CN105236738A - Curve-surface glass material - Google Patents
Curve-surface glass material Download PDFInfo
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- CN105236738A CN105236738A CN201510540176.0A CN201510540176A CN105236738A CN 105236738 A CN105236738 A CN 105236738A CN 201510540176 A CN201510540176 A CN 201510540176A CN 105236738 A CN105236738 A CN 105236738A
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- 239000011521 glass Substances 0.000 title claims abstract description 46
- 239000000463 material Substances 0.000 title claims abstract description 24
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims abstract description 12
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 12
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims abstract description 12
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims abstract description 12
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 10
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 claims abstract description 7
- BNIILDVGGAEEIG-UHFFFAOYSA-L disodium hydrogen phosphate Chemical compound [Na+].[Na+].OP([O-])([O-])=O BNIILDVGGAEEIG-UHFFFAOYSA-L 0.000 claims abstract description 7
- 229910021538 borax Inorganic materials 0.000 claims abstract description 6
- 229910000019 calcium carbonate Inorganic materials 0.000 claims abstract description 6
- WUKWITHWXAAZEY-UHFFFAOYSA-L calcium difluoride Chemical compound [F-].[F-].[Ca+2] WUKWITHWXAAZEY-UHFFFAOYSA-L 0.000 claims abstract description 6
- 229910001634 calcium fluoride Inorganic materials 0.000 claims abstract description 6
- 235000019800 disodium phosphate Nutrition 0.000 claims abstract description 6
- ORUIBWPALBXDOA-UHFFFAOYSA-L magnesium fluoride Chemical compound [F-].[F-].[Mg+2] ORUIBWPALBXDOA-UHFFFAOYSA-L 0.000 claims abstract description 6
- 229910001635 magnesium fluoride Inorganic materials 0.000 claims abstract description 6
- 239000000395 magnesium oxide Substances 0.000 claims abstract description 6
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims abstract description 6
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 claims abstract description 6
- 239000000377 silicon dioxide Substances 0.000 claims abstract description 6
- 235000012239 silicon dioxide Nutrition 0.000 claims abstract description 6
- 229910000029 sodium carbonate Inorganic materials 0.000 claims abstract description 6
- AJPJDKMHJJGVTQ-UHFFFAOYSA-M sodium dihydrogen phosphate Chemical compound [Na+].OP(O)([O-])=O AJPJDKMHJJGVTQ-UHFFFAOYSA-M 0.000 claims abstract description 6
- 239000004328 sodium tetraborate Substances 0.000 claims abstract description 6
- 235000010339 sodium tetraborate Nutrition 0.000 claims abstract description 6
- 239000011787 zinc oxide Substances 0.000 claims abstract description 6
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 12
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 claims description 10
- 239000012744 reinforcing agent Substances 0.000 claims description 9
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 6
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims description 6
- -1 polyoxyethylene Polymers 0.000 claims description 6
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 claims description 5
- DPDMMXDBJGCCQC-UHFFFAOYSA-N [Na].[Cl] Chemical compound [Na].[Cl] DPDMMXDBJGCCQC-UHFFFAOYSA-N 0.000 claims description 5
- 229940045641 monobasic sodium phosphate Drugs 0.000 claims description 5
- 229960001866 silicon dioxide Drugs 0.000 claims description 5
- 229910000030 sodium bicarbonate Inorganic materials 0.000 claims description 5
- 235000017557 sodium bicarbonate Nutrition 0.000 claims description 5
- 239000004925 Acrylic resin Substances 0.000 claims description 4
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 claims description 4
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 2
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 claims description 2
- 229920002319 Poly(methyl acrylate) Polymers 0.000 claims description 2
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 2
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 claims description 2
- PNXMTCDJUBJHQJ-UHFFFAOYSA-N propyl prop-2-enoate Chemical compound CCCOC(=O)C=C PNXMTCDJUBJHQJ-UHFFFAOYSA-N 0.000 claims description 2
