CN105199570A - Oil-resistant anti-corrosion waterborne paint and preparation method thereof - Google Patents
Oil-resistant anti-corrosion waterborne paint and preparation method thereof Download PDFInfo
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- CN105199570A CN105199570A CN201510608204.8A CN201510608204A CN105199570A CN 105199570 A CN105199570 A CN 105199570A CN 201510608204 A CN201510608204 A CN 201510608204A CN 105199570 A CN105199570 A CN 105199570A
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- 238000002360 preparation method Methods 0.000 title claims abstract description 17
- 239000003973 paint Substances 0.000 title abstract description 7
- 238000005260 corrosion Methods 0.000 title abstract 4
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims abstract description 42
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 42
- HQKMJHAJHXVSDF-UHFFFAOYSA-L magnesium stearate Chemical compound [Mg+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O HQKMJHAJHXVSDF-UHFFFAOYSA-L 0.000 claims abstract description 42
- 239000003921 oil Substances 0.000 claims abstract description 40
- 229920000609 methyl cellulose Polymers 0.000 claims abstract description 29
- 239000001923 methylcellulose Substances 0.000 claims abstract description 29
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 27
- 229920005989 resin Polymers 0.000 claims abstract description 25
- 239000011347 resin Substances 0.000 claims abstract description 25
- 229920001568 phenolic resin Polymers 0.000 claims abstract description 24
- LRXTYHSAJDENHV-UHFFFAOYSA-H zinc phosphate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O LRXTYHSAJDENHV-UHFFFAOYSA-H 0.000 claims abstract description 24
- 229910000165 zinc phosphate Inorganic materials 0.000 claims abstract description 24
- IVSZLXZYQVIEFR-UHFFFAOYSA-N 1,3-Dimethylbenzene Natural products CC1=CC=CC(C)=C1 IVSZLXZYQVIEFR-UHFFFAOYSA-N 0.000 claims abstract description 23
- LTMRRSWNXVJMBA-UHFFFAOYSA-L 2,2-diethylpropanedioate Chemical compound CCC(CC)(C([O-])=O)C([O-])=O LTMRRSWNXVJMBA-UHFFFAOYSA-L 0.000 claims abstract description 23
- OMIGHNLMNHATMP-UHFFFAOYSA-N 2-hydroxyethyl prop-2-enoate Chemical compound OCCOC(=O)C=C OMIGHNLMNHATMP-UHFFFAOYSA-N 0.000 claims abstract description 23
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 23
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims abstract description 23
- 229920003180 amino resin Polymers 0.000 claims abstract description 23
- 239000008367 deionised water Substances 0.000 claims abstract description 23
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 23
- 239000005011 phenolic resin Substances 0.000 claims abstract description 23
- 239000000843 powder Substances 0.000 claims abstract description 22
- ARXJGSRGQADJSQ-UHFFFAOYSA-N 1-methoxypropan-2-ol Chemical compound COCC(C)O ARXJGSRGQADJSQ-UHFFFAOYSA-N 0.000 claims abstract description 21
- 229910021532 Calcite Inorganic materials 0.000 claims abstract description 21
- 229910000676 Si alloy Inorganic materials 0.000 claims abstract description 21
- UKLDJPRMSDWDSL-UHFFFAOYSA-L [dibutyl(dodecanoyloxy)stannyl] dodecanoate Chemical compound CCCCCCCCCCCC(=O)O[Sn](CCCC)(CCCC)OC(=O)CCCCCCCCCCC UKLDJPRMSDWDSL-UHFFFAOYSA-L 0.000 claims abstract description 21
- 229910000019 calcium carbonate Inorganic materials 0.000 claims abstract description 21
- 239000007822 coupling agent Substances 0.000 claims abstract description 21
- 235000019359 magnesium stearate Nutrition 0.000 claims abstract description 21
- 239000004408 titanium dioxide Substances 0.000 claims abstract description 21
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 claims abstract description 20
- 238000000498 ball milling Methods 0.000 claims description 52
- 238000000576 coating method Methods 0.000 claims description 46
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid group Chemical group C(C1=CC=CC=C1)(=O)O WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 claims description 44
- 239000000463 material Substances 0.000 claims description 36
- 238000003756 stirring Methods 0.000 claims description 24
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 claims description 22
- DXPPIEDUBFUSEZ-UHFFFAOYSA-N 6-methylheptyl prop-2-enoate Chemical group CC(C)CCCCCOC(=O)C=C DXPPIEDUBFUSEZ-UHFFFAOYSA-N 0.000 claims description 22
- 239000005711 Benzoic acid Substances 0.000 claims description 22
- 239000004593 Epoxy Substances 0.000 claims description 22
- 235000010233 benzoic acid Nutrition 0.000 claims description 22
- SXDBWCPKPHAZSM-UHFFFAOYSA-N bromic acid Chemical compound OBr(=O)=O SXDBWCPKPHAZSM-UHFFFAOYSA-N 0.000 claims description 22
- 229960000935 dehydrated alcohol Drugs 0.000 claims description 22
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 22
- 229920003986 novolac Polymers 0.000 claims description 22
- ZTFZSHLWORMEHO-UHFFFAOYSA-A pentaaluminum;[oxido(phosphonatooxy)phosphoryl] phosphate Chemical compound [Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O.[O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O.[O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O ZTFZSHLWORMEHO-UHFFFAOYSA-A 0.000 claims description 22
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 claims description 22
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 21
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 20
- 239000013530 defoamer Substances 0.000 claims description 20
- 239000011863 silicon-based powder Substances 0.000 claims description 20
- 230000008719 thickening Effects 0.000 claims description 20
- 239000005995 Aluminium silicate Substances 0.000 claims description 19
- 235000012211 aluminium silicate Nutrition 0.000 claims description 19
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 19
- 239000006185 dispersion Substances 0.000 claims description 16
- 239000011812 mixed powder Substances 0.000 claims description 16
- 239000011268 mixed slurry Substances 0.000 claims description 16
