CN104695277A - Decorative plate finishing paper and production method thereof - Google Patents
Decorative plate finishing paper and production method thereof Download PDFInfo
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Abstract
本发明目的是用一种新型装饰板材饰面纸替代木皮及科技木用于人造板贴面,基纸为150—350g/m2,上层仿真印刷日渐稀少的天然珍贵的树种,还可以创造印刷其它艺术图案,压贴后效果逼真。本发明中的装饰板材饰面基纸添加化纤,主要目的为增加纸张强度,使纸张柔软而有韧性。本发明产品主要用于纤维板、刨花板等人造板贴面,可替代木皮、科技木等贴面材料,本发明的饰面纸还可以涂有阻燃胶液,具备阻燃特性。The purpose of this invention is to use a new type of decorative panel facing paper to replace veneer and technical wood for wood-based panel veneer. The base paper is 150-350g/m 2 . Other artistic patterns, the effect is realistic after pressing. The main purpose of adding chemical fiber to the decorative base paper of the decorative board in the present invention is to increase the strength of the paper and make the paper soft and tough. The product of the invention is mainly used for veneering wood-based panels such as fiberboards and particle boards, and can replace veneer materials such as veneer and technical wood. The veneer paper of the invention can also be coated with flame-retardant glue, which has flame-retardant properties.
Description
技术领域 technical field
本发明属于人造板贴面用特种纸技术领域,具体涉及一种新型装饰板材饰面纸及其生产方法。 The invention belongs to the technical field of special paper for veneering wood-based panels, and in particular relates to a novel decorative panel veneer paper and a production method thereof.
背景技术 Background technique
国内传统的人造板装饰板材饰面材料有薄木、科技木、浸渍装饰原纸、聚烯羟(奥克赛)薄膜等,薄木又称木皮,是一种具有珍贵树种特色的木质片状薄型饰面或贴面材料,用于家具贴面的木皮品种常见的有水曲柳、柞木、楸木、榆木、西南桦,较为珍贵的有樱桃木、黑胡桃木、红橡木以及更为高档的诸如白影木、柚木、酸枝木、花梨木、紫檀木等。科技木也叫人造薄木,由一般树种的旋切单板仿照天然木材或珍贵树种的色调染色后再按纤维方向胶合成木方后制成的刨切薄木。浸渍装饰原纸是一种以木浆和钛白粉为主要原料经特殊工艺加工而成的工业特种用纸,经印刷、三聚氰胺树脂浸胶后用于纤维板、刨花板等人造板的护面层纸、面层用纸和底层用纸。聚烯羟(奥克赛)薄膜为塑料类装饰基材。上述装饰板材饰面材料薄木和科技木需要使用大量木材,科技木、浸渍装饰原纸在生产过程中需要使用大量三聚氰胺甲醛树脂、胶粘剂及添加剂、着色剂(包括染料和颜料)等。聚烯羟(奥克赛)薄膜属于塑料,无法自然降解。 Domestic traditional wood-based panel decorative panel materials include veneer, technical wood, impregnated decorative base paper, polyolefin (Oxy) film, etc. veneer, also known as veneer, is a thin wood veneer with the characteristics of precious tree species. Or veneer materials, the common species of veneer used for furniture veneer are ash, oak, catalpa, elm, southwest birch, more precious cherry wood, black walnut, red oak and more high-end such as White shadow wood, teak, rosewood, rosewood, rosewood, etc. Technological wood is also called artificial veneer. It is a sliced veneer made of rotary-cut veneer of general tree species imitating the color tone of natural wood or precious tree species, and then glued into wood according to the fiber direction. Impregnated decorative base paper is a kind of industrial special paper made of wood pulp and titanium dioxide as the main raw materials through special process. Layer paper and bottom paper. Polyolefin (Oxy) film is a plastic decorative substrate. The veneer wood and technical wood for the above-mentioned decorative panels need to use a large amount of wood, and the production process of technical wood and impregnated decorative base paper requires a large amount of melamine-formaldehyde resin, adhesives and additives, colorants (including dyes and pigments), etc. Polyolefin (Oxy) film is plastic and cannot be degraded naturally.
发明内容 Contents of the invention
本发明目的是用一种新型装饰板材饰面纸替代木皮及科技木用于人造板贴面,克重为(150—350)g/m2,可在上层加贴印刷好花纹的装饰纸再压贴,也可在表层直接仿真印刷日渐稀少的天然珍贵的树种,还可以创造印刷其它艺术图案,压贴后效果逼真。 The purpose of this invention is to use a new type of decorative board veneer paper to replace veneer and technical wood for wood-based panel veneer . Pressing and pasting can also directly simulate and print increasingly rare natural and precious tree species on the surface, and can also create and print other artistic patterns, and the effect after pressing and pasting is realistic.
