CN105062715B - A kind of household automatic dishwasher purificant for having high degerming effect and excellent rinsing effect concurrently - Google Patents
A kind of household automatic dishwasher purificant for having high degerming effect and excellent rinsing effect concurrently Download PDFInfo
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- CN105062715B CN105062715B CN201510490708.4A CN201510490708A CN105062715B CN 105062715 B CN105062715 B CN 105062715B CN 201510490708 A CN201510490708 A CN 201510490708A CN 105062715 B CN105062715 B CN 105062715B
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- automatic dishwasher
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- 230000000694 effects Effects 0.000 title claims abstract description 33
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 24
- 239000012752 auxiliary agent Substances 0.000 claims abstract description 11
- 239000002738 chelating agent Substances 0.000 claims abstract description 11
- 239000000725 suspension Substances 0.000 claims abstract description 11
- 239000002994 raw material Substances 0.000 claims abstract description 8
- 239000002904 solvent Substances 0.000 claims abstract description 8
- 230000003165 hydrotropic effect Effects 0.000 claims abstract description 7
- 239000002736 nonionic surfactant Substances 0.000 claims abstract description 7
- 239000003755 preservative agent Substances 0.000 claims abstract description 5
- 230000002335 preservative effect Effects 0.000 claims abstract description 5
- 239000000203 mixture Substances 0.000 claims description 30
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 27
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid group Chemical group C(CC(O)(C(=O)O)CC(=O)O)(=O)O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 18
- 239000004615 ingredient Substances 0.000 claims description 18
- 238000001035 drying Methods 0.000 claims description 13
- 238000003756 stirring Methods 0.000 claims description 12
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 11
- JIAARYAFYJHUJI-UHFFFAOYSA-L zinc dichloride Chemical compound [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 claims description 6
- 239000008367 deionised water Substances 0.000 claims description 5
- 229910021641 deionized water Inorganic materials 0.000 claims description 5
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L magnesium chloride Substances [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 claims description 5
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims description 4
- 230000033228 biological regulation Effects 0.000 claims description 4
- NSFKBZXCXCJZDQ-UHFFFAOYSA-N cumene;sodium Chemical group [Na].CC(C)C1=CC=CC=C1 NSFKBZXCXCJZDQ-UHFFFAOYSA-N 0.000 claims description 4
- 238000002360 preparation method Methods 0.000 claims description 4
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims description 4
- 229910001629 magnesium chloride Inorganic materials 0.000 claims description 3
- 239000011592 zinc chloride Substances 0.000 claims description 3
- 235000005074 zinc chloride Nutrition 0.000 claims description 3
- 229940048842 sodium xylenesulfonate Drugs 0.000 claims description 2
- QUCDWLYKDRVKMI-UHFFFAOYSA-M sodium;3,4-dimethylbenzenesulfonate Chemical compound [Na+].CC1=CC=C(S([O-])(=O)=O)C=C1C QUCDWLYKDRVKMI-UHFFFAOYSA-M 0.000 claims description 2
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims 1
- 238000005660 chlorination reaction Methods 0.000 claims 1
- 241000588724 Escherichia coli Species 0.000 abstract description 13
- 241000191967 Staphylococcus aureus Species 0.000 abstract description 13
- 238000005260 corrosion Methods 0.000 abstract description 10
- 230000003750 conditioning effect Effects 0.000 abstract 1
- 241000894006 Bacteria Species 0.000 description 14
- 238000004851 dishwashing Methods 0.000 description 14
- 239000000047 product Substances 0.000 description 11
- 238000012360 testing method Methods 0.000 description 10
- 238000005406 washing Methods 0.000 description 10
- 239000003599 detergent Substances 0.000 description 8
- 244000005700 microbiome Species 0.000 description 7
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 6
- 229920000742 Cotton Polymers 0.000 description 5
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 5
- 244000052616 bacterial pathogen Species 0.000 description 5
- 238000004140 cleaning Methods 0.000 description 5
- 230000000813 microbial effect Effects 0.000 description 5
- 229920006243 acrylic copolymer Polymers 0.000 description 4
