CN105080702B - A kind of efficient coal-series pyrite dry method process of enriching and system - Google Patents
A kind of efficient coal-series pyrite dry method process of enriching and system Download PDFInfo
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Abstract
一种高效的煤系黄铁矿干法富集工艺及系统,属于矿物加工分选工艺及系统。当黄铁矿以粗粒集合体嵌布解离度较高时,不需要进行破碎操作,采用干法重介质流化床分选机或者复合式干法分选机与振动流化床分选机联合富集工艺。当高硫矸石中的黄铁矿嵌布粒度较细解离度较低时,对样品进行破碎解离操作,采用振动流化床分选机细粒高硫矸石中的硫铁矿进行富集。干法重介质流化床分选机和复合式干法分选机富集回收黄铁矿指缓冲仓+6mm煤矸石物料经给料机和皮带机进入分选机,密度大的黄铁矿进入床层底部与矸石实现分离,精矿与尾矿分别进入精矿仓和尾矿仓,精矿为黄铁矿,尾矿为矸石。该工艺流程简单,技术路线合理,处理量大,运行稳定,有效减少运行成本。
A high-efficiency coal-measure pyrite dry enrichment process and system belongs to the mineral processing and separation process and system. When the dissociation degree is high when the pyrite is embedded in coarse-grained aggregates, no crushing operation is required, and a dry heavy medium fluidized bed separator or a combined dry separator and vibrating fluidized bed separator are used to separate the pyrite. machine combined enrichment process. When the pyrite embedded in the high-sulfur gangue has a fine particle size and a low degree of dissociation, the sample is crushed and dissociated, and the pyrite in the fine-grained high-sulfur gangue is enriched by a vibrating fluidized bed separator. . Dry heavy medium fluidized bed sorter and compound dry sorter enrich and recover pyrite refers to the buffer bin + 6mm coal gangue material enters the sorter through the feeder and belt conveyor, and the dense pyrite It enters the bottom of the bed and separates from the gangue. The concentrate and tailings enter the concentrate bin and the tailing bin respectively. The concentrate is pyrite and the tailings are gangue. The process is simple, the technical route is reasonable, the processing capacity is large, the operation is stable, and the operation cost is effectively reduced.
Description
技术领域technical field
本发明涉及一种矿物加工分选工艺,特别是一种高效的煤系黄铁矿干法富集工艺。The invention relates to a mineral processing and separation process, in particular to a high-efficiency dry enrichment process of coal series pyrite.
技术背景technical background
作为我国排放量最大的工业废弃物,煤矸石约占我国每年所排放工业废弃物的25%。随着我国煤炭开采量以及煤炭入选率的进一步增加,预计2015年煤矸石的排放量将达到8亿多吨,累计储存总量将接近45亿吨。煤矸石中的矿物质在日晒、雨淋、风化等不利的自然条件下,常常会发生化学反应,产生大量的酸性水或携带重金属的离子水,对矿区的生态环境产生严重的污染。除此之外,矸石中常常含有硫铁矿和含碳矿物质,在与空气接触的条件下存在自燃的隐患,甚至产生SO2、CO2、NH3等有毒气体和烟雾,对人的生活造成严重的破坏。As the largest industrial waste in my country, coal gangue accounts for about 25% of the industrial waste discharged in my country every year. With the further increase of my country's coal mining volume and coal selection rate, it is estimated that the discharge of coal gangue will reach more than 800 million tons in 2015, and the cumulative storage will be close to 4.5 billion tons. Minerals in coal gangue often undergo chemical reactions under unfavorable natural conditions such as sunlight, rain, and weathering, producing a large amount of acidic water or ionized water carrying heavy metals, which seriously pollutes the ecological environment of the mining area. In addition, gangue often contains pyrite and carbon-containing minerals, and there is a hidden danger of spontaneous combustion under the condition of contact with air, and even produces toxic gases and smoke such as SO 2 , CO 2 , NH 3 , which are harmful to human life. cause serious damage.
随着上部煤层开采量逐年降低,开采逐年向下部煤层转移,高硫煤占用较大比例,尤其西南地区所占比例高达80% 以上,由于大部分S元素是以硫铁矿的形式存在,经过分选加工后大部分硫铁矿赋存于煤矸石中,矸石中的全硫含量高达10%以上。相对于普通矸石,高硫矸石的堆放更易导致自燃甚至爆炸等现象的发生,环境的污染以及生产安全等问题更加突出。As the mining volume of the upper coal seam decreases year by year, the mining shifts to the lower coal seam year by year, and high-sulfur coal occupies a large proportion, especially in the southwest region, where the proportion is as high as more than 80%. Since most of the S element exists in the form of pyrite, after After sorting and processing, most of the pyrite occurs in coal gangue, and the total sulfur content in gangue is as high as 10%. Compared with ordinary gangue, the stacking of high-sulfur gangue is more likely to cause spontaneous combustion or even explosion, and the problems of environmental pollution and production safety are more prominent.
目前,对矸石中硫铁矿富集主要以湿法分选为主,而硫铁矿中硫元素遇水易发生氧化,引发自燃等现象,分选后需要对精矿进行干燥、脱水处理,生产成本较高;同时,水资源日益短缺,各国都在倡导节约用水,我国于2010年开始进行国家水资源战略规划,明确对水资源的利用提出控制的要求,因此,我们急需研究无水环境下的选矿工艺。At present, the enrichment of pyrite in gangue is mainly based on wet separation, and the sulfur element in pyrite is easily oxidized when it meets water, causing spontaneous combustion and other phenomena. After separation, the concentrate needs to be dried and dehydrated. The production cost is high; at the same time, water resources are increasingly scarce, and all countries are advocating water conservation. my country began to carry out national water resources strategic planning in 2010, and clearly put forward control requirements for the use of water resources. Therefore, we urgently need to study water-free environments. The following beneficiation process.
