CN106567267B - Aqueous pigment digital ink-jet printing in textiles ink and its preparation and application - Google Patents
Aqueous pigment digital ink-jet printing in textiles ink and its preparation and application Download PDFInfo
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- CN106567267B CN106567267B CN201610991294.8A CN201610991294A CN106567267B CN 106567267 B CN106567267 B CN 106567267B CN 201610991294 A CN201610991294 A CN 201610991294A CN 106567267 B CN106567267 B CN 106567267B
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
- D06P5/30—Ink jet printing
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/0023—Digital printing methods characterised by the inks used
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/0041—Digital printing on surfaces other than ordinary paper
- B41M5/0047—Digital printing on surfaces other than ordinary paper by ink-jet printing
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/30—Inkjet printing inks
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/30—Inkjet printing inks
- C09D11/32—Inkjet printing inks characterised by colouring agents
- C09D11/322—Pigment inks
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/30—Inkjet printing inks
- C09D11/38—Inkjet printing inks characterised by non-macromolecular additives other than solvents, pigments or dyes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/445—Use of auxiliary substances before, during or after dyeing or printing
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/52—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing synthetic macromolecular substances
- D06P1/5207—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- D06P1/525—Polymers of unsaturated carboxylic acids or functional derivatives thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/52—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing synthetic macromolecular substances
- D06P1/5264—Macromolecular compounds obtained otherwise than by reactions involving only unsaturated carbon-to-carbon bonds
- D06P1/5285—Polyurethanes; Polyurea; Polyguanides
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/64—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
- D06P1/651—Compounds without nitrogen
- D06P1/65106—Oxygen-containing compounds
- D06P1/65118—Compounds containing hydroxyl groups
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
- Ink Jet Recording Methods And Recording Media Thereof (AREA)
Abstract
The present invention provides a kind of aqueous pigment digital ink-jet printing in textiles ink and its preparation and application.The aqueous pigment digital ink-jet printing in textiles ink, it is characterized in that, comprising dispersible pigment color paste, nanocomposite adhesive and deionized water, the nanocomposite adhesive includes polyaminoester emulsion, Organic fluoride modified polyacrylate nanoemulsions and another polyacrylate dispersion.The present invention uses nanocomposite adhesive, emphasis solves the problems, such as that washing fastness is low on PRINTED FABRIC through aqueous pigment ink-jet printing ink, and the industrial applications for aqueous pigment ink-jet printing ink in the digital ink-jet printed field of fabric provide new solution.
Description
Technical field
The present invention relates to a kind of aqueous pigment digital ink-jet printing in textiles inks and preparation method thereof, while being related to the ink
Water ink-jet printed method on the fabric.
Background technique
Traditional silk screen, rotary scream printing operating procedure complexity are tediously long, and are not able to satisfy high-quality, small lot, style multiplicity
Change, personalized requirement, and digital ink-jet printed technology gets rid of Conventional decal color separation, plate-making, the analog form for making net, has
The clear superiority of easy to operate, pollution-free, low energy consumption, high repayment brings unprecedented opportunity to develop to textile printing and dyeing industry.
Digital ink-jet printed is that required decalcomania is inputted in computer in digital form, scans and edits by computer color separation in printing
After processing, in the digital inkjet printing machine by computer control, directly printing ink is accurately ejected on fabric, is printed
Various required color patterns out.Digital ink-jet printed ink is the important consumptive material of digit printing, and the property of digit printing ink
Printing quality can be directly influenced, the digital ink-jet printed ink of presently used fabric contaminates mainly based on dye ink
Expect that there are shortcomings for ink: (1) dye ink does not have versatility.Different fabrics needs different types of dye ink
It is able to satisfy stamp requirement, since replacement ink needs cleaning sprayer and pipeline, causes to operate more troublesome；(2) production technology is complicated,
There are certain environmental pollutions.It needs to pre-process fabric before ink-jet printed, needs to carry out gas steaming to fabric after ink-jet printed
The post-processings such as fixation, washing removal loose colour, the process is more complicated, and energy consumption is higher.Fabric post-processing stages generally require more
Secondary washing could remove the dyestuff not being securely held, because will cause certain environmental pollution；(3) light fastness is poor.One
As dyestuff be all low molecular weight water-soluble dye, easily decompose under illumination condition, causing to fade changes colour, and influences the product of PRINTED FABRIC
Matter.
The disadvantages mentioned above of dye ink hinders the popularization of digital ink-jet printed technology, therefore exploitation is avoided that dye ink
The task of the novel ink-jet printing ink of disadvantage is extremely urgent, and pigment ink-jetting printing ink comes into existence as the situation requires.Pigment jetting print
Flower ink, in the film forming mechanism of fabric surface, will be adhered on the fabric based on adhesive without compatibility and reactive pigment,
Using the surface for making pigmentation and being firmly secured to fabric is baked, to assign the gorgeous color of fabric and figure abundant
Case.Pigment ink-jetting printing ink can be common to various fabrics, such as cotton, hair, silk, cotton synthetic fibre, dacron and blended fabric, spray
Transformation fabric variety does not need replacement ink and cleaning sprayer and pipeline during ink-printed, and ink waste is less, hardly dirty
Contaminate environment.In addition, the simple process of pigment ink-jetting printing ink, no post-processing and washing process, water-saving, power saving, low energy consumption.
