CN105632899A - Device patterning preparation method in vacuum environment - Google Patents
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Abstract
Description
技术领域technical field
本发明涉及微纳米器件制备工艺技术领域,尤其涉及在真空环境中器件图形化制备方法。The invention relates to the technical field of micro-nano device preparation technology, in particular to a device pattern preparation method in a vacuum environment.
背景技术Background technique
在微纳米尺度器件的研究中,各类异质材料接触界面结构、状态和性质越来越吸引人们的目光,成为纳米器件领域的关注焦点和热点,特别是金属与材料的接触直接关系到载流子的电学输运性能,对器件整体性能起到了至关重要影响作用。In the research of micro-nano-scale devices, the structure, state and properties of various heterogeneous material contact interfaces are attracting more and more people's attention, and become the focus and hot spot in the field of nano-devices, especially the contact between metals and materials is directly related to load-carrying. The electrical transport performance of the current plays a crucial role in the overall performance of the device.
纳米器件中精细微电极的加工和电极间的绝缘层的制备,不仅仅只是获得尺寸微细的金属电极的导电连通和绝缘保护,更加关注的是制备出重复性好、稳定可靠性高、性能优异的器件,因而对加工工艺有着极为苛刻的要求。The processing of fine micro-electrodes and the preparation of insulating layers between electrodes in nano-devices are not only to obtain the conductive connection and insulation protection of fine-sized metal electrodes, but also to prepare the products with good repeatability, high stability and reliability, and excellent performance. devices, which have extremely stringent requirements on the processing technology.
传统的光刻工艺制备图形化器件不仅工艺复杂,而且容易引入材料表面污染和结构损伤,造成材料的本征物理与化学性质的改变,在一定程度上影响了产品的性能和成品率。如何在不影响样品表面成分、结构能级和物性的原始状态情况下制备出图形化的高质量微电极和相应的绝缘保护层,成为提升研究创新性和突破核心技术的关键问题。The preparation of patterned devices by the traditional photolithography process is not only complicated, but also easily introduces material surface contamination and structural damage, resulting in changes in the intrinsic physical and chemical properties of the material, affecting the performance and yield of the product to a certain extent. How to prepare patterned high-quality microelectrodes and corresponding insulating protective layers without affecting the original state of the sample surface composition, structural energy level, and physical properties has become a key issue for improving research innovation and breaking through core technologies.
发明内容Contents of the invention
本发明提供真空环境中器件图形化制备方法,在真空环境中,利用物理气相沉积方式,与图形化系统互锁联动实现器件图形化制备,其发明内容如下:The invention provides a device pattern preparation method in a vacuum environment. In a vacuum environment, the physical vapor deposition method is used to interlock with the pattern system to realize the device pattern preparation. The content of the invention is as follows:
真空环境中器件图形化制备方法,其中,包括以下步骤:A device patterned preparation method in a vacuum environment, which includes the following steps:
(1)将衬底置于真空环境中;(1) placing the substrate in a vacuum environment;
(2)在所述衬底上设有用于制备器件图形的掩膜板;(2) A mask plate for preparing device patterns is provided on the substrate;
(3)所述掩膜板或所述衬底连接用于移动操作的移动平台;(3) The mask plate or the substrate is connected to a mobile platform for mobile operation;
(4)所述移动平台将掩膜板定位在衬底上;(4) The mobile platform positions the mask plate on the substrate;
(5)采用物理气相沉积方式在衬底上沉积器件所需薄膜材料。(5) The thin film material required for the device is deposited on the substrate by means of physical vapor deposition.
进一步地,步骤(5)中所述物理气相沉积方式为溅射、热蒸发、分子束外延、电子束蒸发、离子镀以及激光脉冲沉积中的一种。Further, the physical vapor deposition method in step (5) is one of sputtering, thermal evaporation, molecular beam epitaxy, electron beam evaporation, ion plating and laser pulse deposition.
进一步地,步骤(4)中所述移动平台连接计算机辅助控制系统,所述计算机辅助控制系统用于通过控制移动平台实现掩膜板在衬底上的定位。Further, the mobile platform in step (4) is connected to a computer-aided control system, and the computer-aided control system is used to realize the positioning of the mask plate on the substrate by controlling the mobile platform.
