CN105899550A - Systems and compositions for creating three-dimensional objects - Google Patents
Systems and compositions for creating three-dimensional objects Download PDFInfo
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- CN105899550A CN105899550A CN201580002913.XA CN201580002913A CN105899550A CN 105899550 A CN105899550 A CN 105899550A CN 201580002913 A CN201580002913 A CN 201580002913A CN 105899550 A CN105899550 A CN 105899550A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/16—Writing inks
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/101—Inks specially adapted for printing processes involving curing by wave energy or particle radiation, e.g. with UV-curing following the printing
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/16—Writing inks
- C09D11/17—Writing inks characterised by colouring agents
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Abstract
本发明示出和描述了用于创建三维艺术品和物体的系统和方法。Systems and methods for creating three-dimensional artwork and objects are shown and described herein.
Description
相关申请的交叉引用Cross References to Related Applications
本申请要求2014年10月20日提交的标题为“用于创建三维艺术品和物体的系统和方法”的第62/066,002号美国临时申请的权益。所述临时专利申请的完整公开内容在此通过引用并入本文。This application claims the benefit of US Provisional Application No. 62/066,002, filed October 20, 2014, entitled "System and Method for Creating Three-Dimensional Artwork and Objects." The entire disclosure of said provisional patent application is hereby incorporated by reference.
技术领域technical field
本发明总体上涉及书写和绘图工具领域,更具体地涉及用于创建三维艺术品和物体的工具和油墨。The present invention relates generally to the field of writing and drawing implements, and more particularly to implements and inks for creating three-dimensional artwork and objects.
背景技术Background technique
目前可使用采用电源和粉末的三维打印机(three-dimensional printer)来打印机器中的物体。例如,第7,435,368号美国专利教导了一种三维打印机,其采用喷墨式打印头和粉末以还原(prototype)和打印三维模型。其他三维打印装置是更灵活的并且采用挤出热物质的笔式装置和电源以提供这样的材料,该材料冷却形成三维材料,更像喷胶枪。Three-dimensional printers using power and powder are currently available to print objects in the machine. For example, US Patent No. 7,435,368 teaches a three-dimensional printer that uses an inkjet print head and powder to prototype and print a three-dimensional model. Other 3D printing devices are more flexible and employ a pen-like device that extrudes hot material and a power source to deliver a material that cools to form a three-dimensional material, much like a glue gun.
然而,这些装置和方法供儿童使用是笨重或危险的。需要供儿童使用的用于提供三维绘图技术的系统和装置,其无需使用电子机械或热化学品。However, these devices and methods are cumbersome or dangerous for children to use. There is a need for systems and devices for use by children that provide three-dimensional mapping techniques that do not require the use of electromechanical or hot chemicals.
本发明的公开内容Disclosure of the invention
本发明包括这样的系统和装置,其通过在不粘表面上挤出快干复合物,然后去除干燥的艺术品或物体来允许儿童和成人创建用于包含在较大物体或较大件艺术品中的三维物体和艺术品。The present invention includes systems and devices that allow children and adults to create objects for inclusion in larger objects or larger pieces of art by extruding a quick-drying compound on a non-stick surface and then removing the dried art or object. 3D objects and artwork in .
本发明包括快干或快凝(fast-setting)复合物,其可被垂直挤出以创建三维物体。快凝复合物通过光进行固化。The present invention includes quick-drying or fast-setting compounds that can be extruded vertically to create three-dimensional objects. Fast-setting compounds are cured by light.
通过考虑详细描述和附图,本发明的其他方面将变得显而易见。Other aspects of the invention will become apparent by consideration of the detailed description and accompanying drawings.
附图的几个视图的简述BRIEF DESCRIPTION OF THE SEVERAL VIEWS OF THE DRAWINGS
在下列附图中,附图形成说明书的一部分并且应结合说明书进行解释,其中在全文中使用相同的引用符号并尽可能在各个视图中表示相似的部件:In the following drawings, which form a part of the specification and are to be interpreted in conjunction with the specification, the same reference symbols are used throughout and refer to similar parts in the various views as far as possible:
图1是本发明的第一个实施方案的笔的透视图;Figure 1 is a perspective view of a pen according to a first embodiment of the present invention;
图2是本发明的笔和书写板的透视图;Figure 2 is a perspective view of the pen and tablet of the present invention;
图3是本发明的实施方案的笔的右截面图;Fig. 3 is the right sectional view of the pen of the embodiment of the present invention;
图4是本发明的第二个实施方案的右侧立面(elevational)图;Figure 4 is a right elevational view of a second embodiment of the present invention;
图5是本发明的第三个实施方案的笔的透视图;Figure 5 is a perspective view of a pen of a third embodiment of the present invention;
图6是本发明的第三个实施方案的部件分解图;Figure 6 is an exploded view of a third embodiment of the present invention;
图7是本发明的第三个实施方案的前立面图;Fig. 7 is the front elevation view of the third embodiment of the present invention;
图8是本发明的第三个实施方案的后立面图;Figure 8 is a rear elevation view of a third embodiment of the present invention;
图9是本发明的第三个实施方案的移除储液囊(reservoir)的右侧立面图;Figure 9 is a right side elevational view of a third embodiment of the present invention with the reservoir removed;
图10是本发明的第三个实施方案的顶视图;以及Figure 10 is a top view of a third embodiment of the present invention; and
图11是本发明的第三个实施方案的底视图。Figure 11 is a bottom view of a third embodiment of the present invention.
