CN105789334B - A kind of Schottky barrier semiconductor rectifier and its manufacturing method - Google Patents
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- H10D8/605—Schottky-barrier diodes of the trench conductor-insulator-semiconductor barrier type, e.g. trench MOS barrier Schottky rectifiers [TMBS]
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Abstract
本发明公开了一种肖特基势垒半导体整流器,包括肖特基势垒金属层、外延层及第一沟槽,第一沟槽内设有隔离层及二氧化硅栅氧层,二氧化硅栅氧层向上延伸形成介质墙壁,介质墙壁两侧设有导电多晶硅侧墙,外延层上部与导电多晶硅侧墙之间设有第二沟槽,外延层上部设有横向均匀掺杂区和梯度掺杂区,梯度掺杂区与二氧化硅栅氧层之间设有沟道,外延层下部、横向均匀掺杂区、梯度掺杂区及二氧化硅栅氧层之间设有间隔区,第二沟槽中设有第三沟槽,肖特基势垒金属层位于第三沟槽内侧表面与外延层接触形成肖特基势垒。本发明正向导通特性与器件可靠性好。本发明还公开了一种肖特基势垒半导体整流器制造方法,工艺窗口大,易于控制,光刻次数少,制造成本低。
The invention discloses a Schottky barrier semiconductor rectifier, which comprises a Schottky barrier metal layer, an epitaxial layer and a first groove, and an isolation layer and a silicon dioxide gate oxide layer are arranged in the first groove, and the silicon dioxide The silicon gate oxide layer extends upwards to form a dielectric wall. Conductive polysilicon sidewalls are provided on both sides of the dielectric wall. A second trench is provided between the upper part of the epitaxial layer and the conductive polysilicon sidewall. The upper part of the epitaxial layer is provided with a horizontal uniform doping area and a gradient In the doping region, a channel is provided between the gradient doping region and the silicon dioxide gate oxide layer, and a spacer is provided between the lower part of the epitaxial layer, the lateral uniform doping region, the gradient doping region and the silicon dioxide gate oxide layer, A third groove is arranged in the second groove, and the Schottky barrier metal layer is located on the inner surface of the third groove and contacts the epitaxial layer to form a Schottky barrier. The invention has good forward conduction characteristics and device reliability. The invention also discloses a manufacturing method of the Schottky barrier semiconductor rectifier, which has a large process window, is easy to control, has less photolithography times and low manufacturing cost.
Description
技术领域technical field
本发明涉及半导体器件制造技术领域,尤其是涉及一种肖特基势垒半导体整流器及其制造方法。The invention relates to the technical field of semiconductor device manufacturing, in particular to a Schottky barrier semiconductor rectifier and a manufacturing method thereof.
背景技术Background technique
半导体整流器作为电能的转换器件,出于系统效率提高的考虑,在降低正向导通压降、提高反向阻断电压、减小反向漏电、提高开关速度等性能提升上的要求越来越高。As a conversion device of electric energy, semiconductor rectifiers have higher and higher requirements for performance improvement such as reducing forward voltage drop, increasing reverse blocking voltage, reducing reverse leakage, and increasing switching speed for the sake of improving system efficiency. .
早先作为半导体整流器使用的PN结二极管,由于正向导通时需要克服PN结势垒导致正向导通压降高,以及正向导通时的少子注入导致开关速度慢,已经在很多应用领域被肖特基势垒二极管取代。肖特基势垒二极管通常由低掺杂浓度的N型外延层与顶面沉积的金属层接触形成肖特基势垒构成。器件正向导通时用于克服肖特基势垒所需要的电压低于PN结势垒,并且肖特基势垒二极管为多子导电器件,开关速度快。即便如此,由于肖特基势垒的存在,很小的正向导通电流也会产生一定的正向导通压降。通过选用不同的金属可以降低势垒高度从而减小该正向导通压降,但是反向漏电会随之增大,反向阻断电压也可能降低。同时,肖特基势垒二极管还存在势垒高度降低效应,即随着反向偏置电压升高势垒高度降低的现象,该现象会进一步增大反向漏电、降低反向阻断电压并降低器件可靠性,从而限制了低势垒高度在器件中的应用。为克服上述问题,美国专利 US 5365102 披露了一种沟槽肖特基势垒二极管,其显著特点是在N型外延层中存在若干周期排布的沟槽栅,而N型外延层与顶面沉积的金属层形成的肖特基势垒存在于沟槽栅之间。所述沟槽栅由延伸入N型外延层中的沟槽,覆盖在沟槽表面的隔离层,以及填充其中的与顶面沉积的金属层连接的导电材料组成。周期排布的沟槽栅结构降低了器件反向偏置时肖特基势垒处的电场强度,部分抑制了势垒高度降低效应,使器件可以采用较低的势垒高度。但是肖特基势垒依然存在,并且沟槽栅结构占用了可导电表面积,使得器件小电流下正向导通压降偏大的问题依然存在。The PN junction diode used as a semiconductor rectifier earlier, due to the need to overcome the PN junction barrier during forward conduction, resulting in high forward conduction voltage drop, and the low switching speed caused by minority carrier injection during forward conduction, has been adopted by SCHOTT in many application fields. base barrier diodes instead. Schottky barrier diodes are usually composed of an N-type epitaxial layer with a low doping concentration and a metal layer deposited on the top surface to form a Schottky barrier. The voltage required to overcome the Schottky barrier is lower than the PN junction barrier when the device is forward-conducting, and the Schottky barrier diode is a multi-subconductive device with fast switching speed. Even so, due to the existence of the Schottky barrier, a small forward conduction current will also produce a certain forward conduction voltage drop. By selecting different metals, the barrier height can be reduced to reduce the forward conduction voltage drop, but the reverse leakage will increase accordingly, and the reverse blocking voltage may also decrease. At the same time, the Schottky barrier diode also has the effect of reducing the barrier height, that is, the phenomenon that the barrier height decreases with the increase of the reverse bias voltage, which will further increase the reverse leakage, reduce the reverse blocking voltage and Reduce device reliability, thereby limiting the application of low barrier height in devices. In order to overcome the above problems, US Patent No. 5,365,102 discloses a trench Schottky barrier diode, which is characterized in that there are several periodically arranged trench gates in the N-type epitaxial layer, and the N-type epitaxial layer and the top surface A Schottky barrier formed by the deposited metal layer exists between the trench gates. The trench gate is composed of a trench extending into the N-type epitaxial layer, an isolation layer covering the surface of the trench, and a conductive material filled therein and connected to a metal layer deposited on the top surface. The periodically arranged trench gate structure reduces the electric field intensity at the Schottky barrier when the device is reverse-biased, partially suppresses the effect of reducing the barrier height, and enables the device to adopt a lower barrier height. However, the Schottky barrier still exists, and the trench gate structure occupies the conductive surface area, so that the problem of large forward conduction voltage drop under low current of the device still exists.
