CN105107637A - Method for preparing collecting agent for recycling sulphide ores from tailings - Google Patents
Method for preparing collecting agent for recycling sulphide ores from tailings Download PDFInfo
- Publication number
- CN105107637A CN105107637A CN201510638173.0A CN201510638173A CN105107637A CN 105107637 A CN105107637 A CN 105107637A CN 201510638173 A CN201510638173 A CN 201510638173A CN 105107637 A CN105107637 A CN 105107637A
- Authority
- CN
- China
- Prior art keywords
- tailings
- lead
- grade
- zinc
- ore
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 title claims abstract description 35
- 238000000034 method Methods 0.000 title claims description 7
- 238000004064 recycling Methods 0.000 title 1
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims abstract description 15
- 238000003756 stirring Methods 0.000 claims abstract description 12
- -1 phosphate ester Chemical class 0.000 claims abstract description 8
- 238000002360 preparation method Methods 0.000 claims abstract description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 7
- 229910019142 PO4 Inorganic materials 0.000 claims abstract description 5
- 239000007788 liquid Substances 0.000 claims abstract description 5
- 239000010452 phosphate Substances 0.000 claims abstract description 5
- 150000002191 fatty alcohols Chemical class 0.000 claims abstract description 3
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 21
- 229910052725 zinc Inorganic materials 0.000 claims description 21
- 239000011701 zinc Substances 0.000 claims description 21
- 229910052500 inorganic mineral Inorganic materials 0.000 claims description 16
- 239000011707 mineral Substances 0.000 claims description 16
- 238000005188 flotation Methods 0.000 claims description 15
- 239000002994 raw material Substances 0.000 claims description 14
- 230000003647 oxidation Effects 0.000 claims description 12
- 238000007254 oxidation reaction Methods 0.000 claims description 12
- 229910052950 sphalerite Inorganic materials 0.000 claims description 12
- 229910052787 antimony Inorganic materials 0.000 claims description 9
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 8
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 claims description 8
- 239000011593 sulfur Substances 0.000 claims description 8
- 229910052717 sulfur Inorganic materials 0.000 claims description 8
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 6
- 229910000004 White lead Inorganic materials 0.000 claims description 6
- 229910052949 galena Inorganic materials 0.000 claims description 6
- 229910052864 hemimorphite Inorganic materials 0.000 claims description 6
- XCAUINMIESBTBL-UHFFFAOYSA-N lead(ii) sulfide Chemical compound [Pb]=S XCAUINMIESBTBL-UHFFFAOYSA-N 0.000 claims description 6
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 claims description 6
- 229910000010 zinc carbonate Inorganic materials 0.000 claims description 6
- 239000004088 foaming agent Substances 0.000 claims description 4
- 238000010408 sweeping Methods 0.000 claims description 4
- 239000002002 slurry Substances 0.000 claims description 2
- 229940056932 lead sulfide Drugs 0.000 claims 1
- 229910052981 lead sulfide Inorganic materials 0.000 claims 1
- 239000003814 drug Substances 0.000 abstract description 2
- 238000005303 weighing Methods 0.000 abstract 1
- 238000011084 recovery Methods 0.000 description 14
- 229910000365 copper sulfate Inorganic materials 0.000 description 5
- ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 description 5
- 229910052569 sulfide mineral Inorganic materials 0.000 description 5
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 4
- BBMCTIGTTCKYKF-UHFFFAOYSA-N 1-heptanol Chemical compound CCCCCCCO BBMCTIGTTCKYKF-UHFFFAOYSA-N 0.000 description 2
- 239000005083 Zinc sulfide Substances 0.000 description 2
- 239000012190 activator Substances 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- ZSIAUFGUXNUGDI-UHFFFAOYSA-N hexan-1-ol Chemical compound CCCCCCO ZSIAUFGUXNUGDI-UHFFFAOYSA-N 0.000 description 2