- 239000006260 foam Substances 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 159000000000 sodium salts Chemical class 0.000 description 4
- 239000000243 solution Substances 0.000 description 4
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 3
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- 229910052708 sodium Inorganic materials 0.000 description 3
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- CHHHXKFHOYLYRE-UHFFFAOYSA-M 2,4-Hexadienoic acid, potassium salt (1:1), (2E,4E)- Chemical compound [K+].CC=CC=CC([O-])=O CHHHXKFHOYLYRE-UHFFFAOYSA-M 0.000 description 2
- 229940100555 2-methyl-4-isothiazolin-3-one Drugs 0.000 description 2
- QCDWFXQBSFUVSP-UHFFFAOYSA-N 2-phenoxyethanol Chemical compound OCCOC1=CC=CC=C1 QCDWFXQBSFUVSP-UHFFFAOYSA-N 0.000 description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- WHUUTDBJXJRKMK-UHFFFAOYSA-N Glutamic acid Natural products OC(=O)C(N)CCC(O)=O WHUUTDBJXJRKMK-UHFFFAOYSA-N 0.000 description 2
- JLVVSXFLKOJNIY-UHFFFAOYSA-N Magnesium ion Chemical compound [Mg+2] JLVVSXFLKOJNIY-UHFFFAOYSA-N 0.000 description 2
- 241001465754 Metazoa Species 0.000 description 2
- 229910019142 PO4 Inorganic materials 0.000 description 2
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 2
- 108010077895 Sarcosine Proteins 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 238000004061 bleaching Methods 0.000 description 2
- 239000011575 calcium Substances 0.000 description 2
- 229910052791 calcium Inorganic materials 0.000 description 2
- 239000003153 chemical reaction reagent Substances 0.000 description 2
- NEHMKBQYUWJMIP-UHFFFAOYSA-N chloromethane Chemical compound ClC NEHMKBQYUWJMIP-UHFFFAOYSA-N 0.000 description 2
- 238000005202 decontamination Methods 0.000 description 2
- 230000003588 decontaminative effect Effects 0.000 description 2
- 238000001514 detection method Methods 0.000 description 2
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- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 235000013922 glutamic acid Nutrition 0.000 description 2
- 239000004220 glutamic acid Substances 0.000 description 2
- 239000008233 hard water Substances 0.000 description 2
- 208000015181 infectious disease Diseases 0.000 description 2
- 229910001425 magnesium ion Inorganic materials 0.000 description 2
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 2
- 239000011976 maleic acid Substances 0.000 description 2
- 235000013372 meat Nutrition 0.000 description 2
- BEGLCMHJXHIJLR-UHFFFAOYSA-N methylisothiazolinone Chemical group CN1SC=CC1=O BEGLCMHJXHIJLR-UHFFFAOYSA-N 0.000 description 2
- 235000006408 oxalic acid Nutrition 0.000 description 2
- 230000001717 pathogenic effect Effects 0.000 description 2
- 229960005323 phenoxyethanol Drugs 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 2
- 239000010452 phosphate Substances 0.000 description 2
- 239000011574 phosphorus Substances 0.000 description 2
- 229910052698 phosphorus Inorganic materials 0.000 description 2
- 229920001983 poloxamer Polymers 0.000 description 2
- 239000004302 potassium sorbate Substances 0.000 description 2
- 229940069338 potassium sorbate Drugs 0.000 description 2
- 235000010241 potassium sorbate Nutrition 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- FSYKKLYZXJSNPZ-UHFFFAOYSA-N sarcosine Chemical compound C[NH2+]CC([O-])=O FSYKKLYZXJSNPZ-UHFFFAOYSA-N 0.000 description 2
- 239000013049 sediment Substances 0.000 description 2
- 238000013112 stability test Methods 0.000 description 2
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 2
- 238000009736 wetting Methods 0.000 description 2
- FFRBMBIXVSCUFS-UHFFFAOYSA-N 2,4-dinitro-1-naphthol Chemical compound C1=CC=C2C(O)=C([N+]([O-])=O)C=C([N+]([O-])=O)C2=C1 FFRBMBIXVSCUFS-UHFFFAOYSA-N 0.000 description 1
- WJIUUKVQXQFABS-RGMNGODLSA-N C(C(=O)O)(=O)O.C(CC)N[C@@H](CCO)C(=O)O Chemical compound C(C(=O)O)(=O)O.C(CC)N[C@@H](CCO)C(=O)O WJIUUKVQXQFABS-RGMNGODLSA-N 0.000 description 1
- 241001478240 Coccus Species 0.000 description 1
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- 241000305071 Enterobacterales Species 0.000 description 1
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 1
- 241001272567 Hominoidea Species 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 206010040047 Sepsis Diseases 0.000 description 1
- 229920002125 Sokalan® Polymers 0.000 description 1
- 241000209140 Triticum Species 0.000 description 1
