CN105143423B - The method of thickening liquid detergent composition - Google Patents
The method of thickening liquid detergent composition Download PDFInfo
- Publication number
- CN105143423B CN105143423B CN201480024247.5A CN201480024247A CN105143423B CN 105143423 B CN105143423 B CN 105143423B CN 201480024247 A CN201480024247 A CN 201480024247A CN 105143423 B CN105143423 B CN 105143423B
- Authority
- CN
- China
- Prior art keywords
- amine
- composition
- acid
- sulfonic acid
- surfactant
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 111
- 238000000034 method Methods 0.000 title claims abstract description 65
- 230000008719 thickening Effects 0.000 title claims abstract description 35
- 239000003599 detergent Substances 0.000 title claims abstract description 29
- 239000007788 liquid Substances 0.000 title claims abstract description 27
- 150000001412 amines Chemical class 0.000 claims abstract description 55
- -1 alkylbenzene sulfonate Chemical class 0.000 claims abstract description 32
- 229920001577 copolymer Polymers 0.000 claims abstract description 30
- 239000003945 anionic surfactant Substances 0.000 claims abstract description 24
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 23
- 239000003513 alkali Substances 0.000 claims abstract description 22
- QJRVOJKLQNSNDB-UHFFFAOYSA-N 4-dodecan-3-ylbenzenesulfonic acid Chemical compound CCCCCCCCCC(CC)C1=CC=C(S(O)(=O)=O)C=C1 QJRVOJKLQNSNDB-UHFFFAOYSA-N 0.000 claims abstract description 11
- 238000006386 neutralization reaction Methods 0.000 claims abstract description 9
- 238000004519 manufacturing process Methods 0.000 claims abstract description 6
- 230000003472 neutralizing effect Effects 0.000 claims abstract description 4
- 239000004094 surface-active agent Substances 0.000 claims description 41
- 239000002253 acid Substances 0.000 claims description 35
- 239000003795 chemical substances by application Substances 0.000 claims description 31
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 30
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 claims description 23
- 239000003205 fragrance Substances 0.000 claims description 16
- 108090000790 Enzymes Proteins 0.000 claims description 15
- 102000004190 Enzymes Human genes 0.000 claims description 15
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims description 15
- 239000002585 base Substances 0.000 claims description 14
- 230000003213 activating effect Effects 0.000 claims description 9
- 238000002156 mixing Methods 0.000 claims description 9
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 8
- 238000004140 cleaning Methods 0.000 claims description 8
- 239000002738 chelating agent Substances 0.000 claims description 7
- 239000003086 colorant Substances 0.000 claims description 7
- 239000002563 ionic surfactant Substances 0.000 claims description 7
- 230000003165 hydrotropic effect Effects 0.000 claims description 6
- 239000003605 opacifier Substances 0.000 claims description 6
- 125000000129 anionic group Chemical group 0.000 claims description 5
- 150000005846 sugar alcohols Polymers 0.000 claims description 5
- 150000001335 aliphatic alkanes Chemical class 0.000 claims description 4
- 229940092714 benzenesulfonic acid Drugs 0.000 claims description 4
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 3
- 239000005864 Sulphur Substances 0.000 claims description 3
- SRSXLGNVWSONIS-UHFFFAOYSA-N benzenesulfonic acid Chemical compound OS(=O)(=O)C1=CC=CC=C1 SRSXLGNVWSONIS-UHFFFAOYSA-N 0.000 claims description 3
- 150000003839 salts Chemical class 0.000 claims description 3
- CMCBDXRRFKYBDG-UHFFFAOYSA-N 1-dodecoxydodecane Chemical compound CCCCCCCCCCCCOCCCCCCCCCCCC CMCBDXRRFKYBDG-UHFFFAOYSA-N 0.000 claims description 2
- 230000015572 biosynthetic process Effects 0.000 claims description 2
- 239000003755 preservative agent Substances 0.000 claims description 2
- 230000002335 preservative effect Effects 0.000 claims description 2
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims 2
- 239000004743 Polypropylene Substances 0.000 claims 1
- 150000005215 alkyl ethers Chemical class 0.000 claims 1
- 229920001155 polypropylene Polymers 0.000 claims 1
- 229910052938 sodium sulfate Inorganic materials 0.000 claims 1
- 235000011152 sodium sulphate Nutrition 0.000 claims 1
- 229920000642 polymer Polymers 0.000 description 59
- CERQOIWHTDAKMF-UHFFFAOYSA-N alpha-methacrylic acid Natural products CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 24
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 16
- 239000000178 monomer Substances 0.000 description 16
- SXHLENDCVBIJFO-UHFFFAOYSA-M sodium;2-[2-(2-dodecoxyethoxy)ethoxy]ethyl sulfate Chemical group [Na+].CCCCCCCCCCCCOCCOCCOCCOS([O-])(=O)=O SXHLENDCVBIJFO-UHFFFAOYSA-M 0.000 description 16
- 229920002125 Sokalan® Polymers 0.000 description 15
- 125000000217 alkyl group Chemical group 0.000 description 15
- 239000000463 material Substances 0.000 description 15
- 229940088598 enzyme Drugs 0.000 description 14
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 13
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 13
- 235000019441 ethanol Nutrition 0.000 description 13
- 229920002873 Polyethylenimine Polymers 0.000 description 11
- 150000001875 compounds Chemical class 0.000 description 11
- 229940057950 sodium laureth sulfate Drugs 0.000 description 11
- 238000007046 ethoxylation reaction Methods 0.000 description 10
- GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulfite Chemical compound [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 description 10
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 9
- 238000007792 addition Methods 0.000 description 9
- 229920000058 polyacrylate Polymers 0.000 description 9
- 239000003054 catalyst Substances 0.000 description 7
- 239000004615 ingredient Substances 0.000 description 7
- 229920005610 lignin Polymers 0.000 description 7
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 6
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 6
- 229920006243 acrylic copolymer Polymers 0.000 description 6
- 229910052799 carbon Inorganic materials 0.000 description 6
- 239000000975 dye Substances 0.000 description 6
- 150000002148 esters Chemical class 0.000 description 6
- 230000003287 optical effect Effects 0.000 description 6
- 125000001931 aliphatic group Chemical group 0.000 description 5
- 230000000694 effects Effects 0.000 description 5
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 5
- 238000012986 modification Methods 0.000 description 5
- 230000004048 modification Effects 0.000 description 5
- 239000000344 soap Substances 0.000 description 5
- 235000010265 sodium sulphite Nutrition 0.000 description 5
- 239000002562 thickening agent Substances 0.000 description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 4
- SOGAXMICEFXMKE-UHFFFAOYSA-N Butylmethacrylate Chemical compound CCCCOC(=O)C(C)=C SOGAXMICEFXMKE-UHFFFAOYSA-N 0.000 description 4
- DBVJJBKOTRCVKF-UHFFFAOYSA-N Etidronic acid Chemical compound OP(=O)(O)C(O)(C)P(O)(O)=O DBVJJBKOTRCVKF-UHFFFAOYSA-N 0.000 description 4
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 4
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 4
- 229910052783 alkali metal Inorganic materials 0.000 description 4
- 238000004061 bleaching Methods 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- 125000001183 hydrocarbyl group Chemical group 0.000 description 4
- 238000006116 polymerization reaction Methods 0.000 description 4
- 239000002243 precursor Substances 0.000 description 4
- 238000002360 preparation method Methods 0.000 description 4
- 230000008569 process Effects 0.000 description 4
- 229910052708 sodium Inorganic materials 0.000 description 4
- 239000011734 sodium Substances 0.000 description 4
- 159000000000 sodium salts Chemical class 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 4
- 229920002554 vinyl polymer Polymers 0.000 description 4
- 238000005406 washing Methods 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 3
- NOWKCMXCCJGMRR-UHFFFAOYSA-N Aziridine Chemical group C1CN1 NOWKCMXCCJGMRR-UHFFFAOYSA-N 0.000 description 3
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- 241000207199 Citrus Species 0.000 description 3
- ROSDSFDQCJNGOL-UHFFFAOYSA-N Dimethylamine Chemical compound CNC ROSDSFDQCJNGOL-UHFFFAOYSA-N 0.000 description 3
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 3
- 241000283986 Lepus Species 0.000 description 3
- 229920001732 Lignosulfonate Polymers 0.000 description 3
- 239000004367 Lipase Substances 0.000 description 3
- 108090001060 Lipase Proteins 0.000 description 3
- 102000004882 Lipase Human genes 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 230000002378 acidificating effect Effects 0.000 description 3
- 150000001340 alkali metals Chemical class 0.000 description 3
- 229960003237 betaine Drugs 0.000 description 3
- 150000001721 carbon Chemical group 0.000 description 3
- 125000002091 cationic group Chemical group 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 235000020971 citrus fruits Nutrition 0.000 description 3
- 238000004132 cross linking Methods 0.000 description 3
- 239000003431 cross linking reagent Substances 0.000 description 3
- 235000014113 dietary fatty acids Nutrition 0.000 description 3
- SYELZBGXAIXKHU-UHFFFAOYSA-N dodecyldimethylamine N-oxide Chemical compound CCCCCCCCCCCC[N+](C)(C)[O-] SYELZBGXAIXKHU-UHFFFAOYSA-N 0.000 description 3
- 239000000194 fatty acid Substances 0.000 description 3
- 229930195729 fatty acid Natural products 0.000 description 3
- 239000000835 fiber Substances 0.000 description 3
- 239000012530 fluid Substances 0.000 description 3
- 235000011187 glycerol Nutrition 0.000 description 3
- KWIUHFFTVRNATP-UHFFFAOYSA-N glycine betaine Chemical compound C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 3
