CN105358716A - Foundry equipment and method of controlling said equipment - Google Patents
Foundry equipment and method of controlling said equipment Download PDFInfo
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- CN105358716A CN105358716A CN201480035122.2A CN201480035122A CN105358716A CN 105358716 A CN105358716 A CN 105358716A CN 201480035122 A CN201480035122 A CN 201480035122A CN 105358716 A CN105358716 A CN 105358716A
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21B—MANUFACTURE OF IRON OR STEEL
- C21B3/00—General features in the manufacture of pig-iron
- C21B3/04—Recovery of by-products, e.g. slag
- C21B3/06—Treatment of liquid slag
- C21B3/08—Cooling slag
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21B—MANUFACTURE OF IRON OR STEEL
- C21B2400/00—Treatment of slags originating from iron or steel processes
- C21B2400/02—Physical or chemical treatment of slags
- C21B2400/03—Removing sulfur
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21B—MANUFACTURE OF IRON OR STEEL
- C21B2400/00—Treatment of slags originating from iron or steel processes
- C21B2400/05—Apparatus features
- C21B2400/06—Conveyors on which slag is cooled
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Abstract
Description
技术领域technical field
本发明大体上涉及对来自金属工业并且更特别地来自炼铁工业的炉渣(炉渣)进行粒化(granulation)。The present invention generally relates to the granulation of slag (slag) from the metal industry and more particularly from the iron industry.
背景技术Background technique
传统上,在水中对冶金炉渣进行粒化。Traditionally, metallurgical slags are granulated in water.
水淬确保冶金炉渣的快速固化,这是在高炉炉渣的情况下用于获得有价值产品的必要条件。首先用水射流将热液态炉渣流分裂(fragmentize)成非常小的颗粒,并将这些颗粒转移到水槽中。通过热液态炉渣与水之间的直接接触,汲取来自热炉渣的能量。由于这必须在环境压力下发生,所以炉渣的温度立即降至100℃以下的温度水平。Water quenching ensures rapid solidification of metallurgical slags, which is a necessary condition for obtaining valuable products in the case of blast furnace slags. The hot liquid slag stream is first fragmentized with a water jet into very small particles and these particles are transferred to a water tank. The energy from the hot slag is extracted by direct contact between the hot liquid slag and the water. Since this has to take place at ambient pressure, the temperature of the slag drops immediately to a temperature level below 100°C.
然而,水粒化工艺的主要缺点在于:包含在热液态炉渣中的硫与水反应,并生成二氧化硫(SO2)和硫化氢(H2S)。However, the main disadvantage of the water granulation process is that the sulfur contained in the hot liquid slag reacts with the water and generates sulfur dioxide (SO 2 ) and hydrogen sulfide (H 2 S).
此外,必须注意的是,必须小心地以足够快的速度将炉渣的温度降低足够的程度,以获得玻璃化或非晶态的炉渣而非获得(部分地)结晶炉渣,结晶炉渣在市场上不利地损失很多价格(约15倍)。Furthermore, it must be noted that care must be taken to reduce the temperature of the slag sufficiently fast enough to obtain a vitrified or amorphous slag rather than to obtain a (partially) crystalline slag, which is disadvantageous in the market Lose a lot of price (about 15 times).
可能还期望以可用形式从炉渣回收至少一些热量。为了以有效的方式利用此可能性,必需使炉渣迅速冷却到以下温度水平:该温度水平对于使材料的处理较容易而言是足够低的,但对于以可用水平保存能量而言是足够高的。It may also be desirable to recover at least some of the heat from the slag in a usable form. In order to exploit this possibility in an efficient manner, it is necessary to rapidly cool the slag to a temperature level that is low enough to make handling of the material easier, but high enough to conserve energy at usable levels .
克服生成有毒气体的缺点并回收至少一部分热量的一种可能性包括将液态炉渣与相同化学组成的冷炉渣颗粒混合。然后,炉渣可以在热交换器中经受热量回收。然而,已经发现,由于液态炉渣的高黏度,所以不易于将冷炉渣颗粒与液态炉渣混合,并因此不可能足够快地冷却液态炉渣以获得玻璃化炉渣。One possibility to overcome the disadvantage of generating toxic gases and recover at least part of the heat consists in mixing liquid slag with cold slag particles of the same chemical composition. The slag can then undergo heat recovery in a heat exchanger. However, it has been found that due to the high viscosity of the liquid slag it is not easy to mix the cold slag particles with the liquid slag and it is therefore not possible to cool the liquid slag fast enough to obtain vitrified slag.
已经提出了将(冷)固态金属颗粒添加到热液态炉渣中的另一方案(WO2012/034897,WO2012/080364)。其效果是,炉渣以玻璃状态迅速固化,而未产生有毒气体。此外,固态金属颗粒是化学惰性的并且可以容易地被分离、回收和再利用(参见WO2012/034897)。最后,来自固化的炉渣和金属颗粒二者的热量都可以回收到适当的装置(如,热交换器)中(参见WO2012/080364)。Another approach to adding (cold) solid metal particles to hot liquid slag has been proposed (WO2012/034897, WO2012/080364). As a result, the slag solidifies rapidly in a glassy state without producing toxic gases. Furthermore, solid metal particles are chemically inert and can be easily separated, recycled and reused (see WO2012/034897). Finally, the heat from both the solidified slag and the metal particles can be recovered into suitable means such as heat exchangers (see WO2012/080364).
然而,在实践中,上述解决方案的效率高度地取决于炉渣的适当浇注和金属颗粒的正确配量。所述效率甚至由于以下事实而恶化:除非预见到了技术上复杂或要求高能的附加设备(所述附加设备例如新填充的铸模中中的实际炉渣填充水平确定装置、加热的或耐火材料衬里的输送盛桶和/或等效物),否则液态炉渣的进入流通常不能被控制。在不具有这样的额外措施的情况下,对金属颗粒的任何合适的计量变得复杂并且甚至不稳定。In practice, however, the efficiency of the above solutions is highly dependent on proper pouring of the slag and correct dosing of the metal particles. Said efficiency is even worsened by the fact that unless technically complex or energy-demanding additional equipment (such as actual slag filling level determination devices in newly filled molds, conveying of heated or refractory linings) is foreseen ladles and/or equivalent), otherwise the inflow of liquid slag cannot normally be controlled. Any suitable metering of metal particles becomes complicated and even unstable without such additional measures.
技术问题technical problem
本发明的目的是提供一种用于干炉渣粒化的方法以及相应的装置,其允许从减小的环境影响和增加的能量回收潜能中获益,同时易于实现,并且使用起来既安全又有效。It is an object of the present invention to provide a method for dry slag granulation and a corresponding device which allow benefiting from reduced environmental impact and increased energy recovery potential while being easy to implement and safe and efficient to use .
发明内容Contents of the invention
为了实现此目的,本发明提出了一种用于使用铸造设备对热液态炉渣进行干炉渣粒化的方法,所述铸造设备包括具有多个铸造模具的循环输送机,所述循环输送机被设置成将第一区段中的所述铸造模具从炉渣浇注区通过冷却区移动至排出区并将第二区段中的所述铸造模具返回至所述炉渣浇注区,所述方法包括以下连续步骤:In order to achieve this object, the invention proposes a method for dry slag granulation of hot liquid slag using a casting plant comprising a circulating conveyor with a plurality of casting moulds, the circulating conveyor being arranged to move said casting molds in a first section from a slag pouring zone through a cooling zone to a discharge zone and return said casting molds in a second section to said slag pouring zone, said method comprising the following successive steps :
a)在所述炉渣浇注区中向位置N中的铸造模具浇注一定量的热液态炉渣,a) pouring a certain amount of hot liquid slag into the casting mold in position N in said slag pouring zone,
b)使容纳有所述热液态炉渣的铸造模具移动到所述冷却区内的位置N+n中,b) moving the casting mold containing said hot liquid slag into position N+n in said cooling zone,
c)通过将确定量的固态金属颗粒从分配装置投入到位置N+n中的容纳有所述热液态炉渣的所述铸造模具中,将所述固态金属颗粒添加到所述模具中,所述分配装置设置在所述模具上方并且包括用于存储所述固态金属颗粒的至少一个料斗,c) adding said solid metal particles to said casting mold containing said hot liquid slag in position N+n by dropping a defined amount of said solid metal particles into said mold from a dispensing device, said a dispensing device is arranged above said mold and comprises at least one hopper for storing said solid metal particles,
d)在所述排出区从所述模具中排出已冷却的固化炉渣,d) discharging cooled solidified slag from said mold at said discharge zone,
其中,在位置N和N+n之间的位置处测量步骤(a)中浇注到所述铸造模具中的热液态炉渣的实际量,其中n为1至10之间的数字,优选地在1至4之间,最优选地n为2,wherein the actual amount of hot liquid slag poured into said casting mold in step (a) is measured at a position between N and N+n, where n is a number between 1 and 10, preferably between 1 to 4, most preferably n is 2,
其中,基于测得的热液态炉渣的量调整步骤(b)中的移动速度V铸机,wherein the moving speed V of the casting machine in step (b) is adjusted on the basis of the measured amount of hot liquid slag,
其中,基于固定的炉渣/金属颗粒比λ确定步骤(c)所需的金属颗粒的量,wherein the amount of metal particles required for step (c) is determined based on a fixed slag/metal particle ratio λ,
其中,通过在基于所述速度V铸机确定的时间t期间打开设置在所述料斗的出口处的至少一个驱动滑动门,控制步骤(c)中由所述分配装置添加的金属颗粒的量,并且其中,基于所确定的金属颗粒的量、所确定的打开时间t和所述至少一个驱动滑动门的特性来确定所述至少一个驱动滑动门的开度x。wherein the amount of metal particles added by said distributing means in step (c) is controlled by opening at least one actuated sliding door provided at the outlet of said hopper during a time t determined on the basis of said speed V caster , And wherein, the opening x of the at least one actuated sliding door is determined based on the determined amount of metal particles, the determined opening time t and properties of the at least one actuated sliding door.