Therefore pigment ink-jetting printing ink is it will be apparent that still the technology exists still at present for the advantages of textile ink-jet stamp
An open question: failing to find suitable textile binding agent, low so as to cause ink-jet printed product washing fastness.
Currently, be applied to textile coating stamp adhesive be usually polyacrylate or polyaminoester emulsion and they
Modified resin, wherein polyacrylate adhesive with it is relatively broad.Polyacrylate dispersion fabric surface at
The film transparency is good, stronger to the adhesive capacity of fiber, and has preferable water resistance, weatherability and mechanical property, but there are hands
Sense is easier to the disadvantages of hard, hot sticky cold crisp.Aqueous polyurethane emulsion it is good at film dynamic performance, it is with higher elasticity and it is good
Permeability, and heat-resisting, cold-resistant, resistance to bent mill, feel particularly soft, fastness to wet rubbing and smoothness are good, and epithelium is not tacky, does not adsorb
Dust.As long as traditional coating printing adhesive size not network blocking, and if carrying out use as ink-jet printed adhesive, tradition
Coating printing adhesive emulsion stability is inadequate, and partial size is too big, is easy the expensive piezo jets of blocking, thus cannot be used for ink-jet
Stamp.The ink-jet printed requirement to adhesive is: (1) emulsion particle diameter can be stablized and not be demulsified under nanoscale, high and low temperature；
(2) emulsion film forming is firm and elasticity is good, and cementitiousness is strong, and washing fastness is high；(3) it forms a film soft, not tacky.
Have about the most representative patent of aqueous pigment type ink-jet ink containing polyacrylate dispersion
US7338988, US70301175, but the ink-jet ink in these patents is mainly for the plastic films material such as PP, PVC, PU
Coloring, the glass transition temperature of polyacrylate dispersion used is above room temperature, forms hard film on ground, it is clear that
It may not apply to soft fabric.Domestic room width is completed et al. to carboxylic acid-based copolymer in aqueous pigment ink-jet printing ink
The dual function of pigment hyper-dispersant and textile binding agent is played simultaneously, but carboxylic acid-based copolymer comes from hyper-dispersant angle
It sees, due to lacking single-point or multiple spot pigment anchoring group, and solvent free chain in macromolecular chain, therefore is copolymerized through polyocarboxy acid type
The pigment stability of object hyper-dispersant will not be satisfactory；From the perspective of textile binding agent, carboxylic acid-based copolymer oversubscription
Powder content is less, although esterification occurs with cellulosic fabric, hardly reacts with chemical & blended fabrics such as terylene, nylon,
Therefore bonding effect is not ideal enough.Crosslinking agent is added in pigment ink-jetting printing ink by patent CN101100815, to improve
Dry, fastness to wet rubbing, but effect is still not ideal enough, fastness to wet rubbing only have 2-3 grades, and 3-4 grades of dry fastness, and actually face
If existing in material type ink-jet printing ink if there is crosslinking agent, then all may at any time in the transport of ink or storing process
Reaction is crosslinked, causes the storage stability of ink bad, and prints fluency and also will appear serious problems.Patent
CN1583898 uses self-crosslinking acrylic ester resin as plant adhesive, the results show: fabric surface after stamp
Crosslinked polyacrylate film is relatively hard and crisp, easily falls off from fabric after dry state or hygrometric state friction, washing fastness is reduced to 2
Grade.E.I.Du Pont Company in recent years disclosed patent WO2005/071026, WO2009/076386, WO2009/137747 to have
Adhesive of the polyaminoester emulsion of cross-linked structure as ink-jet printing ink, but the washing fastness of fabric still will not be high,
The polyaminoester emulsion adhesive and crosslinking agent with cross-linked structure is added in WO2009/137753 simultaneously in the ink, and in ink
Existing crosslinking agent easily causes the crosslinking of ink polyurethane in transport or storing process, cause ink storage stability,
It is bad to print fluency.