- 239000002994 raw material Substances 0.000 claims description 10
- 230000015572 biosynthetic process Effects 0.000 claims description 8
- 239000007788 liquid Substances 0.000 claims description 8
- 238000002844 melting Methods 0.000 claims description 8
- 230000008018 melting Effects 0.000 claims description 8
- 239000011248 coating agent Substances 0.000 claims description 3
- -1 m-xylene phenolic resin Chemical compound 0.000 abstract description 6
- 239000000440 bentonite Substances 0.000 abstract description 2
- 229910000278 bentonite Inorganic materials 0.000 abstract description 2
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 abstract description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract 2
- DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 abstract 2
- GOXQRTZXKQZDDN-UHFFFAOYSA-N 2-Ethylhexyl acrylate Chemical compound CCCCC(CC)COC(=O)C=C GOXQRTZXKQZDDN-UHFFFAOYSA-N 0.000 abstract 1
- FXIHWFULEZIREG-UHFFFAOYSA-N 2-bromo-2-hydroxypropanoic acid Chemical compound CC(O)(Br)C(O)=O FXIHWFULEZIREG-UHFFFAOYSA-N 0.000 abstract 1
- 229920000180 alkyd Polymers 0.000 abstract 1
- QPLNUHHRGZVCLQ-UHFFFAOYSA-K aluminum;[oxido(phosphonooxy)phosphoryl] phosphate Chemical compound [Al+3].OP([O-])(=O)OP([O-])(=O)OP(O)([O-])=O QPLNUHHRGZVCLQ-UHFFFAOYSA-K 0.000 abstract 1
- 239000002518 antifoaming agent Substances 0.000 abstract 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 abstract 1
- 230000007797 corrosion Effects 0.000 abstract 1
- 239000012975 dibutyltin dilaurate Substances 0.000 abstract 1
- 239000003085 diluting agent Substances 0.000 abstract 1
- 239000003822 epoxy resin Substances 0.000 abstract 1
- SLGWESQGEUXWJQ-UHFFFAOYSA-N formaldehyde;phenol Chemical compound O=C.OC1=CC=CC=C1 SLGWESQGEUXWJQ-UHFFFAOYSA-N 0.000 abstract 1
- 235000010981 methylcellulose Nutrition 0.000 abstract 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 abstract 1
- 239000012188 paraffin wax Substances 0.000 abstract 1
- 229920000647 polyepoxide Polymers 0.000 abstract 1
- 239000000377 silicon dioxide Substances 0.000 abstract 1
- 239000002562 thickening agent Substances 0.000 abstract 1
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 abstract 1
- 230000002421 anti-septic effect Effects 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 2
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 239000002612 dispersion medium Substances 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 229920000592 inorganic polymer Polymers 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000004846 water-soluble epoxy resin Substances 0.000 description 1
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- Paints Or Removers (AREA)
Abstract
The invention discloses oil-resistant anti-corrosion waterborne paint which is prepared from alkyd resin, phenol formaldehyde epoxy resin, m-xylene phenolic resin, butyl etherified amino resin, hydroxyl bromopropanoic acid resin, phthalic acid dibutyl ester, hydroxyethyl acrylate, 2-ethylhexyl acrylate, diethyl malonate, methyl methacrylate, aluminum triphosphate, zinc phosphate, anhydrous ethanol, aluminum oxide, chlorinated paraffin, methyl cellulose, talcum powder, organic bentonite, silicon alloy powder, calcite, zinc stearate, titanium dioxide, kaoline, calcium carbonate, silica powder, dibutyltin dilaurate, magnesium stearate, thickeners, diluent, defoaming agents, coupling agents, propylene glycol monomethyl ether and deionized water. The invention further discloses a preparation method of the oil-resistant anti-corrosion waterborne paint. The obtained waterborne paint is good oil resistance and corrosion resistance and high in adhesion and hardness.
Description
Technical field
The present invention relates to a kind of water-borne coatings, particularly relate to a kind of oil resistance anticorrosion water-borne coatings and preparation method thereof.
Background technology
Every coating using water as solvent or make dispersion medium, all can be described as water-borne coatings.Water-borne coatings comprises water soluble paint, water-reducible coatings, water-dispersible paint 3 kinds.Water soluble paint take water soluble resin as film forming matter, with polyvinyl alcohol and various modifier thereof for representative, in addition also has water-soluble Synolac, water-soluble epoxy resin and inorganic polymer water-base resin etc.
Water-borne coatings function singleness of the prior art, oil resistant and antiseptic property poor, bonding force is weak, cannot meet the demand of actual use.
Summary of the invention
For solving in background technology the technical problem existed, the present invention proposes a kind of oil resistance anticorrosion water-borne coatings and preparation method thereof, the water-borne coatings oil resistant of gained and antiseptic property good, strong adhesion, hardness is high.
A kind of oil resistance anticorrosion water-borne coatings that the present invention proposes, its raw material comprises by weight: Synolac 80-120 part, novolac epoxy 20-50 part, m-dimethyl benzene phenolic resin 5-15 part, butylated amino resin 2-9 part, hydroxyl third bromic acid resin 5-15 part, adjacent benzoic acid dibutylester 3-8 part, Hydroxyethyl acrylate 2-9 part, Isooctyl acrylate monomer 3-6 part, diethyl malonate 1-8 part, methyl methacrylate 2-8 part, aluminium triphosphate 2-6 part, zinc phosphate 1-5 part, dehydrated alcohol 3-6 part, aluminium sesquioxide 3-9 part, clorafin 4-9 part, methylcellulose gum 2-8 part, talcum powder 1-7 part, organobentonite 3-8 part, silicon alloy powder 2-9 part, calcite 1-6 part, Zinic stearas 4-8 part, titanium dioxide 2-9 part, kaolin 2-6 part, calcium carbonate 4-9 part, silicon powder 1-5 part, dibutyl tin laurate 2-7 part, Magnesium Stearate 1-6 part, thickening material 1-6 part, thinner 2-5 part, defoamer 4-9 part, coupling agent 2-6 part, propylene glycol monomethyl ether 4-6 part, deionized water 12-26 part.
