CN105358111A - Non-woven fabric and process for forming the same - Google Patents
Non-woven fabric and process for forming the same Download PDFInfo
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- CN105358111A CN105358111A CN201480038130.2A CN201480038130A CN105358111A CN 105358111 A CN105358111 A CN 105358111A CN 201480038130 A CN201480038130 A CN 201480038130A CN 105358111 A CN105358111 A CN 105358111A
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- 238000003490 calendering Methods 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
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- 229910003460 diamond Inorganic materials 0.000 description 1
- 239000010432 diamond Substances 0.000 description 1
- PRAKJMSDJKAYCZ-UHFFFAOYSA-N dodecahydrosqualene Natural products CC(C)CCCC(C)CCCC(C)CCCCC(C)CCCC(C)CCCC(C)C PRAKJMSDJKAYCZ-UHFFFAOYSA-N 0.000 description 1
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Classifications
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- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H3/00—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length
- D04H3/08—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the method of strengthening or consolidating
- D04H3/14—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the method of strengthening or consolidating with bonds between thermoplastic yarns or filaments produced by welding
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
- D04H1/54—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by welding together the fibres, e.g. by partially melting or dissolving
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
- D04H1/54—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by welding together the fibres, e.g. by partially melting or dissolving
- D04H1/559—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by welding together the fibres, e.g. by partially melting or dissolving the fibres being within layered webs
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Nonwoven Fabrics (AREA)
- Absorbent Articles And Supports Therefor (AREA)
Abstract
本发明涉及一种适用于卫生吸收制品的包含第一非织造网的非织造织物,所述网包含一个侧面,该侧面具有独立化粘合区域的第一图案,其限定了具有六边形形状的未粘合区域的第二图案,并且其中该粘合区域的表面积为所述侧面的总表面积的10-30%且该未粘合区域的表面积为所述侧面的总表面积的70-90%。本发明还涉及一种包含本发明的非织造织物的吸收制品,以及用于形成该非织造织物的方法。
The present invention relates to a nonwoven fabric suitable for use in sanitary absorbent articles comprising a first nonwoven web comprising a side having a first pattern of individualized bonded areas defining a hexagonal shape. and wherein the surface area of the bonded areas is 10-30% of the total surface area of the sides and the surface area of the unbonded areas is 70-90% of the total surface area of the sides . The present invention also relates to an absorbent article comprising the nonwoven fabric of the present invention, and a method for forming the nonwoven fabric.
Description
技术领域technical field
本发明涉及一种非织造织物,一种包含该非织造织物的卫生吸收制品,以及用于形成该非织造织物的方法。The present invention relates to a nonwoven fabric, a sanitary absorbent article comprising the nonwoven fabric, and a method for forming the nonwoven fabric.
背景技术Background technique
非织造织物广泛应用在用于个人护理或卫生的一次性吸收制品中。在这些制品中,柔软的外观是非常重要的,因为这将令穿用者或护理人员确信该制品体验舒适。Nonwoven fabrics are widely used in disposable absorbent articles for personal care or hygiene. In these articles, the appearance of softness is very important as this will reassure the wearer or caregiver that the article is comfortable to experience.
在WO2012/024576A1中,记载了一种适于穿用者的下体穿用的吸收制品,其目的在于增强该吸收制品的感知柔软性。所述文件中记载的吸收制品包括液体可渗透的顶片、液体不可渗透的背片以及置于顶片和背片之间的吸收芯。所述液体不可渗透的背片包含液体不可渗透的面向穿用者层、水蒸气可渗透的聚合物膜以及非织造网的面向衣物层的层压体。该非织造网压印有菱形形状的粘合压痕的第一图案,该第一图案限定了也具有菱形形状的未粘合凸起区域的第二图案。关于这一点参照图3A-4B。在制造所述非织造网的过程中,需要水缠结或水饱和工艺来增加蓬松度和/或厚度,增强视觉和触觉柔软性信号。然而,这种水缠结或水饱和工艺的缺点是,它大大增加了该吸收制品的制造成本。此外,所述吸收制品的柔软性仍有改进的空间。In WO 2012/024576 A1 an absorbent article adapted to be worn on the lower body of the wearer is described, the purpose of which is to enhance the perceived softness of the absorbent article. The absorbent article described in said document comprises a liquid-permeable topsheet, a liquid-impermeable backsheet and an absorbent core interposed between the topsheet and the backsheet. The liquid impermeable backsheet comprises a laminate of a liquid impermeable wearer facing layer, a water vapor permeable polymeric film, and a garment facing layer of a nonwoven web. The nonwoven web is embossed with a first pattern of diamond-shaped bonded indentations defining a second pattern of unbonded raised areas also having diamond shapes. Reference is made in this regard to Figures 3A-4B. During the manufacture of the nonwoven webs, hydroentanglement or water saturation processes are required to increase loft and/or thickness, enhance visual and tactile softness signals. However, a disadvantage of this hydroentanglement or water saturation process is that it greatly increases the manufacturing cost of the absorbent article. Furthermore, there is still room for improvement in the softness of the absorbent articles.
WO2006/048173记载了一种用于机械封闭系统的成圈非织造材料。该织物热粘合有粘合压痕的第一图案,该第一图案产生了较大的未粘合凸起区域的第二图案以及较小的未粘合区域的第三图案。该压痕是三叶形和线性几何形状的组合。这对所述织物的机械稳定性提供了积极效果,但缺点是它限制了悬垂性——柔软性感知的一个重要特征。WO2006/048173 describes a looped nonwoven material for mechanical closure systems. The fabric is thermally bonded with a first pattern of bonded indentations that produces a second pattern of larger unbonded raised areas and a third pattern of smaller unbonded areas. This indentation is a combination of trefoil and linear geometries. This provides a positive effect on the mechanical stability of the fabric, but has the disadvantage that it limits the drape - an important feature for the perception of softness.
此外,在JP2005245913中记载了一种用于清洁硬质表面如大理石地板的擦拭物(wiper)。该擦拭物通常由单层的非织造材料组成。该非织造层由含有超过40%的微纤维(熔喷)的纤维混合物组成。纤维混合物的其余部分由天然纤维(如棉花)以及主要由聚酯制成的支撑纤维组成。这种结构和高的单位重量归因于所述织物预期的高清洁效率,而非令人感到愉快的手感和穿用者的舒适感。因此,这些擦拭物不适于需要足够高的柔软性的卫生应用,特别不适于需要与穿用者的皮肤直接接触的个人卫生吸收制品。Furthermore, a wiper for cleaning hard surfaces such as marble floors is described in JP2005245913. The wipes typically consist of a single layer of nonwoven material. The nonwoven layer consists of a fiber mixture containing more than 40% microfibres (meltblown). The remainder of the fiber blend consists of natural fibers such as cotton, as well as support fibers mainly made of polyester. This structure and high basis weight are attributable to the expected high cleaning efficiency of the fabric rather than the pleasing hand and wearer comfort. Therefore, these wipes are not suitable for hygienic applications requiring a sufficiently high level of softness, particularly for personal hygiene absorbent articles requiring direct contact with the wearer's skin.
