CN104485422A - Single-layer solar battery and preparing method of single-layer solar battery - Google Patents
Single-layer solar battery and preparing method of single-layer solar battery Download PDFInfo
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- YVTHLONGBIQYBO-UHFFFAOYSA-N zinc indium(3+) oxygen(2-) Chemical compound [O--].[Zn++].[In+3] YVTHLONGBIQYBO-UHFFFAOYSA-N 0.000 claims description 2
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- 229910001218 Gallium arsenide Inorganic materials 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
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- LBAIJNRSTQHDMR-UHFFFAOYSA-N magnesium phthalocyanine Chemical compound [Mg].C12=CC=CC=C2C(N=C2NC(C3=CC=CC=C32)=N2)=NC1=NC([C]1C=CC=CC1=1)=NC=1N=C1[C]3C=CC=CC3=C2N1 LBAIJNRSTQHDMR-UHFFFAOYSA-N 0.000 description 1
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- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K30/00—Organic devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation
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- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K30/00—Organic devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation
- H10K30/80—Constructional details
- H10K30/81—Electrodes
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E10/00—Energy generation through renewable energy sources
- Y02E10/50—Photovoltaic [PV] energy
- Y02E10/549—Organic PV cells
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Abstract
The invention discloses a single-layer solar battery, which comprises a transparent insulation substrate, a transparent anode electrode layer, a photosensitive layer, a cathode electrode layer and an organic protection layer, wherein the transparent anode electrode layer, the photosensitive layer, the cathode electrode layer and the organic protection layer are sequentially laminated and formed on the transparent insulation substrate, a metal nanometer particle layer is formed on at least one side of the cathode electrode layer, the work function value of metal nanometer particles in the metal nanometer particle layer is lower than the power function value of the cathode electrode layer, the cathode electrode layer is formed by a single-layer, double-layer or multi-layer grapheme film, the thickness of the cathode electrode layer is 0.5 to 10nm, the thickness of the photosensitive layer is 100 to 1000nm, a second passivation layer is formed in a part, uncovered by a back side contact element, of the back side of the substrate layer and on the back side contact element, and the refractive index of the second passivation film is higher than 2.6. The single-layer solar battery has the advantages that the metal nanometer particle layer is formed on at least one side of the cathode electrode layer of the single-layer solar battery, the power function value of the metal nanometer particle layer is lower than the power function value of the catheter electrode layer, and the efficiency of the solar battery is further improved through the passivation layer arranged at the back side.
Description
Technical field
The invention belongs to technical field of solar batteries, particularly relate to a kind of individual layer solar cell and preparation method thereof.
Background technology
Solar cell is a kind of is the photovoltaic device of electric energy by transform light energy.Report efficiency is the inorganic solar cell of 4% from Bell Laboratory in 1954, since half a century, solar cell obtains development at full speed, all starts Lai Yichang " green energy resource revolution " in the world.After the nineties in 20th century, grown up again in inorganic solar cell family GaAs, cadmium telluride etc. photovoltaic device.But until today, high cost is the matter of utmost importance of restriction inorganic semiconductor solar cell large-scale promotion application.But Cost Problems is main or brought by inorganic material itself, so only have the green energy resource of real low cost to be only solve energy problem's effective way.
The research of organic solar batteries starts from 1958, magnesium phthalocyanine dye (MgPc) is clipped between the electrode of two different work functions by Keams and Calvin, make " sandwich " structure, thus obtain the open circuit voltage of 200mV, but its short circuit current exports then very low, so its energy conversion efficiency is also relatively low.This individual layer solar battery structure, 1986 by C.W.Tang adopt double layer heterojunction structure substitute, obtain the energy conversion efficiency of 1%.
Namely the reason that energy conversion efficiency is increased dramatically is think that double layer heterojunction structure provides the interface of an efficient exciton fractionation, and in other words double layer heterojunction structure makes neutral electron-hole pair split into free carrier and becomes more easy.It is evident that, the introducing of double layer heterojunction structure considerably increases the complexity of organic solar batteries device, and due to the output of quality to whole battery of heterojunction structure be vital, so to heterojunction growth control overflow comparatively harsh.