如已经提到的,在实践中面临困难的主要原因在于不仅要处理炉渣的不可控性,而且还要处理炉渣的可变流量,同时在炉渣和金属颗粒之间具有特定比率是重要的。As already mentioned, the main reason for the difficulties faced in practice is that not only the uncontrollability of the slag, but also the variable flow of the slag has to be dealt with, while it is important to have a certain ratio between the slag and the metal particles.
本方法的主要优点在于,通过在步骤(a)之后、步骤(c)之前简单地测量铸造模具内的热液态炉渣的量,可以控制整个过程。The main advantage of this method is that by simply measuring the amount of hot liquid slag inside the casting mold after step (a) and before step (c), the entire process can be controlled.
首先,该测量值用于控制模具中液态炉渣的量。事实上,看起来清楚的是,该循环输送机的模具应当被填充有适当(最大)量的炉渣,该量应当使得在铸造模具中留有足够的空间以用于按照固定的炉渣/金属颗粒比λ添加一定量的金属颗粒。因此,对热液态炉渣的量的测量允许通过调整输送机的速度来控制所述量,例如通过在该量低于预期(适当)量时使输送机的速度减缓,而在液态炉渣的量超出预期(适当)量时使输送机加速来进行控制所述量。如果液态炉渣的量近似为预期量,则不需要进行速度调整。First, this measurement is used to control the amount of liquid slag in the mould. In fact, it seems clear that the mold of the circulating conveyor should be filled with a suitable (maximum) amount of slag which leaves enough space in the casting mold for the fixed slag/metal particle Add a certain amount of metal particles than λ. Thus, the measurement of the amount of hot liquid slag allows controlling said amount by adjusting the speed of the conveyor, for example by slowing the speed of the conveyor when the amount is lower than the expected (appropriate) amount, and when the amount of liquid slag exceeds The amount is controlled by accelerating the conveyor when the (appropriate) amount is expected. If the amount of liquid slag is approximately the expected amount, no speed adjustment is required.
其次,上述对液态炉渣的量的测量用于针对该特定的铸造模具确定金属颗粒的实际需要量。Second, the above-mentioned measurement of the amount of liquid slag is used to determine the actual required amount of metal particles for that particular foundry mould.
在另一方面,本发明还提出了一种用于对热液态炉渣进行干炉渣粒化的设备,所述设备包括具有多个铸造模具的循环输送机,所述循环输送机被设置成将第一区段的所述铸造模具从炉渣浇注区通过冷却区移动至排出区并使第二区段中的所述铸造模具返回所述炉渣浇注区,并且其中,所述设备还包括:In another aspect, the invention also proposes an apparatus for dry slag granulation of hot liquid slag, said apparatus comprising a circulating conveyor with a plurality of casting moulds, said circulating conveyor being arranged to take the first Moving said casting molds in one section from a slag pouring zone through a cooling zone to a discharge zone and returning said casting molds in a second section to said slag pouring zone, and wherein said apparatus further comprises:
·分配装置,所述分配装置设置在所述冷却区中,位于位置N+n处的所述模具上方并且包括至少一个用于存储固态金属颗粒的料斗,所述分配装置包括位于所述料斗的出口处的至少一个滑动门,对所述滑动门的驱动允许控制由所述分配装置分配的金属颗粒的量,a distribution device arranged in the cooling zone above the mold at position N+n and comprising at least one hopper for storing solid metal particles, the distribution device comprising a at least one sliding door at the outlet, the actuation of which allows controlling the amount of metal particles dispensed by the dispensing device,
·至少一个传感器,所述传感器能够测量介于炉渣浇注位置N和金属颗粒添加位置N+n之间的位置中的铸造模具内所浇注的热液态炉渣的实际量,其中n为1至10之间的数字,优选地在1至4之间,At least one sensor capable of measuring the actual amount of poured hot liquid slag in the casting mold in a position between the slag pouring position N and the metal particle addition position N+n, where n is between 1 and 10 between numbers, preferably between 1 and 4,
·控制单元,其用以:基于所测量的热液态炉渣的量调整所述输送机的移动速度V铸机;基于固定的炉渣/金属颗粒比λ确定要由所述分配装置添加的金属颗粒的必需量;通过在基于所述速度V铸机确定的时间t期间打开设置在所述料斗的出口处的所述至少一个驱动滑动门,控制要由所述分配装置添加的金属颗粒的量;以及基于所确定的金属颗粒的量、所确定的打开时间t和所述至少一个滑动门的特性来确定所述至少一个驱动滑动门的开度x。A control unit to: adjust the moving speed of the conveyor V caster based on the measured amount of hot liquid slag; determine the amount of metal particles to be added by the distribution device based on a fixed slag/metal particle ratio λ necessary amount; controlling the amount of metal particles to be added by said distribution means by opening said at least one actuated sliding door provided at the outlet of said hopper during a time t determined on the basis of said speed V caster ; and The opening x of the at least one actuated sliding door is determined based on the determined amount of metal particles, the determined opening time t and properties of the at least one sliding door.
在本发明的上下文中,应当注意的是,在浇注区中和冷却区中对模具的输送优选地基本为线性,即在浇注区和冷却区中,一个或多个倾斜角基本不变。此外,在此上下文中,相对于炉渣浇注区中正被填充的模具的位置N所指示的位置仅是示例性的。事实上,在本文中由N+n指示的位置中的分配装置的实际位置可以位于并非为模具的长度l的倍数的距离d处,即,当位置N中的模具位于炉渣沟(slagrunner,出渣槽)下方时,不一定会发生向位置N+n中的模具内填充金属颗粒。因此,炉渣浇注区中正被填充的模具和分配装置之间的距离d可以是0.1l至9l之间的任何距离,优选地在0.5l至3l之间,特别地约1l(即n约为2)。在实践中,仅限制距离d的下限值,以允许测量浇注在铸造模具内的热液态炉渣的实际量。上限通常取决于以下事实:炉渣应当仍然处于充分的液态以允许金属颗粒适当渗入炉渣中。In the context of the present invention, it should be noted that the conveyance of the mold in the pouring zone and in the cooling zone is preferably substantially linear, ie the one or more inclination angles are substantially constant in the pouring zone and in the cooling zone. Furthermore, in this context the position indicated relative to the position N of the mold being filled in the slag pouring zone is merely exemplary. In fact, the actual position of the distribution device in the position indicated here by N+n may be located at a distance d which is not a multiple of the length l of the mold, i.e. when the mold in position N is located in a slagrunner (out of slag trough), the filling of metal particles into the mold in position N+n does not necessarily occur. Thus, the distance d between the mold being filled in the slag pouring zone and the distribution device may be any distance between 0.1 l and 9 l, preferably between 0.5 l and 3 l, in particular about 1 l (i.e. n is about 2 ). In practice, only the lower value of the distance d is limited to allow measurement of the actual amount of hot liquid slag poured in the casting mould. The upper limit generally depends on the fact that the slag should still be in a sufficiently liquid state to allow proper infiltration of metal particles into the slag.
在本发明的另一方面中,该方法或该设备还包括:在步骤(c)之后于位置N+n的下游位置中测量铸造模具中炉渣和金属颗粒的实际结合量,即炉渣/颗粒混合物的量(的装置);基于所测量的炉渣和金属颗粒的结合量以及先前确定的热液态炉渣的量来计算步骤(c)中金属颗粒的实际添加量;以及如果所计算的金属颗粒的实际添加量与先前确定的金属颗粒的量不符,则调整所述至少一个滑动门的特性。In another aspect of the invention, the method or the apparatus further comprises: measuring the actual combined amount of slag and metal particles in the casting mold, i.e. the slag/particle mixture, in a position downstream of position N+n after step (c) the amount (of means); based on the measured combined amount of slag and metal particles and the previously determined amount of hot liquid slag to calculate the actual amount of metal particles added in step (c); and if the calculated actual amount of metal particles If the added amount does not correspond to the previously determined amount of metal particles, the properties of the at least one sliding door are adjusted.
该进一步优选的实施方式的主要优点在于,其允许使用所产生炉渣/颗粒混合物的量的实际测量值作为反馈而通过作用于分配装置(特别地通过调节一个或多个滑动门)来调整(或校正)金属颗粒的量。The main advantage of this further preferred embodiment is that it allows adjustment (or Correction) the amount of metal particles.