发明内容Contents of the invention
本发明目的是要提供一种线路合理、清洁高效、安全可靠的高效的煤系黄铁矿干法富集工艺。The object of the present invention is to provide a dry enrichment process of coal-measure pyrite with reasonable lines, clean and efficient, safe and reliable.
为了实现上述目的,本发明采用了如下的技术方案:干法富集工艺:首先对样品进行筛分分级:当黄铁矿以粗粒集合体嵌布解离度较高时,待选高硫煤矸石经由给料机先进入6mm的分级筛,筛分成+6mm、-6mm两个粒度级,筛分分级后的两种物料分别送入缓冲仓,其中-6mm物料再利用3mm、1mm、0.5mm的分级筛分别筛分成-6+3mm、-3+1mm、-1+0.5mm、-0.5mm四个粒级,并将筛分分级后的物料送入缓冲仓,所述筛分分级后的物料+3mm、+1mm和+0.5mm分别进入下一级振动流化床分选机进行分选,从振动流化床分选机分选出的3mm、1mm、0.5mm的精矿和尾矿;筛分分级后的物料+6mm直接进入干法重介质流化床分选机或者复合式干法分选机分选富集回收黄铁矿,获得精矿和尾矿;当高硫矸石中黄铁矿嵌布粒度较细解离度较低时,样品需要先进入破碎机进行闭路破碎至-6mm,利用3mm、1mm、0.5mm的分级筛分别筛分成-6+3mm、-3+1mm、-1+0.5mm、-0.5mm四个粒级,并将筛分分级后的物料送入缓冲仓,其中,-0.5mm的物料作为介质加入分选机中促进矿物的分选,也可以直接掺入精矿,调节精矿的品位;筛分分级后的3mm、1mm、0.5mm的物料分别进入下一级振动流化床分选机进行分选,获得精矿和尾矿。In order to achieve the above object, the present invention adopts the following technical scheme: dry enrichment process: firstly, the sample is screened and classified: when the pyrite is embedded in a coarse aggregate with a high degree of dissociation, the high-sulfur to be selected The coal gangue first enters the 6mm grading sieve through the feeder, and is screened into two particle size grades of +6mm and -6mm. The two materials after screening and grading are sent to the buffer bin respectively, and the -6mm material is reused 3mm, 1mm, 0.5 The grading sieve of mm is sieved into four grades of -6+3mm, -3+1mm, -1+0.5mm, -0.5mm respectively, and the materials after sieving and grading are sent to the buffer bin. The materials +3mm, +1mm and +0.5mm respectively enter the next stage vibrating fluidized bed separator for separation, and the concentrates and tailings of 3mm, 1mm and 0.5mm separated from the vibrating fluidized bed separator ore; the screened and classified material +6mm directly enters the dry heavy medium fluidized bed separator or the compound dry separator for separation, enrichment and recovery of pyrite to obtain concentrate and tailings; when high sulfur gangue When the particle size of the medium pyrite embedding is finer and the dissociation degree is low, the sample needs to enter the crusher for closed-circuit crushing to -6mm, and use 3mm, 1mm, and 0.5mm grading sieves to sieve into -6+3mm, -3+ 1mm, -1+0.5mm, -0.5mm four grades, and the screened and classified materials are sent to the buffer bin, in which -0.5mm materials are added to the sorting machine as a medium to promote the separation of minerals. It can be directly mixed into the concentrate to adjust the grade of the concentrate; the 3mm, 1mm, and 0.5mm materials after screening and classification are respectively sent to the next stage of vibrating fluidized bed separator for separation to obtain concentrate and tailings.
所述的干法重介质流化床分选机或者复合式干法分选机富集回收黄铁矿指缓冲仓+6mm煤矸石物料经给料机和皮带机进入分选机,密度大的黄铁矿进入床层底部与矸石实现分离;精矿与尾矿分别进入精矿仓和尾矿仓;所述精矿为黄铁矿,尾矿为矸石。The dry heavy medium fluidized bed sorter or compound dry sorter for enrichment and recovery of pyrite refers to the buffer bin + 6mm coal gangue material enters the sorter through the feeder and belt conveyor, and the denser The pyrite enters the bottom of the bed and is separated from the gangue; the concentrate and the tailings enter the concentrate bin and the tailing bin respectively; the concentrate is pyrite, and the tailings are gangue.
所述的振动流化床分选机分选是将缓冲仓内-6+3mm、-3+1mm、-1+0.5mm物料分别经给料机和皮带机输送至振动流化床分选机进行分选,床层内不同密度物料在振动流化床分选机中在流化床中的稀相区进行干扰沉降,黄铁矿因其密度大的特征富集在床层底部;分选后的精矿与尾矿分别进入精矿仓和尾矿仓;所述的精矿为黄铁矿,尾矿为矸石。The sorting of the vibrating fluidized bed sorting machine is to transport the -6+3mm, -3+1mm, -1+0.5mm materials in the buffer bin to the vibrating fluidized bed sorting machine respectively through the feeder and the belt conveyor For separation, materials with different densities in the bed are disturbed and settled in the dilute phase area in the fluidized bed in the vibrating fluidized bed separator, and pyrite is enriched at the bottom of the bed because of its high density; The final concentrate and tailings enter the concentrate bin and the tailings bin respectively; the concentrate is pyrite, and the tailings are gangue.