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- 230000002378 acidificating effect Effects 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 230000006978 adaptation Effects 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 238000007605 air drying Methods 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 230000002421 anti-septic effect Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 229920001400 block copolymer Polymers 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- XNEYCQMMVLAXTN-UHFFFAOYSA-N carbonic acid;magnesium Chemical compound [Mg].OC(O)=O XNEYCQMMVLAXTN-UHFFFAOYSA-N 0.000 description 1
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- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 1
- 238000012851 eutrophication Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 150000002191 fatty alcohols Chemical class 0.000 description 1
- 235000013312 flour Nutrition 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000008103 glucose Substances 0.000 description 1
- 125000000291 glutamic acid group Chemical group N[C@@H](CCC(O)=O)C(=O)* 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 229910052738 indium Inorganic materials 0.000 description 1
- 238000011081 inoculation Methods 0.000 description 1
- 239000006210 lotion Substances 0.000 description 1
- 235000012054 meals Nutrition 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- 229940050176 methyl chloride Drugs 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 230000002906 microbiologic effect Effects 0.000 description 1
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- YVJGIGDFHMIDFH-FTWQHDNSSA-N n-[(2s,3r,4r,5r,6r)-4,5-dihydroxy-6-(hydroxymethyl)-2-methoxyoxan-3-yl]-5-(dimethylamino)naphthalene-1-sulfonamide Chemical compound CO[C@H]1O[C@H](CO)[C@H](O)[C@H](O)[C@H]1NS(=O)(=O)C1=CC=CC2=C(N(C)C)C=CC=C12 YVJGIGDFHMIDFH-FTWQHDNSSA-N 0.000 description 1
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- 229920005646 polycarboxylate Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920000056 polyoxyethylene ether Polymers 0.000 description 1
- 235000010482 polyoxyethylene sorbitan monooleate Nutrition 0.000 description 1
- 229920000053 polysorbate 80 Polymers 0.000 description 1
- 229910052573 porcelain Inorganic materials 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
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- 210000002966 serum Anatomy 0.000 description 1
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- 239000001509 sodium citrate Substances 0.000 description 1
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 description 1
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Landscapes
- Detergent Compositions (AREA)
Abstract
The invention discloses a kind of household automatic dishwasher purificant with degerming effect, it contains each raw material components of following percentage by weight：5.0 15.0% nonionic surfactant；1.0 5.0% chelating agent；0.05 2.0% preservative；2.0 10.0% suspension dispersive agent；1.0% 10.0% hydrotropic agent；0.1% 10.0% solvent；0.1 8.0% anticorrosive auxiliary agent；0.5 3%pH value conditioning agents；0.1 0.3% essence.Specific anti-corrosion degerming component is added with the present invention, while ensureing Product Safety, the Escherichia coli or staphylococcus aureus being likely to be present on tableware can effectively be removed, more than 99.00% is reached to both clearances, the product of the present invention can be used in the home life, energy-conserving and environment-protective, there is good application prospect.
Description
Technical field
The present invention relates to household automatic dishwasher purificant, belong to daily chemical product technical field, specifically, this hair
It is bright to be related to a kind of household automatic dishwasher purificant with efficient degerming effect.
Background technology
Automatic dish-washing machine purificant is a kind of weakly acidic detergent, and it is that after completed washings, tableware and will put that it, which is acted on,
The residual water droplet on bowl frame surface is tried one's best reductions, and to be dried, each consumption is very few, can cause tableware surface leave water mark with
Bai Hen, can make tableware surface seem greasy using excessive.Therefore functionally, its design is the need based on following several respects
Will：1st, the residual alkali of cleaning fluid is neutralized.2nd, drying is accelerated.3rd, water stain, the outward appearance of improvement tableware, especially to transparent glass is reduced
Glass cup etc..4th, the froth breaking/suds washed the dishes in trough.