- 238000000465 moulding Methods 0.000 abstract description 4
- 230000006835 compression Effects 0.000 abstract description 2
- 238000007906 compression Methods 0.000 abstract description 2
- 238000002834 transmittance Methods 0.000 abstract description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 abstract 2
- UIIMBOGNXHQVGW-DEQYMQKBSA-M Sodium bicarbonate-14C Chemical compound [Na+].O[14C]([O-])=O UIIMBOGNXHQVGW-DEQYMQKBSA-M 0.000 abstract 1
- 229910000397 disodium phosphate Inorganic materials 0.000 abstract 1
- 239000003623 enhancer Substances 0.000 abstract 1
- 229910000403 monosodium phosphate Inorganic materials 0.000 abstract 1
- 235000019799 monosodium phosphate Nutrition 0.000 abstract 1
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 abstract 1
- 239000001103 potassium chloride Substances 0.000 abstract 1
- 235000011164 potassium chloride Nutrition 0.000 abstract 1
- 239000011780 sodium chloride Substances 0.000 abstract 1
- 230000008023 solidification Effects 0.000 abstract 1
- 238000007711 solidification Methods 0.000 abstract 1
- 229910001928 zirconium oxide Inorganic materials 0.000 abstract 1
- 239000000126 substance Substances 0.000 description 8
- 238000005516 engineering process Methods 0.000 description 6
- 238000004519 manufacturing process Methods 0.000 description 4
- 229910052751 metal Inorganic materials 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- 230000000694 effects Effects 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 238000010791 quenching Methods 0.000 description 3
- 230000000171 quenching effect Effects 0.000 description 3
- 239000002994 raw material Substances 0.000 description 3
- 238000007493 shaping process Methods 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- 230000005226 mechanical processes and functions Effects 0.000 description 2
- 229910004298 SiO 2 Inorganic materials 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 210000005252 bulbus oculi Anatomy 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 230000001066 destructive effect Effects 0.000 description 1
- 239000002241 glass-ceramic Substances 0.000 description 1
- 230000008676 import Effects 0.000 description 1
- MRELNEQAGSRDBK-UHFFFAOYSA-N lanthanum(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[La+3].[La+3] MRELNEQAGSRDBK-UHFFFAOYSA-N 0.000 description 1
- 230000035800 maturation Effects 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 125000004433 nitrogen atom Chemical group N* 0.000 description 1
- 239000000075 oxide glass Substances 0.000 description 1
- SIWVEOZUMHYXCS-UHFFFAOYSA-N oxo(oxoyttriooxy)yttrium Chemical compound O=[Y]O[Y]=O SIWVEOZUMHYXCS-UHFFFAOYSA-N 0.000 description 1
- 238000006748 scratching Methods 0.000 description 1
- 230000002393 scratching effect Effects 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 239000005368 silicate glass Substances 0.000 description 1
- 239000005361 soda-lime glass Substances 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 229910000679 solder Inorganic materials 0.000 description 1
Landscapes
- Glass Compositions (AREA)
Abstract
The invention relates to the technical field of display glass materials and particularly relates to a curve-surface glass material which includes the following components, by weight, 40-70 parts of silicon dioxide, 12-15 parts of calcium carbonate, 2-4 parts of borax, 2-4 parts of calcium fluoride, 2-4 parts of magnesium fluoride, 5-10 parts of disodium hydrogen phosphate, 5-10 parts of sodium dihydrogen phosphate, 5-10 parts of sodium hydrogen phosphate, 5-10 parts of sodium bicarbonate, 5-10 parts of sodium carbonate, 4-5 parts of potassium chloride, 4-5 parts of sodium chloride, 0.01-0.03 parts of magnesium oxide, 0.01-0.03 parts of zinc oxide, 0.01-0.03 parts of zirconium oxide, 1-3 parts of a solidifying agent and 2-3.5 parts of a solidification enhancer. The curve-surface glass material is ensured to have high light transmittance and excellent mechanical moulding performance, so that the curve-surface glass material is suitable for being prepared into a curve-surface structure with compression resistance and impact resistance indexes in every part maintained to be uniform.
