CN106367600A - A method of treating high-zinc and iron-containing dust sludge by using a rotary kiln - Google Patents
A method of treating high-zinc and iron-containing dust sludge by using a rotary kiln Download PDFInfo
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- CN106367600A CN106367600A CN201610737311.5A CN201610737311A CN106367600A CN 106367600 A CN106367600 A CN 106367600A CN 201610737311 A CN201610737311 A CN 201610737311A CN 106367600 A CN106367600 A CN 106367600A
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- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 title claims abstract description 86
- 239000000428 dust Substances 0.000 title claims abstract description 67
- 239000011701 zinc Substances 0.000 title claims abstract description 44
- 229910052742 iron Inorganic materials 0.000 title claims abstract description 43
- 229910052725 zinc Inorganic materials 0.000 title claims abstract description 43
- 238000000034 method Methods 0.000 title claims abstract description 34
- 239000010802 sludge Substances 0.000 title description 10
- 239000008188 pellet Substances 0.000 claims abstract description 60
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 51
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims abstract description 45
- 239000003546 flue gas Substances 0.000 claims abstract description 45
- 229910052799 carbon Inorganic materials 0.000 claims abstract description 41
- 239000003245 coal Substances 0.000 claims abstract description 29
- 239000000463 material Substances 0.000 claims abstract description 29
- 239000002245 particle Substances 0.000 claims abstract description 28
- 238000001035 drying Methods 0.000 claims abstract description 26
- 239000002131 composite material Substances 0.000 claims abstract description 25
- 239000007921 spray Substances 0.000 claims abstract description 25
- 238000001816 cooling Methods 0.000 claims abstract description 20
- 239000007789 gas Substances 0.000 claims abstract description 12
- 238000006722 reduction reaction Methods 0.000 claims description 34
- 238000002485 combustion reaction Methods 0.000 claims description 21
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 17
- 239000000696 magnetic material Substances 0.000 claims description 12
- 238000005453 pelletization Methods 0.000 claims description 10
- 238000002347 injection Methods 0.000 claims description 9
- 239000007924 injection Substances 0.000 claims description 9
- 229910052751 metal Inorganic materials 0.000 claims description 9
- 239000002184 metal Substances 0.000 claims description 9
- 238000001465 metallisation Methods 0.000 claims description 9
- 238000006243 chemical reaction Methods 0.000 claims description 6
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Inorganic materials [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims description 6
- 238000002309 gasification Methods 0.000 claims description 5
- 235000013980 iron oxide Nutrition 0.000 claims description 5
- 239000003500 flue dust Substances 0.000 claims description 4
- 239000000446 fuel Substances 0.000 claims description 4
- 229910052500 inorganic mineral Inorganic materials 0.000 claims description 4
- 239000011707 mineral Substances 0.000 claims description 4
- 238000002156 mixing Methods 0.000 claims description 4
- 238000011084 recovery Methods 0.000 claims description 4
- 239000011435 rock Substances 0.000 claims description 4
- 239000000919 ceramic Substances 0.000 claims description 3
- 239000003638 chemical reducing agent Substances 0.000 claims description 3
- 229930195733 hydrocarbon Natural products 0.000 claims description 3
- 150000002430 hydrocarbons Chemical class 0.000 claims description 3
- 239000000203 mixture Substances 0.000 claims description 3
- 238000006213 oxygenation reaction Methods 0.000 claims description 3
- 230000036632 reaction speed Effects 0.000 claims description 3
- 239000004215 Carbon black (E152) Substances 0.000 claims description 2
- 239000003795 chemical substances by application Substances 0.000 claims description 2
- VBMVTYDPPZVILR-UHFFFAOYSA-N iron(2+);oxygen(2-) Chemical class [O-2].[Fe+2] VBMVTYDPPZVILR-UHFFFAOYSA-N 0.000 claims description 2
- 238000007885 magnetic separation Methods 0.000 claims description 2
- 238000000926 separation method Methods 0.000 claims description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 2
- 244000046052 Phaseolus vulgaris Species 0.000 claims 3
- 235000010627 Phaseolus vulgaris Nutrition 0.000 claims 3
- 239000000843 powder Substances 0.000 claims 3
- 239000000470 constituent Substances 0.000 claims 2
- 239000012716 precipitator Substances 0.000 claims 1
- 238000005507 spraying Methods 0.000 claims 1
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 abstract description 41
- 229910000831 Steel Inorganic materials 0.000 abstract description 9
- 239000010959 steel Substances 0.000 abstract description 9
- 238000007596 consolidation process Methods 0.000 abstract description 4
- 238000009825 accumulation Methods 0.000 abstract description 2
- 238000003912 environmental pollution Methods 0.000 abstract description 2
- 235000014692 zinc oxide Nutrition 0.000 description 17
- 239000011787 zinc oxide Substances 0.000 description 16
- 238000004519 manufacturing process Methods 0.000 description 7
- 238000005245 sintering Methods 0.000 description 6
- 230000005484 gravity Effects 0.000 description 5
- 239000011734 sodium Substances 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- 229910052739 hydrogen Inorganic materials 0.000 description 3
- 239000001257 hydrogen Substances 0.000 description 3
- 239000006148 magnetic separator Substances 0.000 description 3
- 235000010755 mineral Nutrition 0.000 description 3
- 229910052708 sodium Inorganic materials 0.000 description 3
- 238000009628 steelmaking Methods 0.000 description 3
- 239000010878 waste rock Substances 0.000 description 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 2
- 229910004298 SiO 2 Inorganic materials 0.000 description 2
- 229910052783 alkali metal Inorganic materials 0.000 description 2
- 150000001340 alkali metals Chemical class 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- 239000003610 charcoal Substances 0.000 description 2