When routine use automatic dish-washing machine cleans tableware, special dish-washing machine detergent can be used to be washed, cleaned
The master of tableware washes the stage, is either emulsified the dirt washed away or Betengent product all inevitably has one in itself
A little dirts, or raw material are remained on tableware or in the wash solution of cleaning, and general dish-washing machine can all be provided with rinsing program,
The spot of residual is rinsed out as far as possible.This stage, with the use of upper special bleaching of dish washing machine agent, can be more efficient reach this
One purpose, and if purificant recipe ingredient have concurrently rinsing and degerming effect, more guarantees can be brought to our daily life.
The daily tableware used after the meal, particularly remains the tableware of meat, if cleaned not in time, often by micro- life
The pollution of thing, especially some pathogenic bacteria, it is Escherichia coli and staphylococcus aureus to contact more two kinds.E
Bacterium (E.coli) is commonly known as Escherichia coli, is that Escherich had found in 1885, some special serum of Escherichia coli
Type has pathogenic to humans and animals, especially to baby and cub (fowl), often causes severe diarrhea and septicemia.Staphylococcus aureus
Bacterium (Staphylococcus aureus Rosenbach) is a kind of important pathogen of the mankind, can cause a variety of severe infections.
There is the nickname of " thermophilic meat bacterium ".Staphylococcus aureus is ubiquitous in nature, the row of empty gas and water, dust and humans and animals
Letting out in thing can all find.Thus, the chance that food is polluted by it is a lot.
In recent years, the Center for Disease Control is reported, the infection as caused by staphylococcus aureus accounts for second, is only second to
Escherichia coli.For both common pathogenic bacteria, how to be removed in dishwashing procedure, be that industry is badly in need of asking for solution
Topic.China Patent Publication No. CN1070421A discloses a kind of rinsing drying brightener for tableware, and fatty alcohol polyoxy is used in invention
The surfactant such as the dilute ether phosphate salt of second and APES mainly emulsifies decontamination composition as it.Chinese patent is public
The number of opening CN101018850A discloses a kind of purificant containing hydrophobically modified polycarboxylate, main by adding poly- carboxylic in invention
Acids polymers, elution of the improved formulations during bleaching of dish washing machine is common during effectively scattered or emulsification dishwashing
Dirt, the insoluble salt of the scattered metal ion that can bring the water hardness finally gives the dish without point and without deposit.It is beautiful
State patent US03941713A1 discloses a kind of detergent composition, is equally used as invention using monoalkyl polyoxyethylene ethers phosphate
Main component, for emulsion dispersion decontamination, raw material is using phosphate as main component, during microorganism decomposition, P elements
It is likely to result in the eutrophication of water body.
Thus, the special dish-washing machine detergent of prior art stills need further to improve necessity of its formula.
The content of the invention
It is an object of the invention to provide a kind of household automatic dishwasher purificant with efficient degerming effect, ensureing
While good rinsing and quick-drying effect, product can be made to keep stable during storage, not by microorganism pollution, effectively gone
Except the microbial pathogens for being likely to remain at tableware surface.
Another object of the present invention is to provide a kind of above-mentioned household automatic dishwasher with efficient degerming effect to rinse
The preparation method of agent.
A kind of household automatic dishwasher purificant with degerming effect proposed by the present invention, it contains following weight percent
Each raw material components of ratio：
1.0-5.0% chelating agent；5.0-15.0% nonionic surfactant；2.0-10.0% suspended dispersed
Agent；1.0%-10.0% hydrotropic agent；0.05-2.0% anti-corrosion bacteria remover；0.1%-10.0% quick-drying solvent；
0.1-8.0% anticorrosive auxiliary agent；0.5-3% pH value regulator；0.1-0.3% essence；And surplus is deionized water.
The household automatic dishwasher purificant of the present invention, the chelating agent is glutamic acid N, and N, the sodium of oxalic acid four, methyl are sweet
The mixture of one or both of propylhomoserin oxalic acid and sodium citrate, wherein more preferably MDGA, methyl
Glycine oxalic acid is that a kind of new chelating agent has excellent sequestering power, using safety, is not produced any harmful
Material, biological degradability is good, there is higher solubility property to inorganic sediment, adds somewhat to the rinsing effect of product
Really, preferential addition is 2%-3%.
