position sensor on the single-axis movement module 103 is communicated with the controller in real time to improve the accuracy of motion control. The stage motion control module controls the motor on the Z-axis single-axis movement module 101 according to the processing code information generated by the model to be printed, and drives the lead screw in the module to move, thereby controlling the moving position of the stage 107 in the Z-axis direction , moving speed and moving acceleration; at the same time, the control module will also collect the data of the position sensor on the Z-axis single-axis moving module 101, and communicate with the controller in real time so as to improve the accuracy of motion control. The print head switching mechanism control module controls the power source 104 motor of the print head switching mechanism 105 to rotate according to the printing material required by the model to be printed, and drives a shaft connected to the print head frame 106 to rotate with a belt pulley, thereby rotating the print head frame 106, Make the required print head 110 or 111 or 112 rotate to the working position, where the shaft is connected with the bearing fixed on the bracket; at the same time, a position sensor is installed on the print head frame 106, which communicates with the controller in real time to collect the print head The rotation position information of the frame 106 improves the position accuracy of the print head.
打印头控制模块将根据上位控制系统生成的加工代码信息在需要的时刻进行打印头的运动控制和数据采集。如图1所示,在液态物堆积打印方法的第一实施例中,打印头112是FDM式打印头,打印头控制模块将控制一步进电机运动,将所需打印的热塑性PLC丝材送入高温熔融室,熔融室在电热丝加热下达到高温(60℃),将丝材从固态变为流动态,经过电机的压力从喷嘴挤出,在这个过程中,打印头控制模块不断采集熔融室内安装的热电阻温度传感器的数据,构成PID闭环控制提高温度控制精度;打印头111是电机驱动的活塞挤出式打印头,打印头控制模块将控制一步进电机运动,推动一个活塞在打印材料容器内移动,从而挤出水凝胶,容器壁上均匀分布电热丝,容器壁四周对称分布四个温度传感器,打印头控制模块不断采集温度传感器数据对电热丝进行通断电控制,从而使得容器保持一定温度,保证凝胶的流动性和温度环境;打印头110是气压喷出式的打印头(气压调整模块未示出),其上装有一电控式的气压调整装置,气压调整装置的空气出口联通到装有打印材料的容器,打印头控制模块控制容器内的气压大小,实现物料的喷出作业。在液态物堆积打印方法的第二实施例中,打印头112是FDM式打印头,打印头结构、打印原理和控制方式如前所述,这里不再赘述;打印头111是电机驱动的活塞挤出式打印头,打印头结构、打印原理和控制方式如前所述,这里不再赘述;打印头110是一个紫外线发射器,打印头控制模块控制该发射器电源的通断。The print head control module will carry out the motion control and data collection of the print head when needed according to the processing code information generated by the host control system. As shown in Figure 1, in the first embodiment of the method for accumulating and printing liquid objects, the print head 112 is an FDM print head, and the print head control module will control the movement of a stepping motor to send the desired printed thermoplastic PLC wire to the Entering the high-temperature melting chamber, the melting chamber reaches a high temperature (60°C) under the heating of the electric heating wire, changing the filament from solid to fluid state, and extruding from the nozzle through the pressure of the motor. During this process, the print head control module continuously collects and melts The data of the thermal resistance temperature sensor installed in the room constitutes a PID closed-loop control to improve the temperature control accuracy; the print head 111 is a motor-driven piston extrusion print head, and the print head control module will control the movement of the stepping motor to push a piston to print The material container moves to extrude the hydrogel. The heating wire is evenly distributed on the container wall, and four temperature sensors are symmetrically distributed around the container wall. The print head control module continuously collects the temperature sensor data to control the heating wire on and off, so that The container maintains a certain temperature to ensure the fluidity and temperature environment of the gel; the print head 110 is an air pressure ejection type print head (the air pressure adjustment module is not shown), and an electronically controlled air pressure adjustment device is housed on it. The air outlet is connected to the container containing the printing material, and the print head control module controls the air pressure in the container to realize the ejection of the material. In the second embodiment of the liquid accumulation printing method, the print head 112 is an FDM print head, and the structure, printing principle and control mode of the print head are as described above, and will not be repeated here; the print head 111 is a motor-driven piston squeezer. The output type print head, the print head structure, printing principle and control method are as mentioned above, and will not be repeated here; the print head 110 is an ultraviolet emitter, and the print head control module controls the power on and off of the emitter.