有利地,所述至少一个滑动门的特性包括随所述开度x变化的颗粒的质量流量颗粒(颗粒/x曲线),其中,所述开度是滑动门在打开和关闭状态(或基本关闭状态,见下文)之间必须被移动的距离。事实上,此参数基本上根据滑动门的开度限定了每单位时间流经该滑动门的颗粒的量。该参数可以被表示为离散曲线,并且可以根据滑动门的特定类型和颗粒的特定类型(见下文的详细描述)通过实验确定。Advantageously, the characteristic of said at least one sliding door comprises the mass flow rate of particles ( particles /x curve) as a function of said opening x, wherein said opening is the sliding door in the open and closed state (or substantially closed state, see below) must be moved. In fact, this parameter basically defines the amount of particles that flow through the sliding door per unit of time, depending on the opening of the sliding door. This parameter can be represented as a discrete curve and can be determined experimentally depending on the particular type of sliding door and the particular type of particles (see detailed description below).
在又一实施方式中,在步骤(a)浇注到铸造模具中的热液态炉渣的实际量和/或步骤(c)后铸造模具中的炉渣和金属颗粒的实际结合量是通过下述方式测量的:分别确定所述模具中炉渣的高度h炉渣、炉渣/金属颗粒的高度h混合物;并且基于该铸造模具的已知形状计算相应的体积V炉渣和/或V混合物,以及确定炉渣的质量M炉渣和/或基于V混合物和V炉渣之间的差值确定金属颗粒的质量M颗粒'。In yet another embodiment, the actual amount of hot liquid slag poured into the casting mold after step (a) and/or the actual combined amount of slag and metal particles in the casting mold after step (c) is measured by of: determining the height h of slag in said mold, height h of slag , of slag/metal particle mixture , respectively; and calculating the corresponding volume V slag and/or V mixture based on the known shape of the foundry mould, and determining the mass M of slag slag and/or determine the mass Mparticle' of the metal particles based on the difference between Vmixture and Vslag .
优选地,通过下述方式实现量的测量:非接触式地,如通过一个或多个激光测距仪,测量铸造模具内的炉渣或炉渣/金属颗粒混合物的高度。也可以使用其他装置,例如雷达、声检测装置或光检测装置等。Preferably, the amount is measured by measuring the height of the slag or slag/metal particle mixture within the casting mold contactlessly, eg by means of one or more laser distance meters. Other devices, such as radar, acoustic or optical detection devices, etc. may also be used.
在本发明的又一方面中,输送机优选地为所谓的双斜率铸机,其中,还可以通过如下方式来控制所述模具中的液态炉渣的量:将所述循环输送机的第一区段中的所述炉渣浇注区设置为以第一倾斜角α输送所述铸造模具,所述第一倾斜角将所述模具在所述炉渣浇注区中的有效最大填充体积限定为值Vα,任何过量的炉渣都会倾泻返回至位置N-1、N-2等中的上游铸造模具,并且其中,所述冷却区被设置为具有第二倾斜角,该第二倾斜角β小于α,使得所述模具在所述冷却区中的有效最大填充体积具有的值Vβ大于Vα。In yet another aspect of the invention, the conveyor is preferably a so-called double-slope caster, wherein the amount of liquid slag in the mold can also be controlled by placing the first zone of the circulating conveyor The slag pouring zone in a section is arranged to convey the casting mold at a first inclination angle α which limits the effective maximum filling volume of the mold in the slag pouring zone to a value V α , Any excess slag will be poured back to the upstream casting mold in position N-1, N-2 etc., and wherein the cooling zone is arranged with a second inclination angle β less than α such that all The effective maximum filling volume of the mold in the cooling zone has a value V β greater than V α .
因此,包含此种双斜率输送机的实施方式的另一优点在于,循环输送机的模具被填充有限定量的炉渣。对于给定的模具,该炉渣的限定量取决于该模具在被填充时的倾斜角度:斜率越陡,则直到炉渣溢出或倾泻至紧邻的一个或多个模具(即,位于正被填充的模具上游的紧邻的一个或多个模具)为止能填充到模具中的炉渣越少。因此,在倾斜角α下,有效最大填充体积(即,有用体积)可以被定义为Vα。如果倾斜角减小(较不陡峭或甚至为水平的),则模具中的实际填充水平降低并且模具的有效最大填充体积(即,有用体积)增加至Vβ,由此向要在冷却区中添加的固态金属颗粒提供空间。因此,如果冷却区中的倾斜角β低于浇注区中的角度α,则可以向模具中添加相当于Vβ-Vα的理论最大量的金属颗粒,而不会有溢出或溅出的风险。Therefore, another advantage of an embodiment comprising such a double-slope conveyor is that the mold of the circulating conveyor is filled with a limited amount of slag. For a given mould, the limited amount of slag depends on the angle of inclination of the mold as it is being filled: the steeper the slope, the greater the amount of slag until the slag overflows or pours into the immediately adjacent mold or molds (i.e., at the mold being filled). the mold or molds immediately upstream) the less slag can be filled into the mold. Therefore, at an inclination angle α, the effective maximum filling volume (ie useful volume) can be defined as V α . If the inclination angle is reduced (less steep or even horizontal), the actual fill level in the mold is reduced and the effective maximum fill volume (i.e. useful volume) of the mold is increased to V β , thereby increasing the volume to be filled in the cooling zone. The added solid metal particles provide space. Therefore, if the inclination angle β in the cooling zone is lower than the angle α in the pouring zone, a theoretical maximum amount of metal particles corresponding to V β - V α can be added to the mold without risk of spillage or splashing .
在本发明的一个优选实施方式中,所述炉渣浇注区中的所述倾斜角α和所述冷却区中的所述倾斜角β被选择为使得:所述模具在所述炉渣浇注区中的有效最大填充体积Vα介于所述模具在所述冷却区中的有效最大填充体积Vβ的0.25倍至0.75倍之间,优选地介于0.30倍至0.60倍之间,甚至更优选地为0.45倍至0.55倍。特别地,倾斜角α和β被选择为使得Vα约为1/2Vβ。In a preferred embodiment of the present invention, the inclination angle α in the slag pouring zone and the inclination angle β in the cooling zone are selected such that: the mold in the slag pouring zone The effective maximum filling volume Vα is between 0.25 and 0.75 times the effective maximum filling volume Vβ of the mold in the cooling zone, preferably between 0.30 and 0.60 times, even more preferably between 0.45 times to 0.55 times. In particular, the inclination angles α and β are chosen such that V α is approximately 1/2V β .
虽然很大程度上取决于模具的几何形状,但在实践中适当的角度β通常介于0°(水平)至50°之间,更优选地介于10°至40°之间,而角度α通常比角度β大5°至20°。Although largely dependent on the geometry of the mold, in practice a suitable angle β is usually between 0° (horizontal) and 50°, more preferably between 10° and 40°, while the angle α Typically 5° to 20° greater than angle β.
在使用双斜率输送机的情况下,还可以通过下述方式来控制所述铸造模具的移动:监测正被填充的铸造模具的至少两个(或更多个)紧邻上游(位置N-1和N-2)的铸造模具的温度,以及改变步骤(b)中的移动速度。Where a dual-slope conveyor is used, the casting mold movement can also be controlled by monitoring at least two (or more) immediately upstream of the casting mold being filled (positions N-1 and N-2) the temperature of the casting mold, and changing the moving speed in step (b).
特别优选地,通过下述方式来控制该设备:如果位置N-1中的铸造模具的温度由于缺少来自位置N(浇注位置)的热液态炉渣的逆流而未显著增加,则降低步骤(b)中的移动速度,并且如果位置N-2中的铸造模具的温度由于来自位置N-1中的铸造模具的热液态炉渣的逆流而增加,则增加步骤(b)中的移动速度。因此,换言之,如果正被填充的模具的紧邻上游(N-1)的模具的温度没有增加到接近热液态炉渣的温度的值,即具有远低于此值的温度,没有炉渣向回倾泻,因此模具的填充至多是充足的,然而可能未完成:则使输送机减缓速度。另一方面,如果仅N-1中的模具是热的(容纳有液态炉渣)而N-2中的模具不是热的,则认为输送机的速度是适当的,不用改变速度。最后,如果不仅N-1中的模具变热,而且N-2中的模具也变热,则输送机的速度过低并且必须被增加。Particularly preferably, the device is controlled by reducing step (b) if the temperature of the casting mold in position N-1 does not increase significantly due to lack of counterflow of hot liquid slag from position N (pouring position) and if the temperature of the casting mold in position N-2 increases due to the reverse flow of hot liquid slag from the casting mold in position N-1, increase the moving speed in step (b). Thus, in other words, if the temperature of the mold immediately upstream (N-1) of the mold being filled does not increase to a value close to the temperature of the hot liquid slag, i.e. has a temperature well below this value, no slag pours back, The filling of the mold is therefore sufficient at best, but may not be complete: the conveyor is then slowed down. On the other hand, if only the molds in N-1 are hot (containing liquid slag) and the molds in N-2 are not, then the speed of the conveyor is considered appropriate and no speed change is required. Finally, if not only the molds in N-1 but also the molds in N-2 become hot, the speed of the conveyor is too low and must be increased.
对温度的监测可以通过任何适当的装置进行,例如用热电偶或类似装置进行;然而,优选地以非接触式方式(例如通过高温计)实现上述监测。Monitoring of the temperature may be carried out by any suitable means, for example with a thermocouple or similar; however, it is preferably accomplished in a non-contact manner, for example by a pyrometer.