美国专利 US 5818084 披露了一种不采用肖特基势垒的半导体整流器,该器件的阳极由沟槽MOSFET器件的栅极、源极、以及体电极短接构成,阴极由沟槽MOSFET器件的漏极构成。该技术的显著特点是采用沟槽栅结构,沟道垂直于半导体晶圆表面,利用MOSFET器件体效应降低开启阈值电压,使器件阳极加正电,即正向偏置时,形成导电沟道所需的电压低于PN结二极管正向开启电压。同时,因为该整流器正向导电通道为MOSFET器件沟道,所以正向导通过程无少子注入现象。将该整流器集成于沟槽MOSFET芯片内,可避免MOSFET寄生的PN结体二极管开启,从而进一步避免寄生二极管从正向导通到反向关闭切换时引入的大反向恢复电流和高反向恢复电压尖峰的问题。然而,基于该技术的器件作为独立的半导体整流器,正向导通压降大于肖特基势垒二极管。美国专利 US 6420225 披露了一种基于平面MOSFET的半导体整流器,即器件阳极由平面MOSFET器件的栅极、源极和体电极短接构成,阴极由漏极构成。该器件通过各向异性刻蚀形成介质侧墙,利用侧墙保护下方的离子注入区域形成沟道。美国专利 US 6448160 披露了一种基于平面MOSFET的半导体整流器,该器件通过氧等离子体各向同性刻蚀的方法部分剥离光刻胶,通过离子注入在光刻胶剥离掉的区域下方形成沟道。美国专利 US 6765264 披露了一种基于平面MOSFET的半导体整流器,该器件通过各向同性刻蚀的方法,使介质掩膜的侧壁由垂直硅晶圆表面变成具有一定坡度,透过该坡度侧壁进行离子注入,形成沟道,沟道掺杂浓度具有梯度。这些技术的显著特点是采用平面栅结构,沟道平行于半导体晶圆表面,沟道长度短。由于采用了短沟道并沟道掺杂梯度分布,形成导电沟道的阈值电压显著降低,从而降低了器件的正向导通压降,特别是小电流下的正向导通压降显著低于肖特基势垒二极管。然而,由于形成短沟道及沟道掺杂梯度分布的方法限制,这类器件通常基于平面栅结构,器件内部寄生有体掺杂区域构成的结型场效应管,寄生结型场效应管增大了导电通道上的串联电阻,同时限制导电沟道密度的提高;为了避免器件反向偏置时短沟道可能带来的穿通漏电,外延层掺杂浓度也通常较低,进一步增大了导电通道上的串联电阻;上述两点使器件大电流下的正向导通压降较高,通常高于沟槽肖特基势垒二极管。U.S. Patent US 5818084 discloses a semiconductor rectifier without Schottky barrier. The anode of the device is formed by shorting the gate, source, and body electrodes of the trench MOSFET device, and the cathode is formed by the drain of the trench MOSFET device. pole pose. The salient feature of this technology is the use of a trench gate structure, the channel is perpendicular to the surface of the semiconductor wafer, and the body effect of the MOSFET device is used to reduce the turn-on threshold voltage, so that the anode of the device is positively charged, that is, when it is forward biased, a conductive channel is formed. The required voltage is lower than the forward turn-on voltage of the PN junction diode. At the same time, because the forward conduction channel of the rectifier is the channel of the MOSFET device, there is no minority carrier injection phenomenon in the forward conduction process. The rectifier is integrated in the trench MOSFET chip, which can prevent the parasitic PN junction diode of the MOSFET from turning on, thereby further avoiding the large reverse recovery current and high reverse recovery voltage introduced when the parasitic diode switches from forward conduction to reverse conduction Spike question. However, devices based on this technology act as stand-alone semiconductor rectifiers with a forward voltage drop greater than that of a Schottky barrier diode. US Patent No. 6,420,225 discloses a semiconductor rectifier based on a planar MOSFET, that is, the anode of the device is formed by shorting the gate, source and body electrodes of the planar MOSFET device, and the cathode is formed by the drain. The device forms a dielectric side wall by anisotropic etching, and uses the side wall to protect the ion implantation region below to form a channel. US Patent No. 6,448,160 discloses a semiconductor rectifier based on a planar MOSFET. The photoresist is partially stripped by an oxygen plasma isotropic etching method, and a channel is formed under the stripped area of the photoresist by ion implantation. US Patent US 6765264 discloses a semiconductor rectifier based on a planar MOSFET. The device uses isotropic etching to change the sidewall of the dielectric mask from vertical to the surface of the silicon wafer to have a certain slope. Through the slope side The wall is implanted with ions to form a channel, and the doping concentration of the channel has a gradient. The salient feature of these technologies is the use of a planar gate structure, the channel is parallel to the surface of the semiconductor wafer, and the channel length is short. Due to the short channel and channel doping gradient distribution, the threshold voltage of the conductive channel is significantly reduced, thereby reducing the forward conduction voltage drop of the device, especially the forward conduction voltage drop under small current is significantly lower than Xiao Tertyl barrier diode. However, due to the limitations of the methods for forming short channels and channel doping gradient distribution, such devices are usually based on a planar gate structure, and there are junction field effect transistors formed by parasitic body doping regions inside the device, and the parasitic junction field effect transistors increase The series resistance on the conductive channel is increased, and at the same time, the increase of the conductive channel density is limited; in order to avoid the possible punch-through leakage caused by the short channel when the device is reverse biased, the doping concentration of the epitaxial layer is usually low, which further increases the Series resistance on the conduction channel; the above two points make the forward conduction voltage drop of the device high under high current, usually higher than that of trench Schottky barrier diode.
