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CN106298636B - A kind of control method of ultralow K dielectric material etching depth - Google Patents

A kind of control method of ultralow K dielectric material etching depth Download PDF

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Publication number
CN106298636B
CN106298636B CN201510266174.7A CN201510266174A CN106298636B CN 106298636 B CN106298636 B CN 106298636B CN 201510266174 A CN201510266174 A CN 201510266174A CN 106298636 B CN106298636 B CN 106298636B
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etching
depth
ultralow
dielectric material
etching depth
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CN106298636A (en
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孙武
李莉
杨乐
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Semiconductor Manufacturing International Shanghai Corp
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Semiconductor Manufacturing International Shanghai Corp
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/70Manufacture or treatment of devices consisting of a plurality of solid state components formed in or on a common substrate or of parts thereof; Manufacture of integrated circuit devices or of parts thereof
    • H01L21/71Manufacture of specific parts of devices defined in group H01L21/70
    • H01L21/768Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics
    • H01L21/76801Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics characterised by the formation and the after-treatment of the dielectrics, e.g. smoothing
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/02Manufacture or treatment of semiconductor devices or of parts thereof
    • H01L21/04Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
    • H01L21/18Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
    • H01L21/30Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26
    • H01L21/31Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26 to form insulating layers thereon, e.g. for masking or by using photolithographic techniques; After treatment of these layers; Selection of materials for these layers
    • H01L21/3105After-treatment
    • H01L21/311Etching the insulating layers by chemical or physical means
    • H01L21/31105Etching inorganic layers
    • H01L21/31111Etching inorganic layers by chemical means
    • H01L21/31116Etching inorganic layers by chemical means by dry-etching
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/67Apparatus specially adapted for handling semiconductor or electric solid state devices during manufacture or treatment thereof; Apparatus specially adapted for handling wafers during manufacture or treatment of semiconductor or electric solid state devices or components ; Apparatus not specifically provided for elsewhere
    • H01L21/67005Apparatus not specifically provided for elsewhere
    • H01L21/67242Apparatus for monitoring, sorting or marking
    • H01L21/67253Process monitoring, e.g. flow or thickness monitoring

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  • Engineering & Computer Science (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • General Physics & Mathematics (AREA)
  • Manufacturing & Machinery (AREA)
  • Computer Hardware Design (AREA)
  • Physics & Mathematics (AREA)
  • Power Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Drying Of Semiconductors (AREA)

Abstract

The present invention provides a kind of control method of ultralow K dielectric material etching depth, method includes the following steps: first, set the gas flow of etching gas on etching machine, the ultralow K layer of dielectric material on a wafer is etched using the etching gas, then measures the etching depth of the ultralow K layer of dielectric material of the wafer;Then, according to the etching depth of measurement, judge whether the etching depth deviates target depth by APC system;If the etching depth deviates the etching depth, by the gas flow parameter of the APC system output adjustment, etching machine adjusts etching gas flow according to the parameter, and then the etching depth of lower wafer is made to be more nearly the target depth.The present invention adjusts the flow of etching gas on board by APC feedback, and changes the etching depth of ultralow K dielectric material by the difference of etched flux between wafer and wafer, so that etching depth be made to meet technique requirement.