优选地,自动控制模块的数据通信方式采用Modbus协议下的RS485通讯总线。Preferably, the data communication mode of the automatic control module adopts the RS485 communication bus under the Modbus protocol.
本发明还提供了一种液态物堆积打印方法,这里的液态物是指两种打印材料:一,热塑性材料,熔融温度在45℃~400℃之间。二,液态化合物/液态混合物(包括:浊液,溶液,胶体)。The present invention also provides a method for accumulating and printing liquid objects, where the liquid objects refer to two kinds of printing materials: 1. thermoplastic materials, the melting temperature of which is between 45°C and 400°C. Second, liquid compounds/liquid mixtures (including: turbid liquid, solution, colloid).
该打印方法包括以下步骤:The printing method includes the following steps:
S101,上位控制系统根据待打印模型的信息和用户的精度要求,首先将模型划分成若干层,然后依据工艺要求设计打印路径:根据材料和加工需要选择相对应的打印头110、111或112,并规划此打印头对应的运动路径。最后将生成的数据传输给自动控制模块;S101, the upper control system first divides the model into several layers according to the information of the model to be printed and the accuracy requirements of the user, and then designs the printing path according to the process requirements: select the corresponding print head 110, 111 or 112 according to the material and processing needs, And plan the motion path corresponding to this print head. Finally, the generated data is transmitted to the automatic control module;
S102,自动控制模块根据上位控制系统生成的数据执行相应的动作。首先,根据层片数据控制Z轴单轴移动模块101驱动载物台107至产品的各层对应位置;根据所需要的打印头110、111或112数据驱动打印头切换机构105旋转打印头架106到指定角度,使得所需要的打印头110、111或112到达工作位置;当打印头就位后,根据所规划的运动控制信息(位置、速度和加速度)控制X轴单轴移动模块102和Y轴单轴移动模块103驱动打印头模块到达指定的位置,同时控制打印头以所设计的方式执行物料喷出/挤出作业或者控制后处理装置对已经打印完的材料进行再加工;对下一个打印头重复驱动打印头切换机构运动、驱动X轴单轴移动模块和Y轴单轴移动模块运动、控制打印头执行物料喷出/挤出或再加工三个步骤,从而完成对该层的打印;对所有层都重复执行前述步骤,从而完成该产品的打印。S102, the automatic control module executes corresponding actions according to the data generated by the host control system. First, control the Z-axis single-axis moving module 101 to drive the stage 107 to the corresponding position of each layer of the product according to the layer data; drive the print head switching mechanism 105 to rotate the print head frame 106 according to the required print head 110, 111 or 112 data To the specified angle, so that the required print head 110, 111 or 112 reaches the working position; when the print head is in place, control the X-axis single-axis movement module 102 and Y according to the planned motion control information (position, speed and acceleration) The single-axis moving module 103 drives the print head module to the designated position, and at the same time controls the print head to perform material ejection/extrusion operations in the designed way or controls the post-processing device to reprocess the printed materials; for the next The printing head repeatedly drives the movement of the printing head switching mechanism, drives the movement of the X-axis single-axis moving module and the Y-axis single-axis moving module, and controls the printing head to perform three steps of material ejection/extrusion or reprocessing, so as to complete the printing of this layer ;repeat the preceding steps for all layers to complete the print for this product.
在本发明所述的液态物堆积打印方法中,在所述步骤S101中,还包括以下步骤:In the method for accumulating and printing liquid objects according to the present invention, in the step S101, the following steps are further included:
上位控制系统根据打印工艺要求(待打印材料的加工特性),设计打印头110、111或112的工作参数;The host control system designs the working parameters of the print head 110, 111 or 112 according to the printing process requirements (processing characteristics of the material to be printed);
上位控制系统根据打印工艺要求(物料的粗细),设计打印头110、111或112的进给率;The host control system designs the feed rate of the print head 110, 111 or 112 according to the printing process requirements (material thickness);
上位控制系统根据打印工艺要求(何时应当选择何种打印头工作),设计启动打印头切换机构105的时间和旋转角度。The host control system designs the time and rotation angle for starting the print head switching mechanism 105 according to the requirements of the printing process (when and which print head should be selected to work).