本发明中的装饰板材饰面纸添加化纤,主要目的为增加纸张强度,使纸张柔软而有韧性。 The main purpose of adding chemical fibers to the decorative board decorative paper in the present invention is to increase the strength of the paper and make the paper soft and tough.
本发明产品与印刷装饰纸复合后使用或直接印刷后压贴使用,主要用于纤维板、刨花板等人造板贴面,可替代木皮、科技木等贴面材料,本发明的饰面纸还可以涂有阻燃胶液,具备阻燃特性。 The product of the present invention is used after compounding with printed decorative paper or directly printed and pasted. It is mainly used for veneering wood-based panels such as fiberboard and particle board, and can replace veneer, technical wood and other veneer materials. The decorative paper of the present invention can also be coated with There are flame retardant glue, with flame retardant properties.
本发明要求保护一种装饰板材饰面纸,其特征在于,所述的装饰板材饰面纸由下述重量百分比的原料生产: The present invention claims to protect a decorative board facing paper, which is characterized in that the decorative board facing paper is produced from the following raw materials in weight percentage:
木浆 65%—90% Wood pulp 65%—90%
化纤 5%—25% Chemical fiber 5%—25%
助剂 5%—10% Additives 5%—10%
所述装饰板材饰面纸在纸机干燥部增加涂布工艺和浸浸工艺,其中所用涂布胶液和浸渍胶液固总质量占所述基纸的成纸重量比例分别为: The decorative board decorative paper adds a coating process and an impregnation process in the drying section of the paper machine, wherein the total mass of the coating glue and impregnating glue to the paper weight ratio of the base paper is respectively:
涂布胶液 5%—15% Coating glue 5%—15%
浸渍胶液 10%—15% 。 Impregnated glue 10%-15%.
前述的装饰板材饰面纸,其中: The aforementioned decorative sheet facing paper, wherein:
木浆为长纤维针叶木浆和短纤维阔叶木浆,两者重量百分比例为长纤维针叶木浆30%—60%,短纤维阔叶木浆40%—70%; The wood pulp is long-fiber coniferous wood pulp and short-fiber hardwood pulp, and the percentage by weight of the two is 30%-60% of long-fiber softwood pulp and 40%-70% of short-fiber hardwood pulp;
所述化纤为涤纶、锦纶、腈纶、氯纶、维纶中的一种或多种,细度为1-10D,长度为5-20mm; The chemical fiber is one or more of polyester, nylon, acrylic, polyvinyl chloride, and vinylon, with a fineness of 1-10D and a length of 5-20mm;
所述的助剂重量百分占比为:聚丙烯酰胺1%—4%,聚酰胺环氧氯丙烷4%—6%; The percentage by weight of the additives is: polyacrylamide 1%-4%, polyamide epichlorohydrin 4%-6%;
所述涂布胶液中,各成分按占绝干重量份比例计为:钛白粉5%—10%,钙粉10%—25%,聚乙烯醇15%—30%,分散剂3%,抗水剂2%,胶乳30%—65%; In the coating glue, each component is calculated as follows in terms of absolute dry weight: 5%-10% of titanium dioxide, 10%-25% of calcium powder, 15%-30% of polyvinyl alcohol, 3% of dispersant, 2% anti-water agent, 30%-65% latex;
所述浸渍胶液中,各成分按占重量份比例计为: 三聚氰胺改性脲醛胶25%—40%,改性甘油1%,改性淀粉5%,聚乙烯醇5%,渗透剂JF-C2%, 聚丁二烯树脂57%—62%; In the impregnating glue, each component is calculated by weight ratio: 25%-40% of melamine modified urea-formaldehyde glue, 1% of modified glycerin, 5% of modified starch, 5% of polyvinyl alcohol, penetrant JF- C2%, polybutadiene resin 57%-62%;
所述新型装饰板材饰面基纸的成纸指标如下:定量150—350g/m2,厚度0.8—2.5mm,抗张强度大于5kn/m, 撕裂度纵向大于3500mn,横向大于4000mn,耐破度大于500kpa; The paper-forming index of the new-type decorative board veneer base paper is as follows: basis weight 150-350g/ m2 , thickness 0.8-2.5mm, tensile strength greater than 5kn/m, tearing degree greater than 3500mn in the longitudinal direction and greater than 4000mn in the transverse direction. The degree is greater than 500kpa;
所述基纸还需涂布改性阻燃液,改性阻燃液为将阻燃剂和改性剂加入丙烯酸胶乳中搅拌均匀而制得。 The base paper also needs to be coated with a modified flame retardant solution, which is prepared by adding a flame retardant and a modifier into acrylic latex and stirring evenly.