- 239000001257 hydrogen Substances 0.000 description 3
- 229910052739 hydrogen Inorganic materials 0.000 description 3
- 238000011065 in-situ storage Methods 0.000 description 3
- 235000019421 lipase Nutrition 0.000 description 3
- 229910052757 nitrogen Inorganic materials 0.000 description 3
- 239000003921 oil Substances 0.000 description 3
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 3
- 238000012545 processing Methods 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 description 2
- ZTGKHKPZSMMHNM-UHFFFAOYSA-N 3-(2-phenylethenyl)benzene-1,2-disulfonic acid Chemical compound OS(=O)(=O)C1=CC=CC(C=CC=2C=CC=CC=2)=C1S(O)(=O)=O ZTGKHKPZSMMHNM-UHFFFAOYSA-N 0.000 description 2
- YGUMVDWOQQJBGA-VAWYXSNFSA-N 5-[(4-anilino-6-morpholin-4-yl-1,3,5-triazin-2-yl)amino]-2-[(e)-2-[4-[(4-anilino-6-morpholin-4-yl-1,3,5-triazin-2-yl)amino]-2-sulfophenyl]ethenyl]benzenesulfonic acid Chemical compound C=1C=C(\C=C\C=2C(=CC(NC=3N=C(N=C(NC=4C=CC=CC=4)N=3)N3CCOCC3)=CC=2)S(O)(=O)=O)C(S(=O)(=O)O)=CC=1NC(N=C(N=1)N2CCOCC2)=NC=1NC1=CC=CC=C1 YGUMVDWOQQJBGA-VAWYXSNFSA-N 0.000 description 2
- RKWGIWYCVPQPMF-UHFFFAOYSA-N Chloropropamide Chemical compound CCCNC(=O)NS(=O)(=O)C1=CC=C(Cl)C=C1 RKWGIWYCVPQPMF-UHFFFAOYSA-N 0.000 description 2
- 102100026735 Coagulation factor VIII Human genes 0.000 description 2
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 2
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 2
- 101000911390 Homo sapiens Coagulation factor VIII Proteins 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
- WOBHKFSMXKNTIM-UHFFFAOYSA-N Hydroxyethyl methacrylate Chemical compound CC(=C)C(=O)OCCO WOBHKFSMXKNTIM-UHFFFAOYSA-N 0.000 description 2
- 108091005804 Peptidases Proteins 0.000 description 2
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 2
- 239000004365 Protease Substances 0.000 description 2
- 102100037486 Reverse transcriptase/ribonuclease H Human genes 0.000 description 2
- PJANXHGTPQOBST-VAWYXSNFSA-N Stilbene Natural products C=1C=CC=CC=1/C=C/C1=CC=CC=C1 PJANXHGTPQOBST-VAWYXSNFSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 2
- 125000002339 acetoacetyl group Chemical group O=C([*])C([H])([H])C(=O)C([H])([H])[H] 0.000 description 2
- 150000004996 alkyl benzenes Chemical class 0.000 description 2
- 150000001408 amides Chemical class 0.000 description 2
- 239000002280 amphoteric surfactant Substances 0.000 description 2
- 150000001642 boronic acid derivatives Chemical class 0.000 description 2
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 229920006037 cross link polymer Polymers 0.000 description 2
- 238000000151 deposition Methods 0.000 description 2
- DUYCTCQXNHFCSJ-UHFFFAOYSA-N dtpmp Chemical compound OP(=O)(O)CN(CP(O)(O)=O)CCN(CP(O)(=O)O)CCN(CP(O)(O)=O)CP(O)(O)=O DUYCTCQXNHFCSJ-UHFFFAOYSA-N 0.000 description 2
- 238000005538 encapsulation Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- SUPCQIBBMFXVTL-UHFFFAOYSA-N ethyl 2-methylprop-2-enoate Chemical compound CCOC(=O)C(C)=C SUPCQIBBMFXVTL-UHFFFAOYSA-N 0.000 description 2
- STVZJERGLQHEKB-UHFFFAOYSA-N ethylene glycol dimethacrylate Chemical compound CC(=C)C(=O)OCCOC(=O)C(C)=C STVZJERGLQHEKB-UHFFFAOYSA-N 0.000 description 2
- 239000004744 fabric Substances 0.000 description 2
- 150000004665 fatty acids Chemical class 0.000 description 2
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 2
- YDSWCNNOKPMOTP-UHFFFAOYSA-N mellitic acid Chemical compound OC(=O)C1=C(C(O)=O)C(C(O)=O)=C(C(O)=O)C(C(O)=O)=C1C(O)=O YDSWCNNOKPMOTP-UHFFFAOYSA-N 0.000 description 2
- 238000004806 packaging method and process Methods 0.000 description 2
- HWGNBUXHKFFFIH-UHFFFAOYSA-I pentasodium;[oxido(phosphonatooxy)phosphoryl] phosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O HWGNBUXHKFFFIH-UHFFFAOYSA-I 0.000 description 2
- 239000002304 perfume Substances 0.000 description 2
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 2
- IEQIEDJGQAUEQZ-UHFFFAOYSA-N phthalocyanine Chemical compound N1C(N=C2C3=CC=CC=C3C(N=C3C4=CC=CC=C4C(=N4)N3)=N2)=C(C=CC=C2)C2=C1N=C1C2=CC=CC=C2C4=N1 IEQIEDJGQAUEQZ-UHFFFAOYSA-N 0.000 description 2
- 239000004584 polyacrylic acid Substances 0.000 description 2
- 229920000728 polyester Polymers 0.000 description 2
- 150000003138 primary alcohols Chemical class 0.000 description 2
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 2
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 2
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 2
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 241000894007 species Species 0.000 description 2
- 239000003381 stabilizer Substances 0.000 description 2
- 235000021286 stilbenes Nutrition 0.000 description 2
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 2
- 239000000725 suspension Substances 0.000 description 2
- VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical group ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 description 2
- 239000004753 textile Substances 0.000 description 2
- JCZPMGDSEAFWDY-SQOUGZDYSA-N (2r,3s,4r,5r)-2,3,4,5,6-pentahydroxyhexanamide Chemical compound NC(=O)[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO JCZPMGDSEAFWDY-SQOUGZDYSA-N 0.000 description 1
- VXWBQOJISHAKKM-UHFFFAOYSA-N (4-formylphenyl)boronic acid Chemical class OB(O)C1=CC=C(C=O)C=C1 VXWBQOJISHAKKM-UHFFFAOYSA-N 0.000 description 1
- JSYPRLVDJYQMAI-ODZAUARKSA-N (z)-but-2-enedioic acid;prop-2-enoic acid Chemical compound OC(=O)C=C.OC(=O)\C=C/C(O)=O JSYPRLVDJYQMAI-ODZAUARKSA-N 0.000 description 1
- LRGXCBHOBRUTJN-UHFFFAOYSA-N 1,1'-biphenyl;sodium Chemical compound [Na].[Na].C1=CC=CC=C1C1=CC=CC=C1 LRGXCBHOBRUTJN-UHFFFAOYSA-N 0.000 description 1
- KCZIUKYAJJEIQG-UHFFFAOYSA-N 1,3,5-triazin-2-amine Chemical compound NC1=NC=NC=N1 KCZIUKYAJJEIQG-UHFFFAOYSA-N 0.000 description 1
- IEORSVTYLWZQJQ-UHFFFAOYSA-N 2-(2-nonylphenoxy)ethanol Chemical compound CCCCCCCCCC1=CC=CC=C1OCCO IEORSVTYLWZQJQ-UHFFFAOYSA-N 0.000 description 1
- JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 description 1
- OMIGHNLMNHATMP-UHFFFAOYSA-N 2-hydroxyethyl prop-2-enoate Chemical compound OCCOC(=O)C=C OMIGHNLMNHATMP-UHFFFAOYSA-N 0.000 description 1
- QENRKQYUEGJNNZ-UHFFFAOYSA-N 2-methyl-1-(prop-2-enoylamino)propane-1-sulfonic acid Chemical class CC(C)C(S(O)(=O)=O)NC(=O)C=C QENRKQYUEGJNNZ-UHFFFAOYSA-N 0.000 description 1
- ITOLXGQFDAFXMV-UHFFFAOYSA-N 2-sulfanyltetradecanoic acid Chemical class CCCCCCCCCCCCC(S)C(O)=O ITOLXGQFDAFXMV-UHFFFAOYSA-N 0.000 description 1
- ZXVONLUNISGICL-UHFFFAOYSA-N 4,6-dinitro-o-cresol Chemical compound CC1=CC([N+]([O-])=O)=CC([N+]([O-])=O)=C1O ZXVONLUNISGICL-UHFFFAOYSA-N 0.000 description 1
- MXMWUQAFMKOTIQ-UHFFFAOYSA-N 4-(carboxymethoxy)-4-oxobutanoic acid Chemical class OC(=O)CCC(=O)OCC(O)=O MXMWUQAFMKOTIQ-UHFFFAOYSA-N 0.000 description 1
- DBCAQXHNJOFNGC-UHFFFAOYSA-N 4-bromo-1,1,1-trifluorobutane Chemical compound FC(F)(F)CCCBr DBCAQXHNJOFNGC-UHFFFAOYSA-N 0.000 description 1
- AJIZFKGVFSUKIP-UHFFFAOYSA-N 4-morpholin-4-yl-n-phenyl-1,3,5-triazin-2-amine Chemical compound C1COCCN1C1=NC=NC(NC=2C=CC=CC=2)=N1 AJIZFKGVFSUKIP-UHFFFAOYSA-N 0.000 description 1
- RZVAJINKPMORJF-UHFFFAOYSA-N Acetaminophen Chemical compound CC(=O)NC1=CC=C(O)C=C1 RZVAJINKPMORJF-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 1
- 239000004382 Amylase Substances 0.000 description 1
- 102000013142 Amylases Human genes 0.000 description 1
- 108010065511 Amylases Proteins 0.000 description 1
- BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 description 1
- ONYKNTRMIOQQBJ-UHFFFAOYSA-N C(CCC(=O)O)(=O)O.C(CCC(=O)O)(=O)O.[O] Chemical compound C(CCC(=O)O)(=O)O.C(CCC(=O)O)(=O)O.[O] ONYKNTRMIOQQBJ-UHFFFAOYSA-N 0.000 description 1
- 108010059892 Cellulase Proteins 0.000 description 1
- KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 description 1
- 244000248349 Citrus limon Species 0.000 description 1
- 235000005979 Citrus limon Nutrition 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- BRDJPCFGLMKJRU-UHFFFAOYSA-N DDAO Chemical compound ClC1=C(O)C(Cl)=C2C(C)(C)C3=CC(=O)C=CC3=NC2=C1 BRDJPCFGLMKJRU-UHFFFAOYSA-N 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- 239000004117 Lignosulphonate Substances 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-L Malonate Chemical compound [O-]C(=O)CC([O-])=O OFOBLEOULBTSOW-UHFFFAOYSA-L 0.000 description 1
- 241000378467 Melaleuca Species 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 1
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 1
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 1
- REYJJPSVUYRZGE-UHFFFAOYSA-N Octadecylamine Chemical compound CCCCCCCCCCCCCCCCCCN REYJJPSVUYRZGE-UHFFFAOYSA-N 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- DWAQJAXMDSEUJJ-UHFFFAOYSA-M Sodium bisulfite Chemical compound [Na+].OS([O-])=O DWAQJAXMDSEUJJ-UHFFFAOYSA-M 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- 241000592342 Tracheophyta Species 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- 125000002777 acetyl group Chemical group [H]C([H])([H])C(*)=O 0.000 description 1
- 150000001252 acrylic acid derivatives Chemical class 0.000 description 1
- 239000012190 activator Substances 0.000 description 1
- 125000002252 acyl group Chemical group 0.000 description 1
- 238000012644 addition polymerization Methods 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 125000003545 alkoxy group Chemical group 0.000 description 1
- 125000005037 alkyl phenyl group Chemical group 0.000 description 1
- 150000008052 alkyl sulfonates Chemical class 0.000 description 1
- 235000019418 amylase Nutrition 0.000 description 1
- 150000001450 anions Chemical group 0.000 description 1
- 230000003466 anti-cipated effect Effects 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 239000002216 antistatic agent Substances 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 125000003710 aryl alkyl group Chemical group 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- SRSXLGNVWSONIS-UHFFFAOYSA-M benzenesulfonate Chemical compound [O-]S(=O)(=O)C1=CC=CC=C1 SRSXLGNVWSONIS-UHFFFAOYSA-M 0.000 description 1