在本发明所述的液态物堆积打印方法中,在所述步骤S102中,还包括以下步骤:In the method for accumulating and printing liquid objects according to the present invention, in the step S102, the following steps are further included:
采集3D打印机上安装的各类传感器的测量数据,包括XYZ三轴的位置传感器、打印头切换机构的位置传感器和打印头上安装的各类传感器。Collect the measurement data of various sensors installed on the 3D printer, including the XYZ three-axis position sensor, the position sensor of the print head switching mechanism, and various sensors installed on the print head.
基于本发明所提出的多材料3D打印机和液态物堆积打印方法,可以进行如下打印操作,以突破目前3D打印技术遇到的两大瓶颈:Based on the multi-material 3D printer and liquid accumulation printing method proposed by the present invention, the following printing operations can be performed to break through the two major bottlenecks encountered by the current 3D printing technology:
其一,通过先使用热塑性材料打印出具有复杂空间结构的容器,在每一层容器构造完成后,将低粘度液态物填充在其中,之后逐层如此,层层叠加,从而精确控制低粘度液态物的空间构型。在此提出液态物堆积打印方法的第一实施例加以说明,如图2、图3、图4所示。在该实施例中,使用了PCL、包埋了活细胞的水凝胶、包含了生化环境调节剂和营养物质的培养基三种材料进行打印。先使用FDM式打印头991打印完全由PCL组成的第零层001,构成容器的底部,然后开始逐层打印多材料层第一层、第二层、第三层……直到最后。在每一单层的打印过程中,先用PCL材料打印,将外围封闭,内部再用其他材料填充。以第三层的打印为例,如图2所示,在该层完成PCL材料031的打印后,使用图1中的打印头切换机构105将工作打印头切换到水凝胶打印头992,如图3所示,开始打印水凝胶材料,将水凝胶032填充在PCL控制的空间构造031中。在该层完成水凝胶材料的打印后,使用图1中的打印头切换机构105将工作打印头切换到培养基打印头993,如图4所示,开始在包埋了活细胞的水凝胶中均匀打印包含了生化环境调节剂和营养物质的培养基033。另外,可以在图2中看到,第一层的011、第二层的021和第三层的031用PCL材料打印,将外围封闭,内部用其他打印头打印其他材料。第三层的内部也有PCL填充031,用以作为内部容器控制水凝胶和培养基的空间构型。在图2中还可以看到,之前打印完成的第二层的构造:PLC控制第二层的空间构型021,在空隙中填充水凝胶022,在水凝胶上喷洒培养基023。First, by using thermoplastic materials to print out a container with a complex spatial structure, after the construction of each layer of container is completed, the low-viscosity liquid is filled in it, and then layer by layer, layer by layer, so as to precisely control the low-viscosity liquid The spatial configuration of objects. The first embodiment of the liquid object accumulation printing method is proposed here for illustration, as shown in FIG. 2 , FIG. 3 , and FIG. 4 . In this embodiment, three materials are used for printing, PCL, hydrogel embedded with living cells, and culture medium containing biochemical environmental regulators and nutrients. First use the FDM print head 991 to print the zeroth layer 001, which is completely composed of PCL, to form the bottom of the container, and then start to print the first layer, the second layer, the third layer of the multi-material layer layer by layer... until the end. In the printing process of each single layer, the PCL material is used to print first, the periphery is closed, and the interior is filled with other materials. Take the printing of the third layer as an example, as shown in Figure 2, after the printing of the PCL material 031 is completed on this layer, use the print head switching mechanism 105 in Figure 1 to switch the working print head to the hydrogel print head 992, as As shown in Figure 3, the hydrogel material starts to be printed, and the hydrogel 032 is filled in the space structure 031 controlled by the PCL. After the printing of the hydrogel material is completed on this layer, use the printing head switching mechanism 105 in Fig. 1 to switch the working printing head to the medium printing head 993, as shown in Fig. Medium 033 containing biochemical environmental regulators and nutrients is uniformly printed in the glue. In addition, it can be seen in Figure 2 that the 011 of the first layer, the 021 of the second layer and the 031 of the third layer are printed with PCL materials, the periphery is closed, and other materials are printed with other print heads inside. The inside of the third layer is also filled with PCL 031, which is used as an inner container to control the spatial configuration of the hydrogel and the medium. It can also be seen in Figure 2 that the structure of the second layer printed before: PLC controls the spatial configuration 021 of the second layer, fills the hydrogel 022 in the gap, and sprays the medium 023 on the hydrogel.