- JQJCSZOEVBFDKO-UHFFFAOYSA-N lead zinc Chemical compound [Zn].[Pb] JQJCSZOEVBFDKO-UHFFFAOYSA-N 0.000 description 2
- 230000007774 longterm Effects 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 229910052984 zinc sulfide Inorganic materials 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- ZOOODBUHSVUZEM-UHFFFAOYSA-N ethoxymethanedithioic acid Chemical compound CCOC(S)=S ZOOODBUHSVUZEM-UHFFFAOYSA-N 0.000 description 1
- 229910052959 stibnite Inorganic materials 0.000 description 1
- IHBMMJGTJFPEQY-UHFFFAOYSA-N sulfanylidene(sulfanylidenestibanylsulfanyl)stibane Chemical compound S=[Sb]S[Sb]=S IHBMMJGTJFPEQY-UHFFFAOYSA-N 0.000 description 1
- 238000010301 surface-oxidation reaction Methods 0.000 description 1
- 239000012991 xanthate Substances 0.000 description 1
Landscapes
- Manufacture And Refinement Of Metals (AREA)
Abstract
一种用于回收尾矿中硫化矿捕收剂的制备方法，包括如下步骤：首先按质量比称取磷酸脂:氢氧化钠:水＝1～2:2～5:4～10混合，搅拌至溶解得溶液1，然后将含6～7个C的脂肪醇按质量比1～2:2～7加入溶液1中，搅拌至溶解得溶液2，将溶液2置于高压反应釜内，在压力为4～5Mpa，温度为300～450℃条件下反应4～5h，得到一种粘稠状带有特殊气味的液体，即为用于回收尾矿中硫化矿的捕收剂。采用本发明制备得的捕收剂能够捕收尾矿中的硫化矿，易溶于水，且具有良好的选择性及耐低温性能。药剂用量少。A preparation method for recovering a sulfide ore collector in tailings, comprising the steps of: first weighing phosphate ester by mass ratio: sodium hydroxide: water=1～2:2～5:4～10 and mixing, stirring until dissolved to obtain solution 1, then add fatty alcohol containing 6-7 C into solution 1 at a mass ratio of 1-2:2-7, stir until dissolved to obtain solution 2, put solution 2 in a high-pressure reactor, and The pressure is 4-5Mpa and the temperature is 300-450°C for 4-5 hours to obtain a viscous liquid with a special smell, which is a collector for recovering sulfide ore in tailings. The collector prepared by the invention can collect the sulfide ore in the tailings, is easily soluble in water, and has good selectivity and low temperature resistance. The dosage of medicine is less.
Description
一、技术领域1. Technical field
本发明涉及一种硫化矿选浮捕收剂，具体是一种用于回收尾矿中硫化矿捕收剂的制备方法，适用于长期堆存尾矿中部分表面氧化的硫化矿的选浮捕收剂。The invention relates to a sulfide ore separation and flotation collector, in particular to a preparation method for recovering sulfide ore collectors in tailings, which is suitable for the separation, flotation and capture of partially oxidized sulfide ores in tailings for long-term storage Receiver.
二、背景技术2. Background technology
在一些复杂多金属硫化矿的尾矿库中，常含有一定价值的硫化矿物，这些硫化矿物是在当时的选矿过程中，由于要考虑多金属的综合回收，再加上以前选矿技术水平的限制，未能及时回收，被当成尾矿堆于尾矿库中。由于长时间堆存，这些硫化矿表面或多或少形成氧化膜，如果再次回收这部分硫化矿物则比较难。目前国内外对这些硫化矿一般都是采用硫酸或硫酸铜先活化，然后加长碳链黄药进行浮选捕收，硫化矿的浮选回收率在60～65％之间，捕收效果不甚理想，特别是对于表面氧化比较严重的矿物，必须加大量的硫酸或硫酸铜对硫化矿物进行活化，然后再进行捕收。尽管如此，还是有部分硫化矿物未能回收，达不到二次资源利用的目的。如何尽量回收这部分硫化矿物，提高其回收率目前则是选矿界关注的问题。In the tailing pools of some complex polymetallic sulfide ores, there are often sulfide minerals of certain value. These sulfide minerals were produced during the beneficiation process at that time, due to the consideration of the comprehensive recovery of polymetallic and the limitation of the previous beneficiation technology level , failed to be recovered in time, and were piled up in the tailings pond as tailings. Due to the long-term stockpiling, the surface of these sulfide ores has more or less formed an oxide film, and it is more difficult to recover this part of the sulfide ores. At present, these sulfide ores are generally activated by sulfuric acid or copper sulfate at home and abroad, and then the carbon chain lengthening xanthate is used for flotation collection. The flotation recovery rate of sulfide ores is between 60% and 65%, and the collection effect is not very good. Ideally, especially for minerals with serious surface oxidation, it is necessary to add a large amount of sulfuric acid or copper sulfate to activate the sulfide minerals, and then collect them. Nevertheless, there are still some sulfide minerals that cannot be recovered, failing to achieve the purpose of secondary resource utilization. How to recover this part of sulfide minerals as much as possible and improve its recovery rate is currently a concern of the mineral processing industry.
