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CN106192597A - A kind of bamboo base tobacco trademark paper and preparation method thereof - Google Patents

A kind of bamboo base tobacco trademark paper and preparation method thereof Download PDF

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Publication number
CN106192597A
CN106192597A CN201610804750.3A CN201610804750A CN106192597A CN 106192597 A CN106192597 A CN 106192597A CN 201610804750 A CN201610804750 A CN 201610804750A CN 106192597 A CN106192597 A CN 106192597A
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Prior art keywords
bamboo
paper
preparation
bambusae
days
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CN201610804750.3A
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CN106192597B (en
Inventor
施丰成
罗诚
李东亮
黄馨
周容
杨涛
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Yunnan Bagu Biotechnology Co Ltd
China Tobacco Sichuan Industrial Co Ltd
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Yunnan Bagu Biotechnology Co Ltd
China Tobacco Sichuan Industrial Co Ltd
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    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H27/00Special paper not otherwise provided for, e.g. made by multi-step processes
    • D21H27/10Packing paper
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21CPRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
    • D21C3/00Pulping cellulose-containing materials
    • D21C3/02Pulping cellulose-containing materials with inorganic bases or alkaline reacting compounds, e.g. sulfate processes
    • D21C3/026Pulping cellulose-containing materials with inorganic bases or alkaline reacting compounds, e.g. sulfate processes in presence of O2, e.g. air
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21CPRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
    • D21C5/00Other processes for obtaining cellulose, e.g. cooking cotton linters ; Processes characterised by the choice of cellulose-containing starting materials
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H11/00Pulp or paper, comprising cellulose or lignocellulose fibres of natural origin only
    • D21H11/12Pulp from non-woody plants or crops, e.g. cotton, flax, straw, bagasse
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00Coated paper; Coating material
    • D21H19/10Coatings without pigments
    • D21H19/14Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12

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  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Paper (AREA)

Abstract

The invention discloses a kind of bamboo base tobacco trademark paper and preparation method thereof.The present invention uses natural bamboo to be raw material, prepares bamboo base paper by paper process, then by the method adding bamboo extractive on body paper, is prepared as tobacco trademark paper.Described bamboo extractive is Succus Bambusae, Succus Bambusae, Flos bambusae omeiensi extract and the mixture of bamboo leaf essential oil, wherein, bamboo extractive includes the composition of following mass percent: Succus Bambusae 10~35%, Succus Bambusae 5~15%, Flos bambusae omeiensi extract 5~10%, bamboo leaf essential oil 2~5%, surplus be concentration be the aqueous solution of propylene glycol of 10%.The label paper of the present invention not only has environmental protection, degradable, the environmental protection feature of natural bacteriostatic, and has pure white softness, infiltration guarantor's ink, fiber tough smooth feature fine and smooth, continuous, is provided simultaneously with salubrious natural, the bamboo perfume (or spice) feature of sweet Liang Run.

Description

一种竹基烟用商标纸及其制备方法A kind of bamboo-based trademark paper for cigarettes and its preparation method

技术领域technical field

本发明涉及一种卷烟材料技术领域,具体涉及一种竹基烟用商标纸及其制备方法。The invention relates to the technical field of cigarette materials, in particular to a trademark paper for bamboo-based cigarettes and a preparation method thereof.

背景技术Background technique

烟用商标纸是香烟烟盒的外包装材料,目前公认公用的是白卡纸、普通转移纸或镭射转移纸。第一种材料是以木浆为原料制备而成,后两种材料通过真空镀铝转移膜与白卡纸复合的方式制备。上述包装纸均使用了木浆,造成了资源的大量浪费,同时后两者使用了金属铝,会对环境造成一定污染,不环保。Cigarette label paper is the outer packaging material of cigarette boxes. Currently, it is generally recognized that white cardboard, ordinary transfer paper or laser transfer paper is commonly used. The first material is prepared from wood pulp, and the latter two materials are prepared by compounding vacuum aluminized transfer film and white cardboard. The above-mentioned wrapping papers all use wood pulp, which causes a lot of waste of resources. Meanwhile, the latter two use metal aluminum, which will cause certain pollution to the environment and is not environmentally friendly.