- 229940077388 benzenesulfonate Drugs 0.000 description 1
- 239000007844 bleaching agent Substances 0.000 description 1
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 1
- 239000004327 boric acid Substances 0.000 description 1
- 235000010338 boric acid Nutrition 0.000 description 1
- XNNQFQFUQLJSQT-UHFFFAOYSA-N bromo(trichloro)methane Chemical compound ClC(Cl)(Cl)Br XNNQFQFUQLJSQT-UHFFFAOYSA-N 0.000 description 1
- 230000003139 buffering effect Effects 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 125000002837 carbocyclic group Chemical group 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- CREMABGTGYGIQB-UHFFFAOYSA-N carbon carbon Chemical group C.C CREMABGTGYGIQB-UHFFFAOYSA-N 0.000 description 1
- 239000011203 carbon fibre reinforced carbon Substances 0.000 description 1
- 150000007942 carboxylates Chemical class 0.000 description 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 1
- 125000002843 carboxylic acid group Chemical group 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 239000003518 caustics Substances 0.000 description 1
- 210000004027 cell Anatomy 0.000 description 1
- 210000000170 cell membrane Anatomy 0.000 description 1
- 229940106157 cellulase Drugs 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- UHZZMRAGKVHANO-UHFFFAOYSA-M chlormequat chloride Chemical compound [Cl-].C[N+](C)(C)CCCl UHZZMRAGKVHANO-UHFFFAOYSA-M 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- NSFKBZXCXCJZDQ-UHFFFAOYSA-N cumene;sodium Chemical compound [Na].CC(C)C1=CC=CC=C1 NSFKBZXCXCJZDQ-UHFFFAOYSA-N 0.000 description 1
- 108010005400 cutinase Proteins 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 150000004985 diamines Chemical class 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- VUJGKADZTYCLIL-YHPRVSEPSA-L disodium;5-[(4-anilino-6-morpholin-4-yl-1,3,5-triazin-2-yl)amino]-2-[(e)-2-[4-[(4-anilino-6-morpholin-4-yl-1,3,5-triazin-2-yl)amino]-2-sulfonatophenyl]ethenyl]benzenesulfonate Chemical compound [Na+].[Na+].C=1C=C(\C=C\C=2C(=CC(NC=3N=C(N=C(NC=4C=CC=CC=4)N=3)N3CCOCC3)=CC=2)S([O-])(=O)=O)C(S(=O)(=O)[O-])=CC=1NC(N=C(N=1)N2CCOCC2)=NC=1NC1=CC=CC=C1 VUJGKADZTYCLIL-YHPRVSEPSA-L 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 239000003792 electrolyte Substances 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 239000003344 environmental pollutant Substances 0.000 description 1
- 125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 230000000855 fungicidal effect Effects 0.000 description 1
- 239000000417 fungicide Substances 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- ORTRWBYBJVGVQC-UHFFFAOYSA-N hexadecane-1-thiol Chemical compound CCCCCCCCCCCCCCCCS ORTRWBYBJVGVQC-UHFFFAOYSA-N 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- CBOIHMRHGLHBPB-UHFFFAOYSA-N hydroxymethyl Chemical compound O[CH2] CBOIHMRHGLHBPB-UHFFFAOYSA-N 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 230000003834 intracellular effect Effects 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 238000010409 ironing Methods 0.000 description 1
- 239000004310 lactic acid Substances 0.000 description 1
- 235000014655 lactic acid Nutrition 0.000 description 1
- 238000011031 large-scale manufacturing process Methods 0.000 description 1
- 239000003446 ligand Substances 0.000 description 1
- 235000019357 lignosulphonate Nutrition 0.000 description 1
- 229910003002 lithium salt Inorganic materials 0.000 description 1
- 159000000002 lithium salts Chemical class 0.000 description 1
- 238000011068 loading method Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 1
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical group CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 1
- DVEKCXOJTLDBFE-UHFFFAOYSA-N n-dodecyl-n,n-dimethylglycinate Chemical compound CCCCCCCCCCCC[N+](C)(C)CC([O-])=O DVEKCXOJTLDBFE-UHFFFAOYSA-N 0.000 description 1
- ONLRKTIYOMZEJM-UHFFFAOYSA-N n-methylmethanamine oxide Chemical compound C[NH+](C)[O-] ONLRKTIYOMZEJM-UHFFFAOYSA-N 0.000 description 1
- 229920000847 nonoxynol Polymers 0.000 description 1
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000001117 oleyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])/C([H])=C([H])\C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 125000000913 palmityl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 108010087558 pectate lyase Proteins 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- 238000001259 photo etching Methods 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 231100000719 pollutant Toxicity 0.000 description 1
- 229920000233 poly(alkylene oxides) Polymers 0.000 description 1
- 229920000768 polyamine Polymers 0.000 description 1
- 229920005646 polycarboxylate Polymers 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- FBCQUCJYYPMKRO-UHFFFAOYSA-N prop-2-enyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCC=C FBCQUCJYYPMKRO-UHFFFAOYSA-N 0.000 description 1
- 150000003219 pyrazolines Chemical class 0.000 description 1
- 150000003254 radicals Chemical class 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 150000003333 secondary alcohols Chemical class 0.000 description 1
- 239000003352 sequestering agent Substances 0.000 description 1
- 229940079827 sodium hydrogen sulfite Drugs 0.000 description 1
- 235000010267 sodium hydrogen sulphite Nutrition 0.000 description 1
- AXMCIYLNKNGNOT-UHFFFAOYSA-N sodium;3-[[4-[(4-dimethylazaniumylidenecyclohexa-2,5-dien-1-ylidene)-[4-[ethyl-[(3-sulfophenyl)methyl]amino]phenyl]methyl]-n-ethylanilino]methyl]benzenesulfonate Chemical compound [Na+].C=1C=C(C(=C2C=CC(C=C2)=[N+](C)C)C=2C=CC(=CC=2)N(CC)CC=2C=C(C=CC=2)S([O-])(=O)=O)C=CC=1N(CC)CC1=CC=CC(S(O)(=O)=O)=C1 AXMCIYLNKNGNOT-UHFFFAOYSA-N 0.000 description 1
- ODBPOHVSVJZQRX-UHFFFAOYSA-M sodium;[2-[2-[bis(phosphonomethyl)amino]ethyl-(phosphonomethyl)amino]ethyl-(phosphonomethyl)amino]methyl-hydroxyphosphinate Chemical compound [Na+].OP(=O)(O)CN(CP(O)(O)=O)CCN(CP(O)(=O)O)CCN(CP(O)(O)=O)CP(O)([O-])=O ODBPOHVSVJZQRX-UHFFFAOYSA-M 0.000 description 1
- MWNQXXOSWHCCOZ-UHFFFAOYSA-L sodium;oxido carbonate Chemical compound [Na+].[O-]OC([O-])=O MWNQXXOSWHCCOZ-UHFFFAOYSA-L 0.000 description 1
- LJFWQNJLLOFIJK-UHFFFAOYSA-N solvent violet 13 Chemical compound C1=CC(C)=CC=C1NC1=CC=C(O)C2=C1C(=O)C1=CC=CC=C1C2=O LJFWQNJLLOFIJK-UHFFFAOYSA-N 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000013112 stability test Methods 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- KDYFGRWQOYBRFD-UHFFFAOYSA-L succinate(2-) Chemical compound [O-]C(=O)CCC([O-])=O KDYFGRWQOYBRFD-UHFFFAOYSA-L 0.000 description 1
- 150000003467 sulfuric acid derivatives Polymers 0.000 description 1
- 229910021653 sulphate ion Inorganic materials 0.000 description 1
- 239000000516 sunscreening agent Substances 0.000 description 1
- 239000000375 suspending agent Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 239000003760 tallow Substances 0.000 description 1
- KKEYFWRCBNTPAC-UHFFFAOYSA-L terephthalate(2-) Chemical compound [O-]C(=O)C1=CC=C(C([O-])=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-L 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- GEKDEMKPCKTKEC-UHFFFAOYSA-N tetradecane-1-thiol Chemical group CCCCCCCCCCCCCCS GEKDEMKPCKTKEC-UHFFFAOYSA-N 0.000 description 1
- 150000007970 thio esters Chemical class 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 229910052723 transition metal Inorganic materials 0.000 description 1
- 150000003624 transition metals Chemical class 0.000 description 1
- 150000003673 urethanes Chemical class 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/30—Amines; Substituted amines ; Quaternized amines
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D10/00—Compositions of detergents, not provided for by one single preceding group
- C11D10/04—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap
- C11D10/042—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap based on anionic surface-active compounds and soap
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D11/00—Special methods for preparing compositions containing mixtures of detergents
- C11D11/0094—Process for making liquid detergent compositions, e.g. slurries, pastes or gels
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D11/00—Special methods for preparing compositions containing mixtures of detergents
- C11D11/04—Special methods for preparing compositions containing mixtures of detergents by chemical means, e.g. by sulfonating in the presence of other compounding ingredients followed by neutralising
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3757—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions
- C11D3/3765—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions in liquid compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/29—Sulfates of polyoxyalkylene ethers
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
Abstract
The method for the liquid detergent composition that manufacture is thickened using the acrylate copolymer of linear and/or crosslinked alkali swellability, wherein described composition includes anionic surfactant, the anionic surfactant include by during the method linear alkyl benzene sulfonic acid by one or more amine and formed linear alkylbenzene sulfonate (LAS), the described method comprises the following steps：A) acrylate copolymer of the alkali swellability is mixed with water, then b) further at least one amine is mixed with the mixture of step a), the amount of the amine, which is more than, is enough the amount for neutralizing the linear alkyl benzene sulfonic acid, and then the linear alkyl benzene sulfonic acid c) is added in the mixture of the thickening of step b), form corresponding anionic surfactant from there through neutralization.