三、发明内容3. Contents of the invention
本发明的目的在于提供一种用于回收尾矿中硫化矿捕收剂的制备方法，它能够在加少量硫酸铜活化的条件下实现尾矿中硫化矿的浮选回收。The purpose of the present invention is to provide a preparation method for recovering the sulfide ore collector in the tailings, which can realize the flotation recovery of the sulfide ores in the tailings under the condition of adding a small amount of copper sulfate for activation.
本发明采用以下技术方案实现上述目的：一种用于回收尾矿中硫化矿捕收剂的制备方法，包括如下步骤：The present invention adopts the following technical solutions to achieve the above object: a preparation method for reclaiming a sulfide ore collector in tailings, comprising the steps of:
首先按质量比称取磷酸脂:氢氧化钠:水＝1～2:2～5:4～10混合，搅拌至溶解得溶液1，然后将含6～7个C的脂肪醇按质量比1～2:2～7加入溶液1中，搅拌至溶解得溶液2，将溶液2置于高压反应釜内，在压力为4～5Mpa，温度为300～450℃条件下反应4～5h，得到一种粘稠状带有特殊气味的液体，即为用于回收尾矿中硫化矿的捕收剂。First, weigh phosphate ester according to the mass ratio: sodium hydroxide: water=1～2:2～5:4～10, stir until dissolved to obtain solution 1, and then the fatty alcohol containing 6～7 C is mixed according to the mass ratio of 1 ~2:2~7 was added to solution 1, stirred until dissolved to obtain solution 2, put solution 2 in a high-pressure reactor, and reacted for 4-5 hours at a pressure of 4-5Mpa and a temperature of 300-450°C to obtain a A viscous liquid with a special smell is the collector used to recover sulfide ore in tailings.
所述捕收剂在回收尾矿中硫化矿的应用，矿物原料为硫化铅锌尾矿，尾矿中铅品位为0.33％～0.53％，锑品位0.26％，锌品位1.02％～1.14％，硫品位5.65％～6.33％，；物相分析表明，铅矿物主要以方铅矿为主，少量白铅矿、车轮矿及脆硫锑铅矿，锌以闪锌矿为主，少量铁闪锌矿、菱锌矿及异极矿，原料中铅氧化率为34.64％，锌氧化率27.17％，或者是矿物原料为锡铅锑锌尾矿，尾矿中铅品位为0.33％，锑品位0.26％，锌品位1.14％，硫品位6.33％，锡品位0.24％，物相分析表明，锡以锡石为主，铅锑矿物主要以脆硫锑铅矿为主，少量白铅矿、车轮矿及方铅矿，锌以铁闪锌矿为主，少量闪锌矿、菱锌矿及异极矿，原料中铅氧化率为35.53％，锌氧化率26.80％。The application of the collector in the recovery of sulfide ore in tailings, the mineral raw material is lead-zinc sulfide tailings, the lead grade in the tailings is 0.33%-0.53%, the antimony grade is 0.26%, the zinc grade is 1.02%-1.14%, the sulfur The grade is 5.65%～6.33%. The physical phase analysis shows that the lead minerals are mainly galena, a small amount of white lead ore, wheel ore and brittle styroite, the zinc is mainly sphalerite, and a small amount of sphalerite , smithsonite and hemimorphite, the lead oxidation rate in raw materials is 34.64%, the zinc oxidation rate is 27.17%, or the mineral raw materials are tin-lead-antimony-zinc tailings, the lead grade in the tailings is 0.33%, the antimony grade is 0.26%, The grade of zinc is 1.14%, the grade of sulfur is 6.33%, and the grade of tin is 0.24%. The phase analysis shows that the tin is mainly cassiterite, the lead and antimony minerals are mainly brittle styroite, and a small amount of white lead ore, wheelite and galena Ore, zinc is mainly sphalerite, a small amount of sphalerite, smithsonite and hemimorphite, the oxidation rate of lead in raw materials is 35.53%, and the oxidation rate of zinc is 26.80%.