由此可见,现有技术在半导体整流器正向导通压降上还有欠缺,进一步改善器件结构和制造方法具有重要意义。It can be seen that the prior art still lacks in the forward conduction voltage drop of the semiconductor rectifier, and it is of great significance to further improve the device structure and manufacturing method.
发明内容Contents of the invention
本发明是为了解决现有技术的半导体整流器所存在的上述问题,提供了一种基于沟槽栅结构、同时具有短沟道和肖特基势垒接触,具有更佳的正向导通特性,尤其是更佳的大电流下正向导通压降表现和更好器件可靠性的肖特基势垒半导体整流器。The present invention is to solve the above-mentioned problems existing in the semiconductor rectifier in the prior art, and provides a trench gate structure based on a short channel and a Schottky barrier contact, which has better forward conduction characteristics, especially It is a Schottky barrier semiconductor rectifier with better forward voltage drop performance under high current and better device reliability.
本发明还提供了一种肖特基势垒半导体整流器制造方法,该制造方法工艺窗口大,易于控制,制造步骤少,制造成本低,实现了基于沟槽栅结构的短沟道并沟道掺杂梯度分布,能有效提高器件的正向导通性能。The present invention also provides a method for manufacturing a Schottky barrier semiconductor rectifier. The manufacturing method has a large process window, is easy to control, has few manufacturing steps, and has low manufacturing cost. The impurity gradient distribution can effectively improve the forward conduction performance of the device.
为了实现上述目的,本发明采用以下技术方案:In order to achieve the above object, the present invention adopts the following technical solutions:
本发明的一种肖特基势垒半导体整流器,自上而下包括阳极金属层、肖特基势垒金属层、第一导电类型轻掺杂的外延层、第一导电类型重掺杂的单晶硅衬底及阴极金属层,所述外延层上部横向间隔设置有若干第一沟槽,所述第一沟槽内填充有导电多晶硅,所述导电多晶硅与第一沟槽之间设有隔离层,所述隔离层上设有二氧化硅栅氧层,所述二氧化硅栅氧层厚度小于隔离层,二氧化硅栅氧层顶部向上延伸并高于外延层顶面形成介质墙壁,所述介质墙壁的两侧设有第一导电类型的导电多晶硅侧墙,外延层上部与介质墙壁外侧的导电多晶硅侧墙之间的区域形成第二沟槽,位于介质墙壁外侧的导电多晶硅侧墙底部设有高出于第二沟槽底部的第一导电类型重掺杂区,所述外延层上部设有将第二沟槽、第一导电类型重掺杂区和外延层隔开的第二导电类型非均匀掺杂区,所述第二导电类型非均匀掺杂区包括横向均匀掺杂区和梯度掺杂区,所述梯度掺杂区位于横向均匀掺杂区两侧的上部与二氧化硅栅氧层接触形成沟道,所述外延层下部、横向均匀掺杂区、梯度掺杂区及二氧化硅栅氧层之间设有间隔区,所述横向均匀掺杂区在纵向具有掺杂梯度分布,所述第二沟槽中设有第三沟槽,所述第三沟槽穿透第二导电类型非均匀掺杂区并延伸入外延层,所述肖特基势垒金属层覆盖于第三沟槽内侧,并与外延层接触形成肖特基势垒。A Schottky barrier semiconductor rectifier of the present invention comprises an anode metal layer, a Schottky barrier metal layer, a lightly doped epitaxial layer of the first conductivity type, and a monolayer heavily doped of the first conductivity type from top to bottom. A crystalline silicon substrate and a cathode metal layer, the upper part of the epitaxial layer is laterally provided with a plurality of first grooves at intervals, the first grooves are filled with conductive polysilicon, and isolation is provided between the conductive polysilicon and the first grooves Layer, the isolation layer is provided with a silicon dioxide gate oxide layer, the thickness of the silicon dioxide gate oxide layer is smaller than the isolation layer, the top of the silicon dioxide gate oxide layer extends upward and is higher than the top surface of the epitaxial layer to form a dielectric wall, so Conductive polysilicon sidewalls of the first conductivity type are provided on both sides of the dielectric wall, the area between the upper part of the epitaxial layer and the conductive polysilicon sidewall outside the dielectric wall forms a second groove, and the bottom of the conductive polysilicon sidewall located outside the dielectric wall A heavily doped region of the first conductivity type is provided higher than the bottom of the second trench, and a second conductive region separating the second trench, the heavily doped region of the first conductivity type and the epitaxial layer is provided on the upper part of the epitaxial layer. Type non-uniformly doped region, the second conductivity type non-uniformly doped region includes a lateral uniformly doped region and a gradient doped region, and the gradiently doped region is located on both sides of the lateral uniformly doped region and the silicon dioxide The gate oxide layer is contacted to form a channel, and a spacer is provided between the lower part of the epitaxial layer, the horizontal uniformly doped region, the gradient doped region and the silicon dioxide gate oxide layer, and the horizontal uniformly doped region has doped in the longitudinal direction. Gradient distribution, the second groove is provided with a third groove, the third groove penetrates the non-uniformly doped region of the second conductivity type and extends into the epitaxial layer, and the Schottky barrier metal layer covers Inside the third trench and in contact with the epitaxial layer to form a Schottky barrier.