Description
Technical field
The present invention relates to the linear alkylbenzene (LAB)s for preparing the anionic surfactant containing amine neutralization, particularly amine neutralizes
The method of the liquid laundry detergent compositions of the acrylate copolymer thickening of sulfonate.
Background technology
The detergent composition that acrylate polymer is used to thicken use in personal care is well-known.In general, it adds in
The anionic surfactant of such composition is preneutralization.For the manufacture of the detergent composition of laundry,
Common practice is the acid precursors in situ for neutralizing the anionic surfactant linear alkylbenzene sulfonate (LAS) (LAS) and makes
With the heat generated by the exothermic reaction come assist process.When preparing liquid laundry detergent compositions, usually using caustic alkali
The acid precursors (LAS acid) and aliphatic acid of LAS are neutralized, to obtain LAS sodium and soap in the liquid of gained.It it is known that using amine, example
The pH of the liquid is neutralized and/or adjusts such as the mixture of monoethanolamine (MEA), triethanolamine (TEA) and the two.
US2010/0197557 A1 (Dial) are described using HASE (emulsion of the alkali swellability of hydrophobically modified) association type
Polymer-thickened abrasive cleaning composition.Composition 2 and composition 4 in table 1 also include detergent alkylate sulphur in addition to MEA
Sour sodium (LAS).Both stability test is not passed through.The presence of the sodium salt of LAS in addition to being used for the MEA of pH adjustings shows
LAS is being added to before said composition during an independence by causticity alkali neutralization.Solution party claimed
Case be avoid using crosslinked thickening polymer and with relatively high composition pH (>10).Therefore, in embodiment, make
Association type polymer always HASE polymer.It is formed it was found that Acusol 820 is use in these compositions preferable
One of mould assembly thickening polymer.It clearly teaches to obtain more stable composition by the embodiment, the inventor
LAS is eliminated from composition.
Dow Chemicals provide the Acusol series of acrylate thickening agent, and have disclosed following be directed to
The preparation guide being incorporated to of Acusol 820.It " 820 thickeners of ACUSOL and surfactant, solvent, oil, salt and is washing
Common other compositions are compatible in agent and detergent product.The makers-up of detergent and detergent will have found without difficulty
ACUSOL 820 is incorporated into the best mode in its respective specific products.Operating flexibility is (low viscous before neutralization by product
Spend liquid) physical characteristic provide, and its high thickening efficiency allows different operation sequences.Following combination process meets big
Most preparation demands：
1. ACUSOL 820 is introduced into preparation water.This should provide at least three times dilution of the polymer.
2. add in nonionic surface active agent (if any).
3. addition anionic surfactant (if any)-it is low pH first.(in highly acid component, such as sulphur
In the case of acid, preferably the component is dispersed in system before the polymer is added in, and part is neutralized (for example, to pH
About 4-5)).
4. add in builder, filler, particle.
5. adding in dyestuff, fragrance is then added in.
6. with selected alkali neutralization.
When following the combination process of the announcement by the MEA liquid neutralized in the fabrication process for wherein LAS acid, we
It was found that the liquid of gained is unstable and is separated.With this announcement on the contrary, in fact we are determining to include amine when them
Improved be incorporated in method that stable composition is provided during the LAS of neutralization encounters difficulty really.
WO2011/117427 (Lamberti) disclose comprising as thickener and suspending agent containing one or more second
The liquid waterborne detergent composition of the polyacrylate of the crosslinked alkali swellability of acyl acetyl group or Cyanoacetyl.These classes
The crosslinked polymer of type is referred to alternatively as CASE polymer.The composition is selected from anionic surface also containing 5-60wt%
Activating agent, amphoteric surfactant, cationic surface active agent, amphoteric ionic surfactant, non-ionic surface are lived
Property agent and its detergent system of mixture.Embodiment in WO2011/117427 is all using the anionic table of preneutralization
Face activating agent, and without using any LAS (or MEA).PH presentation of information in the described embodiment is when the surface with preneutralization
The dispersion of polyacrylate generates acidic mixture when activating agent mixes, then using sodium hydroxide by the acidic mixture
It adjusts to weakly acidic final pH.It is we have determined that several non-by being carried out to the method described in WO2011/117427
Obvious modification can use the LAS of MEA preneutralizations simultaneously, and even so, the method for gained can not be used as wherein
The replacer for the method that LAS is routinely neutralized in situ, and still need other methods for changing to reach the present invention.
Desirably (it is included in WO2011/ using the polymer using alkali swellability for realizing the LAS to being neutralized comprising amine
The cross-linked polymer of type described in 117427) thickening stabilization liquid consistent large-scale production manufacturing method.
US6376446 (Melaleuca), which is disclosed, adds in acrylate polymer (together with dyestuff) as detergent system
Make the terminal stage of method.We it has been shown that such method although be under laboratory scale it is feasible be not suitable for
Wherein carry out the full-scale plant neutralized in situ of linear alkyl benzene sulfonic acid.It is not entirely clear that it is in US6376446
It is no to use such sulfonic acid.The amount of the MEA used in embodiment 1 is not enough to neutralize LAS acid, and most possible only for pH
It adjusts and adds in.
Summary of the invention
According to the present invention, manufacture is provided using the acrylate copolymer of linear and/or crosslinked alkali swellability to increase
The method of thick liquid detergent composition, wherein the composition includes anionic surfactant, the anionic
Surfactant include by during the method linear alkyl benzene sulfonic acid by one or more amine and formed straight chain alkane
Base benzene sulfonate, the described method comprises the following steps：
A) acrylate copolymer of alkali swellability is mixed with water, then
B) further at least one amine is mixed with the mixture of step a), the amount of the amine, which is more than, to be enough to neutralize straight chain alkane
The amount of base benzene sulfonic acid, and then
C) linear alkyl benzene sulfonic acid is added in the mixture of the thickening of step b), formed accordingly from there through neutralizing
Anionic surfactant.
Preferably, also by the mixed with polymers in hydrotropic agent, most preferably monopropylene glycol-MPG- and step a).It is optimal
Selection of land, by the mixed with polymers in nonionic surface active agent and step a).Can also will be in fluorescer and step a) it is poly-
Close object mixing.The surfactant acid includes the combination of LAS acid or LAS acid and aliphatic acid.It is preferred that by the polyacrylic acid
PH is less than 8 when ester copolymer adds in the mixture.With excessively high pH cause viscosity accelerated accumulation to be generally used for through
Mass produce to Ji the incompatible level of the processing equipment of liquid detergent composition.Refer to that batch size is at least on a large scale
500Kg, most preferably at least 1 ton.Added in by preventing all amine base until be added completely into the acrylate copolymer come
PH is kept sufficiently low.Some amine can be added in before the acrylate copolymer, condition is pH not to be allowed to be too high.
However, this is less preferable method choice.
Preferably, the amine includes monoethanolamine, is optionally combined with triethanolamine.It it is preferred that will be enough during step b)
Amine mixed with the mixture of step a), to thicken the acrylate copolymer and can be used to neutralize in the step c) straight
Alkyl group benzene sulfonic acid.In the case where anionic surfactant includes LAS and soap, using be at least enough to neutralize LAS acid with
Form the amine of LAS.Can be quantified in LAS acid and afterwards the other alkali of dosing, be preferably also amine, optionally different amine with
Adjust pH.The soap preferably in amine and is formed by aliphatic acid.
Citric acid can be added between LAS acid and aliphatic acid.
Preferably, any alkyl ether sulfate (AES) anionic surfactant, especially is added in after the step b)
It is sodium laureth sulfate (SLES).It is highly preferred that after step c).It is in the other components that step c) is preferably added to afterwards
Chelating agent (Dequest), cleaning cleaning polyalcohol (such as ethoxylation polyethylene imine), preservative, colorant and opacifier, tune
Color dyestuff（shading dyes）, enzyme and fragrance.
When amine is mixed with acrylate copolymer mixture a), preferably used during step b) and be sufficiently stirred (energy
Amount inputs), to ensure local high alkalinity region is not present in the mixture, it will cause part is highly viscous to establish simultaneously hardly possible
To handle " lumpy object " mixture.
Detailed description of the invention
Surfactant
In order to which effective laundry wash acts on, the composition has at least 10wt%, preferably at least 15wt% and most preferably
The gross activity detergent surfactant of at least 25wt% is horizontal.For the purpose of the amount, not including any polymeric material such as
EPEI and including soap.It is essential that the composition is included in the anionic table neutralized during the method using amine
Face activating agent.The amount of the anionic surfactant preferably comprises the 20-50% of total surfactant system.
Surfactant contributes to except crude removal from textile material, and additionally aids the dirt that will be removed with solution
Or form of suspension is maintained in wash liquid.Anionic surfactant or anionic surfactant and non-ionic
The blend of surfactant is the preferred feature of the composition.The amount for the anionic surfactant that amine neutralizes is at least
5wt%。
Anionic surfactant
Anionic surfactant in total surfactant system includes alkylbenzenesulfonate, particularly with C8-
C15Alkyl chain length linear alkylbenzene sulfonate (LAS).Counter ion counterionsl gegenions for anionic surfactant are amine, such as
MEA or TEA can be used.
Suitable linear alkyl sulfonate surfactant includes the alkyl chain length with 8-15, more preferable 12-14
Detal LAS。
It is also desirable that the composition includes the alkyl polyethoxylated sulfates of formula (I)（alkyl polyethoxylate
sulphate）Anionic surfactant：
RO(C2H4O)xSO3 -M+ (I)
Wherein R is the saturation or undersaturated alkyl chain for having 10-22 carbon atom, and M is so that the compound is water
The cation of dissolubility, particularly alkali metal, ammonium or substituted ammonium cation, and x average out to 1-15.
Preferably, R is the hydrocarbyl chain for having 12-16 carbon atom, and M is sodium and x average out to 1-3, preferably x are 3；This is cloudy
Ionic surfactant sodium laureth sulfate (SLES).It is the sodium salt of lauryl ether sulfonic acid, wherein main C12 bays
Alkyl（lauryl alkyl）By every mole of ethylene oxide ethoxylation 3 moles average.It is added in by any LAS acid
After amine and polymer, preferably the surfactant of this ethoxylation is added in the form of preneutralization.