Summary of the invention
The present invention is directed to the current aqueous pigment ink-jet printing ink not satisfactory problem of washing fastness on the fabric, provides
A kind of good aqueous pigment ink-jet printing ink of washing fastness and its preparation and application, in the ink-jet printing ink simultaneously
Containing there are two types of polyacrylate dispersion and a kind of polyaminoester emulsions as nanocomposite adhesive, one of organic fluorine richness
Polyacrylate dispersion partial size is higher in nanoscale, emulsion particle internal crosslinking degree, in fabric surface film forming due to being crosslinked not
Demulsification film forming occurs, still with the fractions distribution of hydrophobic nanometre particle by another polyacrylate dispersion and polyaminoester emulsion
In the laminated film of formation.It is good that the nano effect that this well-designed nanostructure is showed can be such that film has
Hydrophobicity performance.The granules of pigments being scattered in film is not easy to fall off from fabric, and adhesive force is preferable, the washing of ink-jet printed fabric
Fastness obtains larger raising, and soft.Aqueous pigment ink-jet printing ink system containing above-mentioned nanocomposite adhesive
Standby simple process has good storage stability and printing fluency, and compared with dye-type ink-jet printing ink, can
Omit pre-treatment and the aftertreatment technology of fabric.
In order to solve the above-mentioned technical problem, present invention employs following technical solutions:
A kind of aqueous pigment digital ink-jet printing in textiles ink, which is characterized in that include dispersible pigment color paste, nano combined viscous
Mixture and deionized water, the nanocomposite adhesive include polyaminoester emulsion, Organic fluoride modified polyacrylate nano-emulsion
Liquid and another polyacrylate dispersion.
Preferably, the Organic fluoride modified polyacrylate nanoemulsions do not occur after textile ink-jet stamp demulsification at
Film is formed with the fractions distribution of hydrophobicity nanoparticle in the polyaminoester emulsion and another polyacrylate dispersion
In laminated film.
Preferably, the synthetic method of the Organic fluoride modified polyacrylate nanoemulsions includes: by 10-15 parts by weight
Methyl methacrylate (MMA), 2-4 weight parts of methacrylic acid hexafluoro butyl ester (HFBM), 0.1-1 parts by weight Emulsifier, 0.1-1
Parts by weight ethylene glycol dimethacrylate is added in 15-25 parts by weight water, and stirring, pre-emulsification 25-35min obtains monomer
Pre-emulsion；Then, the pre-emulsion of 25-35 weight parts monomers is added in reaction vessel, is warming up to 75-85 DEG C, added
2-5 parts by weight concentration is the initiator potassium persulfate aqueous solution of 0.7%-0.9%, reacts 25-35min, then 4-8 parts by weight are dense
The pre-emulsion of initiator potassium persulfate aqueous solution and remaining monomer that degree is 0.7%-0.9% is added dropwise to reaction vessel simultaneously
In, 1-3h is reacted to get required Organic fluoride modified polyacrylate nanoemulsions, partial size 40-70nm is arrived.
It is highly preferred that the emulsifier is by the 465 and lauryl sodium sulfate SDS of worry that disappears with mass ratio 1: 0.5-1.5
It mixes.
It is highly preferred that the emulsifier by disappear 465 and lauryl sodium sulfate SDS of worry with mass ratio 1: 1 mixing and
At.
Preferably, the nanocomposite adhesive is by polyaminoester emulsion 10%-50% and Organic fluoride modified polyacrylic acid
Ester nanoemulsions 10%-50% and another kind polyacrylate dispersion 10%-50% are combined；The polyaminoester emulsion
For MK-119, PU328-9K, PU628-9K, BY-6336 or BY-6337；Another polyacrylate dispersion is BD-4838, BD-
4895, QY-001, QY-003 or QY-004.
Preferably, the aqueous pigment digital ink-jet printing in textiles ink further includes surfactant, moisturizer, pH
At least one of regulator and antibacterial agent.
Preferably, the aqueous pigment digital ink-jet printing in textiles ink is by dispersible pigment color paste 5.0-25.0%, surface
Activating agent 0.2-2.0%, nanocomposite adhesive 5.0-15.0%, moisturizer 5.0-35.0%, pH adjusting agent 0.5-2.0%,
The deionized water of antibacterial agent 0.1-0.5% and surplus composition.
Preferably, the surfactant are as follows: BYK-125, BYK-140, benzalkonium chloride, lauryl sodium sulfate, ten
Dialkyl benzene sulfonic acids sodium, α-sodium olefin sulfonate, Disodium sulfosuccinate, alkyl polyoxyethylene ether ammonium sulfate, dibutyl naphthalenesulfonic acid
In sodium, octyl phenol polyoxyethylene ether, triton x-100, lauric acid alkanolamide, this Pan 20, this Pan 60, this Pan 80 and Tween 80
One kind.
Preferably, the moisturizer is 2-Pyrrolidone, n-methyl-2-pyrrolidone, octyl-pyrrolidone, second two
Alcohol, diethylene glycol, triethylene glycol, tetraethylene glycol, glycerine, 1,2-PD, 1,3-PD, methyl propanediol, ethyl hydroxyl
Base propylene glycol, a contracting propylene glycol, two contracting propylene glycol, 1,2- butanediol, 1,4-butanediol, 1,2,4-butanetriol, 1,5-PD,
Tert-pentyl alcohol, pentaerythrite, 2- methyl -2,4- pentanediol, it is cyclohexanol, 1,2- hexylene glycol, 2 methyl cyclohexanol, heptandiol, just pungent
One or more of alcohol, polyethylene glycol (PEG) 200, PEG-400 and PEG-800.