本发明的目的是提供了一种适用于卫生吸收制品的非织造织物,所述非织造织物具有粘合区域和未粘合区域的简化图案,其可更容易地制造且同时显示出改善的柔软性。It is an object of the present invention to provide a nonwoven suitable for hygienic absorbent articles with a simplified pattern of bonded and unbonded regions which can be manufactured more easily and at the same time exhibits improved softness sex.
本发明的进一步目的是提供一种具有改善的柔软性和高拉伸强度的尺寸稳定的非织造织物。A further object of the present invention is to provide a dimensionally stable nonwoven fabric with improved softness and high tensile strength.
本发明的另一个目的是提供一种具有足够的剪切强度以便在个人卫生吸收制品中用作纺织品背片(textilebacksheet)或接合区(landingzone)的非织造织物。Another object of the present invention is to provide a nonwoven fabric having sufficient shear strength to be used as a textile backsheet or landing zone in personal hygiene absorbent articles.
本发明的又一个目的是提供可用作卫生吸收制品如湿擦拭物和干擦拭物的非织造织物。Yet another object of the present invention is to provide nonwoven fabrics that can be used as hygienic absorbent articles such as wet wipes and dry wipes.
发明内容Contents of the invention
现已发现,当使用特定的粘合区域和未粘合区域的图案时,可以实现本发明的目的。It has now been found that the objects of the invention can be achieved when a specific pattern of bonded and unbonded areas is used.
因此,本发明涉及一种适用于卫生吸收制品的包含非织造网的非织造织物,所述网包含一个侧面,该侧面具有独立化粘合区域的第一图案,其限定了具有六边形形状的未粘合区域的第二图案,并且其中该粘合区域的表面积为所述侧面的总表面积的10-30%且该未粘合区域的表面积为所述侧面的总表面积的70-90%。Accordingly, the present invention relates to a nonwoven fabric suitable for use in hygienic absorbent articles comprising a nonwoven web comprising a side having a first pattern of individualized bonded areas defining a hexagonal shape. and wherein the surface area of the bonded areas is 10-30% of the total surface area of the sides and the surface area of the unbonded areas is 70-90% of the total surface area of the sides .
本发明一个主要的优点在于,本发明的图案的制造相对简单且具有改善的感知柔软性。此外,本发明的非织造织物的三维表面为其使用者提供了富有美感的外观。另外一个主要的优点是,本发明的非织造织物显示出改善的柔软性并且同时显示出高拉伸强度。这是出人意料的,因为通常认为热粘合的非织造织物的柔软性和尺寸稳定性(即,高拉伸强度)是相互排斥的特征。A major advantage of the present invention is that the pattern of the present invention is relatively simple to manufacture and has improved perceived softness. Furthermore, the three-dimensional surface of the nonwoven fabric of the present invention provides an aesthetically pleasing appearance to its user. Another major advantage is that the nonwovens according to the invention exhibit improved softness and at the same time high tensile strength. This is surprising since softness and dimensional stability (ie, high tensile strength) of thermally bonded nonwoven fabrics are generally considered to be mutually exclusive characteristics.
具体实施方式detailed description
根据本发明,所述非织造织物包含非织造网,所述网包含一个侧面,该侧面具有独立化粘合区域的第一图案,其限定了具有六边形形状的未粘合区域的第二图案,并且其中该粘合区域的表面积为所述侧面的总表面积的10-30%且该未粘合区域的表面积为所述侧面的总表面积的70-90%。根据本发明所使用的未粘合区域的高表面积提供了引人注目的高柔软性。此外,大的未粘合区域使纤维胀大(bulkup)且增加织物的膨松度。从视觉和触觉上,这均被认为是甚至更高的柔软性。优选地,未粘合区域的表面积为所述侧面的总表面积的至少70%且小于85%。优选地,未粘合区域的表面积为所述侧面的总表面积的75-85%。According to the present invention, said nonwoven fabric comprises a nonwoven web comprising a side having a first pattern of individualized bonded areas defining a second pattern of unbonded areas having a hexagonal shape. pattern, and wherein the surface area of the bonded area is 10-30% of the total surface area of the side and the surface area of the unbonded area is 70-90% of the total surface area of the side. The high surface area of the unbonded areas used according to the invention provides a noticeably high softness. In addition, large unbonded areas bulk up the fibers and increase the bulk of the fabric. This is considered an even higher softness, both visually and tactilely. Preferably, the surface area of the unbonded area is at least 70% and less than 85% of the total surface area of said sides. Preferably, the surface area of the unbonded areas is 75-85% of the total surface area of the sides.
粘合区域的表面积优选大于所述侧面的总表面积的15%且最多30%,更优选为15-25%。The surface area of the bonding area is preferably greater than 15% and at most 30%, more preferably 15-25%, of the total surface area of the sides.
独立化粘合区域的第一图案限定了具有六边形形状的未粘合区域的第二图案。The first pattern of individualized bonded areas defines a second pattern of unbonded areas having a hexagonal shape.
优选地,所述非织造织物的侧面仅具有第一图案和第二图案,这意味着在所述非织造织物的侧面上没有其它的粘合区域或未粘合区域的图案。Preferably, the side of the nonwoven fabric has only the first pattern and the second pattern, which means that there are no other patterns of bonded or unbonded regions on the side of the nonwoven fabric.
因此,本发明还涉及一种适用于吸收制品的包含非织造网的非织造织物,所述网包含一个侧面,该侧面具有由第一图案和第二图案组成的整体图案,其中第一图案为独立化粘合区域的图案,其限定了具有六边形形状的未粘合区域的第二图案,并且其中该粘合区域的表面积为所述侧面的总表面积的10-30%且该未粘合区域的表面积为所述侧面的总表面积的70-90%。Accordingly, the present invention also relates to a nonwoven fabric suitable for use in an absorbent article comprising a nonwoven web comprising a side having an overall pattern consisting of a first pattern and a second pattern, wherein the first pattern is A pattern of individualized bonded areas that defines a second pattern of unbonded areas having a hexagonal shape, and wherein the bonded areas have a surface area of 10-30% of the total surface area of the sides and the unbonded areas The combined area has a surface area of 70-90% of the total surface area of the sides.
优选地,独立化粘合区域具有非线性形状。在本申请的上下文中,非线性形状被定义为本身不是线性或者不包含一个或多个线性部分的形状。Preferably, the individualized adhesive regions have a non-linear shape. In the context of this application, a non-linear shape is defined as a shape that is not itself linear or does not contain one or more linear parts.
合适地,未粘合区域具有规则的或不规则的六边形形状,其中一个或多个边具有不同的长度。优选地,未粘合区域具有规则的六边形形状。Suitably, the unbonded area has a regular or irregular hexagonal shape with one or more sides of different lengths. Preferably, the unbonded areas have a regular hexagonal shape.
