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CN104526836A - Solid inorganic powder 3D printing method based on selective laser melting technology - Google Patents

Solid inorganic powder 3D printing method based on selective laser melting technology Download PDF

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Publication number
CN104526836A
CN104526836A CN201410800172.7A CN201410800172A CN104526836A CN 104526836 A CN104526836 A CN 104526836A CN 201410800172 A CN201410800172 A CN 201410800172A CN 104526836 A CN104526836 A CN 104526836A
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powder
solid inorganic
inorganic thing
laser
selective laser
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袁鸿
吴伟伟
陈捷
王康
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Nanjing Tech University
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Nanjing Tech University
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B28WORKING CEMENT, CLAY, OR STONE
    • B28BSHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
    • B28B1/00Producing shaped prefabricated articles from the material
    • B28B1/001Rapid manufacturing of 3D objects by additive depositing, agglomerating or laminating of material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C64/00Additive manufacturing, i.e. manufacturing of three-dimensional [3D] objects by additive deposition, additive agglomeration or additive layering, e.g. by 3D printing, stereolithography or selective laser sintering

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  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Chemical & Material Sciences (AREA)
  • Mechanical Engineering (AREA)
  • Ceramic Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Materials Engineering (AREA)
  • Optics & Photonics (AREA)

Abstract

本发明提供的一种基于选择性激光熔化技术的固体无机物粉末3D打印方法,其主要步骤包括:第一步:将上述三种材料粉末按照配比要求充分混合均匀;第二步:将粉末材料均匀平铺在快速成型机上,并充分压实;第三步:利用上述激光器选择性地熔化相关区域,当完成一层后,工作台上升一个层厚的高度;第四步:重复第二步和第三步,直至制件成型完成。本发明在该方法的基础上进行了改进,提出了一种新的方法过程,用激光器取代了喷头,当激光束照射到粉末表面使得温度达到粘结剂粉末熔点时,使得粘结剂粉末熔化包裹周围的固体无机物粉末,从而成形。

The present invention provides a 3D printing method for solid inorganic powder based on selective laser melting technology, the main steps of which include: the first step: fully mix the above three material powders according to the proportion requirements; the second step: mix the powder The material is evenly spread on the rapid prototyping machine and fully compacted; the third step: use the above-mentioned laser to selectively melt the relevant area, and when a layer is completed, the workbench rises to a layer thickness height; The first step and the third step until the part is formed. The present invention improves on the basis of this method, and proposes a new method process, which replaces the nozzle with a laser, and when the laser beam irradiates the powder surface so that the temperature reaches the melting point of the binder powder, the binder powder is melted Wrap the surrounding solid inorganic powder to form it.

Description

一种基于选择性激光熔化技术的固体无机物粉末3D打印方法A 3D printing method of solid inorganic powder based on selective laser melting technology

技术领域technical field

本发明属于增材制造领域,更具体的说涉及一种基于选择性激光熔化技术的固体无机物粉末3D打印方法。The invention belongs to the field of additive manufacturing, and more specifically relates to a 3D printing method of solid inorganic powder based on selective laser melting technology.

背景技术Background technique

增材制造技术又被称为快速成型技术、3D打印技术,它是一种以数字模型文件为基础,集CAD/CAM技术、激光加工技术、数控技术和新材料技术等科学领域的最新成果为一体,运用粉末、塑料等“可粘结”材料,通过逐层打印的方式来构造三维实体制造的技术。按照方法过程和所适用材料种类的不同,3D打印技术大体可以分为七大类:立体光刻技术(SLA)、分层实体制造技术(LOM)、熔融挤压成型技术(FDM)、三维印刷技术(3DP)、激光立体成形(净近成形LENS)方法、激光选区熔化技术(SLS)以及选择性激光熔化成型技术(SLM)。对于非金属材料来说,我们通常采用三维印刷技术(3DP),将粉末材料与粘结剂粉末充分混合均匀后,平铺在三维成型机上,通过喷头向指定区域喷射粘结剂溶液,粘结剂溶液与粘结剂粉末及基体粉末等经过毛细渗透,从而使得周围粉末可以固化成形Additive manufacturing technology is also called rapid prototyping technology and 3D printing technology. It is based on digital model files and integrates the latest achievements in scientific fields such as CAD/CAM technology, laser processing technology, numerical control technology and new material technology One, using "bondable" materials such as powder and plastic, to construct a three-dimensional solid manufacturing technology by layer-by-layer printing. According to the different methods and types of materials used, 3D printing technology can be roughly divided into seven categories: stereolithography (SLA), layered entity manufacturing (LOM), fusion extrusion molding (FDM), and three-dimensional printing. technology (3DP), laser stereoforming (net near shaping LENS) method, selective laser melting technology (SLS) and selective laser melting technology (SLM). For non-metallic materials, we usually use three-dimensional printing technology (3DP). After the powder material and binder powder are fully mixed and evenly spread on the three-dimensional molding machine, the binder solution is sprayed to the designated area through the nozzle to bond The agent solution, the binder powder and the matrix powder are infiltrated by capillary, so that the surrounding powder can be solidified and formed

