CN106036351A - Organic-acid sterilizing and deodorizing agent and preparation method thereof - Google Patents
Organic-acid sterilizing and deodorizing agent and preparation method thereof Download PDFInfo
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- 150000007524 organic acids Chemical class 0.000 title claims abstract description 17
- 238000002360 preparation method Methods 0.000 title claims abstract description 8
- 230000001877 deodorizing effect Effects 0.000 title abstract description 5
- 230000001954 sterilising effect Effects 0.000 title abstract description 4
- 239000003795 chemical substances by application Substances 0.000 title abstract 2
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims abstract description 27
- 239000000835 fiber Substances 0.000 claims abstract description 18
- 244000046052 Phaseolus vulgaris Species 0.000 claims abstract description 17
- 235000010627 Phaseolus vulgaris Nutrition 0.000 claims abstract description 17
- KSEBMYQBYZTDHS-HWKANZROSA-M (E)-Ferulic acid Natural products COC1=CC(\C=C\C([O-])=O)=CC=C1O KSEBMYQBYZTDHS-HWKANZROSA-M 0.000 claims abstract description 9
- CWVRJTMFETXNAD-FWCWNIRPSA-N 3-O-Caffeoylquinic acid Natural products O[C@H]1[C@@H](O)C[C@@](O)(C(O)=O)C[C@H]1OC(=O)\C=C\C1=CC=C(O)C(O)=C1 CWVRJTMFETXNAD-FWCWNIRPSA-N 0.000 claims abstract description 9
- PZIRUHCJZBGLDY-UHFFFAOYSA-N Caffeoylquinic acid Natural products CC(CCC(=O)C(C)C1C(=O)CC2C3CC(O)C4CC(O)CCC4(C)C3CCC12C)C(=O)O PZIRUHCJZBGLDY-UHFFFAOYSA-N 0.000 claims abstract description 9
- CWVRJTMFETXNAD-KLZCAUPSSA-N Neochlorogenin-saeure Natural products O[C@H]1C[C@@](O)(C[C@@H](OC(=O)C=Cc2ccc(O)c(O)c2)[C@@H]1O)C(=O)O CWVRJTMFETXNAD-KLZCAUPSSA-N 0.000 claims abstract description 9
- 235000007164 Oryza sativa Nutrition 0.000 claims abstract description 9
- 240000008042 Zea mays Species 0.000 claims abstract description 9
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 claims abstract description 9
- 235000002017 Zea mays subsp mays Nutrition 0.000 claims abstract description 9
- CWVRJTMFETXNAD-JUHZACGLSA-N chlorogenic acid Chemical compound O[C@@H]1[C@H](O)C[C@@](O)(C(O)=O)C[C@H]1OC(=O)\C=C\C1=CC=C(O)C(O)=C1 CWVRJTMFETXNAD-JUHZACGLSA-N 0.000 claims abstract description 9
- 235000001368 chlorogenic acid Nutrition 0.000 claims abstract description 9
- 229940074393 chlorogenic acid Drugs 0.000 claims abstract description 9
- FFQSDFBBSXGVKF-KHSQJDLVSA-N chlorogenic acid Natural products O[C@@H]1C[C@](O)(C[C@@H](CC(=O)C=Cc2ccc(O)c(O)c2)[C@@H]1O)C(=O)O FFQSDFBBSXGVKF-KHSQJDLVSA-N 0.000 claims abstract description 9
- BMRSEYFENKXDIS-KLZCAUPSSA-N cis-3-O-p-coumaroylquinic acid Natural products O[C@H]1C[C@@](O)(C[C@@H](OC(=O)C=Cc2ccc(O)cc2)[C@@H]1O)C(=O)O BMRSEYFENKXDIS-KLZCAUPSSA-N 0.000 claims abstract description 9
- 235000005822 corn Nutrition 0.000 claims abstract description 9
- KSEBMYQBYZTDHS-HWKANZROSA-N ferulic acid Chemical compound COC1=CC(\C=C\C(O)=O)=CC=C1O KSEBMYQBYZTDHS-HWKANZROSA-N 0.000 claims abstract description 9
- 235000001785 ferulic acid Nutrition 0.000 claims abstract description 9
- 229940114124 ferulic acid Drugs 0.000 claims abstract description 9
- KSEBMYQBYZTDHS-UHFFFAOYSA-N ferulic acid Natural products COC1=CC(C=CC(O)=O)=CC=C1O KSEBMYQBYZTDHS-UHFFFAOYSA-N 0.000 claims abstract description 9
- 235000013312 flour Nutrition 0.000 claims abstract description 9
- 235000009566 rice Nutrition 0.000 claims abstract description 9
- QURCVMIEKCOAJU-UHFFFAOYSA-N trans-isoferulic acid Natural products COC1=CC=C(C=CC(O)=O)C=C1O QURCVMIEKCOAJU-UHFFFAOYSA-N 0.000 claims abstract description 9
- 229940083980 lavender extract Drugs 0.000 claims abstract description 8
- 235000020723 lavender extract Nutrition 0.000 claims abstract description 8
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 claims abstract description 7
- 229920000036 polyvinylpyrrolidone Polymers 0.000 claims abstract description 7
- 239000001267 polyvinylpyrrolidone Substances 0.000 claims abstract description 7
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 claims abstract description 6
- 239000000661 sodium alginate Substances 0.000 claims abstract description 6
- 235000010413 sodium alginate Nutrition 0.000 claims abstract description 6
- 229940005550 sodium alginate Drugs 0.000 claims abstract description 6