药剂制度及操作条件为：The pharmaceutical system and operating conditions are:
采用一次粗选、三次扫选、二次精选的浮选流程。It adopts a flotation process of one roughing, three times of sweeping and two times of fine selection.
浮选时，将尾矿加入搅拌桶搅拌分散后，调节矿浆pH值到6～6.5，浮选过程中，将尾矿加入搅拌桶搅拌分散，然后加入硫酸铜活化剂150g/t，再加入所述硫化矿捕收剂，最后再加入2#油100g/t作起泡剂对尾矿中硫化矿进行捕收。During flotation, put the tailings into the mixing tank for stirring and dispersing, and then adjust the pH value of the slurry to 6-6.5. Describe the sulfide ore collector, and finally add 2# oil 100g/t as a foaming agent to collect the sulfide ore in the tailings.
所述捕收剂总用量为：120～140g/t。The total dosage of the collector is: 120-140g/t.
本发明的具体优点在于：Concrete advantages of the present invention are:
1、采用本发明制备得的捕收剂能够捕收尾矿中的硫化矿，易溶于水，且具有良好的选择性及耐低温性能。1. The collector prepared by the present invention can collect sulfide ore in tailings, is easily soluble in water, and has good selectivity and low temperature resistance.
2、药剂用量少。2. The dosage of medicine is less.
具体实施方式Detailed ways
以下通过具体实施例对本发明的技术方案作进一步描述。The technical solutions of the present invention will be further described below through specific examples.
实施例1Example 1
本实施例为一种用于回收尾矿中硫化矿捕收剂的制备方法，包括如下步骤：This embodiment is a preparation method for recovering a sulfide ore collector in tailings, comprising the following steps:
首先按质量比称取磷酸脂:氢氧化钠:水＝1:2:4混合，搅拌至溶解得溶液1，然后将正己醇按质量比1:2加入溶液1中，搅拌至溶解得溶液2，然后将溶液2置于高压反应釜内，在压力为4Mpa，温度为300℃条件下反应4h，得到一种粘稠状带有特殊气味的液体，即为用于回收尾矿中硫化矿的捕收剂。First, weigh phosphate ester by mass ratio: sodium hydroxide: water = 1:2:4, stir until dissolved to obtain solution 1, then add n-hexanol in solution 1 by mass ratio 1:2, stir until dissolved to obtain solution 2 , and then put solution 2 in a high-pressure reactor, and react for 4 hours at a pressure of 4Mpa and a temperature of 300°C to obtain a viscous liquid with a special smell, which is used to recover sulfide ore in tailings. Collector.
实施例2Example 2
本实施例为一种用于回收尾矿中硫化矿捕收剂的另一制备方法，包括如下步骤：This embodiment is another preparation method for reclaiming the sulfide ore collector in the tailings, comprising the following steps:
首先按质量比称取磷酸脂:氢氧化钠:水＝2:5:10混合，搅拌至溶解得溶液1，然后将正庚醇按质量比2:7加入溶液1中，搅拌至溶解得溶液2，然后将溶液2置于高压反应釜内，在压力为5Mpa，温度为450℃条件下反应5h，得到一种粘稠状带有特殊气味的液体，即为用于回收尾矿中硫化矿的捕收剂。First, weigh phosphate ester by mass ratio: sodium hydroxide: water = 2:5:10, stir until dissolved to obtain solution 1, then add n-heptanol in solution 1 by mass ratio 2:7, stir until dissolved to obtain solution 2. Then put solution 2 in a high-pressure reactor, and react for 5 hours at a pressure of 5Mpa and a temperature of 450°C to obtain a viscous liquid with a special smell, which is used to recover sulfide ore in tailings of collectors.
实施例3Example 3
本实施例为实施例1制备得的捕收剂用于回收尾矿中的硫化矿的应用实例。This example is an application example of using the collector prepared in Example 1 to recover sulfide ore in tailings.
1、矿物原料1. Mineral raw materials
矿物原料为硫化铅锌尾矿，尾矿中铅品位为0.53％，锌品位1.02％，硫品位5.65％；物相分析表明，铅矿物主要以方铅矿为主，少量白铅矿、车轮矿及脆硫锑铅矿，锌以闪锌矿为主，少量铁闪锌矿、菱锌矿及异极矿。原料中铅氧化率为34.64％，锌氧化率达27.17％。The mineral raw material is lead-zinc sulfide tailings. The lead grade in the tailings is 0.53%, the zinc grade is 1.02%, and the sulfur grade is 5.65%. Phase analysis shows that the lead minerals are mainly galena, and a small amount of white lead ore and wheel ore And brittle stibnite, zinc is mainly sphalerite, a small amount of sphalerite, smithsonite and hemimorphite. The lead oxidation rate in the raw material is 34.64%, and the zinc oxidation rate reaches 27.17%.