实施本发明的最佳方式Best Mode for Carrying Out the Invention
整个说明书引用的“一个实施方案(one embodiment)”、“实施方案(anembodiment)”、“一个实施例(one example)”或“实施例(an example)”是指与该实施方案或实施例有关的特定特征、结构或特性包括在本发明的至少一个实施方案中。因此,在本说明书中多个地方出现的短语“在一个实施方案中(in one embodiment)”、“在实施方案中(in an embodiment)”、“一个实施例(one example)”或“实施例(an example)”不一定全部是指相同的实施方案或实施例。此外,可以任何合适的组合和/或子组合形式将特定特征、结构或特性结合在一个或多个实施方案或实施例中。此外,应当理解,在此提供的附图是为了向本领域一般技术人员解释的目的并且附图不必按比例绘制。References throughout the specification to "one embodiment", "anembodiment", "one example" or "an example" refer to The particular feature, structure or characteristic is included in at least one embodiment of the invention. Thus, in various places in this specification the phrases "in one embodiment", "in an embodiment", "one example" or "an example (an example)" are not necessarily all referring to the same embodiment or example. Furthermore, particular features, structures or characteristics may be combined in any suitable combination and/or subcombination in one or more embodiments or examples. Furthermore, it should be understood that the drawings provided herein are for purposes of explanation to those of ordinary skill in the art and that the drawings are not necessarily drawn to scale.
仅为了方便而非限制的目的,在下文定义了一些术语以帮助理解示例性实施方案。在下文未定义权利要求中使用的术语的情况下,应该给予该术语达到相关领域技术人员给予该术语最宽定义的程度,如在出版的公开出版物和授权专利中所体现的。For convenience and not limitation, some terms are defined below to aid in the understanding of the exemplary embodiments. To the extent a term used in a claim is not defined below, that term should be given the broadest definition persons skilled in the pertinent art have given that term, as reflected in published publications and issued patents.
如本文使用的,当放置在数值“X”之前时,术语“约”是指从X减X的10%延伸至X加X的10%的区间,优选X减X的5%延伸至X加X的5%的区间,且甚至更优选X减X的2%延伸至X加X的2%的区间。As used herein, the term "about" when placed before the numerical value "X" refers to an interval extending from X minus 10% of X to X plus 10% of X, preferably extending from X minus 5% of X to X plus The interval of 5% of X, and even more preferably X minus 2% of X extends to the interval of X plus 2% of X.
术语“倾斜”不以限制性意义使用,因为倾斜表面也可能是弓形或圆锥形的。The term "inclined" is not used in a limiting sense, since inclined surfaces may also be arcuate or conical.
术语“复合物(compound)”、“组合物”、“成分”和“组分”有时可交换使用,用于指一种或多种化学组分。如本文使用的,术语“复合物”是指由两种或多种单独要素成分(elements)组成的混合物。The terms "compound", "composition", "ingredient" and "component" are sometimes used interchangeably to refer to one or more chemical components. As used herein, the term "complex" refers to a mixture consisting of two or more individual elements.
术语“油墨”意指包括任何染色材料,其包括但不限于油墨、染料、颜料或其他类似的染色液体。The term "ink" is intended to include any coloring material including, but not limited to, inks, dyes, pigments, or other similar coloring liquids.
如本文使用的,术语“光”是指日光或人造光,包括本领域已知的白炽光、LED光、荧光光源。As used herein, the term "light" refers to daylight or artificial light, including incandescent light, LED light, fluorescent light sources known in the art.
当用于描述本发明的油墨组合物时,术语“液体”意指包括能够在给定表面上分散或展开的组合物的任何非固体的物理状态,即,处于其高度可流动状态以及半固体粘性状态两者。When used to describe the ink composition of the present invention, the term "liquid" is meant to include any non-solid physical state of the composition capable of being dispersed or spread over a given surface, i.e., in its highly flowable state as well as semi-solid Sticky state both.
如本文使用的,术语“喷嘴”包括用于引导或改变流体流动的任何常规或优选的静态机械装置。As used herein, the term "nozzle" includes any conventional or preferred static mechanical device for directing or altering the flow of a fluid.
如本文使用的,术语“触针(stylus)”不只包括笔形装置,而且,术语“笔”和“触针”可通用和交换使用。As used herein, the term "stylus" does not include only pen-shaped devices, and the terms "pen" and "stylus" are used interchangeably and interchangeably.