- 238000004891 communication Methods 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 230000001590 oxidative effect Effects 0.000 description 2
- 229910052700 potassium Inorganic materials 0.000 description 2
- 239000002893 slag Substances 0.000 description 2
- 239000002910 solid waste Substances 0.000 description 2
- 239000002699 waste material Substances 0.000 description 2
- -1 CH 4 Substances 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 229910002091 carbon monoxide Inorganic materials 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 238000005272 metallurgy Methods 0.000 description 1
- 239000004570 mortar (masonry) Substances 0.000 description 1
- 230000001706 oxygenating effect Effects 0.000 description 1
- 230000000149 penetrating effect Effects 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- RNWHGQJWIACOKP-UHFFFAOYSA-N zinc;oxygen(2-) Chemical class [O-2].[Zn+2] RNWHGQJWIACOKP-UHFFFAOYSA-N 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B7/00—Working up raw materials other than ores, e.g. scrap, to produce non-ferrous metals and compounds thereof; Methods of a general interest or applied to the winning of more than two metals
- C22B7/02—Working-up flue dust
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B1/00—Preliminary treatment of ores or scrap
- C22B1/14—Agglomerating; Briquetting; Binding; Granulating
- C22B1/16—Sintering; Agglomerating
- C22B1/216—Sintering; Agglomerating in rotary furnaces
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B1/00—Preliminary treatment of ores or scrap
- C22B1/14—Agglomerating; Briquetting; Binding; Granulating
- C22B1/24—Binding; Briquetting ; Granulating
- C22B1/2406—Binding; Briquetting ; Granulating pelletizing
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B7/00—Working up raw materials other than ores, e.g. scrap, to produce non-ferrous metals and compounds thereof; Methods of a general interest or applied to the winning of more than two metals
- C22B7/001—Dry processes
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
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- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Mechanical Engineering (AREA)
- Geology (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Environmental & Geological Engineering (AREA)
- Materials Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Geochemistry & Mineralogy (AREA)
- Manufacture And Refinement Of Metals (AREA)
Abstract
本发明涉及一种利用回转窑处理高锌含铁尘泥的方法,高炉瓦斯灰、转炉OG泥混合、造球;湿球团干燥预热,干燥预热热源为回转窑高温烟气经高低温复合空气换热器产生的热风;在回转窑窑头设置粒煤喷枪、残炭喷枪和粒矿喷枪,将高挥发份煤、残炭、高品位铁矿喷吹入窑;干燥后的球团送入回转窑,在回转窑内直接还原及高温固结后,得到高温金属化球团;金属化球团与过剩残炭等物料经冷却到常温后,磁选分离,得到金属化球团;出回转窑的高温烟气经脱除大颗粒粉尘,再进入高低温复合空气换热器冷却,然后进入布袋除尘器,回收氧化锌粉。本发明使钢铁企业产生的高锌含铁尘泥得到了高效利用,解决了高锌含铁尘泥堆积所造成的环境污染。
The present invention relates to a method for treating high-zinc iron-containing dust and mud by using a rotary kiln, wherein blast furnace gas ash and converter OG mud are mixed and pelletized; wet pellets are dried and preheated, and the drying and preheating heat source is the hot air generated by the high-temperature flue gas of the rotary kiln through a high-low temperature composite air heat exchanger; a granular coal spray gun, a residual carbon spray gun and a granular ore spray gun are arranged at the kiln head of the rotary kiln, and high-volatile coal, residual carbon and high-grade iron ore are sprayed into the kiln; the dried pellets are sent to the rotary kiln, and high-temperature metallized pellets are obtained after direct reduction and high-temperature consolidation in the rotary kiln; the metallized pellets and materials such as excess residual carbon are cooled to room temperature and magnetically separated to obtain metallized pellets; the high-temperature flue gas out of the rotary kiln is subjected to large-particle dust removal, and then enters the high-low temperature composite air heat exchanger for cooling, and then enters the bag filter to recover zinc oxide powder. The present invention makes efficient use of the high-zinc iron-containing dust and mud generated by steel enterprises, and solves the environmental pollution caused by the accumulation of high-zinc iron-containing dust and mud.
Description
技术领域technical field
本发明涉及冶金和矿物工程技术领域,是一种钢铁企业高锌含铁尘泥生产金属化炉料、回收氧化锌粉的工艺。The invention relates to the technical field of metallurgy and mineral engineering, and relates to a process for producing metallized charge and recovering zinc oxide powder from high-zinc and iron-containing dust in iron and steel enterprises.
背景技术Background technique
含铁尘泥是钢铁工业种类最多、成分最杂的固体废物,总产生量约占钢铁产量的5~6%,是仅次于高炉渣、钢渣的第三大宗固体废物。钢铁生产过程中产生的含铁尘泥主要有:烧结除尘灰、球团除尘灰、高炉瓦斯灰、转炉OG泥、炼钢除尘灰、出铁场集尘等。含铁尘泥的主要成分为铁,其铁含量一般为TFe30~65%,同时含有一定的Zn 、K、Na等有害元素,其中高炉瓦斯灰泥含Zn高的可达7~10%,在此称为高锌含铁尘泥。Iron-containing dust is the solid waste with the most types and the most complex components in the iron and steel industry. The total production volume accounts for about 5-6% of the iron and steel production, and it is the third largest solid waste after blast furnace slag and steel slag. The iron-containing dust generated in the steel production process mainly includes: sintering dust, pellet dust, blast furnace gas dust, converter OG mud, steelmaking dust, casthouse dust, etc. The main component of iron-containing dust sludge is iron, and its iron content is generally TFe30-65%, and it also contains certain harmful elements such as Zn, K, Na, etc. Among them, the Zn content of blast furnace gas mortar can reach 7-10%. This is called high-zinc iron-containing dust.
在钢铁企业中,炼铁及炼钢尘泥中锌主要以ZnO形式存在,当含铁尘泥供烧结进行利用时,由于烧结过程为氧化性气氛,物料中含有的氧化锌仍然会留存在烧结矿中,最终造成锌在高炉内的循环富集,影响高炉的正常生产。目前,除烧结除尘灰、球团除尘灰供烧结机进行利用外,其余高锌含铁尘泥大量堆积。In iron and steel enterprises, zinc in ironmaking and steelmaking dust mainly exists in the form of ZnO. When iron-containing dust is used for sintering, since the sintering process is an oxidizing atmosphere, the zinc oxide contained in the material will still remain in the sintering process. In the mine, it will eventually cause the cyclic enrichment of zinc in the blast furnace, affecting the normal production of the blast furnace. At present, except for sintering dust removal and pellet dust removal, which are used by sintering machines, other high-zinc iron-containing dust sludge is accumulated in large quantities.
