CN105274832A - Preparation method for nanosilver spunlace non-woven fabrics - Google Patents
Preparation method for nanosilver spunlace non-woven fabrics Download PDFInfo
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- CN105274832A CN105274832A CN201510155332.1A CN201510155332A CN105274832A CN 105274832 A CN105274832 A CN 105274832A CN 201510155332 A CN201510155332 A CN 201510155332A CN 105274832 A CN105274832 A CN 105274832A
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- Prior art keywords
- spunlace non
- woven cloth
- nano silver
- padding
- preparation
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- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 title claims abstract description 80
- 238000002360 preparation method Methods 0.000 title claims abstract description 21
- 239000004745 nonwoven fabric Substances 0.000 title abstract description 9
- 238000000034 method Methods 0.000 claims abstract description 35
- 238000001035 drying Methods 0.000 claims abstract description 14
- 239000011347 resin Substances 0.000 claims abstract description 10
- 229920005989 resin Polymers 0.000 claims abstract description 10
- 238000012545 processing Methods 0.000 claims abstract description 9
- 239000004744 fabric Substances 0.000 claims description 56
- 230000008569 process Effects 0.000 claims description 30
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 15
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical group [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims description 14
- 229910000077 silane Inorganic materials 0.000 claims description 14
- 239000003292 glue Substances 0.000 claims description 9
- 239000007822 coupling agent Substances 0.000 claims description 6
- 239000007788 liquid Substances 0.000 claims description 6
- 239000002245 particle Substances 0.000 abstract description 18
- 230000000844 anti-bacterial effect Effects 0.000 abstract description 17
- 238000004519 manufacturing process Methods 0.000 abstract description 7
- 239000000243 solution Substances 0.000 abstract 3
- 239000011259 mixed solution Substances 0.000 abstract 2
- 239000006087 Silane Coupling Agent Substances 0.000 abstract 1
- 239000000853 adhesive Substances 0.000 abstract 1
- 230000001070 adhesive effect Effects 0.000 abstract 1
- 239000007864 aqueous solution Substances 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 238000003756 stirring Methods 0.000 abstract 1
- 239000000463 material Substances 0.000 description 5
- 230000000845 anti-microbial effect Effects 0.000 description 4
- 230000003115 biocidal effect Effects 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 239000004599 antimicrobial Substances 0.000 description 3
- 239000013558 reference substance Substances 0.000 description 3
- 229910052709 silver Inorganic materials 0.000 description 3
- 239000004332 silver Substances 0.000 description 3
- 241000191967 Staphylococcus aureus Species 0.000 description 2
- 230000002421 anti-septic effect Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000011017 operating method Methods 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 206010059866 Drug resistance Diseases 0.000 description 1
- 238000005054 agglomeration Methods 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- 239000003242 anti bacterial agent Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 230000003750 conditioning effect Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 230000008447 perception Effects 0.000 description 1
- 230000002688 persistence Effects 0.000 description 1
- 230000003389 potentiating effect Effects 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 230000001954 sterilising effect Effects 0.000 description 1
- 238000004659 sterilization and disinfection Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 238000009941 weaving Methods 0.000 description 1
Landscapes
- Chemical Or Physical Treatment Of Fibers (AREA)
Abstract
The invention discloses a preparation method for nanosilver spunlace non-woven fabrics. The method comprises the following steps: by weight, firstly, 1 part of nanosilver aqueous solution with 2000-5000ppm is weighed and dissolved in 10 parts of silane coupling agent, and a mixed solution is formed after full stirring; secondly, 1-2 parts of resin adhesive is weighed and added into the mixed solution, the mixture is stirred fully and a dip padding solution is prepared; thirdly, spunlace non-woven fabrics are subjected to dip padding processing in the dip padding solution; fourthly, the spunlace non-woven fabrics after dip padding are subjected to drying processing, and a finished product is obtained. The method is advantageous in that during preparation, nanosilver particles cannot aggregate and are dispersed in the solution fully and uniformly, furthermore the nanosilver particles are distributed uniformly on the spunlace non-woven fabrics after dip padding processing, and product antibacterial effects are ensured; the preparation steps are simple and convenient, and the production cost is lowered.
Description
Technical field
The present invention relates to antibacterial nonwoven cloth made production technical field, particularly a kind of preparation method of nano silver spunlace non-woven cloth.