前述装饰板材饰面纸的制作方法,其特征在于,包括如下步骤: The preparation method of the aforesaid decorative plate facing paper is characterized in that it comprises the following steps:
A、将化纤放入高速水力搅拌器中进行分散,其步骤为先将化纤、浓度为15%的氢氧化钠溶液按重量比1:1.5比例浸泡20分钟,然后滤去水分,放入清水,化纤和清水重量比为1:200,搅拌时间为20分钟; A. Put the chemical fiber in a high-speed hydraulic mixer for dispersion. The steps are to first soak the chemical fiber and 15% sodium hydroxide solution at a weight ratio of 1:1.5 for 20 minutes, then filter out the water, and put it in clean water. The weight ratio of chemical fiber and clear water is 1:200, and the stirring time is 20 minutes;
B、将长纤维木浆、短纤维木浆按比例在水力碎浆机中碎解,浓度为4%—6%,碎解30分钟后加入分散后的化纤,然后再搅拌20-30分钟; B. Disintegrate the long-fiber wood pulp and short-fiber wood pulp in a hydraulic pulper in proportion to a concentration of 4%-6%, add the dispersed chemical fiber after 30 minutes of disintegration, and then stir for 20-30 minutes;
C、木浆、化纤按下述重量比加入,并在加填池中加入下述重量比的助剂,混合后抽入抄前池加水将浓度调到0.8%—1.2%; C. Add wood pulp and chemical fiber according to the following weight ratio, and add the following additives in the filling tank, pump it into the forebay tank after mixing, add water to adjust the concentration to 0.8%-1.2%;
木浆 65%—90% Wood pulp 65%—90%
化纤 5%—25% Chemical fiber 5%—25%
助剂 5%—10% Auxiliary 5%—10%
D、为使化纤在上浆过程中分散均匀,使用特制的大压力布浆器通过多条柔性塑料软管布浆方式向流浆箱输浆,这种布浆方式消除了设备脉冲振荡,浆料通过分流的方式在流浆箱中形成多支对称流,使浆料在纵横幅方向上的浆流保持一致; D. In order to make the chemical fiber disperse evenly during the sizing process, use a special high-pressure slurry distributor to deliver slurry to the headbox through multiple flexible plastic hoses. This slurry distribution method eliminates the pulse oscillation of the equipment and the slurry Multiple symmetrical flows are formed in the headbox by means of flow diversion, so that the slurry flow in the vertical and horizontal direction of the slurry is consistent;
E、采用长网纸机抄造; E. Using fourdrinier paper machine to make paper;
F、经过成型网滤水,压榨,第一干燥区烘缸干燥后,进行机内涂布,涂布量为5%—15%; F. Filter the water through the forming net, squeeze, and dry in the first drying zone, then carry out in-machine coating, and the coating amount is 5%-15%;
G、第二干燥区烘箱干燥后,进行软压光,然后进行机内浸渍,浸渍量为10%—15%; G. After drying in the oven in the second drying zone, perform soft calendering, and then impregnate in the machine, and the impregnation amount is 10%-15%;
H、进入第三干燥区烘箱干燥后制作符合要求的新型装饰板材饰面纸。 H. After entering the third drying zone and drying in the oven, make a new type of decorative board facing paper that meets the requirements.
前述的装饰板材饰面纸的制作方法,其特征在于也可以是包括如下步骤: The method for making the aforesaid decorative board facing paper is characterized in that it may also comprise the following steps:
A、将化纤放入高速水力搅拌器中进行分散,其步骤为先将化纤、浓度为15%的氢氧化钠溶液按重量比1:1.5比例浸泡20分钟,然后滤去水分,放入清水,化纤和清水重量比为1:200,搅拌时间为20分钟; A. Put the chemical fiber in a high-speed hydraulic mixer for dispersion. The steps are to first soak the chemical fiber and 15% sodium hydroxide solution at a weight ratio of 1:1.5 for 20 minutes, then filter out the water, and put it in clean water. The weight ratio of chemical fiber and clear water is 1:200, and the stirring time is 20 minutes;
B、将长纤维木浆、短纤维木浆按比例在水力碎浆机中碎解,浓度为4%—6%,碎解30分钟后加入分散后的化纤,然后再搅拌20-30分钟; B. Disintegrate the long-fiber wood pulp and short-fiber wood pulp in a hydraulic pulper in proportion to a concentration of 4%-6%, add the dispersed chemical fiber after 30 minutes of disintegration, and then stir for 20-30 minutes;
C、木浆、化纤按下述重量比加入,并在加填池中加入下述重量比的助剂,混合后抽入抄前池加水将浓度调到0.8%—1.2%; C. Add wood pulp and chemical fiber according to the following weight ratio, and add the following additives in the filling tank, pump it into the forebay tank after mixing, add water to adjust the concentration to 0.8%-1.2%;
木浆 65%—90% Wood pulp 65%—90%
化纤 5%—25% Chemical fiber 5%—25%
助剂 5%—10% Auxiliary 5%—10%
