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CN104501203A - Gas mixture ratio control apparatus and method implementing low-nitrogen combustion by oxygen-deficient CO2-rich gas - Google Patents

Gas mixture ratio control apparatus and method implementing low-nitrogen combustion by oxygen-deficient CO2-rich gas Download PDF

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Publication number
CN104501203A
CN104501203A CN201410804389.5A CN201410804389A CN104501203A CN 104501203 A CN104501203 A CN 104501203A CN 201410804389 A CN201410804389 A CN 201410804389A CN 104501203 A CN104501203 A CN 104501203A
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Prior art keywords
air
boiler
gas
smoke
airduct
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Pending
Application number
CN201410804389.5A
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Chinese (zh)
Inventor
程学勤
叶平
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SHANSHUILE SHENZHEN ENVIRONMENTAL TECHNOLOGIES CO LTD
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SHANSHUILE SHENZHEN ENVIRONMENTAL TECHNOLOGIES CO LTD
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Priority to CN201410804389.5A priority Critical patent/CN104501203A/en
Publication of CN104501203A publication Critical patent/CN104501203A/en
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E20/00Combustion technologies with mitigation potential
    • Y02E20/34Indirect CO2mitigation, i.e. by acting on non CO2directly related matters of the process, e.g. pre-heating or heat recovery

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Abstract

The invention provides a gas mixture ratio control apparatus and method implementing low-nitrogen combustion by oxygen-deficient CO2-rich gas. The apparatus comprises an air preheater, a mixed gas tank, a blower, a boiler flue gas reflow pipe, a fresh air pipe and a blower air pipe; one end of a flue gas incoming chamber of the air preheater is communicated with a flue gas outlet of a boiler and communicated with the mixed gas tank through the boiler flue gas reflow pipe; a fresh air outlet of the fresh air preheater is communicated with the mixed gas tank through the fresh air pipe; the mixed gas tank is communicated with an air inlet of the blower; the blower is communicated with a primary air chamber inlet of the boiler. The blower extracts boiler flue gas and fresh air through the boiler flue gas reflow pipe and the fresh air pipe, respectively; the boiler flue gas and the fresh air are mixed well in the mixed gas tank; mixed gas is blown into the boiler by the blower; various gases engage in oxidation-reduction reactions in a hearth of the boiler; thus, oxygen nitride is eliminated or largely decreased.

