CN105861170A - Water expelling type automobile windscreen cleaning agent and preparation method - Google Patents
Water expelling type automobile windscreen cleaning agent and preparation method Download PDFInfo
- Publication number
- CN105861170A CN105861170A CN201610286406.XA CN201610286406A CN105861170A CN 105861170 A CN105861170 A CN 105861170A CN 201610286406 A CN201610286406 A CN 201610286406A CN 105861170 A CN105861170 A CN 105861170A
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- CN
- China
- Prior art keywords
- type automobile
- window glass
- expelling water
- agent
- automobile window
- Prior art date
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 60
- 238000002360 preparation method Methods 0.000 title claims abstract description 12
- 239000012459 cleaning agent Substances 0.000 title abstract 5
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 22
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 20
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 17
- 239000001257 hydrogen Substances 0.000 claims abstract description 17
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims abstract description 14
- 229920000570 polyether Polymers 0.000 claims abstract description 13
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims abstract description 12
- 239000000839 emulsion Substances 0.000 claims abstract description 12
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims abstract description 10
- VWDWKYIASSYTQR-UHFFFAOYSA-N sodium nitrate Chemical compound [Na+].[O-][N+]([O-])=O VWDWKYIASSYTQR-UHFFFAOYSA-N 0.000 claims abstract description 10
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims abstract description 9
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 claims abstract description 9
- 238000005260 corrosion Methods 0.000 claims abstract description 9
- 230000007797 corrosion Effects 0.000 claims abstract description 9
- 229910017604 nitric acid Inorganic materials 0.000 claims abstract description 9
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims abstract description 7
- QTTDXDAWQMDLOF-UHFFFAOYSA-J tetrasodium 3-[[4-[[4-[(6-amino-1-hydroxy-3-sulfonatonaphthalen-2-yl)diazenyl]-6-sulfonatonaphthalen-1-yl]diazenyl]naphthalen-1-yl]diazenyl]naphthalene-1,5-disulfonate Chemical compound [Na+].[Na+].[Na+].[Na+].Nc1ccc2c(O)c(N=Nc3ccc(N=Nc4ccc(N=Nc5cc(c6cccc(c6c5)S([O-])(=O)=O)S([O-])(=O)=O)c5ccccc45)c4ccc(cc34)S([O-])(=O)=O)c(cc2c1)S([O-])(=O)=O QTTDXDAWQMDLOF-UHFFFAOYSA-J 0.000 claims abstract description 7
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims abstract description 6
- 239000002736 nonionic surfactant Substances 0.000 claims abstract description 6
- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 claims abstract description 6
- 235000010234 sodium benzoate Nutrition 0.000 claims abstract description 6
- 239000004299 sodium benzoate Substances 0.000 claims abstract description 6
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 claims abstract description 5
- 235000010344 sodium nitrate Nutrition 0.000 claims abstract description 5
- 239000004317 sodium nitrate Substances 0.000 claims abstract description 5
- AEQDJSLRWYMAQI-UHFFFAOYSA-N 2,3,9,10-tetramethoxy-6,8,13,13a-tetrahydro-5H-isoquinolino[2,1-b]isoquinoline Chemical compound C1CN2CC(C(=C(OC)C=C3)OC)=C3CC2C2=C1C=C(OC)C(OC)=C2 AEQDJSLRWYMAQI-UHFFFAOYSA-N 0.000 claims abstract description 3
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims abstract description 3
- CDQSJQSWAWPGKG-UHFFFAOYSA-N butane-1,1-diol Chemical compound CCCC(O)O CDQSJQSWAWPGKG-UHFFFAOYSA-N 0.000 claims abstract description 3
- 239000000176 sodium gluconate Substances 0.000 claims abstract description 3
- 235000012207 sodium gluconate Nutrition 0.000 claims abstract description 3
- 229940005574 sodium gluconate Drugs 0.000 claims abstract description 3
- 239000005357 flat glass Substances 0.000 claims description 39
- 239000011521 glass Substances 0.000 claims description 20
- 229920002545 silicone oil Polymers 0.000 claims description 16
- 238000000034 method Methods 0.000 claims description 13
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 10
- 239000000203 mixture Substances 0.000 claims description 9
- 239000012752 auxiliary agent Substances 0.000 claims description 8
- 229960000935 dehydrated alcohol Drugs 0.000 claims description 8