发明内容Contents of the invention

本发明要解决的技术问题是提供一种新型的、方法过程简单且可用于水泥、石材和碳化硅等在激光照射时不发生表面改性的固体无机物粉末的3D打印方法。The technical problem to be solved by the present invention is to provide a new type of 3D printing method for solid inorganic powders, such as cement, stone and silicon carbide, which do not undergo surface modification when irradiated by laser light, and which have a simple process.

一种基于选择性激光熔化技术的固体无机物粉末3D打印方法,A 3D printing method of solid inorganic powder based on selective laser melting technology,

第一,配制固体无机物粉末材料,其配方为:固体无机物粉末、粘结剂和添加剂;First, prepare solid inorganic powder materials, the formula of which is: solid inorganic powder, binder and additives;

其中,固体无机物粉末是特指对激光照射不发生表面改性的粉末;粘结剂选用熔点为200~300℃的聚乙烯醇(PVA)粉末;添加剂选用气相白炭黑粉末;Among them, the solid inorganic powder refers to the powder that does not undergo surface modification to laser irradiation; the binder is polyvinyl alcohol (PVA) powder with a melting point of 200-300 °C; the additive is fumed silica powder;

第二,固体无机物粉末材料配方的比例分配如下:上述三种材料的体积比为(4-6):2:1,根据不同的固体无机物粉末比例可有所调整;Second, the ratio distribution of the solid inorganic powder material formula is as follows: the volume ratio of the above three materials is (4-6): 2:1, which can be adjusted according to different solid inorganic powder ratios;

第三,该方法所采用的激光器是二氧化碳激光器,激光功率范围为15~35W。Thirdly, the laser used in this method is a carbon dioxide laser, and the laser power ranges from 15 to 35W.

第四,该固体无机物三维成型制造方法所采用的方法是选择性激光熔化法。Fourth, the method adopted in the three-dimensional molding manufacturing method of solid inorganic matter is a selective laser melting method.

所述选择性激光熔化固体无机物的3D打印方法的步骤如下:The steps of the 3D printing method of selective laser melting solid inorganic matter are as follows:

第一步:将权利要求1所述的三种材料粉末按照配比要求充分混合均匀;The first step: fully mix the three material powders described in claim 1 according to the proportioning requirements;

第二步:将粉末材料均匀平铺在快速成型机上,并充分压实;The second step: evenly spread the powder material on the rapid prototyping machine and fully compact it;

第三步:利用上述激光器选择性地熔化相关区域,当完成一层后,工作台上升一个层厚的高度;Step 3: Use the above-mentioned laser to selectively melt the relevant area. When a layer is completed, the workbench rises to a height of layer thickness;

第四步:重复第二步和第三步,直至制件成型完成。Step 4: Repeat the second and third steps until the part is formed.

本发明的有益效果是:The beneficial effects of the present invention are:

本发明在该方法的基础上进行了改进,提出了一种新的方法过程,用激光器取代了喷头,当激光束照射到粉末表面使得温度达到粘结剂粉末熔点时,使得粘结剂粉末熔化包裹周围的固体无机物粉末,从而成形。将这种方法与一般的3DP方法相比,简化了方法过程,一般的3DP方法得经历液滴形成、液滴撞击粉材表面、液滴在粉材中润湿以及黏结固化粉粒这四个过程,方法过程相对复杂,受诸多因素控制,且不能保证最终成型件的性能。The present invention improves on the basis of this method, and proposes a new method process, which replaces the nozzle with a laser, and when the laser beam irradiates the powder surface so that the temperature reaches the melting point of the binder powder, the binder powder is melted Wrap the surrounding solid inorganic powder to form it. Compared with the general 3DP method, this method simplifies the method process. The general 3DP method has to go through the four stages of droplet formation, droplet impact on the surface of the powder, wetting of the droplet in the powder, and bonding and solidification of the powder. Process, method The process is relatively complex, controlled by many factors, and cannot guarantee the performance of the final molded part.