2、浮选流程：一次粗选、三次扫选、二次精选。2. Flotation process: one rough selection, three sweeping selections, and two selections.
3、药剂制度及操作条件：3. Pharmaceutical system and operating conditions:
浮选时，将尾矿加入搅拌桶搅拌分散后，调节矿浆pH值到6～6.5后，然后加入硫酸铜150g/t作活化剂，再加入所述用于回收尾矿中的硫化矿捕收剂120g/t，最后再加入2#油100g/t作起泡剂对尾矿中硫化矿进行捕收。During flotation, add the tailings to the mixing tank to stir and disperse, adjust the pH value of the pulp to 6-6.5, then add 150g/t copper sulfate as an activator, and then add the sulfide ore collection for recovery of tailings. Agent 120g/t, and finally add 2# oil 100g/t as foaming agent to collect sulfide ore in tailings.
4、浮选指标4. Flotation index
铅回收率达到87.57％，锌回收率达到85.61％，硫回收率达到86.04％。The lead recovery rate reached 87.57%, the zinc recovery rate reached 85.61%, and the sulfur recovery rate reached 86.04%.
实施例4Example 4
本实施例为采用实施例2制备得的用于尾矿中硫化矿捕收剂的应用实例。This example is an application example of the sulfide ore collector used in tailings prepared in Example 2.
1、矿物原料1. Mineral raw materials
矿物原料为锡铅锑锌尾矿，尾矿中铅品位为0.33％，锑品位0.26％，锌品位1.14％，硫品位6.33％，锡品位0.24％；物相分析表明，锡以锡石为主，铅锑矿物主要以脆硫锑铅矿为主，少量白铅矿、车轮矿及方铅矿，锌以铁闪锌矿为主，少量闪锌矿、菱锌矿及异极矿。原料中铅氧化率为35.53％，锌氧化率达26.80％。The mineral raw material is tin-lead-antimony-zinc tailings. The lead grade in the tailings is 0.33%, the grade of antimony is 0.26%, the grade of zinc is 1.14%, the grade of sulfur is 6.33%, and the grade of tin is 0.24%. The phase analysis shows that the tin is mainly cassiterite , the lead-antimony minerals are mainly brittle styroite, a small amount of white lead ore, wheelite and galena, zinc is mainly sphalerite, a small amount of sphalerite, smithsonite and hemimorphite. The lead oxidation rate in the raw material is 35.53%, and the zinc oxidation rate reaches 26.80%.
2、浮选流程：一次粗选、三次扫选、二次精选。2. Flotation process: one rough selection, three sweeping selections, and two selections.
3、药剂制度及操作条件：3. Pharmaceutical system and operating conditions:
浮选时，将尾矿加入搅拌桶搅拌分散后，调节矿浆pH值到6～6.5后，然后加入硫酸铜150g/t作活化剂，再加入所述用于回收尾矿中的硫化矿捕收剂140g/t，最后再加入2#油100g/t作起泡剂对尾矿中硫化矿进行捕收。During flotation, add the tailings to the mixing tank to stir and disperse, adjust the pH value of the pulp to 6-6.5, then add 150g/t copper sulfate as an activator, and then add the sulfide ore collection for recovery of tailings. Agent 140g/t, and finally add 2# oil 100g/t as foaming agent to collect sulfide ore in tailings.
4、浮选指标4. Flotation index
铅回收率达到89.73％，锑回收率88.50％，锌回收率达到83.71％，硫回收率达到85.92％。The lead recovery rate reached 89.73%, the antimony recovery rate reached 88.50%, the zinc recovery rate reached 83.71%, and the sulfur recovery rate reached 85.92%.
