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CN106036351A - Organic-acid sterilizing and deodorizing agent and preparation method thereof - Google Patents

Organic-acid sterilizing and deodorizing agent and preparation method thereof Download PDF

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CN106036351A
CN106036351A CN201610385549.6A CN201610385549A CN106036351A CN 106036351 A CN106036351 A CN 106036351A CN 201610385549 A CN201610385549 A CN 201610385549A CN 106036351 A CN106036351 A CN 106036351A
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杨山礼
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    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23BPRESERVATION OF FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES; CHEMICAL RIPENING OF FRUIT OR VEGETABLES
    • A23B2/00Preservation of foods or foodstuffs, in general
    • A23B2/70Preservation of foods or foodstuffs, in general by treatment with chemicals
    • A23B2/725Preservation of foods or foodstuffs, in general by treatment with chemicals in the form of liquids or solids
    • A23B2/729Organic compounds; Microorganisms; Enzymes
    • A23B2/733Compounds of undetermined constitution obtained from animals or plants
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23BPRESERVATION OF FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES; CHEMICAL RIPENING OF FRUIT OR VEGETABLES
    • A23B2/00Preservation of foods or foodstuffs, in general
    • A23B2/70Preservation of foods or foodstuffs, in general by treatment with chemicals
    • A23B2/725Preservation of foods or foodstuffs, in general by treatment with chemicals in the form of liquids or solids
    • A23B2/729Organic compounds; Microorganisms; Enzymes
    • A23B2/742Organic compounds containing oxygen

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  • Engineering & Computer Science (AREA)
  • Wood Science & Technology (AREA)
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  • Chemical & Material Sciences (AREA)
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  • Polymers & Plastics (AREA)
  • Disinfection, Sterilisation Or Deodorisation Of Air (AREA)

Abstract

本发明公开了一种有机酸杀菌除臭剂及其制备方法,其组成原料的重量份为:豆荚纤维140‑180、米糠纤维100‑120、膨化豆渣80‑90、玉米面粉30‑50、熏衣草提取液70‑90、苹果提取液30‑50、海藻酸钠3‑5、阿魏酸7‑9、绿原酸3‑5、柠檬酸1‑2、聚乙烯吡咯烷酮2‑3。本发明将豆荚纤维、米糠纤维、膨化豆渣、玉米面粉科学配合作为载体,载体分子间孔隙较大,吸附性能好,经过熏衣草提取液、苹果提取液处理后得到改性载体,可以与硫化氢、硫醇、氨、胺、醛、酮、酸等臭味分子发生化学反应而达到彻底除臭的效果,改性载体与阿魏酸、绿原酸、柠檬酸的配合使用使得本发明杀菌除臭作用进一步增强,净化效果大大增加。The invention discloses an organic acid sterilizing and deodorizing agent and a preparation method thereof. The raw materials are composed of 140-180 parts by weight of bean pod fiber, 100-120 parts of rice bran fiber, 80-90 part of puffed bean dregs, 30-50 part of corn flour, smoked Laminaria extract 70‑90, apple extract 30‑50, sodium alginate 3‑5, ferulic acid 7‑9, chlorogenic acid 3‑5, citric acid 1‑2, polyvinylpyrrolidone 2‑3. In the present invention, the scientific combination of bean pod fiber, rice bran fiber, puffed bean dregs, and corn flour is used as the carrier. The pores between the carrier molecules are relatively large and the adsorption performance is good. The modified carrier is obtained after being treated with lavender extract and apple extract, which can be combined with vulcanization Hydrogen, mercaptans, ammonia, amines, aldehydes, ketones, acids and other odor molecules undergo chemical reactions to achieve a complete deodorizing effect. The combination of modified carriers and ferulic acid, chlorogenic acid, and citric acid makes the present invention sterilize The deodorizing effect is further enhanced, and the purification effect is greatly increased.