- 239000002253 acid Substances 0.000 claims abstract description 5
- 229960004106 citric acid Drugs 0.000 claims abstract description 5
- 235000015165 citric acid Nutrition 0.000 claims abstract description 5
- 239000002994 raw material Substances 0.000 claims abstract description 4
- 240000007594 Oryza sativa Species 0.000 claims abstract 4
- 239000000203 mixture Substances 0.000 claims description 15
- 239000002781 deodorant agent Substances 0.000 claims description 11
- 239000002245 particle Substances 0.000 claims description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 9
- 230000000844 anti-bacterial effect Effects 0.000 claims description 7
- 239000007788 liquid Substances 0.000 claims description 3
- 239000007779 soft material Substances 0.000 claims description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 abstract description 6
- 230000000694 effects Effects 0.000 abstract description 5
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical class S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 abstract description 4
- 229910021529 ammonia Inorganic materials 0.000 abstract description 3
- 238000001179 sorption measurement Methods 0.000 abstract description 3
- 150000001299 aldehydes Chemical class 0.000 abstract description 2
- 150000001412 amines Chemical class 0.000 abstract description 2
- 150000002576 ketones Chemical class 0.000 abstract description 2
- 239000011148 porous material Substances 0.000 abstract description 2
- 238000000746 purification Methods 0.000 abstract description 2
- 241001466453 Laminaria Species 0.000 abstract 1
- 150000007513 acids Chemical class 0.000 abstract 1
- 239000000969 carrier Substances 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 238000004073 vulcanization Methods 0.000 abstract 1
- 241001465754 Metazoa Species 0.000 description 9
- 235000019645 odor Nutrition 0.000 description 9
- 210000003608 fece Anatomy 0.000 description 7
- 241000209094 Oryza Species 0.000 description 5
- 238000004332 deodorization Methods 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- QMMFVYPAHWMCMS-UHFFFAOYSA-N Dimethyl sulfide Chemical compound CSC QMMFVYPAHWMCMS-UHFFFAOYSA-N 0.000 description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 3
- 239000007789 gas Substances 0.000 description 3
- 229910000037 hydrogen sulfide Inorganic materials 0.000 description 3
- 239000010871 livestock manure Substances 0.000 description 3
- 239000001301 oxygen Substances 0.000 description 3
- 229910052760 oxygen Inorganic materials 0.000 description 3
- 241000282887 Suidae Species 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 238000003975 animal breeding Methods 0.000 description 2
- 239000003674 animal food additive Substances 0.000 description 2
- 150000001720 carbohydrates Chemical class 0.000 description 2
- 235000014633 carbohydrates Nutrition 0.000 description 2
- OSVXSBDYLRYLIG-UHFFFAOYSA-N dioxidochlorine(.) Chemical compound O=Cl=O OSVXSBDYLRYLIG-UHFFFAOYSA-N 0.000 description 2
- -1 indole organic acids Chemical class 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 2
- 235000005985 organic acids Nutrition 0.000 description 2
- ZFRKQXVRDFCRJG-UHFFFAOYSA-N skatole Chemical compound C1=CC=C2C(C)=CNC2=C1 ZFRKQXVRDFCRJG-UHFFFAOYSA-N 0.000 description 2
- GETQZCLCWQTVFV-UHFFFAOYSA-N trimethylamine Chemical compound CN(C)C GETQZCLCWQTVFV-UHFFFAOYSA-N 0.000 description 2
- OCJBOOLMMGQPQU-UHFFFAOYSA-N 1,4-dichlorobenzene Chemical compound ClC1=CC=C(Cl)C=C1 OCJBOOLMMGQPQU-UHFFFAOYSA-N 0.000 description 1
- 239000004155 Chlorine dioxide Substances 0.000 description 1
- IMROMDMJAWUWLK-UHFFFAOYSA-N Ethenol Chemical compound OC=C IMROMDMJAWUWLK-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- LSDPWZHWYPCBBB-UHFFFAOYSA-N Methanethiol Chemical compound SC LSDPWZHWYPCBBB-UHFFFAOYSA-N 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 235000010443 alginic acid Nutrition 0.000 description 1
- 239000000783 alginic acid Substances 0.000 description 1
- 229960001126 alginic acid Drugs 0.000 description 1
- 229920000615 alginic acid Polymers 0.000 description 1
- 150000004781 alginic acids Chemical class 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- SIKJAQJRHWYJAI-UHFFFAOYSA-N benzopyrrole Natural products C1=CC=C2NC=CC2=C1 SIKJAQJRHWYJAI-UHFFFAOYSA-N 0.000 description 1