更进一步地,所述掩膜板的定位精度为小于50nm。Furthermore, the positioning accuracy of the mask is less than 50nm.
优选地,所述掩膜板呈平整状,掩膜板材料为硅片、玻璃片、石英片、金属片、陶瓷片和有机塑料片中的一种。Preferably, the mask is flat, and the material of the mask is one of silicon wafers, glass wafers, quartz wafers, metal wafers, ceramic wafers and organic plastic wafers.
优选地,步骤(5)中所述器件所需薄膜材料为金属或介质。Preferably, the thin film material required for the device in step (5) is metal or dielectric.
更优选地,金属材料为金、银、钛、铜、镍、钨、锌中的一种或多种的复合材料;绝缘介质材料为氮化硅、氧化硅、氧化铪、氧化铝中的一种或多种。More preferably, the metal material is a composite material of one or more of gold, silver, titanium, copper, nickel, tungsten, and zinc; the insulating dielectric material is one of silicon nitride, silicon oxide, hafnium oxide, and aluminum oxide. one or more species.
优选地,应用所述掩膜板制备出器件图形的最小特征尺寸在亚微米范围。Preferably, the minimum feature size of the device pattern prepared by using the mask plate is in the submicron range.
本发明还提供复杂器件图形化制备方法,其中采用以上方法制备器件图形,包括以下步骤:The present invention also provides a complex device pattern preparation method, wherein the device pattern is prepared by the above method, including the following steps:
(1)在衬底区域沉积形成第1类器件图形;(1) Depositing and forming a first-class device pattern in the substrate area;
(2)在衬底区域沉积形成第2类器件图形;(2) Depositing and forming a second type of device pattern in the substrate area;
……...
(n)在衬底区域沉积形成第n类器件图形;(n) Depositing and forming the nth type device pattern in the substrate area;
以上所述第1类、第2类、…、第n类器件图形之间组合、叠加形成复杂器件图形。Combination and superimposition of the device patterns of the first type, the second type, ..., the nth type mentioned above form a complex device pattern.
进一步地,所述第n类器件图形,n为大于1的自然数。Further, in the nth type of device pattern, n is a natural number greater than 1.
本发明的有益效果:Beneficial effects of the present invention:
(1)工艺简单,提高器件制备的性能。(1) The process is simple, and the performance of device preparation is improved.
本发明的真空环境中器件图形化制备方法,避免采用现有复杂的光刻工艺和技术,在真空环境下直接实现器件图形化的制备,保证了器件本征的物理与化学性质,不影响器件表面成分、结构能级和物性的原始状态,提高了器件制备的性能。The device patterned preparation method in a vacuum environment of the present invention avoids the use of existing complex photolithography processes and technologies, and directly realizes the device patterned preparation in a vacuum environment, ensuring the intrinsic physical and chemical properties of the device without affecting the device The original state of surface composition, structural energy level and physical properties improves the performance of device fabrication.
(2)避免器件表面污染和防止结构损伤。(2) Avoid device surface contamination and prevent structural damage.
在本发明的真空环境中器件图形化制备方法中,采用计算机辅助控制系统,在真空环境下实现对掩膜板的精确控制和移动,保证了器件在制备过程中的清洁性,从而免除使用现有技术中光刻工艺光敏材料的涂覆和去除所带来的器件表面污染和结构损伤的问题。In the device patterned preparation method in a vacuum environment of the present invention, a computer-aided control system is used to realize precise control and movement of the mask in a vacuum environment, ensuring the cleanliness of the device during the preparation process, thereby eliminating the need to use There are problems of device surface contamination and structural damage caused by the coating and removal of photosensitive materials in the photolithography process in the technology.
(3)制备复杂器件图形,提升器件功能。(3) Prepare complex device graphics to improve device functions.
在本发明的真空环境中器件图形化制备方法中,通过不断改变掩膜板上制备图案的形状、尺寸和衬底的相对位置,通过多次沉积,可实现复杂器件图形的制备,比如环形的图案、立体结构图案,器件的复杂程度越大,器件的功能越多。In the device pattern preparation method in a vacuum environment of the present invention, by continuously changing the shape, size and relative position of the substrate on the mask plate, through multiple depositions, the preparation of complex device patterns can be realized, such as annular Patterns, three-dimensional structure patterns, the greater the complexity of the device, the more functions the device has.