Nonionic surface active agent
Nonionic surface active agent includes the ethoxylate of primary and secondary alcohol, is averaged 1- especially with every mol of alcohol
The C of 20 moles of ethylene oxide ethoxylation8-C20Aliphatic alcohol, and 1-10 moles average more particularly using every mol of alcohol
The C of ethylene oxide ethoxylation10-C15Primary aliphatic alcohols and aliphatic secondary alcohol.Unethoxylated nonionic surface active agent includes
Alkyl polyglycoside, glycerol monoethers and polyhydroxy amides (glucamide).The mixture of nonionic surface active agent can be used.
When wherein including nonionic surface active agent, the composition contains 0.2wt%-40wt%, preferably 1wt%-20wt%, more excellent
Select the nonionic surface active agent of 5-15wt%, such as alcohol ethoxylate, nonyl phenol ethoxylate, alkyl polyglycoside, alkane
Base dimethyl amine（alkyldimethylamineoxide）, ethoxylated fatty acid single ethanol amide, aliphatic acid monoethanol
The N- acyl N-alkyl derivatives (" glucamide ") of amide, polyhydroxy alkyl fatty acid amide or aminoglucose.
The nonionic surface active agent that can be used includes primary alcohol ethoxylate and secondary alcohol ethoxyl compound, especially
Using the C of every mol of alcohol ethylene oxide ethoxylation 1-35 moles average8-C20Aliphatic alcohol, and more particularly use and often rub
The C of your alcohol ethylene oxide ethoxylation 1-10 moles average10-C15Primary aliphatic alcohols and aliphatic secondary alcohol.
It is preferred that before thickening polymer and also desirably in step c), the anionic surface of the sour form of addition is lived
Property agent before nonionic surface active agent is added to the method.
Amine oxide surfactant
The composition may comprise up to the amine oxide of the following formula of 10wt%：
R1N(O)(CH2R2)2
Wherein R1It is long chain alkyl group, each CH2R2It is short chain groups.R2It is preferably selected from hydrogen, methyl and-CH2OH.In general, R1
It can be saturation or undersaturated primary hydrocarbyl group or branched chain hydrocarbyl groups to be, preferably R1It is primary alkyl-group.R1It is to have about 8
To the hydrocarbyl group of about 18 chain length.
It is C that preferred amine oxide, which has,8-C18The R of alkyl1With the R for being H2.Pass through C12-14Alkyl dimethyl amine oxide, ten
Six alkyl dimethyl amine oxides, octadecyl amine oxide illustrate these amine oxides.
Preferred amine oxide material is lauryl dimethyl amine oxide, also referred to as dodecyldimethylamine oxide or
DDAO.Such amine oxide material from Huntsman with trade name Empigen OB commercially available from.
Amine oxide in this article is applicable in also available from Akzo Chemie and Ethyl Corp..Referring to for optional oxygen
The compilation of the McCutcheon of Hua An manufacturers and the survey article of Kirk-Othmer.
Although the R in certain preferred embodiments2It is H, but there can be the R slightly larger than H2.Specifically, R2Can be
CH2OH, such as double (2- ethoxys) amine oxides of cetyl, double (2- ethoxys) amine oxides of tallow, double (the 2- hydroxyl second of stearyl
Base) double (2- ethoxys) amine oxides of amine oxide and oleyl.
Preferred amine oxide has following formula：
O- - N+(Me)2R1 (3)
Wherein R1It is C12-16Alkyl, preferably C12-14Alkyl；Me is methyl.
Amphoteric ionic surfactant
It is that there are certain that can prepare with the up to system without nonionic surface active agent of the LAS of 95wt%, condition
A little amphoteric ionic surfactants, such as carbon is for glycine betaine (carbobetain).Preferred zwitterionic materials are can be from
The carbon that Huntsman is obtained with title Empigen BB is for glycine betaine.Glycine betaine and/or amine oxide are improved in the composition
Particular pollutant detergency.
Any amine oxide surfactant and amphoteric ionic surfactant preferably add in after step c).
Other surfactant
The other surfaces activating agent that can will differ from preferred LAS, SLES and nonionic surface active agent is added to
The mixture of detergent surfactant.However, it is preferred to it is substantially absent from cationic surface active agent.
Amine
The presence of amine is needed, to neutralize the anionic surfactant acid and provide buffering and pH controls；Preferably
Amine is MEA and TEA.If these amine exist, these amine are preferably with 1 to 15wt% level in the composition.It is described
Composition is preferably alkalescence, and more preferable final pH is at least 8.
Thickening polymer
The thickening polymer is the acrylate copolymer of linear and/or crosslinked alkali swellability.Such alkali soluble is swollen
The copolymer (ASE) of property optionally at least one monomer with hydrophobically modified (HASE) or with crosslinked group (CASE), and
Can have both hydrophobically modified and crosslinking (C-HASE).
As used herein, term " (methyl) acrylic acid " refers to acrylic or methacrylic acid, and " (methyl) acrylic acid
Ester " refers to acrylate or methacrylate.Term " acrylate copolymer " refer to acrylic monomers (i.e. acrylic acid (AA),
Methacrylic acid (MAA) and their ester) polymer and acrylic monomers containing at least 50% copolymer.AA's and MAA
Ester includes but not limited to, methyl methacrylate (MMA), ethyl methacrylate (EMA), butyl methacrylate (BMA), first
Base hydroxy-ethyl acrylate (HEMA), methyl acrylate (MA), ethyl acrylate (EA), butyl acrylate (BA) and acrylic acid hydroxyl second
Ester (HEA) and other of AA or MAA Arrcostab.
Preferred acrylic copolymer has at least 75%, more preferably at least 90%, even more desirably at least 95% and most
Preferably at least 98% monomer residue derived from (methyl) acrylic acid or (methyl) acrylate monomer.Term " vinyl list
Body " refers to be suitable for addition polymerization and the monomer containing single polymerizable carbon-carbon's double bond.
(methyl) acrylic acid wherein each containing one or more lipophilic groups that can be modified by using lipophilic
Ester residue carrys out hydrophobic property matter.Such group suitably in identical copolymer component and is connected to hydrophilic with hydrophilic chain
Chain, the hydrophilic chain are, for example, polyoxyethylene chain.Optionally, the thickening acrylic copolymer, which can contain, can be used for making to gather
It closes object and is copolymerized to other entities containing vinyl so that the vinyl of polymer property is altered or modified.Polymerizable groups can directly connect
It is connected to lipophilic group or can for example be connected indirectly by such as up to 60 one or more, preferably up to 40 water solubilitys
Group (such as-CH [R] CH2O- groups or-CH [R] CH2NH- groups, wherein R are hydrogen or methyl) is connected to lipophilic group.It can
Selection of land, the polymerizable groups can pass through hydrophilic component (such as polyoxyethylene) and the urethanes containing degree of unsaturation
The reaction of compound is connected to lipophilic group.Number of the molecular weight of one or more lipophilic modified groups preferably with such group
Amount selects together, to provide the lipophilicity content of the required bottom line in the thickening polymer, and preferably exists
Satisfactory performance is provided in the fluid composition of wide scope.
The amount for the component that lipophilic in the thickening polymer is modified is preferably at least 5%, more preferably at least 7.5%, and most
Preferably at least 10%；And preferably no greater than 25%, more preferably no more than 20%, more preferably no more than 18%, and most preferably no greater than
15%。
Although it is anticipated that branched group, the lipophilic modified group is preferably the saturated alkyl of straight chain in itself, but can be with
It is aralkyl or alkyl carbocyclic group group, such as at least six and the alkyl phenyl of up to 30 carbon atoms.It is it is appreciated that described
Alkyl can be synthesis or with natural, and can specifically contain a certain range of chain length in the latter case.
The chain length of the lipophilic modified group is preferably less than 25, more preferably 8-22, and most preferably 10-18 carbon
Atom.The hydrophilic component for the copolymer that the lipophilic is modified can be suitably polyoxyethylene component, preferably comprise at least
One have at least two, preferably at least 5, more preferably at least 10 and up to 60, preferably up to 40, more preferably up to about 30
The chain of a ethylene oxide unit.Such component is usually generated with the mixing of chain length.
Preferably, any (methyl) acrylic acid C2-C4 Arrcostab residues in the copolymer are (methyl) acrylic acid
C2-C3 Arrcostab residues, and most preferably EA.Preferably, the amount of (methyl) acrylic acid C2-C4 Arrcostab residues is at least
20%, more preferably at least 30%, more preferably at least 40%, and most preferably at least 50%.Preferably, (methyl) acrylic acid C2-C4 alkyl
The amount of ester residue is not more than 75%, more preferably no more than 70%, and most preferably no greater than 65%.Preferably, acrylic acid residue is in this hair
Amount in the bright middle copolymer used is at least 5%, more preferably at least 7.5%, more preferably at least 10%, and most preferably at least 15%.
Preferably, the amount of acrylic acid residue is not more than 27.5%, more preferably no more than 25%, and most preferably no greater than 22%.By making to have
The acrylic acid or acrylic acid oligomer of polymerizable vinyl are included in monomer mixture to be used for generating copolymer, by propylene
Sour residue is introduced into copolymer.Preferably, the copolymer contains to provide at least 15%, more preferably at least 17.5% and most
Preferably at least 20% acrylic acid is plus the residue derived from methacrylic acid of the amount of the total content of methacrylic acid.Preferably,
The acrylic acid of the copolymer is not more than 65%, more preferably no more than 50%, and most preferably not plus the total content of methacrylic acid
More than 40%.Optionally, hydrophilic co-monomer of the copolymer also containing 2%-25%, preferably 5%-20%, it is however preferred to have hydroxyl
Base, carboxylic acid or sulfonic acid functional（functionality）Hydrophilic co-monomer.The example of hydrophilic co-monomer includes
(methyl) acrylic acid 2- hydroxyl ethyl esters (HEMA or HEA), itaconic acid and acrylamido -2- methyl propane sulfonic acids.
Waterborne compositions preferably comprise from 0.1% and preferably no greater than 10% thickening polymer；That is, it is one or more to increase
The total amount of thick polymer is within this range.Preferably, amount of the thickening polymer in the waterborne compositions is at least
0.3%, more preferably at least 0.5%, more preferably at least 0.7%, most preferably at least 1%.Preferably, the thickening polymer is in the water
Property composition in amount no more than 7%, more preferably no more than 5%, and most preferably no greater than 3%.Uncrosslinked acrylic copolymer
Molecular weight usually in the range of about 100,000 to 1,000,000.