D、为使化纤在上浆过程中分散均匀,使用特制的大压力布浆器通过多条柔性塑料软管布浆方式向流浆箱输浆,这种布浆方式消除了设备脉冲振荡,浆料通过分流的方式在流浆箱中形成多支对称流,使浆料在纵横幅方向上的浆流保持一致; D. In order to make the chemical fiber disperse evenly during the sizing process, use a special high-pressure slurry distributor to deliver slurry to the headbox through multiple flexible plastic hoses. This slurry distribution method eliminates the pulse oscillation of the equipment and the slurry Multiple symmetrical flows are formed in the headbox by means of flow diversion, so that the slurry flow in the vertical and horizontal direction of the slurry is consistent;
E、采用长网纸机抄造; E. Using fourdrinier paper machine to make paper;
F、经过成型网滤水,压榨,第一干燥区干燥后,进行机内涂布,涂布量为5%—15%; F. Filter the water through the forming net, squeeze, and dry in the first drying zone, then coat in the machine, and the coating amount is 5%-15%;
G、第二干燥区干燥后,进行机内浸渍,浸渍量为10%—15%; G. After drying in the second drying zone, carry out impregnation in the machine, and the impregnation amount is 10%-15%;
H、将阻燃剂和改性剂按质量比混合搅拌均匀获得改性阻燃液,将改性阻燃液与丙烯酸胶乳一起搅拌均匀,获得阻燃施胶液; H. Mix and stir the flame retardant and modifier according to the mass ratio to obtain a modified flame retardant liquid, and stir the modified flame retardant liquid and acrylic latex evenly to obtain a flame retardant sizing liquid;
I、步骤G基纸第二干燥后的半成品在施胶涂布机上浸渍施胶液,浸渍温度10-25℃; I. The semi-finished product after the second drying of the base paper in step G is impregnated with a sizing solution on a sizing coater, and the immersion temperature is 10-25° C.;
J、然后在120~180℃下通过热风循环系统对基纸半成品中渗透的施胶液干燥胶化; J. Then dry and gel the sizing solution permeated into the base paper semi-finished product through the hot air circulation system at 120~180°C;
H、进入第三干燥区干燥后制作符合要求的新型装饰板材饰面纸。第一干燥区为烘缸,第二第三干燥区为热风循环烘箱干燥。 H. After entering the third drying zone to dry, make a new type of decorative board facing paper that meets the requirements. The first drying zone is a drying cylinder, and the second and third drying zones are drying in a hot air circulation oven.
本发明在F步骤采用的机内涂布,以及步骤I中在施胶涂布机上操作,还可以采用全自动控制的辊涂方式,配置有电控系统控制辊涂过程,向其输入原纸厚度的参数,以及辊涂时的下压力大小,以控制附加涂层的最终厚度在0.01-0.1mm之间; The present invention adopts in-machine coating in F step, and operates on the sizing coater in step I, can also adopt the roll coating mode of automatic control, is equipped with electronic control system to control the roll coating process, and input base paper thickness to it Parameters, as well as the size of the downforce during roller coating, to control the final thickness of the additional coating between 0.01-0.1mm;
所述辊涂也可以针对基纸半成品上下表面分别辊涂,其可以分别上下设置有两个涂辊,启动辊涂机,将上下涂辊间隙调节至比半成品材料厚度小1-3mm,利用涂辊 作用使得半成品材料随辊涂方向前进,并在前进过程中将涂辊中的阻燃施胶液均匀辊涂在半成品表面上; The roller coating can also be roller-coated on the upper and lower surfaces of the base paper semi-finished product, which can be respectively provided with two coating rollers up and down, start the roller coating machine, adjust the gap between the upper and lower coating rollers to be 1-3mm smaller than the thickness of the semi-finished material, and use the coating The action of the roller makes the semi-finished material advance with the direction of roller coating, and evenly rolls the flame-retardant sizing solution in the coating roller on the surface of the semi-finished product during the advancing process;
所述的阻燃剂可以是磷系阻燃剂、氮系阻燃剂或磷-氮系阻燃剂,具体可以为三羟甲基氧化磷(THPO)或二苯基磷酸酯(BDP); The flame retardant may be a phosphorus-based flame retardant, a nitrogen-based flame retardant or a phosphorus-nitrogen-based flame retardant, specifically trihydroxymethylphosphine oxide (THPO) or diphenyl phosphate (BDP);
所述的改性剂可以为二甲基氧化锡或/和二丁基二氯化锡; Described modifying agent can be dimethyl tin oxide or/and dibutyl tin dichloride;
阻燃剂还可以使用双酚A-双(二苯基磷酸酯)即BDP是一种环保型非卤有机磷系阻燃剂,适用于热塑性材料,特别适用于PC/ABS共混物的阻燃改性。 Flame retardants can also use bisphenol A-bis (diphenyl phosphate), that is, BDP is an environmentally friendly non-halogenated organophosphorus flame retardant, suitable for thermoplastic materials, especially for PC/ABS blends. combustion modification.