与不可控和且可变化的炉渣流相关联的另一一般性问题在于,(确定量的)金属颗粒的添加必须在由炉渣流赋予的期限内完成。因此,所产生的困难是,在输送机需要不断地进一步移动模具的情况下,可用于将金属颗粒的所需添加量引进到部分填充的铸造模具中的时间是有限的。因此,本方法的重要优点在于,用于计量固态金属颗粒的量的滑动门的使用允许快速打开和关闭,从而极大地缩短了用以引入正确量的颗粒所需的时间。Another general problem associated with an uncontrollable and variable slag flow is that the addition of (determined amounts of) metal particles must be done within the deadlines imposed by the slag flow. Thus, the difficulty that arises is that the time available to introduce the required addition of metal particles into a partially filled casting mold is limited in the event that the conveyor needs to constantly move the mold further. Thus, an important advantage of the present method is that the use of a sliding door for metering the amount of solid metal particles allows rapid opening and closing, thereby greatly reducing the time required to introduce the correct amount of particles.
适当的滑动门(阀)通常包括滑动板,该滑动板设置成通过通常沿位于开口(在此情况下为料斗的出口)前方的滑动框推动和/或转动该滑动板而关闭该开口。能够以与模具的输送方向平行或优选地与该方向垂直的方式实现板的滑动。因此,在本发明的上下文中,滑动移动可以是平移(例如线性滑动门)、旋转(例如旋转式滑动门;旋转轴线优选地与由开口形成的平面平行或垂直于该平面)或甚至其组合(例如曲线滑动门)。因此本文所用的相关术语“开度”应当被理解为打开滑动门所需的滑动移动(推动和/或旋转)的幅度。A suitable sliding gate (valve) typically comprises a sliding plate arranged to close the opening (in this case the outlet of the hopper) by pushing and/or turning the sliding plate, usually along a sliding frame located in front of the opening. The sliding of the plates can be achieved parallel to or preferably perpendicular to the conveying direction of the mould. Thus, in the context of the present invention, the sliding movement may be translational (such as a linear sliding door), rotational (such as a revolving sliding door; the axis of rotation is preferably parallel to or perpendicular to the plane formed by the opening) or even a combination thereof (eg curved sliding doors). Therefore, the related term "opening degree" used herein should be understood as the magnitude of sliding movement (push and/or rotation) required to open the sliding door.
在滑动门的优选实施方式中,具有多个间隔开的孔的固定板被放置在开口(料斗的出口)的前方,并因此(仅)部分地阻挡该出口。相应的可移动滑动板呈现出相应的孔,这些孔可以被滑动到固定板的孔的前方以用于打开门,并且可以被滑动到不同的位置以用于关闭固定板的孔。优选地,对于线性滑动门而言这些孔具有大致矩形或方形的形状,或者对于具有垂直于开口的旋转轴线的旋转滑动门而言这些孔具有大致扇形的形状,并且滑动板中相邻孔之间的空间的尺寸被定为基本上关闭固定板的相应孔。多个孔的主要优点在于,滑动门的行程(即,在打开状态和关闭状态之间的滑动距离)显著减小,由于可用于实现该动作的时间是有限的,因而这是是有利的。In a preferred embodiment of the sliding door, a fixed plate with a plurality of spaced apart holes is placed in front of the opening (the outlet of the hopper) and thus (only) partially blocks this outlet. The respective movable sliding plates present corresponding holes which can be slid in front of the holes of the fixed plate for opening the door and which can be slid to different positions for closing the holes of the fixed plate. Preferably, the holes have a generally rectangular or square shape for a linear sliding door, or a generally fan-shaped shape for a rotary sliding door with an axis of rotation perpendicular to the opening, and between adjacent holes in the sliding plate The space between is sized to substantially close the corresponding aperture of the fixing plate. The main advantage of multiple holes is that the travel of the sliding door (ie the sliding distance between the open and closed states) is significantly reduced, which is advantageous since the time available to achieve this action is limited.
在另一优选的方面中,该滑动门包括两行或更多行的多个孔。在这样的情况下,甚至更优选地是使相邻行的孔以交错(锯齿形)方式设置,以进一步提高颗粒在炉渣中的均匀分布。In another preferred aspect, the sliding door includes two or more rows of apertures. In such cases, it is even more preferred to have adjacent rows of holes arranged in a staggered (zigzag) fashion to further improve the even distribution of the particles in the slag.
在又一方面中,分配装置包括两个或更多个可单独控制的驱动滑动门,每个滑动门连接至相同料斗或不同料斗的出口。有利地,分配装置包括具有两个可单独控制的驱动滑动门的一个(或两个)料斗,每个滑动门覆盖铸造模具的表面的基本一半。两个(或更多个)独立驱动滑动门的设置允许当模具正在分配装置下方移动时在打开时间方面较灵活,并且允许如果其中的一个门失效或被阻塞时在冗余度方面较灵活。In yet another aspect, the dispensing device comprises two or more individually controllable actuated sliding doors, each connected to an outlet of the same hopper or a different hopper. Advantageously, the dispensing device comprises a hopper (or two) with two individually controllable actuated sliding doors, each covering substantially half of the surface of the casting mould. The provision of two (or more) independently actuated sliding doors allows for flexibility in opening times when the mold is moving under the dispensing device, and in redundancy if one of the doors fails or becomes blocked.
一个或多个滑动门由任何适当的装置(例如气动装置、液压装置)驱动,和/或由一个或多个电机驱动。优选地,对滑动门的驱动通过一个或多个液压缸实现。The one or more sliding doors are driven by any suitable means (eg pneumatic means, hydraulic means), and/or by one or more electric motors. Preferably, the actuation of the sliding door is achieved by one or more hydraulic cylinders.
在又一方面,滑动门的行程是受限的,使得固定板的孔并未被完全关闭。这种做法的优点是双重的:驱动甚至更快,并且滑动门和固定板的磨损显著减少。事实上,已经注意到对于给定直径的金属颗粒来说,将滑动门关闭到给每个孔留下剩余开口就足够了,其中每个剩余开口通常表现为颗粒的直径(或在同时使用不同直径的颗粒时最小颗粒的直径)的0.3倍至1.5倍,优选地约0.8倍至1.3倍,最优选地在约1.1倍至1.25倍之间。In yet another aspect, the travel of the sliding door is limited such that the aperture of the fixing plate is not fully closed. The advantages of this approach are twofold: the actuation is even faster, and there is significantly less wear and tear on the sliding doors and fixed plates. In fact, it has been noted that for a metal particle of a given diameter, it is sufficient to close the sliding door to leave a residual opening for each hole, where each remaining opening typically represents the diameter of the particle (or at the same time using a different The diameter of the particle is 0.3 to 1.5 times the diameter of the smallest particle), preferably about 0.8 to 1.3 times, most preferably about 1.1 to 1.25 times.
在另一方面中,本发明的方法和设备还包含有用以精确地确定模具(中的一些),且特别是位于分配装置下方的模具的位置的装置。任何常规的装置均可以用于该目的,特别是接触式装置和/或非接触式装置,如开关、激光器、感应器等。In another aspect, the method and apparatus of the present invention also comprise means for precisely determining the position of the mold(s), and in particular the molds located below the dispensing means. Any conventional means can be used for this purpose, in particular contact means and/or non-contact means, such as switches, lasers, sensors and the like.
优选地,从约0.1m至3m且优选地约0.2m至2m的高度投放固态金属颗粒,以获得炉渣和固态金属颗粒的快速且有效的混合。颗粒穿过液态炉渣至期望深度所需的精确高度(即精确的能量大小)取决于炉渣的成分、炉渣的温度、固态金属颗粒的密度和直径等。由于将金属颗粒投入热液态炉渣中可能会引起一些溅出或飞溅,所以分配装置优选地包括至少设置在料斗和滑动门下方的侧面上的防溅板,该防溅板近似延伸到模具的上顶部。Preferably, the solid metal particles are dosed from a height of about 0.1 m to 3 m and preferably about 0.2 m to 2 m to obtain a rapid and efficient mixing of the slag and solid metal particles. The precise height (ie, the precise amount of energy) required for the particles to penetrate the liquid slag to the desired depth depends on the composition of the slag, the temperature of the slag, the density and diameter of the solid metal particles, etc. Since throwing metal particles into the hot liquid slag may cause some splashing or splashing, the dispensing device preferably includes splash guards arranged at least on the sides below the hopper and sliding doors, extending approximately to the upper side of the mould. top.
有利地,固态金属颗粒具有至少2.5g/cm3的密度。由于炉渣和金属颗粒之间存在密度差,所以金属颗粒和炉渣完全地混合。Advantageously, the solid metal particles have a density of at least 2.5 g/cm 3 . Due to the density difference between the slag and the metal particles, the metal particles and the slag are thoroughly mixed.
优选地,固态金属颗粒为球状,以便具有良好的混合性能,并确保炉渣的快速且有效的冷却。Preferably, the solid metal particles are spherical in order to have good mixing properties and to ensure fast and efficient cooling of the slag.
优选地,固态金属颗粒具有至少2mm的直径,其优选地大于5mm且最优选地大于10mm。有利地,固态金属颗粒具有小于80mm的直径,其优选地小于50mm且最优选地小于25mm。Preferably, the solid metal particles have a diameter of at least 2mm, which is preferably greater than 5mm and most preferably greater than 10mm. Advantageously, the solid metal particles have a diameter of less than 80mm, preferably less than 50mm and most preferably less than 25mm.
