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CN106561642A - Protection liquid for controlling disease and pest injuries of stumps, and preparation method thereof - Google Patents

Protection liquid for controlling disease and pest injuries of stumps, and preparation method thereof Download PDF

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Publication number
CN106561642A
CN106561642A CN201610864645.9A CN201610864645A CN106561642A CN 106561642 A CN106561642 A CN 106561642A CN 201610864645 A CN201610864645 A CN 201610864645A CN 106561642 A CN106561642 A CN 106561642A
Authority
CN
China
Prior art keywords
protective liquid
pest
stub
treating
preventing
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610864645.9A
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Chinese (zh)
Inventor
于绍杰
于子淇
纪腾
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shandong Tailin Creating Environmental Technology Research And Development Co Ltd
Original Assignee
Shandong Tailin Creating Environmental Technology Research And Development Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shandong Tailin Creating Environmental Technology Research And Development Co Ltd filed Critical Shandong Tailin Creating Environmental Technology Research And Development Co Ltd
Priority to CN201610864645.9A priority Critical patent/CN106561642A/en
Publication of CN106561642A publication Critical patent/CN106561642A/en
Pending legal-status Critical Current

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Classifications

    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/08Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing solids as carriers or diluents
    • A01N25/10Macromolecular compounds
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/10Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
    • A01N47/18Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof containing a —O—CO—N< group, or a thio analogue thereof, directly attached to a heterocyclic or cycloaliphatic ring
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N53/00Biocides, pest repellants or attractants, or plant growth regulators containing cyclopropane carboxylic acids or derivatives thereof

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  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Dentistry (AREA)
  • Plant Pathology (AREA)
  • Engineering & Computer Science (AREA)
  • Pest Control & Pesticides (AREA)
  • Agronomy & Crop Science (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Toxicology (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

The invention relates to a protection liquid for controlling disease and pest injuries of stumps. The protection liquid comprises, by mass, 50-70 parts of a pure acrylic emulsion, 0.1-1 part of 2,2,4-trimethyl-1,3-pentanediol isobutyrate, 0.1-1 part of a mildew inhibition aid, 0.1-1 part of a thickener, 0.1-1 part of phthalthrin, 0.1-1 part of permethrin and 5-20 parts of water. The protection liquid allows medicines to enter the surfaces or holes of the stumps, and the protection liquid can form a protection film to seal the medicines in the stumps and isolate air and water, so volatility and failure of the medicines are prevented, the action degree of medicine effects is improved, and the pest elimination effect is improved.