如本文使用的,术语“储液囊”包括用于容纳流体的容器或室。As used herein, the term "reservoir" includes a container or chamber for containing fluid.
尽管本文在描述附图时可进行方位引用,诸如上部、下部、向下、向上、向后、底部、前面、背面等,但为了方便,相对于附图(如通常观察的)进行这些引用。这些方位不旨在按字面意思解释或以任何形式限制本发明。此外,为了描述的目的在本文使用诸如“第一”、“第二”和“第三”的术语,这些术语不旨在表示或暗示相对的重要性或显著性。术语包括上述特别提及的词语、其派生词和类似的输入词语。Although directional references, such as upper, lower, downward, upward, rearward, bottom, front, rear, etc., may be made herein in describing the drawings, for convenience these references are made with respect to the drawings (as viewed normally). These orientations are not intended to be interpreted literally or to limit the invention in any way. Furthermore, terms such as "first", "second" and "third" are used herein for descriptive purposes, and these terms are not intended to indicate or imply relative importance or significance. The terminology includes the words specifically mentioned above, derivatives thereof and similar imported words.
在本文中使用的“包括(including)”、“包括(comprising)”或“具有(having)”及其变型意指包括此后列举的项目及其等同物以及附加项目。"Including", "comprising" or "having" and variations thereof as used herein are meant to include the items listed thereafter and their equivalents as well as additional items.
除非另外规定或限制,术语“安装”、“连接”、“支持”和“联接”及其变型概括地使用并且包括直接和间接的安装、连接、支持和联接两者。此外,“连接”和“联接”不局限于物理或机械连接或联接。Unless otherwise specified or limited, the terms "mount," "connect," "support," and "couple" and variations thereof are used generically and include both direct and indirect mounting, connecting, supporting, and coupling. Furthermore, "connected" and "coupled" are not limited to physical or mechanical connections or couplings.
本发明提供包括可压缩储液囊502的笔100,其具有近端104、远端106和从近端104延伸至远端106的侧壁108,储液囊502容纳液体复合物110;喷嘴112联接至储液囊502的近端104,液体复合物通过喷嘴离开储液囊。当挤压储液囊502时,储液囊502中的液体复合物110被迫离开喷嘴112。笔100由允许容易压缩储液囊502的薄壁塑性材料组成。喷嘴112足够大,使得足以将一定量的复合物110挤出在表面上。提供帽116。The present invention provides a pen 100 comprising a compressible reservoir 502 containing a liquid compound 110 having a proximal end 104, a distal end 106, and a sidewall 108 extending from the proximal end 104 to the distal end 106; Coupled to the proximal end 104 of the reservoir 502, the liquid compound exits the reservoir through a nozzle. When the reservoir 502 is squeezed, the liquid compound 110 in the reservoir 502 is forced out of the nozzle 112 . The pen 100 is composed of a thin-walled plastic material that allows the reservoir 502 to be easily compressed. Nozzle 112 is large enough to extrude a quantity of compound 110 onto the surface. A cap 116 is provided.
如图2所示,笔100用于给予油墨组合物以在具有缺口或凹口201(待填充油墨)的平面或表面200上绘制二维物体。优选地,表面为由适当材料(诸如具有不粘涂层的硅酮或层压塑性材料)组成的不粘表面202。表面202为透明的并且包括期望的绘图物体204或者提供期望的绘图物体204形式的凹口201。可备选地,将绘图物体204打印成平面202。As shown in Figure 2, the pen 100 is used to impart an ink composition to draw a two-dimensional object on a plane or surface 200 having indentations or notches 201 (to be filled with ink). Preferably, the surface is a non-stick surface 202 composed of a suitable material such as silicone or laminated plastic with a non-stick coating. Surface 202 is transparent and includes the desired drawing object 204 or a notch 201 that provides the desired drawing object 204 form. Alternatively, drawing object 204 is printed as plane 202 .
液体油墨复合物110是在储液囊502中和当从喷嘴112中挤出时保持为液体或凝胶形式的材料。当与光接触时,液体复合物110开始迅速硬化并且凝固成纤维材料302。纤维材料302是柔性的,但足够致密以保持一定形状。因此,在硬化时,其可从绘图表面202去除并且用于创建诸如图2示出的物体三维物体。液体复合物110可由许多不同材料组成,所述材料允许在暴露于光时快速干燥。液体复合物110可包括染料材料以允许改变绘图物体的颜色。Liquid ink compound 110 is a material that remains in liquid or gel form within reservoir 502 and when extruded from nozzle 112 . When exposed to light, the liquid composite 110 begins to harden rapidly and solidifies into the fibrous material 302 . The fibrous material 302 is flexible but dense enough to hold a shape. Thus, when hardened, it can be removed from the drawing surface 202 and used to create a three-dimensional object such as that shown in FIG. 2 . Liquid composite 110 can be composed of many different materials that allow for rapid drying when exposed to light. The liquid composition 110 may include a dye material to allow changing the color of the drawn object.