Description

A kind of control method of ultralow K dielectric material etching depth
Technical field
The present invention relates to field of semiconductor manufacture, more particularly to a kind of controlling party of ultralow K dielectric material etching depth Method.
Background technique
As the node of complementary metal oxide semiconductor (CMOS) device is reduced to 28nm and hereinafter, is partly leading at present In the last part technology of body manufacture, integrated circuit is constituted in order to connect all parts, usually using the gold with opposite high conductivity Belong to material such as copper to be routed, that is, metal line.And be used to connect between metal line is usually conductive plunger.With Conductive plunger is generally in the structure for connecting the active area of semiconductor devices and other integrated circuits.
When characteristic size reaches deep-submicron following technique, when making thin copper film or conductive plunger, it must use As dielectric layer, (the ultralow k is less than or equal to the dielectric material of ultralow dielectric (Ultra low k, ULK) for dielectric constant 2.5), the advantage is that the K value of ultralow K dielectric material is lower, the interconnection capacitance of the interconnection structure constructed on chip is smaller, because This, is if using ultralow K dielectric material as the isolation medium of different circuit layers, the influence of RC retardation ratio just very little.Existing During forming thin copper film or conductive plunger, groove or through-hole are formed by etching ultralow K dielectric material, then in groove Or conductive materials are filled in through-hole.
Etching depth is generally controlled by etch period in the prior art, when the time for reaching setting, is then automatically stopped Etching operation, the etching depth of ultralow K dielectric material is target depth at this time.But general used etching gas is Small molecule single carbon fluoro-gas (CF4) when, the etching depth situation in a linear relationship with etch period is just had, quarter could be relied on The erosion time controls the etching depth, as shown in Figure 1.The many because being known as of etch rate stability are influenced, for example, chamber ring Border, etc., when being influenced in etching process by various factors, etching depth is not changing linearly then at any time.In ultralow K In the etching technics of dielectric material, when etching depth is not changed linearly with the process time, then be difficult with the process time come Control etching depth.
Currently, if when ultralow K dielectric material is as side wall protection structure, using macromolecular etching gas, such as C4F8, into Row etching, but the etching depth of this etching gas is not changed linearly with etch period, as shown in Figure 2.Therefore, for C4F8Such macromolecular etching gas, then be difficult to have etch period to control etching depth.
Therefore it provides a kind of control method of new ultralow K dielectric material etching depth is those skilled in the art's needs The project of solution.
Summary of the invention
In view of the foregoing deficiencies of prior art, the purpose of the present invention is to provide a kind of ultralow K dielectric materials to etch The control method of depth can not use the time during etching ultralow K dielectric material for solving etching gas in the prior art Come the problem of controlling etching depth.
In order to achieve the above objects and other related objects, the present invention provides a kind of control of ultralow K dielectric material etching depth Method processed, the control method include at least:
The gas flow for setting etching gas on etching machine etches the ultralow K on a wafer using the etching gas and is situated between Then the material bed of material measures the etching depth of the ultralow K layer of dielectric material of the wafer;
According to the etching depth of measurement, judge whether the etching depth deviates target depth by APC system, if The etching depth is equal to the target depth, then descends wafer using the etching gas with upper wafer same gas flow Body;If the etching depth deviates the etching depth, by the gas flow parameter of the APC system output adjustment, etching Machine adjusts etching gas flow according to the parameter, and then it is deep so that the etching depth of lower wafer is more nearly the target Degree.
A kind of scheme of optimization of control method as the ultralow K dielectric material etching depth of the present invention, the ultralow K are situated between The etching depth of the material bed of material is in nonlinear change with etch period.
A kind of scheme of optimization of control method as the ultralow K dielectric material etching depth of the present invention, the ultralow K are situated between The etching depth and gas flow of the material bed of material are in the linear relationship of inverse ratio.
The scheme of a kind of optimization of control method as the ultralow K dielectric material etching depth of the present invention, if a upper platelet Round etching depth is greater than target depth, then by APC control system according to the linear relationship of the etching depth and gas flow, The flow of the etching gas of lower wafer is tuned up;If the etching depth of upper wafer is less than target depth, controlled by APC System processed turns the flow of the etching gas of lower wafer down according to the linear relationship of the etching depth and gas flow.
A kind of scheme of optimization of control method as the ultralow K dielectric material etching depth of the present invention, is measured using OCD System measures the etching depth of the ultralow K layer of dielectric material of the wafer.
A kind of scheme of optimization of control method as the ultralow K dielectric material etching depth of the present invention, the ultralow K are situated between The dielectric constant of the material bed of material is less than 2.6.
A kind of scheme of optimization of control method as the ultralow K dielectric material etching depth of the present invention, etches a platelet The round time is more than 30s.
A kind of scheme of optimization of control method as the ultralow K dielectric material etching depth of the present invention, the etching gas Body is fluorine-containing more carbon gases.
A kind of scheme of optimization of control method as the ultralow K dielectric material etching depth of the present invention, the etching gas Body is C4F8、C4F6Or C5F6One of or a variety of combinations.
A kind of scheme of optimization of control method as the ultralow K dielectric material etching depth of the present invention, the etching gas The range of flow of gas is 25~40sccm.