Description

一种有机酸杀菌除臭剂及其制备方法A kind of organic acid bactericidal deodorant and preparation method thereof

技术领域technical field

本发明涉及饲料添加剂加工制备技术领域,具体涉及一种有机酸杀菌除臭剂及其制备方法。The invention relates to the technical field of feed additive processing and preparation, in particular to an organic acid bactericidal deodorant and a preparation method thereof.

背景技术Background technique

随着我国规模化、集约化畜牧业的发展,动物养殖中产生的臭粪、臭气对环境的污染不断加剧。恶化的环境不但对人类的健康造成极大的威胁,而且也严重影响着动物的健康和生产性能的发挥,因此,对畜牧场臭粪、臭气的治理愈来愈引起人们的重视。动物养殖中产生污染,主要来源于动物粪尿中携带的一些有毒或有异味的物质,这些物质种类繁杂,绝大部分为有机类恶臭气体,例如吲哚类有机酸、粪臭素、脂肪类胺硫醇、硫化氢等。动物排泄物所含有机物大致可分为含氮化合物和碳水化合物两大类,它们在缺氧的环境下分解出不同的臭味气体。含氮化合物在无氧时分解为氨、硫化氢、硫酸、乙烯醇、三甲胺、二甲基硫醚等恶臭气体;碳水化合物在缺氧时因氧化不完全而分解为甲烷、有机酸、醇类等带有臭味或酸味的物质。传统依靠物理吸附和香味掩盖等除臭剂并不能从根本上消除臭味分子的存在,臭味实际上依然存在,所以除臭效果并不理想,依靠二氧化氯、对二氯苯等化学品除臭,虽然除臭效果相对较好,但其对人和动物的刺激性较大,不适宜添加到饲料中使用。随着绿色饲料理念的深入,人们越来越重视饲料的安全问题,因此,研究开发可以在动物体内、体外除臭且安全环保的饲料添加剂具有广阔的市场前景和应用价值。With the development of large-scale and intensive animal husbandry in China, the pollution of stinky feces and odors produced in animal breeding to the environment is increasing. The deteriorating environment not only poses a great threat to human health, but also seriously affects the health and production performance of animals. Therefore, people pay more and more attention to the control of stinky dung and odor in livestock farms. Pollution in animal breeding mainly comes from some toxic or odorous substances carried in animal excrement and urine. These substances are of various types, most of which are organic odorous gases, such as indole organic acids, skatole, fatty amines Mercaptans, hydrogen sulfide, etc. The organic matter contained in animal excrement can be roughly divided into two categories: nitrogen-containing compounds and carbohydrates, which decompose into different odorous gases in an oxygen-deficient environment. Nitrogen-containing compounds decompose into malodorous gases such as ammonia, hydrogen sulfide, sulfuric acid, vinyl alcohol, trimethylamine, and dimethyl sulfide in the absence of oxygen; carbohydrates decompose into methane, organic acids, alcohols due to incomplete oxidation in the absence of oxygen Smelly or sour-tasting substances such as Traditional deodorants such as physical adsorption and fragrance masking cannot fundamentally eliminate the existence of odor molecules, and the odor actually still exists, so the deodorization effect is not ideal. Relying on chemicals such as chlorine dioxide and p-dichlorobenzene Deodorization, although the deodorization effect is relatively good, but it is more irritating to humans and animals, so it is not suitable to be added to feed. With the deepening of the concept of green feed, people pay more and more attention to the safety of feed. Therefore, the research and development of feed additives that can deodorize in vivo and in vitro of animals and are safe and environmentally friendly has broad market prospects and application value.

发明内容Contents of the invention

为了弥补现有技术的不足,本发明提供了一种有机酸杀菌除臭剂及其制备方法。In order to make up for the deficiencies of the prior art, the invention provides an organic acid bactericidal deodorant and a preparation method thereof.

