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CN105016680A - Fireproof rendering coat mortar and preparation method and application thereof - Google Patents

Fireproof rendering coat mortar and preparation method and application thereof Download PDF

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Publication number
CN105016680A
CN105016680A CN201510400260.2A CN201510400260A CN105016680A CN 105016680 A CN105016680 A CN 105016680A CN 201510400260 A CN201510400260 A CN 201510400260A CN 105016680 A CN105016680 A CN 105016680A
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Prior art keywords
mass parts
fire prevention
finishing mucilage
parts
powder
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CN201510400260.2A
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Chinese (zh)
Inventor
胡岛蜻
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CHONGQING CITY HUTE BUILDING MATERIALS Ltd Co
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CHONGQING CITY HUTE BUILDING MATERIALS Ltd Co
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Priority to CN201510400260.2A priority Critical patent/CN105016680A/en
Publication of CN105016680A publication Critical patent/CN105016680A/en
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Abstract

The invention relates to a fireproof rendering coat mortar and a preparation method and application thereof. The fireproof rendering coat mortar consists of the following components in parts by weight: 280-310 parts of 425R ordinary Portland cement, 540-560 parts of dry sand, 50-100 parts of heavy calcium carbonate, 5-8 parts of micro-silicon powder, 3-6 parts of cellulose hydroxypropyl methyl, 12-15 parts of re-dispersible polymer emulsion powder, 2-5 parts of 7-11 mm polypropylene fiber, 2-3 parts of 7-11 glassfiber, 2-5 parts of wood fiber, 30-36 parts of fireproof powder and 180-210 parts of water. The fireproof rendering coat mortar reaches good synergistic effect through appropriate proportioning of components, is high in bonding strength and high in anti-cracking performance, and has good fire resistance.