Preferably, the weight ratio of Synolac, novolac epoxy, m-dimethyl benzene phenolic resin, butylated amino resin, hydroxyl third bromic acid resin and deionized water is 80-120:25-45:8-12:3-8:6-14:14-24.
Preferably, the weight ratio of adjacent benzoic acid dibutylester, Hydroxyethyl acrylate, Isooctyl acrylate monomer, diethyl malonate and methyl methacrylate is 4-7:3-8:4-5:2-7:3-7.
Preferably, the weight ratio of aluminium triphosphate, zinc phosphate and dehydrated alcohol is 3-5:2-4:4-5.
Preferably, its raw material comprises by weight: Synolac 85-115 part, novolac epoxy 25-45 part, m-dimethyl benzene phenolic resin 8-12 part, butylated amino resin 3-8 part, hydroxyl third bromic acid resin 6-14 part, adjacent benzoic acid dibutylester 4-7 part, Hydroxyethyl acrylate 3-8 part, Isooctyl acrylate monomer 4-5 part, diethyl malonate 2-7 part, methyl methacrylate 3-7 part, aluminium triphosphate 3-5 part, zinc phosphate 2-4 part, dehydrated alcohol 4-5 part, aluminium sesquioxide 4-8 part, clorafin 5-8 part, methylcellulose gum 3-7 part, talcum powder 2-6 part, organobentonite 4-7 part, silicon alloy powder 3-8 part, calcite 2-5 part, Zinic stearas 5-7 part, titanium dioxide 3-8 part, kaolin 3-5 part, calcium carbonate 5-8 part, silicon powder 2-4 part, dibutyl tin laurate 3-6 part, Magnesium Stearate 2-5 part, thickening material 2-5 part, thinner 3-4 part, defoamer 5-8 part, coupling agent 3-5 part, propylene glycol monomethyl ether 4.5-5.5 part, deionized water 14-24 part.
The preparation method of a kind of oil resistance anticorrosion water-borne coatings that the present invention proposes, comprises the steps:
S1, by proportioning, Synolac, novolac epoxy, m-dimethyl benzene phenolic resin and dehydrated alcohol to be mixed, stir formation dispersion liquid, add butylated amino resin, hydroxyl third bromic acid resin and thinner again, be uniformly mixed rear ultrasonic disperse 20-30min, then add talcum powder, organobentonite, silicon alloy powder, calcite, titanium dioxide, kaolin two and calcium carbonate, be cooled to room temperature after ball milling and obtain material a;
S2, methylcellulose gum is put into ball mill carry out ball milling, then add silicon powder and Hydroxyethyl acrylate, continue to stir 8-16min, form the mixed powder A of surface active;
S3, methylcellulose gum is heated to melting mixes with adjacent benzoic acid dibutylester, Isooctyl acrylate monomer, diethyl malonate, methyl methacrylate, aluminium triphosphate, zinc phosphate, then aluminium sesquioxide and clorafin is slowly added, homogenizer is moved to after stirring 40-60min with the speed of 600-1000 rev/min, add material a and mixed powder A, with the Rate Dispersion 20-50min of 3700-3900 rev/min, obtain mixed slurry;
S4, in mixed slurry, add dibutyl tin laurate, Magnesium Stearate, thickening material, defoamer, coupling agent, propylene glycol monomethyl ether and deionized water lentamente, 35-45min is stirred with the speed of 380-450r/min, then Ball milling 2-3h, obtains oil resistance anticorrosion water-borne coatings.
Preferably, in S1, Ball-milling Time is 40-60min, and ball milling temperature is 45-55 DEG C.
Preferably, in S2, rotational speed of ball-mill is 2500-2900r/min, and ball milling temperature is 60-80 DEG C, and Ball-milling Time is 45-65min.
The raw material of a kind of oil resistance anticorrosion water-borne coatings of the present invention comprises: Synolac, novolac epoxy, m-dimethyl benzene phenolic resin, butylated amino resin, hydroxyl third bromic acid resin, adjacent benzoic acid dibutylester, Hydroxyethyl acrylate, Isooctyl acrylate monomer, diethyl malonate, methyl methacrylate, aluminium triphosphate, zinc phosphate, dehydrated alcohol, aluminium sesquioxide, clorafin, methylcellulose gum, talcum powder, organobentonite, silicon alloy powder, calcite, Zinic stearas, titanium dioxide, kaolin, calcium carbonate, silicon powder, dibutyl tin laurate, Magnesium Stearate, thickening material, thinner, defoamer, coupling agent, propylene glycol monomethyl ether and deionized water, the proportioning of each component of conservative control take Synolac as major ingredient, auxiliary interpolation novolac epoxy, m-dimethyl benzene phenolic resin, butylated amino resin, hydroxyl third bromic acid resin, adjacent benzoic acid dibutylester, Hydroxyethyl acrylate, Isooctyl acrylate monomer, diethyl malonate and methyl methacrylate, as filmogen, make the oil resistant of film forming and antiseptic property effectively improve, the aluminium triphosphate added can effectively improve the anticorrosion of water-borne coatings of the present invention and resistance toheat, the zinc phosphate added, dehydrated alcohol, aluminium sesquioxide, clorafin, methylcellulose gum, talcum powder, organobentonite, silicon alloy powder, calcite, Zinic stearas, titanium dioxide, kaolin, calcium carbonate and silicon powder are as filler, effectively improve wear resisting property and the hardness of water-borne coatings of the present invention, wherein zinc phosphate, aluminium sesquioxide and clorafin with the use of, the proportioning of conservative control three, effectively can improve the resistance toheat of water-borne coatings of the present invention as fire retardant, the dibutyl tin laurate added, Magnesium Stearate, thickening material, thinner, defoamer, coupling agent, propylene glycol monomethyl ether and deionized water are as auxiliary agent, effectively can improve the over-all properties of water-borne coatings of the present invention, oil resistant and antiseptic property good, strong adhesion, hardness is high.