The present invention household automatic dishwasher purificant, the nonionic surfactant be AEO-
9th, at least one of AEO -7, Pluronic PE 6800 or two or more mixtures.It is wherein preferred
Pluronic PE 6800, it has excellent emulsification clean effect, and foam volume is low, will not be in automatic dish-washing machine running
It is middle to produce a large amount of foams, cause washing to bear to machine, preferably addition is 10.0%-15.0%.
The present invention household automatic dishwasher purificant, the suspension dispersive agent be maleic acid/acrylic copolymer sodium salt,
Maleic acid/at least one of olefin copolymer sodium salt and polyacrylic acid sodium salt or two or more mixtures, wherein it is preferred that horse
Carry out sour/acrylic copolymer sodium salt, preferential addition is 2%-5%.
The household automatic dishwasher purificant of the present invention, the hydrotropic agent is cumene sodium sulfonate and xylene monosulfonic acid
The mixture of one or both of sodium, wherein more preferably cumene sodium sulfonate, preferably addition are 2%-4%.
The household automatic dishwasher purificant of the present invention, the anti-corrosion bacteria remover is methylisothiazolinone, methyl chloride is different
Mixture more than one or both of thiazolinone, Phenoxyethanol and potassium sorbate.
The household automatic dishwasher purificant of the present invention, the quick-drying solvent is one or both of ethanol and isopropanol
Mixture；The anticorrosive auxiliary agent is magnesium chloride and at least one or two mixture of zinc chloride；The pH value regulator
For citric acid.
The household automatic dishwasher purificant of the present invention, the essence is not particularly limited requirement, preferably addition
0.1%-0.3%.
The household automatic dishwasher purificant of the present invention, its pH value is between 3.0-6.0.
The present invention has the preparation method of the household automatic dishwasher purificant of efficient degerming effect, and it includes following step
Suddenly：
1) first add a certain amount of deionized water into ingredients pot, input chelating agent, nonionic surfactant, water-soluble help
Long agent, quick-drying solvent, stir；
2) input suspension dispersive agent and anticorrosive auxiliary agent, stir；
3) citric acid is added, regulation pH value stirs to proper range；
4) essence and anti-corrosion bacteria remover are put into ingredients pot, is stirred；
5) other auxiliary agents are added into ingredients pot, are stirred；
6) water of the addition surplus into ingredients pot is continued, through examining qualified and being packed.
The invention has the advantages that and beneficial effect：
1st, the present invention is added with anti-corrosion degerming component, and while ensureing stabilization, the security of product, effectively removing may be residual
The Escherichia coli or staphylococcus aureus being deposited in, more than 99.00% is reached to both clearances.
2nd, water body will not be polluted without using phosphide is contained in the present invention, burden is brought to environment.
3rd, the comprehensive low bubble table of nonionic for having used EO-PO blocks is lived and antiredeposition composition in the present invention, molten to rinse
Liquid provides good spreading wetting ability, and effectively takes away the composition that may be remained or deposit.
4th, currently preferred chelating agent is a kind of new chelating agent, there is excellent sequestering power, using safety, is not produced
Raw any harmful material, biological degradability is good, has higher solubility property to inorganic sediment, there is collaboration corrosion-resistant
Effect, product of the invention can be used in the home life, and energy-conserving and environment-protective have good application prospect.
5th, present invention surprisingly has found that, containing methylisothiazolinone, methylchloroisothiazandnone, Phenoxyethanol and
At least one of potassium sorbate or two or more mixtures can be removed efficiently greatly as the dishwasher detergent composition of bacteria remover
Enterobacteria and staphylococcus aureus, while having good deterging net effect.The purificant composition of the present invention is without phosphorus
Compound, while product primary demand is kept, reduces the pollution to water body, meets the demand of environmental protection.
Embodiment
The household automatic dishwasher purificant of the present invention, its raw material components included have：Chelating agent, non-ionic surface active
Agent, suspension dispersive agent, hydrotropic agent, anti-corrosion bacteria remover, quick-drying solvent, anticorrosive auxiliary agent, pH value regulator and other help
Agent such as essence etc..
Dirt can be weakened by reducing water surface tension and its distinctive wetting, scattered, emulsification, solubilization using surfactant
Dirt tableware surface adhesive force, easily from tableware surface departs from and is distributed to water.Also prevent soil redeposition to tableware
The effect on surface, can avoid after cleaning dirt form spot and film again in tableware surface.