As described above, the control method of ultralow K dielectric material etching depth of the invention, this method comprises: firstly, setting The gas flow of etching gas on etching machine etches the ultralow K layer of dielectric material on a wafer using the etching gas, then Measure the etching depth of the ultralow K layer of dielectric material of the wafer;Then, according to the etching depth of measurement, by APC system Judge whether the etching depth deviates target depth, if the etching depth is equal to the target depth, next platelet Circle is using the etching gas with upper wafer same gas flow;If the etching depth deviates the etching depth, by The gas flow parameter of the APC system output adjustment, etching machine adjusts etching gas flow according to the parameter, and then makes The etching depth of lower wafer is more nearly the target depth.The present invention etches gas by APC feedback to adjust on board The flow of body, and change by the difference of etched flux between wafer and wafer the etching depth of ultralow K dielectric material, to make Etching depth meets technique requirement.
Detailed description of the invention
Fig. 1 is CF in the prior art4The etching depth of etching gas with the process time variation schematic diagram.
Fig. 2 is C in the prior art4F8The etching depth of etching gas with the process time variation schematic diagram.
Fig. 3 is the ultralow K dielectric material etching depth control method flow chart of the present invention.
Fig. 4 is different flow C in the present invention4F8Etching gas etches remaining depth with the variation schematic diagram of process time.
Fig. 5 is C in the present invention4F8The etching depth of etching gas with gas flow variation schematic diagram.
Specific embodiment
Illustrate embodiments of the present invention below by way of specific specific example, those skilled in the art can be by this specification Other advantages and efficacy of the present invention can be easily understood for disclosed content.The present invention can also pass through in addition different specific realities The mode of applying is embodied or practiced, the various details in this specification can also based on different viewpoints and application, without departing from Various modifications or alterations are carried out under spirit of the invention.
Please refer to attached drawing.It should be noted that only the invention is illustrated in a schematic way for diagram provided in the present embodiment Basic conception, only shown in schema then with related component in the present invention rather than component count, shape when according to actual implementation Shape and size are drawn, when actual implementation kenel, quantity and the ratio of each component can arbitrarily change for one kind, and its component cloth Office's kenel may also be increasingly complex.
In deep-submicron technique below, when making metal line or conductive plunger in last part technology, it is situated between using ultralow K During electric material is as dielectric layer, inventors have found that if using fluorine-containing more carbon etching gas (such as C4F8) etch period Control the etching depth (i.e. time reach in setting time then stop etching) of dielectric material, then it is when reaching etch period, super The etching depth of low-K dielectric material is not the etching depth reached required by technique or the depth as shallow than technique requirement, Than depth required by technique.In consideration of it, the present invention provides a kind of control method, this method is controlled by control etched flux The offset of through-hole or etching groove in ultralow K dielectric material can be effectively reduced in the depth of etching.
The present invention provides a kind of control method of ultralow K dielectric material etching depth, as shown in figure 3, the control method Including at least following steps:
The gas flow for setting etching gas on etching machine etches the ultralow K on a wafer using the etching gas and is situated between Then the material bed of material measures the etching depth of the ultralow K layer of dielectric material of the wafer;
According to the etching depth of measurement, judge whether the etching depth deviates target depth by APC system, if The etching depth is equal to the target depth, then descends wafer using the etching gas with upper wafer same gas flow Body;If the etching depth deviates the etching depth, by the gas flow parameter of the APC system output adjustment, etching Machine adjusts etching gas flow according to the parameter, and then it is deep so that the etching depth of lower wafer is more nearly the target Degree.
The control method of ultralow K dielectric material etching depth of the invention is discussed in detail below with reference to specific attached drawing.
Step 1 is first carried out, sets the gas flow of etching gas on etching machine, utilizes etching gas etching one Then ultralow K layer of dielectric material on wafer measures the etching depth of the ultralow K layer of dielectric material of the wafer.
Etching mode of the invention is related to dry etching, and etching gas is activated under certain condition in active particle, benefit With the effect of active particle physically or chemically, the shape of required groove or through-hole is etched in layer to be etched.
It is necessary to have good electrical isolations as the barrier material between metal interconnecting wires for the ultralow K layer of dielectric material Performance, ultralow K dielectric material can be achieved by increasing the modes such as loose hole on the basis of low-K dielectric material.It is described The dielectric constant of ultralow K layer of dielectric material is below 2.6.
The etching gas can choose fluorine-containing more carbon compound gases, such as C4F8、C4F6Or C5F6One of or A variety of combinations.Certainly, the etching gas can also be other gases suitable for the ultralow K dielectric material of etching, herein Unlimited, in the present embodiment, the etching gas is C4F8Gas.
The gas flow of the etching gas is selected at 25~40sccm (standard milliliters per minute).Preferably, the quarter The gas flow for losing gas controls within the scope of 17~27sccm.
In the present embodiment, it is preferred to use OCD (optical feature dimension measurement) measures the etching depth of wafer.OCD can be with The surface of ultralow K layer of dielectric material to be etched is projected light beams upon, one group of spectrum line, the spectrum are obtained by reflected light later Information comprising measurement part in line.
Then step 2 is executed, according to the etching depth of measurement, the etching depth is judged by APC system whether Deviate target depth, if the etching depth is equal to the target depth, lower wafer is using identical as upper wafer The etching gas of gas flow;If the etching depth deviates the etching depth, by the gas of the APC system output adjustment Body flow parameter, etching machine adjust etching gas flow according to the parameter, and then make the etching depth of lower wafer more The closely described target depth of adjunction.