发明内容Contents of the invention

[要解决的技术问题][Technical problem to be solved]

本发明的目的是解决上述现有技术的问题,提供一种竹基烟用商标纸及其制备方法。The purpose of the present invention is to solve the problems of the above-mentioned prior art, and provide a kind of bamboo-based cigarette label paper and a preparation method thereof.

[技术方案][Technical solutions]

为了达到上述的技术效果,本发明采取以下技术方案:In order to achieve the above-mentioned technical effect, the present invention takes the following technical solutions:

一种竹基烟用商标纸的制备方法,它包括以下步骤:A preparation method for bamboo-based cigarette label paper, comprising the following steps:

(1)(1)将嫩慈竹风干,在窑池中水沤40天脱青后捞起晾干,并切割后打烂,采用石灰进行碱法制浆,得到竹料;(1) (1) air-dry the bamboo of Nenci bamboo, pick it up and dry in the kiln pond after water retting for 40 days, remove the blueness, and smash it after cutting, adopt lime to carry out alkaline pulping, and obtain bamboo material;

(2)将制得的竹料再经粗打、细打,直至纤维分裂,用清水洗涤后,蒸煮使竹料中的竹纤维分解变软成熟料;(2) The bamboo material obtained is through rough beating and fine beating again until the fibers are split, and after washing with clear water, steaming makes the bamboo fiber in the bamboo material decompose and become soft and mature material;

(3)将熟料放入米汤中自然发酵7天,捣碎成绒,制备成竹浆浆料;(3) Put the clinker into the rice soup and ferment naturally for 7 days, mash it into velvet, and prepare it into bamboo pulp slurry;

(4)将得到的竹浆浆料抄成竹基原纸;(4) the bamboo pulp slurry obtained is copied into bamboo base base paper;

(5)在竹基原纸上涂布竹子提取物,低温烘干、切割包装,制备得到竹基烟用商标纸;所述竹子提取物是竹汁、竹沥、慈竹花萃取液和竹叶精油的混合物,其中,竹子提取物中包括以下质量百分比的成分:竹汁10~35%、竹沥5~15%、慈竹花萃取液5~10%、竹叶精油2~5%,余量是浓度为10%的丙二醇水溶液。(5) Bamboo extract is coated on bamboo-based base paper, dried at low temperature, cut and packaged, and bamboo-based cigarette trademark paper is prepared; the bamboo extract is bamboo juice, bamboo leek, Cizhu flower extract and bamboo leaf essential oil wherein, the bamboo extract comprises the following components by mass percentage: 10-35% of bamboo juice, 5-15% of bamboo leek, 5-10% of Arthia japonica flower extract, 2-5% of bamboo leaf essential oil, and the balance is 10% aqueous solution of propylene glycol.

本发明更进一步的技术方案,所述采用石灰进行碱法制浆是用石灰沤泡15天后生火蒸煮7天。In a further technical solution of the present invention, the alkali pulping by using lime is soaked with lime for 15 days and then boiled for 7 days.

本发明更进一步的技术方案,在步骤(2)中,所述蒸煮的时间为6~8天。In the further technical solution of the present invention, in step (2), the cooking time is 6-8 days.

本发明更进一步的技术方案,在步骤(5)中,所述竹子提取物的涂布量为竹基原纸质量的1~50%。In the further technical solution of the present invention, in step (5), the coating amount of the bamboo extract is 1-50% of the mass of the bamboo-based base paper.

本发明更进一步的技术方案,所述竹浆浆料的打浆度为22~45°SR;竹基原纸的定量为200~250g/m2In a further technical solution of the present invention, the beating degree of the bamboo pulp slurry is 22-45°SR; the basis weight of the bamboo-based base paper is 200-250 g/m 2 .