其二,通过在打印头架上设置材料后处理打印头,在每一层需要后处理的材料打印完后,将打印头架切换到后处理打印头上,对材料进行进一步加工,从而解决3D材料打印过程中的后处理难题,有效拓宽可打印3D打印材料的种类。在此提出液态物堆积打印方法的第二实施例加以说明,如图5、图6、图7、图8所示。在该实施例中,使用了3DSystems公司的InfinityTMRinse-Away水溶性支撑材料、生胶[成分为:甲基乙烯基硅油、硅烷偶联剂、光引发剂二苯甲酮(BP)、MQ硅树脂、交联剂三烯丙基异氰脲酸酯(TAIC)]二种材料进行打印,并使用紫外线发射器进行硅胶的交联加工。先使用FDM式打印头991打印完全由水溶性支撑材料组成的第零层001,构成产品的底部,然后开始打印逐层多材料层第一层、第二层……直到最后。在每一单层的打印过程中,先用水溶性支撑材料打印,用以控制交联前成流动态的生胶的空间构型,然后打印生胶,最后使用紫外光发射器交联固化生胶。以第二层的打印为例,如图5所示,在该层完成水溶性支撑材料021的打印后,使用图1中的打印头切换机构105将工作打印头切换到生胶打印头992,如图6所示,开始打印生胶材料,将生胶032填充在水溶性支撑材料控制的空间构造021中。在该层完成生胶材料的打印后,使用图1中的打印头切换机构105将工作打印头切换到紫外线发射器打印头993,如图7所示,对生胶进行紫外线辐照,从而实现对生胶的交联,实现3D打印过程中的再加工。最后,用水洗去水溶性支撑材料,得到所要的硅胶产品,如图8所示。另外,在图5中可以看到,第一层011和第二层021使用了水溶性支撑材料打印。在图5中还可以看到,之前打印完成的第一层的构造:水溶性支撑材料控制第一层的空间构型011,在空隙中填充生胶012。Second, by setting the material post-processing print head on the print head frame, after each layer of material that needs post-processing is printed, the print head frame is switched to the post-processing print head to further process the material, thereby solving the problem of 3D printing. The post-processing problems in the material printing process effectively broaden the types of 3D printing materials that can be printed. A second embodiment of the method for accumulating and printing liquid objects is proposed here for illustration, as shown in FIG. 5 , FIG. 6 , FIG. 7 , and FIG. 8 . In this embodiment, the Infinity TM Rinse-Away water-soluble support material of 3DSystems company, raw rubber [ingredients are: methyl vinyl silicone oil, silane coupling agent, photoinitiator benzophenone (BP), MQ Silicone resin, cross-linking agent triallyl isocyanurate (TAIC)] two materials for printing, and use UV emitter for cross-linking of silicone. First use the FDM print head 991 to print the zeroth layer 001, which is completely composed of water-soluble support materials, to form the bottom of the product, and then start printing the first layer, the second layer... until the end. In the printing process of each single layer, the water-soluble support material is first printed to control the spatial configuration of the raw rubber before cross-linking, then the raw rubber is printed, and finally the UV light emitter is used to cross-link and cure the raw rubber. glue. Taking the printing of the second layer as an example, as shown in Figure 5, after the printing of the water-soluble support material 021 is completed on this layer, the working printing head is switched to the raw rubber printing head 992 by using the printing head switching mechanism 105 in Figure 1 , As shown in FIG. 6 , the raw rubber material is printed, and the raw rubber 032 is filled in the space structure 021 controlled by the water-soluble support material. After the raw rubber material is printed on this layer, use the print head switching mechanism 105 in Figure 1 to switch the working print head to the UV emitter print head 993, as shown in Figure 7, to irradiate the raw rubber with ultraviolet light, thereby realizing Cross-linking of raw rubber to realize reprocessing during 3D printing. Finally, the water-soluble support material is washed away with water to obtain the desired silica gel product, as shown in FIG. 8 . In addition, it can be seen in FIG. 5 that the first layer 011 and the second layer 021 are printed using water-soluble support materials. It can also be seen in Figure 5 that the structure of the first layer printed before: the water-soluble support material controls the spatial configuration 011 of the first layer, and raw rubber 012 is filled in the gaps.