所述的振动流化床分选机分选是通过调节气流速度、振动强度、床层高度、分选时间因素来控制产品分选后产品的回收率和产率;振动流化床分选机的工作气速为:1.05~1.75m/s;床层高度为:80~200mm;振动强度:1.21~6.44;分选时间为:100~200s。The sorting of the described vibrating fluidized bed sorter is to control the recovery and productivity of the product after product sorting by adjusting the air velocity, vibration intensity, bed height and sorting time factors; the vibrating fluidized bed sorting machine The working gas velocity is: 1.05~1.75m/s; bed height: 80~200mm; vibration intensity: 1.21~6.44; sorting time: 100~200s.
所述的干法重介质流化床分选机分选是通过调节气流速度、开孔率、加重质组成、床层高度、分选时间来控制产品分选后产品的回收率和产率;流化床的工作气速为:1.05~1.35m/s,加重质组成为:-0.50+0.15mm磁铁矿粉含量占60~90%,真密度为4.2g/cm3~4.8g/cm3;床层高度为150~300mm,分选时间为:100~200s。The separation of the dry heavy medium fluidized bed separator is to control the recovery rate and yield of the product after product separation by adjusting the air velocity, opening ratio, weight composition, bed height, and separation time; The working gas velocity of the fluidized bed is: 1.05~1.35m/s, the aggravated mass composition is: -0.50+0.15mm, the content of magnetite powder accounts for 60~90%, and the true density is 4.2g/cm 3 ~4.8g/cm 3 ; The bed height is 150~300mm, and the sorting time is 100~200s.
复合式干法分选机分选是通过调节气流速度、振动强度、振动频率、分选时间来控制产品分选后产品的回收率和产率;操作气速为1.05~1.35m/s,振动强度为1~5mm,振动频率40~60HZ,分选时间为100~200s。The sorting of the compound dry sorting machine is to control the recovery rate and yield of the product after sorting by adjusting the air velocity, vibration intensity, vibration frequency and sorting time; the operating gas velocity is 1.05~1.35m/s, and the vibration The strength is 1~5mm, the vibration frequency is 40~ 60HZ , and the sorting time is 100~200s.
干法富集工艺的系统包括:风包、鼓风机、给料机、分级筛、破碎机、缓冲仓、干法重介质流化床分选机分选机、复合式干法分选机、振动流化床分选机;风包与鼓风机相连,鼓风机与干法重介质流化床分选机、复合式干法分选机和振动流化床分选机相连,为物料的分选提供适当的风量;The system of dry enrichment process includes: wind bag, blower, feeder, grading screen, crusher, buffer bin, dry heavy medium fluidized bed separator, compound dry separator, vibration Fluidized bed separator; the wind drum is connected with the blower, and the blower is connected with the dry heavy medium fluidized bed separator, the compound dry method separator and the vibrating fluidized bed separator to provide proper air volume;
当黄铁矿以粗粒集合体嵌布解离度较高时,给料机与6mm的分级筛相连,6mm分级筛的两个产品出口处也各置于一个缓冲仓相连,+6mm物料的缓冲仓与空气重介质流化床或者复合式干法分选机连接,-6mm物料的缓冲仓与3mm的分级筛连接,3mm分级筛的两个产品出口处各置于一个缓冲仓,+3mm物料的缓冲仓与振动流化床分选机连接,-3mm物料的缓冲仓与1mm的分级筛连接,1mm分级筛的两个产品出口处各置于一个缓冲仓,+1mm物料的缓冲仓与振动流化床分选机连接,-1mm物料的缓冲仓与0.5mm的分级筛连接,0.5 mm分级筛的两个产品出口处也各置于一个缓冲仓,+0.5mm物料的缓冲仓与振动流化床分选机连接;When the dissociation degree of pyrite is high in coarse-grained aggregates, the feeder is connected with a 6mm grading sieve, and the two product outlets of the 6mm grading sieve are also connected with a buffer warehouse, and the +6mm material The buffer bin is connected with the air-heavy medium fluidized bed or compound dry sorting machine, the buffer bin for -6mm material is connected with the 3mm grading screen, and the two product outlets of the 3mm grading screen are each placed in a buffer bin, +3mm The material buffer bin is connected to the vibrating fluidized bed sorter, the -3mm material buffer bin is connected to the 1mm grading sieve, the two product outlets of the 1mm grading sieve are each placed in a buffer bin, and the +1mm material buffer bin is connected to the The vibrating fluidized bed sorter is connected, the buffer bin of -1mm material is connected with the 0.5mm grading sieve, and the two product outlets of the 0.5 mm grading sieve are also placed in a buffer bin, and the buffer bin of +0.5mm material is connected with the vibration Fluidized bed separator connection;
当高硫矸石中黄铁矿嵌布粒度较细解离度较低时,给料机与破碎机相连,破碎机与 6mm分级筛相连进行闭路破碎,6mm分级筛与-6mm物料的缓冲仓相连,-6mm物料的缓冲仓与3mm的分级筛连接,3mm分级筛的两个产品出口处各置于一个缓冲仓,+3mm物料的缓冲仓与振动流化床分选机连接,-3mm物料的缓冲仓与1mm的分级筛连接, 1mm分级筛的两个产品出口处各置于一个缓冲仓,+1mm物料的缓冲仓与振动流化床分选机连接,-1mm物料的缓冲仓与0.5mm的分级筛连接,0.5 mm分级筛的两个产品出口处也各置于一个缓冲仓,+0.5mm物料的缓冲仓与振动流化床分选机连接。When the particle size of pyrite embedding in high-sulfur gangue is fine and the degree of dissociation is low, the feeder is connected with the crusher, the crusher is connected with the 6mm grading screen for closed-circuit crushing, and the 6mm grading screen is connected with the buffer bin for -6mm materials , the buffer bin of -6mm material is connected with the 3mm grading sieve, and the two product outlets of the 3mm grading sieve are respectively placed in a buffer bin, the buffer bin of +3mm material is connected with the vibrating fluidized bed separator, and the -3mm material The buffer bin is connected to the 1mm grading screen, and the two product outlets of the 1mm grading screen are each placed in a buffer bin, the buffer bin for +1mm materials is connected to the vibrating fluidized bed separator, and the buffer bin for -1mm materials is connected to the 0.5mm The two product outlets of the 0.5mm grading sieve are also placed in a buffer bin, and the buffer bin for +0.5mm materials is connected to the vibrating fluidized bed separator.