Claims (2)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510638173.0A CN105107637A (en) | 2015-09-30 | 2015-09-30 | Method for preparing collecting agent for recycling sulphide ores from tailings |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510638173.0A CN105107637A (en) | 2015-09-30 | 2015-09-30 | Method for preparing collecting agent for recycling sulphide ores from tailings |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105107637A true CN105107637A (en) | 2015-12-02 |
Family
ID=54655876
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510638173.0A Pending CN105107637A (en) | 2015-09-30 | 2015-09-30 | Method for preparing collecting agent for recycling sulphide ores from tailings |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105107637A (en) |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102753485A (en) * | 2010-02-16 | 2012-10-24 | 纳尔科公司 | Sulfide flotation aid |
| CN103923119A (en) * | 2014-04-28 | 2014-07-16 | 中蓝连海设计研究院 | Preparation method and applications of alkyl phosphite |
| CN104437888A (en) * | 2014-11-21 | 2015-03-25 | 广西大学 | Method for preparing zinc-sulfur mineral depressor |
| CN104549765A (en) * | 2014-11-21 | 2015-04-29 | 广西大学 | Preparation method for cassiterite mineral collector |
-
2015
- 2015-09-30 CN CN201510638173.0A patent/CN105107637A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102753485A (en) * | 2010-02-16 | 2012-10-24 | 纳尔科公司 | Sulfide flotation aid |
| CN103923119A (en) * | 2014-04-28 | 2014-07-16 | 中蓝连海设计研究院 | Preparation method and applications of alkyl phosphite |
| CN104437888A (en) * | 2014-11-21 | 2015-03-25 | 广西大学 | Method for preparing zinc-sulfur mineral depressor |
| CN104549765A (en) * | 2014-11-21 | 2015-04-29 | 广西大学 | Preparation method for cassiterite mineral collector |
Non-Patent Citations (2)
| Title |
|---|
| 冉隆文: "《精细磷化工技术》", 30 April 2005, 化学工业出版社 * |
| 张泾生,阙煊兰: "《矿用药剂》", 29 November 2008, 冶金工业出版社 * |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN105149100B (en) | A kind of method that barite is reclaimed from Pb-Zn tailings | |
| CN100562369C (en) | High iron pelitization wulfenite floatation method | |
| CN104148163B (en) | A kind of beneficiation method processing low-grade tin-lead-zinc multi-metal oxygen ore deposit | |
| CN106513181B (en) | A kind of flotation method of sulfide ore gold-bearing ore | |
| CN104437882B (en) | A kind of method of microfine Pb-Zn deposits thing in FLOTATION SEPARATION mine tailing | |
| CN103639061A (en) | Flotation method for lead and zinc ore difficult to select | |
| CN104549769A (en) | Method for separating sulfoarsenic mineral from gangue by flotation | |
| CN105127007A (en) | Floatation method of sulfur-oxygen mixed lead antimony ore | |
| CN108456153B (en) | Phenylpropenyl hydroxamic acid and its preparation method and its application in the flotation of tungsten ore | |
| CN105107634A (en) | Method for recovering associated sulphide copper-zinc ore from cyaniding slag of gold-silver concentrate | |
| CN104841564B (en) | Lead-silver residue flotation combined collecting agent and application process thereof | |
| CN106861919B (en) | A kind of tin-lead soldering collecting agent and its application | |
| CN104689923B (en) | A kind of method that silver is reclaimed in the peracid zinc leaching residue from high temperature | |
| CN101003029A (en) | Method for floating inhibited iron sulfide minerals | |
| CN105080728B (en) | A kind of flotation separation method of antimony sulfide and gold-bearing pyrite | |
| CN102205279B (en) | Collective floatation method for recycling silvers from high leaching residues | |
| CN104815762B (en) | A kind of preparation method of tennantite collecting agent | |
| CN101607228B (en) | Preparation method of sulfide mineral collector | |
| CN105170339B (en) | The method for floating of sulphur oxygen mixed mineral in a kind of recovery mine tailing | |
| CN106345607B (en) | A kind of selecting smelting combination technique handling difficultly-selected copper zinc ore | |
| CN104549763B (en) | A method for flotation separation of limonite from zinc oxide concentrate | |
| CN107185724A (en) | A kind of method for floating that gold sulphide ores are reclaimed from tailings | |
| CN105903572B (en) | A kind of method for eliminating copper ion in secondary copper sulfide polymetallic ore slurry solution | |
| CN105107637A (en) | Method for preparing collecting agent for recycling sulphide ores from tailings | |
| CN108160311B (en) | Method for dressing and smelting weakly magnetic mineral coated sulfur-oxygen mixed zinc ore |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WD01 | Invention patent application deemed withdrawn after publication | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20151202 |