Background technology
Along with the raising of people's living standard, self-health perception day by day strengthens, especially also more and more higher to the antibacterial requirement of living-hygienic goods.Nano Silver is a class antibacterial agent, and have the antibacterial activity of powerful antibacterial, bactericidal action and wide spectrum, persistence is good, has no drug resistance and security is high, is widely used in the fields such as weaving, coating, medical treatment, environmental protection.
The method preparing nanometer silver antimicrobial nonwoven fabric generally adopted at present is: by the technique of Final finishing, arranged by nano silver antimicrobials on nonwoven fabric, make it have antibacterial activity.Above-mentioned preparation method effectively can control the relevant parameter of nano silver antimicrobials, easily meets different antibacterial requirement.But the antiseptic of most manufacturer production is chemical powder body material in prior art, its bacteriostasis rate and sterilizing rate effect unsatisfactory.Due in process of production, the surface area of antimicrobial powder material and surface energy are very large, easily mutually adsorb and reunite, and also the stable meeting of maintenance is very difficult to make the antiseptic occurring to reunite effectively be evenly dispersed in solvent, reunite and disperseed uneven nano silver antimicrobials that nonwoven surface antibacterial effect can be made uneven, even local loses antibacterial action, has a strong impact on product quality.
Summary of the invention
Goal of the invention: for the problems referred to above, the object of this invention is to provide a kind of preparation method of nano silver spunlace non-woven cloth, there is not agglomeration in nano silver particles, and dispersed, ensures product antibacterial effect, reduces production cost simultaneously.
Technical scheme: a kind of preparation method of nano silver spunlace non-woven cloth, with mass ratio range, comprises the steps:
Step one: take 1 part of nano-silver water solution and 10 parts of coupling agents, be dissolved in by nano-silver water solution in coupling agent, after being fully uniformly mixed, forms Nano Silver mixed liquor;
Step 2: take 1-2 part resin glue, then adds in the described Nano Silver mixed liquor formed in step one, after being fully uniformly mixed, forms leach mill solution;
Step 3: the padding machine work nest described leach mill solution formed in step 2 being injected padder, then immerses padding machine work nest by spunlace non-woven cloth, carries out padding process process;
Step 4: take out the spunlace non-woven cloth after padding in step 3, carry out drying and processing, bake out temperature 70-90 DEG C, drying time 3-4h, the soft degree of the spunlace non-woven cloth after oven dry is equal to knitted cloth, is nano silver spunlace non-woven cloth finished product.
Further, in described step one, the Nano Silver concentration of nano-silver water solution is 2000-5000ppm.
Further, the coupling agent in described step one is silane coupler.
Further, in the padding process process of described step 3, padding machine pressure is 5-7MPa.
Further, the spunlace non-woven cloth after the padding process process in described step 3 treats that liquid rate is 50-80%.
In described preparation method, nano-silver water solution, silane coupler and resin glue is fully mixed with in leach mill solution, resin glue can improve the viscosity of leach mill solution, reduce nano silver particles mobility in the solution, prevent nano silver particles from reuniting, make it dispersed in the solution, and be evenly distributed on spunlace non-woven cloth by padding process; Silane coupler is as surface conditioning agent; nano silver particles can be protected when padding post-drying process; prevent its sex change because of high temperature; ensure that the stable of nano silver particles antibacterial effect; silane coupler improves the stability of nano silver particles in leach mill solution simultaneously; improve the dispersiveness of nano silver particles, also play the effect preventing nano silver particles from reuniting.
Beneficial effect: compared with prior art, advantage of the present invention is: first, resin glue improves the viscosity of leach mill solution, reduce the mobility of nano silver particles, and silane coupler improves the stability of nano silver particles in leach mill solution, above-mentioned two kinds of materials act on simultaneously and prevent nano silver particles from reuniting, make it dispersed in leach mill solution, and then be evenly distributed on spunlace non-woven cloth, nano silver particles has potent antibacterial effect, the antibacterial effect equalization stable of nonwoven fabric entirety, ensure that the quality of product; The second, in preparation process nano silver particles by padding, baking step and Final finishing on spunlace non-woven cloth, operating procedure is simple and convenient, reduces production cost.
Detailed description of the invention
Below in conjunction with specific embodiment, illustrate the present invention further, these embodiments should be understood only be not used in for illustration of the present invention and limit the scope of the invention, after having read the present invention, the amendment of those skilled in the art to the various equivalent form of value of the present invention has all fallen within the application's claims limited range.