- 235000019398 chlorine dioxide Nutrition 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 230000002542 deteriorative effect Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000029087 digestion Effects 0.000 description 1
- 230000002550 fecal effect Effects 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 230000002496 gastric effect Effects 0.000 description 1
- 238000000338 in vitro Methods 0.000 description 1
- 238000001727 in vivo Methods 0.000 description 1
- PZOUSPYUWWUPPK-UHFFFAOYSA-N indole Natural products CC1=CC=CC2=C1C=CN2 PZOUSPYUWWUPPK-UHFFFAOYSA-N 0.000 description 1
- RKJUIXBNRJVNHR-UHFFFAOYSA-N indolenine Natural products C1=CC=C2CC=NC2=C1 RKJUIXBNRJVNHR-UHFFFAOYSA-N 0.000 description 1
- 244000144972 livestock Species 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 230000000873 masking effect Effects 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 239000005416 organic matter Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 238000012827 research and development Methods 0.000 description 1
- 229940074386 skatole Drugs 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 238000004659 sterilization and disinfection Methods 0.000 description 1
- 239000003206 sterilizing agent Substances 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 210000002700 urine Anatomy 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23B—PRESERVATION OF FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES; CHEMICAL RIPENING OF FRUIT OR VEGETABLES
- A23B2/00—Preservation of foods or foodstuffs, in general
- A23B2/70—Preservation of foods or foodstuffs, in general by treatment with chemicals
- A23B2/725—Preservation of foods or foodstuffs, in general by treatment with chemicals in the form of liquids or solids
- A23B2/729—Organic compounds; Microorganisms; Enzymes
- A23B2/733—Compounds of undetermined constitution obtained from animals or plants
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23B—PRESERVATION OF FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES; CHEMICAL RIPENING OF FRUIT OR VEGETABLES
- A23B2/00—Preservation of foods or foodstuffs, in general
- A23B2/70—Preservation of foods or foodstuffs, in general by treatment with chemicals
- A23B2/725—Preservation of foods or foodstuffs, in general by treatment with chemicals in the form of liquids or solids
- A23B2/729—Organic compounds; Microorganisms; Enzymes
- A23B2/742—Organic compounds containing oxygen
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- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Chemical & Material Sciences (AREA)
- Food Science & Technology (AREA)
- Polymers & Plastics (AREA)
- Disinfection, Sterilisation Or Deodorisation Of Air (AREA)
Abstract
本发明公开了一种有机酸杀菌除臭剂及其制备方法,其组成原料的重量份为:豆荚纤维140‑180、米糠纤维100‑120、膨化豆渣80‑90、玉米面粉30‑50、熏衣草提取液70‑90、苹果提取液30‑50、海藻酸钠3‑5、阿魏酸7‑9、绿原酸3‑5、柠檬酸1‑2、聚乙烯吡咯烷酮2‑3。本发明将豆荚纤维、米糠纤维、膨化豆渣、玉米面粉科学配合作为载体,载体分子间孔隙较大,吸附性能好,经过熏衣草提取液、苹果提取液处理后得到改性载体,可以与硫化氢、硫醇、氨、胺、醛、酮、酸等臭味分子发生化学反应而达到彻底除臭的效果,改性载体与阿魏酸、绿原酸、柠檬酸的配合使用使得本发明杀菌除臭作用进一步增强,净化效果大大增加。The invention discloses an organic acid sterilizing and deodorizing agent and a preparation method thereof. The raw materials are composed of 140-180 parts by weight of bean pod fiber, 100-120 parts of rice bran fiber, 80-90 part of puffed bean dregs, 30-50 part of corn flour, smoked Laminaria extract 70‑90, apple extract 30‑50, sodium alginate 3‑5, ferulic acid 7‑9, chlorogenic acid 3‑5, citric acid 1‑2, polyvinylpyrrolidone 2‑3. In the present invention, the scientific combination of bean pod fiber, rice bran fiber, puffed bean dregs, and corn flour is used as the carrier. The pores between the carrier molecules are relatively large and the adsorption performance is good. The modified carrier is obtained after being treated with lavender extract and apple extract, which can be combined with vulcanization Hydrogen, mercaptans, ammonia, amines, aldehydes, ketones, acids and other odor molecules undergo chemical reactions to achieve a complete deodorizing effect. The combination of modified carriers and ferulic acid, chlorogenic acid, and citric acid makes the present invention sterilize The deodorizing effect is further enhanced, and the purification effect is greatly increased.