Description

A kind of fire prevention finishing mucilage and its preparation method and application
Technical field
The present invention relates to a kind of fire prevention finishing mucilage, belong to coating material for building, particularly the finishing mucilage of external wall insulation protective layer.
Background technology
When the lagging material of outer wall heat preservation system adopts non-combustible material or do not have the flame retardant material of propagating flame, generally there is not fire safety sex chromosome mosaicism in outer wall heat preservation system.But what the use of current China was maximum is the high molecular foam material with high-efficiency insulated heat insulating function, based on polystyrene foamed plastics and hard polyurethane foam.Because high molecular foam material has the danger of initiation fire, the widely used fire resistance of flammable or inflammable organic insulation material to system based on polystyrene foam and hard polyurethane foam of outer wall heat preservation system exerts a decisive influence, and becomes the cause of outer wall heat preservation system fire safety sex chromosome mosaicism.Therefore the fire safety performance of outer wall heat preservation system has become the safety problem riveted the attention from all fields.
Finishing mucilage is the surface being applied in buildings and component surface and base material, plays protection basic unit, has the rubber cement of certain ornamental effect.Finishing mucilage is mainly used in the cracking resistance protective layer in heat-insulation system outside thermal insulation layer, is also referred to as polymkeric substance finishing mucilage.Finishing mucilage has following characteristics: not bearing load; Float coat and stratum basale will have enough cohesive strengths, make it in construction process or do not come off under long-term deadweight and environmental activity, do not ftracture; Float coat mostly is thin layer; Be used for dry environment, big area is exposed in air.Finishing mucilage is required it is not ultimate compression strength, but workability and the cohesive force with base material thereof.Workability requires that it easily smears uniformly smooth thin layer, constructability.Cohesive force requires that it can bond firmly with ground, long-term unlikely cracking or come off, and is in wet environment or is subject to External Force Acting position (as ground and dado etc.), also should have higher water tolerance and intensity.But the finishing mucilage used in the market does not have fire line or fire resistance is not good, there is certain potential safety hazard.
Summary of the invention
In view of this, object of the present invention provides a kind of fire prevention finishing mucilage, and not only cohesive strength is large for this finishing mucilage, cracking resistance ability is strong, and has good flame retardant resistance.
For achieving the above object, the technical solution used in the present invention is as follows:
A kind of fire prevention finishing mucilage, composed of the following components: the 425R ordinary Portland cement of 280-310 mass parts, the oven dry sand of 540-560 mass parts, the water-ground limestone of 50-100 mass parts, the SILICA FUME of 5-8 mass parts, the Vltra tears of 3-6 mass parts, the redispersable latex powder of 12-15 mass parts, the polypropylene fibre of 2-5 mass parts 7-11mm, the glass fibre of 2-3 mass parts 7-11mm, the wood fibre of 2-5 mass parts, the fire prevention powder of 25-36 mass parts, the water of 180-210 mass parts.
Further, described fire prevention finishing mucilage is composed of the following components: the 425R ordinary Portland cement of 300 mass parts, the oven dry sand of 550 mass parts, the water-ground limestone of 75 mass parts, the SILICA FUME of 6 mass parts, the Vltra tears of 5 mass parts, the redispersable latex powder of 13 mass parts, 3 mass parts length are polypropylene fibre, the glass fibre of 2.5 mass parts, the wood fibre of 4 mass parts, the fire prevention powder of 33 mass parts, the water of 200 mass parts of 7-11mm.
Described SILICA FUME is also silicon ash or poly-silicon ash, be iron alloy when smelting duriron and industrial silicon (Pure Silicon Metal), what produce in ore-smelting furnace has beaten the very strong SiO of volatility 2precipitate with air rapid oxidation condensation after discharge with Si gas.In the concrete of cement based, mortar and refractory material casting material, mix appropriate SILICA FUME, can function as follows: significantly improve resistance to compression, anti-folding, impervious, anticorrosion, shock resistance and wear resisting property; Have water conservation, prevent segregation, bleeding, significantly reduce the effect of concrete pumping resistance; In the work-ing life of significant prolongation concrete, particularly under the severe environment such as villiaumite system erosion, sulphate attack, high humidity, the weather resistance of concrete can be made to double even several times; Significantly reduce the ash that lands of jetting cement and mould material, improve single jetting thickness; The necessary composition of High Strength Concrete, the engineer applied of existing C150 concrete; Have effect of about 5 times of cement, in ordinary concrete and Low Cement Castable, application can reduce costs, improve weather resistance; Effectively prevent concrete alkali-aggregate reaction; Improve the compactness of casting type refractory materials, with Al 2o 3and when depositing, more easily generate mullite phase, make its hot strength, shaking property of heat resistanceheat resistant strengthens; There is extremely strong volcano ash effect, during mixed concrete, can with hydrolysis product of cement Ca (OH) 2secondary reaction of hydration occurs, and form gelled product, filling concrete stone structure, improves the microtexture of slurry, improves mechanical property and the weather resistance of hardenite; SILICA FUME is unformed spherical particle, can improve concrete rheological property; The average particle size particle size of SILICA FUME is smaller, has good filling effect, can be filled between cement granules space, improves concrete strength and weather resistance.