It should be noted that curve graph as shown in Figure 4 can be obtained according to the experimental result of batch wafer.Wherein, scheme 4 be with etching gas C4F8For, the ordinate in the figure indicates to etch remaining depth, i.e. etching gas eats up some ultra-low K Jie Material rear surface is with a distance from target depth;Abscissa indicates the process time.As can be seen from Figure 4 C4F8Ultralow K is etched to be situated between The etching residue depth of the material bed of material is in nonlinear change with the entire process time.If the process time, curve was basic less than 30 It changes linearly, after 30 seconds, curve is gentle, etches remaining depth and does not change again at any time substantially.Therefore, for technique Etching technics of the time less than 30 seconds is controlled using the process time and etches remaining depth.And being directed in the present embodiment is work Etching process of the skill time at 30 seconds or more, whole process are in nonlinear change, cannot control etching using the process time again Remaining depth.Subtract the remaining depth of etching since etching depth is equal to target depth, so etching depth also should be with the process time In nonlinear change.In addition, uppermost solid line indicates that flow is the etching gas of 25sccm, and intermediate lines indicate in Fig. 4 The etching gas of 22sccm, nethermost lines indicate the etching gas of 20sccm, it can be seen that the variation of this three curves becomes Gesture is identical, and etching gas flow is smaller, and it is smaller (i.e. etching depth is then bigger) to etch remaining depth.
In addition, obtaining relationship as shown in Figure 5 according to the experiment of early period, ordinate is etching depth, abscissa in the figure For the etched flux of etching gas, the etching depth and gas flow of ultralow K layer of dielectric material are in the linear relationship of inverse ratio, i.e. gas Body flow is bigger, etches more shallow;Gas flow is smaller, etches deeper.The reason of why will appear inverse relation is, fluorine-containing More carbon macromolecular etching gas (such as C4F8And C4F6) when etching ultralow K layer of dielectric material (ULK), it can generate a large amount of more Polymers (Polymer), polymer can be gathered in channel bottom, slow down trench etch rate, possibly even make under serious situation Stop at etching groove, so reducing gas flow is actually the amount for reducing polymer and generating, the blocking of etching groove is made With reduction, the rate of etching is improved, carves deeper.The data of these etching depths and gas flow be transferred to APC system by APC system storage.
APC system combines statistical process control (SPC) and feedback control (Feedback Control), and utilization is past Process data predicts the parameter setting of next group processing procedure, can so reduce process variation caused by a variety of causes.
The purpose of APC system is to solve the problems, such as parameters and performance indicator drift in technical process, shorten measurement institute Take time, timely correction error, its implementation help to improve productivity, reduce energy consumption, improve product quality and continuity, with And improve the safety etc. of technique, so that process equipment can be realized stringenter process window, meet future 28nm technology The requirement of node or following technology, effective monitoring technical process and board, to improve yield and overall device efficiency.
After the completion of the etching technics of upper wafer, the etching depth data of the wafer, APC system are acquired by APC Discriminatory analysis is carried out to the etching depth of collection according to the interior formula set or Rule of judgment, sees whether the etching depth deviates Target depth, if the etching depth just rests at the target depth, lower wafer is used and upper wafer The etching gas of same gas flow, i.e. gas flow do not change.If the etching depth deviates the etching depth, by institute The gas flow parameter of APC system output adjustment is stated, etching machine adjusts etching gas flow according to the parameter, and then under making The etching depth of wafer is more nearly the target depth.Specifically, if the etching depth of upper wafer is greater than target Depth (crosses quarter over-etch), then by APC control system according to the linear pass of etching depth as shown in Figure 5 and gas flow System, the flow of the etching gas of lower wafer is tuned up;If it is (at once shallow that the etching depth of upper wafer is less than target depth ), then by APC control system according to the linear relationship of the etching depth and gas flow as shown in Figure 5, by lower wafer The flow of etching gas turn down.
It can be seen that the etching depth and gas stream of the above wafer of selection of every wafer etching gas flow Amount is reference basis, and suitable gas flow parameter is exported by APC system, which is transferred to etching machine, makes etching machine Be adjusted to corresponding gas flow, so controlled by gas flow current wafer etch ultralow K layer of dielectric material etching it is deep Degree, to meet technique requirement.
In conclusion the present invention provides a kind of control method of ultralow K dielectric material etching depth, this method includes following Step: firstly, setting the gas flow of etching gas on etching machine, the etching gas is utilized to etch the ultralow K on a wafer Then layer of dielectric material measures the etching depth of the ultralow K layer of dielectric material of the wafer;Then, according to the quarter of measurement Depth is lost, judges whether the etching depth deviates target depth by APC system;If the etching depth deviates the etching Depth, then by the gas flow parameter of the APC system output adjustment, etching machine adjusts etching gas stream according to the parameter Amount, and then the etching depth of lower wafer is made to be more nearly the target depth.The present invention adjusts board by APC feedback The flow of upper etching gas, and the etching for changing by the difference of etched flux between wafer and wafer ultralow K dielectric material is deep Degree, so that etching depth be made to meet technique requirement.
So the present invention effectively overcomes various shortcoming in the prior art and has high industrial utilization value.
The above-described embodiments merely illustrate the principles and effects of the present invention, and is not intended to limit the present invention.It is any ripe The personage for knowing this technology all without departing from the spirit and scope of the present invention, carries out modifications and changes to above-described embodiment.Cause This, institute is complete without departing from the spirit and technical ideas disclosed in the present invention by those of ordinary skill in the art such as At all equivalent modifications or change, should be covered by the claims of the present invention.