通过使用笔100摹写二维物体204。当挤出油墨复合物110时,其变干燥。一旦复合物干燥,就从绘图表面202去除油墨纤维材料302。可通过在纤维材料件之间提供连接件304将诸如眼镜的眼镜脚的其他二维物体连接至干燥的纤维材料302。以该方式,创建三维物体306。A two-dimensional object 204 is traced by using the pen 100 . When the ink composite 110 is extruded, it dries. Once the composite is dry, the ink fibrous material 302 is removed from the drawing surface 202 . Other two-dimensional objects, such as temples of eyeglasses, may be joined to dry fibrous material 302 by providing connectors 304 between pieces of fibrous material. In this way, a three-dimensional object 306 is created.
图3示出具有相对于外部侧壁108的内部部分的笔100。示出位于外部储液囊内的内部储液囊502以容纳复合物110。内部储液囊502与喷嘴112连接。通过手动操作夹持系统500使容纳在储液囊内的复合物110偏离储液囊502。当在侧壁108上施加压力时,将偏置夹504、506挤压至在502的每个侧面上的储液囊502中。通过枢轴连接件602在笔的远端枢轴连接偏置夹504、506。FIG. 3 shows the pen 100 having an inner portion relative to the outer sidewall 108 . The inner reservoir 502 is shown positioned within the outer reservoir to contain the composite 110 . Internal reservoir 502 is connected to nozzle 112 . The compound 110 contained within the reservoir is deflected away from the reservoir 502 by manual manipulation of the clamping system 500 . When pressure is applied on sidewall 108 , biasing clips 504 , 506 are squeezed into reservoir 502 on each side of 502 . The biasing clips 504 , 506 are pivotally connected at the distal end of the pen by a pivot connection 602 .
图4示出没有图3的夹持系统500的笔350的可备选的实施方案。笔100由外部套管352组成,外部套管352形成用于容纳组合物110的可压缩储液囊354。在手动压缩套管352时,压缩储液囊354以从喷嘴356挤出组合物110。FIG. 4 shows an alternative embodiment of the pen 350 without the clamping system 500 of FIG. 3 . The pen 100 consists of an outer sleeve 352 forming a compressible reservoir 354 for containing the composition 110 . Upon manual compression of cannula 352 , reservoir 354 is compressed to extrude composition 110 from nozzle 356 .
由上所述,应该清楚与使用一般的笔或铅笔时所采用的方式类似,人们可使用笔100进行书写、打印、绘制或着色。以基本上相同的方式夹住笔。以与笔或铅笔的书写尖端基本上相同的方式移动喷嘴。唯一的不同在于,使用者在食指和拇指之间同时挤压笔100以当使用者给予喷嘴书写、打印、绘制或着色动作时引起和控制液体复合物从喷嘴112的流动。From the above, it should be clear that one can use the pen 100 to write, print, draw or color in a manner similar to that used when using a normal pen or pencil. Clip the pen in essentially the same way. Move the nozzle in essentially the same way as the writing tip of a pen or pencil. The only difference is that the user squeezes the pen 100 between the index finger and thumb simultaneously to cause and control the flow of the liquid compound from the nozzle 112 when the user gives the nozzle a writing, printing, drawing or coloring action.
本发明的油墨组合物包括光可固化树脂。更具体地,本发明的油墨组合物为包含不饱和预聚物和光引发剂的混合物。可使用的另外成分包括但不限于染料和弹性体。The ink composition of the present invention includes a photocurable resin. More specifically, the ink composition of the present invention is a mixture comprising an unsaturated prepolymer and a photoinitiator. Additional ingredients that may be used include, but are not limited to, dyes and elastomers.
油墨组合物使用不饱和预聚物或光可固化树脂。不饱和预聚物或光可固化树脂可以以足以给予组合物期望的固化速率的量存在。不饱和预聚物选自由不饱和聚氨酯预聚物、不饱和聚丙烯酸酯预聚物、不饱和环氧基预聚物或其各种比例的共聚物组成的组。以整个组合物的重量计,不饱和预聚物或光可固化树脂可以以小于60%至约85%的量存在。The ink composition uses an unsaturated prepolymer or a photocurable resin. The unsaturated prepolymer or photocurable resin may be present in an amount sufficient to give the composition the desired rate of cure. The unsaturated prepolymer is selected from the group consisting of unsaturated polyurethane prepolymer, unsaturated polyacrylate prepolymer, unsaturated epoxy prepolymer or copolymers thereof in various proportions. The unsaturated prepolymer or photocurable resin may be present in an amount from less than 60% to about 85% by weight of the total composition.
本发明的油墨组合物包括选自聚合光引发剂的苯甲酰基氧化膦种类的光引发剂。优选地,使用的光引发剂为2,4,6-三甲基苯甲酰基二苯基氧化膦。以整个组合物的重量计,光引发剂可以以小于1%至约10%的量存在。The ink composition of the present invention includes a photoinitiator selected from the benzoylphosphine oxide class of polymeric photoinitiators. Preferably, the photoinitiator used is 2,4,6-trimethylbenzoyldiphenylphosphine oxide. Photoinitiators may be present in amounts of less than 1% to about 10% by weight of the total composition.