Description
Technical field
The present invention relates to display glass field of material technology, be specifically related to a kind of bend glass material.
Background technology
Curved surface TV refers to that screen is with certain curvature, has the televisor of certain curved-surface shape, and curvature and the eyeball radian of general surface TV are basically identical.And curved-surface display technology had been developed maturation in recent years, such as: within 2013, Korea S's lg electronics releases its First curved surface OLED TV, the effect that lg electronics is emphasized is WRGB tetra-color pixel technology on 55 cun of screens, radian modeling and adding, and 3D image effect can be allowed more true to nature.In fact, lg electronics and Samsung all in January, 2013, curved surface were shown in U.S. CE S exhibition, but its manufacturing technology was also very immature at that time.Samsung also immediately following thereafter, and in July final Samsung also release 55 cun of curved surface LED TVs.So far panel factory of Liang great Korea S and TV factory start to have been pushed to by OLED TV be not plane but new era of curved surface.
Along with curved-surface display technology in recent years full-fledged, curved surface TV, flexible displays, curved surface mobile phone etc. all arises at the historic moment.And on some products, by increasing bend glass material, namely can reach certain curved-surface display effect, curved-surface display function also can consider that covering surface glass material is to increase certain performance.
Current functional glass roughly comprises hot functional glass, mechanical function glass, chemical functional glass etc.
High rigidity, high strength, high tenacity glass etc. all belong to mechanical function glass.Glass in use, will come in contact with other materials unavoidably, easily cause scuffing.For avoiding scratching, will increase the hardness of glass, containing the alumina silicate glass of yttrium oxide, lanthanum trioxide, its Vickers' hardness is significantly higher than soda-lime-silica glass.In oxide glass, import the glass of nitrogen-atoms, its Vickers' hardness is higher.High rigidity glass can be used as the table illiteracy etc. of windshield glass of automobile and clock and watch.
Hot functional glass mainly refers to thermal expansivity little (or variable), the non-destructive low-expansion heat-resisting glass through suddenly cold and hot.Low-expansion glass-ceramic has very high thermostability, is to manufacture cooker, the ideal material of tableware.The coefficient of expansion of devitrified glass can regulate within the specific limits, therefore can be used for and various metals sealing-in, also can be used as metal and pottery, the solder of metal and glass.Also have in addition and just can soften at low temperatures, for glass, the sealing by fusing of metal and electronic component or bonding leaded low melting glass.These glass are mainly used in electronic industry.
Chemical glass consist of SiO
2account for 81%, B
2o
3account for 12%, Na
2o accounts for 5% and Al
2o
3account for 2%.The thermal expansivity of chemical glass is little, so resistance to suddenly cold and hot; Chemical glass also has high thermostability and chemical stability-and these performances are all more excellent than potassic glass.In addition, fusing (the softening in other words) temperature carrying out chemical glass compared with potassic glass is higher, and more not easily breaks when being impacted.Therefore, chemical glass is the material in order to manufacture some chemical apparatus more more excellent than potassic glass.
In the manufacturing processed of glass, the selection of the moiety of glass is different, and the difference of formula rate, the light transmission that all directly can affect vial can mechanical-moulded property.
Summary of the invention
For solving the deficiencies in the prior art, the invention provides a kind of bend glass material.
A kind of bend glass material, comprise each component of following weight part: the silicon-dioxide of 40 ~ 70 weight parts, the calcium carbonate of 12 ~ 15 weight parts, the borax of 2 ~ 4 weight parts, the Calcium Fluoride (Fluorspan) of 2 ~ 4 weight parts, the magnesium fluoride of 2 ~ 4 weight parts, 5 ~ 10 disodium-hydrogens, 5 ~ 10 SODIUM PHOSPHATE, MONOBASIC, 5 ~ 10 sodium hydrogen phosphates, the sodium bicarbonate of 5 ~ 10 weight parts, the sodium carbonate of 5 ~ 10 weight parts, the Repone K of 4 ~ 5 weight parts, the sodium-chlor of 4 ~ 5 weight parts, the magnesium oxide of 0.01 ~ 0.03 weight part, the zinc oxide of 0.01 ~ 0.03 weight part, the zirconium white of 0.01 ~ 0.03 weight part, the solidifying agent of 1 ~ 3 weight part, the reinforcing agent of 2 ~ 3.5.