Accompanying drawing explanation
Fig. 1 is the schematic flow sheet of a kind of oil resistance anticorrosion water-borne coatings preparation method that the present invention proposes.
Embodiment
Below in conjunction with specific embodiment, the present invention is described in detail; should understand; embodiment is only for illustration of the present invention, instead of for limiting the present invention, any amendment, equivalent replacement etc. made on basis of the present invention is all in protection scope of the present invention.
As shown in Figure 1, Fig. 1 is the schematic flow sheet of a kind of oil resistance anticorrosion water-borne coatings preparation method that the present invention proposes.
With reference to Fig. 1, the preparation method of a kind of oil resistance anticorrosion water-borne coatings that the present invention proposes, comprises the steps:
S1, by proportioning, Synolac, novolac epoxy, m-dimethyl benzene phenolic resin and dehydrated alcohol to be mixed, stir formation dispersion liquid, add butylated amino resin, hydroxyl third bromic acid resin and thinner again, be uniformly mixed rear ultrasonic disperse 20-30min, then add talcum powder, organobentonite, silicon alloy powder, calcite, titanium dioxide, kaolin two and calcium carbonate, be cooled to room temperature after ball milling and obtain material a;
S2, methylcellulose gum is put into ball mill carry out ball milling, then add silicon powder and Hydroxyethyl acrylate, continue to stir 8-16min, form the mixed powder A of surface active;
S3, methylcellulose gum is heated to melting mixes with adjacent benzoic acid dibutylester, Isooctyl acrylate monomer, diethyl malonate, methyl methacrylate, aluminium triphosphate, zinc phosphate, then aluminium sesquioxide and clorafin is slowly added, homogenizer is moved to after stirring 40-60min with the speed of 600-1000 rev/min, add material a and mixed powder A, with the Rate Dispersion 20-50min of 3700-3900 rev/min, obtain mixed slurry;
S4, in mixed slurry, add dibutyl tin laurate, Magnesium Stearate, thickening material, defoamer, coupling agent, propylene glycol monomethyl ether and deionized water lentamente, 35-45min is stirred with the speed of 380-450r/min, then Ball milling 2-3h, obtains oil resistance anticorrosion water-borne coatings.
In embodiment, the weight part of Synolac can be 80 parts, 85 parts, 90 parts, 95 parts, 100 parts, 105 parts, 110 parts, 115 parts, 120 parts; The weight part of novolac epoxy can be 20 parts, 25 parts, 30 parts, 35 parts, 40 parts, 45 parts, 50 parts; The weight part of m-dimethyl benzene phenolic resin can be 5 parts, 6 parts, 7 parts, 8 parts, 9 parts, 10 parts, 11 parts, 12 parts, 13 parts, 14 parts, 15 parts; The weight part of butylated amino resin can be 2 parts, 3 parts, 4 parts, 5 parts, 6 parts, 7 parts, 8 parts, 9 parts; The weight part of hydroxyl third bromic acid resin can be 5 parts, 6 parts, 7 parts, 8 parts, 9 parts, 10 parts, 11 parts, 12 parts, 13 parts, 14 parts, 15 parts; The weight part of adjacent benzoic acid dibutylester can be 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts, 5.5 parts, 6 parts, 6.5 parts, 7 parts, 7.5 parts, 8 parts; The weight part of Hydroxyethyl acrylate can be 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts, 5.5 parts, 6 parts, 6.5 parts, 7 parts, 7.5 parts, 8 parts, 8.5 parts, 9 parts; The weight part of Isooctyl acrylate monomer can be 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts, 5.5 parts, 6 parts; The weight part of diethyl malonate can be 1 part, 1.5 parts, 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts, 5.5 parts, 6 parts, 6.5 parts, 7 parts, 7.5 parts, 8 parts; The weight part of methyl methacrylate can be 2 parts, 3 parts, 4 parts, 5 parts, 6 parts, 7 parts, 8 parts; The weight part of aluminium triphosphate can be 2 parts, 3 parts, 4 parts, 5 parts, 6 parts; The weight part of zinc phosphate can be 1 part, 2 parts, 3 parts, 4 parts, 5 parts; The weight part of dehydrated alcohol can be 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts, 5.5 parts, 6 parts; The weight part of aluminium sesquioxide can be 3 parts, 4 parts, 5 parts, 6 parts, 7 parts, 8 parts, 9 parts; The weight part of clorafin can be 4 parts, 4.5 parts, 5 parts, 5.5 parts, 6 parts, 6.5 parts, 7 parts, 7.5 parts, 8 parts, 8.5 parts, 9 parts; The weight part of methylcellulose gum can be 2 parts, 3 parts, 4 parts, 5 parts, 6 parts, 7 parts, 8 parts; Talcous weight part can be 1 part, 2 parts, 3 parts, 4 parts, 5 parts, 6 parts, 7 parts; Bentonite weight part can be 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts, 5.5 parts, 6 parts, 6.5 parts, 7 parts, 7.5 parts, 8 parts; The weight part of silicon alloy powder can be 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts, 5.5 parts, 6 parts, 6.5 parts, 7 parts, 7.5 parts, 8 parts, 8.5 parts, 9 parts; The weight part of calcite can be 1 part, 1.5 parts, 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts, 5.5 parts, 6 parts; The weight part of Zinic stearas can be 4 parts, 5 parts, 6 parts, 7 parts, 8 parts; The weight part of titanium dioxide can be 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts, 5.5 parts, 6 parts, 6.5 parts, 7 parts, 7.5 parts, 8 parts, 8.5 parts, 9 parts; Kaolinic weight part can be 2 parts, 3 parts, 4 parts, 5 parts, 6 parts; The weight part of calcium carbonate can be 4 parts, 4.5 parts, 5 parts, 5.5 parts, 6 parts, 6.5 parts, 7 parts, 7.5 parts, 8 parts, 8.5 parts, 9 parts; The weight part of silicon powder can be 1 part, 2 parts, 3 parts, 4 parts, 5 parts; The weight part of dibutyl tin laurate can be 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts, 5.5 parts, 6 parts, 6.5 parts, 7 parts; The weight part of Magnesium Stearate can be 1 part, 1.5 parts, 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts, 5.5 parts, 6 parts; The weight part of thickening material can be 1 part, 1.5 parts, 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts, 5.5 parts, 6 parts; The weight part of thinner can be 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts; The weight part of defoamer can be 4 parts, 4.5 parts, 5 parts, 5.5 parts, 6 parts, 6.5 parts, 7 parts, 7.5 parts, 8 parts, 8.5 parts, 9 parts; The weight part of coupling agent can be 2 parts, 3 parts, 4 parts, 5 parts, 6 parts; The weight part of propylene glycol monomethyl ether can be 4 parts, 4.5 parts, 5 parts, 5.5 parts, 6 parts; The weight part of deionized water can be 12 parts, 13 parts, 14 parts, 15 parts, 16 parts, 17 parts, 18 parts, 19 parts, 20 parts, 21 parts, 22 parts, 23 parts, 24 parts, 25 parts, 26 parts.