Description

The Apparatus and method for that the gas and vapor permeation ratio that anoxic CO 2 enriched gas realizes low nitrogen burning controls
Technical field
The present patent application relates to the Apparatus and method for that a kind of anoxic CO 2 enriched gas realizes the gas and vapor permeation ratio control of low nitrogen burning, relate to the technological transformation of middle-size and small-size industrial layers combusting boiler, can realize energy-conservation and alleviate boiler combustion time nitrogen oxide generation, thus reach the object of energy-saving and emission-reduction, environmental protect.
Background technology
Fuel three kinds of combustion systems are in the boiler layer combustion, boiling type burning, suspension combustion.Layer combustion is exactly be placed in by fuel on the fire grate of fixing or movement, formed uniform, have the certain thickness bed of material, air passes into bottom fire grate, carries out combustion reaction by fuel bed, and the boiler of employing layer combustion is grate furnace.Grate furnace is divided into again according to fire grate form difference: handwarmer, stoker feed stove, and wherein stoker feed stove has chain furnace, vibration grate furnace, reciprocating grate furnace, spreader stoker boiler etc.
Existing boiler combustion, boiler smoke is arranged outward without reflow treatment, make the boiler smoke nitrous oxides concentration of outer row and temperature higher, cause toxic emission to exceed standard and thermal pollution; The blast temperature of boiler blower is gas at normal temperature, makes the waste heat of boiler discharged gas fume can not get effective utilization, the fuel that waste is valuable.
Summary of the invention
The present patent application is in order to improve the efficiency of combustion of boiler and reduce the generation of nitrogen oxide, the Apparatus for () and method therefor that the gas and vapor permeation ratio providing a kind of anoxic CO 2 enriched gas to realize low nitrogen burning controls.
An object of the present patent application is to provide a kind of equipment realizing the gas and vapor permeation ratio control of low nitrogen burning.
Specifically, the equipment that the gas and vapor permeation ratio that anoxic CO 2 enriched gas described in the present patent application realizes low nitrogen burning controls, comprise air preheater, mist case, air blast, boiler smoke backflow smoke pipe, fresh air airduct and air blast airduct, the exhanst gas outlet of one end and boiler that the flue gas of air preheater enters smoke-box communicates, and communicated with mist case by boiler smoke backflow smoke pipe, the fresh air gas outlet of air preheater is communicated with mist case by fresh air airduct, mist case communicates with the air intake vent of air blast, air blast is communicated with the First air air compartment air intake vent of boiler by air blast airduct, for the First air air compartment of boiler provides mist.
Further, one end of described boiler smoke backflow smoke pipe enters smoke-box by the flue gas being welded to connect air preheater, and the other end is connected with mist case by welding.
Further, described boiler smoke return duct is provided with the first valve, is used for controlling the size of smoke backflow gas flow.
Further, one end of described fresh air airduct is by being welded to connect the fresh air gas outlet of air preheater, and the other end is connected with mist case by welding.
Further, described fresh air airduct is provided with the second valve, controls the air capacity size of the fresh preheated air supplemented.
The Apparatus and method for that the gas and vapor permeation ratio that described anoxic CO 2 enriched gas realizes low nitrogen burning controls, by regulating above-mentioned two valves, controls the air quantity of two strands of gases.
Further, described boiler smoke backflow smoke pipe is connected with screw by flange with the first valve.
Further, air inlet and air outlet flange and the bolt of described air blast airduct and air blast are connected, and described air blast airduct and mist case are by being welded to connect.
Another object of the present patent application is to provide the method that anoxic CO 2 enriched gas realizes the gas and vapor permeation ratio control of low nitrogen burning, described method uses above-mentioned equipment, the exhanst gas outlet of one end and boiler that the flue gas of air preheater enters smoke-box communicates, and be connected with mist case by boiler smoke backflow smoke pipe, the fresh air gas outlet of air preheater is communicated with mist case by fresh air airduct, mist case is connected with the air intake vent of air blast, air blast is connected with the First air air compartment air intake vent of boiler by air blast airduct, for the First air air compartment of boiler provides gaseous mixture, smoke backflow in boiler smoke backflow smoke pipe makes the gas concentration lwevel of boiler internal higher, cause the fuel anoxycausis of boiler internal, the carbon dioxide of backflow and carbon black granules and fuel Formed, following reaction can be formed: C+CO under this ignition temperature and anoxia condition 2=2CO, 2C+O 2=2CO, the main source of boiler discharged nitrous oxides is fuel NO, the nitric oxide that the organic nitrogen both in fuel can generate fast when lower temperature combustion, accounts for the nitrogen oxide ratio of boiler waste gas discharge more than 90%, when the carbon monoxide of the very high concentration produced under the nitric oxide generated runs into anoxycausis condition, following chemical reaction can be there is under this temperature conditions: 2CO+2NO=2CO 2+ N 2, the conversion of nitric oxide gas being about to generate becomes nitrogen, thus realizes removing most fuel NO in combustion, reaches the emission reduction effect reducing nitrogen oxide generation.
Further, in said method, the fresh air of supplement boiler, by the preheating of air preheater, makes outer row's temperature of boiler smoke reduce, and makes full use of the waste heat in boiler smoke, reach the object of energy-saving and emission-reduction.
Further, in said method, described air blast extracts the mist of boiler backflow flue gas and the fresh air through air preheater preheating from mist case, delivers in the First air air compartment of boiler lower end.
