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CN1051750A - Lnoganic medium heat-conducting material - Google Patents

Lnoganic medium heat-conducting material Download PDF

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Publication number
CN1051750A
CN1051750A CN 89108521 CN89108521A CN1051750A CN 1051750 A CN1051750 A CN 1051750A CN 89108521 CN89108521 CN 89108521 CN 89108521 A CN89108521 A CN 89108521A CN 1051750 A CN1051750 A CN 1051750A
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渠玉芝
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Abstract

The present invention relates to the heat conducting material technology.Material of the present invention is the mixture of being made up of multiple metallic element and multiple inorganic elements reagent.Metallic element comprises strontium, beryllium, sodium, titanium, cobalt, chromium, potassium, lawrencium etc.Inorganic elements reagent comprises EF-44, CH-104, ZH-104, HTM, TX-206, X-301 etc.This medium excites after being heated, and produces physical reaction association simultaneously heating.Its heat conduction efficiency exceeds routine.Hold out broad prospects utilizing on the waste heat.

Description

Lnoganic medium heat-conducting material
The invention belongs to the heat-conduction medium material, particularly under specific temperature, accept to excite element to induce and make the medium a kind of efficient heat conducting material of intensification rapidly.
In heat passage technical field, realize that the high duty heat transfer of certain distance often adopts thermal convection technology, for example hot pipe technique at present.Adopting the thermal convection technology is that to rely on working fluid to inhale in continuous circulation to put latent heat to realize heat passage, and its shortcoming is the system architecture complexity, the running cost height.Adopt the thermal conduction technology realize heat passage can simplied system structure, but still have nothing to do in the report of high-efficiency thermal conductive material both at home and abroad at present.
The objective of the invention is to propose a kind of technical scheme of novel heat-conduction medium material, open up new thermal conduction technical field, change or replace the thermal convection technology of at present heat passage middle application with material of the present invention.
Heat-conduction medium material of the present invention all is made of inorganic materials, is a kind of thermally conductive material of multiple metallic element composition and mixture of the heat conduction exciting agent that multiple inorganic elements reagent is formed of having comprised.The multiple metallic element that material of the present invention adopts is the whole or wherein several elements among sodium, potassium, beryllium, strontium, titanium, chromium, cobalt, the lawrencium various element.Outside above-mentioned metallic element, can also mix other metallic element.The multiple inorganic elements reagent that material of the present invention adopts is CH-104, ZH-104, EF-44, HTM or HTM-40, XT-206 or XT-206 and relevant rail guide element mixed thing, all kinds of reagent such as X-301, boron oxide (containing crystal water), peroxidation boron whole or wherein several.Multiple metallic element is participated in the material best results that is mixed with the simple substance form, and its shared weight percent is no more than 10% and is advisable.All the other are multiple inorganic elements reagent.Aforesaid multiple metallic element also can adopt compound form to participate in material and be mixed, and the suitable thermal conduction effect preferably that also has is mixed.When being mixed with compound form participation material, the shared weight percent of metallic element gross weight is advisable to be no more than 12%, and all the other are inorganic elements reagent.More than multiple weight metal per-cent do not comprise other metal ingredient of not addressing, can mix.
Material of the present invention can have multiple mixing formula in aforementioned range.
The embodiment of material of the present invention is as follows: (all being weight percentage)
Prescription one:
Strontium accounts for 1.25%, and beryllium accounts for 1.38%, and sodium accounts for 1.95%, and EF-44 accounts for 29.2%, and CH-104 accounts for 26.19%, and HTM-40 accounts for 13.88%, and TX-206 or TX-206 and the relevant rail guide element composition that is mixed accounts for 26.15%.
Prescription two:
Strontium accounts for 1.25%, beryllium accounts for 1.38%, sodium accounts for 1.95%, titanium accounts for 1.50%, EF-44 accounts for 27.7%, CH-104 accounts for 26.19%, and HTM or HTM-40 account for 13.88%, and TX-206 or TX-206 and the relevant rail guide element composition that is mixed accounts for 26.15%.
Prescription three:
Strontium accounts for 1.25%, beryllium accounts for 1.38%, sodium accounts for 1.95%, EF-44 accounts for 21.5%, and CH-104 accounts for 18.5%, HTM or HTM-40 account for 6.32%, TX-206 or TX-206 and relevant rail guide element are mixed, and composition accounts for 18.5%, X-301 accounts for 30.6%.
Prescription four:
Sodium accounts for 1.95%, strontium accounts for 1.25%, beryllium accounts for 1.38%, titanium accounts for 1.50%, lawrencium accounts for 1.50%, EF-44 accounts for 27.7%, CH-104 accounts for 26.19%, HTM or HTM-40 account for 12.38%, and TX-206 or TX-206 and the relevant rail guide element composition that is mixed accounts for 26.15%.
Prescription five:
Sodium accounts for 1.95%, beryllium accounts for 1.38%, cobalt accounts for 1.25%, titanium accounts for 1.5%, EF-44 accounts for 29.2%, CH-104 accounts for 26.19%, and HTM or HTM-40 account for 13.88%, TX-206 or TX-206 and relevant rail guide element are mixed, and composition accounts for 24.65%.