以上详细描述了本发明的较佳具体实施例。应当理解,本领域的普通技术无需创造性劳动就可以根据本发明的构思作出诸多修改和变化。因此,凡本技术领域中技术人员依本发明的构思在现有技术的基础上通过逻辑分析、推理或者有限的实验可以得到的技术方案,皆应在由权利要求书所确定的保护范围内。The preferred specific embodiments of the present invention have been described in detail above. It should be understood that those skilled in the art can make many modifications and changes according to the concept of the present invention without creative efforts. Therefore, all technical solutions that can be obtained by those skilled in the art based on the concept of the present invention through logical analysis, reasoning or limited experiments on the basis of the prior art shall be within the scope of protection defined by the claims.
Claims (18)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611117769.7A CN106626358B (en) | 2016-12-07 | 2016-12-07 | A kind of multi-material 3D printer and liquid object accumulation 3D printing method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611117769.7A CN106626358B (en) | 2016-12-07 | 2016-12-07 | A kind of multi-material 3D printer and liquid object accumulation 3D printing method |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN106626358A true CN106626358A (en) | 2017-05-10 |
| CN106626358B CN106626358B (en) | 2019-08-06 |
Family
ID=58819371
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201611117769.7A Expired - Fee Related CN106626358B (en) | 2016-12-07 | 2016-12-07 | A kind of multi-material 3D printer and liquid object accumulation 3D printing method |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106626358B (en) |
Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107379516A (en) * | 2017-09-18 | 2017-11-24 | 合肥工业大学 | A kind of poroelasticity foam preparation method based on moisturecuring silica gel 3D printing |
| CN108414688A (en) * | 2018-03-05 | 2018-08-17 | 中南大学 | A kind of piston and pneumatic dual-purpose 3D printing biomaterial extrusion test device |
| CN108819237A (en) * | 2018-06-04 | 2018-11-16 | 江苏海事职业技术学院 | A kind of 3D printer and its Method of printing for the printing of indoor decorations model |
| CN108995209A (en) * | 2018-08-29 | 2018-12-14 | 深圳市合泰英龙科技有限公司 | A kind of full-automatic 3D insole printer |
| CN109228306A (en) * | 2018-09-05 | 2019-01-18 | 西安交通大学 | A kind of printer and Method of printing that write-through printing is combined with the printing of fused deposition formula |
| CN109703018A (en) * | 2019-02-25 | 2019-05-03 | 彭俊植 | It is a kind of without the comprehensive 3D printing system of support electromagnetic levitation type and method |
| CN109866430A (en) * | 2019-04-03 | 2019-06-11 | 江苏海之风科技有限公司 | It is a kind of for monitoring the monitoring system of printed material temperature |
| CN111872318A (en) * | 2020-06-29 | 2020-11-03 | 哈尔滨鼎智瑞光科技有限公司 | Sand core model for additive manufacturing by using liquid metal liquid |
| CN112008975A (en) * | 2020-08-25 | 2020-12-01 | 北京优思弗科技有限公司 | Multi-head cooperative 3D printing equipment and printing method |
| CN113733544A (en) * | 2021-08-10 | 2021-12-03 | 深圳市维智梅克科技有限公司 | Method and device for controlling 3D printer by using joystick and readable storage medium |
| CN115847811A (en) * | 2022-11-03 | 2023-03-28 | 青岛理工大学 | Continuous fiber composite material rotary structure multi-shaft integrated 3D printer and printing method thereof |
| CN115891171A (en) * | 2022-11-16 | 2023-04-04 | 哈尔滨工业大学 | A water-soluble support method for light-curing 3D printing |