- 235000015393 sodium molybdate Nutrition 0.000 claims description 8
- 239000011684 sodium molybdate Substances 0.000 claims description 8
- TVXXNOYZHKPKGW-UHFFFAOYSA-N sodium molybdate (anhydrous) Chemical compound [Na+].[Na+].[O-][Mo]([O-])(=O)=O TVXXNOYZHKPKGW-UHFFFAOYSA-N 0.000 claims description 8
- 239000001117 sulphuric acid Substances 0.000 claims description 8
- 235000011149 sulphuric acid Nutrition 0.000 claims description 8
- XFRVVPUIAFSTFO-UHFFFAOYSA-N 1-Tridecanol Chemical compound CCCCCCCCCCCCCO XFRVVPUIAFSTFO-UHFFFAOYSA-N 0.000 claims description 7
- 229920000056 polyoxyethylene ether Polymers 0.000 claims description 7
- 229940051841 polyoxyethylene ether Drugs 0.000 claims description 7
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 6
- 239000002994 raw material Substances 0.000 claims description 6
- 239000000975 dye Substances 0.000 claims description 4
- 239000002253 acid Substances 0.000 claims description 3
- 229960004756 ethanol Drugs 0.000 claims description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical group [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims 1
- 230000003628 erosive effect Effects 0.000 claims 1
- 150000002431 hydrogen Chemical class 0.000 claims 1
- 229910052717 sulfur Inorganic materials 0.000 claims 1
- 239000011593 sulfur Substances 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract description 11
- 238000007710 freezing Methods 0.000 abstract description 4
- 230000032683 aging Effects 0.000 abstract description 2
- 239000003112 inhibitor Substances 0.000 abstract 2
- -1 methyl hydrogen Chemical compound 0.000 abstract 2
- 239000004721 Polyphenylene oxide Substances 0.000 abstract 1
- 239000012964 benzotriazole Substances 0.000 abstract 1
- 229920001296 polysiloxane Polymers 0.000 abstract 1
- ULWHHBHJGPPBCO-UHFFFAOYSA-N propane-1,1-diol Chemical compound CCC(O)O ULWHHBHJGPPBCO-UHFFFAOYSA-N 0.000 abstract 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 description 15
- 238000004140 cleaning Methods 0.000 description 7
- 230000002209 hydrophobic effect Effects 0.000 description 6
- 230000002528 anti-freeze Effects 0.000 description 3
- 239000012528 membrane Substances 0.000 description 3
- 238000013329 compounding Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 241001062009 Indigofera Species 0.000 description 1
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 1
- 206010039203 Road traffic accident Diseases 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000033228 biological regulation Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 230000001804 emulsifying effect Effects 0.000 description 1
- IDGUHHHQCWSQLU-UHFFFAOYSA-N ethanol;hydrate Chemical compound O.CCO IDGUHHHQCWSQLU-UHFFFAOYSA-N 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 230000008014 freezing Effects 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 230000005764 inhibitory process Effects 0.000 description 1
- 239000006210 lotion Substances 0.000 description 1
- 239000000693 micelle Substances 0.000 description 1
- VLAPMBHFAWRUQP-UHFFFAOYSA-L molybdic acid Chemical compound O[Mo](O)(=O)=O VLAPMBHFAWRUQP-UHFFFAOYSA-L 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 230000010355 oscillation Effects 0.000 description 1
- FGIUAXJPYTZDNR-UHFFFAOYSA-N potassium nitrate Chemical compound [K+].[O-][N+]([O-])=O FGIUAXJPYTZDNR-UHFFFAOYSA-N 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
- C11D1/721—End blocked ethers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/825—Mixtures of compounds all of which are non-ionic
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/042—Acids
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/046—Salts
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/046—Salts
- C11D3/048—Nitrates or nitrites
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2006—Monohydric alcohols
- C11D3/201—Monohydric alcohols linear
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2079—Monocarboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/28—Heterocyclic compounds containing nitrogen in the ring
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/40—Dyes ; Pigments
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Detergent Compositions (AREA)
Abstract