附图说明Description of drawings

图1是本发明的基于选择性激光熔化技术的固体无机物粉末3D打印方法的流程示意图。Fig. 1 is a schematic flow chart of the 3D printing method of solid inorganic powder based on selective laser melting technology of the present invention.

具体实施方式Detailed ways

下面对本发明的技术方案进行说明,以便于本技术领域的技术人员理解。The technical solutions of the present invention are described below to facilitate the understanding of those skilled in the art.

实施例1:Example 1:

本实施方案中的材料配方为:水泥粉末、聚乙烯醇(PVA)粉末和气相白炭黑粉末。The material formula in this embodiment is: cement powder, polyvinyl alcohol (PVA) powder and fumed white carbon black powder.

一种基于选择性激光熔化技术的固体无机物粉末3D打印方法,包括以下步骤:A method for 3D printing of solid inorganic powder based on selective laser melting technology, comprising the following steps:

第一步:将上述三种材料粉末按照体积配比4:2:1充分混合均匀;Step 1: Fully mix the above three material powders according to the volume ratio of 4:2:1;

第二步:将粉末材料均匀平铺在快速成型机上,并充分压实;The second step: evenly spread the powder material on the rapid prototyping machine and fully compact it;

第三步:利用激光器选择性地熔化相关区域,所采用的激光功率为15W,当完成一层后,工作台上升一个层厚的高度;Step 3: Use the laser to selectively melt the relevant area. The laser power used is 15W. After one layer is completed, the workbench rises to a height of layer thickness;

第四步:重复第二步和第三步,直至制件成型完成。Step 4: Repeat the second and third steps until the part is formed.

实施例2:Example 2:

本实施方案中的材料配方为:石材粉末、聚乙烯醇(PVA)粉末和气相白炭黑粉末。The material formula in this embodiment is: stone material powder, polyvinyl alcohol (PVA) powder and fumed white carbon black powder.

一种基于选择性激光熔化技术的固体无机物粉末3D打印方法,包括以下步骤:A method for 3D printing of solid inorganic powder based on selective laser melting technology, comprising the following steps:

第一步:将上述三种材料粉末按照体积配比5:2:1充分混合均匀;Step 1: Fully mix the above three material powders according to the volume ratio of 5:2:1;

第二步:将粉末材料均匀平铺在快速成型机上,并充分压实;The second step: evenly spread the powder material on the rapid prototyping machine and fully compact it;

第三步:利用激光器选择性地熔化相关区域,所采用的激光功率为25W,当完成一层后,工作台上升一个层厚的高度;Step 3: Use the laser to selectively melt the relevant area. The laser power used is 25W. When one layer is completed, the workbench rises to a height of layer thickness;

第四步:重复第二步和第三步,直至制件成型完成。Step 4: Repeat the second and third steps until the part is formed.

实施例3:Example 3:

本实施方案中的材料配方为:碳化硅粉末、聚乙烯醇(PVA)粉末和气相白炭黑粉末。The material formula in this embodiment is: silicon carbide powder, polyvinyl alcohol (PVA) powder and fumed silica powder.

一种基于选择性激光熔化技术的固体无机物粉末3D打印方法,包括以下步骤:A method for 3D printing of solid inorganic powder based on selective laser melting technology, comprising the following steps:

第一步:将上述三种材料粉末按照体积配比6:2:1充分混合均匀;Step 1: Fully mix the above three material powders according to the volume ratio of 6:2:1;

第二步:将粉末材料均匀平铺在快速成型机上,并充分压实;The second step: evenly spread the powder material on the rapid prototyping machine and fully compact it;

第三步:利用激光器选择性地熔化相关区域,所采用的激光功率为35W,当完成一层后,工作台上升一个层厚的高度;Step 3: Use the laser to selectively melt the relevant area. The laser power used is 35W. After one layer is completed, the workbench rises to a height of layer thickness;

第四步:重复第二步和第三步,直至制件成型完成。Step 4: Repeat the second and third steps until the part is formed.