It is crosslinked, crosslinking agent in the acrylic copolymer, such as with two or more olefinics not
The monomer of saturated group is included in together with copolymer component during polymerization.The example of such monomer includes phthalic acid two
Allyl ester, divinylbenzene, allyl methacrylate, two acryloyl butanediol ester of dimethacrylate
(diacrylobutylene glycol dimethacrylate) or ethylene glycol dimethacrylate.When in use, crosslinking
The amount of agent is typically based on the 0.01%-2% of the weight of the copolymer component, preferably 0.1-1%, and more preferable 0.2-0.8%.When
During using crosslinking agent, thickening acrylic copolymer can be prepared in the presence of chain-transferring agent.The example of suitable chain-transferring agent
It is carbon tetrachloride, bromofom, monobromo chloroform and the compound with sulfydryl, for example, chain alkyl mercaptan and thioesters, such as ten
Dialkyl group-, octyl group-, myristyl-or cetyl-mercaptan or butyl-, iso-octyl-or dodecyl-mercapto acetic acid esters.
In use, the amount of the chain-transferring agent is typically based on the 0.01%-5% of the weight of the copolymer component, preferably 0.1%-1%.
If the crosslinking agent and chain-transferring agent（They are conflicting operations for polymerizeing purpose）It is used in combination, then not only
It observes outstanding efficiency, also has very high compatibility with hydrophilic surfactant active, such as increased by the clarity of product
It is confirmed.
Hydrophobically modified polyacrylate thickening copolymer can be obtained as Acusol polymer from Dow.
The preferred thickening acrylic copolymer type that can be used is described in WO2011/117427 (Lamberti)
In.These preferred polymer include：
I) thickener of 0.2%-10%, the thickener are that can pass through the crosslinking that the polymerization of following substance obtains by weight
Alkali swellability polyacrylate：
A) the Mono-olefinic unsaturated monomer containing carboxylic acid group of 20-70% by weight；
B) (methyl) acrylate of 20-70% by weight；
C) unsaturated monomer containing one or more acetoacetyls or Cyanoacetyl of 0.05-3% by weight；
D) the multi-ethylenical unsaturated monomer of 0.01-3% by weight；E) the non-ionic propylene of 0- 10% by weight
Sour association type monomer；
Ii) the detergent component of 5-60% by weight, the detergent component by be selected from anionic surfactant,
Amphoteric surfactant, cationic surface active agent, amphoteric ionic surfactant, nonionic surface active agent and its
At least one compound composition of mixture.
The polyacrylate of such crosslinked alkali swellability containing one or more acetoacetyls or Cyanoacetyl
Possess high thickening capacity in the presence of surfactant and electrolyte, uniform and limpid solution be provided, and possess with it is existing
The polyacrylate of the crosslinked alkali swellability of technology is compared to improved suspension and thickening property.The crosslinked thickening of the type gathers
Closing object can be used as Viscolam thickening polymers to be obtained from Lamberti.
Optional compositions
Other polymers
EPEI
Polymer for the particularly preferred species in the composition is polyethylene imine, preferably modified poly- Asia
Ethylimido.Polyethylene imine is the material being made of ethylenimine unit-CH2CH2NH-, and when for branch when, nitrogen
On hydrogen by ethylenimine unit another chain replace.These polyethylene imines can be for example, by such as titanium dioxide
It polymerize ethylenimine in the presence of the catalyst such as carbon, sodium hydrogensulfite, sulfuric acid, hydrogen peroxide, hydrochloric acid, acetic acid to prepare.With
The U.S. Patent No. of the Ulrich of mandate in 5 days December nineteen thirty-nine et al. is described in the specific method for preparing these polyamine main chains
No. 2,182,306；The U.S. Patent No. 3,033,746 of the Mayle that on May 8th, 1962 authorizes et al.；On July 16th, 1940
The U.S. Patent No. of the Esselmann of mandate et al. 2,208,095；The U.S. of the nineteen fifty-seven September Crowther authorized on the 17th
Patent the 2,806,839th；The U.S. Patent No. 2,553,696 of the Wilson authorized with 21 days Mays nineteen fifty-one.
Preferably, the EPEI includes the polyethylene imine main chain with about 300 to about 10000 weight average molecular weight；Its
Described in polyethylene imine main chain modification be intended to keep polymer it is not quaternized.Such non-ionic EPEI is represented by
PEI (X) YEO, wherein X represent the molecular weight of non-modified PEI and Y represents each nitrogen original in polyethylene imine main chain
The average mol of the ethoxylation of son.The ethoxylation can be each modified 9 to 40 ethoxy groups, preferably its
In the range of 16-26, most preferably 18-22.
The polyethyleneimine polymers preferably with the level of 0.01-25wt% but more preferably at least 2wt% and/or
Level less than 9.5wt%, most preferably 3-9wt% and 2:1 to 7:1st, preferably 3:1 to 6:1 or even to 5:1 non-soap surface
Activating agent is present in the composition ratio of EPEI.
Polyester dirt release polymer
The composition can optionally include the dirt release polymer of 0.3wt% or more, the dirt release polymerization
Object is compatibility for polyester textile（substantive）.Such polymer usually has by propylene glycol ester terephthalate's weight
The multiple unit fabric compatibility mid-block formed and the polyalkylene oxide being blocked (are usually the PEG blocked with methyl termini
750 to 2000) one or two end-blocks.
Other polymers type
In addition to dirt release polymer, can also use dye transfer inhibiting polymers, antiredeposition polymer and
Cotton dirt release polymer is based particularly on modified cellulosic material those.
Hydrotropic agent
Hydrotropic agent be neither water is nor the solvent of traditional surfactant, contribute to surfactant and
Solubilising of the other components in waterborne liquid is so that the waterborne liquid is homogeneous.It, can in suitable hydrotropic agent
Using as preferably and be mentioned that：MPG (monopropylene glycol), glycerine, cumene sodium sulfonate, ethyl alcohol, other glycol (such as dipropyl two
Alcohol), diether and urea.
Enzyme
Preferably at least one or more enzymes can reside in the composition.It is preferred that by least two, more preferably
At least three kinds of different classes of enzymes are applied in combination.Preferred enzyme is selected from protease, amylase, mannonase pectate lyase
Enzyme and cellulase.In other enzymes that can be used, it should be noted that lipase, phosphatidase, cutinase, peroxide
Enzyme, oxidizing ferment.Enzyme desirably combines offer, especially protease with enzyme stabilizers.Suitable enzyme stabilizers include polyalcohol, example
Such as propylene glycol or glycerine, sugar or sugar alcohol, lactic acid, boric acid or boronic acid derivatives, such as aromatic borate or boronic acid derivative
Object, such as 4- formyl phenylboronic acids, and institute can be prepared as described in such as WO 92/19709 and WO 92/19708
State composition.
Lignin compound
When comprising lipase, lignin compound can be so as to the amount optimized by repetition test be used for the composition
In.Lignin is the component of all vascular plants, is mostly present between eucaryotic cell structure, and be also present in it is intracellular and
In cell membrane.
Lignin polymers by the modification that sulfonate ester group substitutes are preferred.Preferably, modified sulfomethylated lignin
Hydrochlorate is substituted by anion or alkoxy.Modified lignin polymers are discussed in WO/2010/033743.Most preferably
Ground, the modified lignin polymers are lignosulfonates (lignosulphonates).Lignosulfonates can pass through
Howard methods obtain.
Fluorescer
Comprising fluorescer, it may be advantageous in the composition.In general, these fluorescers are with their alkali metal salt
Form such as sodium salt is provided and used.The total amount of the one or more fluorescers used in the composition is usually 0.005-
2wt%, more preferable 0.01-0.5wt%.
Preferably fluorescent species are：Two-styrylbiphenyl compounds, such as Tinopal (trade mark) CBS-X, diamines
Stilbene disulfonic acid（Di-amine stilbene di-sulphonic acid）Compound, such as Tinopal DMS pure
Xtra, Tinopal 5BMGX and Blankophor (trade mark) HRH and pyrazoline compounds, such as Blankophor SN.
Preferably fluorescer is：2 (4- styryl -3- sulfophenyls) -2H- naphthols [1,2-d] 1-Sodium-1,2,4-Triazoles, 4,4'- are double
{ [(4- anilino-s -6- (N- methyl-N-2- ethoxys) amino 1,3,5- triazine -2- bases)] amino } stilbene -2-2' disulfonates,
Double { [(4- anilino- -6- morpholino -1,3,5- triazine -2- bases)] amino } stilbene -2-2' disulfonates of 4,4'- and 4,4'- are double
(2- sulfostyryls) biphenyl disodium.
Bleaching catalyst
Composition can include the effective bleach systems of weight.Such system does not use traditional percarbonate and drift usually
White activator approach.Air bleaching catalysts system is preferred.Those skilled in the art can be from for example：WO 98/39098；WO
98/39406、WO 97/48787、WO 00/29537；It is obtained in WO 00/52124 and WO00/60045 (being incorporated by reference into)
Suitable complex compound and for forming the organic molecule of complex compound (ligand) precursor.The example of preferred catalyst is that MeN4Py matches somebody with somebody
The transition metal complex of body (double (pyridine -2- the bases) -1- aminoethanes of double (pyridine -2- bases-the methyl) -1,1- of N, N-).Properly
Bispidon catalyst materials and its effect description in WO02/48301.The bleaching catalyst can be encapsulated, to reduce
During storage with the interaction of the other components of liquid.
Optical white also can be used." optical white " is anyization that reactive albic material is formed when exposed to sunlight
Substance is learned, and is not preferably consumed permanently in the reaction.Preferred optical white includes singlet oxygen optical white and free radical
Optical white.Suitable singlet oxygen optical white can be selected from Water Soluble Phthalocyanines, the phthalocyanine particularly to metallize
Object is closed, wherein the metal is Zn or Al-Z1, wherein Z1 is halogen root, sulfate radical, nitrate anion, carboxylate radical, alkanol root
（alkanolate）Or hydroxide ion.Preferably, the phthalocyanine has the 1-4 SO with its covalent bonding3X group, wherein
X is alkali metal or ammonium ion.Such compound is described in WO2005/014769 (Ciba).
When it is present, the bleaching catalyst is usually with the water of about 0.0001- about 10wt%, preferably from about 0.001- about 5wt%
It is flat to introduce.
Fragrance
The composition will generally comprise fragrance.The fragrance of oil-containing is not preferred.In addition, the composition can use
The fragrance of some encapsulatings.Reduce the composition generated fragrance steam before it is diluted using the fragrance of encapsulating
Amount.When raising concentration of perfume is so that the amount of fragrance can be maintained at reasonably high-level when washing every time, this is important.