合适地,未粘合区域的表面积在20-50mm2范围内,优选在22-45mm2的范围内,并且更优选在23-40mm2的范围内。Suitably, the surface area of the unbonded region is in the range 20-50 mm 2 , preferably in the range 22-45 mm 2 , and more preferably in the range 23-40 mm 2 .
合适地,非织造网的单位重量在5-80g/m2的范围内,优选在6-50g/m2的范围内,且更优选至少8g/m2且小于40g/m2,甚至更优选在8-30g/m2的范围内。Suitably, the nonwoven web has a basis weight in the range of 5-80 g/m 2 , preferably in the range of 6-50 g/m 2 , and more preferably at least 8 g/m 2 and less than 40 g/m 2 , even more preferably In the range of 8-30g/m2.
合适地,独立化粘合区域具有对称形状,如圆形、菱形、矩形、正方形、椭圆形、三角形、心形、月形、星形、六边形、八边形或其他多边形形状。优选地,粘合区域具有圆形或六边形形状。更优选地,该粘合区域具有圆形形状。Suitably, the individualized adhesive regions have a symmetrical shape, such as a circle, rhombus, rectangle, square, ellipse, triangle, heart, moon, star, hexagon, octagon or other polygonal shape. Preferably, the bonding area has a circular or hexagonal shape. More preferably, the bonding area has a circular shape.
合适地,粘合区域的最大宽度在0.7-1.5mm的范围内,优选在0.75-1.25mm的范围内,且更优选在0.8-1.2mm的范围内。Suitably, the bonded area has a maximum width in the range of 0.7-1.5mm, preferably in the range of 0.75-1.25mm, and more preferably in the range of 0.8-1.2mm.
合适地,粘合区域的表面积在0.38-1.77mm2的范围内,优选在0.44-1.22mm2的范围内,且更优选在0.50-1.13mm2的范围内。合适地,离散的未粘合区域的厚度在0.4-1.5mm的范围内,优选在0.4-0.9mm的范围内,更优选在0.4-0.8mm的范围内,且最优选在0.5-0.7mm的范围内。Suitably, the surface area of the bonding region is in the range of 0.38-1.77 mm 2 , preferably in the range of 0.44-1.22 mm 2 , and more preferably in the range of 0.50-1.13 mm 2 . Suitably, the discrete unbonded areas have a thickness in the range of 0.4-1.5 mm, preferably in the range of 0.4-0.9 mm, more preferably in the range of 0.4-0.8 mm, and most preferably in the range of 0.5-0.7 mm. within range.
合适地,偶数个粘合区域限定单个的未粘合区域。优选地,单个的未粘合区域由6、12、18或24个独立化粘合区域限定,更优选12、18或24个独立化粘合区域,且最优选由12个独立化粘合区域限定。Suitably, an even number of bonded areas defines a single unbonded area. Preferably, a single unbonded area is defined by 6, 12, 18 or 24 individually bonded areas, more preferably 12, 18 or 24 individually bonded areas, and most preferably by 12 individually bonded areas limited.
合适地,根据WSP110.4,本发明的非织造网在MD上的拉伸强度在1-4N每克单位重量的范围内,优选在1.2-3.5N每克单位重量的范围内,且更优选在1.3-3.0N每克单位重量的范围内。具有这种拉伸强度的非织造网提供了具有高拉伸强度的非织造制品。Suitably, according to WSP110.4, the tensile strength of the nonwoven web of the present invention in MD is in the range of 1-4 N per gram unit weight, preferably in the range of 1.2-3.5 N per gram unit weight, and more preferably In the range of 1.3-3.0N per gram unit weight. A nonwoven web with such tensile strength provides a nonwoven article with high tensile strength.
优选地,所述非织造网具有至少8g/m2且小于40g/m2的单位重量,并且所述粘合区域的表面积优选大于所述侧面的总表面积的15%且最多30%。更优选地,该非织造网的单位重量在8-30g/m2的范围内,并且该粘合区域的表面积为所述侧面的总表面积的15-25%。具有这种低单位重量和高粘合区域的非织造网提供了具有改善的柔软性的非织造制品,使其在个人卫生吸收制品的应用中极引人注目。Preferably, the nonwoven web has a basis weight of at least 8 g/ m2 and less than 40 g/m2, and the surface area of the bonded regions is preferably greater than 15% and at most 30% of the total surface area of the sides. More preferably, the basis weight of the nonwoven web is in the range of 8-30 g/m 2 and the surface area of the bonded areas is 15-25% of the total surface area of the sides. Nonwoven webs with such low basis weight and high bonded areas provide nonwoven articles with improved softness, making them attractive for personal hygiene absorbent applications.
更优选地,所述非织造网具有至少8g/m2且小于40g/m2的单位重量;该非织造网的粘合区域的表面积优选大于所述侧面的总表面积的15%且最多30%,并且根据WSP110.4,该非织造网在机器纵向(MD)上的拉伸强度在1-4N每克单位重量的范围内。More preferably, the nonwoven web has a basis weight of at least 8 g/ m2 and less than 40 g/m2; the surface area of the bonded regions of the nonwoven web is preferably greater than 15% and at most 30% of the total surface area of the sides , and according to WSP110.4, the tensile strength of the nonwoven web in the machine direction (MD) is in the range of 1-4N per gram unit weight.
所述WSP测试方法为在非织造工业中国际上公认的测试方法,如本领域技术人员所理解。The WSP test method is an internationally recognized test method in the nonwoven industry, as understood by those skilled in the art.
甚至更优选地,所述非织造网的单位重量在8-30g/m2的范围内,该非织造网的粘合区域的表面积为所述侧面的总表面积的15-25%;并且该非织造网的拉伸强度在1.2-3.5N每克单位重量的范围内。具有这种低单位重量、高粘合面积和高拉伸强度的非织造网提供了具有优异的柔软性和尺寸稳定性的非织造制品。Even more preferably, said nonwoven web has a basis weight in the range of 8-30 g/m 2 , the nonwoven web has a bonded area having a surface area of 15-25% of the total surface area of said sides; The tensile strength of the woven web is in the range of 1.2-3.5 N per gram unit weight. A nonwoven web having such a low basis weight, high bond area, and high tensile strength provides a nonwoven article with excellent softness and dimensional stability.
合适的非织造网可以通过本领域已知的用于制备非织造物的任何方式来制备。Suitable nonwoven webs can be prepared by any means known in the art for making nonwovens.
所述非织造网可以是单层或多层非织造物,其具有例如至少一层纺粘纤维网,所述纺粘纤维网连接到至少一层的熔喷纤维网、梳理纤维网或其他合适材料上。The nonwoven web may be a single layer or multilayer nonwoven having, for example, at least one layer of a spunbond web connected to at least one layer of a meltblown web, a carded web, or other suitable material.
优选地,本发明的非织造织物还包含第二非织造网。Preferably, the nonwoven fabric of the present invention further comprises a second nonwoven web.