一种上述的制备方法制备得到竹基烟用商标纸。A kind of above-mentioned preparation method prepares the trademark paper for bamboo-based tobacco.

下面将详细地说明本发明。The present invention will be described in detail below.

本发明用石灰蒸煮竹片,在高温下石灰与竹片中的木素反应生成水溶物,使纤维分离分散成为浆料。在上述过程中,SH-、OH-等离子与木素发生亲核反应,使木素大分子的醚键断裂,大分子变成小分子,并且亲液性的酚羟基增加,木素的亲液性增强,使木素自竹片中溶出。这种方法制得的竹浆大致保留了纤维的天然长度,去除了大部分木素,能用来生产强度高、柔软的高档纸。本发明蒸煮的过程主要是脱木素的过程。此外,本发明还结合了传统的米汤发酵造纸的方法,通过米汤造纸,改变纤维的形态,增加纤维的蓬松度,是纸浆获得较好的机械强度和透气性,以保证纸页的抄造质量。The invention uses lime to cook bamboo slices, and the lime reacts with lignin in the bamboo slices at high temperature to form water-soluble matter, so that the fibers are separated and dispersed to form slurry. In the above process, SH - , OH - plasma and lignin have a nucleophilic reaction, which breaks the ether bond of the lignin macromolecule, and the macromolecule becomes a small molecule, and the lyophilic phenolic hydroxyl group increases, and the lyophilicity of lignin Enhanced to dissolve lignin from bamboo chips. The bamboo pulp produced by this method roughly retains the natural length of the fiber, removes most of the lignin, and can be used to produce high-grade paper with high strength and softness. The cooking process of the present invention is mainly a process of delignification. In addition, the present invention also combines the traditional rice soup fermentation papermaking method to change the shape of the fiber and increase the bulkiness of the fiber through the rice soup to make paper, so that the pulp can obtain better mechanical strength and air permeability, so as to ensure the papermaking quality of the paper.

本发明使用天然竹子为原料(纤维较长),通过造纸法制备竹基原纸,再通过在原纸上添加竹子提取物的方法,制备成烟用商标纸。竹纤维是从自然生长的竹子中提取出的纤维素纤维,竹纤维具有较强的抗菌、杀菌及抑菌的作用,其透气性强、过滤效果好,尤其是对大肠杆菌与黄色葡萄球菌具有较好的抵抗作用;而且竹纤维的吸湿性、吸油性及除臭能力也高于普通的醋酸纤维。竹纤维在较短的时间内就能挥发降解,可回收利用,因此提高香烟废物的利用率,对环境及土壤污染减小、绿色环保。通过在原纸上涂布一定量的低温鲜榨竹汁、竹沥、慈竹花萃取物、竹叶精油的复配物,使原纸具备清爽自然、甘甜凉润的竹香特征,可明显丰富卷烟的香气。The invention uses natural bamboo as a raw material (with longer fibers), prepares bamboo-based base paper through a papermaking method, and then prepares trademark paper for cigarettes by adding bamboo extract to the base paper. Bamboo fiber is cellulose fiber extracted from naturally growing bamboo. Bamboo fiber has strong antibacterial, bactericidal and bacteriostatic effects. It has strong air permeability and good filtering effect, especially for Escherichia coli and Staphylococcus aureus. Better resistance; and the hygroscopicity, oil absorption and deodorization ability of bamboo fiber are also higher than ordinary acetate fiber. Bamboo fiber can volatilize and degrade in a short period of time, and can be recycled, so the utilization rate of cigarette waste is improved, the pollution to the environment and soil is reduced, and it is green and environmentally friendly. By coating a certain amount of low-temperature freshly squeezed bamboo juice, bamboo leek, Cizhu flower extract, and bamboo leaf essential oil on the base paper, the base paper has a refreshing, natural, sweet and cool bamboo fragrance, which can significantly enrich the flavor of cigarettes. aroma.