一种肖特基势垒半导体整流器制造方法,包括以下步骤:A method for manufacturing a Schottky barrier semiconductor rectifier, comprising the following steps:
(一)在第一导电类型的重掺杂单晶硅衬底上生长第一导电类型轻掺杂的外延层。(1) Growing a lightly doped epitaxial layer of the first conductivity type on a heavily doped single crystal silicon substrate of the first conductivity type.
(二)采用光刻和干法刻蚀在外延层中形成第一沟槽。(2) Forming a first trench in the epitaxial layer by photolithography and dry etching.
(三)在整个结构顶层生长二氧化硅层作为隔离层。(3) A silicon dioxide layer is grown on the top layer of the entire structure as an isolation layer.
(四)在整个结构表面沉积氮化硅层作为掩膜层。(4) A silicon nitride layer is deposited on the entire surface of the structure as a mask layer.
(五)在整个结构表面沉积二氧化硅填充层使第一沟槽被填满。(5) Depositing a silicon dioxide filling layer on the entire surface of the structure to fill the first trench.
(六)采用湿法腐蚀选择性去除部分二氧化硅填充层,曝露出第一沟槽上部。(6) Selectively removing part of the silicon dioxide filling layer by wet etching to expose the upper part of the first trench.
(七)采用湿法腐蚀选择性去除未被二氧化硅填充层保护的掩膜层。(7) Selectively remove the mask layer not protected by the silicon dioxide filling layer by wet etching.
(八)采用湿法腐蚀选择性去除未被掩膜层保护的隔离层以及剩余的二氧化硅填充层。(8) Wet etching is used to selectively remove the isolation layer not protected by the mask layer and the remaining silicon dioxide filling layer.
(九)采用湿法腐蚀去除剩余的掩膜层。(9) Wet etching is used to remove the remaining mask layer.
(十)在整个结构顶层生长二氧化硅栅氧层。(10) A silicon dioxide gate oxide layer is grown on the top layer of the entire structure.
(十一)在整个结构顶层沉积导电多晶硅,使导电多晶硅填充满第一沟槽。(11) Depositing conductive polysilicon on the top layer of the entire structure, so that the conductive polysilicon fills the first trench.
(十二)采用干法刻蚀选择性去除部分导电多晶硅,使导电多晶硅顶面与外延层顶面齐平。(12) Selectively remove part of the conductive polysilicon by dry etching, so that the top surface of the conductive polysilicon is flush with the top surface of the epitaxial layer.
(十三)采用干法刻蚀选择性去除部分二氧化硅栅氧层,使第一沟槽两侧的外延层的顶部曝露出来。(13) Part of the silicon dioxide gate oxide layer is selectively removed by dry etching, so that the tops of the epitaxial layer on both sides of the first trench are exposed.
(十四)采用干法刻蚀选择性去除部分导电多晶硅和外延层,使二氧化硅栅氧层高出外延层顶面形成介质墙壁。(14) Selectively remove part of the conductive polysilicon and the epitaxial layer by dry etching, so that the silicon dioxide gate oxide layer is higher than the top surface of the epitaxial layer to form a dielectric wall.
(十五)在整个结构顶层沉积第一导电类型导电多晶硅。(15) Depositing polysilicon of the first conductivity type on the top layer of the entire structure.
(十六)采用热处理使第一导电类型导电多晶硅中的杂质扩散入外延层顶部,形成第一导电类型重掺杂区。(16) Heat treatment is used to diffuse impurities in the polysilicon of the first conductivity type into the top of the epitaxial layer to form a heavily doped region of the first conductivity type.
(十七)采用干法刻蚀去除部分第一导电类型导电多晶硅和外延层,在介质墙壁的两侧形成第一导电类型的导电多晶硅侧墙,无侧墙阻挡的外延层中形成第二沟槽,且第二沟槽的深度大于第一导电类型重掺杂区厚度。(17) Use dry etching to remove part of the conductive polysilicon of the first conductivity type and the epitaxial layer, form the conductive polysilicon sidewalls of the first conductivity type on both sides of the dielectric wall, and form the second trench in the epitaxial layer without sidewall barriers groove, and the depth of the second groove is greater than the thickness of the heavily doped region of the first conductivity type.
(十八)采用第一次离子注入在第二沟槽下方的外延层中引入第二导电类型的第一横向均匀分布杂质区,在第一导电类型重掺杂区下方引入第二导电类型的第一梯度分布杂质区。(18) Using the first ion implantation to introduce the first laterally evenly distributed impurity region of the second conductivity type into the epitaxial layer below the second trench, and introduce the impurity region of the second conductivity type under the heavily doped region of the first conductivity type The first gradient distribution impurity region.
(十九)采用第二次离子注入在第二沟槽下方的外延层中引入第二导电类型的第二横向均匀分布杂质区,在第一导电类型重掺杂区下方引入第二导电类型的第二梯度分布杂质区。(19) Use the second ion implantation to introduce a second laterally evenly distributed impurity region of the second conductivity type into the epitaxial layer below the second trench, and introduce a second conductivity type impurity region under the heavily doped region of the first conductivity type. The second gradient distribution impurity region.