The invention relates to a water expelling type automobile windscreen cleaning agent and a preparation method, and belongs to the technical field of cleaning agents. The cleaning agent is prepared from 0.01%-2% of a nonionic surfactant, 5%-12% of a water expelling agent, 0.1%-1% of auxiliaries, 0.1%-1% of corrosion inhibitors, 30%-60% of anti-freezing agents, 0-0.001% of dye and the balance water, wherein polyether and/or alcohol alkoxylate are/is adopted as the nonionic surfactant, methyl hydrogen polysiloxane emulsion is adopted as the water expelling agent, more than one of sulfuric acid, nitric acid, hydrochloric acid and phosphoric acid is adopted as the auxiliaries, more than one of benzotriazole, sodium benzoate, sodium benzoate, sodium nitrate and sodium gluconate is adopted as the corrosion inhibitors, more than one of methanol, ethanol, ethanediol, propanediol, butanediol and glycerol is adopted as the anti-freezing agents, and direct fast blue is adopted as the dye. The cleaning agent can easily and effectively remove stains on an automobile windscreen and is good in water expelling effect and anti-freezing performance, extremely low in corrosivity, high in using safety and capable of delaying windscreen wiper aging.
Description
Technical field
The present invention relates to a kind of expelling water type automobile window glass abluent and preparation method, specifically, relate to
A kind of automobile window glass abluent with expelling water function and preparation method thereof, belongs to abluent technical field.
Background technology
Along with development and the raising of people's living standard of auto industry, automobile has had been enter into huge numbers of families.Vapour
Car is the most no longer a kind of simple walking-replacing tool, and it is more like a member in family, to its kinsfolk
Bring the impact of many impacts, especially secure context.For driver, automobile window glass
Perspective rate and fineness directly affect drive safety and comfortableness.Therefore, it is equipped with a to love car
The automobile window glass abluent of excellent performance is particularly important.
It is known that the rainy day is no more than the interference to driver's sight line to maximum effect that driver brings, especially
It is when raining heavily, and the effect of wiper is had a greatly reduced quality, and it is hidden that this brings safety greatly for safe driving
Suffer from.At present, most automobile window glass abluents that market is sold only have cleaning, antifreeze function, and
The automobile window glass abluent the most also with expelling water function is very the fewest.Although also there being specialty on market
Glass drives aqua product, but using method is complex, and this fast pace life being present brings inconvenience,
It is unsatisfactory that it promotes situation.
Therefore, the appearance of a kind of automobile window glass abluent integrating cleaning, antifreeze and expelling water, become
Needs for market.
Summary of the invention
An object of the present invention there are provided a kind of expelling water type automobile window glass abluent, described glass
Abluent can not only remove the spot on automobile window glass easily, effectively, and has good expelling water
Effect, delay the features such as wiper is aging.
The two of the purpose of the present invention there are provided the preparation side of a kind of expelling water type automobile window glass abluent
Method.
It is an object of the invention to be achieved through the following technical solutions.
A kind of expelling water type automobile window glass abluent, with the oeverall quality of described glass cleaner raw material be
100% meter, wherein, each composition component and mass percent thereof are as follows:
Wherein, nonionic surfactant is polyethers and/or isomeric alcohol polyethenoxy ether, and preferred, polyethers is polyethers
F68, preferably isomeric alcohol polyethenoxy ether are isomerous tridecanol polyoxyethylene ether 1303.Described non-ionic surface is lived
Property agent all has stronger cleaning to general spot, and its critical micelle concentration is relatively low, has under low concentration
Strong cleaning performance, can low concentration use；Foaminess is less, it is possible to reduce the bubble remained on glass after cleaning
Foam, reaches to make the effect that glass is the most transparent, reduce wiper number of oscillations.