| WO2024093329A1 (en) * | 2022-10-31 | 2024-05-10 | Syncord 3D Technology Limited | Apparatus and method for three-dimensional printing |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103231513A (en) * | 2013-04-01 | 2013-08-07 | 杭州笔水画王电子科技有限公司 | 3D printing method and 3D printer |
| CN203779869U (en) * | 2014-03-03 | 2014-08-20 | 常州晨凯快速制造技术有限公司 | Rapid laser forming machine |
| CN104175554A (en) * | 2014-07-24 | 2014-12-03 | 合肥斯科尔智能科技有限公司 | Three-dimensional printer with double injector heads working alternately |
| CN105252776A (en) * | 2015-11-19 | 2016-01-20 | 上海复志信息技术有限公司 | Desktop-level 3D printer |
| CN105500700A (en) * | 2014-12-30 | 2016-04-20 | 青岛智能产业技术研究院 | Three-dimensional color printing device and method |
| CN105563841A (en) * | 2016-02-26 | 2016-05-11 | 东莞劲胜精密组件股份有限公司 | A 3D printing manufacturing method and device for a porous three-dimensional component |
| GB2538522A (en) * | 2015-05-19 | 2016-11-23 | Dst Innovations Ltd | Electronic circuit and component construction |
-
2016
- 2016-12-07 CN CN201611117769.7A patent/CN106626358B/en not_active Expired - Fee Related
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103231513A (en) * | 2013-04-01 | 2013-08-07 | 杭州笔水画王电子科技有限公司 | 3D printing method and 3D printer |
| CN203779869U (en) * | 2014-03-03 | 2014-08-20 | 常州晨凯快速制造技术有限公司 | Rapid laser forming machine |
| CN104175554A (en) * | 2014-07-24 | 2014-12-03 | 合肥斯科尔智能科技有限公司 | Three-dimensional printer with double injector heads working alternately |
| CN105500700A (en) * | 2014-12-30 | 2016-04-20 | 青岛智能产业技术研究院 | Three-dimensional color printing device and method |
| GB2538522A (en) * | 2015-05-19 | 2016-11-23 | Dst Innovations Ltd | Electronic circuit and component construction |
| CN105252776A (en) * | 2015-11-19 | 2016-01-20 | 上海复志信息技术有限公司 | Desktop-level 3D printer |
| CN105563841A (en) * | 2016-02-26 | 2016-05-11 | 东莞劲胜精密组件股份有限公司 | A 3D printing manufacturing method and device for a porous three-dimensional component |
Non-Patent Citations (3)
| Title |
|---|
| 杨岩等: "《风向互联网时代的创业和投资》", 31 July 2016, 机械工业出版社 * |
| 王运赣等: "《3D打印技术修订本》", 31 July 2014, 华中科技大学出版社 * |
| 袁哲俊等: "《精密和超精密加工技术》", 31 July 1999, 机械工业出版社 * |
Cited By (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107379516A (en) * | 2017-09-18 | 2017-11-24 | 合肥工业大学 | A kind of poroelasticity foam preparation method based on moisturecuring silica gel 3D printing |
| CN108414688B (en) * | 2018-03-05 | 2020-05-22 | 中南大学 | A piston and pneumatic dual-purpose 3D printing biomaterial extrusion test device |
| CN108414688A (en) * | 2018-03-05 | 2018-08-17 | 中南大学 | A kind of piston and pneumatic dual-purpose 3D printing biomaterial extrusion test device |
| CN108819237A (en) * | 2018-06-04 | 2018-11-16 | 江苏海事职业技术学院 | A kind of 3D printer and its Method of printing for the printing of indoor decorations model |
| CN108995209A (en) * | 2018-08-29 | 2018-12-14 | 深圳市合泰英龙科技有限公司 | A kind of full-automatic 3D insole printer |
| CN109228306A (en) * | 2018-09-05 | 2019-01-18 | 西安交通大学 | A kind of printer and Method of printing that write-through printing is combined with the printing of fused deposition formula |
| CN109703018A (en) * | 2019-02-25 | 2019-05-03 | 彭俊植 | It is a kind of without the comprehensive 3D printing system of support electromagnetic levitation type and method |
| CN109866430A (en) * | 2019-04-03 | 2019-06-11 | 江苏海之风科技有限公司 | It is a kind of for monitoring the monitoring system of printed material temperature |