(二十)采用第三次离子注入在第二沟槽下方的外延层中引入第二导电类型的第三横向均匀分布杂质区。(20) Using the third ion implantation to introduce a third lateral uniformly distributed impurity region of the second conductivity type into the epitaxial layer below the second trench.
(二十一)采用热处理激活注入的杂质,第一横向均匀分布杂质区、第二横向均匀分布杂质区、第三横向均匀分布杂质区构成横向均匀掺杂区,第一梯度分布杂质区、第二梯度分布杂质区构成梯度掺杂区,横向均匀掺杂区与梯度掺杂区构成第二导电类型非均匀掺杂区,以分隔开第一导电类型重掺杂区、第二沟槽和外延层下部。(21) The implanted impurities are activated by heat treatment. The first uniformly distributed impurity region, the second uniformly distributed impurity region, and the third uniformly distributed impurity region form a uniformly doped lateral region. The first gradiently distributed impurity region, the second The two gradiently distributed impurity regions constitute a gradient doping region, and the lateral uniform doping region and the gradient doping region constitute a second conductivity type non-uniform doping region to separate the first conductivity type heavily doped region, the second trench and the The lower part of the epitaxial layer.
(二十二)采用光刻和干法刻蚀在第二沟槽中部形成第三沟槽,通过刻蚀时间控制,使第三沟槽深度超过第二导电类型非均匀掺杂区底部。(22) The third trench is formed in the middle of the second trench by photolithography and dry etching, and the depth of the third trench exceeds the bottom of the non-uniformly doped region of the second conductivity type by controlling the etching time.
(二十三)在整个结构顶面沉积肖特基势垒金属层。(23) Depositing a Schottky barrier metal layer on the top surface of the entire structure.
(二十四)在整个结构顶面沉积阳极金属层。(24) Deposit an anodic metal layer on the top surface of the entire structure.
(二十五)对第一导电类型重掺杂的单晶硅衬底减薄后,在底面沉积阴极金属层,即得沟槽栅结构半导体整流器。(25) After thinning the heavily doped single crystal silicon substrate of the first conductivity type, a cathode metal layer is deposited on the bottom surface to obtain a semiconductor rectifier with trench gate structure.
作为优选,步骤(二十)中第三次离子注入采用的注入能量低于步骤(十九)中第二次离子注入采用的注入能量。Preferably, the implantation energy used for the third ion implantation in step (20) is lower than the implantation energy used for the second ion implantation in step (19).
因此,本发明具有如下有益效果:Therefore, the present invention has following beneficial effect:
(1)采用沟槽栅结构,消除了寄生结型场效应管,减少了导电通道上的串联电阻,可以降低器件正向导通压降;(1) The trench gate structure is adopted to eliminate the parasitic junction field effect transistor, reduce the series resistance on the conductive channel, and reduce the forward voltage drop of the device;
(2)采用沟槽栅结构,易于提高导电沟道密度,可以降低器件正向导通压降;(2) Using trench gate structure, it is easy to increase the density of conductive channels and reduce the forward conduction voltage drop of the device;
(3)延伸入外延层中的相邻的沟槽栅,可以在器件反向偏置时形成夹断以保护沟道,降低沟道处电场强度,抑制短沟道穿通漏电,使得外延层可以采用更高的掺杂浓度,从而降低器件正向导通压降;(3) The adjacent trench gate extending into the epitaxial layer can form a pinch-off when the device is reverse biased to protect the channel, reduce the electric field intensity at the channel, and suppress short-channel punch-through leakage, so that the epitaxial layer can Higher doping concentration is used to reduce the forward conduction voltage drop of the device;
(4)沟槽栅采用厚隔离层与薄栅氧层结合的结构,较厚的隔离层利于分担更多反向偏置电压,降低沟道处电场强度,抑制短沟道穿通漏电;较薄的栅氧层可以有效降低阈值电压;(4) The trench gate adopts a structure combining a thick isolation layer and a thin gate oxide layer. A thicker isolation layer is conducive to sharing more reverse bias voltage, reducing the electric field intensity at the channel, and suppressing short-channel punch-through leakage; thinner The gate oxide layer can effectively reduce the threshold voltage;
(5)器件中设置的间隔区,可以在器件反向偏置时形成夹断以保护沟道,进一步抑制短沟道穿通漏电,使得外延层可以采用更高的掺杂浓度,从而降低器件正向导通压降;(5) The spacer region set in the device can form a pinch-off to protect the channel when the device is reverse biased, and further suppress the short-channel punch-through leakage, so that the epitaxial layer can use a higher doping concentration, thereby reducing the positive current of the device. conduction pressure drop;
(6)沟道长度短且掺杂浓度可梯度调制,有效降低阈值电压,从而降低器件正向导通压降,同时可以抑制器件反向偏置时可能发生的短沟道穿通漏电;(6) The channel length is short and the doping concentration can be adjusted in gradients, which can effectively reduce the threshold voltage, thereby reducing the forward conduction voltage drop of the device, and at the same time can suppress the short-channel punch-through leakage that may occur when the device is reverse-biased;