Description

A kind of protective liquid and preparation method of preventing and treating stub pest and disease damage
Technical field
The present invention relates to the protective liquid and preparation method of a kind of preventing and treating stub pest and disease damage, belong to forestry protection technology field.
Background technology
Bursaphelenchus xylophilus, Anoplophorae seu Aprionae, loose neck as etc. harmful organism be the Major Pests that endanger pinaster, pine nematode has morbidity Lethal speed is fast, and its spread in china is rapid, and monitoring preventing and treating is difficult, and pinaster once catches an illness, most fast 40 days can be withered, be it is a kind of very Dangerous quarantine object.In order to ensure Forestry safety, the preventing and controlling for doing pine nematode well are extremely important.
At present, epidemic-stricken area is wiped out and treated insect pests and plant diseases pine nematode and is mainly fallen ill wood using felling cleaning, and the stump for carrying over is pine Nematicide most intractable entity in wiping out and treating insect pests and plant diseases, stump is contained within Anoplophorae seu Aprionae and Bursaphelenchus xylophilus show that stump is that pine nematode is important and invades Dye source, in prior art, general being removed the evil using medicine kills the insect pest such as Bursaphelenchus xylophilus or Anoplophorae seu Aprionae, such as 16% hongxianqing, chrysanthemum ester etc. The medicament that medicament is configured by a certain percentage with water or other solvents;Although effective agent can enter cut down pile body surface or In the stump hole accomplished fluently, but due to the volatility of medicine, cause the drug effect of medicine play well.
In the medicine of disease tree stump is removed the evil, prior art typically adopts the operation in national standard working specification, to cutting down Stake carries out plastic sheeting and ties up the envelope stake of closing method, because the limitation for manually tying up film operation causes to stump bad sealing, leakage Gas and the drawback generally existing such as cost of labor is higher, cause medicine contact the polypides such as Anoplophorae seu Aprionae or Bursaphelenchus xylophilus well, extremely Kill not thoroughly, and go out harm continuation because the hardness of thin film not enough often leads to part residual insect rupture of membranes, so as to cause disease The effect of tree stump is very poor.
The content of the invention
In order to the effect for solving the problems, such as disease tree stump in prior art is poor, the present invention provides a kind of preventing and treating stub disease The protective liquid of insect pest.
Technical scheme is as follows:
A kind of protective liquid of preventing and treating stub pest and disease damage, component and mass fraction are:Pure-acrylic emulsion:50-70,2,2,4- front threes Base -1,3- pentanediol mono isobutyrates:0.1-1, mould proof auxiliary agent:0.1-1, thickening agent:0.1-1, tetramethrin:0.1-1, chlorine chrysanthemum Ester:0.1-1, water:5-20.One aspect of the present invention makes medicament that protecting film is formed into cutting down in pile body surface or hole, on the other hand, will Medicament is enclosed in stump, isolation air and moisture, it is to avoid the volatilization and failure of medicament, improves the performance degree of drug effect, And improve effect.
Preferably:Component and mass fraction are:Pure-acrylic emulsion:60,2,2,4- trimethyl -1,3- pentanediol list isopropylformic acid .s Ester:0.5, mould proof auxiliary agent:0.1, thickening agent:0.5, tetramethrin:0.3, Permethrin:0.1, water:10.
In order to differentiate operating area and plantation varieties, preferably:Also including the colorant of 0.1-1 mass parts.
Preferably:Oxide of the colorant for ferrum.
Preferably:The component and mass fraction of pure-acrylic emulsion be:Methyl methacrylate 30-40 parts, butyl acrylate 15-20 parts, methacrylic acid 6-10 parts.
Preferably:The component and mass fraction of pure-acrylic emulsion be:36 parts of methyl methacrylate, butyl acrylate 18 Part, 6 parts of methacrylic acid.
Preferably:Mould proof auxiliary agent is N- (2- benzimidazolyls)-methyl carbamate.
Preferably:Thickening agent is hydroxypropyl methyl cellulose.
Present invention also offers the method for preparing above-mentioned protective liquid, comprises the steps of:First water is filled with pure-acrylic emulsion Divide fusion, add 2,2,4- trimethyl -1,3- pentanediol mono isobutyrates are stirred, and then add mould proof helping Agent, stirs, and adds thickening agent, stirs, and is eventually adding tetramethrin and Permethrin, has prepared after being sufficiently stirred for Into.
Present invention also offers protective liquid is sprayed to stump surface, spraying knot by the method that above-mentioned protective liquid protects stub Shu Hou, silicon dioxide of the mass fraction for 20-40 is uniformly shed in coating surface.
Preferably, silicon dioxide particle diameter is 80-120 mesh, and mass fraction is 30 parts.
The invention has the beneficial effects as follows:
The characteristics of protective liquid of the present invention has infiltration, effectively can carry out totally-enclosed anoxybiotic process, in addition to stump The characteristics of protective liquid also has fast filming, has very high intensity, hardness, even if Monochamus alternatus Hope is not poisoned with poison by medicine after film forming It also is difficult to come outbreak out, protective liquid effective protective action for pine nematode has.
Specific embodiment
Comparative example 1:
Directly the hole on epidemic disease wood stump surface and drill bit punching directly spray 16% hongxianqing, by extra large in Laoshan difference The experimental data statistics of 200 plants of epidemic disease wood is pulled out, effective killing rate is 95%.
Comparative example 2:
Plastic sheeting ties up the envelope stake of closing method, is cut down by tying up closing method stump process to 300 plastic sheetings of Laoshan Stake is counted, and effective killing rate is 2%.
Comparative example 3:
A kind of wingceltis wood insect paint, is made up of coating and base material.Coating is:Hydroxypropyl cyclodextrin 2-4 parts, hat Ether 1-2 parts, Permethrin 0.5-1 parts, tetramethrin 0.5-1 parts, dimethyl phthalate 0.5-1 parts, 0.01 part of stearmide, second 0.01 part of alcohol.Coating with base material proportioning is:Coating:4%th, acrylate:30%th, vinyl acetate 15%, Calcium Carbonate 45%th, Griffith's zinc white. 5%, polyhydric alcohol 0.5%, cellulose ether 0.5%.Experiment system is carried out in 100 plants of pine nematodiasis woods of Laoshan Meter, killing rate is zero.
Embodiment 1:
A kind of protective liquid of preventing and treating stub pest and disease damage, component and mass fraction are:Pure-acrylic emulsion:60,2,2,4- trimethyls- 1,3- pentanediol mono isobutyrates:0.5, mould proof auxiliary agent:0.1, thickening agent:0.5, tetramethrin:0.3, Permethrin:0.1, water:10. The component and mass fraction of pure-acrylic emulsion be:36 parts of methyl methacrylate, 18 parts of butyl acrylate, 6 parts of methacrylic acid.It is anti- Mould auxiliary agent is N- (2- benzimidazolyls)-methyl carbamate.Thickening agent is hydroxypropyl methyl cellulose.
The method that the present invention prepares above-mentioned protective liquid, comprises the steps of:First water is fully merged with pure-acrylic emulsion, then Add 2,2,4- trimethyl -1,3- pentanediol mono isobutyrates to stir, then add mould proof auxiliary agent, stirring is equal It is even, thickening agent is added, is stirred, be eventually adding tetramethrin and Permethrin, prepared after being sufficiently stirred for and complete.
Protective liquid is sprayed to stump surface by the method for present invention protection stub, after spraying terminates, is 30 by mass fraction Silicon dioxide uniformly shed in coating surface.
By 100 plants of pine nematodiasis woods of Laoshan are carried out with experiment statisticses, totally-enclosed stump processes protective liquid and effectively kills Worm rate is 100%.One aspect of the present invention makes medicament that protecting film is formed into cutting down in pile body surface or hole, on the other hand, by medicament It is enclosed in stump, isolation air and moisture, it is to avoid the volatilization and failure of medicament, improves the performance degree of drug effect, and carry High effect.