目前存在用回转窑处理高锌含铁尘泥的工艺,但存在收集的锌灰ZnO含量低、脱锌率低、还原后的物料金属化率低、回转窑产能低等问题。目前处理高锌含铁尘泥的回转窑工艺不造球,因此在回转窑转动过程中产生大量粉尘,粉尘随烟气进入除尘系统,经布袋除尘后,进入锌灰,使收集的锌灰ZnO含量降低;由于没有采取措施强化窑内还原性气氛,在高温还原中后期还原性气氛较弱,还原反应速度降低、甚至停滞,造成还原后的物料金属化率低、还原后的物料中含锌仍然较高(1%左右)、脱锌率低、回转窑产能低等问题。At present, there is a process of using a rotary kiln to treat high-zinc and iron-containing dust, but there are problems such as low ZnO content in the collected zinc ash, low dezincification rate, low metallization rate of the reduced material, and low production capacity of the rotary kiln. At present, the rotary kiln process for processing high-zinc and iron-containing dust sludge does not make pellets, so a large amount of dust is generated during the rotation of the rotary kiln, and the dust enters the dust removal system with the flue gas, and enters the zinc ash after bag dust removal, making the collected zinc ash ZnO As no measures have been taken to strengthen the reducing atmosphere in the kiln, the reducing atmosphere is weak in the middle and later stages of high-temperature reduction, and the reduction reaction speed decreases or even stagnates, resulting in low metallization rate of the reduced material and zinc content in the reduced material Still high (about 1%), low dezincification rate, low production capacity of rotary kiln and other problems.
发明内容Contents of the invention
本发明为解决以上技术问题,提出一种利用回转窑处理高锌含铁尘泥的方法。In order to solve the above technical problems, the present invention proposes a method for treating high-zinc iron-containing dust and sludge by using a rotary kiln.
本发明采用的技术方案是:一种利用回转窑处理高锌含铁尘泥的方法,其步骤为:(1)高炉瓦斯灰、转炉OG泥按30~40:60~70比例配料及混合后,采用圆盘造球方法生产粒度为8~15mm的湿球团;(2)湿球团经皮带输送到链箅机或带式干燥机,进行干燥预热,干燥预热所需热源为回转窑高温烟气经空气换热器产生的热风;(3)球团经干燥预热后的温度为500℃左右,球团由链箅机或带式干燥机送入回转窑,在回转窑内经过窑温1050~1100℃、时间90~120min的直接还原及高温固结后,得到高温金属化球团,回转窑由含碳燃料燃烧放热,高温金属化球团混有残炭;(4)混有残炭的高温金属化球团冷却到常温后,经干式磁选机进行磁选分离,分离出磁性物料和非磁性物料,得到金属化率及强度较高的金属化球团和非磁性物料,所得金属化球团供给高炉或转炉使用,非磁性物料经3mm振动筛筛分后,-3mm部分作为整个系统的排灰点排出,+3mm部分经矿物分离机分出残炭和废石,废石排出,残炭作为可回收物料,回收利用;(5)回转窑设二次燃烧室,出回转窑的高温烟气经二次燃烧室将回转窑排出的烟气中未完全燃烧的可燃物进行二次燃烧,烟气进一步经重力除尘器脱除大颗粒粉尘,而后进入高低温复合空气换热器冷却,烟气冷却后温度降至180~200℃,然后进入布袋除尘器,回收含氧化锌粉烟尘,回收的含氧化锌粉烟尘含有ZnO 50~60%。The technical scheme adopted in the present invention is: a method for treating high-zinc iron-containing dust sludge by using a rotary kiln, the steps of which are: (1) Blast furnace gas ash and converter OG mud are mixed in a ratio of 30-40:60-70 and mixed , using the disc pelletizing method to produce wet pellets with a particle size of 8-15mm; (2) The wet pellets are transported to the chain grate machine or belt dryer through the belt for drying and preheating. The heat source required for drying and preheating is rotary The high-temperature flue gas of the kiln passes through the hot air generated by the air heat exchanger; (3) The temperature of the pellets after drying and preheating is about 500°C, and the pellets are sent into the rotary kiln by a chain grate machine or a belt dryer. After direct reduction and high-temperature consolidation at a kiln temperature of 1050-1100°C for 90-120 minutes, high-temperature metallized pellets are obtained. The rotary kiln burns carbon-containing fuel to release heat, and the high-temperature metallized pellets are mixed with residual carbon; (4 ) After the high-temperature metallized pellets mixed with residual carbon are cooled to normal temperature, they are separated by magnetic separation through a dry magnetic separator to separate magnetic materials and non-magnetic materials, and obtain metallized pellets with high metallization rate and strength and For non-magnetic materials, the obtained metallized pellets are used in blast furnaces or converters. After the non-magnetic materials are screened by a 3mm vibrating screen, the -3mm part is discharged as the ash discharge point of the entire system, and the +3mm part is separated by a mineral separator. Waste rocks, waste rocks are discharged, and residual charcoal is used as recyclable materials for recycling; (5) The rotary kiln is equipped with a secondary combustion chamber, and the high-temperature flue gas exiting the rotary kiln passes through the secondary combustion chamber to incompletely exhaust the flue gas discharged from the rotary kiln. The burned combustibles undergo secondary combustion. The flue gas is further removed by the gravity dust collector to remove large particles of dust, and then enters the high-low temperature composite air heat exchanger for cooling. After the flue gas is cooled, the temperature drops to 180-200°C, and then enters the bag filter. , Recovery of dust containing zinc oxide powder, the recovery of dust containing zinc oxide powder contains ZnO 50 ~ 60%.