Prescription six:
Strontium accounts for 1.25%, beryllium accounts for 1.38%, sodium accounts for 1.95%, titanium accounts for 1.50%, cobalt accounts for 1.45%, lawrencium accounts for 1.40%, EF-44 accounts for 27.75%, CH-104 accounts for 26.14%, HTM or HTM-40 account for 12.33%, TX-206 or TX-206 and relevant rail guide element are mixed, and composition accounts for 24.85%.
Prescription seven:
Strontium accounts for 1.25%, beryllium accounts for 1.38%, sodium accounts for 1.95%, titanium accounts for 1.50%, cobalt accounts for 1.45%, lawrencium accounts for 1.40%, CH-104 accounts for 26.19%, HTM or HTM-40 account for 12.43%, TX-206 or TX-206 and relevant rail guide element are mixed, and composition accounts for 24.75%, EF-44 accounts for 27.7%.
Prescription eight:
Strontium accounts for 1.25%, beryllium accounts for 1.38%, titanium accounts for 1.55%, cobalt accounts for 2.15%, lawrencium accounts for 1.45%, EF-44 accounts for 28.70%, CH-104 accounts for 26.26%, and HTM or HTM-40 account for 12.48%, TX-206 or TX-206 and relevant rail guide element are mixed, and composition accounts for 24.78%.
Prescription nine:
Beryllium hydroxide accounts for 12%, strontium hydroxide accounts for 1.5%, potassium bichromate accounts for 18%, and sodium dichromate 99 accounts for 2%, ammonium chromate accounts for 5%, lawrencium accounts for 0.4%, boron oxide (containing crystal water) accounts for 4%, peroxidation boron accounts for 0.5%, CH-104 accounts for 0.6%, ZH-104 accounts for 30%, TX-206 accounts for 25%, EF-44 accounts for 0.5%, HTM-40 accounts for 0.5%.
The scope of setting forth according to technical solution of the present invention can also design some assembly sides.
Material of the present invention must be operated under 15~20 ℃ normal temperature in the process of being mixed with.The sodium Metal 99.5 element should carry out participating in after the oxide treatment and is mixed.Material of the present invention should be preserved under normal temperature, lucifuge condition.
The using method of dielectric material of the present invention is that utilization excites and the passivation means are plated in this dielectric material on the heat conducting element inwall, forms the heat-conduction medium rete.Under specific temperature, the metallic element in the medium is induced by the exciting of element that excite in the heat conduction exciting agent, heats up rapidly and produces physical transformation, realizes the thermal conduction of element.When specified temp disappeared, dielectric material of the present invention just recovered ortho states.Said process can repeatedly repeat and dielectric material does not change.Adopt the heat-conduction component of this media coating can adopt metallic substance to manufacture, also can adopt ceramic to manufacture.The structure of heat-conduction component is advisable so that thermal conductive cavity to be arranged in the sealing negative pressure, and this dielectric material forms the thermal conduction rete on the inwall of negative pressure inner chamber, can rapidly thermal energy conduction be arrived the other end in the heating of an end of heat conducting element.In having required the sealing negative pressure, the thermal conductive cavity, adopt this dielectric material that structure, the shape of heat-conduction component are not had particular requirement; Can design according to application need: can grow, can lack; Can be square, Keyuan Garden; Flexible, revolution; Can be in a tubular form or sheet.Thermal conduction effect is unaffected.Adopt material of the present invention, in heat transfer process, also can association generate heat, make the thermo-efficiency of heat-conduction component exceed routine because dielectric material produces the physical transformation phenomenon.
A kind of embodiment of material using method of the present invention is:
Inwall at first that heat-conduction component is to be coated cleans up and does Passivation Treatment, and the powder of the material of the present invention of packing into then is again with the thermal conductive cavity sealed after being vacuumized of element.Be heated to specified temp for the element that disposes, for example 100 ℃, the dielectric material of the present invention in the airtight negative pressure inner chamber just can be induced and be excited, and is plated on film forming on the internal chamber wall.So far, heat-conduction component is manufactured and is finished.
Another kind of simple making method is the element bore seal that Passivation Treatment is finished, at one end make a call to an aperture then, load material of the present invention by aperture to the element inner chamber, heating there is not the other end of punching then, material of the present invention is subjected to after the thermal excitation from the outside exhaust of aperture, in moment that air discharging finishes closed pores immediately, and little eyelet welding is dead.Heat-conduction component is manufactured and is finished.
Dielectric material of the present invention has long work-ing life.Measure according to inspection center of the Ministry of Aerospace Industry, adopt the dielectric material of the present invention of multiple metallic element mixture, in sealing negative pressure Working environment, can use continuously 110,000 hours.
Adopt the system architecture of dielectric material making heat-conduction component of the present invention simple, running cost is low.Dielectric material of the present invention is can be stimulated about 50 ℃ in temperature, and conducts heat energy rapidly, for recovery waste heat has been opened up wide prospect.