本发明的技术方案如下:Technical scheme of the present invention is as follows:

一种有机酸杀菌除臭剂,其组成原料的重量份为:豆荚纤维140-180、米糠纤维100-120、膨化豆渣80-90、玉米面粉30-50、熏衣草提取液70-90、苹果提取液30-50、海藻酸钠3-5、阿魏酸7-9、绿原酸3-5、柠檬酸1-2、聚乙烯吡咯烷酮2-3。An organic acid sterilizing and deodorant agent. The raw materials are composed of 140-180 parts by weight of bean pod fiber, 100-120 parts of rice bran fiber, 80-90 parts of puffed bean dregs, 30-50 parts of corn flour, 70-90 parts of lavender extract, Apple extract 30-50, sodium alginate 3-5, ferulic acid 7-9, chlorogenic acid 3-5, citric acid 1-2, polyvinylpyrrolidone 2-3.

所述的有机酸杀菌除臭剂的制备方法,包括以下步骤:The preparation method of described organic acid bactericidal deodorant comprises the following steps:

(1)将豆荚纤维、米糠纤维、膨化豆渣、玉米面粉进行混合,得到预改性载体,待用;(1) Mix bean pod fiber, rice bran fiber, puffed bean dregs, and corn flour to obtain a pre-modified carrier for use;

(2)将熏衣草提取液、苹果提取液进行混合,再加入海藻酸钠混合成有一定黏稠度的溶液,得到改性溶液,待用;(2) Mix lavender extract and apple extract, then add sodium alginate and mix to form a solution with a certain viscosity to obtain a modified solution for use;

(3)将步骤(2)的改性溶液加入到步骤(1)的预改性载体中浸渍过夜,然后放入60-70℃温度下干燥至含水量小于15%,得到改性载体,取出,待用;(3) Add the modified solution in step (2) to the pre-modified carrier in step (1) and soak overnight, then dry at 60-70°C until the water content is less than 15%, to obtain a modified carrier, take it out ,stand-by;

(4)将阿魏酸、绿原酸、柠檬酸混合并加水溶解,再加入聚乙烯吡咯烷酮使酸液均匀分散,得到有机酸溶液,待用;(4) Mix ferulic acid, chlorogenic acid, and citric acid, add water to dissolve, then add polyvinylpyrrolidone to disperse the acid liquid evenly, and obtain an organic acid solution for use;

(5)将步骤(4)的有机酸溶液与步骤(3)的改性载体混合,制成软材,用制粒机制成粒径3-6mm的颗粒,将所得颗粒置于60-70℃环境中干燥至含水量降至8%以下,取出,真空包装,得到成品。(5) Mix the organic acid solution in step (4) with the modified carrier in step (3) to make a soft material, use a granulator to make particles with a particle size of 3-6mm, and place the obtained particles at 60-70°C Dry in the environment until the water content drops below 8%, take it out, and vacuum pack it to get the finished product.

本发明的有益效果:Beneficial effects of the present invention:

1、本发明将豆荚纤维、米糠纤维、膨化豆渣、玉米面粉科学配合作为载体,载体分子间孔隙较大,吸附性能好,经过熏衣草提取液、苹果提取液处理后得到改性载体,可以与硫化氢、硫醇、氨、胺、醛、酮、酸等臭味分子发生化学反应而达到彻底除臭的效果,改性载体与阿魏酸、绿原酸、柠檬酸的配合使用使得本发明杀菌除臭作用进一步增强,净化效果大大增加。1. The present invention uses bean pod fiber, rice bran fiber, puffed bean dregs, and corn flour as a scientific carrier. The pores between the carrier molecules are relatively large and the adsorption performance is good. After being treated with lavender extract and apple extract, the modified carrier can be obtained. Chemically react with odor molecules such as hydrogen sulfide, mercaptan, ammonia, amine, aldehyde, ketone, acid, etc. to achieve a complete deodorizing effect. The combination of modified carrier and ferulic acid, chlorogenic acid, citric acid makes this product The sterilization and deodorization effect of the invention is further enhanced, and the purification effect is greatly increased.