(7)沟道长度和沟道掺杂浓度可通过侧墙形貌调制,也可通过离子注入的能量、剂量、注入次数调制,易于实现短沟道;(7) The channel length and channel doping concentration can be modulated by the sidewall morphology, and can also be modulated by the energy, dose, and implantation times of ion implantation, which is easy to realize short channels;
(8)重掺杂区由导电多晶硅与外延层接触并热扩散实现,重掺杂区杂质浓度分布均匀,对沟道长度影响小,易于实现短沟道;(8) The heavily doped region is realized by contacting the conductive polysilicon with the epitaxial layer and thermally diffusing. The impurity concentration in the heavily doped region is evenly distributed, which has little effect on the channel length and is easy to realize a short channel;
(9)二氧化硅栅氧层延伸出外延层表面形成介质墙壁,不会因工艺过程损失等因素影响沟道长度,易于实现短沟道;(9) The silicon dioxide gate oxide layer extends out of the surface of the epitaxial layer to form a dielectric wall, which will not affect the channel length due to process loss and other factors, and is easy to realize a short channel;
(10)间隔区宽度可以通过侧墙形貌调制,间隔区深度可以通过第二沟槽深度和离子注入的能量、注入次数调制,易形成夹断;(10) The width of the spacer can be modulated by the shape of the sidewall, and the depth of the spacer can be modulated by the depth of the second trench, the energy of ion implantation, and the number of implants, which is easy to form pinch-off;
(11)引入肖特基势垒区域,随着器件正向偏置电压升高,肖特基势垒区域参与导电,可以降低大电流下器件正向导通压降,或者在器件处于长时间大电流正向导通条件下,随着结温升高肖特基势垒开始正向导通,降低导电沟道的负担,提高器件可靠性;(11) Introducing the Schottky barrier region, as the forward bias voltage of the device increases, the Schottky barrier region participates in conduction, which can reduce the forward conduction voltage drop of the device under high current, or when the device is in a long time large Under the current forward conduction condition, as the junction temperature rises, the Schottky barrier begins to conduct forward conduction, reducing the burden on the conductive channel and improving device reliability;
(12)工艺流程采用自对准工艺,工艺窗口大,易于控制,整个流程光刻次数少,制造步骤少,制造流程短,制造成本低。(12) The process adopts a self-alignment process, which has a large process window and is easy to control. The number of photolithography in the whole process is small, the manufacturing steps are few, the manufacturing process is short, and the manufacturing cost is low.
附图说明Description of drawings
图1是本发明一种结构剖视图。Fig. 1 is a sectional view of a structure of the present invention.
图2 是实施例1步骤(六)的结构示意图。Fig. 2 is a schematic structural diagram of step (6) of embodiment 1.
图3是实施例1步骤(九)的结构示意图。Fig. 3 is a schematic structural diagram of step (nine) of embodiment 1.
图4是实施例1步骤(十二)的结构示意图。Fig. 4 is a schematic structural diagram of step (12) of embodiment 1.
图5是实施例1步骤(十六)的结构示意图。Fig. 5 is a schematic structural diagram of step (16) of embodiment 1.
图6是实施例1步骤(二十)的结构示意图。Fig. 6 is a schematic structural diagram of step (20) of embodiment 1.
图7是实施例1步骤(二十一)的结构示意图。Fig. 7 is a schematic structural diagram of step (21) of Embodiment 1.
图8是实施例1步骤(二十三)的结构示意图。Fig. 8 is a schematic structural diagram of step (twenty-three) of embodiment 1.
图中:阳极金属层1,外延层2,单晶硅衬底3,阴极金属层4,第一沟槽5,导电多晶硅6,隔离层7,介质墙壁8,导电多晶硅侧墙9,第二沟槽10,第一导电类型重掺杂区11,第二导电类型非均匀掺杂区12,横向均匀掺杂区13,梯度掺杂区14,沟道15,间隔区16,第一横向均匀分布杂质区17,第一梯度分布杂质区18,第二横向均匀分布杂质区19,第二梯度分布杂质区20,第三横向均匀分布杂质区21,掩膜层22,二氧化硅填充层23,二氧化硅栅氧层24,第三沟槽25,肖特基势垒金属层26,第一导电类型导电多晶硅27。In the figure: anode metal layer 1, epitaxial layer 2, monocrystalline silicon substrate 3, cathode metal layer 4, first trench 5, conductive polysilicon 6, isolation layer 7, dielectric wall 8, conductive polysilicon sidewall 9, second Trench 10, first conductivity type heavily doped region 11, second conductivity type non-uniform doping region 12, lateral uniform doping region 13, gradient doping region 14, channel 15, spacer region 16, first lateral uniform doping region Distribution impurity region 17, first gradient distribution impurity region 18, second lateral uniform distribution impurity region 19, second gradient distribution impurity region 20, third lateral uniform distribution impurity region 21, mask layer 22, silicon dioxide filling layer 23 , a silicon dioxide gate oxide layer 24 , a third trench 25 , a Schottky barrier metal layer 26 , and a conductive polysilicon 27 of the first conductivity type.
具体实施方式Detailed ways
下面结合附图和具体实施方式对本发明做进一步的描述。The present invention will be further described below in conjunction with the accompanying drawings and specific embodiments.