除了苯甲酰基氧化膦种类的光引发剂之外,可使用第二光引发剂。该第二光引发剂选自(4-二甲基氨基)苯甲酸乙酯或(2-二甲基氨基)苯甲酸乙酯组成的组。以整个组合物的重量计,第二光引发剂可以以小于1%至约5%的量存在。In addition to photoinitiators of the benzoylphosphine oxide class, a second photoinitiator may be used. The second photoinitiator is selected from the group consisting of ethyl (4-dimethylamino)benzoate or ethyl (2-dimethylamino)benzoate. The second photoinitiator may be present in an amount from less than 1% to about 5% by weight of the total composition.
可使用硅弹性体光分散剂(light dispersing agent)。以整个组合物的重量计,光分散剂可以以小于1%至约5%的量存在。Silicone elastomer light dispersing agents may be used. Optical dispersants may be present in amounts of less than 1% to about 5% by weight of the total composition.
组合物中可包含丙二醇作为防腐剂和乳化剂。以整个组合物的重量计,乳化剂可以以小于1%至约10%的量存在。Propylene glycol may be included in the composition as a preservative and emulsifier. Emulsifiers may be present in amounts from less than 1% to about 10% by weight of the total composition.
组合物中可包含增塑剂。可接受的增塑剂可包括但不限于环氧化大豆油。以整个组合物的重量计,增塑剂可以以小于1%至约10%的量存在。Plasticizers may be included in the composition. Acceptable plasticizers may include, but are not limited to, epoxidized soybean oil. Plasticizers may be present in amounts of less than 1% to about 10% by weight of the total composition.
组合物中可包含增稠剂。增稠剂可包括但不限于单硬脂酸甘油酯。以整个组合物的重量计,增稠剂可以以小于1%至约5%的量存在。Thickeners may be included in the composition. Thickening agents may include, but are not limited to, glyceryl monostearate. Thickeners may be present in amounts of less than 1% to about 5% by weight of the total composition.
组合物中可包含稳定剂。稳定剂可包括但不限于丁基化羟基甲苯或丁基化羟基苯甲醚或类似物。以整个组合物的重量计,稳定剂可以以小于1%至约2%的量存在。Stabilizers may be included in the composition. Stabilizers may include, but are not limited to, butylated hydroxytoluene or butylated hydroxyanisole, or the like. Stabilizers may be present in amounts of less than 1% to about 2% by weight of the total composition.
组合物中可包含另外的油和溶剂以调整处于其液体形式的组合物的粘度。Additional oils and solvents may be included in the composition to adjust the viscosity of the composition in its liquid form.
可用于本发明的染料包括但不限于FD&C黄色#5(购自B F Goodrich HiltonDavis Chemical Company,Brecksville,Ohio)、FD&C黄色#6(购自B F Goodrich HiltonDavis Chemical Company)、D&C黄色#10(购自Warner Jenkinson,St.Louis,Mo.)、FD&C蓝色#1(购自B F Goodrich Hilton Davis Chemical Company)、D&C红色#28(购自WarnerJenkinson)、D&C红色#33(购自Warner Jenkinson)、品红色分散体(Magenta Dispersion)(购自Warner Jenkinson)、绿色分散体(Green Dispersion)(购自Colorcon,West Point,Pa.)和黄色分散体(Yellow Dispersion)(购自Colorcon)。Dyes useful in the present invention include, but are not limited to, FD&C Yellow #5 (available from B F Goodrich Hilton Davis Chemical Company, Brecksville, Ohio), FD&C Yellow #6 (available from B F Goodrich Hilton Davis Chemical Company), D&C Yellow #10 (available from Warner Jenkinson, St. Louis, Mo.), FD&C Blue #1 (available from B F Goodrich Hilton Davis Chemical Company), D&C Red #28 (available from Warner Jenkinson), D&C Red #33 (available from Warner Jenkinson), Magenta Disperse Magenta Dispersion (available from Warner Jenkinson), Green Dispersion (available from Colorcon, West Point, Pa.), and Yellow Dispersion (available from Colorcon).
染料以足以给予组合物明显着色的量存在。以整个组合物的重量计,染料可以以小于1%至约10%的量存在。The dye is present in an amount sufficient to impart substantial coloring to the composition. Dyes may be present in amounts from less than 1% to about 10% by weight of the total composition.
许多颜料可用作本发明组合物的染料成分。液体填充组合物可被着色为红色、品红色、粉红色、黄色、蓝色、橙色、紫色、紫罗兰色、绿色等。通常,使用高度可见的诱人颜色,包括颜色的荧光版本。A wide variety of pigments can be used as the dye component of the compositions of the present invention. The liquid fill composition can be colored red, magenta, pink, yellow, blue, orange, purple, violet, green, and the like. Often, highly visible, alluring colors are used, including fluorescent versions of the colors.