优选地,固态金属颗粒由选自铁、钢、铝、铜、铬、镍、它们的合金以及它们与其他金属的合金的组中的金属制成。Preferably, the solid metal particles are made of a metal selected from the group of iron, steel, aluminium, copper, chromium, nickel, their alloys and their alloys with other metals.
在实践中,优选地使用钢球,原因在于容易获得不同直径的钢球。In practice, steel balls are preferably used due to the ease of obtaining steel balls of different diameters.
在从输送机排出炉渣饼期间和/或之后,优选地,将该炉渣饼压碎成尺寸约为40-120mm且体积密度约为2-5g/cm3的颗粒,优选地压碎成尺寸约为40-90mm且体积密度约为2-5g/cm3的颗粒。During and/or after discharge of the slag cake from the conveyor, preferably the slag cake is crushed into particles of a size of about 40-120 mm and a bulk density of about 2-5 g/cm 3 , preferably crushed into a size of about Particles with a diameter of 40-90 mm and a bulk density of approximately 2-5 g/cm 3 .
此后,优选地将仍然热的炉渣颗粒和变热的固态金属颗粒装入热交换器中,用逆流流动的冷却气体将其冷却并使其从热交换器排出。Thereafter, the still hot slag particles and heated solid metal particles are preferably charged into a heat exchanger, cooled with countercurrent flow of cooling gas and discharged from the heat exchanger.
根据一个优选实施方式,热交换器被细分为多个子单元,每个所述子单元具有颗粒进入口、颗粒排出口、冷却气体进入口和冷却气体排出口,其中,至少一个子单元通过颗粒进入口装有热的炉渣颗粒和变热的固态金属颗粒,冷却的炉渣颗粒和冷却的固态金属颗粒通过所述颗粒排出口从所述至少一个子单元排出,所述冷却气体进入口和所述冷却气体排出口在颗粒的装入和排出期间是关闭的,并且其中,在装入和排出颗粒的同时,至少一个其他子单元通过经由冷却气体进入口注入冷却气体流并从所述冷却气体排出口收回变热的冷却气体流而被冷却,所述颗粒进入口和所述颗粒排出口在颗粒的冷却期间是关闭的,并且其中,变热的冷却气体用于能量回收。According to a preferred embodiment, the heat exchanger is subdivided into a plurality of subunits, each of which has a particle inlet, a particle outlet, a cooling gas inlet and a cooling gas outlet, wherein at least one subunit passes through the particle The inlet port contains hot slag particles and heated solid metal particles, the cooled slag particles and cooled solid metal particles are discharged from the at least one subunit through the particle discharge port, the cooling gas inlet port and the The cooling gas outlet is closed during the charging and discharging of particles, and wherein, while charging and discharging the particles, at least one other subunit is injected with a flow of cooling gas through the cooling gas inlet and drawn from said cooling gas discharge. The outlet is cooled by withdrawing a stream of heated cooling gas, the particle inlet and the particle outlet are closed during the cooling of the particles, and wherein the heated cooling gas is used for energy recovery.
因此,根据本发明的优选实施方式的方法提出了使用包括多个子单元的热交换器,所述多个子单元不连续地进行操作。因为为了保证最有效地利用发电周期而在热交换器的出口处获得恒定的热气流是有利的,所以多个热交换器子单元以保证基本恒定的热气流的方式交替操作。通过这样做,可以获得与分批式材料处理分离的基本连续的气体处理。Therefore, the method according to a preferred embodiment of the invention proposes the use of a heat exchanger comprising a plurality of subunits which operate discontinuously. Since it is advantageous to obtain a constant hot gas flow at the outlet of the heat exchangers in order to ensure the most efficient use of the power generation cycle, multiple heat exchanger subunits are alternately operated in such a way as to ensure a substantially constant hot gas flow. By doing so, substantially continuous gas processing separate from batch material processing can be obtained.
在热交换器子单元中之一处于清空/填充阶段的每个时刻,没有冷却气体在清空/填充期间流经该热交换器子单元。At each moment when one of the heat exchanger subunits is in the emptying/filling phase, no cooling gas flows through this heat exchanger subunit during emptying/filling.
相同量的颗粒被填充到交换器中,并从该交换器提取出来。同时,没有材料进入或离开其他热交换器子单元;因此,上述颗粒能够在冷却期间与环境完全隔绝。The same amount of particles is filled into and extracted from the exchanger. At the same time, no material enters or leaves other heat exchanger subunits; thus, the above-mentioned particles can be completely isolated from the environment during cooling.
优选地,子单元中的一个子单元通过颗粒进入口装有热的炉渣颗粒和变热的固态金属颗粒,而同时通过该子单元的颗粒排出口排出冷却的炉渣颗粒和冷却的固态金属颗粒。Preferably, one of the subunits is loaded with hot slag particles and heated solid metal particles through the particle inlet, while simultaneously discharging cooled slag particles and cooled solid metal particles through the particle discharge of the subunit.
一旦热交换器子单元被填满,将颗粒进入口和颗粒排出口密封并将该子单元重新连接至冷却气体流,而可能将另一热交换器子单元断开。因此,通过这些热交换器子单元的冷却气体流不会遭遇任何泄漏,从而防止灰尘和能量留在系统中。因此,仅需要在炉渣的装入和排出期间对热交换器子单元降压。Once the heat exchanger subunit is filled, the particle inlet and particle outlet are sealed and the subunit is reconnected to the cooling gas flow, while the other heat exchanger subunit may be disconnected. Hence, the cooling gas flow through these heat exchanger subunits does not encounter any leakage, preventing dust and energy from remaining in the system. Therefore, the heat exchanger subunit only needs to be depressurized during the charging and discharging of slag.
根据一个优选实施方式,在被装入热交换器子单元中的一个热交换器子单元之前,热的炉渣颗粒和变热的固态金属颗粒首先被装入隔热的前置室(pre-chamber)中。优选地,该前置室通过耐火内衬或材料石盒而是隔热的。炉渣的低热传导率提供优异的隔热性能。According to a preferred embodiment, the hot slag particles and the heated solid metal particles are first charged into an insulated pre-chamber before being charged into one of the heat exchanger subunits. )middle. Preferably, the prechamber is insulated by a refractory lining or material stone box. The low thermal conductivity of slag provides excellent insulation properties.
炉渣颗粒和固态金属颗粒还可以在冷却之后并且在从热交换器子单元排出后被装入后置室(post-chamber)中。换言之,周期时间和所装入颗粒的量可以被选择为使得:热交换器子单元内的热传递可以受控并保持准稳态。因此,通过相应地选择周期时间,由热交换器子单元的装入/排出所引起的出口气体温度波动将被最小化。The slag particles and solid metal particles may also be charged into a post-chamber after cooling and after being discharged from the heat exchanger sub-unit. In other words, the cycle time and the amount of charged particles can be chosen such that the heat transfer within the heat exchanger subunit can be controlled and kept quasi-steady. Thus, by choosing the cycle time accordingly, the outlet gas temperature fluctuations caused by the charging/discharging of the heat exchanger subunits will be minimized.
根据另一优选实施方式,热液态炉渣被固化为炉渣饼,并且通过与固态金属颗粒混合而冷却至约650℃至750℃。有利地,将热液态炉渣与大约相同体积的固态金属颗粒混合,优选地产生含有约40%至约60%体积的固态金属颗粒的混合物。所需的金属颗粒的体积取决于期望的目标温度、金属颗粒的密度和热容量等。对于钢球,40%至60%(总体积的体积百分比)是优选的。According to another preferred embodiment, the hot liquid slag is solidified into a slag cake and cooled to about 650°C to 750°C by mixing with solid metal particles. Advantageously, mixing the hot liquid slag with approximately the same volume of solid metal particles preferably results in a mixture containing from about 40% to about 60% by volume solid metal particles. The required volume of metal particles depends on the desired target temperature, the density and heat capacity of the metal particles, and the like. For steel balls, 40% to 60% (volume percent of total volume) is preferred.
优选地,热交换器子单元在1.2巴(bar)至4巴的压力(即,在子单元中炉渣层的底部处测量的绝对压力)下操作。Preferably, the heat exchanger subunit operates at a pressure (ie absolute pressure measured at the bottom of the slag layer in the subunit) of 1.2 bar to 4 bar.
附图说明Description of drawings
现在将参照附图、通过示例来描述本发明的优选实施方式,在附图中:Preferred embodiments of the invention will now be described, by way of example, with reference to the accompanying drawings, in which:
图1是干炉渣粒化设备的优选实施方式的截面示意图;Fig. 1 is a schematic cross-sectional view of a preferred embodiment of a dry slag granulation plant;
图2是滑动门阀的对于分配装置有用的一些部件的示意图;Figure 2 is a schematic illustration of some components of a sliding gate valve useful for a dispensing device;
图3是具有交错孔的双滑动门(未示出料斗)的实施方式的立体俯视图;Figure 3 is a perspective top view of an embodiment of a double sliding door (hopper not shown) with staggered holes;
图4是图1的干炉渣粒化设备的一部分的截面图;Figure 4 is a cross-sectional view of a portion of the dry slag granulation plant of Figure 1;
图5是根据本发明方法的另一优选实施方式的略图;Figure 5 is a schematic diagram of another preferred embodiment of the method according to the invention;
图6是根据本发明方法的又一优选实施方式的略图;以及Figure 6 is a schematic diagram of yet another preferred embodiment of the method according to the invention; and
图7(a)和图7(b)是示出了操作本文所述的设备的自校正方法的优选实施方式。Figures 7(a) and 7(b) are diagrams illustrating a preferred embodiment of a self-calibrating method of operating the devices described herein.