[有益效果][beneficial effect]

本发明与现有技术相比,具有以下的有益效果:Compared with the prior art, the present invention has the following beneficial effects:

本发明的商标纸不仅具有绿色环保、易降解、天然抑菌的环保特点,且具有洁白柔软、浸润保墨、纤维细腻、绵韧平整的特点,同时具备清爽自然、甘甜凉润的竹香特征。The trademark paper of the present invention is not only environmentally friendly, easy to degrade, and naturally antibacterial, but also has the characteristics of whiteness and softness, soaking ink retention, fine fibers, toughness and smoothness, and has a refreshing, natural, sweet and cool bamboo fragrance. .

具体实施方式detailed description

下面结合本发明的实施例对本发明作进一步的阐述和说明。The present invention will be further elaborated and illustrated below in conjunction with the embodiments of the present invention.

实施例1:Example 1:

一种竹基烟用商标纸的制备方法,它包括以下步骤:A preparation method for bamboo-based cigarette label paper, comprising the following steps:

1)将嫩慈竹风干,在窖池中水沤40天脱青后捞起晾干,并切割后打烂,整齐堆放于沤料池内,用石灰沤泡15天后生火蒸煮7天;1) Air-dry the Nenci bamboo, retting in water for 40 days in the cellar, remove green, pick up and dry, cut and smash, stack neatly in the retting pool, soak in lime for 15 days, then cook for 7 days;

2)将蒸煮后的竹料进行粗打、细打,直至纤维分裂,用清水洗涤后重新蒸煮5天使竹纤维分解变软成熟料;2) Roughly beating and finely beating the cooked bamboo material until the fibers are split, washed with clear water and re-cooked for 5 days to decompose the bamboo fiber and soften the mature material;

3)将熟料在米汤中自然发酵7天,捣碎成绒,制备成打浆度为22°SR竹浆浆料;3) Naturally ferment the clinker in rice soup for 7 days, mash it into velvet, and prepare a bamboo pulp slurry with a beating degree of 22°SR;

4)将竹浆浆料抄成200g/m2竹基原纸;4) the bamboo pulp slurry is copied into 200g/m 2 bamboo base base paper;

5)在竹基原纸上涂布重量比为5%的竹子提取物,其配比为:竹汁18%、竹沥10%、慈竹花萃取液5%、竹叶精油3%,余量是浓度为10%的丙二醇水溶液。5) coating weight ratio on the bamboo base base paper is 5% bamboo extract, and its proportioning is: 18% of bamboo juice, 10% of bamboo leek, 5% of Cizhu flower extract, 3% of bamboo leaf essential oil, and the balance is 10% aqueous solution of propylene glycol.

6)低温烘干,切割包装,制备成烟用商标纸。6) Drying at low temperature, cutting and packaging, and preparing trademark paper for cigarettes.

实施例2Example 2

1)将嫩慈竹风干,在窖池中水沤40天脱青后捞起晾干,并切割后打烂,整齐堆放于沤料池内,用石灰沤泡15天后生火蒸煮7天;1) Air-dry the Nenci bamboo, retting it in the cellar for 40 days, take it out and dry it, cut it, smash it, stack it neatly in the retting pool, soak it with lime for 15 days, and then cook it for 7 days;

2)将蒸煮后的竹料进行粗打、细打,直至纤维分裂,用清水洗涤后重新蒸煮5天使竹纤维分解变软成熟料;2) Roughly beating and finely beating the cooked bamboo material until the fibers are split, washed with clear water and re-cooked for 5 days to decompose the bamboo fiber and soften the mature material;

3)将熟料在米汤中自然发酵7天,捣碎成绒,制备成打浆度为35°SR竹浆浆料;3) Naturally ferment the clinker in rice soup for 7 days, mash it into velvet, and prepare a bamboo pulp slurry with a beating degree of 35°SR;

4)将竹浆浆料抄成220g/m2竹基原纸;4) the bamboo pulp slurry is copied into 220g/m 2 bamboo base base paper;

5)在竹基原纸上涂布重量比为15%的竹子提取物,其配比为:竹汁18%、竹沥15%、慈竹花萃取液8%、竹叶精油1%,余量是浓度为10%的丙二醇水溶液。5) coating weight ratio on the bamboo base base paper is 15% bamboo extract, and its proportioning is: 18% of bamboo juice, 15% of bamboo leek, 8% of Cizhu flower extract, 1% of bamboo leaf essential oil, and the balance is 10% aqueous solution of propylene glycol.