Description
技术领域technical field
本发明涉及饲料添加剂加工制备技术领域,具体涉及一种有机酸杀菌除臭剂及其制备方法。The invention relates to the technical field of feed additive processing and preparation, in particular to an organic acid bactericidal deodorant and a preparation method thereof.
背景技术Background technique
随着我国规模化、集约化畜牧业的发展,动物养殖中产生的臭粪、臭气对环境的污染不断加剧。恶化的环境不但对人类的健康造成极大的威胁,而且也严重影响着动物的健康和生产性能的发挥,因此,对畜牧场臭粪、臭气的治理愈来愈引起人们的重视。动物养殖中产生污染,主要来源于动物粪尿中携带的一些有毒或有异味的物质,这些物质种类繁杂,绝大部分为有机类恶臭气体,例如吲哚类有机酸、粪臭素、脂肪类胺硫醇、硫化氢等。动物排泄物所含有机物大致可分为含氮化合物和碳水化合物两大类,它们在缺氧的环境下分解出不同的臭味气体。含氮化合物在无氧时分解为氨、硫化氢、硫酸、乙烯醇、三甲胺、二甲基硫醚等恶臭气体;碳水化合物在缺氧时因氧化不完全而分解为甲烷、有机酸、醇类等带有臭味或酸味的物质。传统依靠物理吸附和香味掩盖等除臭剂并不能从根本上消除臭味分子的存在,臭味实际上依然存在,所以除臭效果并不理想,依靠二氧化氯、对二氯苯等化学品除臭,虽然除臭效果相对较好,但其对人和动物的刺激性较大,不适宜添加到饲料中使用。随着绿色饲料理念的深入,人们越来越重视饲料的安全问题,因此,研究开发可以在动物体内、体外除臭且安全环保的饲料添加剂具有广阔的市场前景和应用价值。With the development of large-scale and intensive animal husbandry in China, the pollution of stinky feces and odors produced in animal breeding to the environment is increasing. The deteriorating environment not only poses a great threat to human health, but also seriously affects the health and production performance of animals. Therefore, people pay more and more attention to the control of stinky dung and odor in livestock farms. Pollution in animal breeding mainly comes from some toxic or odorous substances carried in animal excrement and urine. These substances are of various types, most of which are organic odorous gases, such as indole organic acids, skatole, fatty amines Mercaptans, hydrogen sulfide, etc. The organic matter contained in animal excrement can be roughly divided into two categories: nitrogen-containing compounds and carbohydrates, which decompose into different odorous gases in an oxygen-deficient environment. Nitrogen-containing compounds decompose into malodorous gases such as ammonia, hydrogen sulfide, sulfuric acid, vinyl alcohol, trimethylamine, and dimethyl sulfide in the absence of oxygen; carbohydrates decompose into methane, organic acids, alcohols due to incomplete oxidation in the absence of oxygen Smelly or sour-tasting substances such as Traditional deodorants such as physical adsorption and fragrance masking cannot fundamentally eliminate the existence of odor molecules, and the odor actually still exists, so the deodorization effect is not ideal. Relying on chemicals such as chlorine dioxide and p-dichlorobenzene Deodorization, although the deodorization effect is relatively good, but it is more irritating to humans and animals, so it is not suitable to be added to feed. With the deepening of the concept of green feed, people pay more and more attention to the safety of feed. Therefore, the research and development of feed additives that can deodorize in vivo and in vitro of animals and are safe and environmentally friendly has broad market prospects and application value.