It is even furthermore preferable that the fragrance is not only encapsulated, and the encapsulated fragrance is also provided with sinking
Auxiliary agent is accumulated to increase the efficiency of depositing perfume and reservation on the fabric.The deposition aid preferably passes through covalent bond, entanglement or strong
Absorption is preferably attached to the encapsulation object by covalent bond or entanglement.
Builder and chelating agent
The detergent composition can also be optionally containing low relative levels Organic detergent builders or chelating agent
Material.Example includes alkali metal, citrate, succinate, malonate, carboxymethyl succinates, carboxylate, polycarboxylate
With poly- acetyl group carboxylate.Specific example includes sodium salt, the potassium of oxygen disuccinic acid, mellitic acid, benzene polycarboxylic acid and citric acid
Salt and lithium salts.Other examples are DEQUESTTM(the organic phospho acid ester type chelating agent sold by Thermphos) and alkane hydroxyethylidene diphosphonic acid
Ester.
Other suitable organic washing-assisting detergents include polymer and the copolymerization of the known higher molecular weight with builder capacity
Object.For example, such material include suitable polyacrylic acid, poly and poly propenoic acid maleic acid and they
Salt, such as by BASF with title SOKALANTMThose of sale.
If you are using, the organic washing-assisting detergent material can account for the about 0.5%-20wt% of the composition, preferably
1wt%-10wt%.The preferred horizontal 10wt% for being less than the composition of builder, and preferably smaller than 5wt%.Preferred chelating agent
It is HEDP (1-Hydroxy ethylene-1,1-diphosphonic acid), such as sold with Dequest 2010.It is equally suitable but because
Its cleaning effect for providing it is poor and less preferably Dequest 2066 (diethylene triamine penta(methylene phosphonic acid) or
Seven sodium of DTPMP).
External structure agent
The composition can by using in the composition formed structured network one or more materials and
Its rheological characteristic is made further to be modified.Suitable structural agent includes rilanit special, microfibrous cellulose and based on natural
Structural agent, such as citrus pulp fiber（citrus pulp fibre）.Citrus pulp fiber be it is particularly preferred, especially if
Comprising if lipase in the composition.The presence of external structure agent assigns shear thinning rheological characteristic and also allows material all
As encapsulation object and visual beacon steadily float on a liquid.
Other optional members
The composition can contain one or more other optional members.Such components include：Foamed promoter, anti-corrosion
Agent (such as fungicide), polyeletrolyte, anti-shrinking medium, anti wrinkling agent, antioxidant, sun-screening agent, corrosion inhibitor, drapability assign
Agent（drape imparting agents）, antistatic agent and ironing aids.The composition can further include colorant, pearl
Photo etching and/or opacifier and dope dye.Suitably combining for object of mixing colours will be 0.002wt% Acid Violet 50 (100%
Activity) and 0.0005wt% Solvent Violet 13 (100% activity).They will be added in during or after step c), excellent
Step c) is selected in add in afterwards.
Packaging and use
Preferably, provided in being packed with the multipurpose plastic of top seal object or bottom lock object and use the method
The fluid composition obtained.Quantitative dosing measuring device can be as a part for lid or as integrated system and the packaging
It provides together.Can by measure about 35ml dosage and directly or add it in quantitative dosing apparatus washing machine (such as
Muzzle-loading automatic washing machine) in use the fluid composition.
The present invention is further described now with reference to following non-limiting example.
Embodiment
Comparative example A, B and C
The liquid detergent composition based on LAS MEA not thickened is made.Then by three kinds of polyacrylate thickenings altogether
The aqueous solution of polymers is slowly added into each composition, while uses 2 blade agitators mechanical agitation under 350-400rpm
The composition.
Each thickening polymer used is the commercially available association type polymer thickened in alkaline conditions.The polymerization
Object is：
A) the Viscolam CK57 from Lamberti
B) the Acusol 820 from Dow
C) the Acusol 805s from Dow.
The method generates detergent composition A, B and C of limpid, stable thickening under laboratory scale.However, by
In the difficulty that the horizontal mixed tensor is provided under extensive, and due also to the inevitable extension of batch time, leads
The rear Adding Way for causing such energy intensive is for the extensive preparation of polymer-thickened detergent liquid can not
Capable.
Comparative example D-G
In order to attempt reduce processing time, then implemented under laboratory scale (1kg) wherein in the method compared with
Early add in the certain methods modification of the polymer.These also use impractically sufficiently mixing.Different additions
Order is specified in table 1, and wherein ingredient is added to the order in the composition by digital representation.All these method modifications are led
It causes to lack composition stability, as being confirmed by being separated or being gelled.
1-addition sequence of table
Comparative example D is as proposed by supplier Dow for the liquid containing sulfonic acid thickened using Acusol 820
Method.Comparative example G is similar to the method used by Lamberti in its patent application WO2011/117427, however
It is both without using LAS or without using MEA/TEA.In all cases, composition is stirred 20 minutes, blender is set in
400rpm。
Embodiment 1
We be made by nonionic surface active agent, MPG, thickening polymer and water blend form it is individual pre-
Mixed object., it is surprising that by using this method, high-energy mixing and feelings dramatically increased without processing time are being not required
We produce stable composition under condition.The polymer-thickened liquid combinations of stable 1wt% are provided using such pre-composition
The method of object provides in following table 2.
Table 2
| Addition sequence | Ingredient | As 100% (%) |
| 1 | Softened water | 27.81 |
| 2 | MEA | 6.20 |
| 3 | TEA | 4.00 |
| 4a | NI 7EO | 8.40 |
| 4b | MPG | 8.00 |
| 4c | Thickening polymer | 1.00 |
| 4d | Softened water | 10.00 |
| 5 | Citric acid | 2.50 |
| 6 | Fluorescer | 0.25 |
| 7 | LAS acid | 11.20 |
| 8 | Dequest 2010 | 1.50 |
| 9 | Prifac 5908 | 3.50 |
| 10 | Sodium sulfite | 0.25 |
| 11 | SLES 3EO | 8.40 |
| 12 | EPEI | 3.00 |
| 13 | Enzyme and fragrance | To 100 |
By addition sequence be 4a, 4b, 4c and 4d ingredient with this sequentially be configured to premix blend and as it is same into
Divide and be added to complete combination object（full composition）.
It is crucialIngredient
MEA monoethanolamine (amine base)
TEA triethanolamines (amine base)
The non-ionic C12-15 alcohol 7EO ethoxylates of NI 7EO
Neodol 25-7 (come from Shell Chemicals).
MPG monopropylene glycol (hydrotropic agent)
Thickening polymer Acusol 820 or Viscolam CK57.
LAS acid C12-14Linear alkyl benzene sulfonic acid (acid precursors of LAS)
Lemon acid sequestering agent
2010 chelating agents of Dequest, HEDP (1-Hydroxy ethylene-1,1-diphosphonic acid), from Thermphos.
Saturation lauric fatty acids of the Prifac 5908 from Croda.
SLES 3EO have the sodium laureth sulfate of 3 moles of EO.
EPEI Sokalan HP20- ethoxylation polyethylene imine cleaning cleaning polyalcohols：PEI(600)
20EO, from BASF.
In nonionic surface active agent/polymer pre-mix any gelling or polymer are effectively prevented comprising MPG
Precipitation.Using the method and two kinds of thickening polymers：Stable combination is made in Acusol 820 and Viscolam CK57
Object.
Embodiment 2
Premixing method used in embodiment 1 needs the individual mixing vessel for polymer premixing.Embodiment 2
It is the improvement of embodiment 1, identical composition is made using " one kettle way " method.Amine addition is divided into two individually to add
Add, TEA is added to the polymeric blends before LAS acid and adds in MEA after which.It is if however, to be added
The amount of polymer is less high, then it has been found that before LAS acid is introduced by whole alkali be added to the polymer and
The addition sequence of TEA and MEA is not crucial.We have found that alkali is added to polymer avoids peak viscosity too
Thus height the reason is that mixing can be controlled to ensure to avoid local high pH, and avoids being partially formed for high viscosity " gel ".
Embodiment 3
For use Viscolam CK57 polymer and be added separately to amine base one kettle way method addition sequence
(OOA) it is shown in Table 3.The polymer is disperse easily in the mixture of water, MPG and nonionic surface active agent.MEA's
It adds in the mixture thickened to the highest viscosity seen in this procedure.The viscosity is again when adding in LAS acid
Decline and rise after TEA is added in, but not arrive level high as before.The method is selected for more viscous composition
It is particularly useful.
Table 3
| OOA | Ingredient | As 100% (%) |
| 1 | Softened water | 37.71 |
| 2 | Fluorescer | 0.25 |
| 3 | MPG | 8.00 |
| 4 | NI 7EO | 8.40 |
| 5 | Viscolam CK57 | 1.00 |
| 6 | MEA | 6.20 |
| 7 | LAS acid | 11.20 |
| 8 | TEA | 4.00 |
| 9 | Citric acid | 2.50 |
| 10 | Prifac 5908 | 3.50 |
| 11 | Dequest 2010 | 1.50 |
| 12 | Sodium sulfite | 0.25 |
| 13 | SLES 3EO | 8.40 |
| 14 | EPEI | 3.00 |
| 15 | Fragrance, colorant and the opacifier of enzyme, not oil-containing | To 100 |
The final pH of the detergent liquid is 8.2 ± 0.3, and it is in 21s-1It is with the viscosity finally measured at 20 DEG C
280cP±50cP.The liquid is mutually stable.
Embodiment 4
The other method variant details of MEA and TEA are wherein added in together before LAS acid in table 4.This high time
The method of efficiency is possible for said composition, the reason is that causing higher glue since all amine being added in together
It is not excessively high to spend peak value.
Table 4
| OOA | Ingredient | As 100% (%) |
| 1 | Softened water | 29.01 |
| 2 | Fluorescer | 0.25 |
| 3 | MPG | 8.00 |
| 4 | NI 7EO | 8.40 |
| 5 | Viscolam™ CK571 | 1.00 |
| 6 | TEA | 4.00 |
| 7 | MEA | 6.40 |
| 8 | LAS acid | 11.20 |
| 9 | Citric acid (50%) | 2.50 |
| 10 | Prifac™ 5908 | 3.50 |
| 11 | SLES (3EO) | 8.40 |
| 12 | Dequest™ 2010 | 1.50 |
| 13 | EPEI | 3.00 |
| 14 | Sodium sulfite2 | 0.25 |
| 15 | Softened water | 6.00 |
| 16 | Colorant, opacifier, enzyme and fragrance (in water) | 6.59 |
1 The thickening polymer of alkali swellability.
2 After adding in sodium sulfite, batch of material is cooled to 30 DEG C before other compositions are added in.Selection correctly adds in suitable
Sequence is mainly used for minimizing the batch cycle time.