三羟甲基氧化磷(THPO)和二苯基磷酸酯(BDP)与改性剂二甲基氧化锡、二丁基二氯化锡改性后可具有稳定、优异的阻燃性能。本发明将阻燃剂和改性剂混合搅拌均匀获得改性阻燃液,将改性阻燃液立即加入丙烯酸胶乳中搅拌均匀获得施胶液。改性剂的使用使阻燃剂稳定保持在较高的活性。胶乳对改性阻燃液起到包裹的作用,保持改性阻燃液的活性渗透进壁纸基纸的纤维孔隙中。与现有的价格高昂的阻燃胶乳和阻燃化学纤维相比,本发明中所用的阻燃剂和改性剂价格低廉,与不阻燃化学纤维搭配即可达到难燃效果。采用本发明的方法,可将阻燃饰面纸基纸的成本。 Trihydroxymethyl phosphine oxide (THPO) and diphenyl phosphate (BDP) modified with modifiers dimethyl tin oxide and dibutyl tin dichloride can have stable and excellent flame retardant properties. In the invention, the flame retardant and the modifying agent are mixed and stirred evenly to obtain a modified flame retardant liquid, and the modified flame retardant liquid is immediately added to the acrylic latex and stirred evenly to obtain a sizing liquid. The use of modifiers keeps the flame retardants stable at higher activity. The latex plays a role of wrapping the modified flame retardant liquid, keeping the activity of the modified flame retardant liquid and penetrating into the fiber pores of the wallpaper base paper. Compared with the existing high-priced flame-retardant latex and flame-retardant chemical fibers, the flame-retardants and modifiers used in the present invention are cheap, and can achieve flame-retardant effects when matched with non-flame-resistant chemical fibers. By adopting the method of the invention, the cost of the base paper for the flame-retardant facing paper can be reduced.
与现有技术比本发明所具有的有益效果是: Compared with prior art, the beneficial effect that the present invention has is:
1、本发明在浆料中加入了化纤,使纸张具有了木皮的厚度、柔软度,强度加大,有利于后续制作。 1. In the present invention, chemical fiber is added to the slurry, so that the paper has the thickness and softness of veneer, and the strength is increased, which is beneficial to subsequent production.
2、由于纸张的平整特性,省去了木皮及科技木生产过程中的大部分工序,如木皮拼接、修整,不但节省了大量的木材而且节约了人力成本。 2. Due to the flatness of paper, most of the processes in the production process of veneer and technical wood are omitted, such as veneer splicing and trimming, which not only saves a lot of wood but also saves labor costs.
3、由于木皮加工大多是家庭作坊式生产,加工过程中的漂洗、印染、胶粘等环节产生了大量的污染,而本发明是以纸代木,大型现代化纸机生产,污染集中处理。 3. Since veneer processing is mostly family workshop production, links such as rinsing, printing and dyeing, and gluing in the processing process produce a large amount of pollution, and the present invention is to replace wood with paper, large-scale modern paper machine production, pollution centralized treatment.
4、本发明采用机内涂布、机内浸渍工艺生产,钛白粉涂于纸张表面,相比于加填在纸浆中节省钛白粉,印刷效果好,印刷上木纹浸胶后通过热压设备压贴在纤维板、刨花板、密度板等人造板上,可以达到木皮及科技木贴面板的效果。 4. The present invention is produced by in-machine coating and in-machine impregnation processes. Titanium dioxide is coated on the surface of paper, which saves titanium dioxide compared to filling in pulp, and the printing effect is good. After printing wood grain and dipping, it passes through hot pressing equipment Pressing and pasting on wood-based boards such as fiberboard, particle board, and density board can achieve the effect of veneer and technical wood veneer.
本发明通过采用以上的生产方法,达到了替代木皮的效果,通过印刷木纹装饰,可大量减少名贵木材的砍伐,保护了名贵树种,节约了木材,而且价格相对较低,对实现资源节约、环境保护具有重要的现实意义,可大大促进下游人造板生产行业的快速发展。 The present invention achieves the effect of replacing wood veneer by adopting the above production method. By printing wood grain decoration, the felling of precious wood can be greatly reduced, the precious tree species are protected, wood is saved, and the price is relatively low. Environmental protection has important practical significance and can greatly promote the rapid development of the downstream wood-based panel production industry.
具体实施方式: Detailed ways:
实施例1、 Embodiment 1,
纤维配比:木浆共80%重量百分比,长纤维针叶木浆32%,短纤维阔叶木浆48%,功能纤维为涤纶占15%,纤维细度为2D,长度为5mm,加入助剂5%,其中聚丙烯酰胺 1%,聚酰胺环氧氯丙烷 4%。 Fiber ratio: 80% by weight of wood pulp, 32% of long-fiber coniferous wood pulp, 48% of short-fiber hardwood pulp, 15% of functional fiber polyester, fiber fineness of 2D, length of 5mm, and additive 5 %, of which polyacrylamide 1%, polyamide epichlorohydrin 4%.