参照附图、通过下面对若干非限制性实施方式的详细描述,本发明的其他细节和优点将是显而易见的。Other details and advantages of the invention will become apparent from the following detailed description of several non-limiting embodiments, with reference to the accompanying drawings.
具体实施方式detailed description
图1示意性地示出了干炉渣粒化设备的一个优选实施方式的截面图,该干炉渣粒化设备包括具有线性循环输送机10的炉渣铸机1,该输送机包括多个铸造模具11。要注意的是,也可以使用所谓的双斜率线性炉渣铸机(参见例如图4)。Figure 1 schematically shows a cross-sectional view of a preferred embodiment of a dry slag granulation plant comprising a slag caster 1 with a linear circulating conveyor 10 comprising a plurality of casting molds 11 . It is to be noted that so-called double slope linear slag casters can also be used (see eg Figure 4).
将模具11在第一区段从炉渣浇注区A通过冷却区B输送至排出区C,其中在排出区处将模具中所容纳的固化炉渣饼清空。在第二区段,目前为空的模具被输送回炉渣浇注区。The mold 11 is transported in a first section from the slag pouring zone A through the cooling zone B to the discharge zone C, where the mold is emptied of the solidified slag cake contained therein. In the second section, the now empty mold is conveyed back to the slag pouring area.
来自炉渣沟20的热液态炉渣21被浇注到经过该炉渣沟20下方的铸造模具11中。Hot liquid slag 21 from the slag ditch 20 is poured into the casting mold 11 passing below the slag ditch 20 .
在双斜率输送机的特定情况下(如图4中),倾斜角α相对较陡,以使得最大有效体积Vα(即,当炉渣溢出到上游模具N-1中时该模具中的炉渣的体积)小于该模具到达冷却区B中的位置(图1中>N+2的位置)时的有用体积Vβ,其中倾斜角β较小。优选地,角度α和β被选择为使得Vα为约1/2Vβ。In the specific case of a double-slope conveyor (as in Figure 4), the inclination angle α is relatively steep so that the maximum effective volume V α (i.e., the volume of slag in the upstream mold N-1 when it overflows into this mold volume) is smaller than the useful volume V β of the mold when it reaches the position in cooling zone B (position >N+2 in FIG. 1 ), where the inclination angle β is smaller. Preferably, the angles α and β are chosen such that V α is about ½ V β .
当容纳有热液态炉渣的模具到达浇注位置N和分配装置30的位置N+2之间的位置(即图1和图4中N+1)时,通过传感器(优选地通过激光测距仪(Sh炉渣))来测量模具中热液态炉渣的高度(h炉渣)。When the mold containing the hot liquid slag reaches a position between the pouring position N and the position N+2 of the distribution device 30 (ie, N+1 in FIGS. 1 and 4 ), the sensor (preferably a laser range finder ( Sh slag )) to measure the height of the hot liquid slag in the mold (h slag ).
该测量的结果一方面用于调整输送机的速度(V铸机),并且另一方面用于确定随后要添加到铸造模具中的热炉渣内的颗粒的量。The results of this measurement are used on the one hand to adjust the speed of the conveyor (V -casting machine ) and on the other hand to determine the amount of particles in the hot slag to be subsequently added to the casting mould.
当容纳有热液态炉渣的模具到达分配装置30下方的位置(例如图1和4中的N+2)时,通过使安装在料斗的出口32上的滑动门35打开预定时间t而将容纳于存储料斗31中的一定量(该量是基于所测量的炉渣的量和预定义的炉渣/颗粒比确定的)的固态金属颗粒33(如钢球)引入到模具中。颗粒33通过重力的作用落入模具中并与热液态炉渣21混合。When the mold containing the hot liquid slag reaches a position below the distributing device 30 (for example, N+2 in FIGS. An amount of solid metal particles 33 (eg steel balls) in a storage hopper 31 (the amount is determined based on the measured amount of slag and a predefined slag/particle ratio) is introduced into the mould. The particles 33 fall into the mold by the action of gravity and mix with the hot liquid slag 21 .
可以提供防溅板36以防止液态炉渣和钢球在装入期间从模具飞溅。A splash guard 36 may be provided to prevent liquid slag and steel balls from splashing from the mold during charging.
在将金属颗粒33引入到热液态炉渣21期间,炉渣迅速冷却并以非晶态状态固化。该模具目前容纳有炉渣的固化饼和所添加金属颗粒(例如钢球),然后在前进至排出区C期间进一步冷却下来,在排出区处通过将该模具倒置而使其清空。然后,固化的炉渣饼被压碎成片并且可以前进至热回收单元(未示出)。During the introduction of the metal particles 33 into the hot liquid slag 21, the slag cools rapidly and solidifies in an amorphous state. The mold, now containing a solidified cake of slag and added metal particles such as steel balls, then cools down further during advancement to discharge zone C where it is emptied by inverting the mold. The solidified slag cake is then crushed into pieces and may proceed to a heat recovery unit (not shown).
在该方法的又一优选变型中,使用另一传感器且优选地也通过激光测距仪(Sh混合物),测量模具中的固化炉渣/颗粒混合物的高度(h混合物)。使用该值作为关于颗粒的实际添加的反馈信息,可以调整过程(自校正过程)。下面给出进一步的细节。In yet another preferred variant of the method, the height of the solidified slag/particle mixture in the mold (h mixture ) is measured using another sensor, preferably also by means of a laser distance meter (Sh mixture ). Using this value as feedback information about the actual addition of particles, the process can be adjusted (self-correcting process). Further details are given below.
图2示出了线性滑动门阀35的部分的示意图。在本发明中使用的优选滑动门阀包括具有多个间隔开的孔354的固定板353。对应的滑动板351也存在间隔开的孔352,但这些孔被定位成使得:通过线性滑动(通过沿图2中的箭头指示的方向滑动)可以使孔352从关闭位置到打开位置,其中,在关闭位置中,固定板的所有孔354被滑动板的不具有孔的那些部分(基本上,见上文)关闭,在打开位置处,孔352与孔354基本上对齐。FIG. 2 shows a schematic diagram of part of the linear sliding gate valve 35 . A preferred sliding gate valve for use in the present invention includes a retainer plate 353 having a plurality of spaced apart holes 354 . There are also spaced holes 352 in the corresponding sliding plate 351, but these holes are positioned such that the holes 352 can be brought from a closed position to an open position by sliding linearly (by sliding in the direction indicated by the arrow in FIG. 2 ), wherein In the closed position, all holes 354 of the fixed plate are closed by those parts of the sliding plate (substantially, see above) that do not have holes, and in the open position, the holes 352 are substantially aligned with the holes 354 .
图3示出了不具有用于暂时存储金属颗粒的置顶料斗的双(线性)滑动门阀35的优选实施方式的立体俯视图。出于说明性目的,所述阀中的仅一个阀还包括设置在该阀下方的防溅板36。通过单独的液压缸355相对于固定板353驱动每个阀的滑动板351。Figure 3 shows a perspective top view of a preferred embodiment of a double (linear) sliding gate valve 35 without an overhead hopper for temporary storage of metal particles. For illustrative purposes, only one of the valves also includes a splash guard 36 disposed below the valve. The sliding plate 351 of each valve is driven relative to the fixed plate 353 by individual hydraulic cylinders 355 .
图4基本上对应于操作期间图1的实施方式的下面部分。此外,值得一提的是,出于本发明的目的,图4中示出的双斜率输送机也可以是单斜率输送机。Figure 4 corresponds substantially to the lower part of the embodiment of Figure 1 during operation. Furthermore, it is worth mentioning that, for the purposes of the present invention, the dual-slope conveyor shown in Figure 4 could also be a single-slope conveyor.
如在图4中可见的,位置N中的铸造模具被填充有来自炉渣沟20的热液态炉渣21。As can be seen in FIG. 4 , the casting mold in position N is filled with hot liquid slag 21 from the slag trench 20 .
在单斜率输送机的情况下,通过如上所述的那样使用传感器(Sh炉渣)测量的炉渣的高度(h炉渣)、基于位置N+1中的模具中的液态炉渣的量来调整铸机的速度(V铸机)。In the case of a single-slope conveyor, the adjustment of the casting machine is based on the amount of liquid slag in the mold in position N+1 by the height of the slag (h- slag ) measured using the sensor (Sh- slag ) as described above. Speed (V -casting machine ).