上述对发明进行了示例性描述,显然本发明具体实现并不受上述方式限制,只要采用了本发明的方法构思和技术方案进行的这种非实质性改进,或未经改进将发明的构思和技术方案直接用于其他场合的,均在本发明的保护范围之内。The invention has been described as an example above, and it is obvious that the specific implementation of the present invention is not limited by the above-mentioned method, as long as the method concept and technical solution of the present invention are adopted for this non-substantial improvement, or the concept and concept of the invention are not improved. If the technical solutions are directly used in other occasions, they all fall within the protection scope of the present invention.

Claims (2)

1., based on a solid inorganic thing powder 3D Method of printing for selective laser melting technology, it is characterized in that:
The first, preparation solid inorganic thing dusty material, its formula is: solid inorganic thing powder, binding agent and additive;
Wherein, solid inorganic thing powder refers in particular to irradiate to laser the powder that surface modification does not occur; Binding agent selects fusing point to be polyvinyl alcohol (PVA) powder of 200 ~ 300 DEG C; Additive selects gas-phase silica powder;
The second, the pro rate of solid inorganic thing dusty material formula is as follows: the volume ratio of above-mentioned three kinds of materials is (4-6): 2:1, can adjust to some extent according to different solid inorganic thing powder proportions;
3rd, the laser instrument that the method adopts is carbon dioxide laser, and laser power scope is 15 ~ 35W.
4th, the method that the three-dimensionally shaped manufacture method of this solid inorganic thing adopts is selective laser melting method.
2. the 3D Method of printing of selective laser melting solid inorganic thing according to claim 1, is characterized in that, the step of the 3D Method of printing of described selective laser melting solid inorganic thing is as follows:
The first step: three kinds of material powders according to claim 1 are fully mixed according to ratio requirement;
Second step: dusty material is evenly laid on rapidform machine, and fully compacting;
3rd step: utilize above-mentioned laser instrument optionally to melt relevant range, after completing one deck, workbench rises the height of a thickness;
4th step: repeat second step and the 3rd step, complete until product is shaping.
CN201410800172.7A 2014-12-19 2014-12-19 Solid inorganic powder 3D printing method based on selective laser melting technology Pending CN104526836A (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106007723A (en) * 2016-05-20 2016-10-12 中国科学院上海硅酸盐研究所 Making method of SiC ceramic green body
CN107825706A (en) * 2017-12-15 2018-03-23 佛山三维二次方科技有限公司 The 3D printing technique of thermoplastic macromolecule material
CN110901063A (en) * 2019-12-18 2020-03-24 杭州德迪智能科技有限公司 Targeted induction and directional energy composite three-dimensional forming device and method
CN111689764A (en) * 2020-07-06 2020-09-22 南京理工大学 Low-cost preparation of ceramic powder for selective laser melting and defocusing forming method thereof

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CN103707388A (en) * 2013-12-23 2014-04-09 宁波市鄞州润物工业设计有限公司 Three-dimensional printing method
CN103769586A (en) * 2013-11-26 2014-05-07 王利民 Metal 3D printing product production method by means of low-power laser sintering
CN103817767A (en) * 2014-03-14 2014-05-28 邓湘凌 Method for manufacturing ceramic products with 3D printing technology

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Publication number Priority date Publication date Assignee Title
US6780368B2 (en) * 2001-04-10 2004-08-24 Nanotek Instruments, Inc. Layer manufacturing of a multi-material or multi-color 3-D object using electrostatic imaging and lamination
CN103769586A (en) * 2013-11-26 2014-05-07 王利民 Metal 3D printing product production method by means of low-power laser sintering
CN103707388A (en) * 2013-12-23 2014-04-09 宁波市鄞州润物工业设计有限公司 Three-dimensional printing method
CN103817767A (en) * 2014-03-14 2014-05-28 邓湘凌 Method for manufacturing ceramic products with 3D printing technology

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106007723A (en) * 2016-05-20 2016-10-12 中国科学院上海硅酸盐研究所 Making method of SiC ceramic green body
CN106007723B (en) * 2016-05-20 2018-10-30 中国科学院上海硅酸盐研究所 A kind of manufacturing method of SiC ceramic biscuit
CN107825706A (en) * 2017-12-15 2018-03-23 佛山三维二次方科技有限公司 The 3D printing technique of thermoplastic macromolecule material
CN110901063A (en) * 2019-12-18 2020-03-24 杭州德迪智能科技有限公司 Targeted induction and directional energy composite three-dimensional forming device and method
CN111689764A (en) * 2020-07-06 2020-09-22 南京理工大学 Low-cost preparation of ceramic powder for selective laser melting and defocusing forming method thereof

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