机内涂布:涂布液浓度6%,聚乙烯醇20%,分散剂3%,抗水剂2%,钛白粉5%,钙粉10%,胶乳60%。涂布所用量占前述三种主要原料的总重5%。 In-machine coating: coating liquid concentration 6%, polyvinyl alcohol 20%, dispersant 3%, water repellant 2%, titanium dioxide 5%, calcium powder 10%, latex 60%. The amount used for coating accounts for 5% of the total weight of the aforementioned three main raw materials.
机内浸渍:浸渍配方,三聚氰胺改性脲醛胶30%,改性甘油1%,改性淀粉5%,聚乙烯醇5%,渗透剂JF-C2%, 聚丁二烯树脂57%。浸渍量10%。 In-machine impregnation: impregnation formula, melamine modified urea-formaldehyde glue 30%, modified glycerin 1%, modified starch 5%, polyvinyl alcohol 5%, penetrant JF-C 2%, polybutadiene resin 57%. The impregnation amount is 10%.
成纸定量150g/m2,厚度0.9mm,抗张强度5.2kn/m, 撕裂度纵向3800mn,横向4600mn,耐破度520kpa。 The basis weight of the finished paper is 150g/m 2 , the thickness is 0.9mm, the tensile strength is 5.2kn/m, the tearing degree is 3800mn in longitudinal direction, 4600mn in transverse direction, and the bursting strength is 520kpa.
所述基纸还需涂布改性阻燃液,改性阻燃液为将阻燃剂和改性剂加入丙烯酸胶乳中搅拌均匀而制得。所述阻燃剂为具体可以为三羟甲基氧化磷(THPO)。 The base paper also needs to be coated with a modified flame retardant solution, which is prepared by adding a flame retardant and a modifier into acrylic latex and stirring evenly. The flame retardant may specifically be trihydroxymethyl phosphorus oxide (THPO).
制作方法,其特征在于,包括如下步骤: The production method is characterized in that it comprises the steps of:
步骤B中,浓度为4%,再搅拌为20分钟; In step B, the concentration is 4%, and then stirred for 20 minutes;
步骤C中,将浓度调到0.8%; In step C, adjust the concentration to 0.8%;
步骤F中、涂布量为5%; In step F, the coating amount is 5%;
步骤G中、浸渍量为10%; In step G, the impregnation amount is 10%;
步骤J中、在130℃下通过热风循环。 In step J, circulate hot air at 130°C.
实施例2、 Embodiment 2,
纤维配比:木浆共78%重量百分比,长纤维针叶木浆38%,短纤维阔叶木浆40%,涤纶7%,锦纶9%,两种纤维细度均为5D,长度为10mm,加入助剂固含量为6%,其中聚丙烯酰胺 2%,聚酰胺环氧氯丙烷 4%。 Fiber ratio: 78% by weight of wood pulp, 38% of long-fiber softwood pulp, 40% of short-fiber hardwood pulp, 7% of polyester, and 9% of nylon. The fineness of the two fibers is 5D, and the length is 10mm. Add The solid content of additives is 6%, including 2% polyacrylamide and 4% polyamide epichlorohydrin.
机内涂布:涂布液浓度10%,聚乙烯醇25%,分散剂3%,抗水剂2%,钛白粉10%,钙粉20%,胶乳40%。涂布所用量占前述三种主要原料的总重8%。 In-machine coating: coating liquid concentration 10%, polyvinyl alcohol 25%, dispersant 3%, water repellant 2%, titanium dioxide 10%, calcium powder 20%, latex 40%. The amount used for coating accounts for 8% of the total weight of the aforementioned three main raw materials.
机内浸渍:浸渍配方,三聚氰胺改性脲醛胶25%,改性甘油1%,改性淀粉5%,聚乙烯醇5%,渗透剂JF-C2%, 聚丁二烯树脂62%。浸渍量8%。 In-machine impregnation: impregnation formula, melamine modified urea-formaldehyde glue 25%, modified glycerin 1%, modified starch 5%, polyvinyl alcohol 5%, penetrant JF-C 2%, polybutadiene resin 62%. The impregnation amount is 8%.
成纸定量320g/m2,厚度2.4mm,抗张强度6.5kn/m, 撕裂度纵向5200mn,横向5700mn,耐破度530kpa。 The basis weight of the finished paper is 320g/m 2 , the thickness is 2.4mm, the tensile strength is 6.5kn/m, the tearing degree is 5200mn in the longitudinal direction, 5700mn in the transverse direction, and the bursting strength is 530kpa.