Concrete, described solidifying agent is polymethyl acrylate resin, polymethyl acrylic acid second fat or butyl polyacrylate resin.
Concrete, described reinforcing agent is the two methyl acrylate of polyoxyethylene glycol, the two ethyl propenoate of polyoxyethylene glycol or the two propyl acrylate of polyoxyethylene glycol.
Preferably, the number-average molecular weight of described solidifying agent is 3500 ~ 6000.
Preferably, the number-average molecular weight of described reinforcing agent is 3000 ~ 5000.
Bend glass material provided by the present invention, under the behavior pattern ensureing high-transmittance, can obtain good mechanical processability, be suitable for being made into curved-surface structure, and it is consistent to keep the resistance to compression of each several part to resist index.
Embodiment
Be described principle of the present invention and feature below, example, only for explaining the present invention, is not intended to limit scope of the present invention.
Embodiment 1
Batching: the silicon-dioxide of 40 kilograms, the calcium carbonate of 15 kilograms, the borax of 2 kilograms, the Calcium Fluoride (Fluorspan) of 4 kilograms, the magnesium fluoride of 2 kilograms, 10 disodium-hydrogens, 5 SODIUM PHOSPHATE, MONOBASIC, 10 sodium hydrogen phosphates, the sodium bicarbonate of 5 kilograms, the sodium carbonate of 10 kilograms, the Repone K of 4 kilograms, the sodium-chlor of 5 kilograms, the magnesium oxide of 0.01 kilogram, the zinc oxide of 0.03 kilogram, the zirconium white of 0.01 kilogram, the solidifying agent of 3 kilograms, the reinforcing agent of 2 kilograms.
Then, mixed by above-mentioned raw materials to send in kiln and melt, the temperature of kiln controls between 1750 ~ 1800 DEG C; The material being in molten state is sent into molding device shaping, finally, anneal at the temperature of 650 ~ 680 DEG C, finally, carry out quenching process with the warm water of 50 ~ 80 DEG C, obtain finished product.
Embodiment 2
Batching: the silicon-dioxide of 70 kilograms, the calcium carbonate of 12 kilograms, the borax of 4 kilograms, the Calcium Fluoride (Fluorspan) of 2 kilograms, the magnesium fluoride of 4 kilograms, 5 disodium-hydrogens, 10 SODIUM PHOSPHATE, MONOBASIC, 5 sodium hydrogen phosphates, the sodium bicarbonate of 10 kilograms, the sodium carbonate of 5 kilograms, the Repone K of 5 kilograms, the sodium-chlor of 4 kilograms, the magnesium oxide of 0.03 kilogram, the zinc oxide of 0.01 kilogram, the zirconium white of 0.03 kilogram, the solidifying agent of 1 kilogram, the reinforcing agent of 3.5 kilograms.
Then, mixed by above-mentioned raw materials to send in kiln and melt, the temperature of kiln controls between 1750 ~ 1800 DEG C; The material being in molten state is sent into molding device shaping, finally, anneal at the temperature of 650 ~ 680 DEG C, finally, carry out quenching process with the warm water of 50 ~ 80 DEG C, obtain finished product.
Embodiment 3
Batching: the silicon-dioxide of 65 kilograms, the calcium carbonate of 13 kilograms, the borax of 3 kilograms, the Calcium Fluoride (Fluorspan) of 3 kilograms, the magnesium fluoride of 3 kilograms, 8 disodium-hydrogens, 7 SODIUM PHOSPHATE, MONOBASIC, 8 sodium hydrogen phosphates, the sodium bicarbonate of 7 kilograms, the sodium carbonate of 8 kilograms, the Repone K of 7 kilograms, the sodium-chlor of 5 kilograms, the magnesium oxide of 0.02 kilogram, the zinc oxide of 0.023 kilogram, the zirconium white of 0.02 kilogram, the solidifying agent of 2 kilograms, the reinforcing agent of 2.5 kilograms.