所述高低温复合空气换热器接受的烟气温度不大于1000℃,高低温复合空气换热器与二次燃烧室之间的连通通道设有掺冷风机,当二次燃烧室排出烟气温度大于1000℃时,掺冷风机开启,向连通通道吹入冷风,高温烟气掺混冷风后降温至1000℃以下,所述高低温复合空气换热器为二级换热器,第一级高温段为陶瓷换热器,可将高温烟气温度降至600℃左右,并产生500~700℃的高温热风,第二级低温段为金属换热器,将高温烟气温度由600℃左右降至180~200℃,并产生300~400℃的低温热风;高低温复合空气换热器产生的300~400℃热风鼓入链箅机或带式干燥机干燥段,作为湿球团干燥热源,产生的500~700℃热风一部分鼓入链箅机或带式干燥机预热段,作为球团预热热源;一部分由回转窑窑头鼓入窑内作为高温助燃风。The flue gas temperature received by the high-low temperature composite air heat exchanger is not greater than 1000°C, and the communication channel between the high-low temperature composite air heat exchanger and the secondary combustion chamber is provided with a cooling fan, and when the secondary combustion chamber discharges the flue gas When the temperature is higher than 1000°C, the cooling fan is turned on, and cold air is blown into the communication channel. After the high-temperature flue gas is mixed with cold air, the temperature is lowered to below 1000°C. The high-low temperature composite air heat exchanger is a secondary heat exchanger, and the first stage The high-temperature section is a ceramic heat exchanger, which can reduce the temperature of high-temperature flue gas to about 600°C and generate high-temperature hot air at 500-700°C. The second-stage low-temperature section is a metal heat exchanger, which can reduce the temperature of high-temperature flue gas from about 600°C. Lower to 180-200°C, and generate 300-400°C low-temperature hot air; 300-400°C hot air generated by the high-low temperature composite air heat exchanger is blown into the drying section of the chain grate machine or belt dryer, as a heat source for drying wet pellets , part of the 500-700°C hot air generated is blown into the preheating section of the chain grate machine or belt dryer as a heat source for pellet preheating; part of it is blown into the kiln from the rotary kiln head as high-temperature combustion-supporting air.
所述湿球团干燥预热的时间为20~40min。The drying and preheating time of the wet pellets is 20-40 minutes.
混有残炭的高温金属化球团却到常温时所用的冷却机构为间接式水冷冷却筒。The cooling mechanism used when the high-temperature metallized pellets mixed with residual carbon are cooled to normal temperature is an indirect water-cooled cooling cylinder.
在所述高低温复合空气换热器的烟气通道内设置集尘漏斗,进一步脱除烟气中的粉尘,以此提高所回收的含氧化锌粉烟尘中的ZnO含量。A dust collection funnel is arranged in the flue gas channel of the high-low temperature composite air heat exchanger to further remove dust in the flue gas, thereby increasing the ZnO content in the recycled flue dust containing zinc oxide powder.
在回转窑窑头设置粒煤喷枪、残炭喷枪和粒矿喷枪,粒煤喷枪喷吹粒度为5~15mm高挥发份煤,喷吹粒煤的比例为球团质量的5~10%;残炭喷枪喷吹粒度为3~15mm残炭,喷吹残炭的比例为球团质量的3~5%;粒矿喷枪喷吹粒度为5~10mm高品位铁矿,喷吹高品位铁矿的比例为球团质量的15~20%。At the kiln head of the rotary kiln, a granulated coal spray gun, a residual carbon spray gun and a granulated ore spray gun are installed. The granular coal spray gun sprays high-volatile coal with a particle size of 5-15mm, and the proportion of the granulated coal injected is 5-10% of the pellet mass; The particle size of the carbon spray gun is 3-15mm residual carbon, and the proportion of the injected residual carbon is 3-5% of the mass of the pellets; The proportion is 15-20% of the pellet mass.
进一步的,以窑头出口为回转窑窑长起点,粒度为5~15mm高挥发份煤喷吹到回转窑窑长的1/2~1/3处,粒度为3~15mm的残炭喷吹到回转窑窑长的3/5~1/2处,粒度为5~10mm高品位铁矿喷吹到回转窑窑长的1/2~1/3处;喷吹入窑的高挥发份煤在窑内高温下,放出挥发份,挥发份中的H2在穿过料层时作为还原剂,高挥发份煤中的C及残炭中的C与料层内产生的CO2发生碳气化反应放出CO,实现了碳氢联合还原,提高还原反应速度,高品位铁矿粒喷入窑后,在窑内高温下,粒矿中的铁氧化物与料层内的CO发生反应放出CO2,CO2作为“增氧剂”与喷入窑内的高挥发粒煤中的C及残炭中的C发生碳气化反应放出两倍的CO,增强了料层内的还原性气氛,改善了还原反应动力学条件,这就是高品位粒矿的“增氧”作用。Further, take the outlet of the kiln head as the starting point of the length of the rotary kiln, inject high-volatile coal with a particle size of 5-15mm to 1/2-1/3 of the length of the rotary kiln, and inject residual carbon with a particle size of 3-15mm To 3/5~1/2 of the length of the rotary kiln, the high-grade iron ore with a particle size of 5~10mm is injected to 1/2~1/3 of the length of the rotary kiln; the high volatile coal injected into the kiln At high temperature in the kiln, the volatile matter is released, and the H2 in the volatile matter acts as a reducing agent when passing through the material layer, and the C in the high-volatile coal and the C in the residual carbon and the CO2 produced in the material layer generate carbon gas The reaction releases CO, realizes the combined reduction of carbon and hydrogen, and increases the reduction reaction speed. After the high-grade iron ore particles are sprayed into the kiln, the iron oxides in the granular ore react with the CO in the material layer to release CO under high temperature in the kiln. 2 , CO 2 is used as an "oxygenating agent" to undergo a carbon gasification reaction with C in the highly volatile granular coal and C in the residual carbon injected into the kiln to release twice as much CO, which enhances the reducing atmosphere in the material layer, Improve the kinetic conditions of the reduction reaction, which is the "oxygenation" effect of high-grade granular ore.