有益效果:由于采用了上述方案,避免了以湿法为主的传统富集方法,不仅节约了大量水资源,而且没有涉及到水,避免了二次污染问题和复杂的煤泥水处理系统,利用合理的除尘系统,粉尘污染小,机器运行噪声小,减轻环境污染。由于其系统布置简单,减少了土地的使用,大大减少土地的建设的空间和费用。Beneficial effects: Due to the adoption of the above scheme, the traditional enrichment method based on wet method is avoided, not only saves a lot of water resources, but also does not involve water, avoids the problem of secondary pollution and the complicated slime water treatment system, and utilizes Reasonable dust removal system, less dust pollution, less noise in machine operation, and less environmental pollution. Because the system layout is simple, the use of land is reduced, and the space and cost of land construction are greatly reduced.
优点:该工艺流程简单,技术路线合理,处理量大,运行稳定,可有效减少运行成本。Advantages: The process is simple, the technical route is reasonable, the processing capacity is large, the operation is stable, and the operation cost can be effectively reduced.
附图说明Description of drawings
图1为本发明工艺流程图。Fig. 1 is process flow chart of the present invention.
图2为本发明解离度较高的黄铁矿富集工艺具体实施工艺流程图。Fig. 2 is a specific implementation process flow chart of the pyrite enrichment process with a higher degree of dissociation in the present invention.
图3为本发明解离度较低的黄铁矿富集工艺具体实施工艺流程图。Fig. 3 is a flow chart of the specific implementation of the process for enriching pyrite with a relatively low degree of dissociation in the present invention.
具体实施方式detailed description
干法富集工艺:首先对样品进行筛分分级:当黄铁矿以粗粒集合体嵌布解离度较高时,待选高硫煤矸石经由给料机先进入6mm的分级筛,筛分成+6mm、-6mm两个粒度级,筛分分级后的两种物料分别送入缓冲仓,其中-6mm物料再利用3mm、1mm、0.5mm的分级筛分别筛分成-6+3mm、-3+1mm、-1+0.5mm、-0.5mm四个粒级,并将筛分分级后的物料送入缓冲仓,所述筛分分级后的物料+3mm、+1mm和+0.5mm分别进入下一级振动流化床分选机进行分选,从振动流化床分选机分选出的3mm、1mm、0.5mm的精矿和尾矿;筛分分级后的物料+6mm直接进入干法重介质流化床分选机或者复合式干法分选机分选富集回收黄铁矿,获得精矿和尾矿;当高硫矸石中黄铁矿嵌布粒度较细解离度较低时,样品需要先进入破碎机进行闭路破碎至-6mm,利用3mm、1mm、0.5mm的分级筛分别筛分成-6+3mm、-3+1mm、-1+0.5mm、-0.5mm四个粒级,并将筛分分级后的物料送入缓冲仓,其中,-0.5mm的物料作为介质加入分选机中促进矿物的分选,也可以直接掺入精矿,调节精矿的品位;筛分分级后的3mm、1mm、0.5mm的物料分别进入下一级振动流化床分选机进行分选,获得精矿和尾矿。Dry enrichment process: firstly, sieve and classify the samples: when pyrite is embedded in coarse-grained aggregates and has a high dissociation degree, the high-sulfur coal gangue to be selected enters the 6mm grading sieve through the feeder, and the sieve Divided into two particle size grades of +6mm and -6mm, the two materials after screening and classification are sent to the buffer bin respectively, and the -6mm material is screened into -6+3mm, -3mm by 3mm, 1mm and 0.5mm grading screens +1mm, -1+0.5mm, -0.5mm four grades, and the screened and classified materials are sent to the buffer bin, and the screened and classified materials +3mm, +1mm and +0.5mm respectively enter the lower The first-level vibrating fluidized bed sorter is used for sorting, and the 3mm, 1mm, 0.5mm concentrate and tailings are separated from the vibrating fluidized bed sorter; the material after screening and classification +6mm directly enters the dry process Dense medium fluidized bed sorter or compound dry sorter sorts, enriches and recovers pyrite, and obtains concentrate and tailings; when the particle size of pyrite embedded in high-sulfur gangue is finer, the degree of dissociation is lower , the sample needs to enter the crusher for closed-circuit crushing to -6mm, and use 3mm, 1mm, 0.5mm grading sieves to sieve into four grains of -6+3mm, -3+1mm, -1+0.5mm, -0.5mm Grade, and the screened and graded materials are sent to the buffer bin, in which -0.5mm materials are added to the sorter as a medium to promote the separation of minerals, and can also be directly mixed with concentrate to adjust the grade of concentrate; After classification, the 3mm, 1mm, and 0.5mm materials enter the next stage vibrating fluidized bed separator for separation to obtain concentrates and tailings.