可使用下文详细描述的光或通过来自单独装置或阳光的光来固化油墨组合物。The ink composition can be cured using light as described in detail below or by light from a separate device or sunlight.
笔400的可备选实施方案在图5-11中提供,其使用人造光阵列420来固化从笔400挤出的油墨组合物。外部人造光可用于固化油墨组合物,诸如来自内灯或来自聚光灯的光。还可使用自然阳光。额外的光加速了固化过程。An alternative embodiment of the pen 400 is provided in FIGS. 5-11 that uses an array of artificial light 420 to cure the ink composition extruded from the pen 400 . External artificial light can be used to cure the ink composition, such as light from an interior lamp or from a spotlight. Natural sunlight can also be used. The extra light speeds up the curing process.
笔400包括外壳436和可移除可压缩的储液囊402,该储液囊402具有近端404、远端406和从近端404延伸至远端406的侧壁408,储液囊402容纳液体复合物110;喷嘴412联接至储液囊402的近端404,液体复合物通过喷嘴离开储液囊。当压缩储液囊402时,储液囊402中的液体复合物110被迫离开喷嘴412。可压缩储液囊402由薄壁塑料构建,其允许人手进行手动压缩。喷嘴412足够大,以使一定量的复合物110挤出在表面上。如图所示,储液囊402旨在用于手动压缩储液囊以从储液囊挤出组合物。然而,设想其他挤出机制是合适的并且同样可使用。设想第一实施方案使用的加压夹也可用于压缩本实施方案的储液囊402。The pen 400 includes a housing 436 and a removable compressible reservoir 402 having a proximal end 404, a distal end 406, and a sidewall 408 extending from the proximal end 404 to the distal end 406, the reservoir 402 containing The liquid compound 110; the nozzle 412 is coupled to the proximal end 404 of the reservoir 402 through which the liquid compound exits the reservoir. When the reservoir 402 is compressed, the liquid compound 110 in the reservoir 402 is forced out of the nozzle 412 . The compressible reservoir 402 is constructed of thin walled plastic which allows manual compression by the human hand. Nozzle 412 is large enough to extrude a volume of compound 110 onto the surface. As shown, the reservoir 402 is intended for manual compression of the reservoir to express composition from the reservoir. However, it is contemplated that other extrusion mechanisms are suitable and could equally be used. It is contemplated that the compression clips used with the first embodiment may also be used to compress the reservoir 402 of this embodiment.
如图5所示,笔400是沿着笔400的纵轴延伸的细长结构以适合手。光阵列420提供用于储液囊内的液体油墨在挤出后的固化机制。喷嘴412位于笔400的近端414,邻近照明阵列420,并从那里延长一段距离以允许从喷嘴挤出。As shown in FIG. 5, the pen 400 is an elongated structure extending along the longitudinal axis of the pen 400 to fit the hand. The light array 420 provides a curing mechanism for the liquid ink within the reservoir after extrusion. The nozzle 412 is located at the proximal end 414 of the pen 400, adjacent to the illumination array 420, and extends a distance from there to allow extrusion from the nozzle.
如本领域技术人员理解的,在固化前,必须将油墨组合物从喷嘴中完全挤出,否则喷嘴将被堵塞。因此,在固化前,油墨组合物必须远离喷嘴,并且任何固化机制必须适应该挤出。本发明的人造照明阵列420使用结构有效的喷嘴并结合光布置以提供挤出点附近的固化机制,且不堵塞喷嘴开口438。As will be appreciated by those skilled in the art, the ink composition must be fully extruded from the nozzle prior to curing, otherwise the nozzle will become clogged. Therefore, the ink composition must be kept away from the nozzle prior to curing, and any curing mechanism must accommodate this extrusion. The artificial lighting array 420 of the present invention uses structurally efficient nozzles in combination with a light arrangement to provide a curing mechanism near the point of extrusion without clogging the nozzle openings 438 .
如图9所示,喷嘴从储液囊402的主体452延伸。喷嘴包括圆形末端450,其包括挤出孔448和倾斜喷嘴主体454,其从笔400的近端414的环绕424延伸。图7所示的倾斜喷嘴部分454是具有围绕喷嘴部分454的周长的三个弓形或倾斜凹口456的弓形部分。在弓形凹口456之间,三个弓形桥458沿着喷嘴部分454的周长延伸。结合下文更充分地讨论光阵列420,当与光阵列420一起使用时弓形桥458产生阴影以限制喷嘴的最近尖端的光暴露至远离喷嘴更远的距离。As shown in FIG. 9 , the nozzle extends from the body 452 of the reservoir 402 . The nozzle includes a rounded tip 450 that includes an extrusion aperture 448 and an angled nozzle body 454 that extends from the surround 424 of the proximal end 414 of the pen 400 . The angled nozzle portion 454 shown in FIG. 7 is an arcuate portion having three arcuate or angled notches 456 around the perimeter of the nozzle portion 454 . Between the arcuate notches 456 , three arcuate bridges 458 extend along the perimeter of the nozzle portion 454 . In conjunction with light array 420 discussed more fully below, arcuate bridge 458 creates shadows when used with light array 420 to limit light exposure of the nearest tip of the nozzle to a greater distance away from the nozzle.