Described water-ground limestone, mechanically directly pulverizes natural calcite, Wingdale, chalk, shell etc. and obtains.Because its settling volume (1.1-1.9mL/g) is less than the light calcium carbonate settling volume (2.4-2.8mL/g) chemically produced, be therefore called as water-ground limestone.In formula of the present invention, coarse whiting, as stopping composition, plays a part to reduce production cost, the toughness increasing product and intensity.
Described redispersable latex powder is the powder of the spray-dried rear formation of polymer emulsion, also claims dry powder glue.This powder can be reduced into emulsion rapidly after contact with water, and keeps the character identical with initial latex, and namely after moisture evaporation, this film has high-flexibility, high-weatherability and the high-adhesion to various base material.In formula of the present invention, redispersable latex powder plays following effect: be added in 7-10 days film forming in cement, body of wall and mortar clenched, prevents mortar from ftractureing time uneven in temperature; Adhesive property and the cohesion of material can be improved; Reduce shaping Young's modulus; The elasticity of strongthener and flexural strength; Improve shock-resistance and the weathering resistance of material; Reduce the water-absorbent of material and improve the water-retentivity of use procedure.
Described wood fibre is that natural timber is through chemically treated organic fibre, outward appearance is flocculence, in white or canescence, by screening, division, pyroprocessing, bleaching, chemical treatment, neutralize, be sieved into different lengths and thickness to adapt to the needs of different application material.Wood fibre has good toughness, dispersiveness and chemical stability, and water-retaining capacity is strong, has very excellent thickening resistance to cleavage.
Further, the length of described polypropylene fibre is 9mm.Described polypropylene fibre is the synthon that the isotatic polypropylene obtained with polypropylene polymerization is copied for raw material.Polypropylene fibre has the following advantages: density is 0.90-0.92 g/cm 3, be the lightest in all man-made fiber; Intensity is high, good springiness, wear-resisting, corrosion-resistant; Wear resistance and rebound resilience good, intensity is similar with polyamide fibre to terylene; Chemical proofing is better than general fiber; There is electrical insulating property and heat retention.Polypropylene fibre can be divided into macrofiber, staple fibre, spin glutinous non-woven fabrics, melt spraying non-woven fabrics etc.Be 1.5-200mm as concrete staple length.Polypropylene fibre has splendid dispersiveness and the bond stress with cement matrix in concrete, and resistance to deterioration is good, can ensure to play effect for a long time in concrete.Described glass fibre is a kind of ceramic of excellent performance, and main component is silicon-dioxide, aluminum oxide, calcium oxide, boron oxide, magnesium oxide, sodium oxide etc.Glass fibre has good insulating, thermotolerance is strong, erosion resistance good, physical strength advantages of higher.
Further, described specification of drying sand is 70-140 order.Described oven dry sand can form stronger bonding force with cement slurry, strengthens anti-folding, the ultimate compression strength of slurry, is conducive to the raising of polystyrene granule insulating mortar bulk strength.
Further, the viscosity of described Vltra tears is 200,000 mPas.Described Vltra tears, has another name called hypromellose, HPMC, and English abbreviation is HPMC.Be select the gossypin of high purity as raw material, obtain through special etherificate in the basic conditions.Vltra tears makes mortar have pumping as the water-holding agent of sand-cement slurry, retardant.At slurry of plastering, gypsum material, putty powder or other building materials as tamanori, smear can be improved and extend operable time.As sticking brick, marble, decorative plastic, paste toughener, can also cement consumption be reduced.The water retention property of HPMC makes slurry because of so dry that to chap too soon, can not strengthen the rear intensity of sclerosis after smearing.
Further, described fire prevention powder is inorganic additive flame retardant.Further, the main component of described inorganic additive flame retardant is magnesium hydroxide or aluminium hydroxide.Described fire prevention powder and fire retardant, be the functional aid can giving polymkeric substance flame retardancy, can be divided into additive flame retardant and reactive flame retardant according to using method.Additive flame retardant joins in polymkeric substance by mechanical mix techniques, makes polymkeric substance have flame retardant resistance.Current additive flame retardant mainly contains organic fire-retardant and inorganic combustion inhibitor.Some fire retardants that organic fire-retardant is is representative with bromine system, phosphorus nitrogen system and red phosphorus and compound, inorganic combustion inhibitor is the flame-retardant system such as antimonous oxide, magnesium hydroxide, aluminium hydroxide, silicon system mainly.
The preparation of described fire prevention finishing mucilage comprises the following steps: weigh by raw material ratio, is then inserted by starting material in feed bin and carries out mixing and fully stirring, fire prevention finishing mucilage.
The present invention also aims to provide the application of described fire prevention finishing mucilage in fire protection coating, this fire prevention finishing mucilage is used for external wall insulation.Not only cohesive strength is large for this this finishing mucilage of fire prevention finishing mucilage, cracking resistance ability is strong, and has good flame retardant resistance.
Advantageous Effects of the present invention is:
Fire prevention finishing mucilage of the present invention, reaches good synergy by the proportioning that each component is suitable, and the aspects such as ultimate compression strength, cohesive strength, Young's modulus, shrinking percentage are functional, and cohesive strength is large, and cracking resistance ability is strong, also has good flame retardant resistance simultaneously.
Embodiment