Preferably, the pH adjusting agent is in ammonium hydroxide, monoethanolamine, ethylene glycol amine, triethanolamine and methylethanolamine
One kind.
Preferably, the antibacterial agent is SilvDurTMET antibacterial agent, HR-25 fabric antimicrobial finishing agent, GOOD NICE and
One of AEM5772-5 antimildew and antibacterial agent.
Preferably, viscosity of the aqueous pigment digital ink-jet printing in textiles ink at 25 DEG C of temperature is 2.0-
10.0cP, surface tension 20-60mN/m, pH value 7-9.
The present invention also provides the preparation method of above-mentioned aqueous pigment digital ink-jet printing in textiles ink, feature exists
In, comprising:
Step 1: first in proportion by surfactant 0.2-2.0%, nanocomposite adhesive 5.0-15.0%, moisturizing
Agent 5.0-35.0%, pH adjusting agent 0.5-2.0% and antibacterial agent 0.1-0.5% are added in the deionized water of surplus, are then used
High-speed mixer stirs 40-100min with the revolving speed of 2000-4500rad/min, becomes uniform dicyandiamide solution；
Step 2: dispersible pigment color paste 5.0-25.0% is added in above-mentioned dicyandiamide solution, with high-speed mixer with 1000-
The revolving speed of 3000rad/min stirs 20-60min, becomes uniform ink dispersion；
Step 3: by obtained ink dispersion be 0.2-1.0 μm with aperture filtering with microporous membrane to get aqueous
Pigment digital ink-jet printing in textiles ink.
The present invention also provides use above-mentioned aqueous pigment digital ink-jet printing in textiles ink to spray in various fabrics
Ink-printed method characterized by comprising blue, red, yellow, black (C, M, Y, K) four primaries aqueous pigment digital ink-jet is weaved
Product printing ink is respectively charged into large-scale ink-jet decorating machine print cartridge, by the control of ink-jet printed software, by required color
It is printed on fabric with pattern；Then the fabric after will be ink-jet printed, with 120-160 DEG C of temperature, bakes solid in hot baked machine
Color 4-6min.
Compared with prior art, the beneficial effects of the present invention are:
1, washing fastness is very good.A kind of polyacrylate containing homemade organic fluorine richness in the ink-jet printing ink
Emulsion particle diameter is higher in nanoscale, emulsion particle internal crosslinking degree, fabric surface film forming when due to crosslinking do not occur demulsification at
Film, still with the fractions distribution of hydrophobic nanometre particle formed by another polyacrylate dispersion and polyaminoester emulsion it is compound
In film.The nano effect that this well-designed nanostructure is showed can be that film has good hydrophobicity performance.
The granules of pigments being scattered in film is not easy to fall off from fabric, and adhesive force is preferable, and the washing fastness of ink-jet printed fabric obtains
It greatly improves, and does not influence fabric feeling, be industry of the aqueous pigment ink-jet printing ink in the digital ink-jet printed field of fabric
Change application and provides new solution.
2, ink-jet printed simple process carries out after stamp without to fabric without pre-processing to fabric before stamp
The post-processing such as decatize, washing；
3, there is versatility to different types of fabric.Different types of ink will not be needed because of fabric types difference；
4, environmental pollution is small.Due to drop on demand ink jet stamp, there is no the waste problems of pigment.Fabric after stamp is not required to
Washing removal loose colour, reduces quantity of wastewater effluent；
5, low energy consumption；
6, print performance is good.It is high, bright in colour to print group's precision that fluency is good, and storage stability is good, prints, especially
It is that there is good washing fastness.
Specific embodiment
Present invention will be further explained below with reference to specific examples.It should be understood that these embodiments are merely to illustrate the present invention
Rather than it limits the scope of the invention.In addition, it should also be understood that, after reading the content taught by the present invention, those skilled in the art
Member can make various changes or modifications the present invention, and such equivalent forms equally fall within the application the appended claims and limited
Range.
Each percentage in the present invention is unless otherwise specified mass percent.
CMYK four primaries dispersible pigment color paste described in various embodiments of the present invention are purchased from Cabot (China) limited investment public affairs
Department, wherein the average grain diameter of pigment particles is between 80-150nm.
Polyaminoester emulsion MK-119 of the invention is purchased from Guangzhou to believe Chemical Co., Ltd., PU328-9K, PU628-9K
It is purchased from the auxiliary reagent factory Zhong Fang, the city Tai Xin, BY-6336 or BY-6337 are purchased from Dongguan City Yi Bao resin Co., Ltd；Polyacrylic acid
Ester lotion BD-4838, BD-4895 is purchased from Shanghai Baidao Chemical Co., Ltd., QY-001, QY-003 and QY-004 are purchased from east
Tabernaemontanus bulrush whole world resin Industrial Co., Ltd..