所述非织造网可为可延展的、弹性的或非弹性的。所述非织造网可为纺粘纤维网、熔喷纤维网、气流纤维网或梳理纤维网。如果所述非织造网是熔喷纤维网,则其可包括熔喷微纤维。The nonwoven web can be extensible, elastic or inelastic. The nonwoven web can be a spunbond web, a meltblown web, an air-laid web, or a carded web. If the nonwoven web is a meltblown web, it may comprise meltblown microfibers.
非织造网特别合适地由热塑性聚合物(例如,聚烯烃、聚酯、乙烯共聚物、丙烯共聚物、丁烯共聚物及其组合)的纤维制成,但也可包含与热塑性纤维结合的天然纤维(例如,木材、棉花或人造丝)。该非织造网还可为由两种或更多种不同的纤维的混合物或纤维与颗粒的混合物制成的复合材料。Nonwoven webs are particularly suitably made from fibers of thermoplastic polymers (e.g., polyolefins, polyesters, ethylene copolymers, propylene copolymers, butene copolymers, and combinations thereof), but may also contain natural Fibers (for example, wood, cotton or rayon). The nonwoven web may also be a composite material made from a mixture of two or more different fibers or a mixture of fibers and particles.
所述纤维合适地通过粘合连接在一起以形成粘合纤维网结构。合适的粘合技术包括,但不限于,化学粘合和热粘合,例如,热压延或通过热气流的粘合。The fibers are suitably joined together by bonding to form a bonded web structure. Suitable bonding techniques include, but are not limited to, chemical bonding and thermal bonding, eg, thermal calendering or bonding by hot air flow.
多种合适的聚烯烃均可用于本发明。合适的实例包括聚乙烯、聚丙烯、聚丁二烯、聚(乙烯-丁烯)、聚(乙烯-己烯)、聚(乙烯-辛烯)、聚(乙烯-丙烯)嵌段聚合物,例如苯乙烯/异戊二烯/苯乙烯以及苯乙烯/聚丁二烯/苯乙烯。所述聚烯烃可包括均聚物或共聚物,例如丙烯-α-烯烃共聚物。特别地,后者的共聚物可以有利地用于本发明。优选的是包含丙烯-α-烯烃共聚物和丙烯均聚物的聚烯烃材料。A wide variety of suitable polyolefins can be used in the present invention. Suitable examples include polyethylene, polypropylene, polybutadiene, poly(ethylene-butylene), poly(ethylene-hexene), poly(ethylene-octene), poly(ethylene-propylene) block polymers, Examples include styrene/isoprene/styrene and styrene/polybutadiene/styrene. The polyolefins may comprise homopolymers or copolymers, such as propylene-alpha-olefin copolymers. In particular, the latter copolymers can be advantageously used in the present invention. Preferred are polyolefin materials comprising propylene-alpha-olefin copolymers and propylene homopolymers.
合适地,所述聚烯烃材料的熔体流动速率(MFR)小于90dg/min。使用ASTM测试方法D1238,2.16kg测定该MFR。优选地,所述聚烯烃材料的MFR在15-50dg/min的范围内,更优选在15-35dg/min的范围内。Suitably, said polyolefin material has a melt flow rate (MFR) of less than 90 dg/min. The MFR is determined using ASTM test method D1238, 2.16 kg. Preferably, the MFR of the polyolefin material is in the range of 15-50 dg/min, more preferably in the range of 15-35 dg/min.
优选地,所述纤维由聚乙烯均聚物或聚丙烯均聚物、聚乙烯和聚丙烯的共聚物、聚乙烯和聚丙烯的共混物、聚酯、聚酯的共聚物和/或聚酯的共混物形成。Preferably, the fibers are made of polyethylene homopolymer or polypropylene homopolymer, copolymers of polyethylene and polypropylene, blends of polyethylene and polypropylene, polyester, copolymers of polyester and/or poly A blend of esters is formed.
适合使用的是丙烯基或乙烯基均聚物或共聚物。在丙烯基聚合物的情况下,该聚合物可包含选自乙烯和C4-C10α-烯烃的共聚单体衍生的单元。在乙烯基聚合物的情况下,该聚合物可包含选自C3-C10α-烯烃的共聚单体衍生的单元。合适的聚烯烃材料的实例包括丙烯均聚物、乙烯均聚物、丙烯共聚物以及乙烯共聚物,例如,线性低密度聚乙烯(LLDPE)、高密度聚乙烯(HDPE)和低密度聚乙烯(LDPE)。Suitable for use are propylene or vinyl homopolymers or copolymers. In the case of propylene-based polymers, the polymer may comprise comonomer-derived units selected from ethylene and C4-C10 alpha-olefins. In the case of vinyl polymers, the polymer may comprise comonomer-derived units selected from C3-C10 alpha-olefins. Examples of suitable polyolefin materials include propylene homopolymers, ethylene homopolymers, propylene copolymers and ethylene copolymers, for example, linear low density polyethylene (LLDPE), high density polyethylene (HDPE) and low density polyethylene ( LDPE).
合适的聚酯可为脂族聚酯如聚乳酸,或者芳族聚酯如聚对苯二甲酸乙二醇酯(PET)和聚(对苯二甲酸丙二醇酯)(PTT)。Suitable polyesters may be aliphatic polyesters such as polylactic acid, or aromatic polyesters such as polyethylene terephthalate (PET) and poly(trimethylene terephthalate) (PTT).
除了已包含在所用的聚合物中的添加剂外,可添加其他的添加剂来向所述纤维提供额外的特性。合适的其他添加剂包括热稳定剂、光稳定剂、增滑添加剂、蜡类以及会使所述织物亲水或疏水的添加剂。添加填料材料有时也可为有利的。合适的填料材料包括有机填料材料和无机填料材料。合适的无机填料材料的实例包括矿物质(例如碳酸钙)、金属(例如铝)和不锈钢。合适的有机填料材料的实例包括基于糖的聚合物。In addition to the additives already contained in the polymer used, other additives may be added to provide additional properties to the fibers. Suitable other additives include heat stabilizers, light stabilizers, slip additives, waxes, and additives that render the fabric hydrophilic or hydrophobic. The addition of filler materials may also sometimes be advantageous. Suitable filler materials include organic filler materials and inorganic filler materials. Examples of suitable inorganic filler materials include minerals such as calcium carbonate, metals such as aluminum, and stainless steel. Examples of suitable organic filler materials include sugar-based polymers.
各种纤维截面均是可能的。一般而言,优选圆形的纤维截面,但也可有利地使用三叶形或多叶形的纤维。其他合适的纤维截面包括三角形截面、骨形截面、月形截面、空心纤维截面和带状截面。Various fiber cross-sections are possible. In general, circular fiber cross-sections are preferred, but trilobal or multilobal fibers can also advantageously be used. Other suitable fiber cross-sections include triangular cross-sections, bone-shaped cross-sections, moon-shaped cross-sections, hollow fiber cross-sections, and ribbon-shaped cross-sections.