照明阵列420包括至少两种指向喷嘴412的光416、418,以当从喷嘴412挤出组合物时向其提供光源。在试验中,申请人发现多种光可帮助提高油墨组合物的固化速度。也可在光阵列中提供另外的光422以用另外的光来固化挤出的组合物。使油墨组合物固化的速度显著影响产品的使用。在该方式中,组合物在被挤出时可固化并且凝固。邻近喷嘴454的弓形桥458设置这些光416、418、422。照明阵列420的光指向朝喷嘴的尖端450的一定角度。光的角度可为20度至60度。The lighting array 420 includes at least two lights 416, 418 directed at the nozzle 412 to provide a source of light to the composition as it is extruded from the nozzle 412. In experiments, applicants have discovered that various lights can help increase the curing speed of the ink composition. Additional light 422 may also be provided in the light array to cure the extruded composition with additional light. The speed at which the ink composition is cured significantly affects the use of the product. In this manner, the composition can be cured and set when extruded. These lights 416 , 418 , 422 are positioned adjacent to the arcuate bridge 458 of the nozzle 454 . The light of the illumination array 420 is directed at an angle towards the tip 450 of the nozzle. The angle of light can be from 20 degrees to 60 degrees.
在喷嘴412周围以一定角度排列提供照明阵列420以有效引导光朝向喷嘴412的尖端。如图所示,布置照明阵列为在喷嘴周围等距隔开的光416、418、422。光416、418、422可包括本领域已知的任何灯泡,其足以提供光以固化挤出的组合物。光416、418、422设置在笔400的近端414的环绕424内。环绕424可为凹形并且可为光滑的或有角的并且反光以放大由光元件416、418、422产生的光。示出的环绕424包围喷嘴。An illumination array 420 is provided arranged at an angle around the nozzle 412 to efficiently direct light toward the tip of the nozzle 412 . As shown, the illumination array is arranged as lights 416, 418, 422 equally spaced around the nozzle. Lights 416, 418, 422 may comprise any light bulb known in the art sufficient to provide light to cure the extruded composition. Lights 416 , 418 , 422 are disposed within surround 424 of proximal end 414 of pen 400 . The surround 424 may be concave and may be smooth or angled and reflective to amplify the light generated by the light elements 416 , 418 , 422 . A surround 424 is shown surrounding the nozzle.
可将诸如透镜的适于光透射和放大的放大装置480与笔的外壳436连接。放大装置480可用于放大来自环境或来自光阵列420的光以更快地固化组合物。放大装置480包括至少一个透镜482以放大光。A magnifying device 480 such as a lens adapted for light transmission and magnification may be attached to the housing 436 of the pen. Amplifying device 480 may be used to amplify light from the environment or from light array 420 to cure the composition more quickly. The magnifying means 480 includes at least one lens 482 to magnify the light.
照明阵列420具有电源426和控制电路434。电源426可为存放在装置内的电池并且通过进入位于笔400的远端430的开口428进行更换。按纽432控制照明阵列420的操作。控制电路434调整光阵列420的强度水平处于安全水平和充足水平以固化油墨组合物。控制电路434可包括用于电源426的升压器或减压器。The lighting array 420 has a power source 426 and a control circuit 434 . The power source 426 may be a battery stored within the device and replaced through access to an opening 428 located at the distal end 430 of the pen 400 . Button 432 controls the operation of lighting array 420 . The control circuit 434 adjusts the intensity level of the light array 420 at a safe level and a sufficient level to cure the ink composition. Control circuit 434 may include a voltage booster or voltage reducer for power supply 426 .
可移除储液囊402安装在位于外壳436中的凹进438内。储液囊包括喷嘴412作为一体化结构。在外壳436中放置可压缩储液囊402时将喷嘴412安装在环绕的凹进内。Removable reservoir 402 fits within a recess 438 in housing 436 . The reservoir includes the nozzle 412 as an integral structure. Placing the compressible reservoir 402 in the housing 436 mounts the nozzle 412 in the surrounding recess.
从前述内容可以看出,本发明连同结构固有的其他优点可更好地适合获得本文阐述的所有目的和目标。尽管已经详细描述本发明,上述内容仅为了说明的目的并且不应认为以任何方式限制本发明的范围。如本领域技术人员更显而易见的,各种其他修改和组件包括在本发明的范围内。From the foregoing it will be seen that the present invention, together with other advantages inherent in its structure, is better adapted to attain all the objects and objects set forth herein. While the invention has been described in detail, the foregoing is for illustrative purposes only and should not be construed as limiting the scope of the invention in any way. Various other modifications and components are included within the scope of the invention, as would be more apparent to those skilled in the art.
