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CN105936774A - High dispersion waterborne paint pigment composition and application thereof - Google Patents

High dispersion waterborne paint pigment composition and application thereof Download PDF

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Publication number
CN105936774A
CN105936774A CN201610398353.0A CN201610398353A CN105936774A CN 105936774 A CN105936774 A CN 105936774A CN 201610398353 A CN201610398353 A CN 201610398353A CN 105936774 A CN105936774 A CN 105936774A
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CN
China
Prior art keywords
parts
pigment
water paint
polymolecularity
waterborne paint
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610398353.0A
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Chinese (zh)
Inventor
张建强
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
WUJIANG TUNCUN PIGMENT PLANT
Original Assignee
WUJIANG TUNCUN PIGMENT PLANT
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by WUJIANG TUNCUN PIGMENT PLANT filed Critical WUJIANG TUNCUN PIGMENT PLANT
Priority to CN201610398353.0A priority Critical patent/CN105936774A/en
Publication of CN105936774A publication Critical patent/CN105936774A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D17/00Pigment pastes, e.g. for mixing in paints
    • C09D17/003Pigment pastes, e.g. for mixing in paints containing an organic pigment
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/63Additives non-macromolecular organic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/65Additives macromolecular

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Pigments, Carbon Blacks, Or Wood Stains (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention relates to a high dispersion waterborne paint pigment composition, which comprises the following raw materials by weight: 30-50 parts of an organic pigment, 3-5 parts of fatty acid methyl ester polyoxyethylene ether, 0.5-2 parts of Ninol, 1-4 parts of phthalic acid, 1-2 parts of sodium chloride, 8-15 parts of a solvent, 1-2 parts of n-butylamine, 2-3 parts of N-tallow-N,N,N'N'N'-pentamethyl-11, 3-propanediamine dihydrochloride, 4-8 parts of an emulsifier, 1-2 parts of a dispersant MF, 3-7 parts of 1, 2-o-benzenedicarboxylic acid, and 0.5-1 part of polyester modified polydimethylsiloxane. As a pigment for waterborne paint, the waterborne paint pigment composition provided by the invention is convenient to use, can be fully mixed with water soluble resin, a film-forming agent, water and other raw materials according to the method normally used by the industry so as to obtain waterborne paint, and the use dispersibility is excellent, and the prepared waterborne paint system has good stability. At the same time, the waterborne paint pigment composition involved in the invention has wide applicability, and can be prepared into waterborne paint of various colors.