所述的干法重介质流化床分选机或者复合式干法分选机富集回收黄铁矿指缓冲仓+6mm煤矸石物料经给料机和皮带机进入分选机,密度大的黄铁矿进入床层底部与矸石实现分离;精矿与尾矿分别进入精矿仓和尾矿仓;所述精矿为黄铁矿,尾矿为矸石。The dry heavy medium fluidized bed sorter or compound dry sorter for enrichment and recovery of pyrite refers to the buffer bin + 6mm coal gangue material enters the sorter through the feeder and belt conveyor, and the denser The pyrite enters the bottom of the bed and is separated from the gangue; the concentrate and the tailings enter the concentrate bin and the tailing bin respectively; the concentrate is pyrite, and the tailings are gangue.
所述的振动流化床分选机分选是将缓冲仓内-6+3mm、-3+1mm、-1+0.5mm物料分别经给料机和皮带机输送至振动流化床分选机进行分选,床层内不同密度物料在振动流化床分选机中在流化床中的稀相区进行干扰沉降,黄铁矿因其密度大的特征富集在床层底部;分选后的精矿与尾矿分别进入精矿仓和尾矿仓;所述的精矿为黄铁矿,尾矿为矸石。The sorting of the vibrating fluidized bed sorting machine is to transport the -6+3mm, -3+1mm, -1+0.5mm materials in the buffer bin to the vibrating fluidized bed sorting machine respectively through the feeder and the belt conveyor For separation, materials with different densities in the bed are disturbed and settled in the dilute phase area in the fluidized bed in the vibrating fluidized bed separator, and pyrite is enriched at the bottom of the bed because of its high density; The final concentrate and tailings enter the concentrate bin and the tailings bin respectively; the concentrate is pyrite, and the tailings are gangue.
所述的振动流化床分选机分选是通过调节气流速度、振动强度、床层高度、分选时间因素来控制产品分选后产品的回收率和产率;振动流化床分选机的工作气速为:1.05~1.75m/s;床层高度为:80~200mm;振动强度:1.21~6.44;分选时间为:100~200s。The sorting of the described vibrating fluidized bed sorter is to control the recovery and productivity of the product after product sorting by adjusting the air velocity, vibration intensity, bed height and sorting time factors; the vibrating fluidized bed sorting machine The working gas velocity is: 1.05~1.75m/s; bed height: 80~200mm; vibration intensity: 1.21~6.44; sorting time: 100~200s.
所述的干法重介质流化床分选机分选是通过调节气流速度、开孔率、加重质组成、床层高度、分选时间来控制产品分选后产品的回收率和产率;流化床的工作气速为:1.05~1.35m/s,加重质组成为:-0.50+0.15mm磁铁矿粉含量占60~90%,真密度为4.2g/cm3~4.8g/cm3;床层高度为150~300mm,分选时间为:100~200s。The separation of the dry heavy medium fluidized bed separator is to control the recovery rate and yield of the product after product separation by adjusting the air velocity, opening ratio, weight composition, bed height, and separation time; The working gas velocity of the fluidized bed is: 1.05~1.35m/s, the aggravated mass composition is: -0.50+0.15mm, the content of magnetite powder accounts for 60~90%, and the true density is 4.2g/cm 3 ~4.8g/cm 3 ; The bed height is 150~300mm, and the sorting time is 100~200s.
所述的复合式干法分选机分选是通过调节气流速度、振动强度、振动频率、分选时间来控制产品分选后产品的回收率和产率;操作气速为1.05~1.35m/s,振动强度为1~5mm,振动频率40~60HZ,分选时间为100~200s。The sorting of the compound dry sorting machine is to control the recovery rate and productivity of the product after product sorting by adjusting the air velocity, vibration intensity, vibration frequency and sorting time; the operating gas velocity is 1.05 ~ 1.35m/ s, the vibration intensity is 1~5mm, the vibration frequency is 40~ 60HZ , and the sorting time is 100~200s.