Expelling water agent is containing hydrogen silicone oil emulsion, and described containing hydrogen silicone oil emulsion is that containing hydrogen silicone oil prepares after emulsifying, main
Wanting composition is containing hydrogen silicone oil and emulsifying agent.Described expelling water agent can be hydrophobic automobile window glass surface formation one layer
Film, raindrop water droplet cannot adhere in hydrophobic membrane, under certain gradient with speed, rainwater Automatic-falling,
Leave no trace.Containing hydrogen silicone oil has excellent hydrophobicity, can form waterproof layer at a lot of material surfaces.But also
Its hydrophobicity just so that it is be difficult to be dispersed in water, limits its use in some aspects；And contain
Hydrogen silicone oil emulsion not there is problems in that, it is highly soluble in cold water, and nontoxic has no irritating odor.
The Si--H bond of containing hydrogen silicone oil hydroxyl with glass surface under the effect of auxiliary agent reacts so that containing hydrogen silicone oil
-CH3Towards outside, thus form one layer of netted hydrophobic membrane.
Auxiliary agent is more than one in sulphuric acid, nitric acid, hydrochloric acid and phosphoric acid, preferably sulphuric acid or nitric acid.Described
Auxiliary agent provides a micro-acid environment for described expelling water agent, prevents its network structure to lose efficacy.
Corrosion inhibiter is the one in BTA, sodium benzoate, sodium molybdate, sodium nitrate and sodium gluconate
Above, preferably BTA and sodium molybdate.Described corrosion inhibiter is the institutes such as steel, ferrum, aluminum, copper to material
State the automobile component that glass cleaner is likely to be exposed and play corrosion inhibition.
Antifreezing agent is more than one in methanol, ethanol, ethylene glycol, propylene glycol, butanediol and glycerol,
It is preferably dehydrated alcohol.Described antifreezing agent can significantly reduce the freezing point of described glass cleaner, plays antifreeze
Effect.
Dyestuff is direct fast blue.
The preparation method of a kind of expelling water type automobile window glass abluent of the present invention, described method is compounding
Method, mixes nonionic surfactant, expelling water agent, auxiliary agent, corrosion inhibiter, antifreezing agent, dyestuff and water,
It is stirred until homogeneous under room temperature.
Beneficial effect
1. the invention provides a kind of expelling water type automobile window glass abluent, described glass cleaner can easily,
Dispose the spot on automobile window glass rapidly；
2 the invention provides a kind of expelling water type automobile window glass abluent, glass cleaning described in life-time service
Agent can make the hydrophobic effect of glass be greatly enhanced, and makes rainwater Automatic-falling, driver is greatly improved in the rainy day
Boisterous traffic safety, effectively reduces the generation of Traffic Accidents；Even if in the winter time, falling hydrophobic
Accumulated snow on film can not be solid on glass, can be easy to remove, extend the life-span of wiper；It addition,
Dust is not easy to accumulate in glass surface, but floats in hydrophobic membrane, along with rainwater together landing；
3. the invention provides a kind of expelling water type automobile window glass abluent, described glass cleaner has pole
Good resistance to frost, it is adaptable to the winter of northern area；
4. the invention provides a kind of expelling water type automobile window glass abluent, described glass cleaner has pole
Low corrosivity, safe to use.
5. the invention provides the preparation method of a kind of expelling water type automobile window glass abluent, the letter of described method
Easy operation, can prepare a kind of expelling water type automobile window glass abluent of the present invention.
Detailed description of the invention
Below by specific embodiment, the present invention will be further described.