制成所述非织造网的纤维可合适地为单组分纤维或多组分纤维(例如双组分纤维)。合适的多组分纤维的实例包括对称的和偏心的芯/壳纤维、A/B或A/B/A结构的并列型纤维、橘瓣型纤维、海岛纤维和条纹纤维。优选的是其中两种组分以对称的芯-壳方式排列或者以并列的方式排列的双组分纤维。最优选的为包含聚乙烯和聚丙烯的芯-壳双组分纤维,但是其他合适的聚合物的任何其他的组合也可以,例如聚酯与聚烯烃的组合。一般而言,对于芯-壳纤维,所述芯包含具有较高熔点的组分而所述壳包含具有较低熔点的组分,但使其为颠倒的方式可以是有利的。在一个优选的实施方案中,所述双组分纤维具有聚丙烯的芯和聚乙烯的壳。在优选的实施方案中,所述双组分纤维包含在芯中的10重量%至90重量%的较高熔点的组分和在壳中的90重量%至10重量%的较低熔点的组分。最优选地,该双组分纤维具有在芯中的30重量%至70重量%的较高熔点的组分。该双组分纤维可含有不同类型的聚丙烯。更优选地,该双组分纤维具有聚丙烯(具有较高熔点)的芯和聚丙烯(具有较低熔点)的壳。在另一个优选的实施方案中,并列型双组分纤维包含两种熔体温度和熔体流动速率不同的聚丙烯。The fibers from which the nonwoven web is made may suitably be monocomponent fibers or multicomponent fibers (eg, bicomponent fibers). Examples of suitable multicomponent fibers include symmetric and eccentric core/shell fibers, A/B or A/B/A structured side-by-side fibers, segmented pie fibers, islands-in-the-sea fibers, and striped fibers. Preference is given to bicomponent fibers in which the two components are arranged in a symmetrical core-sheath fashion or in a side-by-side fashion. Most preferred are core-sheath bicomponent fibers comprising polyethylene and polypropylene, but any other combination of other suitable polymers is also possible, such as combinations of polyesters with polyolefins. Generally, for core-sheath fibers, the core contains a component with a higher melting point and the sheath contains a component with a lower melting point, but it may be advantageous to have it reversed. In a preferred embodiment, the bicomponent fibers have a core of polypropylene and a sheath of polyethylene. In a preferred embodiment, the bicomponent fiber comprises 10% to 90% by weight of the higher melting point component in the core and 90% to 10% by weight of the lower melting point component in the sheath. point. Most preferably, the bicomponent fiber has 30% to 70% by weight of the higher melting point component in the core. The bicomponent fibers may contain different types of polypropylene. More preferably, the bicomponent fiber has a core of polypropylene (with a higher melting point) and a sheath of polypropylene (with a lower melting point). In another preferred embodiment, the side-by-side bicomponent fibers comprise two polypropylenes having different melt temperatures and melt flow rates.
所述纤维可根据本领域中已知的纺纱工艺制成。最普遍采用的是纺粘工艺和熔喷工艺,通过以上两种工艺可直接形成非织造织物。The fibers can be produced according to spinning processes known in the art. The most commonly used are the spunbond process and the meltblown process, through which nonwoven fabrics can be directly formed.
纺粘纤维通常是通过将熔融聚合物从每线性米(linearmeter)具有几千个孔的大型纺丝板或者从多排较小纺丝板(例如,含有少至40个孔)挤出而制备。在离开纺丝板之后,将熔融纤维通过横流空气骤冷系统进行骤冷,然后将其拉离纺丝板并通过高速气流细化。在透气性传送带上进行长丝的沉积以产生非织造层。纺粘纤维通常是连续的且纤维直径的范围约在10-100μm之间。Spunbond fibers are typically produced by extruding molten polymer from a large spinneret with several thousand holes per linear meter or from rows of smaller spinnerettes (eg, containing as few as 40 holes) . After exiting the spinneret, the molten fibers are quenched through a cross-flow air quenching system before being drawn off the spinneret and attenuated by a high velocity air stream. Deposition of the filaments is carried out on an air permeable conveyor belt to produce a nonwoven layer. Spunbond fibers are generally continuous and have a fiber diameter in the range of about 10-100 μm.
另一方面,熔喷纤维的直径一般要小的多且通常在0.5-10μm之间。此外,熔喷纤维被认为是大体上不连续的。Meltblown fibers, on the other hand, are generally much smaller in diameter and typically between 0.5-10 μm. Furthermore, meltblown fibers are considered to be substantially discontinuous.
熔喷工艺是通过以下方式来形成纤维的一种工艺:将熔融的热塑性材料通过多个细小、通常为圆形的模头细管以熔融的纱线或长丝的形式挤出至高速、通常为加热的气流中,该气流将熔融的热塑性材料的长丝拉细以降低其直径。所述熔喷工艺通常具有横跨模头宽度的单排长丝的长丝。因此,所述熔喷纤维由高速气流携带并沉积在收集表面上,从而形成无规则分散的熔喷纤维的网。熔喷纤维可为连续或不连续的微纤维。The melt blowing process is a process for forming fibers by extruding molten thermoplastic material in the form of molten yarn or filament through multiple small, usually circular die tubes to high speed, usually A heated gas stream that attenuates filaments of molten thermoplastic material to reduce their diameter. The meltblowing process typically has filaments in a single row of filaments across the width of the die. Thus, the meltblown fibers are carried by the high velocity air stream and deposited on a collecting surface, thereby forming a web of randomly dispersed meltblown fibers. Meltblown fibers can be continuous or discontinuous microfibers.
本发明的非织造织物还可进行其他处理以增加特定的特性。最常见的是局部处理,以使所述织物亲水或使其疏水。最常见的是用亲水性表面活性剂或者用碳氟化合物或硅材料对该织物进行处理。在本发明的上下文中,当置于非织造织物或非织造网表面的水的接触角小于约90时,则该非织造织物或非织造网的表面是“亲水的”,而当置于非织造织物或非织造网表面的水的接触角大于或等于90时,则该非织造织物或非织造网的表面是“疏水的”。The nonwoven fabrics of the present invention may also be subjected to other treatments to add specific properties. Most common are topical treatments to render the fabric hydrophilic or to render it hydrophobic. Most commonly the fabric is treated with a hydrophilic surfactant or with a fluorocarbon or silicon material. In the context of the present invention, a nonwoven fabric or nonwoven web surface is "hydrophilic" when the contact angle of water placed on the surface of the nonwoven fabric or nonwoven web is less than about 90°, and when placed on the surface A surface of a nonwoven fabric or nonwoven web is "hydrophobic" when the contact angle of water on the surface of the nonwoven fabric or nonwoven web is greater than or equal to 90°.
优选地,本发明的非织造织物为疏水的非织造织物。Preferably, the nonwoven fabric of the present invention is a hydrophobic nonwoven fabric.