SilvDur of the inventionTMET antibacterial agent is purchased from Shanghai Runhe Nanometer Material Technology Co., Ltd, HR-25 fabric
Antibacterial finishing agent is purchased from Shanghai Juan Rui Chemical Co., Ltd., and GOOD NICE and AEM5772-5 antimildew and antibacterial agent is purchased from good we
Think anti-biotic material Co., Ltd.
Surfactant B YK-125, BYK-140 of the invention is purchased from Bi Ke auxiliary agent (Shanghai) Co., Ltd..
Embodiment 1
A kind of blue water-based pigment digital ink-jet printing in textiles ink, formula are as shown in table 1.
The blue water-based pigment digital ink-jet printing in textiles ink set of table 1:
Wherein, the synthetic method of the Organic fluoride modified polyacrylate nanoemulsions are as follows: by 12.3g methacrylic acid
Methyl esters (MMA), 2.7g Hexafluorobutyl mathacrylate (HFBM), 0.6g emulsifier are (by worried 465, lauryl sodium sulfate of disappearing
SDS is mixed with mass ratio 1: 1), 0.5g ethylene glycol dimethacrylate be added in 20g water, it is high with 2500rpm revolving speed
Speed stirring, pre-emulsification 30min obtain the pre-emulsion of monomer.Then, the pre-emulsion of 30g monomer is added in three-necked bottle, is heated up
To 80 DEG C, 4g initiator potassium persulfate aqueous solution (concentration 0.82%) is added, reacts 30min.6g is drawn with dropping funel again
Simultaneously, slowly (10 drops/min) are added dropwise to the pre-emulsion of hair agent persulfate aqueous solution (concentration 0.82%) and remaining monomer
In three-necked bottle, 2h is reacted to get required Organic fluoride modified polyacrylate nanoemulsions, partial size (Malvern laser particle is arrived
Instrument Nano-S90 test) it is 40-70nm.The Organic fluoride modified polyacrylate nanoemulsions after textile ink-jet stamp not
Demulsification film forming occurs, with the fractions distribution of hydrophobicity nanoparticle in the polyaminoester emulsion and another polyacrylate
In the laminated film that lotion is formed.
The blue water-based pigment digital ink-jet printing in textiles ink the preparation method comprises the following steps: by listed in table 1
Each component formula, first by surfactant, nanocomposite adhesive, moisturizer, pH adjusting agent and antibacterial agent be added to from
In sub- water, 80min is then stirred with the revolving speed of 2000-4500rad/min with high-speed mixer, becomes uniform solvent body
System；Blue pigment mill base (being purchased from Cabot (China) Investment Co., Ltd) is added in above-mentioned dicyandiamide solution again, with high speed
Blender stirs 30min with the revolving speed of 2000rad/min, becomes uniform ink dispersion；It finally will be obtained
The filtering with microporous membrane that ink dispersion aperture is 0.5 μm is to get blue water-based pigment digital ink-jet printing in textiles ink
Water.
The physical and chemical indexes of the Blue inkjet printing ink at 25 DEG C: surface tension 32.98mN/m is (by BZY-2 full application of brake table
Face tensiometer measures), viscosity 3.08cP (is measured by R/S-CC with cylinder rheometer is taken out), and pH value 8.2 (is surveyed by Ph-20 pen type pH
Examination instrument measures).Measure through high temperature (70 DEG C) and low temperature (0 DEG C) weatherability: the Blue inkjet printing ink storage stability is good.
Ink-jet printed test on dacron obtains: blue ink printing fluency is good, rolls into a ball purity bright in colour,
Line edge is sharp keen, and washing fastness is high.The feel of ink-jet printed front and back dacron is without significant change.
Washing fastness test method: it is tested according to the A method of inspection in national standard GBT 3921-2008.
(1) sample: the blue water-based pigment digital ink-jet textile using the present embodiment having a size of 100mm × 40mm prints
Flower ink uses the dacron of the ink-jet printed technique stamp of conventional digital, and adjacent fabric (meets the cotton of national standard GB/T6151, gathers
Ester fabric) size is identical, and sample is sandwiched between two adjacent fabrics, sutures along short side, and it is composite sample.
(2) instrument: color fastness to washing testing machine, model SW-12All Wenzhou Darong Textile Instrument Co., Ltd.).
(3) soap lye: soap, in terms of dry weight, contained humidity is no more than 5%, and free alkali is (with Na2CO3Meter)≤0.3%, dissociate
Alkali (in terms of NaOH)≤0.1%, total fat composition >=850g/Kg prepare soap fatty acid mixed congealing point≤30 DEG C, iodine number≤50,
Without fluorescent whitening agent.Soap lye is prepared according to the concentration in 1L water (tertiary effluent meets GB/T6682) containing 5g soap.