Then, mixed by above-mentioned raw materials to send in kiln and melt, the temperature of kiln controls between 1750 ~ 1800 DEG C; The material being in molten state is sent into molding device shaping, finally, anneal at the temperature of 650 ~ 680 DEG C, finally, carry out quenching process with the warm water of 50 ~ 80 DEG C, obtain finished product.
The foregoing is only better embodiment of the present invention, not in order to limit the present invention, within the spirit and principles in the present invention all, any amendment done, equivalent replacement, improvement etc., all should be included within protection scope of the present invention.
Claims (5)
1. a bend glass material, it is characterized in that, comprise each component of following weight part: the silicon-dioxide of 40 ~ 70 weight parts, the calcium carbonate of 12 ~ 15 weight parts, the borax of 2 ~ 4 weight parts, the Calcium Fluoride (Fluorspan) of 2 ~ 4 weight parts, the magnesium fluoride of 2 ~ 4 weight parts, 5 ~ 10 disodium-hydrogens, 5 ~ 10 SODIUM PHOSPHATE, MONOBASIC, 5 ~ 10 sodium hydrogen phosphates, the sodium bicarbonate of 5 ~ 10 weight parts, the sodium carbonate of 5 ~ 10 weight parts, the Repone K of 4 ~ 5 weight parts, the sodium-chlor of 4 ~ 5 weight parts, the magnesium oxide of 0.01 ~ 0.03 weight part, the zinc oxide of 0.01 ~ 0.03 weight part, the zirconium white of 0.01 ~ 0.03 weight part, the solidifying agent of 1 ~ 3 weight part, the reinforcing agent of 2 ~ 3.5.
2. bend glass material according to claim 1, is characterized in that: described solidifying agent is polymethyl acrylate resin, polymethyl acrylic acid second fat or butyl polyacrylate resin.
3. bend glass material according to claim 1, is characterized in that: described reinforcing agent is the two methyl acrylate of polyoxyethylene glycol, the two ethyl propenoate of polyoxyethylene glycol or the two propyl acrylate of polyoxyethylene glycol.
4. the bend glass material according to claim 1 or 2 or 3, is characterized in that: the number-average molecular weight of described solidifying agent is 3500 ~ 6000.
5. the bend glass material according to claim 1 or 2 or 3, is characterized in that: the number-average molecular weight of described reinforcing agent is 3000 ~ 5000.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510540176.0A CN105236738A (en) | 2015-08-28 | 2015-08-28 | Curve-surface glass material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510540176.0A CN105236738A (en) | 2015-08-28 | 2015-08-28 | Curve-surface glass material |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105236738A true CN105236738A (en) | 2016-01-13 |
Family
ID=55034626
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510540176.0A Pending CN105236738A (en) | 2015-08-28 | 2015-08-28 | Curve-surface glass material |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105236738A (en) |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101913771A (en) * | 2010-07-05 | 2010-12-15 | 清华大学 | A kind of preparation method of microcrystalline porous foam glass tube |
| US20140193499A1 (en) * | 2011-04-05 | 2014-07-10 | Reg4Life Regeneration Technology, S.A. | Bioactive glass composition, its applications and respective preparation methods |
-
2015
- 2015-08-28 CN CN201510540176.0A patent/CN105236738A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101913771A (en) * | 2010-07-05 | 2010-12-15 | 清华大学 | A kind of preparation method of microcrystalline porous foam glass tube |
| US20140193499A1 (en) * | 2011-04-05 | 2014-07-10 | Reg4Life Regeneration Technology, S.A. | Bioactive glass composition, its applications and respective preparation methods |
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| C06 | Publication | ||
| PB01 | Publication | ||
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Application publication date: 20160113 |