Description

The water paint color compositions of a kind of polymolecularity and application thereof
Technical field
The present invention relates to a kind of pigment used for offset ink, be specifically related to the water of a kind of polymolecularity Property coating pigment compositions and application thereof.
Background technology
The pigment of coating imparts painting color feature, meets coating coating and wants color Ask.Water paint is mainly by water-soluble resin, pigment, aqueous solvent, film former and emulsifying agent etc. Forming through Compound Machining, in use available water is diluted processing, and uses water as owing to adopting For solvent, without benzene, formaldehyde, toluene, dimethylbenzene, free TDI, toxic heavy metal etc., Nontoxic have no irritating odor, harmless, there is preferable safety in utilization, environmental protection. Pigment in the water paint used in prior art, due to its distribution density relatively solvent based coating Much greater, and the polarity of water and surface tension are all the biggest with solvent difference so that dividing of pigment Dissipate more difficulty, directly influence system stability and the viscosity number of coating, use bad dispersibility The water paint of pigment carry out brushing and often can cause coating color defect pockety, sternly Ghost image rings brushing quality.Solve problem many employings pigment of water paint pigment-dispersing difference at present The method being combined with emulsifying agent, but be still difficult to solve pigment bad dispersibility in coating system Problem, deposits for a long time and is easily caused color and luster lamination.
Summary of the invention
Not enough for prior art, the invention provides the water paint pigment of a kind of polymolecularity Compositions, for the pigment of the water paint as stable system.
The present invention solves the technical scheme of above-mentioned technical problem employing: the water of a kind of polymolecularity Property coating pigment compositions, including the raw material of following parts by weight: organic pigment 30~50 parts, Fatty acid methyl ester polyoxyethylene ether 3~5 parts, ninol 0.5~2 parts, sodium chloride 1~2 parts, molten Agent 8~15 parts, n-butylamine 1~2 parts, N-Adeps Bovis seu Bubali base-N, N, N'N'N'-pentamethyl-11,3-third Diamine dihydrochloride 2~3 parts, emulsifying agent 4~8 parts, Dispersant MF 1~2 parts, 1,2-neighbour's benzene two Carboxylic acid 3~7 parts, polyester modification polydimethylsiloxane 0.5~1 part.
Further, the water paint color compositions of described a kind of polymolecularity, including following The raw material of weight portion: organic pigment 40 parts, fatty acid methyl ester polyoxyethylene ether 4 parts, Ni Na That 1.2 parts, 1.5 parts of sodium chloride, solvent 12 parts, n-butylamine 1.5 parts, N-Adeps Bovis seu Bubali base -N, N, N'N'N'-pentamethyl-11,3-propane diamine dihydrochloride 2.5 parts, emulsifying agent 6 part, point Powder MF1.5 part, 1,2-neighbour's benzene dicarboxylic acid 5 parts, polyester modification polydimethylsiloxane 0.8 Part.
Further, described organic pigment is C.I. Pigment Blue 15 class pigment, quinacridone-type pigments or idol Nitrogen pigment.
Further, described solvent is the mixture of deionized water and N-Methyl pyrrolidone, Its mass parts ratio is 1~3:1.
Further, described emulsifying agent is the mixed of dodecyl sodium sulfate and emulsifying agent C-12 Compound, its mass parts is than for 1:2~3.
Further, the water paint color compositions of a kind of polymolecularity is as water paint face The application of material.
Concrete, in use, by the water paint color compositions of the present invention by described weight Amount is after part is on the waiting list described raw material, adds raw materials in ultrasonic vibration dispersing apparatus under uniform temperature It is uniformly dispersed, is subsequently placed in high speed dispersor, add the water-soluble resin of certain proportioning, one-tenth Membrane, aqueous solvent and other auxiliary agents, obtain stability after sufficiently dispersion stir process and make With the water paint of function admirable.
Compared with prior art, the beneficial effect that the present invention possesses: the water paint face of the present invention Feed composition is as the pigment of water paint, easy to use, only need to be according to usual in the industry The raw materials such as the method used and water-soluble resin, film former and water are sufficiently mixed and can obtain aqueous Coating;The use dispersibility of the water paint color compositions of the present invention is excellent, prepares Aqueous coating system stability is preferable;The water paint color compositions pigment suitability of the present invention Extensively, the water paint of shades of colour can be prepared.
Detailed description of the invention
Below in conjunction with specific embodiment, the present invention is described further.
Embodiment 1: the water paint color compositions of a kind of polymolecularity, including following weight The raw material of part: organic pigment 40 parts, fatty acid methyl ester polyoxyethylene ether 4 parts, ninol 1.2 Part, 1.5 parts of sodium chloride, solvent 12 parts, n-butylamine 1.5 parts, N-Adeps Bovis seu Bubali base-N, N, N'N'N'- Pentamethyl-11,3-propane diamine dihydrochloride 2.5 parts, emulsifying agent 6 parts, Dispersant MF 1.5 parts, 1,2-neighbour's benzene dicarboxylic acid 5 parts, polyester modification polydimethylsiloxane 0.8 part.
Further, the α-copper phthalocyanine during described organic pigment is C.I. Pigment Blue 15 class pigment; Described solvent is the mixture of deionized water and N-Methyl pyrrolidone, and its mass parts ratio is 2:1;Described emulsifying agent is dodecyl sodium sulfate and the mixture of emulsifying agent C-12, its matter Amount part ratio is for 2:5.