(4) it tests: composite sample being put into (550 ± 50) mL stainless steel cup in color fastness to washing testing machine, in cup
It is put into the soap lye for being 50: 1 with Composite sample mass ratio.Stainless steel cup is sealed, then along radius be 45mm, revolving speed 40r/min
It is rotated, 40 DEG C of stirring 30min of temperature.Sample is taken out in off-test, is cleaned twice with cold tertiary effluent, then in flowing cool water
Middle flushing 10min is squeezed and is removed moisture.Composite sample is unfolded, connects sample only by a suture with stickers lining, is suspended on not higher than 60
DEG C environment in it is dry.The discoloration that sample is evaluated with discoloration gray scale (GB 250), with staining gray scale (GB
251) staining of adjacent fabric is evaluated.
Washing fastness discoloration and totally 5 grades of staining grade, 5 grades to be optimal, the discoloration grade for evaluating sample is 4-5 grades, staining
It is 4-5 grades.
Embodiment 2
A kind of red aqueous pigment digital ink-jet printing in textiles ink, formula are as shown in table 2.
The red aqueous pigment digital ink-jet printing in textiles ink set of table 2:
The synthetic method of the Organic fluoride modified polyacrylate nanoemulsions is same as Example 1.
The red aqueous pigment digital ink-jet printing in textiles ink the preparation method comprises the following steps: by listed in table 2
Each component formula, first by surfactant, nanocomposite adhesive, moisturizer, pH adjusting agent and antibacterial agent be added to from
In sub- water, 80min is then stirred with the revolving speed of 2000-4500rad/min with high-speed mixer, becomes uniform solvent body
System；Red pigment mill base (being purchased from Cabot (China) Investment Co., Ltd) is added in above-mentioned dicyandiamide solution again, with high speed
Blender stirs 30min with the revolving speed of 2000rad/min, becomes uniform ink dispersion；It finally will be obtained
The filtering with microporous membrane that ink dispersion aperture is 0.5 μm is to get red aqueous pigment digital ink-jet printing in textiles ink
Water.
The physical and chemical indexes of the red ink-jet printing ink at 25 DEG C: surface tension 33.89mN/m is (by BZY-2 full application of brake table
Face tensiometer measures), viscosity 3.12cP (is measured by R/S-CC with cylinder rheometer is taken out), and pH value 8.3 (is surveyed by Ph-20 pen type pH
Examination instrument measures).Measure through high temperature (70 DEG C) and low temperature (0 DEG C) weatherability: the red ink-jet printing ink storage stability is good.
Ink-jet printed test on dacron obtains: red ink printing fluency is good, rolls into a ball purity bright in colour,
Line edge is sharp keen.The feel of ink-jet printed front and back dacron is without significant change.It is surveyed using washing fastness described in embodiment 1
Method for testing, the discoloration grade for evaluating sample is 4-5 grades, and staining is 4-5 grades.
Embodiment 3
A kind of yellow aqueous pigment digital ink-jet printing in textiles ink, formula are as shown in table 3.
3 yellow aqueous pigment digital ink-jet printing in textiles ink set of table:
The synthetic method of the Organic fluoride modified polyacrylate nanoemulsions is same as Example 1.Described is organic
Demulsification film forming does not occur after textile ink-jet stamp for fluorine richness polyacrylate nanoemulsions, in the form of hydrophobicity nanoparticle
It is distributed in the laminated film that the polyaminoester emulsion and another polyacrylate dispersion are formed.
The yellow aqueous pigment digital ink-jet printing in textiles ink the preparation method comprises the following steps: by listed in table 2
Each component formula, first by surfactant, nanocomposite adhesive, moisturizer, pH adjusting agent and antibacterial agent be added to from
In sub- water, 80min is then stirred with the revolving speed of 2000-4500rad/min with high-speed mixer, becomes uniform solvent body
System；Yellow uitramarine mill base (being purchased from Cabot (China) Investment Co., Ltd) is added in above-mentioned dicyandiamide solution again, with high speed
Blender stirs 30min with the revolving speed of 2000rad/min, becomes uniform ink dispersion；It finally will be obtained
The filtering with microporous membrane that ink dispersion aperture is 0.5 μm is to get yellow aqueous pigment digital ink-jet printing in textiles ink
Water.
The physical and chemical indexes of the yellow ink-jet printing ink at 25 DEG C: surface tension 34.01mN/m is (by BZY-2 full application of brake table
Face tensiometer measures), viscosity 3.11cP (is measured by R/S-CC with cylinder rheometer is taken out), and pH value 8.1 (is surveyed by Ph-20 pen type pH
Examination instrument measures).Measure through high temperature (70 DEG C) and low temperature (0 DEG C) weatherability: the yellow ink-jet printing ink storage stability is good.