Embodiment 1
A kind of oil resistance anticorrosion water-borne coatings that the present invention proposes, its raw material comprises by weight: Synolac 100 parts, novolac epoxy 35 parts, m-dimethyl benzene phenolic resin 10 parts, butylated amino resin 5.5 parts, hydroxyl third bromic acid resin 10 parts, adjacent benzoic acid dibutylester 5.5 parts, Hydroxyethyl acrylate 5.5 parts, Isooctyl acrylate monomer 4.5 parts, diethyl malonate 4.5 parts, methyl methacrylate 5 parts, aluminium triphosphate 4 parts, zinc phosphate 3 parts, dehydrated alcohol 4.5 parts, aluminium sesquioxide 6 parts, clorafin 6.5 parts, methylcellulose gum 5 parts, talcum powder 4 parts, organobentonite 5.5 parts, 5.5 parts, silicon alloy powder, 3.5 parts, calcite, Zinic stearas 6 parts, titanium dioxide 5.5 parts, kaolin 4 parts, 6.5 parts, calcium carbonate, silicon powder 3 parts, dibutyl tin laurate 4.5 parts, Magnesium Stearate 3.5 parts, thickening material 3.5 parts, thinner 3.5 parts, defoamer 6.5 parts, coupling agent 4 parts, propylene glycol monomethyl ether 5 parts, deionized water 19 parts.
The preparation method of a kind of oil resistance anticorrosion water-borne coatings that the present invention proposes, comprises the steps:
S1, by proportioning, Synolac, novolac epoxy, m-dimethyl benzene phenolic resin and dehydrated alcohol to be mixed, stir formation dispersion liquid, add butylated amino resin, hydroxyl third bromic acid resin and thinner again, be uniformly mixed rear ultrasonic disperse 25min, then talcum powder, organobentonite, silicon alloy powder, calcite, titanium dioxide, kaolin two and calcium carbonate is added, be cooled to room temperature after ball milling and obtain material a, Ball-milling Time is 50min, and ball milling temperature is 50 DEG C;
S2, methylcellulose gum is put into ball mill carry out ball milling, rotational speed of ball-mill is 2700r/min, and ball milling temperature is 70 DEG C, and Ball-milling Time is 55min, then adds silicon powder and Hydroxyethyl acrylate, continues to stir 12min, forms the mixed powder A of surface active;
S3, methylcellulose gum is heated to melting mixes with adjacent benzoic acid dibutylester, Isooctyl acrylate monomer, diethyl malonate, methyl methacrylate, aluminium triphosphate, zinc phosphate, then aluminium sesquioxide and clorafin is slowly added, homogenizer is moved to after stirring 50min with the speed of 800 revs/min, add material a and mixed powder A, with the Rate Dispersion 35min of 3800 revs/min, obtain mixed slurry;
S4, in mixed slurry, add dibutyl tin laurate, Magnesium Stearate, thickening material, defoamer, coupling agent, propylene glycol monomethyl ether and deionized water lentamente, 40min is stirred with the speed of 415r/min, then Ball milling 2.5h, obtains oil resistance anticorrosion water-borne coatings.
Embodiment 2
A kind of oil resistance anticorrosion water-borne coatings that the present invention proposes, its raw material comprises by weight: Synolac 80 parts, novolac epoxy 50 parts, m-dimethyl benzene phenolic resin 5 parts, butylated amino resin 9 parts, hydroxyl third bromic acid resin 5 parts, adjacent benzoic acid dibutylester 8 parts, Hydroxyethyl acrylate 2 parts, Isooctyl acrylate monomer 6 parts, diethyl malonate 1 part, methyl methacrylate 8 parts, aluminium triphosphate 2 parts, zinc phosphate 5 parts, dehydrated alcohol 3 parts, aluminium sesquioxide 9 parts, clorafin 4 parts, methylcellulose gum 8 parts, talcum powder 1 part, organobentonite 8 parts, 2 parts, silicon alloy powder, 6 parts, calcite, Zinic stearas 4 parts, titanium dioxide 9 parts, kaolin 2 parts, 9 parts, calcium carbonate, silicon powder 1 part, dibutyl tin laurate 7 parts, Magnesium Stearate 1 part, thickening material 6 parts, thinner 2 parts, defoamer 9 parts, coupling agent 2 parts, propylene glycol monomethyl ether 6 parts, deionized water 12 parts.