本发明所取得的有益效果是:1、本发明在处理高锌含铁尘泥的同时,有效利用了尘泥中铁及碳资源,大幅度降低了尘泥中锌、钾和钠等有害碱金属元素,降低了高炉碱金属负荷,对提高高炉使用寿命具有重要意义;The beneficial effects obtained by the present invention are: 1. The present invention effectively utilizes the iron and carbon resources in the dust and greatly reduces the harmful alkali metals such as zinc, potassium and sodium in the dust while processing high-zinc and iron-containing dust; elements, reducing the alkali metal load of the blast furnace, which is of great significance to improving the service life of the blast furnace;
2、通过利用回转窑处理高锌含铁尘泥,不仅可回收高品质氧化锌粉,而且还可以生产出金属化率及强度较高的金属化球团供给高炉使用;2. By using the rotary kiln to process high-zinc iron-containing dust and sludge, not only can high-quality zinc oxide powder be recovered, but also metallized pellets with high metallization rate and strength can be produced for use in blast furnaces;
3、通过在窑头喷吹高挥发份粒煤、残炭、粒矿,实现了碳氢联合还原,增强了还原反应中后期的还原气氛,强化了铁、锌氧化物的还原反应,解决了回转窑处理高锌含铁尘泥金属化率较低、锌含量较高的问题;3. By injecting high-volatile granular coal, residual carbon, and granular ore at the kiln head, the joint reduction of carbon and hydrogen is realized, the reducing atmosphere in the middle and later stages of the reduction reaction is enhanced, and the reduction reaction of iron and zinc oxides is strengthened, which solves the problem of Rotary kiln to deal with the problems of low metallization rate and high zinc content of high-zinc iron-containing dust sludge;
4、本发明使钢铁企业产生的高锌含铁尘泥得到了高效利用,解决了高锌含铁尘泥堆积所造成的环境污染。4. The present invention makes efficient use of the high-zinc and iron-containing dust produced by iron and steel enterprises, and solves the environmental pollution caused by the accumulation of high-zinc and iron-containing dust.
附图说明Description of drawings
图1是本发明的工艺流程图;Fig. 1 is a process flow diagram of the present invention;
图2是本发明的设备关系简图。Fig. 2 is a schematic diagram of the device relationship of the present invention.
具体实施方式detailed description
本发明为利用钢铁企业生产过程中产生的炼铁及炼钢高锌含铁尘泥生产高炉或转炉用的金属化炉料,采用的生产工艺为:(1)高炉瓦斯灰、转炉OG泥按30~40:60~70比例配料及混合后,采用圆盘造球方法生产粒度为8~15mm的湿球团;(2)湿球团经皮带输送到链箅机(或带式干燥机,分干燥段和预热段)进行干燥预热,干燥预热热源为回转窑高温烟气经空气换热器产生的热风。回转窑排烟温度在800℃以上,回转窑后设二次燃烧室,将回转窑排出的烟气中未燃烧完全的可燃物进行二次燃烧,二次燃烧室排出烟气温度为1000℃左右,二次燃烧室烟气经高低温复合空气换热器产生高温热风(500~700℃)和低温热风(300~400℃)。二次燃烧室烟气进入高低温复合空气换热器前设置掺冷风机保护,当二次燃烧室排出烟气温度大于1000℃时,掺冷风机开启。高低温复合空气换热器为二级换热器,第一级高温段为陶瓷换热器,可将高温烟气温度由1000℃左右降至600℃左右,并产生500~700℃的高温热风;第二级低温段为金属换热器,可将高温烟气温度由600℃左右降至180~200℃,并产生300~400℃的低温热风。高低温复合空气换热器产生的低温热风(300~400℃)鼓入链箅机(或带式干燥机)的干燥段,作为湿球团干燥热源,产生的高温热风(500~700℃)一部分鼓入链箅机(或带式干燥机)的预热段,作为球团预热热源;一部分由回转窑窑头鼓入窑内作为高温助燃风。湿球团在链箅机(或带式干燥机)上的干燥预热时间为20~40min;(3)在回转窑窑头设置粒煤喷枪、残炭喷枪和粒矿喷枪,粒煤喷枪喷吹粒度为5~15mm高挥发份煤,喷吹粒煤的比例为球团量的5~10%;残炭喷枪喷吹粒度为3~15mm残炭,喷吹残炭的比例为球团量的3~5%;粒矿喷枪喷吹粒度为5~10mm高品位铁矿,喷吹高品位铁矿的比例为球团量的15~20%;(4)干燥预热后的球团(温度500℃左右)由链箅机(或带式干燥机)送入回转窑,在回转窑内经过窑温1050~1100℃、时间90~120min的直接还原及高温固结后,得到高温金属化球团。由金属化球团与过剩残炭等组成的高温混合物料经间接式水冷冷却筒冷却到常温后,经干式磁选机进行磁选分离,分离出磁性物料和非磁性物料,得到金属化率及强度较高的金属化球团和非磁性物料(残炭及废石),金属化球团供给高炉或转炉使用,非磁性物料经3mm振动筛筛分后,-3mm部分作为整个系统的排灰点排出,+3mm部分经矿物分离机分出残炭和废石,废石排出,残炭返回到回转窑窑头残炭料仓,再经回转窑窑头残炭喷枪喷入窑内循环使用;(5)出回转窑的高温烟气经二次燃烧室将回转窑排出的烟气中未燃烧完全的可燃物进行二次燃烧,再经重力除尘器脱除大颗粒粉尘,而后进入高低温复合空气换热器冷却,烟气冷却后温度降至180~200℃,然后进入布袋除尘器,回收氧化锌粉烟尘,含ZnO50~60%。The present invention utilizes ironmaking and steelmaking high-zinc iron-containing dust sludge produced in the production process of iron and steel enterprises to produce metallized charge for blast furnace or converter. ~40: 60~70 ratio of ingredients and mixing, the disc pelletizing method is used to produce wet pellets with a particle size of 8-15mm; (2) The wet pellets are conveyed to the chain grate machine (or belt dryer, drying section and preheating section) for drying and preheating, and the heat source for drying and preheating is the hot air generated by the high-temperature flue gas of the rotary kiln passing through the air heat exchanger. The exhaust gas temperature of the rotary kiln is above 800°C. A secondary combustion chamber is installed behind the rotary kiln to perform secondary combustion on the unburned combustibles in the flue gas discharged from the rotary kiln. The temperature of the flue gas discharged from the secondary combustion chamber is about 1000°C. , The flue gas from the secondary combustion chamber passes through the high-low temperature composite air heat exchanger to generate high-temperature hot air (500-700°C) and low-temperature hot air (300-400°C). Before the flue gas from the secondary combustion chamber enters the high-low temperature composite air heat exchanger, a cooling fan is installed for protection. When the temperature of the flue gas discharged from the secondary combustion chamber is greater than 1000 ° C, the cooling fan is turned on. The high-low temperature composite air heat exchanger is a two-stage heat exchanger, and the first-stage high-temperature section is a ceramic heat exchanger, which can reduce the temperature of high-temperature flue gas from about 1000°C to about 600°C, and generate high-temperature hot air at 500-700°C ; The second low-temperature section is a metal heat exchanger, which can reduce the temperature of high-temperature flue gas from about 600°C to 180-200°C, and generate low-temperature hot air at 300-400°C. The low-temperature hot air (300-400°C) generated by the high-low temperature composite air heat exchanger is blown into the drying section of the chain grate machine (or