| CN111872318A (en) * | 2020-06-29 | 2020-11-03 | 哈尔滨鼎智瑞光科技有限公司 | Sand core model for additive manufacturing by using liquid metal liquid |
| CN112008975A (en) * | 2020-08-25 | 2020-12-01 | 北京优思弗科技有限公司 | Multi-head cooperative 3D printing equipment and printing method |
| CN113733544A (en) * | 2021-08-10 | 2021-12-03 | 深圳市维智梅克科技有限公司 | Method and device for controlling 3D printer by using joystick and readable storage medium |
| WO2024093329A1 (en) * | 2022-10-31 | 2024-05-10 | Syncord 3D Technology Limited | Apparatus and method for three-dimensional printing |
| CN115847811A (en) * | 2022-11-03 | 2023-03-28 | 青岛理工大学 | Continuous fiber composite material rotary structure multi-shaft integrated 3D printer and printing method thereof |
| CN115891171A (en) * | 2022-11-16 | 2023-04-04 | 哈尔滨工业大学 | A water-soluble support method for light-curing 3D printing |
Also Published As
| Publication number | Publication date |
|---|---|
| CN106626358B (en) | 2019-08-06 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN106626358B (en) | A kind of multi-material 3D printer and liquid object accumulation 3D printing method | |
| US11981077B2 (en) | Systems and methods for 3D printing with multiple exchangeable printheads | |
| US11433599B2 (en) | Print assembly for additive manufacturing system, and methods of use thereof | |
| US10052824B2 (en) | Systems, devices, and methods for three-dimensional printing | |
| US10286601B2 (en) | Color or multi-material three-dimensional (3D) printing | |
| US20180169950A1 (en) | Three-dimensional modelling and/or manufacturing apparatus, and related processes | |
| CN108367464B (en) | How to print on a 3D jet printer | |
| US20180056608A1 (en) | 3d printer with coupling for attaching print head and additional equipment to head carriage | |
| JP2021517462A (en) | Electrohydrodynamic bioprinter systems and methods | |
| CN107009614B (en) | Printing method of 3D product and 3D printer used in method | |
| KR20150042254A (en) | Additive manufacturing system with extended printing volume, and methods of use thereof | |
| CN106735220A (en) | A kind of many material laser selective melting shaped devices and method | |
| EP3055122A1 (en) | Consumable filaments having reversible reinforcement for extrusion-based additive manufacturing | |
| CN109466061A (en) | A multi-material 3D printing device based on electro-hydraulic coupled jet printing | |
| CN105082544A (en) | 3D printer and method for printing object through 3D printer | |
| JP2023510281A (en) | Systems and methods for manufacturing three-dimensional structures | |
| EP3052301B1 (en) | Color or multi-material three-dimensional (3d) printing | |
| CN205009603U (en) | Three-dimensional full-color composite printing device | |
| CN104690960A (en) | 3d printing system | |
| Wagner et al. | Design and development of a multi-tool additive manufacturing system | |
| CN205631414U (en) | Intensification management 3D printer | |
| Yang et al. | Polymeric 3D Printers | |
| Gilbertson | Robotic Spatial Printing For Designers | |
| Hassan | Development of Deposition-Controlled Printhead for Printing Multifunctional Devices | |
| Khan et al. | 3D Printing using Fused Filament Fabrication |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20190806 Termination date: 20211207 |
|
| CF01 | Termination of patent right due to non-payment of annual fee |