The preparation method of a kind of oil resistance anticorrosion water-borne coatings that the present invention proposes, comprises the steps:
S1, by proportioning, Synolac, novolac epoxy, m-dimethyl benzene phenolic resin and dehydrated alcohol to be mixed, stir formation dispersion liquid, add butylated amino resin, hydroxyl third bromic acid resin and thinner again, be uniformly mixed rear ultrasonic disperse 20min, then talcum powder, organobentonite, silicon alloy powder, calcite, titanium dioxide, kaolin two and calcium carbonate is added, be cooled to room temperature after ball milling and obtain material a, Ball-milling Time is 60min, and ball milling temperature is 45 DEG C;
S2, methylcellulose gum is put into ball mill carry out ball milling, rotational speed of ball-mill is 2900r/min, and ball milling temperature is 60 DEG C, and Ball-milling Time is 65min, then adds silicon powder and Hydroxyethyl acrylate, continues to stir 8min, forms the mixed powder A of surface active;
S3, methylcellulose gum is heated to melting mixes with adjacent benzoic acid dibutylester, Isooctyl acrylate monomer, diethyl malonate, methyl methacrylate, aluminium triphosphate, zinc phosphate, then aluminium sesquioxide and clorafin is slowly added, homogenizer is moved to after stirring 40min with the speed of 1000 revs/min, add material a and mixed powder A, with the Rate Dispersion 20min of 3900 revs/min, obtain mixed slurry;
S4, in mixed slurry, add dibutyl tin laurate, Magnesium Stearate, thickening material, defoamer, coupling agent, propylene glycol monomethyl ether and deionized water lentamente, 35min is stirred with the speed of 450r/min, then Ball milling 3h, obtains oil resistance anticorrosion water-borne coatings.
Embodiment 3
A kind of oil resistance anticorrosion water-borne coatings that the present invention proposes, its raw material comprises by weight: Synolac 120 parts, novolac epoxy 20 parts, m-dimethyl benzene phenolic resin 15 parts, butylated amino resin 2 parts, hydroxyl third bromic acid resin 15 parts, adjacent benzoic acid dibutylester 3 parts, Hydroxyethyl acrylate 9 parts, Isooctyl acrylate monomer 3 parts, diethyl malonate 8 parts, methyl methacrylate 2 parts, aluminium triphosphate 6 parts, zinc phosphate 1 part, dehydrated alcohol 6 parts, aluminium sesquioxide 3 parts, clorafin 9 parts, methylcellulose gum 2 parts, talcum powder 7 parts, organobentonite 3 parts, 9 parts, silicon alloy powder, 1 part, calcite, Zinic stearas 8 parts, titanium dioxide 2 parts, kaolin 6 parts, 4 parts, calcium carbonate, silicon powder 5 parts, dibutyl tin laurate 2 parts, Magnesium Stearate 6 parts, thickening material 1 part, thinner 5 parts, defoamer 4 parts, coupling agent 6 parts, propylene glycol monomethyl ether 4 parts, deionized water 26 parts.
The preparation method of a kind of oil resistance anticorrosion water-borne coatings that the present invention proposes, comprises the steps:
S1, by proportioning, Synolac, novolac epoxy, m-dimethyl benzene phenolic resin and dehydrated alcohol to be mixed, stir formation dispersion liquid, add butylated amino resin, hydroxyl third bromic acid resin and thinner again, be uniformly mixed rear ultrasonic disperse 30min, then talcum powder, organobentonite, silicon alloy powder, calcite, titanium dioxide, kaolin two and calcium carbonate is added, be cooled to room temperature after ball milling and obtain material a, Ball-milling Time is 40min, and ball milling temperature is 55 DEG C;
S2, methylcellulose gum is put into ball mill carry out ball milling, rotational speed of ball-mill is 2500r/min, and ball milling temperature is 80 DEG C, and Ball-milling Time is 65min, then adds silicon powder and Hydroxyethyl acrylate, continues to stir 16min, forms the mixed powder A of surface active;
S3, methylcellulose gum is heated to melting mixes with adjacent benzoic acid dibutylester, Isooctyl acrylate monomer, diethyl malonate, methyl methacrylate, aluminium triphosphate, zinc phosphate, then aluminium sesquioxide and clorafin is slowly added, homogenizer is moved to after stirring 60min with the speed of 600 revs/min, add material a and mixed powder A, with the Rate Dispersion 50min of 3700 revs/min, obtain mixed slurry;
S4, in mixed slurry, add dibutyl tin laurate, Magnesium Stearate, thickening material, defoamer, coupling agent, propylene glycol monomethyl ether and deionized water lentamente, 45min is stirred with the speed of 380r/min, then Ball milling 2h, obtains oil resistance anticorrosion water-borne coatings.
Embodiment 4
A kind of oil resistance anticorrosion water-borne coatings that the present invention proposes, its raw material comprises by weight: Synolac 85 parts, novolac epoxy 45 parts, m-dimethyl benzene phenolic resin 8 parts, butylated amino resin 8 parts, hydroxyl third bromic acid resin 8 parts, adjacent benzoic acid dibutylester 7 parts, Hydroxyethyl acrylate 3 parts, Isooctyl acrylate monomer 5 parts, diethyl malonate 2 parts, methyl methacrylate 7 parts, aluminium triphosphate 3 parts, zinc phosphate 4 parts, dehydrated alcohol 4 parts, aluminium sesquioxide 8 parts, clorafin 5 parts, methylcellulose gum 7 parts, talcum powder 2 parts, organobentonite 7 parts, 3 parts, silicon alloy powder, 5 parts, calcite, Zinic stearas 5 parts, titanium dioxide 8 parts, kaolin 3 parts, 8 parts, calcium carbonate, silicon powder 2 parts, dibutyl tin laurate 6 parts, Magnesium Stearate 2 parts, thickening material 5 parts, thinner 3 parts, defoamer 8 parts, coupling agent 3 parts, propylene glycol monomethyl ether 5.5 parts, deionized water 14 parts.