2、本发明选材安全、无毒,可以添加到饲料中供动物食用,改善动物的胃肠消化功能,减少粪臭,还可与动物粪便互混,对粪便进行杀菌除臭。2. The material of the present invention is safe and non-toxic, and can be added to feed for animals to eat, improve the gastrointestinal digestion function of animals, reduce fecal odor, and can also be mixed with animal feces to sterilize and deodorize feces.

具体实施方式detailed description

下面将结合本发明实施例,对本发明中的技术方案进行清楚、完整地描述,凡是其他在不脱离本发明核心的情况下做出的简单的变形或修改均落入本发明的保护范围。The technical solutions in the present invention will be clearly and completely described below in conjunction with the embodiments of the present invention. All other simple deformations or modifications made without departing from the core of the present invention fall within the protection scope of the present invention.

一种有机酸杀菌除臭剂,其组成原料的重量份(千克)为:豆荚纤维140、米糠纤维100、膨化豆渣80、玉米面粉30、熏衣草提取液70、苹果提取液30、海藻酸钠3、阿魏酸7、绿原酸3、柠檬酸1、聚乙烯吡咯烷酮2。An organic acid bactericidal deodorant, the weight parts (kg) of its raw materials are: 140 parts by weight of bean pod fiber, 100 parts of rice bran fiber, 80 parts of puffed bean dregs, 30 parts of corn flour, 70 parts of lavender extract, 30 parts of apple extract, and alginic acid Sodium 3, ferulic acid 7, chlorogenic acid 3, citric acid 1, polyvinylpyrrolidone 2.

所述的有机酸杀菌除臭剂的制备方法,包括以下步骤:The preparation method of described organic acid bactericidal deodorant comprises the following steps:

(1)将豆荚纤维、米糠纤维、膨化豆渣、玉米面粉进行混合,得到预改性载体,待用;(1) Mix bean pod fiber, rice bran fiber, puffed bean dregs, and corn flour to obtain a pre-modified carrier for use;

(2)将熏衣草提取液、苹果提取液进行混合,再加入海藻酸钠混合成有一定黏稠度的溶液,得到改性溶液,待用;(2) Mix lavender extract and apple extract, then add sodium alginate and mix to form a solution with a certain viscosity to obtain a modified solution for use;

(3)将步骤(2)的改性溶液加入到步骤(1)的预改性载体中浸渍过夜,然后放入60℃温度下干燥至含水量小于15%,得到改性载体,取出,待用;(3) Add the modified solution in step (2) to the pre-modified carrier in step (1) and soak overnight, then dry at 60°C until the water content is less than 15%, to obtain a modified carrier, take it out, and wait for use;

(4)将阿魏酸、绿原酸、柠檬酸混合并加水溶解,再加入聚乙烯吡咯烷酮使酸液均匀分散,得到有机酸溶液,待用;(4) Mix ferulic acid, chlorogenic acid, and citric acid, add water to dissolve, then add polyvinylpyrrolidone to disperse the acid liquid evenly, and obtain an organic acid solution for use;

(5)将步骤(4)的有机酸溶液与步骤(3)的改性载体混合,制成软材,用制粒机制成粒径3mm的颗粒,将所得颗粒置于60℃环境中干燥至含水量降至8%以下,取出,真空包装,得到成品。(5) Mix the organic acid solution in step (4) with the modified carrier in step (3) to make a soft material, use a granulator to make particles with a particle size of 3mm, and dry the obtained particles in an environment at 60°C to The water content is reduced to below 8%, taken out, and vacuum-packed to obtain the finished product.

以猪为试验对象,将本发明除臭剂按0.5%的添加量添加于杜长大三元杂交猪饲料中,连续饲喂3-5天时,粪臭开始减轻,饲喂至2-3周后,粪臭得到明显改善,臭味去除率在85%以上。将本发明除臭剂与猪粪混合堆沤,猪粪臭味基本消除。Taking pigs as the test object, the deodorant of the present invention is added to the feed of Du long-term three-way hybrid pigs in an amount of 0.5%, and when fed continuously for 3-5 days, the excrement odor begins to alleviate, and it is fed for 2-3 weeks After that, the manure odor was significantly improved, and the odor removal rate was above 85%. When the deodorant of the present invention is mixed with pig manure and stacked, the smell of pig manure is basically eliminated.