在双斜率输送机的情况下(如图4中所示的),可以另外通过输送机本身的特定形状以及可选地利用一个或多个温度传感器来控制液态炉渣的量。如果来自炉渣沟的炉渣的量超出模具的(局部)容量(Vα),则过量的炉渣通过重力溢出到位置N-1中的紧邻模具中。如果来自炉渣沟的量(流量)甚至更高,则炉渣从N-1中的模具倾泻至N-2中的模具(这实际上是图4中所示的情况)。已知从输送机10的第二区段到达的模具具有与液态炉渣的温度相差甚远的温度(为了简化,该温度也将被称为“环境温度”,尽管此温度通常将介于50℃至300℃之间或甚至更高),已经发现,通过控制N-1和N-2这两个位置的模具温度(TN-1和TN-2),可以提供对铸造过程的简单而有效的控制(同样参见下文)。要理解的是,如果认为必要或可取,那么当然可以监测两个以上的温度。In the case of a double slope conveyor (as shown in Figure 4), the amount of liquid slag can additionally be controlled by the specific shape of the conveyor itself and optionally by means of one or more temperature sensors. If the amount of slag from the slag trench exceeds the (local) capacity (V α ) of the mold, the excess slag overflows by gravity into the immediately adjacent mold in position N-1. If the volume (flow rate) from the slag trench is even higher, the slag is poured from the mold in N-1 to the mold in N-2 (this is actually the case shown in Figure 4). It is known that the mold arriving from the second section of the conveyor 10 has a temperature that is very different from that of the liquid slag (for simplicity this temperature will also be referred to as "ambient temperature", although this temperature will typically be between 50°C to 300°C or even higher), it has been found that by controlling the mold temperature (T N-1 and T N-2 ) at the two positions N-1 and N-2, it is possible to provide simple and effective control of the casting process. control (also see below). It will be appreciated that more than two temperatures may of course be monitored if deemed necessary or desirable.
在图4中,模具N+2位于分配装置30下方,并准备被填充金属颗粒33。如下文详细描述的那样确定要添加的金属颗粒的量。In FIG. 4 , mold N+2 is located below distribution device 30 and is ready to be filled with metal particles 33 . The amount of metal particles to be added is determined as described in detail below.
图4中位置N+3处的铸造模具示出了这样一个模具,其中计算量的金属颗粒已添加至液态炉渣。在这一点,由于大量冷颗粒的瞬间添加,炉渣基本上以非晶态状态固化。看起来清楚的是,图4中由N+2指示的用于插入颗粒的位置不一定必须是填充位置后面的第二个位置,只要炉渣仍然是热的并且处于液态即可。The casting mold at position N+3 in Figure 4 shows such a mold in which a calculated amount of metal particles has been added to the liquid slag. At this point, the slag solidifies substantially in an amorphous state due to the instantaneous addition of a large number of cold particles. It seems clear that the position for inserting particles indicated by N+2 in Figure 4 does not necessarily have to be the second position after the filling position, as long as the slag is still hot and in a liquid state.
可选地,此后测量炉渣/颗粒混合物的量,以验证结果是否与预期量相匹配。如果验证结果与预期量不匹配,则使用该值作为反馈信息以调整过程,如下面进一步描述的。Optionally, the amount of slag/particle mixture is measured thereafter to verify that the results match the expected amount. If the verification result does not match the expected amount, this value is used as feedback information to adjust the process, as described further below.
通过任何已知的接触式或非接触式装置(如开关、感应器、激光器等),可以确定模具在输送机内的精确位置,特别是其在炉渣沟和/或分配装置下方的位置。By any known contact or non-contact means (such as switches, sensors, lasers, etc.), the precise position of the mold within the conveyor, in particular its position below the slag trench and/or the distribution device, can be determined.
过程的描述—调节的目的Description of the process - the purpose of the adjustment
在干炉渣粒化过程中,通过添加冷金属颗粒33(如钢球)使液态炉渣21冷却。此冷却的目的是实现:During dry slag granulation, liquid slag 21 is cooled by adding cold metal particles 33 such as steel balls. The purpose of this cooling is to achieve:
·炉渣的快速冷却· Rapid cooling of slag
·用于进一步热回收的高混合温度· High mixing temperature for further heat recovery
因此,钢球的配量必须是精确的,并且必须遵守钢/炉渣比。Therefore, the dosing of steel balls must be precise and the steel/slag ratio must be respected.
为了实现材料的输送,已选择炉渣铸机10技术。在输送机10的开端处的浇注区A中在上游浇注炉渣21,然后在冷却区B中添加钢球33,例如在图1和图4中所示的。To achieve the conveying of the material, the slag caster 10 technology has been chosen. The slag 21 is poured upstream in the pouring zone A at the beginning of the conveyor 10 and then the steel balls 33 are added in the cooling zone B, as shown for example in FIGS. 1 and 4 .
应当对冷却区B中钢球33的配量以及位置N中的模具11的炉渣填充进行调节。在目前描述的调节模式中,通过测量位置N+1中的模具中炉渣的量并且通过在所述模具经过分配装置30下方时向所述模具中添加计算量的钢球33来进行调节。通过改变铸机10的速度来控制模具中的热液态炉渣的量。The dosing of the steel balls 33 in the cooling zone B and the slag filling of the mold 11 in the position N should be adjusted. In the mode of regulation so far described, regulation is performed by measuring the amount of slag in the mold in position N+1 and by adding a calculated amount of steel balls 33 to the mold as it passes under the distribution device 30 . The amount of hot liquid slag in the mold is controlled by varying the speed of the casting machine 10 .
由于装入时间是有限的,所以使用例如如图2和图3中所示的滑动门阀35进行钢球33的配量。Since the loading time is limited, the metering of the steel balls 33 is carried out using, for example, a sliding gate valve 35 as shown in FIGS. 2 and 3 .
优选调节方式的描述Description of the preferred mode of adjustment
如上面已经提及的,金属颗粒优选地为钢球。必须对这样的钢球的配量以及模具的炉渣填充进行调节。优选地,通过改变以下两个参数进行此调节:As already mentioned above, the metal particles are preferably steel balls. The dosing of such steel balls and the slag filling of the mold must be adjusted. Preferably, this adjustment is made by changing the following two parameters:
·铸机的速度·Speed of casting machine
·投入到每个模具中的金属颗粒(钢球)的量。• The amount of metal pellets (steel balls) charged into each mold.
因为金属颗粒的装入时间是有限的,所以使用例如图2和图3中所示的一个或多个门阀进行配量。Because the loading time of the metal particles is limited, one or more gate valves such as those shown in FIGS. 2 and 3 are used for dosing.
仅当每个模具位于门的下方时才对该模具进行装入操作,因此颗粒被装入其中的模具并非是不确定的。Each mold is loaded only when it is under the door, so it is not undefined which mold the pellet is loaded into.
通过该门装入的材料取决于两个参数:The material loaded through the door depends on two parameters:
·门的开度(x);The opening of the door (x);
·门的打开时间(t)。• Door opening time (t).
如图5中可以看出的,基本调节步骤可以为如下描述的步骤:As can be seen in Figure 5, the basic adjustment steps may be those described as follows:
1.在位置N中的模具中注入液态炉渣(未知量);1. Inject liquid slag (unknown amount) into the mold in position N;
2.一旦模具已经到达位置N+1,使用激光器测量炉渣水平(h炉渣),2. Once the mold has reached position N+1, use the laser to measure the slag level (h slag ),
a)从该高度(h炉渣)换算出模具中炉渣的体积(V炉渣),然后换算出模具中炉渣的质量(M炉渣),a) From this height (h slag ), convert the volume of slag in the mold (V slag ), and then convert the mass of slag in the mold (M slag ),
b)基于炉渣/钢比(λ),确定对于该模具必需的钢球(M钢球),b) Based on the slag/steel ratio (λ), determine the steel balls (M steel balls ) necessary for the mold,
c)基于所记录的炉渣高度(h炉渣)调整铸机速度(V铸机);c) adjust the speed of the caster (V caster ) based on the recorded slag height (hslag);
3.一旦模具已经到达位置N+2,装入钢球,3. Once the mold has reached position N+2, load steel balls,
a)基于铸机速度(V铸机)确定该滑动门的打开时间(t),a) Determine the opening time (t) of the sliding door based on the casting machine speed ( Vcasting machine ),
b)基于以下参数确定门的开度(x),所述参数为b) Determine the opening (x) of the door based on the following parameters, which are
ⅰ.上面确定的所需钢球质量M钢球 ⅰ. The required steel ball quality M steel ball determined above
ⅱ.打开时间(t)ⅱ. Open time (t)
ⅲ.滑动门的特性(曲线)。ⅲ. Characteristics of sliding doors ( curve).
该第一调节方法可以如图5中所示的进行概括。This first adjustment method can be summarized as shown in FIG. 5 .
在又一优选实施方式中,该方法还包括以下步骤:In another preferred embodiment, the method also includes the following steps:
4.一旦模具已经到达位置N+3,利用激光器测量钢球/炉渣混合物的高度(h混合物),4. Once the mold has reached position N+3, use the laser to measure the height of the steel ball/slag mixture (h mixture ),
a)从该高度(h混合物)换算出模具中的混合物体积(V混合物)。确定模具中实际添加的钢球(M钢球')。a) From this height (hmixture), the volume of mixture in the mold ( Vmixture ) is converted. Determine the steel balls actually added in the mold (M steel balls' ).
5.反馈信息—门特性的调整5. Feedback information - adjustment of door characteristics
a)如果M钢球=M钢球',则已投入正确量的钢球→不调整曲线,a) If M steel ball = M steel ball' , the correct amount of steel ball has been put in → no adjustment curve,
b)如果M钢球≠M钢球',则调整曲线以符合所测量的混合物高度。该调整在下文描述。b) If M steel ball ≠M steel ball' , then adjust curve to fit the measured mixture height. This adjustment is described below.