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| US201462066002P | 2014-10-20 | 2014-10-20 | |
| US62/066,002 | 2014-10-20 | ||
| PCT/US2015/033701 WO2016064453A1 (en) | 2014-10-20 | 2015-06-02 | System and composition for creating three-dimensional objects |
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Citations (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN2102851U (en) * | 1991-07-08 | 1992-04-29 | 韩军 | Protruding type writing-painting pen |
| US20070248795A1 (en) * | 2003-06-19 | 2007-10-25 | Serigraph, Inc. | Formed Graphic Applique |
| CN101111362A (en) * | 2005-12-01 | 2008-01-23 | 松下电器产业株式会社 | Three-dimensional structure manufacturing method and manufacturing device |
| CN201141942Y (en) * | 2007-11-09 | 2008-10-29 | 段锋 | Jewelry amplifier |
| CN101563208A (en) * | 2006-12-21 | 2009-10-21 | 爱克发印艺公司 | 3D-inkjet printing methods |
| US20100256255A1 (en) * | 2009-04-07 | 2010-10-07 | Charles Stevens | Jettable ink composition |
| CN102481729A (en) * | 2009-07-29 | 2012-05-30 | 再德克斯私人有限公司 | 3D printing on rotating cylindrical surfaces |
| CN103231514A (en) * | 2013-04-01 | 2013-08-07 | 杭州笔水画王电子科技有限公司 | 3d printer |
| WO2013121230A1 (en) * | 2012-02-17 | 2013-08-22 | The University Court Of The University Of Glasgow | Apparatus and methods for the preparation of reaction vessels with a 3d -printer |
| CN103476570A (en) * | 2011-02-23 | 2013-12-25 | 3D系统公司 | Carrier materials and their applications |
| US20140120319A1 (en) * | 2012-11-01 | 2014-05-01 | Benjamin E. Joseph | 3d mapping using structured light and formation of custom surface contours |
| US20140131908A1 (en) * | 2012-11-14 | 2014-05-15 | Dentsply International Inc. | Three-dimensional fabricating material systems for producing dental products |
| CN203622962U (en) * | 2013-11-21 | 2014-06-04 | 西安嘉乐世纪机电科技有限公司 | 3D (three-dimensional) paintbrush |
| CN203649400U (en) * | 2013-12-10 | 2014-06-18 | 黄德欢 | Three-nozzle photo-curing 3D printer |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2008077850A2 (en) * | 2006-12-21 | 2008-07-03 | Agfa Graphics Nv | 3d-inkjet printing methods |
-
2015
- 2015-06-02 CN CN201580002913.XA patent/CN105899550A/en active Pending
- 2015-06-02 WO PCT/US2015/033701 patent/WO2016064453A1/en not_active Ceased
Patent Citations (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN2102851U (en) * | 1991-07-08 | 1992-04-29 | 韩军 | Protruding type writing-painting pen |
| US20070248795A1 (en) * | 2003-06-19 | 2007-10-25 | Serigraph, Inc. | Formed Graphic Applique |
| CN101111362A (en) * | 2005-12-01 | 2008-01-23 | 松下电器产业株式会社 | Three-dimensional structure manufacturing method and manufacturing device |
| CN101563208A (en) * | 2006-12-21 | 2009-10-21 | 爱克发印艺公司 | 3D-inkjet printing methods |
| CN201141942Y (en) * | 2007-11-09 | 2008-10-29 | 段锋 | Jewelry amplifier |
| US20100256255A1 (en) * | 2009-04-07 | 2010-10-07 | Charles Stevens | Jettable ink composition |
| CN102481729A (en) * | 2009-07-29 | 2012-05-30 | 再德克斯私人有限公司 | 3D printing on rotating cylindrical surfaces |
| CN103476570A (en) * | 2011-02-23 | 2013-12-25 | 3D系统公司 | Carrier materials and their applications |
| WO2013121230A1 (en) * | 2012-02-17 | 2013-08-22 | The University Court Of The University Of Glasgow | Apparatus and methods for the preparation of reaction vessels with a 3d -printer |
| US20140120319A1 (en) * | 2012-11-01 | 2014-05-01 | Benjamin E. Joseph | 3d mapping using structured light and formation of custom surface contours |
| US20140131908A1 (en) * | 2012-11-14 | 2014-05-15 | Dentsply International Inc. | Three-dimensional fabricating material systems for producing dental products |
| CN103231514A (en) * | 2013-04-01 | 2013-08-07 | 杭州笔水画王电子科技有限公司 | 3d printer |
| CN203622962U (en) * | 2013-11-21 | 2014-06-04 | 西安嘉乐世纪机电科技有限公司 | 3D (three-dimensional) paintbrush |
| CN203649400U (en) * | 2013-12-10 | 2014-06-18 | 黄德欢 | Three-nozzle photo-curing 3D printer |
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