Claims (17)

1, a kind of heat-conduction medium material the invention is characterized in that described dielectric material is to have comprised the thermally conductive material of multiple metallic element composition and the mixture of the heat conduction exciting agent that multiple first machine element reagent is formed.
2, dielectric material as claimed in claim 1 is characterized in that described multiple metallic element is the whole or several metallic elements among sodium, potassium, beryllium, strontium, titanium, chromium, cobalt, the lawrencium, can also mix other metallic element outside above-mentioned element.
3, dielectric material as claimed in claim 1, it is characterized in that described multiple inorganic elements reagent is CH-104, ZH-104, EF-44, HTM or HTM-40, XT-206 or XT-206 and relevant rail guide element mixed thing and X-301, boron oxide (containing crystal water), all kinds of reagent such as peroxidation boron whole or wherein several.
4, dielectric material as claimed in claim 2, it is characterized in that described multiple metallic element is mixed with simple substance form participation material, its shared weight percent is no more than 10%, all the other are multiple inorganic elements reagent, also can adopt the metallic compound form to participate in material and be mixed, then the shared weight percent of metallic element is advisable to be no more than 12%, and all the other are inorganic elements reagent, more than multiple weight metal per-cent do not comprise and do not address other metal ingredient that can mix.
5, as claim 1,2,3 or 4 described dielectric materials, it is characterized in that the weight percent of each composition is that strontium accounts for 1.25% in the mixture, beryllium accounts for 1.38%, sodium accounts for 1.95%, EF-44 accounts for 29.2%, CH-104 accounts for 26.19%, and HTM-40 accounts for 13.88%, and TX-206 or TX-206 and the relevant rail guide element composition that is mixed accounts for 26.15%.
6, as claim 1,2,3 or 4 described dielectric materials, it is characterized in that in the mixture that each composition and weight percent thereof are that strontium accounts for 1.25%, beryllium accounts for 1.38%, sodium accounts for 1.95%, titanium accounts for 1.50%, and EF-44 accounts for 27.7%, and CH-104 accounts for 26.19%, HTM or HTM-40 account for 13.88%, and TX-206 or itself and the relevant rail guide element composition that is mixed accounts for 26.15%.
7, as claim 1,2,3 or 4 described dielectric materials, it is characterized in that each composition of mixture and weight percent thereof are: strontium accounts for 1.25%, beryllium accounts for 1.38%, sodium accounts for 1.95%, EF-44 accounts for 21.5%, and CH-104 accounts for 18.5%, and HTM or HTM-40 account for 6.32%, TX-206 or itself and the relevant rail guide element composition that is mixed accounts for 18.5%, and X-301 accounts for 30.6%.
8, as claim 1,2,3 or 4 described dielectric materials, it is characterized in that each composition of mixture and weight percent thereof are: sodium accounts for 1.95%, strontium accounts for 1.25%, beryllium accounts for 1.38%, and titanium accounts for 1.50%, and lawrencium accounts for 1.50%, EF-44 accounts for 27.7%, CH-104 accounts for 26.19%, and HTM or HTM-40 account for 12.38%, and TX-206 or TX-206 and the relevant rail guide element composition that is mixed accounts for 26.15%.
9, as claim 1,2,3 or 4 described dielectric materials, it is characterized in that in the mixture that each composition and weight percent thereof are: sodium accounts for 1.95%, beryllium accounts for 1.38%, cobalt accounts for 1.25%, titanium accounts for 1.5%, and EF-44 accounts for 29.2%, and CH-104 accounts for 26.19%, HTM or HTM-40 account for 13.88%, and TX-206 or TX-206 and the relevant rail guide element composition that is mixed accounts for 24.65%.