该进一步优选的调节方法可以如图6中所示的进行概括。This further preferred adjustment method can be summarized as shown in FIG. 6 .
门特性的调节Adjustment of door characteristics
如果所测量的钢球的量与理论量不相符(M钢球<>M钢球');则应当调节曲线曲线。确定差值ΔM钢球,由于装入时间t是已知的,所以计算所计算的流量和实际流量之间的差值 If the amount of the measured steel ball does not match the theoretical amount (M steel ball <>M steel ball' ); then the curve should be adjusted curve. Determine the difference ΔM steel ball , since the loading time t is known, calculate the difference between the calculated flow and the actual flow
如果则不施加校正,并且发出报警。如果那么将对配量阀的质量流量特性曲线执行校正。if Then no correction is applied and an alarm is issued. if A correction is then performed on the mass flow characteristic curve of the metering valve.
曲线曲线为离散曲线。可以通过针对表中的每个流量值(参照图7(b))调节各个打开长度xn(参照图7(a))对该曲线进行校正。位置距离x越远,校正将越小。curve The curve is a discrete curve. This curve can be corrected by adjusting the respective opening length xn (cf. Fig . 7(a)) for each flow value in the table (cf. Fig. 7(b)). The farther the location is from x, the smaller the correction will be.
为了达到预期流量而施加于x(位置包括在xi和xi+1之间)的校正为Δx。经校正的打开长度为x′=x+Δx。The correction to be applied to x (positions included between xi and xi+1 ) to achieve the desired flow rate is Δx. The corrected open length is x'=x+Δx.
现在,已计算出针对x的校正Δx,材料流表的位置值xn将由经校正的值x′n替换。通过使用以下公式进行更新:Now that the correction Δx for x has been calculated, the position value x n of the material flow table will be replaced by the corrected value x′ n . Update by using the following formula:
对于x以上的xn值:For values of x n above x:
对于x以下的xn值:For values of x n below x:
计算极限值:Compute limit values:
x最小≤x′n≤x最大 x min ≤ x′ n ≤ x max
x最小=配量阀的最小允许打开长度x min = the minimum allowable opening length of the dosing valve
x最大=配量阀的最大允许打开长度xmax = the maximum allowable opening length of the metering valve
其中:in:
x′n:单位为[mm]的新值x′ n : new value in [mm]
xn:单位为[mm]的旧值x n : old value in [mm]
N:材料流表中的值的总数N: total number of values in the material flow table
n:材料流表中考虑的位置(n=1…N)n: position considered in the material flow table (n=1...N)
K1:用以防止过校正的常数因子(K1≥2)K 1 : constant factor to prevent over-correction (K 1 ≥ 2)
图注:Legend:
1铸造设备1 casting equipment
10循环输送机10 cycle conveyor
11铸造模具11 casting mold
20炉渣沟20 slag ditch
21热液态炉渣21 hot liquid slag
30分配装置30 distribution device
31料斗31 Hopper
32料斗出口32 hopper outlet
33固态金属颗粒,例如钢球33 solid metal particles, such as steel balls
35滑动门阀35 sliding door valve
351滑动板351 slide plate
352滑动板中的孔352 Hole in slide plate
353固定板353 fixed plate
354固定板中的孔354 hole in fixed plate
355液压缸355 hydraulic cylinder
36防溅板36 splash guard
A炉渣浇注区A slag pouring area
B冷却区B cooling zone
C排出区C discharge area
Sh炉渣用于测量热液态炉渣的高度的传感器Sh slag sensor for measuring the height of hot liquid slag
Sh混合物用于测量炉渣/颗粒混合物的高度的传感器Sh Mixture Sensor for height measurement of slag/granulate mixture
α炉渣浇注区A中输送机的倾斜角α The inclination angle of the conveyor in the slag pouring zone A
β冷却区B中输送机的倾斜角The inclination angle of the conveyor in the beta cooling zone B
Vα模具在炉渣浇注区A中的有效最大填充体积V α the effective maximum filling volume of the mold in the slag pouring area A
Vβ模具在冷却区B中的有效最大填充体积V is the effective maximum filling volume of the mold in cooling zone B
TN-1用于模具位置N-1的温度传感器T N-1 Temperature sensor for mold position N-1
TN-2用于模具位置N-2的温度传感器T N-2 Temperature sensor for mold position N-2
Claims (26)
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| Application Number | Priority Date | Filing Date | Title |
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| LULU92197 | 2013-05-14 | ||
| LU92197A LU92197B1 (en) | 2013-05-14 | 2013-05-14 | Casting apparatus and method of controlling said apparatus. |
| PCT/EP2014/059881 WO2014184260A1 (en) | 2013-05-14 | 2014-05-14 | Casting apparatus and method of controlling said apparatus |
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| CN (1) | CN105358716A (en) |
| LU (1) | LU92197B1 (en) |
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| WO (1) | WO2014184260A1 (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105907905A (en) * | 2016-06-22 | 2016-08-31 | 中冶东方工程技术有限公司 | Molten slag waste heat recycling device |
| CN107606961A (en) * | 2017-10-17 | 2018-01-19 | 山东泓奥电力科技有限公司 | Liquid slag waste-heat recovery device |
| CN113481376A (en) * | 2021-05-31 | 2021-10-08 | 金川集团股份有限公司 | Method for sorting and recycling copper and nickel in copper smelting furnace slag |
| CN117622812A (en) * | 2022-08-19 | 2024-03-01 | 中冶长天国际工程有限责任公司 | A control system and control method for an adsorption purification system |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110616285A (en) * | 2019-10-29 | 2019-12-27 | 昆明普利惠节能技术有限公司 | Heat accumulating type slag dry type granulator |
| CN112061684A (en) * | 2020-08-18 | 2020-12-11 | 重庆腾弘机械有限公司 | High temperature product link joint conveying feed bin |
| CN113234872A (en) * | 2021-03-09 | 2021-08-10 | 北京市金万旺科技有限公司 | Device and method for thermal-state forming and curing treatment of continuous casting residues |
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| US4277273A (en) * | 1976-10-12 | 1981-07-07 | Edouard Legille | Treatment and handling of metallurgical slag |
| DE3513280C1 (en) * | 1985-04-13 | 1986-08-28 | Waldemar Glowatzki, Maschinen, Apparatebau, Förderanlagen, Blechverarbeitung, 3004 Isernhagen | Cup conveyor |
| WO2012034897A2 (en) * | 2010-09-13 | 2012-03-22 | Paul Wurth S.A. | Dry granulation of metallurgical slag |
| WO2012080364A1 (en) * | 2010-12-15 | 2012-06-21 | Paul Wurth S.A. | Granulation of metallurgical slag |
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| DE1080016B (en) * | 1957-04-11 | 1960-04-14 | Fredenhagen Kommanditgesellsch | Endless carrier belt for piece goods |
-
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- 2013-05-14 LU LU92197A patent/LU92197B1/en active
-
2014
- 2014-05-14 WO PCT/EP2014/059881 patent/WO2014184260A1/en not_active Ceased
- 2014-05-14 TW TW103116913A patent/TW201510226A/en unknown
- 2014-05-14 CN CN201480035122.2A patent/CN105358716A/en active Pending
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|---|---|---|---|---|
| US4277273A (en) * | 1976-10-12 | 1981-07-07 | Edouard Legille | Treatment and handling of metallurgical slag |
| DE3513280C1 (en) * | 1985-04-13 | 1986-08-28 | Waldemar Glowatzki, Maschinen, Apparatebau, Förderanlagen, Blechverarbeitung, 3004 Isernhagen | Cup conveyor |
| WO2012034897A2 (en) * | 2010-09-13 | 2012-03-22 | Paul Wurth S.A. | Dry granulation of metallurgical slag |
| WO2012080364A1 (en) * | 2010-12-15 | 2012-06-21 | Paul Wurth S.A. | Granulation of metallurgical slag |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN105907905A (en) * | 2016-06-22 | 2016-08-31 | 中冶东方工程技术有限公司 | Molten slag waste heat recycling device |
| CN105907905B (en) * | 2016-06-22 | 2018-06-22 | 中冶东方工程技术有限公司 | A kind of molten slag waste-heat recovery device |
| CN107606961A (en) * | 2017-10-17 | 2018-01-19 | 山东泓奥电力科技有限公司 | Liquid slag waste-heat recovery device |
| CN107606961B (en) * | 2017-10-17 | 2023-11-24 | 山东泓奥电力科技有限公司 | Liquid slag waste heat recovery device |
| CN113481376A (en) * | 2021-05-31 | 2021-10-08 | 金川集团股份有限公司 | Method for sorting and recycling copper and nickel in copper smelting furnace slag |
| CN113481376B (en) * | 2021-05-31 | 2022-09-06 | 金川集团股份有限公司 | A kind of copper and nickel in copper smelting slag sorting and recycling processing method |
| CN117622812A (en) * | 2022-08-19 | 2024-03-01 | 中冶长天国际工程有限责任公司 | A control system and control method for an adsorption purification system |
Also Published As
| Publication number | Publication date |
|---|---|
| WO2014184260A1 (en) | 2014-11-20 |
| TW201510226A (en) | 2015-03-16 |
| LU92197B1 (en) | 2014-11-17 |
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