Containing hydrogen silicone oil emulsion described in following example is purchased from Laiyang Sheng Bang organosilicon Science and Technology Ltd., type
Number it is 2021；
Sulphuric acid be commercial available quality concentration be the concentrated sulphuric acid of 98%；Nitric acid be commercial available quality concentration be the dense nitre of 69%
Acid；Hydrochloric acid be commercial available quality concentration be the hydrochloric acid of 36%～38%.
Embodiment 1
A kind of expelling water type automobile window glass abluent, with the oeverall quality of described glass cleaner raw material be
100% meter, wherein, each composition component and mass percent thereof are as follows: polyethers F68 0.01%, containing hydrogen silicone oil
Emulsion 5%, sulphuric acid 0.2%, BTA 0.02%, sodium benzoate 0.1%, dehydrated alcohol 30%, directly
Connecing sun-proof indigo plant 0.001%, surplus is water.
The preparation method of expelling water type automobile window glass abluent described in a kind of the present embodiment, described method is multiple
Method of completing the square, by polyethers F68, containing hydrogen silicone oil emulsion, sulphuric acid, BTA, sodium benzoate, dehydrated alcohol,
Direct fast blue and water mixing, be stirred until homogeneous transparent under room temperature.
Embodiment 2
A kind of expelling water type automobile window glass abluent, with the oeverall quality of described glass cleaner raw material be
100% meter, wherein, each composition component and mass percent thereof are as follows: isomerous tridecanol polyoxyethylene ether 1303
0.1%, containing hydrogen silicone oil emulsion 10%, nitric acid 0.5%, BTA 0.02%, sodium molybdate 0.08%, nothing
Water-ethanol 50%, direct fast blue 0.001%, surplus is water.
The preparation method of expelling water type automobile window glass abluent described in a kind of the present embodiment, described method is multiple
Method of completing the square, by isomerous tridecanol polyoxyethylene ether 1303, containing hydrogen silicone oil emulsion, nitric acid, BTA,
Sodium molybdate, dehydrated alcohol, direct fast blue and water mixing, be stirred until homogeneous transparent under room temperature.
Embodiment 3
A kind of expelling water type automobile window glass abluent, with the oeverall quality of described glass cleaner raw material be
100% meter, wherein, each composition component and mass percent thereof are as follows: polyethers F68 1.5%, isomerous tridecanol
Polyoxyethylene ether 1,303 0.5%, containing hydrogen silicone oil emulsion 12%, hydrochloric acid 1%, sodium molybdate 0.6%, sodium nitrate 0.4%,
Dehydrated alcohol 60%, direct fast blue 0%, surplus is water.
The preparation method of a kind of expelling water type automobile window glass abluent of the present invention, described method is compounding
Method, by polyethers F68, isomerous tridecanol polyoxyethylene ether 1303, containing hydrogen silicone oil emulsion, hydrochloric acid, molybdic acid
Sodium, sodium nitrate, dehydrated alcohol and water mixing, be stirred until homogeneous transparent under room temperature.
Expelling water effect test
(1) automobile wind is used in test by the expelling water type automobile window glass abluent using embodiment 1～3 to prepare
Glass pane thoroughly cleans；
(2) general-utility car windscreen abluent of the prior art is used, to test automobile window glass
Thoroughly clean, be in terms of 100% by the raw material of described general-utility car windscreen abluent, each composition component
And mass percent is as follows: NPE NP-10 0.1%, methanol 25%, triethanolamine
0.5%, water surplus, i.e. can get described general-utility car windscreen by described each composition component mix homogeneously clear
Lotion；
(3) in the rainy day of moderate rain or heavy rain, regulation speed is not less than 40km/h, observes embodiment 1～3 and prepares
The cleaning corresponding with general-utility car windscreen abluent of expelling water type automobile window glass abluent after automobile
Windscreen expelling water effect；Described effect is as follows:
1. use the automobile of the prepared cleaned windscreen of windscreen abluent of embodiment 1～3 in the rain
During traveling, raindrop can move to roof direction, and the impact of driver's sight line is reduced by rainwater.As coordinated windscreen wiper
Device uses, the most better；
2. using the automobile of the common cleaned windscreen of windscreen abluent when travelling in the rain, raindrop are complete
Entirely it is attached on windscreen, has a strong impact on driver's sight line.Even if use wiper, when rainfall is bigger,
The sight line of driver also can be caused significantly impact by rainwater.