Therefore, if can be improved on the basis of original individual layer " sandwich " structure organic solar batteries, also can obtain the performance requirement of heterojunction photovoltaic cell, then will simplify the production routine of organic solar batteries further, and its process costs can be reduced.
Summary of the invention
The object of the invention is to the above-mentioned deficiency overcoming prior art, a kind of individual layer solar cell is provided, comprise transparent insulating substrate, transparent insulating substrate stacks gradually the transparent anode electrode layer of formation, photosensitive layer, negative electrode layer and organic protection layer, described negative electrode layer at least one side is formed with metal nano-particle layer, in described metal nano-particle layer, the work function value of metal nanoparticle is lower than the work function value of negative electrode layer, described negative electrode layer is by individual layer, double-deck or multi-layer graphene film is formed, thickness is 0.5-10nm, the thickness of described photosensitive layer is 100-1000nm, the part do not covered by rear-face contact part at the basalis back side and rear-face contact part are formed with the second passivation layer, the refractive index of described second passivating film is more than 2.6.
Further, in described metal nano-particle layer, metal nanoparticle is at least one metal nanoparticle in lithium, caesium, potassium, sodium.
Further, in described metal nano-particle layer, the work function value of metal nanoparticle is 4.3-2eV, and the thickness of described metal nano-particle layer is 0.5-1nm.
Further, the material of described transparent insulating substrate is quartz glass, silicate glass, vagcor, soda-lime glass, polyvinyl chloride, Merlon or polyester;
The conductive film of described transparent anode electrode layer to be material be tin indium oxide, zinc oxide aluminum, zinc-gallium oxide, indium zinc oxide, gold, aluminium, silver or carbon nano-tube;
The material of described photosensitive layer is phthalocyanine dye, pentacene, porphyrin compound, cyanine dyes, fullerene, PTCDA, Pe, Pe derivative, CdSe, CdS, CdTe, TiO2, ZnO, PbS, SnO2;
The thickness of described transparent insulating substrate is 1.1-1.5mm;
The thickness of described transparent anode electrode layer is 80-120nm.
Correspondingly, present invention also offers a kind of individual layer preparation method of solar battery, it comprises the steps:
Prepare transparent insulating substrate;
The wherein one side of described transparent insulating substrate forms transparent anode electrode layer;
Transparent anode electrode layer deposits light-sensitive material, forms photosensitive layer;
Deposit stacked metal nano-particle layer and cathode layer on a photoresist layer, thus obtain described individual layer solar cell, wherein, at least one face of described negative electrode layer is laminated with metal nano-particle layer;
Wherein, in described metal nano-particle layer the work function value of metal nanoparticle lower than the work function value of negative electrode layer;
Described stacked metal nano-particle layer and the cathode layer of depositing on a photoresist layer is by following three kinds of forming step, any one realizes:
First depositing metallic nanoparticles on a photoresist layer, forms metal nano-particle layer, then forms negative electrode layer by the individual layer be immersed in FeCl3 solution, bilayer or multi-layer graphene film transfer to metal nano-particle layer;
Or, first by the individual layer, bilayer or the multi-layer graphene film transfer that are immersed in FeCl3 solution on photosensitive layer, then on graphene film depositing metallic nanoparticles, form metal nano-particle layer;
Or, first depositing metallic nanoparticles on a photoresist layer, form metal nano-particle layer, again by the individual layer, bilayer or the multi-layer graphene film transfer that are immersed in FeCl3 solution in metal nano-particle layer, form negative electrode layer, then depositing metallic nanoparticles on negative electrode layer, forms another metal nano-particle layer.
Further, in described metal nano-particle layer, metal nanoparticle is at least one metal nanoparticle in lithium, caesium, potassium, sodium.
Further, in described metal nano-particle layer, the work function value of metal nanoparticle is 4.3-2eV, and the thickness of described metal nano-particle layer is 0.5-1nm.