Chelating agent is mainly used in chelating calcium, magnesium ion in water, prevents from generating substantial amounts of calcium carbonate or carbonic acid magnesium precipitate,
Final phase of a chess game surface is attached to, while there is collaboration corrosion-resistant effect.
Suspension dispersive agent is to be dispersed in the material or impurity of removal in water body well, is excluded with the process of draining
Outside automatic dish-washing machine.Hydrotropic agent can improve the cloud point of nonionic surfactant in system, in high-temperature wash process
In, table work will not be because temperature is too high and separates out, it is impossible to plays its effect.
Quick-drying solvent can accelerate the drying rate of tableware surface moisture in automatic dish-washing machine drying course, and cause drift
Stable foam is not produced during washing, is easy to rinsing.
Rinse and anti-corrosion degerming component is introduced in agent prescription, quality safety of the product during storage can be played necessarily
Guaranteeing role.
The present invention it is without phosphorus refer to not add the compound containing P elements in the composition artificially, specifically, poly- carboxylic
Weight content of the hydrochlorate in the detergent composition of the present invention is not higher than 0.0001%；Bacteria remover refers to removal or kills specific micro-
Biological preparation, the degerming removal referred mainly to for Escherichia coli and staphylococcus aureus in invention；Pathogenic bacteria
(Pathogenic bacteria), which refers to, can cause the microorganism of disease to be referred to as pathogenic microorganism or pathogenic bacteria；It is efficiently degerming to refer to
99.00% or more is reached for the clearance of Escherichia coli and staphylococcus aureus.
The present invention is expressed in further detail below by way of specific preferred embodiment, but the present invention be not limited in it is following
Embodiment.
Embodiment 1~4
According to the composition of raw materials of table 1 below, a certain amount of deionized water is first added into ingredients pot, methylglycine two is put into
Acetic acid, EO/PE block copolymers, cumene sodium sulfonate, ethanol, stir；Put into acrylic copolymer and magnesium chloride, stirring
Uniformly；Citric acid is added, regulation pH value stirs to proper range；Essence and preservative are put into ingredients pot, stirring is equal
It is even；Other auxiliary agents are added into ingredients pot, are stirred；Continue the water of the addition surplus into ingredients pot, through examining qualified and entering
Row packaging.
The household automatic dishwasher rinsing agent prescription composition of the embodiment 1~4 of table 1
Embodiment 5~8
According to the composition of raw materials of table 2 below, a certain amount of deionized water is first added into ingredients pot, glutamic acid N, N, two is put into
The sodium of acetic acid four, PE6200, sodium xylene sulfonate, ethanol, stir；Acrylic copolymer and zinc chloride are put into, is stirred；
Citric acid is added, regulation pH value stirs to proper range；Essence and preservative are put into ingredients pot, is stirred；To
Other auxiliary agents are added in ingredients pot, are stirred；Continue the water of the addition surplus into ingredients pot, through examining qualified and being wrapped
Dress.
The household automatic dishwasher rinsing agent prescription composition of the embodiment 5~8 of table 2
Application effect test example
1st, composition stability test
By above-described embodiment, in order to test compatibility stability of the degerming component in invention component, commercially available brand is contrasted
Automatic dish-washing machine purificant, has carried out thimble test, i.e., compound composition is sub-packed in the transparent PET bottles of 250ml,
It is placed in 45 DEG C of baking oven one month, takes out and contrasted with RT sample, observes test sample outward appearance, and test composition
Middle antiseptic content change, color appearance is without obvious flavescence, and it is qualified products that preservative conservation rate, which is more than 50%,.
The purificant component high-temperature stability test data of table 3
In the data display of table 3, embodiment 1-8 component, the compatibility of degerming component and other components is good, stable storing,
The stability of product can effectively be kept.
2nd, rinsing performance is tested
In order to further determine the rinsing performance of detergent composition in invention, setting method of testing is as follows：The drift of tableware
Washing effect can not be embodied with specific correction data, and the form that can be observed by the naked eye is evaluated and tested.30 are looked for respectively not
With the crowd of age bracket, (M-F is close to 1:1) Blind Test is carried out to tableware wash effect, and effect is rinsed to tableware to comment
Point, 5 points of effects are optimal, and fraction is lower, and it is poorer that tableware rinses effect, are 4,3,2,1 points successively, and 0 point indicates without rinsing effect.Comment
The rinsing performance more than or equal to 2 is divided to be determined as qualified.