The preparation method of a kind of oil resistance anticorrosion water-borne coatings that the present invention proposes, comprises the steps:
S1, by proportioning, Synolac, novolac epoxy, m-dimethyl benzene phenolic resin and dehydrated alcohol to be mixed, stir formation dispersion liquid, add butylated amino resin, hydroxyl third bromic acid resin and thinner again, be uniformly mixed rear ultrasonic disperse 22min, then talcum powder, organobentonite, silicon alloy powder, calcite, titanium dioxide, kaolin two and calcium carbonate is added, be cooled to room temperature after ball milling and obtain material a, Ball-milling Time is 55min, and ball milling temperature is 48 DEG C;
S2, methylcellulose gum is put into ball mill carry out ball milling, rotational speed of ball-mill is 2800r/min, and ball milling temperature is 65 DEG C, and Ball-milling Time is 60min, then adds silicon powder and Hydroxyethyl acrylate, continues to stir 9min, forms the mixed powder A of surface active;
S3, methylcellulose gum is heated to melting mixes with adjacent benzoic acid dibutylester, Isooctyl acrylate monomer, diethyl malonate, methyl methacrylate, aluminium triphosphate, zinc phosphate, then aluminium sesquioxide and clorafin is slowly added, homogenizer is moved to after stirring 45min with the speed of 900 revs/min, add material a and mixed powder A, with the Rate Dispersion 25min of 3850 revs/min, obtain mixed slurry;
S4, in mixed slurry, add dibutyl tin laurate, Magnesium Stearate, thickening material, defoamer, coupling agent, propylene glycol monomethyl ether and deionized water lentamente, 38min is stirred with the speed of 440r/min, then Ball milling 2.8h, obtains oil resistance anticorrosion water-borne coatings.
Embodiment 5
A kind of oil resistance anticorrosion water-borne coatings that the present invention proposes, its raw material comprises by weight: Synolac 115 parts, novolac epoxy 25 parts, m-dimethyl benzene phenolic resin 12 parts, butylated amino resin 3 parts, hydroxyl third bromic acid resin 12 parts, adjacent benzoic acid dibutylester 4 parts, Hydroxyethyl acrylate 8 parts, Isooctyl acrylate monomer 4 parts, diethyl malonate 7 parts, methyl methacrylate 3 parts, aluminium triphosphate 5 parts, zinc phosphate 2 parts, dehydrated alcohol 5 parts, aluminium sesquioxide 4 parts, clorafin 8 parts, methylcellulose gum 3 parts, talcum powder 6 parts, organobentonite 4 parts, 8 parts, silicon alloy powder, 2 parts, calcite, Zinic stearas 7 parts, titanium dioxide 3 parts, kaolin 5 parts, 5 parts, calcium carbonate, silicon powder 4 parts, dibutyl tin laurate 3 parts, Magnesium Stearate 5 parts, thickening material 2 parts, thinner 4 parts, defoamer 5 parts, coupling agent 5 parts, propylene glycol monomethyl ether 5.5 parts, deionized water 14 parts.
The preparation method of a kind of oil resistance anticorrosion water-borne coatings that the present invention proposes, comprises the steps:
S1, by proportioning, Synolac, novolac epoxy, m-dimethyl benzene phenolic resin and dehydrated alcohol to be mixed, stir formation dispersion liquid, add butylated amino resin, hydroxyl third bromic acid resin and thinner again, be uniformly mixed rear ultrasonic disperse 28min, then talcum powder, organobentonite, silicon alloy powder, calcite, titanium dioxide, kaolin two and calcium carbonate is added, be cooled to room temperature after ball milling and obtain material a, Ball-milling Time is 45min, and ball milling temperature is 52 DEG C;
S2, methylcellulose gum is put into ball mill carry out ball milling, rotational speed of ball-mill is 2600r/min, and ball milling temperature is 75 DEG C, and Ball-milling Time is 50min, then adds silicon powder and Hydroxyethyl acrylate, continues to stir 15min, forms the mixed powder A of surface active;
S3, methylcellulose gum is heated to melting mixes with adjacent benzoic acid dibutylester, Isooctyl acrylate monomer, diethyl malonate, methyl methacrylate, aluminium triphosphate, zinc phosphate, then aluminium sesquioxide and clorafin is slowly added, homogenizer is moved to after stirring 55min with the speed of 700 revs/min, add material a and mixed powder A, with the Rate Dispersion 45min of 3750 revs/min, obtain mixed slurry;
S4, in mixed slurry, add dibutyl tin laurate, Magnesium Stearate, thickening material, defoamer, coupling agent, propylene glycol monomethyl ether and deionized water lentamente, 42min is stirred with the speed of 390r/min, then Ball milling 2.2h, obtains oil resistance anticorrosion water-borne coatings.
The above; be only the present invention's preferably embodiment; but protection scope of the present invention is not limited thereto; anyly be familiar with those skilled in the art in the technical scope that the present invention discloses; be equal to according to technical scheme of the present invention and inventive concept thereof and replace or change, all should be encompassed within protection scope of the present invention.
Claims (8)
1. an oil resistance anticorrosion water-borne coatings, is characterized in that, its raw material comprises by weight: Synolac 80-120 part, novolac epoxy 20-50 part, m-dimethyl benzene phenolic resin 5-15 part, butylated amino resin 2-9 part, hydroxyl third bromic acid resin 5-15 part, adjacent benzoic acid dibutylester 3-8 part, Hydroxyethyl acrylate 2-9 part, Isooctyl acrylate monomer 3-6 part, diethyl malonate 1-8 part, methyl methacrylate 2-8 part, aluminium triphosphate 2-6 part, zinc phosphate 1-5 part, dehydrated alcohol 3-6 part, aluminium sesquioxide 3-9 part, clorafin 4-9 part, methylcellulose gum 2-8 part, talcum powder 1-7 part, organobentonite 3-8 part, silicon alloy powder 2-9 part, calcite 1-6 part, Zinic stearas 4-8 part, titanium dioxide 2-9 part, kaolin 2-6 part, calcium carbonate 4-9 part, silicon powder 1-5 part, dibutyl tin laurate 2-7 part, Magnesium Stearate 1-6 part, thickening material 1-6 part, thinner 2-5 part, defoamer 4-9 part, coupling agent 2-6 part, propylene glycol monomethyl ether 4-6 part, deionized water 12-26 part.