附图说明Description of drawings
图1为本发明实施例器件图形制备过程的示意图;其中,图1a为所述衬底示意图,图1b为掩膜板定位示意图,图1c为物理气相沉积示意图,图1d为器件图形制备完成示意图。Fig. 1 is a schematic diagram of the device pattern preparation process in an embodiment of the present invention; wherein Fig. 1a is a schematic diagram of the substrate, Fig. 1b is a schematic diagram of mask positioning, Fig. 1c is a schematic diagram of physical vapor deposition, and Fig. 1d is a schematic diagram of the completion of device pattern preparation .
图2为本发明实施例复杂器件图形制备过程的示意图;其中,图2a为复杂器件图形制备过程一示意图,图2b为复杂器件图形制备过程二示意图,图2c为复杂器件图形制备完成示意图。Fig. 2 is a schematic diagram of the complex device pattern preparation process according to an embodiment of the present invention; wherein Fig. 2a is a schematic diagram of the complex device pattern preparation process 1, Fig. 2b is a complex device pattern preparation process 2 schematic diagram, and Fig. 2 c is a complex device pattern preparation completed schematic diagram.
具体实施方式detailed description
为了更好地阐述本发明的技术特点和结构,以下结合本发明的优选实施例及其附图进行详细描述。In order to better illustrate the technical characteristics and structure of the present invention, the following is a detailed description in conjunction with preferred embodiments of the present invention and accompanying drawings.
实施例1Example 1
参阅图1a至图1d,本实施例提供的真空环境中器件图形化制备方法,包括以下步骤:Referring to Fig. 1a to Fig. 1d, the device pattern preparation method in a vacuum environment provided by this embodiment includes the following steps:
(1)将衬底110置于真空环境中,衬底110表面为用于制备器件图形122的区域;(1) The substrate 110 is placed in a vacuum environment, and the surface of the substrate 110 is an area for preparing the device pattern 122;
(2)在衬底110上设有用于制备器件图形122的掩膜板120,掩膜板120呈平整状,掩膜板120的材料为硅片、玻璃片、石英片、金属片、陶瓷片和有机塑料片中的一种。掩膜板120上还包括用于形成器件图形的制备图案121,所制备的器件图形122可以随制备图案121的改变而改变;(2) on the substrate 110, be provided with the mask plate 120 that is used to prepare device pattern 122, mask plate 120 is flat shape, and the material of mask plate 120 is silicon sheet, glass sheet, quartz sheet, metal sheet, ceramic sheet and one of organic plastic sheets. The mask plate 120 also includes a preparation pattern 121 for forming a device pattern, and the prepared device pattern 122 can be changed with the change of the preparation pattern 121;
(3)掩膜板120连接用于操作掩膜板120的移动平台(图未示),或衬底110连接用于操作衬底110的移动平台,使得掩膜板120与衬底110可相对移动,调节掩膜板与衬底的距离。该移动平台由本体、夹具、滑座、工作台、主轴、进给机构等结构组成的三维移动平台或多维移动平台。(3) The mask plate 120 is connected to a mobile platform (not shown) for operating the mask plate 120, or the substrate 110 is connected to a mobile platform for operating the substrate 110, so that the mask plate 120 and the substrate 110 can be relatively Move to adjust the distance between the mask plate and the substrate. The mobile platform is a three-dimensional mobile platform or a multi-dimensional mobile platform composed of a body, a fixture, a sliding seat, a worktable, a spindle, and a feed mechanism.
(4)移动平台连接计算机辅助控制系统(图未示),该计算机辅助控制系统包括输入模块、输出模块、多维坐标系等模块。计算机辅助控制系统通过控制移动平台实现掩膜板120的定位,将掩膜板120精确定位在衬底上,掩膜板120上的制备图案121与衬底110上指定的制备区域相对应,其中,掩膜板120的定位精度小于50nm。(4) The mobile platform is connected to a computer-aided control system (not shown in the figure), and the computer-aided control system includes modules such as an input module, an output module, and a multi-dimensional coordinate system. The computer-aided control system realizes the positioning of the mask plate 120 by controlling the mobile platform, and accurately positions the mask plate 120 on the substrate. The preparation pattern 121 on the mask plate 120 corresponds to the designated preparation area on the substrate 110, wherein , the positioning accuracy of the mask plate 120 is less than 50 nm.