Claims (8)

1. a kind of control method of ultralow K dielectric material etching depth, which is characterized in that the control method includes at least:
The gas flow for setting etching gas on etching machine etches the super low-K dielectric material on a wafer using the etching gas The bed of material, then measures the etching depth of the ultralow K layer of dielectric material of the wafer, and the etching of the ultralow K layer of dielectric material is deep Degree is with gas flow in the linear relationship of inverse ratio;
According to the etching depth of measurement, judge whether the etching depth deviates target depth by APC system, if described Etching depth is equal to the target depth, then descends wafer using the etching gas with upper wafer same gas flow; If the etching depth deviates the etching depth, by the gas flow parameter of the APC system output adjustment, etching machine root Etching gas flow is adjusted according to the parameter, and then the etching depth of lower wafer is made to be more nearly the target depth.
2. the control method of ultralow K dielectric material etching depth according to claim 1, it is characterised in that: if upper a piece of The etching depth of wafer is greater than target depth, then by APC control system according to the linear pass of the etching depth and gas flow System, the flow of the etching gas of lower wafer is tuned up;If the etching depth of upper wafer is less than target depth, by APC control system is according to the linear relationship of the etching depth and gas flow, by the flow of the etching gas of lower wafer It turns down.
3. the control method of ultralow K dielectric material etching depth according to claim 1, it is characterised in that: surveyed using OCD Amount system measures the etching depth of the ultralow K layer of dielectric material of the wafer.
4. the control method of ultralow K dielectric material etching depth according to claim 1, it is characterised in that: the ultralow K The dielectric constant of layer of dielectric material is less than 2.6.
5. the control method of ultralow K dielectric material etching depth according to claim 1, it is characterised in that: etching is a piece of The time of wafer is more than 30s.
6. the control method of ultralow K dielectric material etching depth according to claim 1, it is characterised in that: the etching Gas is fluorine-containing more carbon gases.
7. the control method of ultralow K dielectric material etching depth according to claim 6, it is characterised in that: the etching Gas is C4F8、C4F6Or C5F6One of or a variety of combinations.
8. the control method of ultralow K dielectric material etching depth according to claim 1, it is characterised in that: the etching The range of flow of gas is 25~40sccm.
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CN107378232B (en) * 2017-07-14 2019-03-15 中国科学院微电子研究所 Method and system for processing wafer by laser
CN112490123B (en) * 2020-11-20 2024-05-17 北京北方华创微电子装备有限公司 Complementary etching method and semiconductor etching equipment
CN114481333B (en) * 2022-02-16 2023-10-03 淮安纳微传感器有限公司 Sensor monocrystalline silicon etching quality monitoring method

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CN101599433A (en) * 2008-06-03 2009-12-09 中芯国际集成电路制造(北京)有限公司 Semiconductor etching method and etching system
JP2011040601A (en) * 2009-08-12 2011-02-24 Renesas Electronics Corp Method of manufacturing semiconductor device
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