Embodiment 2: the water paint color compositions of a kind of polymolecularity, including following weight The raw material of part: organic pigment 30 parts, fatty acid methyl ester polyoxyethylene ether 3 parts, ninol 0.5 Part, 1 part of sodium chloride, n-butylamine 1 part, solvent 8 parts, N-Adeps Bovis seu Bubali base-N, N, N'N'N'- Pentamethyl-11,3-propane diamine dihydrochloride 2 parts, emulsifying agent 4 parts, Dispersant MF 1 part, 1,2- Adjacent benzene dicarboxylic acid 3 parts, polyester modification polydimethylsiloxane 0.5 part.
Further, the pigment violet 19 during described organic pigment is quinacridone-type pigments;Institute The solvent stated is the mixture of deionized water and N-Methyl pyrrolidone, and its mass parts ratio is 1:1;Described emulsifying agent is dodecyl sodium sulfate and the mixture of emulsifying agent C-12, its matter Amount part ratio is for 1:3.
Embodiment 3: the water paint color compositions of a kind of polymolecularity, including following weight The raw material of part: organic pigment 50 parts, fatty acid methyl ester polyoxyethylene ether 5 parts, ninol 2 Part, 2 parts of sodium chloride, n-butylamine 2 parts, solvent 15 parts, N-Adeps Bovis seu Bubali base-N, N, N'N'N'- Pentamethyl-11,3-propane diamine dihydrochloride 3 parts, emulsifying agent 8 parts, Dispersant MF 2 parts, 1,2- Adjacent benzene dicarboxylic acid 7 parts, polyester modification polydimethylsiloxane 1 part.
Further, the pigment red 122 during described organic pigment is quinacridone-type pigments;Institute The solvent stated is the mixture of deionized water and N-Methyl pyrrolidone, and its mass parts ratio is 3:1;Described emulsifying agent is dodecyl sodium sulfate and the mixture of emulsifying agent C-12, its matter Amount part ratio is for 1:2.
Embodiment 4: the water paint color compositions of a kind of polymolecularity, including following weight The raw material of part: organic pigment 30 parts, fatty acid methyl ester polyoxyethylene ether 3 parts, ninol 2 Part, 2 parts of sodium chloride, n-butylamine 2 parts, solvent 8 parts, N-Adeps Bovis seu Bubali base-N, N, N'N'N'- Pentamethyl-11,3-propane diamine dihydrochloride 3 parts, emulsifying agent 4 parts, Dispersant MF 2 parts, 1,2- Adjacent benzene dicarboxylic acid 3 parts, polyester modification polydimethylsiloxane 1 part.
Further, the pigment yellow 93 during described organic pigment is AZOpigments;Described is molten Agent is the mixture of deionized water and N-Methyl pyrrolidone, and its mass parts is than for 1:1;Described Emulsifying agent be dodecyl sodium sulfate and the mixture of emulsifying agent C-12, its mass parts ratio is 1:2。
Embodiment 5: the water paint color compositions of a kind of polymolecularity, including following weight The raw material of part: organic pigment 45 parts, fatty acid methyl ester polyoxyethylene ether 4.5 parts, ninol 1.5 parts, 1.4 parts of sodium chloride, n-butylamine 1.1 parts, solvent 10 parts, N-Adeps Bovis seu Bubali base -N, N, N'N'N'-pentamethyl-11,3-propane diamine dihydrochloride 2.2 parts, emulsifying agent 5 part, point Powder MF0.7 part, 1,2-neighbour's benzene dicarboxylic acid 6 parts, polyester modification polydimethylsiloxane 0.6 Part.
Further, the pigment brown 23 during described organic pigment is AZOpigments;Described is molten Agent is the mixture of deionized water and N-Methyl pyrrolidone, and its mass parts is than for 3:2;Described Emulsifying agent be dodecyl sodium sulfate and the mixture of emulsifying agent C-12, its mass parts ratio is 3:8。
In use, by the water paint color compositions of above-described embodiment 1-5 gained by described Weight portion be on the waiting list described raw material after, add raw materials in ultrasonic vibration dispersing apparatus in a constant temperature Be uniformly dispersed under degree, be subsequently placed in high speed dispersor, add certain proportioning water-soluble resin, Film former, aqueous solvent and other auxiliary agents, obtain after sufficiently dispersion stir process stability and The water paint that serviceability is excellent.
In order to test the dispersibility stability of color compositions of the present invention, by above-described embodiment 1-5 After the water paint color compositions of gained is on the waiting list described raw material by described weight portion, by raw material Add in ultrasonic vibration dispersing apparatus at 50 DEG C fully dispersed uniformly, obtain pigment preparations Compositions, then weighs pigment preparations combination in mass parts than the ratio for 3:5:2:1:3 Thing, water-soluble polyester resin, nanometer inorganic filler, film former and water are placed in high speed dispersor, Sufficiently disperse stir process, water paint product will be obtained and carry out dispersibility mensuration storage Stability Determination;By the pigment in each embodiment and the emulsifying agent described in embodiment and dispersion Agent be placed in ultrasonic vibration dispersing apparatus at 50 DEG C fully dispersed uniformly, obtain pre-dispersed face Feed composition, then weighs pigment preparations combination in mass parts than the ratio for 3:5:2:1:3 Thing, water-soluble polyester resin, nanometer inorganic filler, film former and water are placed in high speed dispersor, Sufficiently disperse stir process, the product obtained is entered as the comparative example 1 of the present embodiment Row dispersibility measures storage stability and measures;By the pigment in each embodiment and water-soluble polyester Resin, nanometer inorganic filler, film former and water are claimed than the ratio for 3:5:2:1:3 in mass parts Take and be placed in high speed dispersor, sufficiently disperse stir process, as the present embodiment Comparative example 2 is tested.Concrete outcome is as shown in the table.
Test result shows, the color compositions of the present invention adds emulsifying agent and dispersion than common Pigment and the pure pigment dispersive property in coating system of agent are excellent, and storage stability Preferably, within 30 days, high temperature storage does not shows the phenomenons such as obvious layerings, but commonly adds emulsifying agent With the pigment of dispersant, unconspicuous layering occurs in coating system, and pure pigment is at coating body In system, stored experiment occurs in that and is the most substantially layered, and storage stability is poor.