(5)采用物理气相沉积方式在衬底110上沉积器件所需薄膜材料,其中,物理气相沉积方式为溅射、热蒸发、分子束外延、电子束蒸发、离子镀以及激光脉冲沉积中的一种;器件所需薄膜材料为金属或介质,金属材料为金、银、钛、铜、镍、钨、锌中的一种或多种的复合材料,介质材料为氮化硅、氧化硅、氧化铪、氧化铝中的一种或多种。(5) Deposit thin film materials required for the device on the substrate 110 by physical vapor deposition, wherein the physical vapor deposition is one of sputtering, thermal evaporation, molecular beam epitaxy, electron beam evaporation, ion plating, and laser pulse deposition The thin film material required for the device is metal or dielectric, the metal material is one or more composite materials of gold, silver, titanium, copper, nickel, tungsten, zinc, and the dielectric material is silicon nitride, silicon oxide, oxide One or more of hafnium and aluminum oxide.
实施例2Example 2
本实施例如实施例1中所述的制备方法,还提供复杂器件图形化制备方法,包括以下步骤:This embodiment, such as the preparation method described in Example 1, also provides a patterned preparation method for complex devices, including the following steps:
(1)在衬底区域沉积形成第1类器件图形;(1) Depositing and forming a first-class device pattern in the substrate area;
(2)在衬底区域沉积形成第2类器件图形;(2) Depositing and forming a second type of device pattern in the substrate area;
……...
(n)在衬底区域沉积形成第n类器件图形;(n) Depositing and forming the nth type device pattern in the substrate area;
以上第1类、第2类、…、第n类器件图形之间组合、叠加形成复杂器件图形,其中,n为大于1的自然数。Combination and superimposition of the above-mentioned device patterns of the first category, the second category, ..., the nth category form complex device graphics, wherein n is a natural number greater than 1.
参阅图2a至2c,本实施例在n等于3的情况下介绍复杂器件图形化制备方法的具体实施方式。通过精确移动和控制掩膜板,首先,在衬底110上制备出第1类器件图形123,其次,再制备出第2类器件图形124,最后,通过调整掩膜板上制备图案的大小、形状以及相对位置,可制备出第3类器件图形125,第3类器件图形125的两端分别叠加在第1类器件图形123和第2类器件图形124上,在衬底110上形成复杂器件图形。Referring to FIGS. 2 a to 2 c , this embodiment introduces a specific implementation of a method for patterning complex devices when n is equal to 3. By accurately moving and controlling the mask plate, firstly, the first type device pattern 123 is prepared on the substrate 110, and secondly, the second type device pattern 124 is prepared, and finally, by adjusting the size of the prepared pattern on the mask plate, shape and relative position, the third type of device pattern 125 can be prepared, and the two ends of the third type of device pattern 125 are respectively superimposed on the first type of device pattern 123 and the second type of device pattern 124, forming a complex device on the substrate 110 graphics.
需要说明的是,本实施例的附图均采用非常简化的形式且均使用非精准的比率,仅用于方便、明晰地辅助说明本发明实施例的目的。It should be noted that the drawings of this embodiment are all in a very simplified form and use imprecise ratios, which are only used for the purpose of conveniently and clearly assisting in describing the embodiment of the present invention.
本发明的上述实施例仅仅是为清楚地说明本发明所作的举例,而并非是对本发明的实施方式的限定。对于所属领域的普通技术人员来说,在上述说明的基础上还可以做出其他不同形式的变化或变动。这里无需也无法对所有的实施方式予以穷举。凡在本发明的精神和原则之内所作的任何修改、等同替换和改进等,均应包含在本发明权利要求的保护范围之内。The above-mentioned embodiments of the present invention are only examples for clearly illustrating the present invention, rather than limiting the implementation of the present invention. For those of ordinary skill in the art, other changes or changes in different forms can be made on the basis of the above description. It is not necessary and impossible to exhaustively list all the implementation manners here. All modifications, equivalent replacements and improvements made within the spirit and principles of the present invention shall be included within the protection scope of the claims of the present invention.
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