发明内容Contents of the invention
为了弥补现有技术的不足,本发明提供了一种有机酸杀菌除臭剂及其制备方法。In order to make up for the deficiencies of the prior art, the invention provides an organic acid bactericidal deodorant and a preparation method thereof.
本发明的技术方案如下:Technical scheme of the present invention is as follows:
一种有机酸杀菌除臭剂,其组成原料的重量份为:豆荚纤维140-180、米糠纤维100-120、膨化豆渣80-90、玉米面粉30-50、熏衣草提取液70-90、苹果提取液30-50、海藻酸钠3-5、阿魏酸7-9、绿原酸3-5、柠檬酸1-2、聚乙烯吡咯烷酮2-3。An organic acid sterilizing and deodorant agent. The raw materials are composed of 140-180 parts by weight of bean pod fiber, 100-120 parts of rice bran fiber, 80-90 parts of puffed bean dregs, 30-50 parts of corn flour, 70-90 parts of lavender extract, Apple extract 30-50, sodium alginate 3-5, ferulic acid 7-9, chlorogenic acid 3-5, citric acid 1-2, polyvinylpyrrolidone 2-3.
所述的有机酸杀菌除臭剂的制备方法,包括以下步骤:The preparation method of described organic acid bactericidal deodorant comprises the following steps:
(1)将豆荚纤维、米糠纤维、膨化豆渣、玉米面粉进行混合,得到预改性载体,待用;(1) Mix bean pod fiber, rice bran fiber, puffed bean dregs, and corn flour to obtain a pre-modified carrier for use;
(2)将熏衣草提取液、苹果提取液进行混合,再加入海藻酸钠混合成有一定黏稠度的溶液,得到改性溶液,待用;(2) Mix lavender extract and apple extract, then add sodium alginate and mix to form a solution with a certain viscosity to obtain a modified solution for use;
(3)将步骤(2)的改性溶液加入到步骤(1)的预改性载体中浸渍过夜,然后放入60-70℃温度下干燥至含水量小于15%,得到改性载体,取出,待用;(3) Add the modified solution in step (2) to the pre-modified carrier in step (1) and soak overnight, then dry at 60-70°C until the water content is less than 15%, to obtain a modified carrier, take it out ,stand-by;
(4)将阿魏酸、绿原酸、柠檬酸混合并加水溶解,再加入聚乙烯吡咯烷酮使酸液均匀分散,得到有机酸溶液,待用;(4) Mix ferulic acid, chlorogenic acid, and citric acid, add water to dissolve, then add polyvinylpyrrolidone to disperse the acid liquid evenly, and obtain an organic acid solution for use;
(5)将步骤(4)的有机酸溶液与步骤(3)的改性载体混合,制成软材,用制粒机制成粒径3-6mm的颗粒,将所得颗粒置于60-70℃环境中干燥至含水量降至8%以下,取出,真空包装,得到成品。(5) Mix the organic acid solution in step (4) with the modified carrier in step (3) to make a soft material, use a granulator to make particles with a particle size of 3-6mm, and place the obtained particles at 60-70°C Dry in the environment until the water content drops below 8%, take it out, and vacuum pack it to get the finished product.
本发明的有益效果:Beneficial effects of the present invention:
1、本发明将豆荚纤维、米糠纤维、膨化豆渣、玉米面粉科学配合作为载体,载体分子间孔隙较大,吸附性能好,经过熏衣草提取液、苹果提取液处理后得到改性载体,可以与硫化氢、硫醇、氨、胺、醛、酮、酸等臭味分子发生化学反应而达到彻底除臭的效果,改性载体与阿魏酸、绿原酸、柠檬酸的配合使用使得本发明杀菌除臭作用进一步增强,净化效果大大增加。1. The present invention uses bean pod fiber, rice bran fiber, puffed bean dregs, and corn flour as a scientific carrier. The pores between the carrier molecules are relatively large and the adsorption performance is good. After being treated with lavender extract and apple extract, the modified carrier can be obtained. Chemically react with odor molecules such as hydrogen sulfide, mercaptan, ammonia, amine, aldehyde, ketone, acid, etc. to achieve a complete deodorizing effect. The combination of modified carrier and ferulic acid, chlorogenic acid, citric acid makes this product The sterilization and deodorization effect of the invention is further enhanced, and the purification effect is greatly increased.