belt dryer) as the heat source for drying the wet pellets, and the high-temperature hot air (500-700°C) generated Part of it is blown into the preheating section of the chain grate machine (or belt dryer) as a heat source for pellet preheating; the other part is blown into the kiln from the rotary kiln head as high-temperature combustion-supporting air. The drying and preheating time of the wet pellets on the chain grate machine (or belt dryer) is 20 to 40 minutes; (3) The granular coal spray gun, residual carbon spray gun and granular ore spray gun are installed at the kiln head of the rotary kiln. Blow particle size of 5 ~ 15mm high volatile coal, the proportion of pelletized coal injection is 5 ~ 10% of the amount of pellets; residual carbon spray gun injection particle size of 3 ~ 15mm residual carbon, the proportion of injection residual carbon is the amount of pellets 3-5% of the pellets; the particle size of the ore spray gun is 5-10mm high-grade iron ore, and the proportion of the high-grade iron ore injected is 15-20% of the pellets; (4) The pellets after drying and preheating ( The temperature is about 500°C) is sent to the rotary kiln by the chain grate machine (or belt dryer), and after direct reduction and high-temperature consolidation at a kiln temperature of 1050-1100°C and a time of 90-120 minutes in the rotary kiln, high-temperature metallization is obtained pellets. The high-temperature mixed material composed of metallized pellets and excess residual carbon is cooled to room temperature by an indirect water-cooled cooling cylinder, and then magnetically separated by a dry-type magnetic separator to separate magnetic materials and non-magnetic materials, and the metallization rate is obtained. And metallized pellets with high strength and non-magnetic materials (residual carbon and waste rock). The metallized pellets are supplied to blast furnaces or converters. After the non-magnetic materials are screened by a 3mm vibrating screen, the -3mm part is used as the discharge of the entire system. The ash point is discharged, and the +3mm part is separated into residual carbon and waste rock by the mineral separator, and the waste rock is discharged, and the residual carbon is returned to the residual carbon silo at the kiln head of the rotary kiln, and then sprayed into the kiln by the residual carbon spray gun at the rotary kiln head for circulation Use; (5) The high-temperature flue gas from the rotary kiln passes through the secondary combustion chamber to carry out secondary combustion of the unburned combustibles in the flue gas discharged from the rotary kiln, and then removes large particles of dust through the gravity dust collector, and then enters the high-temperature The low-temperature composite air heat exchanger is cooled, and the temperature of the flue gas is reduced to 180-200 °C after cooling, and then enters the bag filter to recover zinc oxide powder dust, which contains 50-60% ZnO.
在回转窑窑头设置粒煤喷枪,将粒度为5~15mm高挥发份煤喷吹到距窑头出口为回转窑窑长的1/2~1/3处,将粒度为3~15mm的残炭喷吹到距窑头出口为回转窑窑长的3/5~1/2处。距窑头出口为回转窑窑长的1/2~1/3处大致处于窑内高温还原段的中后段,此处瓦斯灰中的碳大部分已消耗,料层内还原性气氛较弱,抛入高挥发份粒煤后,高挥发粒煤中的C及残炭中的C与料层内产生的CO2发生碳气化反应放出CO,增强了料层内的还原性气氛,改善了还原反应动力学条件,有利于提高还原反应速度。同时,喷吹入窑的高挥发份粒煤在窑内高温下,放出挥发份,挥发份中的CH4、焦油、苯、萘等可燃物在回转窑内燃烧做加热燃料,挥发份中的H2在穿过料层时将作为还原剂,还原料层中的铁氧化物,由于H2具有低温还原能力强、穿透能力强的特点,对提高还原速度非常有利。在还原前期,球团温度低于800℃时,以H2还原为主;在还原中后期,球团温度高于800℃时,以CO还原为主,这就是碳氢联合还原技术。Set a granular coal spray gun at the kiln head of the rotary kiln, inject high-volatile coal with a particle size of 5-15mm to a place 1/2-1/3 of the length of the rotary kiln from the outlet of the kiln head, and spray the residual coal with a particle size of 3-15mm The charcoal is injected to the 3/5~1/2 of the length of the rotary kiln from the kiln head outlet. The distance from the exit of the kiln head is 1/2 to 1/3 of the length of the rotary kiln, which is roughly in the middle and rear of the high-temperature reduction section in the kiln, where most of the carbon in the gas ash has been consumed, and the reducing atmosphere in the material layer is relatively weak After throwing high-volatility granular coal, C in high-volatility granular coal and C in residual carbon will undergo carbon gasification reaction with CO2 generated in the material layer to release CO, which enhances the reducing atmosphere in the material layer and improves the The kinetic conditions of the reduction reaction are conducive to increasing the reduction reaction rate. At the same time, the high-volatile granular coal injected into the kiln releases volatile matter at high temperature in the kiln. Combustible substances such as CH 4 , tar, benzene, and naphthalene in the volatile matter are burned in the rotary kiln as heating fuel. When H2 passes through the material layer, it will be used as a reducing agent to reduce the iron oxide in the material layer. Since H2 has the characteristics of strong low-temperature reducing ability and strong penetrating ability, it is very beneficial to increase the reduction speed. In the early stage of reduction, when the pellet temperature is lower than 800°C, H2 reduction is the main method; in the middle and later stages of reduction, when the pellet temperature is higher than 800°C, CO reduction is the main method. This is the combined hydrocarbon reduction technology.