2. oil resistance anticorrosion water-borne coatings according to claim 1, it is characterized in that, the weight ratio of Synolac, novolac epoxy, m-dimethyl benzene phenolic resin, butylated amino resin, hydroxyl third bromic acid resin and deionized water is 80-120:25-45:8-12:3-8:6-14:14-24.
3. oil resistance anticorrosion water-borne coatings according to claim 1 and 2, is characterized in that, the weight ratio of adjacent benzoic acid dibutylester, Hydroxyethyl acrylate, Isooctyl acrylate monomer, diethyl malonate and methyl methacrylate is 4-7:3-8:4-5:2-7:3-7.
4. the oil resistance anticorrosion water-borne coatings according to any one of claim 1-3, is characterized in that, the weight ratio of aluminium triphosphate, zinc phosphate and dehydrated alcohol is 3-5:2-4:4-5.
5. the oil resistance anticorrosion water-borne coatings according to any one of claim 1-4, is characterized in that, its raw material comprises by weight: Synolac 85-115 part, novolac epoxy 25-45 part, m-dimethyl benzene phenolic resin 8-12 part, butylated amino resin 3-8 part, hydroxyl third bromic acid resin 6-14 part, adjacent benzoic acid dibutylester 4-7 part, Hydroxyethyl acrylate 3-8 part, Isooctyl acrylate monomer 4-5 part, diethyl malonate 2-7 part, methyl methacrylate 3-7 part, aluminium triphosphate 3-5 part, zinc phosphate 2-4 part, dehydrated alcohol 4-5 part, aluminium sesquioxide 4-8 part, clorafin 5-8 part, methylcellulose gum 3-7 part, talcum powder 2-6 part, organobentonite 4-7 part, silicon alloy powder 3-8 part, calcite 2-5 part, Zinic stearas 5-7 part, titanium dioxide 3-8 part, kaolin 3-5 part, calcium carbonate 5-8 part, silicon powder 2-4 part, dibutyl tin laurate 3-6 part, Magnesium Stearate 2-5 part, thickening material 2-5 part, thinner 3-4 part, defoamer 5-8 part, coupling agent 3-5 part, propylene glycol monomethyl ether 4.5-5.5 part, deionized water 14-24 part.
6. a preparation method for the oil resistance anticorrosion water-borne coatings according to any one of claim 1-5, is characterized in that, comprise the steps:
S1, by proportioning, Synolac, novolac epoxy, m-dimethyl benzene phenolic resin and dehydrated alcohol to be mixed, stir formation dispersion liquid, add butylated amino resin, hydroxyl third bromic acid resin and thinner again, be uniformly mixed rear ultrasonic disperse 20-30min, then add talcum powder, organobentonite, silicon alloy powder, calcite, titanium dioxide, kaolin two and calcium carbonate, be cooled to room temperature after ball milling and obtain material a;
S2, methylcellulose gum is put into ball mill carry out ball milling, then add silicon powder and Hydroxyethyl acrylate, continue to stir 8-16min, form the mixed powder A of surface active;
S3, methylcellulose gum is heated to melting mixes with adjacent benzoic acid dibutylester, Isooctyl acrylate monomer, diethyl malonate, methyl methacrylate, aluminium triphosphate, zinc phosphate, then aluminium sesquioxide and clorafin is slowly added, homogenizer is moved to after stirring 40-60min with the speed of 600-1000 rev/min, add material a and mixed powder A, with the Rate Dispersion 20-50min of 3700-3900 rev/min, obtain mixed slurry;
S4, in mixed slurry, add dibutyl tin laurate, Magnesium Stearate, thickening material, defoamer, coupling agent, propylene glycol monomethyl ether and deionized water lentamente, 35-45min is stirred with the speed of 380-450r/min, then Ball milling 2-3h, obtains oil resistance anticorrosion water-borne coatings.
7. the preparation method of high-strength abrasion-proof extinguishing waterborn coating according to claim 6, is characterized in that, in S1, Ball-milling Time is 40-60min, and ball milling temperature is 45-55 DEG C.
8. the preparation method of the high-strength abrasion-proof extinguishing waterborn coating according to claim 6 or 7, is characterized in that, in S2, rotational speed of ball-mill is 2500-2900r/min, and ball milling temperature is 60-80 DEG C, and Ball-milling Time is 45-65min.
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| CN105936795A (en) * | 2016-06-08 | 2016-09-14 | 张悦 | Preparation method of Tenebrio molitor culture wooden case inner wall paint |
| CN105949952A (en) * | 2016-06-08 | 2016-09-21 | 张悦 | Method for manufacturing smooth coating on inner wall of tenebrio molitor breeding wood case |
| CN106085102A (en) * | 2016-06-08 | 2016-11-09 | 张悦 | A kind of coating in tenebrio molitor cultivation wooden case |
| CN106010140A (en) * | 2016-06-29 | 2016-10-12 | 安徽正石新型建材有限公司 | Weather-proof hydrophobic coating for plastic pipe surface |
| CN106047105A (en) * | 2016-07-18 | 2016-10-26 | 天长市巨龙车船涂料有限公司 | Alkyd resin paint special for stainless steel |
| CN106147555A (en) * | 2016-07-19 | 2016-11-23 | 董芬芳 | A kind of metal aluminium triphosphate antirusting paint |
| CN106243995A (en) * | 2016-08-01 | 2016-12-21 | 安庆瑞泰化工有限公司 | A kind of water paint of oil resistant and preparation method thereof |
| CN106800807A (en) * | 2017-02-20 | 2017-06-06 | 北京富瑞雪科技发展有限公司 | A kind of waterproof and oilproof woodwork water paint and preparation method thereof |
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| CN107432632A (en) * | 2017-08-31 | 2017-12-05 | 苏州龙行洲实业有限公司 | A kind of wear-resisting Display Rack of Portable, environmental protective |
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Application publication date: 20151230 |