本发明的非织造织物可仅由一种类型的纤维或纤维层(例如纺粘层)组成,但是其还可合适地包含额外的可不同的纤维层。合适的多层织物,例如,可包括一层或多层纺粘层(S)以及一层或多层熔喷层(M),如SMS、SMMS、SSMMS等,其彼此粘附形成本发明的非织造织物。通常,这些多层织物以一个步骤在具有多个织轴的单线上制成,所述多个织轴通常包括纺粘织轴和熔喷织轴的组合。在一些情况下,以两个或更多个独立的步骤来制备本发明的多层可能是有利的或技术上需要的。The nonwoven fabric of the present invention may consist of only one type of fiber or fiber layer (for example a spunbond layer), but it may also suitably contain additional, possibly different, fiber layers. Suitable multilayer fabrics, for example, may include one or more spunbond layers (S) and one or more meltblown layers (M), such as SMS, SMMS, SSMMS, etc., adhered to each other to form the fabric of the present invention. non-woven fabric. Typically, these multilayer fabrics are made in one step on a single wire with multiple beams, often including a combination of spunbond and meltblown beams. In some cases it may be advantageous or technically necessary to prepare the multilayers of the invention in two or more separate steps.
也可使用具有不同的纤维横截面或具有不同的纤维类型的纺粘层。例如,也可将一层三叶形长丝与一层圆形纤维组合,或者将芯-壳双组分层与并列型双组分层组合。Spunbond layers with different fiber cross-sections or with different fiber types can also be used. For example, it is also possible to combine a layer of trilobal filaments with a layer of round fibers, or a core-sheath bicomponent layer with a side-by-side bicomponent layer.
纺粘层与天然纤维的组合也是可能的。优选地,根据本发明所使用的额外的非织造网由熔喷纤维制成。Combinations of spunbond layers with natural fibers are also possible. Preferably, the additional nonwoven web used according to the invention is made of meltblown fibres.
本发明的非织造织物可由一个或多个单层组成,所述非织造织物的单位重量可合适地在5-80g/m2的范围内,优选在6-50g/m2的范围内,且更优选至少8g/m2且小于40g/m2,甚至更优选在8-30g/m2的范围内。The nonwoven fabric of the present invention may consist of one or more single layers, the basis weight of said nonwoven fabric may suitably be in the range of 5-80 g/m 2 , preferably in the range of 6-50 g/m 2 , and More preferably at least 8 g/m 2 and less than 40 g/m 2 , even more preferably in the range of 8-30 g/m 2 .
合适地,根据本发明所使用的非织造网包含至多40重量%的熔喷纤维,基于该非织造网的总重量计。优选地,所述非织造网包含至多30重量%的熔喷纤维,更优选20-30重量%的熔喷纤维,基于该非织造网的总重量计。Suitably, the nonwoven web used according to the invention comprises up to 40% by weight of meltblown fibers, based on the total weight of the nonwoven web. Preferably, the nonwoven web comprises up to 30% by weight of meltblown fibers, more preferably 20-30% by weight of meltblown fibers, based on the total weight of the nonwoven web.
合适地,本发明的非织造网仅包含熔喷纤维,而非熔喷纤维与另一种类型纤维的混合物。Suitably, the nonwoven webs of the present invention comprise meltblown fibers only, not a mixture of meltblown fibers and another type of fiber.
本发明还涉及包含本发明的非织造织物的卫生吸收制品。The present invention also relates to hygienic absorbent articles comprising the nonwoven according to the invention.
合适地,本发明的卫生吸收制品为选自失禁制品、尿布、擦拭物和妇女护理制品的一次性卫生吸收制品。本发明的合适的一次性卫生吸收制品包括选自以下的一次性卫生吸收制品:婴儿尿布、拉拉裤(pull-ups)、训练裤、卫生封闭系统、成人失禁用贴身短内裤和尿布、卫生护垫、卫生巾、医用服装以及绷带。合适的擦拭物可包含用于卫生目的的湿擦拭物或干擦拭物。Suitably, the hygienic absorbent article of the present invention is a disposable hygienic absorbent article selected from incontinence articles, diapers, wipes and feminine care articles. Suitable disposable hygienic absorbent articles of the present invention include disposable hygienic absorbent articles selected from the group consisting of baby diapers, pull-ups, training pants, hygienic closure systems, adult incontinence briefs and diapers, hygienic Pads, sanitary napkins, medical clothing, and bandages. Suitable wipes may comprise wet wipes or dry wipes for hygiene purposes.
一次性卫生吸收制品是不旨在清洗或恢复或重新用作卫生吸收制品的卫生吸收制品。通常,这种吸收制品包括背片、顶片以及置于顶片和背片之间的吸收芯。所述背片具有完整接合区或者其本身用作接合区,并且包含置于吸收制品最外层并防止液体透过卫生吸收制品的非织造网,而穿用者下体的排出物将透过顶片并且被吸收芯吸收。顶片的额外功能是提供皮肤舒适感。Disposable hygienic absorbent articles are hygienic absorbent articles which are not intended to be laundered or restored or reused as hygienic absorbent articles. Typically, such absorbent articles comprise a backsheet, a topsheet and an absorbent core disposed between the topsheet and the backsheet. The backsheet has an integral joining zone or serves as a joining zone itself, and comprises a nonwoven web that is positioned as the outermost layer of the absorbent article and prevents liquids from penetrating the hygienic absorbent article, while exudates from the lower body of the wearer will pass through the top surface. sheet and is absorbed by the absorbent core. An additional function of the topsheet is to provide skin comfort.
此外,一次性卫生吸收制品通常包括钩或环紧固系统,以便使该一次性卫生吸收制品围绕穿用者的下体紧固。当用作用于一次性个人护理卫生吸收制品的环紧固系统或钩紧固系统时,本发明的非织造织物可作为环圈材料的离散片而被粘合或附着到该制品的外层或背片上。或者,本发明的非织造织物可形成这种一次性个人护理卫生吸收制品的整个外层或背片并且用作接合区。所述钩或环紧固系统可为各种市售可得的钩或环紧固系统中的任一种。In addition, disposable sanitary absorbent articles typically include a hook or loop fastening system for fastening the disposable sanitary absorbent article around the lower torso of the wearer. When used as a loop fastening system or a hook fastening system for a disposable personal care hygiene absorbent article, the nonwoven fabric of the present invention may be bonded or attached to the outer layer or the outer layer of the article as discrete pieces of loop material. on the back. Alternatively, the nonwoven fabric of the present invention may form the entire outer layer or backsheet of such disposable personal care hygiene absorbent articles and serve as a land. The hook or loop fastening system may be any of a variety of commercially available hook or loop fastening systems.
本发明的非织造织物可合适地为顶片、背片、接合区和/或环紧固构件的一部分。优选地,本发明的非织造织物为背片和/或接合区的一部分。The nonwoven fabric of the present invention may suitably be part of the topsheet, backsheet, lands and/or loop fastening members. Preferably, the nonwoven fabric of the present invention is part of the backsheet and/or the lands.
本发明还涉及用于形成本发明的非织造织物的方法。The present invention also relates to methods for forming the nonwoven fabrics of the present invention.