干法富集工艺的系统包括:风包、鼓风机、给料机、分级筛、破碎机、缓冲仓、干法重介质流化床分选机分选机、复合式干法分选机、振动流化床分选机;风包与鼓风机相连,鼓风机与干法重介质流化床分选机、复合式干法分选机和振动流化床分选机相连,为物料的分选提供适当的风量;The system of dry enrichment process includes: wind bag, blower, feeder, grading screen, crusher, buffer bin, dry heavy medium fluidized bed separator, compound dry separator, vibration Fluidized bed separator; the wind drum is connected with the blower, and the blower is connected with the dry heavy medium fluidized bed separator, the compound dry method separator and the vibrating fluidized bed separator to provide proper air volume;
当黄铁矿以粗粒集合体嵌布解离度较高时,给料机与6mm的分级筛相连,6mm分级筛的两个产品出口处也各置于一个缓冲仓相连,+6mm物料的缓冲仓与空气重介质流化床或者复合式干法分选机连接,-6mm物料的缓冲仓与3mm的分级筛连接,3mm分级筛的两个产品出口处各置于一个缓冲仓,+3mm物料的缓冲仓与振动流化床分选机连接,-3mm物料的缓冲仓与1mm的分级筛连接,1mm分级筛的两个产品出口处各置于一个缓冲仓,+1mm物料的缓冲仓与振动流化床分选机连接,-1mm物料的缓冲仓与0.5mm的分级筛连接,0.5 mm分级筛的两个产品出口处也各置于一个缓冲仓,+0.5mm物料的缓冲仓与振动流化床分选机连接;When the dissociation degree of pyrite is high in coarse-grained aggregates, the feeder is connected with a 6mm grading sieve, and the two product outlets of the 6mm grading sieve are also connected with a buffer warehouse, and the +6mm material The buffer bin is connected with the air-heavy medium fluidized bed or compound dry sorting machine, the buffer bin for -6mm material is connected with the 3mm grading screen, and the two product outlets of the 3mm grading screen are each placed in a buffer bin, +3mm The material buffer bin is connected to the vibrating fluidized bed sorter, the -3mm material buffer bin is connected to the 1mm grading sieve, the two product outlets of the 1mm grading sieve are each placed in a buffer bin, and the +1mm material buffer bin is connected to the The vibrating fluidized bed sorter is connected, the buffer bin of -1mm material is connected with the 0.5mm grading sieve, and the two product outlets of the 0.5 mm grading sieve are also placed in a buffer bin, and the buffer bin of +0.5mm material is connected with the vibration Fluidized bed separator connection;
当高硫矸石中黄铁矿嵌布粒度较细解离度较低时,给料机与破碎机相连,破碎机与 6mm分级筛相连进行闭路破碎,6mm分级筛与-6mm物料的缓冲仓相连,-6mm物料的缓冲仓与3mm的分级筛连接,3mm分级筛的两个产品出口处各置于一个缓冲仓,+3mm物料的缓冲仓与振动流化床分选机连接,-3mm物料的缓冲仓与1mm的分级筛连接, 1mm分级筛的两个产品出口处各置于一个缓冲仓,+1mm物料的缓冲仓与振动流化床分选机连接,-1mm物料的缓冲仓与0.5mm的分级筛连接,0.5 mm分级筛的两个产品出口处也各置于一个缓冲仓,+0.5mm物料的缓冲仓与振动流化床分选机连接。When the particle size of pyrite embedding in high-sulfur gangue is fine and the degree of dissociation is low, the feeder is connected with the crusher, the crusher is connected with the 6mm grading screen for closed-circuit crushing, and the 6mm grading screen is connected with the buffer bin for -6mm materials , the buffer bin of -6mm material is connected with the 3mm grading sieve, and the two product outlets of the 3mm grading sieve are respectively placed in a buffer bin, the buffer bin of +3mm material is connected with the vibrating fluidized bed separator, and the -3mm material The buffer bin is connected to the 1mm grading screen, and the two product outlets of the 1mm grading screen are each placed in a buffer bin, the buffer bin for +1mm materials is connected to the vibrating fluidized bed separator, and the buffer bin for -1mm materials is connected to the 0.5mm The two product outlets of the 0.5mm grading sieve are also placed in a buffer bin, and the buffer bin for +0.5mm materials is connected to the vibrating fluidized bed separator.
下面结合附图对本发明做进一步说明。The present invention will be further described below in conjunction with the accompanying drawings.
实施例1:Example 1:
当高硫矸石中黄铁矿主要以粗粒集合体嵌布解离度较高时,不需要进行破碎操作,采用干法重介质流化床分选机/复合式干法分选机与振动流化床分选机联合富集工艺。When the pyrite in the high-sulfur gangue is mainly distributed in coarse-grained aggregates with a high degree of dissociation, no crushing operation is required, and a dry heavy-medium fluidized bed separator/combined dry separator and vibration Fluidized bed separator combined enrichment process.