The course of work of the Apparatus and method for that the gas and vapor permeation ratio that anoxic CO 2 enriched gas of the present invention realizes low nitrogen burning controls is: air blast extracts boiler smoke and fresh air respectively by boiler smoke backflow smoke pipe and fresh air airduct, after mixing in mist case, be sent in boiler by air blast airduct, there is redox reaction in various gas, reach the effect eliminating or significantly reduce nitrogen oxide in boiler furnace.
Accompanying drawing explanation
Fig. 1 is the structural representation of the equipment that the gas and vapor permeation ratio realizing low nitrogen burning described in the present patent application controls; Wherein, 1 be boiler, 11 be exhanst gas outlet, 12 be air intake vent, 2 be air preheater, 3 for flue gas, to enter smoke-box, 41 be the first valve, 42 is that the second valve, 5 is fresh air airduct, 7 is mist case, 8 be air blast, 9 is air blast airduct for boiler smoke backflow smoke pipe, 6.
Detailed description of the invention
Below in conjunction with specific embodiment, nonrestrictive explanation is done to the Apparatus for () and method therefor that the gas and vapor permeation ratio that the anoxic CO 2 enriched gas described in the present patent application realizes low nitrogen burning controls.
As shown in Figure 1, the equipment that the gas and vapor permeation ratio realizing low nitrogen burning described in the present patent application controls, comprise air preheater 2, mist case 7, air blast 8, boiler smoke backflow smoke pipe 5, fresh air airduct 6 and air blast airduct 9, the exhanst gas outlet 11 of one end and boiler 1 that the flue gas of air preheater 2 enters smoke-box 3 communicates, and communicated with mist case 7 by boiler smoke backflow smoke pipe 5, the fresh air gas outlet of air preheater 2 is communicated with mist case 7 by fresh air airduct 6, mist case 7 communicates with the air intake vent of air blast 8, air blast 8 is communicated with the First air air compartment air intake vent 12 of boiler 1 by air blast airduct 9, for the First air air compartment of boiler provides mist.Further, one end of described boiler smoke backflow smoke pipe 5 enters smoke-box 3 by the flue gas being welded to connect air preheater, the other end is connected with mist case 7 by welding, described boiler smoke return duct 5 is provided with the first valve 41, be used for controlling the size of smoke backflow gas flow, described fresh air airduct 6 is provided with the second valve 42, control the air capacity size of the fresh preheated air supplemented, by regulating above-mentioned two valves, control the air quantity of two strands of gases, further, described boiler smoke backflow smoke pipe 5 is connected with screw by flange with the first valve 41, described fresh air airduct 6 is connected with screw by flange with the second valve 42, air inlet and air outlet flange and the bolt of described air blast airduct 9 and air blast 8 are connected, described air blast airduct 9 and mist case 7 are by being welded to connect.
The anoxic CO 2 enriched gas of the present patent application realizes the Apparatus and method for of the gas and vapor permeation ratio control of low nitrogen burning, described method uses above-mentioned equipment, the exhanst gas outlet of one end and boiler that the flue gas of air preheater enters smoke-box communicates, and be connected with mist case by boiler smoke backflow smoke pipe, the fresh air gas outlet of air preheater is connected with mist case by fresh air airduct, mist case is connected with the air intake vent of air blast, air blast is connected with the First air air compartment air intake vent of boiler by air blast airduct, for the First air air compartment of boiler provides gaseous mixture, smoke backflow in boiler smoke backflow smoke pipe makes the gas concentration lwevel of boiler internal higher, cause the fuel anoxycausis of boiler internal, the carbon dioxide of backflow and carbon black granules and fuel Formed, following reaction can be formed: C+CO under this ignition temperature and anoxia condition 2=2CO, 2C+O 2=2CO, the main source of boiler discharged nitrous oxides is fuel NO, the nitric oxide that the organic nitrogen both in fuel can generate fast when lower temperature combustion, accounts for the nitrogen oxide ratio of boiler waste gas discharge more than 90%, when the carbon monoxide of the very high concentration produced under the nitric oxide generated runs into anoxycausis condition, following chemical reaction can be there is under this temperature conditions: 2CO+2NO=2CO 2+ N 2, the conversion of nitric oxide gas being about to generate becomes nitrogen, thus realize removing most fuel NO in combustion, reach the emission reduction effect reducing nitrogen oxide generation, in said method, the fresh air of supplement boiler is by the preheating of air preheater, outer row's temperature of boiler smoke is reduced, and the waste heat made full use of in boiler smoke, reach the object of energy-saving and emission-reduction, in said method, described air blast extracts the mist of boiler backflow flue gas and the fresh air through air preheater preheating from mist case, deliver in the First air air compartment of boiler lower end.
The Apparatus and method for that the gas and vapor permeation ratio that anoxic CO 2 enriched gas of the present invention realizes low nitrogen burning controls, air blast extracts boiler smoke and fresh air respectively by boiler smoke backflow smoke pipe and fresh air airduct, after mixing in mist case, be sent in boiler by air blast airduct, there is redox reaction in various gas, reach the effect eliminating or significantly reduce nitrogen oxide in boiler furnace.
It should be understood that; foregoing comprises accompanying drawing; all in order to the public understands described technology contents better; but not above-mentioned technology contents is limited; in fact, all with identical or close principle, the amendment that technique scheme is carried out or improvement; to realize substantially identical technical purpose, then all within the technical scheme that the present patent application is claimed.