Embodiment 1:
A preparation method for nano silver spunlace non-woven cloth, with mass ratio range, comprises the steps:
Step one: the nano-silver water solution 1 part taking 5000ppm, silane coupler 10 parts, is dissolved in nano-silver water solution in silane coupler, after being fully uniformly mixed, forms Nano Silver mixed liquor;
Step 2: take 2 parts of resin glues, adds in the Nano Silver mixed liquor formed in step one, after being fully uniformly mixed, forms leach mill solution;
Step 3: the padding machine work nest leach mill solution formed in step 2 being injected padder, then spunlace non-woven cloth is immersed padding machine work nest, carry out padding process process, padding machine pressure is 7Mpa, and the spunlace non-woven cloth after padding process process treats that liquid rate is 50%;
Step 4: take out the spunlace non-woven cloth after padding, carry out drying and processing, bake out temperature 90 DEG C, drying time 3h, the soft degree of the spunlace non-woven cloth after oven dry is equal to knitted cloth, is nano silver spunlace non-woven cloth finished product.
Embodiment 2:
A preparation method for nano silver spunlace non-woven cloth, with mass ratio range, comprises the steps:
Step one: the nano-silver water solution 1 part taking 4000ppm, silane coupler 10 parts, is dissolved in nano-silver water solution in silane coupler, after being fully uniformly mixed, forms Nano Silver mixed liquor;
Step 2: take 2 parts of resin glues, adds in the Nano Silver mixed liquor formed in step one, after being fully uniformly mixed, forms leach mill solution;
Step 3: the padding machine work nest leach mill solution formed in step 2 being injected padder, then spunlace non-woven cloth is immersed padding machine work nest, carry out padding process process, padding machine pressure is 7Mpa, and the spunlace non-woven cloth after padding process process treats that liquid rate is 60%;
Step 4: take out the spunlace non-woven cloth after padding, carry out drying and processing, bake out temperature 85 DEG C, drying time 3.5h, the soft degree of the spunlace non-woven cloth after oven dry is equal to knitted cloth, is nano silver spunlace non-woven cloth finished product.
Embodiment 3:
A preparation method for nano silver spunlace non-woven cloth, with mass ratio range, comprises the steps:
Step one: the nano-silver water solution 1 part taking 3000ppm, silane coupler 10 parts, is dissolved in nano-silver water solution in silane coupler, after being fully uniformly mixed, forms Nano Silver mixed liquor;
Step 2: take 1.5 parts of resin glues, adds in the Nano Silver mixed liquor formed in step one, after being fully uniformly mixed, forms leach mill solution;
Step 3: the padding machine work nest leach mill solution formed in step 2 being injected padder, then spunlace non-woven cloth is immersed padding machine work nest, carry out padding process process, padding machine pressure is 6Mpa, and the spunlace non-woven cloth after padding process process treats that liquid rate is 70%;
Step 4: take out the spunlace non-woven cloth after padding, carry out drying and processing, bake out temperature 80 DEG C, drying time 3.5h, the soft degree of the spunlace non-woven cloth after oven dry is equal to knitted cloth, is nano silver spunlace non-woven cloth finished product.
Embodiment 4:
A preparation method for nano silver spunlace non-woven cloth, with mass ratio range, comprises the steps:
Step one: the nano-silver water solution 1 part taking 2000ppm, silane coupler 10 parts, is dissolved in nano-silver water solution in silane coupler, after being fully uniformly mixed, forms Nano Silver mixed liquor;
Step 2: take 1 part of resin glue, adds in the Nano Silver mixed liquor formed in step one, after being fully uniformly mixed, forms leach mill solution;
Step 3: the padding machine work nest leach mill solution formed in step 2 being injected padder, then spunlace non-woven cloth is immersed padding machine work nest, carry out padding process process, padding machine pressure is 5Mpa, and the spunlace non-woven cloth after padding process process treats that liquid rate is 80%;
Step 4: take out the spunlace non-woven cloth after padding, carry out drying and processing, bake out temperature 70 DEG C, drying time 3h, the soft degree of the spunlace non-woven cloth after oven dry is equal to knitted cloth, is nano silver spunlace non-woven cloth finished product.
The sample obtain above-mentioned four kinds of embodiments and reference substance carry out the biocidal property effectiveness comparison to staphylococcus aureus, and reference substance is " more nation " nanometer silver antimicrobial medical dressing, and it is market existing high-quality nano silver antibacterial material goods.Biocidal property effect measuring method all operates according to 2.1.8.8 immersion test method in " disinfection technology standard 2002 editions ".The result of biocidal property effectiveness comparison is as shown in table 1.