10, as claim 1,2,3 or 4 described dielectric materials, the composition and the weight percent thereof that it is characterized in that mixture are: strontium accounts for 1.25%, beryllium accounts for 1.38%, and sodium accounts for 1.95%, and titanium accounts for 1.50%, cobalt accounts for 1.45%, lawrencium accounts for 1.40%, and EF-44 accounts for 27.75%, and CH-104 accounts for 26.14%, HTM or HTM-40 account for 12.33%, and TX-206 or TX-206 and the relevant rail guide element composition that is mixed accounts for 24.85%.
11, as claim 1,2,3 or 4 described dielectric materials, it is characterized in that in the mixture that each composition and weight percent thereof are: strontium accounts for 1.25%, beryllium accounts for 1.38%, and sodium accounts for 1.95%, and titanium accounts for 1.50%, cobalt accounts for 1.45%, lawrencium accounts for 1.40%, and EF-44 accounts for 27.7%, and CH-104 accounts for 26.19%, HTM-40 accounts for 12.43%, and TX-206 accounts for 24.75%.
12, as claim 1,2,3 or 4 described dielectric materials, the composition and the weight percent thereof that it is characterized in that mixture are: strontium accounts for 1.25%, beryllium accounts for 1.38%, titanium accounts for 1.55%, and cobalt accounts for 2.15%, and lawrencium accounts for 1.45%, EF-44 accounts for 28.7%, CH-104 accounts for 26.26%, and HTM or HTM-40 account for 12.48%, and TX-206 or TX-206 and the relevant rail guide element composition that is mixed accounts for 24.78%.
13, as claim 1,2,3 or 4 described dielectric materials, it is characterized in that in each composition of mixture, some metallic elements are participated in the material of compound form and are mixed, its composition and weight percent separately are: beryllium hydroxide accounts for 12%, strontium hydroxide accounts for 1.5%, potassium bichromate accounts for 18%, and sodium dichromate 99 accounts for 2%, and ammonium chromate accounts for 5%, lawrencium accounts for 0.4%, boron oxide (containing crystal water) accounts for 4%, and peroxidation boron accounts for 0.5%, and CH-104 accounts for 0.6%, ZH-104 accounts for 30%, TX-206 accounts for 25%, and EF-44 accounts for 0.5%, and HTM-40 accounts for 0.5%.
14, a kind of using method of Lnoganic medium heat-conducting material, it is characterized in that the utilization of this dielectric material excited and the passivation means are plated in and form the heat-conduction medium rete on the heat-conduction component inwall, heat-conduction component can adopt metallic substance to manufacture, and also can adopt ceramic to manufacture.
15, using method as claimed in claim 14 is characterized in that heat-conduction component has thermal conductive cavity in the sealing negative pressure, and the heat-conduction medium rete is plated on the thermal conductive cavity inwall.
16, as claim 14,15 described dielectric material using method, it is characterized in that inwall at first that heat-conduction component is to be coated cleans up and do Passivation Treatment, the dielectric material of packing into then, again with the thermal conductive cavity sealed after being vacuumized of element, give the element that disposes heating again, dielectric material is induced excite, and be plated on film forming on the internal chamber wall.
17, as claim 14,15 described dielectric material using method, it is characterized in that inwall at first that heat-conduction component is to be coated clean up and do Passivation Treatment after seal, at one end make a call to an aperture then, by aperture thorax filling material of the present invention in element, heating there is not the other end of punching then, dielectric material is subjected to after the thermal excitation from the outside exhaust of aperture, in moment that the air discharging finishes closed pores immediately, and little eyelet welding is dead.
CN 89108521 1989-11-15 1989-11-15 Lnoganic medium heat-conducting material Pending CN1051750A (en)