在图2中,本发明的高硫矸石中黄铁矿的富集工艺主要包括:物料准备、干法重介质流化床分选机/复合式干法分选机分选、振动流化床分选机分选三部分。其中物料准备部分包括分级筛、缓冲仓;分选部分包括干法重介质流化床分选机/复合式干法分选机振动流化床分选机分选机。具体步骤如下:In Fig. 2, the enrichment process of pyrite in high-sulfur gangue of the present invention mainly includes: material preparation, dry method heavy medium fluidized bed separator/compound dry method separator separation, vibrating fluidized bed The sorting machine sorts three parts. The material preparation part includes grading screen and buffer bin; the sorting part includes dry heavy medium fluidized bed sorter/combined dry sorter vibrating fluidized bed sorter sorter. Specific steps are as follows:
(1) 物料准备:利用6mm分级筛将待选物料(高硫煤矸石)分成+6mm、-6mm两个粒度级,并将筛分后的物料送入缓冲仓。其中-6mm物料再利用3mm、1mm、0.5mm的分级筛分别筛分成-6+3mm、-3+1mm、-1+0.5mm、-0.5mm四个粒级,并将筛分后的物料送入缓冲仓;-0.5mm的物料作为介质加入分选机中促进矿物的分选,也可以直接掺入精矿,调节精矿的品位;(1) Material preparation: Use a 6mm grading sieve to divide the material to be selected (high-sulfur coal gangue) into two particle size grades of +6mm and -6mm, and send the screened material into the buffer bin. Among them, the -6mm material is screened into four grades of -6+3mm, -3+1mm, -1+0.5mm, -0.5mm by using 3mm, 1mm, and 0.5mm grading sieves, and the screened material is sent to into the buffer bin; -0.5mm material is added to the sorter as a medium to promote the sorting of minerals, and can also be directly mixed into concentrate to adjust the grade of concentrate;
(2)干法重介质流化床分选机/复合式干法分选:将缓冲仓中+6mm煤矸石物料经给料机和皮带机送入干法重介质流化床分选机/复合式干法分选机,密度大的黄铁矿进入床层底部,与矸石实现分离分选后的黄铁矿作为精矿进入精矿仓,分选后尾矿进入尾矿仓;(2) Dry heavy medium fluidized bed sorter/combined dry sorting: the +6mm coal gangue material in the buffer bin is sent to the dry heavy medium fluidized bed sorter via feeder and belt conveyor/ Combined dry separation machine, the dense pyrite enters the bottom of the bed, and the pyrite after separation and separation from gangue enters the concentrate bin as concentrate, and the tailings enter the tailing bin after separation;
(3)振动流化床分选机分选:将缓冲仓内-6+3mm、-3+1mm、-1+0.5mm、-0.5mm四个粒级物料利用皮带机分别送入振动流化床分选机对进行分选,不同密度的物料在振动流化床分选机中的稀相区中进行干扰沉降,黄铁矿由于密度较大最终富集在床层底部,与矸石中的其他矿物完成分离,分选后的黄铁矿作为精矿进入精矿仓,分选后尾矿进入尾矿仓。(3) Vibrating fluidized bed sorting machine sorting: the materials in the buffer bin -6+3mm, -3+1mm, -1+0.5mm, -0.5mm are sent to the vibrating fluidized by belt conveyor respectively. The bed sorter is used for sorting, and materials with different densities are disturbed and settled in the dilute phase area of the vibrating fluidized bed sorter, and the pyrite is finally enriched at the bottom of the bed due to its high density, and it is separated from the waste in the gangue. The separation of other minerals is completed, and the sorted pyrite enters the concentrate bin as a concentrate, and the sorted tailings enter the tailing bin.
所述的干法重介质流化床分选机/复合式干法分选机与振动流化床分选机联合分选工艺适用于黄铁矿在高硫矸石中主要以粗粒集合体嵌布,并且黄铁矿解离度较高的情形。其中,干法重介质流化床分选机富集黄铁矿可以通过调节气流速度、开孔率、加重质组成、床层高度、分选时间等因素来控制产品分选后产品的回收率和产率;复合式干法分选机分选是通过调节气流速度、振动强度、振动频率、分选时间来控制产品分选后产品的回收率和产率;振动流化床分选机富集黄铁矿,可以通过调节气流速度、振动强度、床层高度、分选时间等因素来控制产品分选后产品的回收率和产率。所述的干法重介质流化床分选机的工作气速为:1.05~1.35m/s,加重质组成为:-0.50+0.15mm磁铁矿粉含量占60~90%,真密度为4.2g/cm3~4.8g/cm3;床层高度为150~300mm,分选时间为:100~200s。复合式干法分选机的操作气速为:1.05~1.35m/s;振动强度为:1~5mm;振动频率为:40~60HZ;分选时间为100~200s。振动流化床分选机的工作气速为:1.05~1.75m/s;床层高度为:80~200mm;振动强度:1.21~6.44;分选时间为:100~200s。The combined separation process of dry dense medium fluidized bed separator/compound dry separator and vibrating fluidized bed separator is suitable for pyrite embedding in high-sulfur gangue mainly as coarse-grained aggregates. Cloth, and pyrite dissociation degree is higher. Among them, the enrichment of pyrite by dry heavy medium fluidized bed separator can control the recovery rate of products after product separation by adjusting air velocity, opening ratio, weight composition, bed height, separation time and other factors. and yield; compound dry sorting machine sorting is to control the recovery rate and yield of products after product sorting by adjusting air velocity, vibration intensity, vibration frequency and sorting time; vibrating fluidized bed sorter is rich To collect pyrite, the recovery rate and yield of the product after separation can be controlled by adjusting the air velocity, vibration intensity, bed height, separation time and other factors. The working gas velocity of the dry heavy medium fluidized bed separator is: 1.05~1.35m/s, and the weight composition is: -0.50+0.15mm The magnetite powder content accounts for 60~90%, and the true density is 4.2g/cm 3 ~4.8g/cm 3 ; the bed height is 150~300mm, and the separation time is 100~200s. The operating gas velocity of the compound dry sorting machine is: 1.05~1.35m/s; the vibration intensity is: 1~5mm; the vibration frequency is: 40~ 60HZ ; the sorting time is 100~200s. The working gas velocity of the vibrating fluidized bed separator is: 1.05~1.75m/s; the bed height: 80~200mm; the vibration intensity: 1.21~6.44; the separation time: 100~200s.
实施例2、Embodiment 2,
当高硫矸石中的黄铁矿嵌布粒度较细解离度较低时,首先对样品进行破碎解离操作,直接采用振动流化床分选机富集细粒高硫矸石中的硫铁矿。When the pyrite in the high-sulfur gangue has a fine particle size and a low degree of dissociation, the sample is first crushed and dissociated, and the vibrating fluidized bed separator is directly used to enrich the sulfur iron in the fine-grained high-sulfur gangue mine.