The rinsing performance of table 4 evaluates and tests data
Data above shows that the rinsing performance of Example formulations has reached the wash effect needed.
3rd, wash effect is tested
Bacteria-eliminating efficacy (main test strain is Escherichia coli and staphylococcus aureus) detection method is as follows：
Prepare before 1 experiment：
1.1 prepare artificial dirt, and the formula of artificial dirt is as follows：Miscella 15%, wheat flour 15%, whole milk powder
7.5%, fresh whole egg liquid 30%, distilled water 32.5%；Dirt compound method is with reference to GB 9985-2000 manual dishwashings with washing
Wash agent；
1.2 prepare dirt bacteria suspension (Escherichia coli, golden yellow glucose coccus prepare respectively), and artificial dirt is added by 1%
In sterilized water, 0.05% Tween 80 adds bacteria suspension so that the dense initial bacterium of dirt bacteria suspension is 105CFU/mL；
1.3 prepare cleaning solutions, accurately weigh 0.8g liquid detergents and are dissolved in containing in 2000mL 250mg/L hard water, hard water city
Sell basin (bore 34cm, bottom footpath 24cm) splendid attire.
The degerming rate of 2 service plates is determined
2.1 instrument
(1) balance；
(2) commercially available basin (bore 34cm, bottom footpath 24cm)；
(3) white porcelain vegetable dish (external diameter 200mm, try to get to the heart of a matter smeared portion about 140mm)；
(4) the brown paintbrush of pig, 102mm；
(5) graduated cylinder, 1000ml；
(6) stopwatch；
Equipment needed for microorganism detection is with reference to QB/T 2738-2012.
Reagent：Required reagent is with reference to QB/T 2738-2012 and GB 9985-2000.
2.2 experimental arrangement
2.2.1 dirt bacteria suspension is dipped with aseptic cotton carrier uniformly to smear 3 times in dish surface (service plate bottom), is often applied once
60 ° are rotated, is rotated for the last time around plate 1 week, 4 plates is smeared altogether, stand 20 minutes, wherein 2 for when being inoculated with
Count plate, 2 are used for count plate after washing, it is desirable to which viable bacteria reclaims concentration not less than 104CFU/mL after inoculation；
2.2.2 the service plate for scribbling dirt is put into equipped with cleaning solution basin, then scrubbed with 102mm bristles paintbrush, first
Clockwise brush five times, another mistake hour hands brush five times, so in triplicate after, the dirt being applied on service plate is largely washed down, finally
The dirt under not washing and foam are scrubbed off again, about 50s is taken；After washing, rushed 30 seconds with running water (flow velocity 90-100mL/S),
Natural air drying 20 minutes, the micro organism quantity uniformly smeared with aseptic cotton carrier on service plate surface, plate count cotton swab (uses water 10mL
Normal saline dilution, is designated as 100), obtaining washing rear microbial count；
2.2.3 the micro organism quantity on another 2 service plate surfaces, plate count cotton swab is equally uniformly smeared with aseptic cotton carrier
(water 10mL normal saline dilutions are used, are designated as 100), obtaining washing preceding microbial count；
2.3 experimental result
Degerming rate=(wash preceding microbial count average value-washes rear microbial count average value)/wash before microbial count put down
Average * 100%
The degerming test result of the purificant of table 5
The test data of upper table shows, Example formulations component to the clearance of Escherichia coli and staphylococcus aureus all
More than 99.00% has been reached, has reached that effective degerming requirement is significantly better than common control's sample.
In summary, the household automatic dishwasher purificant with efficient degerming effect of the invention, is ensureing well
While rinsing and quick-drying effect, product can be made to keep stable during storage, not by microorganism pollution, effectively removing may
The microbial pathogens of tableware surface are remained in, more than 99.00% is reached to the clearance of Escherichia coli and staphylococcus aureus；
And in order to chelating the calcium in water body, magnesium ion etc. in rinse cycle, it is to avoid depositional phenomenon, and environment is not caused negatively
Influence, introduces the good sequestering ingredient of biological degradability in invention, it has collaboration corrosion-resistant effect concurrently.