在回转窑窑头设置粒矿喷枪,将粒度为5~10mm的高品位粒矿喷吹到距窑头出口为回转窑窑长的1/2~1/3处。距窑头出口为回转窑窑长的1/2~1/3处大致处于窑内高温还原段的中后段,此处瓦斯灰中的碳大部分已消耗,料层内还原性气氛较弱。喷入粒矿后,在窑内高温下,喷吹入窑的高品位粒矿中的铁氧化物与料层内的CO发生还原反应放出CO2,CO2作为“增氧剂”与喷入窑内的高挥发粒煤中的C及残炭中的C发生碳气化反应放出两倍的CO,增强了料层内的还原性气氛,改善了还原反应动力学条件,有利于提高还原反应速度,这就是高品位粒矿的“增氧”作用。The granular ore spray gun is installed at the kiln head of the rotary kiln, and the high-grade granular ore with a particle size of 5-10 mm is sprayed to a place 1/2 to 1/3 of the length of the rotary kiln from the outlet of the kiln head. The distance from the exit of the kiln head is 1/2 to 1/3 of the length of the rotary kiln, which is roughly in the middle and rear of the high-temperature reduction section in the kiln, where most of the carbon in the gas ash has been consumed, and the reducing atmosphere in the material layer is relatively weak . After injecting granular ore, at high temperature in the kiln, the iron oxide in the high-grade granular ore injected into the kiln undergoes a reduction reaction with CO in the material layer to release CO 2 . The carbon gasification reaction of C in the highly volatile granular coal and C in the residual carbon in the kiln releases twice the amount of CO, which enhances the reducing atmosphere in the material layer, improves the kinetic conditions of the reduction reaction, and is conducive to improving the reduction reaction. Speed, this is the "oxygenation" effect of high-grade granular ore.
出回转窑的高温烟气经二次燃烧室后,先经重力除尘器脱除大颗粒粉尘,再进入高低温复合空气换热器冷却,冷却后温度降至180~200℃。高低温复合空气换热器产生的低温热风(300~400℃)鼓入链箅机(或带式干燥机)的干燥段,作为湿球团干燥热源;产生的高温热风(500~700℃)一部分由回转窑窑头鼓入窑内作为高温助燃风,一部分鼓入链箅机(或带式干燥机)的预热段,作为球团预热热源。由于回收利用了回转窑的高温烟气热量,可有效降低燃料消耗。After the high-temperature flue gas exiting the rotary kiln passes through the secondary combustion chamber, it first passes through the gravity dust collector to remove large particles of dust, and then enters the high-low temperature composite air heat exchanger for cooling. After cooling, the temperature drops to 180-200°C. The low-temperature hot air (300-400°C) generated by the high-low temperature composite air heat exchanger blows into the drying section of the chain grate machine (or belt dryer) as a heat source for drying wet pellets; the generated high-temperature hot air (500-700°C) Part of it is blown into the kiln from the head of the rotary kiln as high-temperature combustion-supporting air, and part of it is blown into the preheating section of the chain grate machine (or belt dryer) as a heat source for pellet preheating. Since the high-temperature flue gas heat of the rotary kiln is recycled, fuel consumption can be effectively reduced.
出回转窑的高温烟气先经重力除尘器脱除大颗粒粉尘,再进入高低温复合空气换热器冷却,在高低温复合空气换热器的烟气通道内设置了集尘漏斗,可进一步脱除烟气中的粉尘,这样就提高了布袋除尘器回收的氧化锌粉中ZnO含量。The high-temperature flue gas exiting the rotary kiln first passes through the gravity dust collector to remove large particles of dust, and then enters the high-low temperature composite air heat exchanger for cooling. A dust collection funnel is installed in the flue gas channel of the high-low temperature composite air heat exchanger, which can further The dust in the flue gas is removed, which increases the ZnO content in the zinc oxide powder recovered by the bag filter.
本发明所用的高锌含铁尘泥中含有较高的氧化锌,在还原炉的高温及还原性气氛下,氧化锌被还原成金属锌,由于金属锌的熔点为419.53℃、沸点为907℃,生成的金属锌在窑内高温下气化,以锌蒸汽的形式随烟气排出。金属锌蒸汽遇到氧化性气氛后再次氧化,生成细小的氧化锌固体颗粒,经布袋除尘收集后,可获得氧化锌含量50~60%的副产品。因此,本方法既可以生产出金属化球团,还具有脱锌和收锌功能。The high-zinc iron-containing dust sludge used in the present invention contains relatively high zinc oxide. Under the high temperature and reducing atmosphere of the reduction furnace, zinc oxide is reduced to metallic zinc. Since the melting point of metallic zinc is 419.53°C and the boiling point is 907°C , the generated metal zinc is gasified at high temperature in the kiln, and discharged with the flue gas in the form of zinc vapor. Metal zinc vapor encounters an oxidative atmosphere and oxidizes again to form fine zinc oxide solid particles. After being collected by bag dust removal, a by-product with a zinc oxide content of 50-60% can be obtained. Therefore, the method can not only produce metallized pellets, but also have the functions of dezincification and zinc collection.
本发明在采用高炉瓦斯灰、转炉OG泥混合料造球时,根据转炉OG泥粒度较细、CaO含量较高的特点,在不配加粘结剂的情况下进行造球生产。When the present invention adopts the mixture of blast furnace gas ash and converter OG mud to make pellets, according to the characteristics of converter OG mud particle size is finer and the content of CaO is higher, pelletizing is carried out without adding binder.
1、物料的选择1. Selection of materials
高炉瓦斯灰:铁品位为25~41%、SiO2含量2~8.5%、ZnO含量4~8%、K2O含量0.6~0.8%、Na2O含量0.15~0.20%、C含量15~36%;Blast furnace gas ash: iron grade 25-41%, SiO 2 content 2-8.5%, ZnO content 4-8%, K 2 O content 0.6-0.8%, Na 2 O content 0.15-0.20%, C content 15-36 %;
转炉OG泥:烘干研磨后粒度为-200目占80%以上,铁品位为42~65%、SiO2含量2~4%、ZnO含量0.2~0.4%、K2O含量0.1~0.3%、Na2O含量0.1~0.3%;Converter OG mud: After drying and grinding, the particle size is -200 mesh, accounting for more than 80%, the iron grade is 42-65%, the SiO 2 content is 2-4%, the ZnO content is 0.2-0.4%, and the K 2 O content is 0.1-0.3%. Na 2 O content 0.1-0.3%;
高挥发份煤:固定碳含量为44~46%、灰分含量为7~9%、挥发份含量为47~49%、喷吹高挥发份煤粒度为5~15mm;High volatile coal: fixed carbon content of 44-46%, ash content of 7-9%, volatile content of 47-49%, injection high-volatile coal particle size of 5-15mm;
2、原料的配料及混合2. Ingredients and mixing of raw materials
高炉瓦斯灰、转炉OG泥按30~40:60~70比例配料及混合后,得到混合物料。Blast furnace gas ash and converter OG mud are batched and mixed according to the ratio of 30-40:60-70 to obtain a mixed material.