2、本发明选材安全、无毒,可以添加到饲料中供动物食用,改善动物的胃肠消化功能,减少粪臭,还可与动物粪便互混,对粪便进行杀菌除臭。2. The material of the present invention is safe and non-toxic, and can be added to feed for animals to eat, improve the gastrointestinal digestion function of animals, reduce fecal odor, and can also be mixed with animal feces to sterilize and deodorize feces.
具体实施方式detailed description
下面将结合本发明实施例,对本发明中的技术方案进行清楚、完整地描述,凡是其他在不脱离本发明核心的情况下做出的简单的变形或修改均落入本发明的保护范围。The technical solutions in the present invention will be clearly and completely described below in conjunction with the embodiments of the present invention. All other simple deformations or modifications made without departing from the core of the present invention fall within the protection scope of the present invention.
一种有机酸杀菌除臭剂,其组成原料的重量份(千克)为:豆荚纤维140、米糠纤维100、膨化豆渣80、玉米面粉30、熏衣草提取液70、苹果提取液30、海藻酸钠3、阿魏酸7、绿原酸3、柠檬酸1、聚乙烯吡咯烷酮2。An organic acid bactericidal deodorant, the weight parts (kg) of its raw materials are: 140 parts by weight of bean pod fiber, 100 parts of rice bran fiber, 80 parts of puffed bean dregs, 30 parts of corn flour, 70 parts of lavender extract, 30 parts of apple extract, and alginic acid Sodium 3, ferulic acid 7, chlorogenic acid 3, citric acid 1, polyvinylpyrrolidone 2.
所述的有机酸杀菌除臭剂的制备方法,包括以下步骤:The preparation method of described organic acid bactericidal deodorant comprises the following steps:
(1)将豆荚纤维、米糠纤维、膨化豆渣、玉米面粉进行混合,得到预改性载体,待用;(1) Mix bean pod fiber, rice bran fiber, puffed bean dregs, and corn flour to obtain a pre-modified carrier for use;
(2)将熏衣草提取液、苹果提取液进行混合,再加入海藻酸钠混合成有一定黏稠度的溶液,得到改性溶液,待用;(2) Mix lavender extract and apple extract, then add sodium alginate and mix to form a solution with a certain viscosity to obtain a modified solution for use;
(3)将步骤(2)的改性溶液加入到步骤(1)的预改性载体中浸渍过夜,然后放入60℃温度下干燥至含水量小于15%,得到改性载体,取出,待用;(3) Add the modified solution in step (2) to the pre-modified carrier in step (1) and soak overnight, then dry at 60°C until the water content is less than 15%, to obtain a modified carrier, take it out, and wait for use;
(4)将阿魏酸、绿原酸、柠檬酸混合并加水溶解,再加入聚乙烯吡咯烷酮使酸液均匀分散,得到有机酸溶液,待用;(4) Mix ferulic acid, chlorogenic acid, and citric acid, add water to dissolve, then add polyvinylpyrrolidone to disperse the acid liquid evenly, and obtain an organic acid solution for use;
(5)将步骤(4)的有机酸溶液与步骤(3)的改性载体混合,制成软材,用制粒机制成粒径3mm的颗粒,将所得颗粒置于60℃环境中干燥至含水量降至8%以下,取出,真空包装,得到成品。(5) Mix the organic acid solution in step (4) with the modified carrier in step (3) to make a soft material, use a granulator to make particles with a particle size of 3mm, and dry the obtained particles in an environment at 60°C to The water content is reduced to below 8%, taken out, and vacuum-packed to obtain the finished product.
以猪为试验对象,将本发明除臭剂按0.5%的添加量添加于杜长大三元杂交猪饲料中,连续饲喂3-5天时,粪臭开始减轻,饲喂至2-3周后,粪臭得到明显改善,臭味去除率在85%以上。将本发明除臭剂与猪粪混合堆沤,猪粪臭味基本消除。Taking pigs as the test object, the deodorant of the present invention is added to the feed of Du long-term three-way hybrid pigs in an amount of 0.5%, and when fed continuously for 3-5 days, the excrement odor begins to alleviate, and it is fed for 2-3 weeks After that, the manure odor was significantly improved, and the odor removal rate was above 85%. When the deodorant of the present invention is mixed with pig manure and stacked, the smell of pig manure is basically eliminated.
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