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CN 89108521 CN1051750A (en) 1989-11-15 1989-11-15 Lnoganic medium heat-conducting material

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CN 89108521 CN1051750A (en) 1989-11-15 1989-11-15 Lnoganic medium heat-conducting material

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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1042040C (en) * 1994-01-31 1999-02-10 中科院广州化学研究所 High heat conducting and electricity conducting solid-solid phase transformation thermal storage material
EP0948430A4 (en) * 1996-10-25 2003-04-16 Yuzhi Qu SUPERCONDUCTING HEAT TRANSFER MEDIUM
US6916430B1 (en) 1996-10-25 2005-07-12 New Qu Energy Ltd. Superconducting heat transfer medium
CN105571363A (en) * 2016-01-31 2016-05-11 浙江陆特能源科技股份有限公司 Coupling device for superconducting tubes
CN108729968A (en) * 2017-04-20 2018-11-02 欧亚光能源科技股份有限公司 Thermal energy power generation device
CN110699046A (en) * 2019-08-26 2020-01-17 山东龙光天旭太阳能有限公司 Superconductive heat transfer medium for solar vacuum heat collection tube and preparation method thereof

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1042040C (en) * 1994-01-31 1999-02-10 中科院广州化学研究所 High heat conducting and electricity conducting solid-solid phase transformation thermal storage material
EP0948430A4 (en) * 1996-10-25 2003-04-16 Yuzhi Qu SUPERCONDUCTING HEAT TRANSFER MEDIUM
US6916430B1 (en) 1996-10-25 2005-07-12 New Qu Energy Ltd. Superconducting heat transfer medium
CN105571363A (en) * 2016-01-31 2016-05-11 浙江陆特能源科技股份有限公司 Coupling device for superconducting tubes
CN108729968A (en) * 2017-04-20 2018-11-02 欧亚光能源科技股份有限公司 Thermal energy power generation device
CN108729968B (en) * 2017-04-20 2020-10-16 欧亚光能源科技股份有限公司 Thermal power generation device
CN110699046A (en) * 2019-08-26 2020-01-17 山东龙光天旭太阳能有限公司 Superconductive heat transfer medium for solar vacuum heat collection tube and preparation method thereof

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