Claims (6)

1. the water paint color compositions of a polymolecularity, it is characterised in that include following The raw material of parts by weight: organic pigment 30~50 parts, fatty acid methyl ester polyoxyethylene ether 3~5 parts, Ninol 0.5~2 parts, sodium chloride 1~2 parts, solvent 8~15 parts, n-butylamine 1~2 parts, N- Adeps Bovis seu Bubali base-N, N, N'N'N'-pentamethyl-11,3-propane diamine dihydrochloride 2~3 parts, emulsifying agent 4~8 parts, Dispersant MF 1~2 parts, 1,2-neighbour's benzene dicarboxylic acid 3~7 parts, the poly-diformazan of polyester modification Radical siloxane 0.5~1 part.
The water paint color compositions of a kind of polymolecularity the most according to claim 1, It is characterized in that, including the raw material of following parts by weight: organic pigment 40 parts, fatty acid methyl Ester polyoxyethylene ether 4 parts, ninol 1.2 parts, 1.5 parts of sodium chloride, solvent 12 parts, just Butylamine 1.5 parts, N-Adeps Bovis seu Bubali base-N, N, N'N'N'-pentamethyl-11,3-propane diamine dihydrochloride 2.5 parts, emulsifying agent 6 parts, Dispersant MF 1.5 parts, 1,2-neighbour's benzene dicarboxylic acid 5 parts, polyester Modified dimethyl polysiloxane 0.8 part.
The water paint pigment combination of a kind of polymolecularity the most according to claim 1 and 2 Thing, it is characterised in that: described organic pigment be C.I. Pigment Blue 15 class pigment, quinacridone-type pigments or AZOpigments.
The water paint pigment combination of a kind of polymolecularity the most according to claim 1 and 2 Thing, it is characterised in that: described solvent is the mixing of deionized water and N-Methyl pyrrolidone Thing, its mass parts ratio is 1~3:1.
The water paint pigment combination of a kind of polymolecularity the most according to claim 1 and 2 Thing, it is characterised in that: described emulsifying agent is dodecyl sodium sulfate and emulsifying agent C-12 Mixture, its mass parts is than for 1:2~3.
6. the water paint color compositions conduct of a kind of polymolecularity described in claim 1 or 2 The application of water paint pigment.
CN201610398353.0A 2016-06-07 2016-06-07 High dispersion waterborne paint pigment composition and application thereof Pending CN105936774A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN117659771A (en) * 2023-12-21 2024-03-08 江西三越新材料有限公司 A high solid content nano water-based color paste and its preparation method

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4152272A (en) * 1976-10-29 1979-05-01 The Procter & Gamble Company Fabric conditioning composition
CN1926197A (en) * 2004-02-26 2007-03-07 科莱恩产品(德国)有限公司 Preparation of transparent phthalocyanine pigments

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4152272A (en) * 1976-10-29 1979-05-01 The Procter & Gamble Company Fabric conditioning composition
CN1926197A (en) * 2004-02-26 2007-03-07 科莱恩产品(德国)有限公司 Preparation of transparent phthalocyanine pigments

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
阎素斋等: "《特种印刷油墨》", 31 May 2004, 化学工业出版社 *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN117659771A (en) * 2023-12-21 2024-03-08 江西三越新材料有限公司 A high solid content nano water-based color paste and its preparation method

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Application publication date: 20160914