所述基纸还需涂布改性阻燃液,改性阻燃液为将阻燃剂和改性剂加入丙烯酸胶乳中搅拌均匀而制得。所述阻燃剂为具体可以为多溴联苯醚。 The base paper also needs to be coated with a modified flame retardant solution, which is prepared by adding a flame retardant and a modifier into acrylic latex and stirring evenly. The flame retardant may specifically be polybrominated diphenyl ethers.
制作方法,其特征在于,包括如下步骤: The production method is characterized in that it comprises the steps of:
步骤B中,浓度为4.5%,再搅拌为23分钟; In step B, the concentration is 4.5%, and then stirred for 23 minutes;
步骤C中,将浓度调到0.9%; In step C, adjust the concentration to 0.9%;
步骤F中、涂布量为7%; In step F, the coating amount is 7%;
步骤G中、浸渍量为12%; In step G, the impregnation amount is 12%;
步骤J中、在150℃下通过热风循环。 In step J, circulate hot air at 150°C.
实施例3: Example 3:
纤维配比:木浆共78%重量百分比,长纤维针叶木浆30%,短纤维阔叶木浆48%,功能纤维为涤纶占9%及维纶占5%,两种纤维细度均为3D,长度为5mm,加入助剂8%,其中聚丙烯酰胺3%,聚酰胺环氧氯丙烷 5%。 Fiber ratio: 78% by weight of wood pulp, 30% of long-fiber coniferous wood pulp, 48% of short-fiber hardwood pulp, 9% of functional fibers polyester and 5% of vinylon, the fineness of both fibers is 3D, The length is 5mm, and 8% of additives are added, including 3% of polyacrylamide and 5% of polyamide epichlorohydrin.
机内涂布:涂布液浓度8%,聚乙烯醇20%,分散剂3%,抗水剂2%,钛白粉5%,钙粉10%,胶乳60%。涂布所用量占前述三种主要原料的总重7%。 In-machine coating: coating liquid concentration 8%, polyvinyl alcohol 20%, dispersant 3%, water repellant 2%, titanium dioxide 5%, calcium powder 10%, latex 60%. The amount used for coating accounts for 7% of the total weight of the aforementioned three main raw materials.
机内浸渍:浸渍配方,三聚氰胺改性脲醛胶35%,改性甘油1%,改性淀粉5%,聚乙烯醇5%,渗透剂JF-C2%, 聚丁二烯树脂52%。浸渍量12%。 In-machine impregnation: impregnation formula, melamine modified urea-formaldehyde glue 35%, modified glycerin 1%, modified starch 5%, polyvinyl alcohol 5%, penetrant JF-C 2%, polybutadiene resin 52%. The impregnation amount is 12%.
成纸定量220g/m2,厚度1.3mm,抗张强度6kn/m, 撕裂度纵向5000mn,横向5200mn,耐破度510kpa。 The basis weight of the finished paper is 220g/m 2 , the thickness is 1.3mm, the tensile strength is 6kn/m, the tearing degree is 5000mn in the longitudinal direction, 5200mn in the transverse direction, and the bursting strength is 510kpa.
所述基纸还需涂布改性阻燃液,改性阻燃液为将阻燃剂和改性剂加入丙烯酸胶乳中搅拌均匀而制得。所述阻燃剂为具体可以为四溴双酚A。 The base paper also needs to be coated with a modified flame retardant solution, which is prepared by adding a flame retardant and a modifier into acrylic latex and stirring evenly. The flame retardant may specifically be tetrabromobisphenol A.
制作方法,其特征在于,包括如下步骤: The production method is characterized in that it comprises the steps of:
步骤B中,浓度为5%,再搅拌为25分钟; In step B, the concentration is 5%, and then stirred for 25 minutes;
步骤C中,将浓度调到1%; In step C, adjust the concentration to 1%;
步骤F中、涂布量为10%; In step F, the coating amount is 10%;
步骤G中、浸渍量为13%; In step G, the impregnation amount is 13%;
步骤J中、在160℃下通过热风循环。 In step J, circulate hot air at 160°C.
the
实施例4 Example 4
纤维配比:木浆共70%重量百分比,长纤维针叶木浆32%,短纤维阔叶木浆38%,功能纤维为维纶占21%,纤维细度为2D,长度为4mm,加入助剂9%,其中聚丙烯酰胺3%,聚酰胺环氧氯丙烷 6%。 Fiber ratio: 70% by weight of wood pulp, 32% of long-fiber softwood pulp, 38% of short-fiber hardwood pulp, 21% of functional fiber is vinylon, fiber fineness is 2D, length is 4mm, and additive 9 is added %, of which polyacrylamide 3%, polyamide epichlorohydrin 6%.