因此,本发明还涉及用于形成非织造织物的方法,其包括以下步骤:Accordingly, the present invention also relates to a method for forming a nonwoven fabric comprising the steps of:
(a)形成非织造网;以及(a) forming a nonwoven web; and
(b)将该非织造网提供至相对放置的第一辊和第二辊之间所限定的辊隙中,由此至少一个辊具有图案化外表面,以便将粘合图案施加到第一非织造网上,由此该粘合图案包含如上文所定义的第一图案和第二图案。(b) providing the nonwoven web to a nip defined between opposed first and second rolls, whereby at least one roll has a patterned outer surface for applying a bonding pattern to the first nonwoven web. The web is woven whereby the bonding pattern comprises a first pattern and a second pattern as defined above.
本发明还涉及用于形成本发明的非织造织物的方法,其包括以下步骤:The present invention also relates to a method for forming the nonwoven fabric of the present invention comprising the steps of:
(a)形成第一非织造网;(a) forming a first nonwoven web;
(b)形成第二非织造网;(b) forming a second nonwoven web;
(c)将所述第一非织造网和第二非织造网提供至相对放置的第一辊和第二辊之间所限定的辊隙中,由此至少一个辊具有图案化外表面,以便施加包含如上文所定义的第一图案和第二图案的粘合图案;以及(c) providing said first nonwoven web and second nonwoven web into a nip defined between opposed first and second rolls, whereby at least one roll has a patterned outer surface, such that applying a bonding pattern comprising a first pattern and a second pattern as defined above; and
(d)将第一非织造网和第二非织造网粘合在一起,以形成非织造织物。(d) Bonding the first nonwoven web and the second nonwoven web together to form a nonwoven fabric.
或者,在将所形成的非织造织物提供至由辊形成的辊隙内之前,可将第一非织造网和第二非织造网预粘合。Alternatively, the first nonwoven web and the second nonwoven web may be prebonded before the formed nonwoven web is provided into a nip formed by rolls.
因此,本发明也涉及用于形成本发明的非织造织物的方法,其包括以下步骤:Accordingly, the present invention also relates to a method for forming the nonwoven fabric of the present invention comprising the steps of:
(a)形成第一非织造网;(a) forming a first nonwoven web;
(b)形成第二非织造网;(b) forming a second nonwoven web;
(c)将所述第一非织造网和第二非织造网粘合在一起以形成非织造织物;以及(c) bonding the first nonwoven web and the second nonwoven web together to form a nonwoven fabric; and
(d)将在步骤(c)中形成的非织造织物提供至相对放置的第一辊和第二辊之间所限定的辊隙中,由此至少一个辊具有图案化外表面,以便将粘合图案施加到第一非织造网上,由此该粘合图案包含如上文所限定的第一和第二图案;以及(d) providing the nonwoven fabric formed in step (c) into a nip defined between opposed first and second rolls, whereby at least one roll has a patterned outer surface so that the adhesive A bonding pattern is applied to the first nonwoven web, whereby the bonding pattern comprises first and second patterns as defined above; and
(e)回收所述非织造织物。(e) Recycling the nonwoven fabric.
在本发明的方法中使用的辊合适地为正圆柱体,其可由任何合适的、耐用的材料制成。这种辊将以本领域中已知的方式来进行操作。The rollers used in the method of the invention are suitably right cylinders, which may be made of any suitable, durable material. Such rollers will be operated in a manner known in the art.
相对放置的辊的位置可以适当地进行调整以在两个辊之间形成辊隙。根据待加工的一种或多种非织造网的特性,辊隙间的辊隙压力可以适当地进行调整。同样的情况也适用于压延辊所必须的温度,该温度需要根据所需的最终特性和待粘合的纤维的种类来调整。The positions of the opposed rollers may be appropriately adjusted to form a nip between the two rollers. Depending on the properties of the nonwoven web or webs to be processed, the nip pressure between the nips can be appropriately adjusted. The same applies to the temperature necessary for the calender rolls, which needs to be adjusted according to the desired final properties and the type of fibers to be bonded.
粘合区域合适地由熔融的方式通过控制至少一个辊的温度来形成。至少一个辊的外表面的温度可通过对该辊加热或冷却来进行调节。加热和冷却可影响正在加工的网的特征以及正在通过各个辊之间所形成的辊隙的单个或多个网的粘合程度。The bonded area is suitably formed by melting by controlling the temperature of at least one roller. The temperature of the outer surface of at least one roller can be adjusted by heating or cooling the roller. Heating and cooling can affect the characteristics of the web being processed and the degree of bonding of a single or multiple webs passing through the nip formed between the individual rolls.
一个待用的辊在其最外层的表面含有粘合图案,该最外层的表面包含限定多个离散的开孔、孔隙或洞的接合区域的连续图案。一个或多个辊中的各个开孔将在非织造织物或非织造网的至少一个侧面上形成离散的未粘合区域。另一个辊将合适地具有比其他的辊更平滑的外表面。优选地,另一个辊的外表面是平滑的或平坦的。各个辊的旋转速度基本上相同。A roll ready for use contains an adhesive pattern on its outermost surface comprising a continuous pattern of bonded areas defining a plurality of discrete openings, voids or holes. Each opening in the one or more rolls will form a discrete unbonded area on at least one side of the nonwoven fabric or nonwoven web. The other roller will suitably have a smoother outer surface than the other rollers. Preferably, the outer surface of the other roller is smooth or flat. The rotational speeds of the respective rollers are substantially the same.
下文将通过非限制性附图来进一步说明本发明。The invention will be further illustrated below by means of the non-limiting figures.
在图1中,非织造织物的侧面显示出具有粘合图案,其包含本发明的第一和第二图案。独立化粘合区域1的第一图案限定了未粘合区域2的第二图案。独立化粘合区域1为圆形且未粘合区域2为六边形形状。In Figure 1, the side of the nonwoven fabric is shown with a bond pattern comprising the first and second patterns of the present invention. The first pattern of individualized bonded areas 1 defines a second pattern of unbonded areas 2 . The individualized bonded areas 1 are circular and the unbonded areas 2 are hexagonal in shape.
实施例Example
根据本发明制备出许多非织造织物。另外,还制备出许多落在本发明范围之外的对比非织造织物。A number of nonwoven fabrics have been prepared in accordance with the present invention. In addition, a number of comparative nonwoven fabrics were prepared which fell outside the scope of the present invention.
所述非织造织物均由聚丙烯以熔融纺丝工艺在Reicofil机器上制成。所述聚丙烯具有25g/10min(在230℃下,2.16kg)的熔体流动速率,并且在230-235℃下加工聚丙烯。在170kg/hr/m的通过量(throughput)下进行纺丝。通过纺丝喷嘴挤出熔体,再将其拉伸、骤冷并且铺设于传送带上。设置线速度以获得相应的单位重量。随后使膨松的纤维通过加热的压延机进行固化。The nonwovens were all made from polypropylene in a melt spinning process on a Reicofil machine. The polypropylene has a melt flow rate of 25 g/10 min (2.16 kg at 230°C), and the polypropylene is processed at 230-235°C. Spinning was performed at a throughput of 170 kg/hr/m. The melt is extruded through a spinning nozzle, drawn, quenched and laid down on a conveyor belt. Set the line speed to obtain the corresponding unit weight. The bulky fibers are then cured by passing them through a heated calender.