In order to make the object, technical solutions and advantages of the present invention clearly, below embodiments of the invention are described in detail.
embodiment 1
A kind of fire prevention finishing mucilage, composed of the following components: the 425R ordinary Portland cement of 280 mass parts, the oven dry sand of 560 mass parts, the water-ground limestone of 50 mass parts, the SILICA FUME of 5 mass parts, the Vltra tears of 6 mass parts, the redispersable latex powder of 15 mass parts, 2 mass parts length are polypropylene fibre, 2 mass parts 7-11mm glass fibre, the wood fibre of 2 mass parts, the fire prevention powder of 25 mass parts, the water of 180 mass parts of 7mm.
Described fire prevention finishing mucilage is concrete preparation method comprise the following steps: weigh by raw material ratio, then inserted by starting material in feed bin and carries out mixing and fully stirring, fire prevention finishing mucilage.
embodiment 2
A kind of fire prevention finishing mucilage, composed of the following components: the 425R ordinary Portland cement of 310 mass parts, the oven dry sand of 540 mass parts, the water-ground limestone of 100 mass parts, the SILICA FUME of 8 mass parts, the Vltra tears of 3 mass parts, the redispersable latex powder of 12 mass parts, 5 mass parts length are polypropylene fibre, the glass fibre of 3 mass parts 11mm, the wood fibre of 5 mass parts, the fire prevention powder of 36 mass parts, the water of 210 mass parts of 11mm.
Concrete preparation method is identical with embodiment 1 for described fire prevention finishing mucilage.
embodiment 3
A kind of fire prevention finishing mucilage, composed of the following components: the 425R ordinary Portland cement of 300 mass parts, the oven dry sand of 550 mass parts, the water-ground limestone of 75 mass parts, the SILICA FUME of 6 mass parts, the Vltra tears of 5 mass parts, the redispersable latex powder of 13 mass parts, 3 mass parts length are polypropylene fibre, the glass fibre of 2.5 mass parts 9mm, the wood fibre of 4 mass parts, the fire prevention powder of 33 mass parts, the water of 200 mass parts of 9mm.
Concrete preparation method is identical with embodiment 1 for described fire prevention finishing mucilage.
embodiment 4
The alkylphenol polyoxyethylene emulsifying agent of the pH adjusting agent of the benzene emulsion of 10 mass parts, 0.5 mass parts, 0.05 mass parts, the ether of cellulose of 1.00 mass parts are fully mixed and stir, finishing mucilage.
embodiment 5
The water-resisting agent of the anti-sag agent of the dispersion agent of the hardening accelerator of the water-holding agent of the flyash of the dry sand of the silicate cement of 20 mass parts, 38 mass parts, 30 mass parts, 0.4 mass parts, 0.5 mass parts, 1.0 mass parts, 0.1 mass parts, 0.5 mass parts, the water of 38 mass parts are stirred, finishing mucilage.
embodiment 6the performance test of fire prevention finishing mucilage
The fire prevention finishing mucilage that embodiment 1-3 is obtained and embodiment 4(control group 1) and the finishing mucilage that obtains of embodiment 5 (control group 2) carry out performance test, test result is as shown in the table:
Note: in upper table, ultimate compression strength, cohesive strength, Young's modulus, shrinking percentage are according to People's Republic of China's chemical industry standard " building mortar fundamental property experimental technique JGJ70-2009 " test, and total fuel value, burning net thermal value are tested according to " material of construction combustion heat value test method GBT14402-2007 ".
Above-mentioned ultimate compression strength, cohesive strength, Young's modulus, shrinking percentage are the ultimate compression strength of finishing mucilage, the index parameter of resistance to cleavage of evaluating preparation.From above-mentioned test result, fire prevention finishing mucilage ultimate compression strength prepared by the present invention, Young's modulus, the forthright index of contraction and control group are approximate, and cohesive strength is better than control group.Prove thus, fire prevention finishing mucilage cohesive strength of the present invention is large, has good cracking resistance.Gross heat of combustion value, the burning net thermal value index of fire prevention finishing mucilage prepared by the present invention are significantly less than control group 1(embodiment 4) and control group 2(embodiment 5), i.e. the flame retardant resistance performance of the fire prevention finishing mucilage of the present invention's acquisition is obviously better than control group.Prove thus, fire prevention finishing mucilage of the present invention has good flame retardant resistance.
In order to verify that the flame retardant resistance of finishing mucilage is glued in obtained fire prevention more intuitively, to the fire prevention finishing mucilage that embodiment 1-3 obtains, and the finishing mucilage (being respectively control group 1 and control group 2) that embodiment 4 and 5 obtains carries out performance test.During test, in order to accelerate experiment process and speed, spread upon on warming plate by the finishing mucilage of acquisition, warming plate is placed after 5 days and is carried out flame retardant resistance test.During test, by finishing mucilage layer and flame contact, temperature is 750 DEG C, and the test duration is 25s.Observe with or without burning, melting or dropping etc., test result is as follows:
From test result, the flame retardant resistance performance of fire prevention finishing mucilage of the present invention is obviously better than embodiment 4(control group 1) and 5(control group 2) finishing mucilage that obtains.Prove, while the finishing mucilage that the present invention obtains has good splitting resistance, to there is good flame retardant resistance thus.
What finally illustrate is, above embodiment is only in order to illustrate technical scheme of the present invention and unrestricted, those of ordinary skill in the art is to be understood that, can modify to technical scheme or equivalent replacement, and not departing from aim and the scope of technical solution of the present invention, it all should be encompassed in the middle of right of the present invention.