如图1所示的一种肖特基势垒半导体整流器,自上而下包括阳极金属层1、肖特基势垒金属层26、第一导电类型轻掺杂的外延层2、第一导电类型重掺杂的单晶硅衬底3及阴极金属层4,外延层上部横向间隔设置有若干第一沟槽5,第一沟槽内填充有导电多晶硅6,导电多晶硅与第一沟槽之间设有隔离层7,隔离层上设有二氧化硅栅氧层24,二氧化硅栅氧层厚度小于隔离层,二氧化硅栅氧层顶部向上延伸并高于外延层顶面形成介质墙壁8,介质墙壁的两侧设有第一导电类型的导电多晶硅侧墙9,外延层上部与介质墙壁外侧的导电多晶硅侧墙之间的区域形成第二沟槽10,位于介质墙壁外侧的导电多晶硅侧墙底部设有高出于第二沟槽底部的第一导电类型重掺杂区11,外延层上部设有将第二沟槽、第一导电类型重掺杂区和外延层隔开的第二导电类型非均匀掺杂区12,第二导电类型非均匀掺杂区包括横向均匀掺杂区13和梯度掺杂区14,梯度掺杂区位于横向均匀掺杂区两侧的上部与隔离层接触形成沟道15,外延层下部、横向均匀掺杂区、梯度掺杂区及隔离层之间设有间隔区16,横向均匀掺杂区在纵向具有掺杂梯度分布,第二沟槽中设有第三沟槽25,第三沟槽穿透第二导电类型非均匀掺杂区并延伸入外延层,肖特基势垒金属层覆盖于第三沟槽内侧,并与外延层接触形成肖特基势垒。A Schottky barrier semiconductor rectifier as shown in Figure 1, from top to bottom includes an anode metal layer 1, a Schottky barrier metal layer 26, a lightly doped epitaxial layer 2 of the first conductivity type, a first conductive A type of heavily doped single crystal silicon substrate 3 and a cathode metal layer 4, a plurality of first trenches 5 are arranged laterally at intervals on the upper part of the epitaxial layer, the first trenches are filled with conductive polysilicon 6, and the gap between the conductive polysilicon and the first trenches An isolation layer 7 is arranged between them, and a silicon dioxide gate oxide layer 24 is arranged on the isolation layer. The thickness of the silicon dioxide gate oxide layer is smaller than that of the isolation layer, and the top of the silicon dioxide gate oxide layer extends upward and is higher than the top surface of the epitaxial layer to form a dielectric wall. 8. Conductive polysilicon sidewalls 9 of the first conductivity type are provided on both sides of the dielectric wall, and the area between the upper part of the epitaxial layer and the conductive polysilicon sidewall outside the dielectric wall forms a second trench 10. The conductive polysilicon sidewall located outside the dielectric wall The bottom of the sidewall is provided with a first conductivity type heavily doped region 11 higher than the bottom of the second trench, and the upper part of the epitaxial layer is provided with a second trench, the first conductivity type heavily doped region and the epitaxial layer. Two conductive type non-uniformly doped regions 12, the second conductive type non-uniformly doped region includes a lateral uniformly doped region 13 and a gradient doped region 14, the gradient doped region is located on the upper part and the isolation layer on both sides of the lateral uniformly doped region A channel 15 is formed by contact, and a spacer 16 is provided between the lower part of the epitaxial layer, the lateral uniformly doped region, the gradient doped region, and the isolation layer, and the lateral uniformly doped region has a doping gradient distribution in the vertical direction. There is a third trench 25, the third trench penetrates the non-uniformly doped region of the second conductivity type and extends into the epitaxial layer, the Schottky barrier metal layer covers the inside of the third trench, and contacts the epitaxial layer to form a Schottky barrier metal layer. Teki barrier.
该肖特基势垒半导体整流器通过以下制造方法得到:The Schottky barrier semiconductor rectifier is obtained by the following manufacturing method:
(一)在第一导电类型的重掺杂单晶硅衬底3上生长第一导电类型轻掺杂的外延层2;(1) growing a lightly doped epitaxial layer 2 of the first conductivity type on the heavily doped single crystal silicon substrate 3 of the first conductivity type;
(二)采用光刻和干法刻蚀在外延层中形成第一沟槽5;(2) Forming the first trench 5 in the epitaxial layer by photolithography and dry etching;
(三)在整个结构顶层生长二氧化硅层作为隔离层7;(3) growing a silicon dioxide layer on the top layer of the entire structure as an isolation layer 7;
(四)在整个结构表面沉积氮化硅层作为掩膜层22;(4) Depositing a silicon nitride layer as a mask layer 22 on the entire surface of the structure;
(五)在整个结构表面沉积二氧化硅填充层23使第一沟槽被填满;(5) Depositing a silicon dioxide filling layer 23 on the entire surface of the structure to fill the first groove;
(六)采用湿法腐蚀选择性去除二氧化硅填充层,曝露出第一沟槽上部(见图2);(6) Selectively remove the silicon dioxide filling layer by wet etching, exposing the upper part of the first trench (see Figure 2);
(七)采用湿法腐蚀选择性去除未被二氧化硅填充层保护的掩膜层;(7) Using wet etching to selectively remove the mask layer not protected by the silicon dioxide filling layer;
(八)采用湿法腐蚀选择性去除未被掩膜层保护的隔离层以及剩余的二氧化硅填充层;(8) Using wet etching to selectively remove the isolation layer not protected by the mask layer and the remaining silicon dioxide filling layer;
(九)采用湿法腐蚀去除剩余的掩膜层(见图3);(9) Remove the remaining mask layer by wet etching (see Figure 3);
(十)在整个结构顶层生长二氧化硅栅氧层24;(10) growing a silicon dioxide gate oxide layer 24 on the top layer of the entire structure;
(十一)在整个结构顶层沉积导电多晶硅6,使导电多晶硅填充满第一沟槽;(11) Deposit conductive polysilicon 6 on the top layer of the entire structure, so that the conductive polysilicon fills the first trench;
(十二)采用干法刻蚀选择性去除部分导电多晶硅,使导电多晶硅顶面与外延层顶面齐平(见图4);(12) Selectively remove part of the conductive polysilicon by dry etching, so that the top surface of the conductive polysilicon is flush with the top surface of the epitaxial layer (see Figure 4);