机内涂布:涂布液浓度9%,聚乙烯醇25%,分散剂3%,抗水剂2%,钛白粉10%,钙粉15%,胶乳45%。涂布所用量占前述三种主要原料的总重8%。 In-machine coating: coating liquid concentration 9%, polyvinyl alcohol 25%, dispersant 3%, water repellant 2%, titanium dioxide 10%, calcium powder 15%, latex 45%. The amount used for coating accounts for 8% of the total weight of the aforementioned three main raw materials.
机内浸渍:浸渍配方,三聚氰胺改性脲醛胶27%,改性甘油1%,改性淀粉5%,聚乙烯醇5%,渗透剂JF-C2%, 聚丁二烯树脂60%。浸渍量8%。 In-machine impregnation: impregnation formula, melamine modified urea-formaldehyde glue 27%, modified glycerin 1%, modified starch 5%, polyvinyl alcohol 5%, penetrant JF-C 2%, polybutadiene resin 60%. The impregnation amount is 8%.
成纸定量300g/m2,厚度2.2mm,抗张强度6.1kn/m, 撕裂度纵向5300mn,横向5400mn,耐破度520kpa。 The basis weight of the finished paper is 300g/m 2 , the thickness is 2.2mm, the tensile strength is 6.1kn/m, the tearing degree is 5300mn in the longitudinal direction, 5400mn in the transverse direction, and the bursting strength is 520kpa.
所述基纸还需涂布改性阻燃液,改性阻燃液为将阻燃剂和改性剂加入丙烯酸胶乳中搅拌均匀而制得。所述阻燃剂为具体可以为三氧化二锑。 The base paper also needs to be coated with a modified flame retardant solution, which is prepared by adding a flame retardant and a modifier into acrylic latex and stirring evenly. The flame retardant may specifically be antimony trioxide.
制作方法,其特征在于,包括如下步骤: The production method is characterized in that it comprises the steps of:
步骤B中,浓度为6%,再搅拌为28分钟; In step B, the concentration is 6%, and then stirred for 28 minutes;
步骤C中,将浓度调到1.1%; In step C, adjust the concentration to 1.1%;
步骤F中、涂布量为13%; In step F, the coating amount is 13%;
步骤G中、浸渍量为15%; In step G, the impregnation amount is 15%;
步骤J中、在180℃下通过热风循环。 In step J, circulate hot air at 180°C.
本发明关于成纸性质的测试方法,具体采用了如下标准的表述: The present invention has specifically adopted the expression of following standard about the test method of paper-forming property:
试样的制取按GB/T 450的规定进行;定量按GB/T 451.2的规定进行;厚度按GB/T 451.3的规定进行;纵向抗张强度按GB/T 12914的规定进行;耐破度按GB/T 454的规定进行;撕裂度按GB/T 455.1的规定进行。 The preparation of the sample shall be carried out according to the provisions of GB/T 450; the quantitative shall be carried out according to the provisions of GB/T 451.2; the thickness shall be carried out according to the provisions of GB/T 451.3; the longitudinal tensile strength shall be carried out according to the provisions of GB/T 12914; According to the provisions of GB/T 454; tearing according to the provisions of GB/T 455.1.
以上所述仅为本发明的较佳实施例而已,并不用以限制本发明,凡在本发明的精神和原则之内所作的任何修改、等同替换和改进等,均应包含在本发明的保护范围之内。本发明所涉及的组成成分和制备方法均可根据实施方式进行相应调整,但不能超出该发明保护范围。 The above descriptions are only preferred embodiments of the present invention, and are not intended to limit the present invention. Any modifications, equivalent replacements and improvements made within the spirit and principles of the present invention should be included in the protection of the present invention. within range. The components and preparation methods involved in the present invention can be adjusted accordingly according to the implementation, but cannot exceed the protection scope of the invention.
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| CN112211034A (en) * | 2020-10-19 | 2021-01-12 | 北京氧道纳米科技有限公司 | Facing paper with formaldehyde purification function |
| CN113927680A (en) * | 2021-09-23 | 2022-01-14 | 江苏建之兴实业股份有限公司 | Novel flame-retardant plate and preparation method thereof |
| CN116277321A (en) * | 2023-03-13 | 2023-06-23 | 佛山橡语木业有限公司 | Production process of formaldehyde-reducing balance paper, balance paper and artificial board |
| CN117488594A (en) * | 2023-12-17 | 2024-02-02 | 枣庄华润纸业有限公司 | Manufacturing process of bleached wood pulp dried-noodle gypsum board facing paper |
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Denomination of invention: The invention relates to a decorative plate facing paper and a production method thereof Effective date of registration: 20210923 Granted publication date: 20160831 Pledgee: Industrial and Commercial Bank of China Limited Tancheng sub branch Pledgor: SHANDONG LUNAN NEW MATERIALS Co.,Ltd. Registration number: Y2021980009765 |
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