本发明的包含具有六边形形状的未粘合区域的非织造织物具有以下特征:粘合区域:17.6%;每cm2的形状的数量:24.8;粘合点的表面积:圆形粘合点的尺寸:0.97mm(直径);以及六边形形状的边与边(side-to-side)的距离:4.8mm。The nonwoven fabric of the present invention comprising unbonded areas with hexagonal shapes has the following characteristics: bonded area: 17.6%; number of shapes per cm 2 : 24.8; surface area of bonded points: circular bonded points Dimensions: 0.97mm (diameter); and side-to-side distance of the hexagonal shape: 4.8mm.
对比非织造织物具有常规的椭圆形形状的粘合区域,其具有以下特征:粘合区域:18.1%;每cm2的形状的数量:49.9;粘合点的表面积:0.363mm2;粘合点的尺寸:0.882×0.524mm。The comparative nonwoven fabric had a conventional oval shaped bonded area with the following characteristics: bonded area: 18.1%; number of shapes per cm 2 : 49.9; surface area of bonded points: 0.363 mm 2 ; bonded points Dimensions: 0.882×0.524mm.
使用WSP110.4作为测试方法来测定在机器纵向(MD)上的拉伸强度(N/5cm),而在织物手感测定仪(Handle-O-Meter)测试中使用WSP90.3。这些测试在非织造工业中都是已知的标准方法。WSP110.4 was used as the test method to determine the tensile strength (N/5 cm) in the machine direction (MD) while WSP90.3 was used in the Handle-O-Meter test. These tests are all known standard methods in the nonwoven industry.
在表1中,示出了具有不断增加单位重量(gsm)的各种非织造织物的这些测试的结果。In Table 1 the results of these tests are shown for various nonwoven fabrics with increasing basis weights (gsm).
表1Table 1
从表1中可以看出,随着单位重量的增加,拉伸强度和硬度增加。然而,具有常规的椭圆形粘合区域的织物显示出在硬度方面比具有六边形形状未粘合区域的非织造织物增加更多。但是,拉伸强度基本上保持相同。例如,具有六边形形状的50gsm织物提供了149N/5cm的拉伸强度,而具有椭圆形形状的50gsm织物提供了160N/5cm的拉伸强度。后者拉升强度仅有不到10%的提高,而同时硬度却比前者高两倍以上(六边形:420mN而椭圆形:870mN)。为了达到420mN的相似柔软性,该椭圆形图案粘合织物的单位重量必须降低至约35gsm。当降低单位重量时,鉴于液体的吸收和保持能力会降低,这是不希望的。显然在相同的柔软性水平下,该常规的椭圆形粘合织物显示出低得多的拉伸强度。这使得该常规的椭圆形粘合织物在卫生吸收制品的应用中不具备吸引力。It can be seen from Table 1 that the tensile strength and hardness increase with the increase of unit weight. However, the fabric with conventional elliptical bonded areas showed a greater increase in stiffness than the nonwoven with hexagonal shaped unbonded areas. However, the tensile strength remained essentially the same. For example, a 50 gsm fabric with a hexagonal shape provides a tensile strength of 149 N/5 cm, while a 50 gsm fabric with an oval shape provides a tensile strength of 160 N/5 cm. The tensile strength of the latter is only increased by less than 10%, while the hardness is more than twice that of the former (hexagon: 420mN and ellipse: 870mN). To achieve a similar softness of 420 mN, the basis weight of the oval pattern bonded fabric had to be reduced to about 35 gsm. This is undesirable in view of the reduced liquid absorption and retention capacity when the basis weight is reduced. Apparently at the same level of softness, the conventional oval bonded fabric exhibits a much lower tensile strength. This makes the conventional oval bonded fabric unattractive for use in hygienic absorbent articles.
这些数据说明高柔软性(低硬度)和高拉伸强度并非相互排斥,并且可以集合在一起以利于所得的材料。因此,本发明的非织造织物在与穿用者的皮肤直接接触的个人卫生吸收制品的应用中更引人关注。These data demonstrate that high softness (low stiffness) and high tensile strength are not mutually exclusive and can come together to benefit the resulting material. Therefore, the nonwoven fabric of the present invention is more attractive in the application of personal hygiene absorbent articles which are in direct contact with the wearer's skin.
Claims (18)
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP13174693.5 | 2013-07-02 | ||
| EP13174693.5A EP2821043A1 (en) | 2013-07-02 | 2013-07-02 | Non-woven fabric and process for forming the same |
| EP14161870 | 2014-03-27 | ||
| EP14161870.2 | 2014-03-27 | ||
| PCT/EP2014/063474 WO2015000774A1 (en) | 2013-07-02 | 2014-06-26 | Non-woven fabric and process for forming the same |
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| Publication Number | Publication Date |
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| CN105358111A true CN105358111A (en) | 2016-02-24 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201480038130.2A Pending CN105358111A (en) | 2013-07-02 | 2014-06-26 | Non-woven fabric and process for forming the same |
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| Country | Link |
|---|---|
| US (1) | US20160362825A1 (en) |
| EP (1) | EP3016625B1 (en) |
| JP (1) | JP6239746B2 (en) |
| CN (1) | CN105358111A (en) |
| BR (1) | BR112015032760A2 (en) |
| DK (1) | DK3016625T3 (en) |
| ES (1) | ES2653574T3 (en) |
| MX (1) | MX2015016580A (en) |
| PE (1) | PE20160110A1 (en) |
| PL (1) | PL3016625T3 (en) |
| WO (1) | WO2015000774A1 (en) |
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| MX2019007013A (en) * | 2016-12-14 | 2019-10-15 | Pfnonwovens Llc | Hydraulically treated nonwoven fabrics and method of making the same. |
| US11560658B2 (en) * | 2017-08-16 | 2023-01-24 | Kimberly-Clark Worldwide, Inc. | Method of making a nonwoven web |
| CN112912046B (en) * | 2018-09-27 | 2023-01-31 | 宝洁公司 | Nonwoven web having visually discernable pattern |
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| EP3941409A1 (en) * | 2019-03-21 | 2022-01-26 | The Procter & Gamble Company | Absorbent articles having discontinuous bond patterns |
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Also Published As
| Publication number | Publication date |
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| MX2015016580A (en) | 2016-05-26 |
| EP3016625B1 (en) | 2017-07-26 |
| JP6239746B2 (en) | 2017-11-29 |
| PL3016625T3 (en) | 2017-12-29 |
| US20160362825A1 (en) | 2016-12-15 |
| WO2015000774A1 (en) | 2015-01-08 |
| BR112015032760A2 (en) | 2017-07-25 |
| EP3016625A1 (en) | 2016-05-11 |
| PE20160110A1 (en) | 2016-02-28 |
| ES2653574T3 (en) | 2018-02-07 |
| DK3016625T3 (en) | 2017-10-23 |
| JP2016528954A (en) | 2016-09-23 |
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