As can be seen here, the expelling water effect of the expelling water type automobile window glass abluent that the present invention provides is significantly better than
General-utility car windscreen abluent.
Claims (7)
1. an expelling water type automobile window glass abluent, it is characterised in that: with described glass cleaner raw material
Oeverall quality be 100% meter, each composition component and mass percent thereof are as follows:
Nonionic surfactant is polyethers and/or isomeric alcohol polyethenoxy ether；
Expelling water agent is containing hydrogen silicone oil emulsion；
Auxiliary agent is more than one in sulphuric acid, nitric acid, hydrochloric acid and phosphoric acid；
Corrosion inhibiter is the one in BTA, sodium benzoate, sodium molybdate, sodium nitrate and sodium gluconate
Above；
Antifreezing agent is more than one in methanol, ethanol, ethylene glycol, propylene glycol, butanediol and glycerol；
Dyestuff is direct fast blue.
A kind of expelling water type automobile window glass abluent the most according to claim 1, it is characterised in that:
Polyethers is polyethers F68, and isomeric alcohol polyethenoxy ether is isomerous tridecanol polyoxyethylene ether 1303.
A kind of expelling water type automobile window glass abluent the most according to claim 1, it is characterised in that:
Auxiliary agent is sulphuric acid or nitric acid.
A kind of expelling water type automobile window glass abluent the most according to claim 1, it is characterised in that:
Corrosion inhibiter is BTA and sodium molybdate.
A kind of expelling water type automobile window glass abluent the most according to claim 1, it is characterised in that:
Antifreezing agent is dehydrated alcohol.
A kind of expelling water type automobile window glass abluent the most according to claim 1, it is characterised in that:
Polyethers is polyethers F68, and isomeric alcohol polyethenoxy ether is isomerous tridecanol polyoxyethylene ether 1303；Auxiliary agent is sulfur
Acid or nitric acid；Corrosion inhibiter is BTA and sodium molybdate；Antifreezing agent is dehydrated alcohol.
7. the preparation of the expelling water type automobile window glass abluent as described in any one of claim 1～6
Method, it is characterised in that: described method is as follows: by nonionic surfactant, expelling water agent, auxiliary agent, delay
Erosion agent, antifreezing agent, dyestuff and water mixing, be stirred until homogeneous under room temperature, obtain described expelling water type automobile air window
Glass cleaner.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610286406.XA CN105861170A (en) | 2016-05-03 | 2016-05-03 | Water expelling type automobile windscreen cleaning agent and preparation method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610286406.XA CN105861170A (en) | 2016-05-03 | 2016-05-03 | Water expelling type automobile windscreen cleaning agent and preparation method |
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| CN105861170A true CN105861170A (en) | 2016-08-17 |
Family
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| Application Number | Title | Priority Date | Filing Date |
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| CN201610286406.XA Pending CN105861170A (en) | 2016-05-03 | 2016-05-03 | Water expelling type automobile windscreen cleaning agent and preparation method |
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| CN108441331A (en) * | 2018-04-18 | 2018-08-24 | 鹤山市金润纳新型材料有限公司 | A kind of automobile glass cleaning agent and preparation method thereof |
| CN111073761A (en) * | 2019-10-14 | 2020-04-28 | 山东药品食品职业学院 | Environment-friendly fog-removing glass water and preparation method thereof |
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| CN107057870A (en) * | 2017-06-09 | 2017-08-18 | 江苏耀兴安全玻璃有限公司 | A kind of expelling water type windscreen cleaning liquid and preparation method thereof |
| CN108441331A (en) * | 2018-04-18 | 2018-08-24 | 鹤山市金润纳新型材料有限公司 | A kind of automobile glass cleaning agent and preparation method thereof |
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Application publication date: 20160817 |