Claims (10)

1. it is a kind of preventing and treating stub pest and disease damage protective liquid, it is characterised in that:Component and mass fraction are:Pure-acrylic emulsion:50-70, 2,2,4- trimethyl -1,3- pentanediol mono isobutyrates:0.1-1, mould proof auxiliary agent:0.1-1, thickening agent:0.1-1, tetramethrin: 0.1-1, Permethrin:0.1-1, water:5-20.
2. the protective liquid of a kind of preventing and treating stub pest and disease damage as claimed in claim 1, it is characterised in that:Component and mass fraction For:Pure-acrylic emulsion:60,2,2,4- trimethyl -1,3- pentanediol mono isobutyrates:0.5, mould proof auxiliary agent:0.1, thickening agent:0.5, Tetramethrin:0.3, Permethrin:0.1, water:10.
3. the protective liquid of a kind of preventing and treating stub pest and disease damage as claimed in claim 1, it is characterised in that:Also include 0.1-1 mass The colorant of part.
4. the protective liquid of a kind of preventing and treating stub pest and disease damage as claimed in claim 3, it is characterised in that:Oxidation of the colorant for ferrum Thing.
5. the protective liquid of a kind of preventing and treating stub pest and disease damage as claimed in claim 1, it is characterised in that:The component of pure-acrylic emulsion and Mass fraction is:Methyl methacrylate 30-40 parts, butyl acrylate 15-20 parts, methacrylic acid 6-10 parts.
6. the protective liquid of a kind of preventing and treating stub pest and disease damage as claimed in claim 1, it is characterised in that:The component of pure-acrylic emulsion and Mass fraction is:36 parts of methyl methacrylate, 18 parts of butyl acrylate, 6 parts of methacrylic acid.
7. the protective liquid of a kind of preventing and treating stub pest and disease damage as claimed in claim 1, it is characterised in that:Mould proof auxiliary agent is N- (2- benzimidazolyls)-methyl carbamate.
8. the protective liquid of a kind of preventing and treating stub pest and disease damage as claimed in claim 1, it is characterised in that:Thickening agent is hydroxypropyl first Base cellulose.
9. the method for preparing the protective liquid as described in claim 1-8, it is characterised in that:Comprise the steps of:First water with it is pure Acrylic emulsion fully merges, and adds 2,2,4- trimethyl -1, and 3- pentanediol mono isobutyrates are stirred, then added Mould proof auxiliary agent, stirs, and adds thickening agent, stirs, and is eventually adding tetramethrin and Permethrin, makes after being sufficiently stirred for It is standby to complete.
10. the method for protecting stump using the protective liquid as described in claim 1-8 is arbitrary, it is characterised in that:Protective liquid is sprayed To stump surface, after spraying terminates, silicon dioxide of the mass fraction for 20-40 is uniformly shed in coating surface.
CN201610864645.9A 2016-09-29 2016-09-29 Protection liquid for controlling disease and pest injuries of stumps, and preparation method thereof Pending CN106561642A (en)

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Application Number Priority Date Filing Date Title
CN201610864645.9A CN106561642A (en) 2016-09-29 2016-09-29 Protection liquid for controlling disease and pest injuries of stumps, and preparation method thereof

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Publication Number Publication Date
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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113801576A (en) * 2021-10-15 2021-12-17 山东省林业科学研究院 Composite material for disposing wood cutting pile for pine wood nematode disease

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113801576A (en) * 2021-10-15 2021-12-17 山东省林业科学研究院 Composite material for disposing wood cutting pile for pine wood nematode disease

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Application publication date: 20170419

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