Claims (9)

1. a fire prevention finishing mucilage, is made up of the component of following mass parts: the 425R ordinary Portland cement of 280-310 mass parts, the oven dry sand of 540-560 mass parts, the water-ground limestone of 50-100 mass parts, the SILICA FUME of 5-8 mass parts, the Vltra tears of 3-6 mass parts, the redispersable latex powder of 12-15 mass parts, the polypropylene fibre of 2-5 mass parts 7-11mm, the glass fibre of 2-3 mass parts 7-11mm, the wood fibre of 2-5 mass parts, the fire prevention powder of 30-36 mass parts, the water of 180-210 mass parts.
2. fire prevention finishing mucilage according to claim 1, is characterized in that: be made up of the component of following weight part: the 425R ordinary Portland cement of 300 mass parts, the oven dry sand of 550 mass parts, the water-ground limestone of 75 mass parts, the SILICA FUME of 6 mass parts, the Vltra tears of 5 mass parts, the redispersable latex powder of 13 mass parts, 3 mass parts length are polypropylene fibre, the glass fibre of 2.5 mass distribution, the wood fibre of 4 mass parts, the fire prevention powder of 33 mass parts, the water of 200 mass parts of 7-11mm.
3. fire prevention finishing mucilage according to claim 1 and 2, is characterized in that: the length of described polypropylene fibre or glass fibre is 9mm.
4. fire prevention finishing mucilage according to claim 1, is characterized in that: described specification of drying sand is 70-140 order.
5. fire prevention finishing mucilage according to claim 1, is characterized in that: the viscosity of described Vltra tears is 200,000 mPas.
6. fire prevention finishing mucilage according to claim 1, is characterized in that: described fire prevention powder is inorganic additive flame retardant.
7. fire prevention finishing mucilage according to claim 6, is characterized in that: the main component of described inorganic additive flame retardant is magnesium hydroxide or aluminium hydroxide.
8. prepare the method for finishing mucilage of preventing fires as defined in claim 1, it is characterized in that: the preparation of described fire prevention finishing mucilage comprises the following steps: weigh by raw material ratio, then starting material are inserted in feed bin and carry out mixing and fully stirring, fire prevention finishing mucilage.
9. the application of fire prevention finishing mucilage in warming plate as described in any one of claim 1 to 7.
CN201510400260.2A 2015-07-08 2015-07-08 Fireproof rendering coat mortar and preparation method and application thereof Pending CN105016680A (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107352909A (en) * 2017-08-02 2017-11-17 上海永丽节能材料有限公司 Celular glass insulating system special plastering rubber cement and preparation method thereof and application method
CN109265106A (en) * 2018-10-24 2019-01-25 山东创伟外墙保温材料集团有限公司 A kind of compound homogeneous construction insulation board
JP2021160956A (en) * 2020-03-31 2021-10-11 太平洋マテリアル株式会社 Polymer cement mortar composition and polymer cement mortar

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107352909A (en) * 2017-08-02 2017-11-17 上海永丽节能材料有限公司 Celular glass insulating system special plastering rubber cement and preparation method thereof and application method
CN107352909B (en) * 2017-08-02 2020-09-11 上海永丽节能材料有限公司 Special finishing mortar for foam glass heat insulation system and preparation method and use method thereof
CN109265106A (en) * 2018-10-24 2019-01-25 山东创伟外墙保温材料集团有限公司 A kind of compound homogeneous construction insulation board
JP2021160956A (en) * 2020-03-31 2021-10-11 太平洋マテリアル株式会社 Polymer cement mortar composition and polymer cement mortar
JP7461776B2 (en) 2020-03-31 2024-04-04 太平洋マテリアル株式会社 Polymer cement mortar composition and polymer cement mortar

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Application publication date: 20151104