Claims (2)

1.一种有机酸杀菌除臭剂,其特征在于,其组成原料的重量份为:豆荚纤维140-180、米糠纤维100-120、膨化豆渣80-90、玉米面粉30-50、熏衣草提取液70-90、苹果提取液30-50、海藻酸钠3-5、阿魏酸7-9、绿原酸3-5、柠檬酸1-2、聚乙烯吡咯烷酮2-3。1. An organic acid bactericidal deodorant is characterized in that, the parts by weight of its raw materials are: pod fiber 140-180, rice bran fiber 100-120, puffed bean dregs 80-90, corn flour 30-50, lavender Extract 70-90, apple extract 30-50, sodium alginate 3-5, ferulic acid 7-9, chlorogenic acid 3-5, citric acid 1-2, polyvinylpyrrolidone 2-3. 2.根据权利要求1所述的有机酸杀菌除臭剂的制备方法,其特征在于包括以下步骤:2. the preparation method of organic acid bactericidal deodorant according to claim 1, is characterized in that comprising the following steps: (1)将豆荚纤维、米糠纤维、膨化豆渣、玉米面粉进行混合,得到预改性载体,待用;(1) Mix bean pod fiber, rice bran fiber, puffed bean dregs, and corn flour to obtain a pre-modified carrier for use; (2)将熏衣草提取液、苹果提取液进行混合,再加入海藻酸钠混合成有一定黏稠度的溶液,得到改性溶液,待用;(2) Mix lavender extract and apple extract, then add sodium alginate and mix to form a solution with a certain viscosity to obtain a modified solution for use; (3)将步骤(2)的改性溶液加入到步骤(1)的预改性载体中浸渍过夜,然后放入60-70℃温度下干燥至含水量小于15%,得到改性载体,取出,待用;(3) Add the modified solution in step (2) to the pre-modified carrier in step (1) and soak overnight, then dry at 60-70°C until the water content is less than 15%, to obtain a modified carrier, take it out ,stand-by; (4)将阿魏酸、绿原酸、柠檬酸混合并加水溶解,再加入聚乙烯吡咯烷酮使酸液均匀分散,得到有机酸溶液,待用;(4) Mix ferulic acid, chlorogenic acid, and citric acid, add water to dissolve, then add polyvinylpyrrolidone to disperse the acid liquid evenly, and obtain an organic acid solution for use; (5)将步骤(4)的有机酸溶液与步骤(3)的改性载体混合,制成软材,用制粒机制成粒径3-6mm的颗粒,将所得颗粒置于60-70℃环境中干燥至含水量降至8%以下,取出,真空包装,得到成品。(5) Mix the organic acid solution in step (4) with the modified carrier in step (3) to make a soft material, use a granulator to make particles with a particle size of 3-6mm, and place the obtained particles at 60-70°C Dry in the environment until the water content drops below 8%, take it out, and vacuum pack it to get the finished product.
CN201610385549.6A 2016-06-03 2016-06-03 Organic-acid sterilizing and deodorizing agent and preparation method thereof Withdrawn CN106036351A (en)

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CN114868912A (en) * 2022-05-23 2022-08-09 广西壮族自治区林业科学研究院 Preparation method of low-fat food
CN114868912B (en) * 2022-05-23 2024-06-25 广西壮族自治区林业科学研究院 A method for preparing low-fat food
CN116784446A (en) * 2023-06-19 2023-09-22 中国农业大学 A composition that synergistically inhibits Pseudomonas aeruginosa and its application
CN116784446B (en) * 2023-06-19 2023-12-08 中国农业大学 A composition that synergistically inhibits Pseudomonas aeruginosa and its application

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Application publication date: 20161026