Claims (10)

1. the equipment that the gas and vapor permeation ratio that an anoxic CO 2 enriched gas realizes low nitrogen burning controls, it is characterized in that: comprise air preheater, mist case, air blast, boiler smoke backflow smoke pipe, fresh air airduct and air blast airduct, the exhanst gas outlet of one end and boiler that the flue gas of air preheater enters smoke-box communicates, and communicated with mist case by boiler smoke backflow smoke pipe, the fresh air gas outlet of air preheater is communicated with mist case by fresh air airduct, mist case communicates with the air intake vent of air blast, air blast is communicated with the First air air compartment air intake vent of boiler by air blast airduct, for the First air air compartment of boiler provides mist.
2. the equipment that the gas and vapor permeation ratio that anoxic CO 2 enriched gas according to claim 1 realizes low nitrogen burning controls, it is characterized in that: one end of described boiler smoke backflow smoke pipe enters smoke-box by the flue gas being welded to connect air preheater, and the other end is connected with mist case by welding.
3. the equipment that the gas and vapor permeation ratio that anoxic CO 2 enriched gas according to claim 1 realizes low nitrogen burning controls, it is characterized in that: one end of described fresh air airduct is by being welded to connect the fresh air air outlet of air preheater, and the other end is connected with mist case by welding.
4. the equipment that the gas and vapor permeation ratio that anoxic CO 2 enriched gas according to claim 1 and 2 realizes low nitrogen burning controls, is characterized in that: described boiler smoke return duct is provided with the first valve, is used for controlling the size of smoke backflow gas flow.
5. the equipment that the gas and vapor permeation ratio that the anoxic CO 2 enriched gas according to claim 1 or 3 realizes low nitrogen burning controls, it is characterized in that: described fresh air airduct is provided with the second valve, control the air capacity size of the fresh preheated air supplemented.
6. the equipment that the gas and vapor permeation ratio that anoxic CO 2 enriched gas according to claim 4 realizes low nitrogen burning controls, is characterized in that: described boiler smoke backflow smoke pipe is connected with screw by flange with the first valve.
7. the equipment that the gas and vapor permeation ratio that anoxic CO 2 enriched gas according to claim 5 realizes low nitrogen burning controls, is characterized in that: described fresh air airduct is connected with screw by flange with the second valve.
8. the equipment that the gas and vapor permeation ratio that anoxic CO 2 enriched gas according to claim 1 and 2 realizes low nitrogen burning controls, it is characterized in that: air inlet and air outlet flange and the bolt of described air blast airduct and blower fan are connected, and described air blast airduct and mist case are by being welded to connect.
9. the method that the gas and vapor permeation ratio that an anoxic CO 2 enriched gas realizes low nitrogen burning controls, it is characterized in that: described method uses the equipment of claim 1-8, the exhanst gas outlet of one end and boiler that the flue gas of air preheater enters smoke-box communicates, and be connected with mist case by boiler smoke backflow smoke pipe, the fresh air gas outlet of air preheater is communicated with mist case by fresh air airduct, mist case is connected with the air intake vent of air blast, air blast is connected with the First air air compartment air intake vent of boiler by air blast airduct, for the First air air compartment of boiler provides gaseous mixture, smoke backflow in boiler smoke backflow smoke pipe makes the gas concentration lwevel of boiler internal higher, cause the fuel anoxycausis of boiler internal, the carbon dioxide of backflow and carbon black granules and fuel Formed, following reaction can be formed: C+CO under this ignition temperature and anoxia condition 2=2CO, 2C+O 2=2CO, the main source of boiler discharged nitrous oxides is fuel NO, the nitric oxide that the organic nitrogen both in fuel can generate fast when lower temperature combustion, accounts for the nitrogen oxide ratio of boiler waste gas discharge more than 90%, when the carbon monoxide of the very high concentration produced under the nitric oxide generated runs into anoxycausis condition, following chemical reaction can be there is under this temperature conditions: 2CO+2NO=2CO 2+ N 2, the conversion of nitric oxide gas being about to generate becomes nitrogen, thus realizes removing most fuel NO in combustion, reaches the emission reduction effect reducing nitrogen oxide generation.
10. the method that the gas and vapor permeation ratio that anoxic CO 2 enriched gas according to claim 9 realizes low nitrogen burning controls, it is characterized in that: in said method, the fresh air of supplement boiler is by the preheating of air preheater, outer row's temperature of boiler smoke is reduced, and the waste heat made full use of in boiler smoke, reach the object of energy-saving and emission-reduction.
CN201410804389.5A 2014-12-19 2014-12-19 Gas mixture ratio control apparatus and method implementing low-nitrogen combustion by oxygen-deficient CO2-rich gas Pending CN104501203A (en)