6)低温烘干,切割包装,制备成烟用商标纸。6) Drying at low temperature, cutting and packaging, and preparing trademark paper for cigarettes.

实施例3Example 3

1)将嫩慈竹风干,在窖池中水沤40天脱青后捞起晾干,并切割后打烂,整齐堆放于沤料池内,用石灰沤泡15天后生火蒸煮7天;1) Air-dry the Nenci bamboo, retting it in the cellar for 40 days, take it out and dry it, cut it, smash it, stack it neatly in the retting pool, soak it with lime for 15 days, and then cook it for 7 days;

2)将蒸煮后的竹料进行粗打、细打,直至纤维分裂,用清水洗涤后重新蒸煮5天使竹纤维分解变软成熟料;2) Roughly beating and finely beating the cooked bamboo material until the fibers are split, washed with clear water and re-cooked for 5 days to decompose the bamboo fiber and soften the mature material;

3)将熟料在米汤中自然发酵7天,捣碎成绒,制备成打浆度为45°SR竹浆浆料;3) Naturally ferment the clinker in rice soup for 7 days, mash it into velvet, and prepare a bamboo pulp slurry with a beating degree of 45°SR;

4)将竹浆浆料抄成250g/m2竹基原纸;4) the bamboo pulp slurry is copied into 250g/m 2 bamboo base base paper;

5)在竹基原纸上涂布重量比为30%的竹子提取物,其配比为:竹汁30%、竹沥5%、慈竹花萃取液10%、竹叶精油5%,余量是浓度为10%的丙二醇水溶液。5) coating weight ratio on the bamboo-based base paper is 30% bamboo extract, and its proportioning is: 30% of bamboo juice, 5% of bamboo leek, 10% of Cizhu flower extract, 5% of bamboo leaf essential oil, and the balance is 10% aqueous solution of propylene glycol.

6)低温烘干,切割包装,制备成烟用商标纸。6) Drying at low temperature, cutting and packaging, and preparing trademark paper for cigarettes.

实施例1~3制备得到的烟用商标纸卷裹香烟后的吸食感官评价表如表1所示。Table 1 shows the sensory evaluation table for smoking after wrapping cigarettes with trademark paper for cigarettes prepared in Examples 1-3.

表1为样品感官评吸结果Table 1 is the result of sensory evaluation of samples

尽管这里参照本发明的解释性实施例对本发明进行了描述,上述实施例仅为本发明较佳的实施方式,本发明的实施方式并不受上述实施例的限制,应该理解,本领域技术人员可以设计出很多其他的修改和实施方式,这些修改和实施方式将落在本申请公开的原则范围和精神之内。Although the present invention has been described here with reference to the illustrative examples of the present invention, the above-mentioned examples are only preferred implementations of the present invention, and the implementation of the present invention is not limited by the above-mentioned examples. It should be understood that those skilled in the art Many other modifications and embodiments can be devised which will fall within the scope and spirit of the principles disclosed in this application.