Embodiment 5
The alternative for being suitable for the polymer of higher level provides in table 5.The liquid is in 21s-1At 20 DEG C
Final viscosity is 280cp (± 50cp).This is similar with method used by embodiment 3.
Table 5
| OOA | Ingredient | As 100% (%) |
| 1 | Softened water | 37.709 |
| 2 | Fluorescer | 0.25 |
| 3 | MPG | 8.00 |
| 4 | NI 7EO | 8.40 |
| 5 | Viscolam CK57 | 1.00 |
| 6 | MEA | 6.20 |
| 7 | LAS acid | 11.20 |
| 8 | TEA | 4.00 |
| 9 | Citric acid | 2.50 |
| 10 | Prifac 5908 | 3.50 |
| 11 | Dequest 2010 | 1.50 |
| 12 | Sodium sulfite | 0.25 |
| 13 | SLES 3EO | 8.40 |
| 14 | EPEI | 3.00 |
| 15 | Enzyme, colorant, opacifier and fragrance | To 100 |
Claims (19)
1. manufacture is using the polypropylene of linear and/or crosslinked alkali swellabilities of the 0.1wt% of composition extremely no more than 10wt%
The method of the liquid detergent composition of acid ester copolymer thickening, wherein the composition includes anionic surfactant,
The anionic surfactant include by during the method linear alkyl benzene sulfonic acid by one or more amine and
The linear alkylbenzene sulfonate (LAS) of formation, the described method comprises the following steps：
A) acrylate copolymer of the alkali swellability is mixed with water, then
B) further at least one amine is mixed with the mixture of step a), the amount of the amine, which is more than, to be enough to neutralize the straight chain alkane
The amount of base benzene sulfonic acid, and then
C) linear alkyl benzene sulfonic acid is added to the mixture of the thickening of step b), corresponding the moon is formed from there through neutralizing
Ionic surfactant.
2. according to the method described in claim 1, wherein also hydrotropic agent is mixed with water in step a).
3. according to the method described in claim 1, wherein also monopropylene glycol is mixed with water in step a).
4. method according to any one of claim 1-3, wherein also by nonionic surface active agent in step a)
It is mixed with water.
5. method according to any one of claim 1-3, wherein also mixing fluorescer with water in step a).
6. method according to any one of claim 1-3, wherein the amine includes monoethanolamine.
7. method according to any one of claim 1-3, wherein the amine further includes triethanolamine.
8. method according to any one of claim 1-3, wherein described to thicken using enough amine in step b)
Acrylate copolymer simultaneously neutralizes the linear alkyl benzene sulfonic acid.
9. method according to any one of claim 1-3, wherein other alkali is added to mixture in step c)
In the linear alkyl benzene sulfonic acid neutralization after adjust pH.
10. method according to any one of claim 1-3, wherein other amine is added to mixture in step c)
In the linear alkyl benzene sulfonic acid neutralization after adjust pH.
11. method according to any one of claim 1-3, wherein adding in the alkyl ether sulphur of preneutralization after step c)
Acid salt surfactant (AES).
12. method according to any one of claim 1-3, wherein adding in the lauryl ether of preneutralization after step c)
Sodium sulphate (SLES).
13. method according to any one of claim 1-3, wherein add in other components after step c), it is described its
He is selected from component：Chelating agent, cleaning cleaning polyalcohol, preservative, dope dye, enzyme, fragrance, colorant and opacifier and its mixing
Object.
14. method according to any one of claim 1-3, wherein the composition includes at least total surface of 10wt%
Activating agent.
15. method according to any one of claim 1-3, wherein the composition includes at least total surface of 15wt%
Activating agent.
16. method according to any one of claim 1-3, wherein the composition includes at least total surface of 25wt%
Activating agent.
17. method according to any one of claim 1-3, wherein the anionic formed by neutralization procedure c)
Surfactant accounts for the 20-50% of the total surfactant system of the composition.
18. the pH of method according to any one of claim 1-3, wherein final composition is alkaline.
19. the pH of method according to any one of claim 1-3, wherein final composition is more than 8.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP13165849.4 | 2013-04-29 | ||
| EP13165849 | 2013-04-29 | ||
| PCT/EP2014/055447 WO2014177321A1 (en) | 2013-04-29 | 2014-03-18 | Process to thicken a liquid detergent composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN105143423A CN105143423A (en) | 2015-12-09 |
| CN105143423B true CN105143423B (en) | 2018-05-29 |
Family
ID=48190332
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201480024247.5A Active CN105143423B (en) | 2013-04-29 | 2014-03-18 | The method of thickening liquid detergent composition |
Country Status (4)
| Country | Link |
|---|---|
| EP (1) | EP2992073B1 (en) |
| CN (1) | CN105143423B (en) |
| BR (1) | BR112015027259B1 (en) |
| WO (1) | WO2014177321A1 (en) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2016139133A1 (en) * | 2015-03-02 | 2016-09-09 | Unilever Plc | Perfumed fluid cleaning fluids |
| GB201520128D0 (en) * | 2015-11-16 | 2015-12-30 | Reckitt Benckiser Vanish Bv | Composition |
| CN109906266B (en) * | 2016-10-31 | 2023-09-01 | 沙特基础工业全球技术有限公司 | 2-Ethylhexanol ethoxylate as a hydrotrope in liquid detergents |
| US11312927B2 (en) * | 2017-05-29 | 2022-04-26 | Dow Global Technologies Llc | Foaming hard surface cleaning composition with a pH color change |
| WO2022157232A1 (en) * | 2021-01-21 | 2022-07-28 | Unilever Ip Holdings B.V. | Composition |
| CN116761874A (en) * | 2021-01-21 | 2023-09-15 | 联合利华知识产权控股有限公司 | combination |
| CN113897249B (en) * | 2021-09-26 | 2023-08-25 | 广州立白企业集团有限公司 | Composite suspending agent and liquid detergent composition with suspending effect |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6376446B1 (en) * | 1999-01-13 | 2002-04-23 | Melaleuca, Inc | Liquid detergent composition |
| CN1361819A (en) * | 1999-07-16 | 2002-07-31 | 荷兰联合利华有限公司 | Liquid abrasive cleaning composition |
| WO2011117427A2 (en) * | 2011-03-25 | 2011-09-29 | Lamberti Spa | Detergent compositions |
| CN102834501A (en) * | 2010-04-19 | 2012-12-19 | 宝洁公司 | Process for making a detergent base composition |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AR017744A1 (en) * | 1999-02-08 | 2001-09-12 | Procter & Gamble | POLYMERIC GLYCOLS AND DIOLES FOR IMPROVED DETERGENT COMPOSITIONS FOR THE WASHING OF VAJILLA |
| US20020193268A1 (en) * | 2000-02-08 | 2002-12-19 | The Procter & Gamble Company | Dishwashing detergent compositions containing color-stabilizing phosphonates |
| CA2618882A1 (en) | 2000-04-11 | 2001-10-18 | Lubrizol Advanced Materials, Inc. | Process for preparing stable aqueous surfactant compositions of a crosslinked alkali-swellable acrylate polymer |
| US8563497B2 (en) * | 2010-04-19 | 2013-10-22 | The Procter & Gamble Company | Process for making a detergent based composition |
-
2014
- 2014-03-18 CN CN201480024247.5A patent/CN105143423B/en active Active
- 2014-03-18 WO PCT/EP2014/055447 patent/WO2014177321A1/en active Application Filing
- 2014-03-18 EP EP14713067.8A patent/EP2992073B1/en active Active
- 2014-04-18 BR BR112015027259-2A patent/BR112015027259B1/en not_active IP Right Cessation
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6376446B1 (en) * | 1999-01-13 | 2002-04-23 | Melaleuca, Inc | Liquid detergent composition |
| CN1361819A (en) * | 1999-07-16 | 2002-07-31 | 荷兰联合利华有限公司 | Liquid abrasive cleaning composition |
| CN102834501A (en) * | 2010-04-19 | 2012-12-19 | 宝洁公司 | Process for making a detergent base composition |
| WO2011117427A2 (en) * | 2011-03-25 | 2011-09-29 | Lamberti Spa | Detergent compositions |
| WO2012130644A1 (en) * | 2011-03-25 | 2012-10-04 | Lamberti Spa | Personal care compositions |
Also Published As
| Publication number | Publication date |
|---|---|
| BR112015027259B1 (en) | 2021-09-28 |
| BR112015027259A2 (en) | 2017-07-25 |
| EP2992073B1 (en) | 2018-12-05 |
| EP2992073A1 (en) | 2016-03-09 |
| WO2014177321A1 (en) | 2014-11-06 |
| CN105143423A (en) | 2015-12-09 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN105143423B (en) | The method of thickening liquid detergent composition | |
| CN104508000B (en) | Alkaline liquid laundry detergent composition comprising polyester | |
| JP2022552939A (en) | Liquid laundry detergent with wash booster | |
| CN103975050A (en) | Laundry compositions | |
| CN103975049A (en) | Laundry compositions | |
| JP7684397B2 (en) | Color care detergent composition | |
| EP2850166B1 (en) | Laundry detergent compositions comprising polyalkoxylated polyethyleneimine | |
| CN104704101A (en) | Laundry compositions | |
| EP4108749A1 (en) | Colour care detergent compositions | |
| US10351806B2 (en) | Detergent formulations with low water content and anti-redeposition polymers | |
| WO2020154347A1 (en) | Polymer blend to stabilize highly alkaline laundry detergent | |
| WO2017202922A1 (en) | Laundry composition | |
| WO2017202923A1 (en) | Laundry composition | |
| EP3097170B1 (en) | Process to manufacture a liquid detergent formulation | |
| WO2021118774A1 (en) | Fabric care composition | |
| EP4108748A1 (en) | Colour care detergent compositions | |
| CN104884597A (en) | Laundry compositions | |
| WO2022271897A1 (en) | Colour care detergent composition | |
| RU2780648C1 (en) | Detergent compositions for laundering with stain removal | |
| DE102016209326A1 (en) | Combination of textile treatment agent and colored scarf | |
| WO2022271898A1 (en) | Colour care detergent compositions |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20210803 Address after: Rotterdam Patentee after: Unilever Intellectual Property Holdings Ltd. Address before: Rotterdam Patentee before: Netherlands Unilever Co.,Ltd. |