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Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105066110A (en) * 2015-08-11 2015-11-18 中山市迦南节能环保科技有限公司 Chain furnace composite combustion system combining coal bed combustion and biomass gasification injection combustion
CN105276606A (en) * 2015-11-30 2016-01-27 深圳市山水乐环保科技有限公司 Air distribution device and method of pure oxygen combustion system
CN105423753A (en) * 2015-11-19 2016-03-23 广东工业大学 Continuous high-temperature low-oxygen combustion aluminum melting furnace with porous spraying pipe heat exchanger
CN105841143A (en) * 2016-05-25 2016-08-10 上海华之邦科技股份有限公司 System and method for reducing NOx emissions through smoke recycling
CN105833682A (en) * 2016-04-21 2016-08-10 成都华西堂环保科技有限公司 Boiler air graded low-nitrogen combustion and denitration process
CN108291716A (en) * 2015-11-19 2018-07-17 爱德华兹有限公司 Waste gas treatment equipment and method
CN109489058A (en) * 2018-11-29 2019-03-19 北京富士特锅炉有限公司 A kind of boiler smoke reflux air blast cooling heat recycling device and its control method
CN109519958A (en) * 2018-12-28 2019-03-26 启明星宇节能科技股份有限公司 Fresh air flue gas ratio adjustment equipment for low nitrogen combustion
CN109579041A (en) * 2018-11-12 2019-04-05 上海理工大学 Low ash high calcium coal soil resistant, slagging boiler air preheater and combustion method

Cited By (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105066110A (en) * 2015-08-11 2015-11-18 中山市迦南节能环保科技有限公司 Chain furnace composite combustion system combining coal bed combustion and biomass gasification injection combustion
CN105066110B (en) * 2015-08-11 2018-10-16 中山市迦南节能环保科技有限公司 Chain furnace composite combustion system combining coal block layer combustion and biomass gasification jet combustion
CN108291716B (en) * 2015-11-19 2019-11-22 爱德华兹有限公司 Exhaust gas treatment equipment and methods
CN105423753A (en) * 2015-11-19 2016-03-23 广东工业大学 Continuous high-temperature low-oxygen combustion aluminum melting furnace with porous spraying pipe heat exchanger
CN108291716A (en) * 2015-11-19 2018-07-17 爱德华兹有限公司 Waste gas treatment equipment and method
US10767860B2 (en) 2015-11-19 2020-09-08 Edwards Limited Effluent gas treatment apparatus and method
CN105276606A (en) * 2015-11-30 2016-01-27 深圳市山水乐环保科技有限公司 Air distribution device and method of pure oxygen combustion system
CN105833682A (en) * 2016-04-21 2016-08-10 成都华西堂环保科技有限公司 Boiler air graded low-nitrogen combustion and denitration process
CN105833682B (en) * 2016-04-21 2018-07-27 成都华西堂环保科技有限公司 A kind of boiler air classification low nitrogen burning and denitrating technique
CN105841143A (en) * 2016-05-25 2016-08-10 上海华之邦科技股份有限公司 System and method for reducing NOx emissions through smoke recycling
CN109579041A (en) * 2018-11-12 2019-04-05 上海理工大学 Low ash high calcium coal soil resistant, slagging boiler air preheater and combustion method
CN109489058A (en) * 2018-11-29 2019-03-19 北京富士特锅炉有限公司 A kind of boiler smoke reflux air blast cooling heat recycling device and its control method
CN109519958A (en) * 2018-12-28 2019-03-26 启明星宇节能科技股份有限公司 Fresh air flue gas ratio adjustment equipment for low nitrogen combustion

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Application publication date: 20150408