Ink-jet printed test on dacron obtains: yellow ink printing fluency is good, rolls into a ball purity bright in colour,
Line edge is sharp keen.The feel of ink-jet printed front and back dacron is without significant change.It is surveyed using washing fastness described in embodiment 1
Method for testing, the discoloration grade for evaluating sample is 4-5 grades, and staining is 4-5 grades.
Embodiment 4
A kind of black water pigment digital ink-jet printing in textiles ink, formula are as shown in table 4.
4 black water pigment digital ink-jet printing in textiles ink set of table:
The synthetic method of the Organic fluoride modified polyacrylate nanoemulsions is same as Example 1.Described is organic
Demulsification film forming does not occur after textile ink-jet stamp for fluorine richness polyacrylate nanoemulsions, in the form of hydrophobicity nanoparticle
It is distributed in the laminated film that the polyaminoester emulsion and another polyacrylate dispersion are formed.
The black water pigment digital ink-jet printing in textiles ink the preparation method comprises the following steps: by listed in table 2
Each component formula, first by surfactant, nanocomposite adhesive, moisturizer, pH adjusting agent and antibacterial agent be added to from
In sub- water, 80min is then stirred with the revolving speed of 2000-4500rad/min with high-speed mixer, becomes uniform solvent body
System；Black pigment mill base (being purchased from Cabot (China) Investment Co., Ltd) is added in above-mentioned dicyandiamide solution again, with high speed
Blender stirs 30min with the revolving speed of 2000rad/min, becomes uniform ink dispersion；It finally will be obtained
The filtering with microporous membrane that ink dispersion aperture is 0.5 μm is to get black water pigment digital ink-jet printing in textiles ink
Water.
The physical and chemical indexes of the black ink-jet printing ink at 25 DEG C: surface tension 31.67mN/m is (by BZY-2 full application of brake table
Face tensiometer measures), viscosity 3.05cP (is measured by R/S-CC with cylinder rheometer is taken out), and pH value 8.3 (is surveyed by Ph-20 pen type pH
Examination instrument measures).Measure through high temperature (70 DEG C) and low temperature (0 DEG C) weatherability: the black ink-jet printing ink storage stability is good.
Ink-jet printed test on dacron obtains: black ink printing fluency is good, rolls into a ball purity bright in colour,
Line edge is sharp keen.The feel of ink-jet printed front and back dacron is without significant change.It is surveyed using washing fastness described in embodiment 1
Method for testing, the discoloration grade for evaluating sample is 4-5 grades, and staining is 4-5 grades.
Application examples
By blue, red, yellow, black (C, M, Y, K) four primaries aqueous pigment digital ink-jet textile print obtained in embodiment 1-4
Flower ink is respectively charged into large-scale ink-jet decorating machine print cartridge, by the control of ink-jet printed software, by required color and figure
Case prints on dacron；Then the fabric after will be ink-jet printed, with 140 DEG C of temperature, bakes fixation in hot baked machine
5min.
Claims (10)
1. a kind of aqueous pigment digital ink-jet printing in textiles ink, which is characterized in that include dispersible pigment color paste, nano combined bonding
Agent, surfactant, moisturizer, pH adjusting agent, deionized water, the nanocomposite adhesive is by polyaminoester emulsion, organic
Fluorine richness polyacrylate nanoemulsions and another polyacrylate dispersion composition.
2. aqueous pigment digital ink-jet printing in textiles ink as described in claim 1, which is characterized in that the Organic fluoride
Demulsification film forming does not occur after textile ink-jet stamp for modified polyacrylate nanoemulsions, is divided in the form of hydrophobicity nanoparticle
It is distributed in the laminated film that the polyaminoester emulsion and another polyacrylate dispersion are formed.
3. aqueous pigment digital ink-jet printing in textiles ink as described in claim 1, which is characterized in that the Organic fluoride
The synthetic method of modified polyacrylate nanoemulsions includes: by 10-15 parts by weight of methylmethacrylate, 2-4 parts by weight first
Base hexafluorobutyl acrylate, 0-1 parts by weight Emulsifier, 0-1 parts by weight ethylene glycol dimethacrylate are added to 15-25 weight
In part water, stirring, pre-emulsification 25-35min obtains the pre-emulsion of monomer；Then, the pre-emulsion of 25-35 weight parts monomers is added
Enter into reaction vessel, be warming up to 75-85 DEG C, adds the initiator potassium persulfate that 2-5 parts by weight concentration is 0.7%-0.9%
Aqueous solution reacts 25-35min, then 4-8 parts by weight concentration for the initiator potassium persulfate aqueous solution of 0.7%-0.9% and is remained
The pre-emulsion of remaining monomer is added dropwise in reaction vessel simultaneously, reacts 1-3h to get required Organic fluoride modified polypropene is arrived
Acid esters nanoemulsions, partial size 40-70nm.
4. aqueous pigment digital ink-jet printing in textiles ink as claimed in claim 3, which is characterized in that the emulsifier
It is mixed by disappearing 465 and lauryl sodium sulfate SDS of worry with mass ratio 1:1.