Claims (6)

1. the preparation method of a bamboo base tobacco trademark paper, it is characterised in that it comprises the following steps:
(1) being air-dried by tender cizu, in kiln pond, bubble picks up after de-green grass or young crops and dries for 40 days, and batters down after cutting, uses Calx to carry out Soda pulping process, obtains bamboo material.
(2) by prepared bamboo material again through slightly beating, carefully beating, until fiber division, after washing with clear water, steaming and decocting makes the bamboo in bamboo material fine Dimension decomposes deliquescing ripe material;
(3) grog is put into natural fermentation 7 days in rice water, smash into floss to pieces, be prepared as bamboo pulp;
(4) bamboo pulp obtained is copied into bamboo base paper;
(5) on bamboo base paper, bamboo extractive it is coated with, oven drying at low temperature, cutting packaging, prepare bamboo base cigarette forming paper;Institute Stating bamboo extractive is Succus Bambusae, Succus Bambusae, Flos bambusae omeiensi extract and the mixture of bamboo leaf essential oil, and wherein, bamboo extractive includes The composition of following mass percent: Succus Bambusae 10~35%, Succus Bambusae 5~15%, Flos bambusae omeiensi extract 5~10%, bamboo leaf essential oil 2~ 5%, surplus be concentration be the aqueous solution of propylene glycol of 10%.
The preparation method of bamboo base tobacco trademark paper the most according to claim 1, it is characterised in that described employing Calx is carried out Soda pulping process be macerate bubble 15 days with Calx after light a fire steaming and decocting 7 days.
The preparation method of bamboo base tobacco trademark paper the most according to claim 1, it is characterised in that in step (2), described The time of steaming and decocting is 6~8 days.
The preparation method of bamboo base tobacco trademark paper the most according to claim 1, it is characterised in that in step (5), described The coating weight of bamboo extractive is the 1~50% of bamboo base paper quality.
The preparation method of bamboo base tobacco trademark paper the most according to claim 1, it is characterised in that beating of described bamboo pulp The degree of beating is 22~45 ° of SR;Quantification of the 200~250g/m of bamboo base paper2
6. the preparation method described in a Claims 1 to 5 any one prepares bamboo base tobacco trademark paper.
CN201610804750.3A 2016-09-06 2016-09-06 A kind of bamboo base tobacco trademark paper and preparation method thereof Active CN106192597B (en)

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CN109989287A (en) * 2017-12-29 2019-07-09 浙江大铭新材料股份有限公司 It is a kind of using bamboo as the paper technology of raw material
CN113293651A (en) * 2021-06-11 2021-08-24 湖北中烟工业有限责任公司 Preparation method of antibacterial cigarette paper

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CN103741539A (en) * 2014-01-15 2014-04-23 李明发 Bamboo-made paper processing method
CN104611993A (en) * 2015-01-14 2015-05-13 广西中烟工业有限责任公司 Cigarette tipping paper coated with composite natural plant extract
CN105040511A (en) * 2015-07-28 2015-11-11 湖北中烟工业有限责任公司 Method for preparing reconstructed tobacco-leaf cigarette paper by replacing part of wood pulp with bamboo pulp
CN105155330A (en) * 2015-08-13 2015-12-16 合肥龙发包装有限公司 Cigarette packaging paper facilitating reduction of carbon monoxide

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CN102268838A (en) * 2011-08-29 2011-12-07 云南绅博源生物科技有限公司 Cigarette paper additive and application thereof
CN103741539A (en) * 2014-01-15 2014-04-23 李明发 Bamboo-made paper processing method
CN104611993A (en) * 2015-01-14 2015-05-13 广西中烟工业有限责任公司 Cigarette tipping paper coated with composite natural plant extract
CN105040511A (en) * 2015-07-28 2015-11-11 湖北中烟工业有限责任公司 Method for preparing reconstructed tobacco-leaf cigarette paper by replacing part of wood pulp with bamboo pulp
CN105155330A (en) * 2015-08-13 2015-12-16 合肥龙发包装有限公司 Cigarette packaging paper facilitating reduction of carbon monoxide

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109989287A (en) * 2017-12-29 2019-07-09 浙江大铭新材料股份有限公司 It is a kind of using bamboo as the paper technology of raw material
CN113293651A (en) * 2021-06-11 2021-08-24 湖北中烟工业有限责任公司 Preparation method of antibacterial cigarette paper

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