The above described is only a preferred embodiment of the present invention, but the implementation of the present invention is not limited to this.Need to refer to
Go out, cited embodiment is served only for that the present invention is further described, it is impossible to be interpreted as to the scope of the present invention
Limitation, art personnel can make some nonessential modifications and adaptations according to present disclosure and fall within this hair
In bright protection domain.
Claims (9)
1. a kind of household automatic dishwasher purificant for having high degerming effect and excellent rinsing effect concurrently, it is characterised in that：It is also
Each raw material components containing following percentage by weight：
2. household automatic dishwasher purificant according to claim 1, it is characterised in that：The preferred addition of chelating agent
For 2%-3%.
3. household automatic dishwasher purificant according to claim 1, it is characterised in that：The nonionic surfactant
It is preferred that addition is 10.0%-15.0%.
4. household automatic dishwasher purificant according to claim 1, it is characterised in that：The suspension dispersive agent preferably adds
Dosage is 2%-5%.
5. household automatic dishwasher purificant according to claim 1, it is characterised in that：The hydrotropic agent preferably adds
Dosage is 2%-4%, and it is cumene sodium sulfonate or sodium xylene sulfonate or two kinds of mixture.
6. household automatic dishwasher purificant according to claim 1, it is characterised in that：The quick-drying solvent be ethanol or
Isopropanol or two kinds of mixture.
7. household automatic dishwasher purificant according to claim 1, it is characterised in that：The anticorrosive auxiliary agent is chlorination
Magnesium or zinc chloride or two kinds of mixture；The pH value regulator is citric acid.
8. household automatic dishwasher purificant according to claim 1, it is characterised in that：The pH value of the purificant exists
3.0-6.0 between.
9. the preparation method of the household automatic dishwasher purificant any one of claim 1-8, it is characterised in that including
Following steps：
1) a certain amount of deionized water, input chelating agent, nonionic surfactant, hydrotropic are first added into ingredients pot
Agent, quick-drying solvent, stir；
2) input suspension dispersive agent and anticorrosive auxiliary agent, stir；
3) citric acid is added, regulation pH value stirs to proper range；
4) essence and preservative are put into ingredients pot, is stirred；
5) other auxiliary agents are added into ingredients pot, are stirred；
6) water of the addition surplus into ingredients pot is continued, through examining qualified and being packed.
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| CN106833935A (en) * | 2016-12-23 | 2017-06-13 | 镇江华域环保设备制造有限公司 | The preparation method of fluid is gone in a kind of decontamination for kitchen use |
| CN107384619B (en) * | 2017-08-02 | 2020-09-11 | 广州立白企业集团有限公司 | Cleaning effervescent tablet with pesticide residue removing and bacterium removing effects and preparation method thereof |
| CN107523430A (en) * | 2017-09-26 | 2017-12-29 | 深圳市洁力士化工产品有限公司 | A kind of glass washing machine special glass cup brightener |
| CN109570162A (en) * | 2018-11-26 | 2019-04-05 | 蓝思科技股份有限公司 | The cleaning method of vacuum formed box |
| CN111073762A (en) * | 2019-12-27 | 2020-04-28 | 佛山市顺德区美的洗涤电器制造有限公司 | Liquid detergent composition suitable for automatic dosing in a dishwasher |
| CN113046192A (en) * | 2019-12-27 | 2021-06-29 | 佛山市顺德区美的洗涤电器制造有限公司 | Curing agent composition suitable for dish-washing machine |
| CN112625809A (en) * | 2020-12-18 | 2021-04-09 | 广州立白企业集团有限公司 | Liquid detergent composition for dishwasher and preparation method thereof |
| CN114774209B (en) * | 2022-05-16 | 2023-08-22 | 佛山市顺德区美的洗涤电器制造有限公司 | Special detergent composition for household automatic dish-washing machine |
| CN115386437A (en) * | 2022-08-31 | 2022-11-25 | 中山百科清洁用品制造有限公司 | A special rinse agent for automatic dishwasher and preparation method thereof |
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| CN1354212A (en) * | 2000-11-22 | 2002-06-19 | 上海白猫有限公司 | Special-purpose tableware dryer for dish-washer |
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