(十三)采用干法刻蚀选择性去除部分二氧化硅栅氧层,使第一沟槽两侧的外延层的顶部曝露出来;(13) Selectively removing part of the silicon dioxide gate oxide layer by dry etching, so that the tops of the epitaxial layers on both sides of the first trench are exposed;
(十四)采用干法刻蚀选择性去除部分导电多晶硅和外延层,使二氧化硅栅氧层高出外延层顶面形成介质墙壁8;(14) Selectively remove part of the conductive polysilicon and epitaxial layer by dry etching, so that the silicon dioxide gate oxide layer is higher than the top surface of the epitaxial layer to form a dielectric wall 8;
(十五)在整个结构顶层沉积第一导电类型导电多晶硅27;(15) Depositing the first conductive type conductive polysilicon 27 on the top layer of the entire structure;
(十六)采用热处理使第一导电类型导电多晶硅中的杂质扩散入外延层顶部,形成第一导电类型重掺杂区11(见图5);(16) Heat treatment is used to diffuse the impurities in the conductive polysilicon of the first conductivity type into the top of the epitaxial layer to form the heavily doped region 11 of the first conductivity type (see FIG. 5 );
(十七)采用干法刻蚀去除部分第一导电类型导电多晶硅和外延层,在介质墙壁的两侧形成第一导电类型的导电多晶硅侧墙9,无侧墙阻挡的外延层中形成第二沟槽10,且第二沟槽的深度大于第一导电类型重掺杂区厚度;(17) Use dry etching to remove part of the conductive polysilicon of the first conductivity type and the epitaxial layer, form the conductive polysilicon sidewall 9 of the first conductivity type on both sides of the dielectric wall, and form the second conductive polysilicon sidewall 9 in the epitaxial layer without sidewall barriers. A trench 10, and the depth of the second trench is greater than the thickness of the heavily doped region of the first conductivity type;
十八)采用第一次离子注入在第二沟槽下方的外延层中引入第二导电类型的第一横向均匀分布杂质区17,在第一导电类型重掺杂区下方引入第二导电类型的第一梯度分布杂质区18;18) Use the first ion implantation to introduce the first lateral uniformly distributed impurity region 17 of the second conductivity type into the epitaxial layer below the second trench, and introduce the second conductivity type under the heavily doped region of the first conductivity type The first gradient distribution impurity region 18;
(十九)采用第二次离子注入在第二沟槽下方的外延层中引入第二导电类型的第二横向均匀分布杂质区19,在第一导电类型重掺杂区下方引入第二导电类型的第二梯度分布杂质区20;(19) Use the second ion implantation to introduce a second laterally evenly distributed impurity region 19 of the second conductivity type into the epitaxial layer below the second trench, and introduce the second conductivity type under the heavily doped region of the first conductivity type The second gradient distribution impurity region 20;
(二十)采用第三次离子注入在第二沟槽下方的外延层中引入第二导电类型的第三横向均匀分布杂质区21,第三次离子注入采用的注入能量低于第二次离子注入采用的注入能量(见图6);(20) The third ion implantation is used to introduce the third laterally evenly distributed impurity region 21 of the second conductivity type into the epitaxial layer below the second trench, and the implantation energy used for the third ion implantation is lower than that of the second ion implantation The injection energy used for the injection (see Figure 6);
(二十一)采用热处理激活注入的杂质,第一横向均匀分布杂质区、第二横向均匀分布杂质区、第三横向均匀分布杂质区构成横向均匀掺杂区13,第一梯度分布杂质区、第二梯度分布杂质区构成梯度掺杂区14,横向均匀掺杂区与梯度掺杂区构成第二导电类型非均匀掺杂区12,以分隔开第一导电类型重掺杂区、第二沟槽和外延层下部(见图7);(21) Heat treatment is used to activate the implanted impurities. The first uniformly distributed impurity region, the second uniformly distributed impurity region, and the third uniformly distributed impurity region form a uniformly doped lateral region 13. The first gradiently distributed impurity region, The second gradient distribution impurity region constitutes the gradient doping region 14, and the lateral uniform doping region and the gradient doping region constitute the second conductivity type non-uniform doping region 12 to separate the first conductivity type heavily doped region, the second The trench and the lower part of the epitaxial layer (see Figure 7);
(二十二)采用光刻和干法刻蚀在第二沟槽中部形成第三沟槽25,通过刻蚀时间控制,使第三沟槽深度超过第二导电类型非均匀掺杂区底部;(22) Forming the third trench 25 in the middle of the second trench by photolithography and dry etching, and controlling the etching time so that the depth of the third trench exceeds the bottom of the non-uniformly doped region of the second conductivity type;
(二十三)在整个结构顶面沉积肖特基势垒金属层26(见图8);(23) Depositing a Schottky barrier metal layer 26 on the top surface of the entire structure (see FIG. 8 );
(二十四)在整个结构顶面沉积阳极金属层1;(24) Depositing an anode metal layer 1 on the top surface of the entire structure;
(二十五)对第一导电类型重掺杂的单晶硅衬底减薄后,在底面沉积阴极金属层4,即得沟槽栅结构半导体整流器(见图1)。(25) After thinning the heavily doped single crystal silicon substrate of the first conductivity type, a cathode metal layer 4 is deposited on the bottom surface to obtain a semiconductor rectifier with a trench gate structure (see Figure 1).
以上所述的实施例只是本发明的一种较佳的方案,并非对本发明作任何形式上的限制,在不超出权利要求所记载的技术方案的前提下还有其它的变体及改型。The embodiment described above is only a preferred solution of the present invention, and does not limit the present invention in any form. There are other variations and modifications on the premise of not exceeding the technical solution described in the claims.
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| CN114864695A (en) * | 2022-04-11 | 2022-08-05 | 无锡锡产微芯半导体有限公司 | Super-barrier rectifier |
| CN114512402A (en) * | 2022-04-19 | 2022-05-17 | 深圳芯能半导体技术有限公司 | A trench type silicon carbide Schottky diode and method of making the same |
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