3、造球3. Ball making
混合物料加入到圆盘造球机中,通过喷入7~10%的水份进行圆盘或圆筒造球,控制母球的粒度为8~15mm;The mixed material is added to the disc pelletizer, and 7-10% water is sprayed into the disc or cylinder to pelletize, and the particle size of the cue ball is controlled to be 8-15mm;
4、湿球团干燥预热4. Wet pellet drying and preheating
粒度为8~15mm的湿球团,经皮带输送到链箅机(或带式干燥机)进行干燥预热,干燥预热热源为回转窑高温烟气经高低温复合空气换热器产生的热风,供给链箅机(或带式干燥机)干燥段的低温热风温度300~400℃,供给链箅机(或带式干燥机)预热段的高温热风温度500~700℃,湿球团在链箅机(或带式干燥机)上的干燥预热时间为20~40min;Wet pellets with a particle size of 8-15mm are transported to the chain grate machine (or belt dryer) by belt for drying and preheating. The heat source for drying and preheating is the hot air generated by the high-temperature flue gas from the rotary kiln passing through the high-low temperature composite air heat exchanger. , the temperature of the low-temperature hot air in the drying section of the supply chain grate machine (or belt dryer) is 300-400°C, the temperature of the high-temperature hot air in the preheating section of the supply chain grate machine (or belt dryer) is 500-700°C, and the wet pellets are The drying preheating time on the chain grate machine (or belt dryer) is 20-40 minutes;
5、球团矿的还原与固结5. Reduction and consolidation of pellets
球团在还原焙烧过程中,通过控制回转窑温度1050~1100℃、时间90~120min,可使球团矿在加热升温、高温还原的过程中得到均匀的还原及固结,并使球团矿的强度得到提高;通过在回转窑窑头喷吹高挥发份粒煤、残炭、高品位粒矿,实现了碳氢联合还原,增强了还原反应中后期的还原性气氛,提高了还原速度。During the reduction and roasting process of the pellets, by controlling the temperature of the rotary kiln at 1050-1100 °C and the time of 90-120 minutes, the pellets can be uniformly reduced and consolidated in the process of heating up and high-temperature reduction, and the pellets The strength of the furnace is improved; by injecting high-volatile granular coal, residual carbon, and high-grade granular ore at the kiln head of the rotary kiln, the joint reduction of hydrocarbons and hydrogen is realized, the reducing atmosphere in the middle and later stages of the reduction reaction is enhanced, and the reduction speed is increased.
6、物料冷却及分离6. Material cooling and separation
高温还原物料经间接式水冷冷却筒冷却到常温后,经干式磁选机进行磁选分离,得到金属化率及强度较高的金属化球团。After the high-temperature reduction material is cooled to normal temperature by an indirect water-cooled cooling cylinder, it is magnetically separated by a dry magnetic separator to obtain metallized pellets with high metallization rate and strength.
7、回收氧化锌7. Recovery of zinc oxide
出回转窑的高温烟气先经重力除尘器脱除大颗粒粉尘,再进入高低温复合空气换热器冷却,冷却后温度降至180~200℃,然后进入布袋除尘器,回收氧化锌粉烟尘,含ZnO 50~60%。The high-temperature flue gas exiting the rotary kiln first passes through the gravity dust collector to remove large particles of dust, and then enters the high-low temperature composite air heat exchanger for cooling. After cooling, the temperature drops to 180-200°C, and then enters the bag filter to recover zinc oxide powder dust , containing ZnO 50-60%.
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Citations (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS55104438A (en) * | 1979-02-06 | 1980-08-09 | Luossavaara Kiirunavaara Ab | Method of sintering pellet |
| JP2004107697A (en) * | 2002-09-13 | 2004-04-08 | Kobe Steel Ltd | Method for drying metal-containing dust produced from blast furnace |
| CN102392125A (en) * | 2011-10-25 | 2012-03-28 | 内蒙古科技大学 | Technology for recovering iron ore concentrate and coke powder from blast furnace gas dust or gas sludge |
| CN102703727A (en) * | 2012-06-29 | 2012-10-03 | 中冶南方工程技术有限公司 | Method for comprehensively utilizing gas and dust in steel works |
| CN102703714A (en) * | 2012-06-04 | 2012-10-03 | 红河锌联科技发展有限公司 | Method for preparing iron powder and recovering nonferrous metal from blast furnace iron making smoke dust |
| CN102766718A (en) * | 2012-07-24 | 2012-11-07 | 新冶高科技集团有限公司 | Method for producing sponge iron and zinc-rich materials by blast furnace zinc-containing ash |
| CN103215437A (en) * | 2013-03-18 | 2013-07-24 | 甘肃酒钢集团宏兴钢铁股份有限公司 | A kind of method that utilizes nickel slag, blast furnace gas ash and steelmaking OG mud to produce nickel-containing pearl iron |
| CN103740939A (en) * | 2013-12-27 | 2014-04-23 | 中冶京诚工程技术有限公司 | Method for producing molten iron and recovering zinc by using zinc-containing dust and sludge of steel plant |
| CN104164527A (en) * | 2014-07-31 | 2014-11-26 | 甘肃酒钢集团宏兴钢铁股份有限公司 | Chain grate-tandem type rotary kiln direct reduction technology for refractory low-grade micro-fine iron ore |
| CN104726699A (en) * | 2015-03-25 | 2015-06-24 | 甘肃酒钢集团宏兴钢铁股份有限公司 | High-strength composite metallized pellets produced by metallurgical iron-containing dust and its production process |
| CN204509429U (en) * | 2015-01-27 | 2015-07-29 | 中钢集团马鞍山矿山研究院有限公司 | A kind of external-heating rotary kiln for valuable metal synthetical recovery in ion dust mud contaning |
| CN105483371A (en) * | 2015-12-21 | 2016-04-13 | 武钢集团昆明钢铁股份有限公司 | Method for comprehensively recycling lead and zinc containing blast furnace dust |
-
2016
- 2016-08-29 CN CN201610737311.5A patent/CN106367600B/en active Active
Patent Citations (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
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