The biocidal property Contrast on effect of table 1 five groups of samples
| Sample ID | Bacteriostasis rate |
| Embodiment 1 | 99％ |
| Embodiment 2 | 99％ |
| Embodiment 3 | 98％ |
| Embodiment 4 | 97％ |
| " more nation " nanometer silver antimicrobial medical dressing | 90％ |
As shown in Table 1, the bacteriostasis rate of sample to staphylococcus aureus that four groups of embodiments obtain is significantly higher than the bacteriostasis rate of reference substance.According to the nano silver spunlace non-woven cloth that the present invention obtains, when preparing leach mill solution, nano silver particles is not reunited, pad rear nano silver particles to be uniformly distributed on nonwoven fabric, make the antibacterial effect of nano silver spunlace non-woven cloth higher than existing high-quality nano silver antibacterial material goods; Simultaneously in preparation process by nano silver particles by padding, baking step and Final finishing on spunlace non-woven cloth, operating procedure is simple, reduces production cost.
Claims (5)
1. a preparation method for nano silver spunlace non-woven cloth, is characterized in that: with mass ratio range, comprises the steps:
Step one: take 1 part of nano-silver water solution and 10 parts of coupling agents, be dissolved in by nano-silver water solution in coupling agent, after being fully uniformly mixed, forms Nano Silver mixed liquor;
Step 2: take 1-2 part resin glue, then adds in the described Nano Silver mixed liquor formed in step one, after being fully uniformly mixed, forms leach mill solution;
Step 3: the padding machine work nest described leach mill solution formed in step 2 being injected padder, then immerses padding machine work nest by spunlace non-woven cloth, carries out padding process process;
Step 4: take out the spunlace non-woven cloth after padding in step 3, carry out drying and processing, bake out temperature 70-90 DEG C, drying time 3-4h, the soft degree of the spunlace non-woven cloth after oven dry is equal to knitted cloth, is nano silver spunlace non-woven cloth finished product.
2. the preparation method of a kind of nano silver spunlace non-woven cloth according to claim 1, is characterized in that: in described step one, the Nano Silver concentration of nano-silver water solution is 2000-5000ppm.
3. the preparation method of a kind of nano silver spunlace non-woven cloth according to claim 1, is characterized in that: the coupling agent in described step one is silane coupler.
4. the preparation method of a kind of nano silver spunlace non-woven cloth according to claim 1, is characterized in that: in the padding process process of described step 3, padding machine pressure is 5-7MPa.
5. the preparation method of a kind of nano silver spunlace non-woven cloth according to claim 1, is characterized in that: the spunlace non-woven cloth after the padding process process in described step 3 treats that liquid rate is 50-80%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510155332.1A CN105274832A (en) | 2015-04-02 | 2015-04-02 | Preparation method for nanosilver spunlace non-woven fabrics |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510155332.1A CN105274832A (en) | 2015-04-02 | 2015-04-02 | Preparation method for nanosilver spunlace non-woven fabrics |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106319754A (en) * | 2016-09-08 | 2017-01-11 | 河南工程学院 | Functional antibacterial composite wool flocculus and preparation method thereof |
| CN107268214A (en) * | 2017-06-20 | 2017-10-20 | 丹阳市斯鲍特体育用品有限公司 | A kind of method that infusion process prepares conductive fencing metallic plastron fabric |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104131457A (en) * | 2014-07-16 | 2014-11-05 | 安徽可丽纳米纺织品有限公司 | Preparation method of antibacterial non-woven fabric and dip padding liquid for preparation |
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2015
- 2015-04-02 CN CN201510155332.1A patent/CN105274832A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104131457A (en) * | 2014-07-16 | 2014-11-05 | 安徽可丽纳米纺织品有限公司 | Preparation method of antibacterial non-woven fabric and dip padding liquid for preparation |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106319754A (en) * | 2016-09-08 | 2017-01-11 | 河南工程学院 | Functional antibacterial composite wool flocculus and preparation method thereof |
| CN107268214A (en) * | 2017-06-20 | 2017-10-20 | 丹阳市斯鲍特体育用品有限公司 | A kind of method that infusion process prepares conductive fencing metallic plastron fabric |
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Application publication date: 20160127 |
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