5. aqueous pigment digital ink-jet printing in textiles ink as described in claim 1, which is characterized in that the nanometer is multiple
Adhesive is closed by polyaminoester emulsion 10%-50% and Organic fluoride modified polyacrylate nanoemulsions 10%-50% and another
Kind polyacrylate dispersion 10%-50% is combined；The polyaminoester emulsion be MK-119, PU328-9K, PU628-9K,
BY-6336 or BY-6337；Another polyacrylate dispersion is BD-4838, BD-4895, QY-001, QY-003 or QY-004.
6. aqueous pigment digital ink-jet printing in textiles ink as described in claim 1, which is characterized in that the aqueous face
Expect digital ink-jet printing in textiles ink by dispersible pigment color paste 5.0-25.0%, surfactant 0.2-2.0%, nano combined bonding
The deionization of agent 5.0-15.0%, moisturizer 5.0-35.0%, pH adjusting agent 0.5-2.0%, antibacterial agent 0.1-0.5% and surplus
Water composition.
7. aqueous pigment digital ink-jet printing in textiles ink as claimed in claim 6, which is characterized in that the surface is living
Property agent are as follows: BYK-125, BYK-140, benzalkonium chloride, lauryl sodium sulfate, neopelex, ɑ-sodium olefin sulfonate,
Disodium sulfosuccinate, alkyl polyoxyethylene ether ammonium sulfate, nekal, octyl phenol polyoxyethylene ether, Qula lead to X-
100, one of lauric acid alkanolamide, this Pan 20, this Pan 60, this Pan 80 and Tween 80；The moisturizer is 2- pyrroles
Alkanone, n-methyl-2-pyrrolidone, octyl-pyrrolidone, ethylene glycol, diethylene glycol, triethylene glycol, tetraethylene glycol, the third three
Alcohol, 1,2- propylene glycol, 1,3- propylene glycol, methyl propanediol, ethyl hydroxy propylene glycol, a contracting propylene glycol, two contracting propylene glycol, 1,2-
Butanediol, 1,4-butanediol, 1,2,4-butanetriol, 1,5-PD, tert-pentyl alcohol, pentaerythrite, 2- methyl -2,4- pentanediol,
In cyclohexanol, 1,2- hexylene glycol, 2 methyl cyclohexanol, heptandiol, n-octyl alcohol, polyethylene glycol 200, PEG-400 and PEG-800
It is one or more of；The pH adjusting agent is one in ammonium hydroxide, monoethanolamine, ethylene glycol amine, triethanolamine and methylethanolamine
Kind；The antibacterial agent is SilvDurTMET antibacterial agent, HR-25 fabric antimicrobial finishing agent, GOOD NICE and AEM5772-5 are anti-
One of mould antibacterial agent.
8. aqueous pigment digital ink-jet printing in textiles ink as described in claim 1, which is characterized in that the aqueous face
Expect that viscosity of the digital ink-jet printing in textiles ink at 25 DEG C of temperature is 2.0-10.0cP, surface tension 20-60mN/m, pH
Value is 7-9.
9. the preparation method of aqueous pigment digital ink-jet printing in textiles ink described in any one of claim 6-8, special
Sign is, comprising:
Step 1: first in proportion by surfactant 0.2-2.0%, nanocomposite adhesive 5.0-15.0%, moisturizer
5.0-35.0%, pH adjusting agent 0.5-2.0% and antibacterial agent 0.1-0.5% are added in the deionized water of surplus, then with high
Fast blender stirs 40-100min with the revolving speed of 2000-4500rad/min, becomes uniform dicyandiamide solution；
Step 2: dispersible pigment color paste 5.0-25.0% is added in above-mentioned dicyandiamide solution, with high-speed mixer with 1000-
The revolving speed of 3000rad/min stirs 20-60min, becomes uniform ink dispersion；
Step 3: by obtained ink dispersion be 0.2-1.0 μm with aperture filtering with microporous membrane to get aqueous pigment
Digital ink-jet printing in textiles ink.
10. aqueous pigment digital ink-jet printing in textiles ink of any of claims 1-8 sprays in various fabrics
Ink-printed method characterized by comprising by blue, red, yellow, black four primaries aqueous pigment digital ink-jet printing in textiles ink
Water is respectively charged into large-scale ink-jet decorating machine print cartridge, and by the control of ink-jet printed software, required color and pattern are beaten
It prints on fabric；Then the fabric after will be ink-jet printed, with 120-160 DEG C of temperature, bakes fixation 4-6min in hot baked machine
?.
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| CN113047066B (en) * | 2021-03-18 | 2023-05-12 | 常州喜莱维纺织科技有限公司 | Ink-jet printed fabric and preparation method thereof |
| CN113026384B (en) * | 2021-03-18 | 2023-01-03 | 常州喜莱维纺织科技有限公司 | Fabric micro-printing method |
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