在图3中,本发明的高硫矸石中黄铁矿的富集工艺主要包括:物料准备、振动流化床分选机分选两部分。其中物料准备部分包括分级筛、缓冲仓;振动流化床分选机分选部分包括振动流化床分选机分选机。具体步骤如下:In Fig. 3, the enrichment process of pyrite in high-sulfur gangue of the present invention mainly includes two parts: material preparation and vibrating fluidized bed sorter sorting. The material preparation part includes grading screen and buffer bin; the sorting part of vibrating fluidized bed separator includes vibrating fluidized bed sorting machine. Specific steps are as follows:
(1)物料准备:利用破碎机将待选物料(高硫煤矸石)破碎至-6mm,并将-6mm的物料筛分成-6+3mm、-3+1mm、-1+0.5mm,-0.5mm四个粒级,筛分后的物料送入缓冲仓;-0.5mm的物料作为介质加入分选机中促进矿物的分选,也可以直接掺入精矿,调节精矿的品位;(1) Material preparation: Use a crusher to crush the material to be selected (high-sulfur coal gangue) to -6mm, and sieve the -6mm material into -6+3mm, -3+1mm, -1+0.5mm, -0.5 mm four grades, the screened material is sent to the buffer bin; -0.5mm material is added to the sorter as a medium to promote the separation of minerals, and can also be directly mixed into the concentrate to adjust the grade of the concentrate;
(2)振动流化床分选机分选:利用皮带机分别将-6+3mm、-3+1mm、-1+0.5mm三个粒级的物料送入振动流化床分选机对进行分选;不同密度的物料在振动流化床分选机中的稀相区中进行干扰沉降,黄铁矿由于密度较大最终富集在床层底部,与矸石中的其他矿物完成分离,分选后的黄铁矿作为精矿进入精矿仓,分选后尾矿进入尾矿仓;(2) Separation by vibrating fluidized bed sorter: Use a belt conveyor to send materials with three particle sizes of -6+3mm, -3+1mm, -1+0.5mm into the vibrating fluidized bed sorter for Separation; materials with different densities interfere with the sedimentation in the dilute phase area of the vibrating fluidized bed separator, and the pyrite is finally enriched at the bottom of the bed due to its high density, and is separated from other minerals in the gangue. The selected pyrite enters the concentrate bin as a concentrate, and the tailings enter the tailing bin after separation;
所述的振动流化床分选机联合分选工艺适用于高硫矸石中黄铁矿嵌布粒度较细,黄铁矿的解离度较低的情形。可以通过调节气流速度、振动强度、床层高度、分选时间等因素来控制产品分选后产品的回收率和产率。振动流化床分选机的工作气速为:1.05~1.75m/s;床层高度为:80~200mm;振动强度:1.21~6.44;分选时间为:100~200s;The combined separation process of the vibrating fluidized bed separator is suitable for the situation where the pyrite embedding particle size in the high-sulfur gangue is relatively fine and the dissociation degree of the pyrite is low. The recovery rate and yield of the product after product sorting can be controlled by adjusting the air velocity, vibration intensity, bed height, sorting time and other factors. The working gas velocity of the vibrating fluidized bed separator is: 1.05~1.75m/s; the bed height: 80~200mm; the vibration intensity: 1.21~6.44; the separation time: 100~200s;
在实际分选过程中,以上三个工艺流程中的任何一个作业产物硫分达标时将不再进行其下游作业。In the actual separation process, when the sulfur content of any one of the above three processes reaches the standard, the downstream operations will not be carried out.
Claims (7)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
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| CN201510561087.4A CN105080702B (en) | 2015-09-06 | 2015-09-06 | A kind of efficient coal-series pyrite dry method process of enriching and system |
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| CN105665122B (en) * | 2016-01-13 | 2017-12-01 | 华北理工大学 | The beneficiation method of troilite is reclaimed from gangue |
| CN106391268A (en) * | 2016-11-29 | 2017-02-15 | 西安科技大学 | Coal crushing, grading and sorting device and method |
| CN106607183B (en) * | 2017-02-09 | 2019-11-08 | 中国矿业大学 | A modular high-density coal-measure oil shale upgrading process and upgrading system |
| CN115945288A (en) * | 2018-09-18 | 2023-04-11 | 中国矿业大学 | A metal mineral enrichment process and system based on dry separation equipment |
| CN109482493B (en) * | 2018-11-22 | 2021-11-26 | 中国矿业大学 | Dry separation process for full-grain-size oil shale |
| CN109482494B (en) * | 2018-11-22 | 2021-11-26 | 中国矿业大学 | Full-particle-level dry method quality-improving and gangue-discharging process for power coal |
| CN111299153A (en) * | 2020-03-04 | 2020-06-19 | 中国矿业大学 | A kind of fluorite tail throwing dry process |
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| CN112871401A (en) * | 2021-01-11 | 2021-06-01 | 河北工程大学 | Coal mine associated mineral product gravity separation screening system and method |
| CN115121575B (en) * | 2022-06-27 | 2023-11-24 | 中国矿业大学 | A method for preparing coal gangue-based active powder and solidifying nuclide Se |
| CN119525009A (en) * | 2024-12-24 | 2025-02-28 | 中国矿业大学 | A fluidized separation and enrichment method for rare earth element carrier minerals from mine solid waste |
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