Individual layer solar cell of the present invention, has following beneficial effect:
Described individual layer solar cell is at least simultaneously formed with metal nano-particle layer at its negative electrode layer, and the work function value of metal nano-particle layer, lower than negative electrode layer work function value, arranges by the back side efficiency that passivation layer improves solar cell further.Target electrode layer is modified, reduce the work function of negative electrode layer, thus further increase work function difference between negative electrode layer and transparent anode electrode layer, thus further enhancing the internal electric field of individual layer solar cell device, thus improve the efficiency that exciton is split, the final energy conversion efficiency promoting individual layer solar cell.Meanwhile, each for this solar cell device layer is formed by the preparation method of individual layer solar cell device successively, makes the connection of each layer closely, firmly, thus make this solar cell device stable performance, production efficiency is high, reduces production cost, is suitable for suitability for industrialized production.
Accompanying drawing explanation
In order to be illustrated more clearly in the embodiment of the present invention or technical scheme of the prior art, be briefly described to the accompanying drawing used required in embodiment or description of the prior art below, apparently, accompanying drawing in the following describes is only some embodiments of the present invention, for those of ordinary skill in the art, under the prerequisite not paying creative work, other accompanying drawing can also be obtained according to these accompanying drawings.
Fig. 1 is the structural representation of individual layer solar cell first execution mode of the embodiment of the present invention;
Fig. 2 is the structural representation of individual layer solar cell second execution mode of the embodiment of the present invention;
Fig. 3 is the structural representation of the third execution mode of individual layer solar cell of the embodiment of the present invention.
In figure: 1-negative electrode layer, 2-metal nano-particle layer, 3-photosensitive layer, 4-transparent anode electrode layer, 5-transparent insulating substrate.
Embodiment
Below by way of specific instantiation, embodiments of the present invention are described, those skilled in the art the content disclosed by this specification can understand other advantages of the present invention and effect easily.The present invention can also be implemented or be applied by embodiments different in addition, and the every details in this specification also can based on different viewpoints and application, carries out various modification or change not deviating under spirit of the present invention.
The invention provides a kind of individual layer solar cell, comprise transparent insulating substrate, with the transparent anode electrode layer stacking gradually formation on transparent insulating substrate, photosensitive layer and negative electrode layer, described negative electrode layer at least one side is formed with metal nano-particle layer, in described metal nano-particle layer, the work function value of metal nanoparticle is lower than the work function value of negative electrode layer, described negative electrode layer is by individual layer, double-deck or multi-layer graphene film is formed, thickness is 0.5-10nm, the thickness of described photosensitive layer is 100-1000nm, the part do not covered by rear-face contact part at the basalis back side and rear-face contact part are formed with the second passivation layer, the refractive index of described second passivating film is more than 2.6.The present embodiment individual layer solar cell has following three kinds of execution modes:
Refer to Fig. 1, the structural representation of individual layer solar cell first execution mode of the display embodiment of the present invention.In present embodiment, this individual layer solar cell comprises transparent insulating substrate 5 and on transparent insulating substrate 5, stacks gradually the transparent anode electrode layer 4 of formation, photosensitive layer 3, metal nano-particle layer 2 and negative electrode layer 1.Because the work function value of metal nanoparticle in metal nano-particle layer 2 is lower than the work function value of negative electrode layer 1, therefore, negative electrode layer 1 chemical stabilization, difficult oxidized, and metal nanoparticle in metal nano-particle layer is chemically active, easily oxidized, present embodiment is that metal nano-particle layer 2 is arranged on photosensitive layer 3, between negative electrode layer 1, that is to say stacked for metal nano-particle layer 2 negative electrode layer 1 that is formed in the one side of photosensitive layer 3, thus it is effective by metal nano-particle layer 2 and oxygen-barrier, effectively protect metal nano-particle layer 2 not oxidized, make the functional stable of metal nano-particle layer 2.
Refer to Fig. 2, the structural representation of individual layer solar cell second execution mode of the display embodiment of the present invention.In present embodiment, this individual layer solar cell comprises transparent insulating substrate 5 and on transparent insulating substrate 5, stacks gradually the transparent anode electrode layer 4 of formation, photosensitive layer 3, metal nano-particle layer 2, negative electrode layer 1 and metal nano-particle layer 2 ', wherein metal nano-particle layer 2 can be the same or different with the material of metal nano-particle layer 2 ', is the metal nanoparticle of work function value lower than the work function value of negative electrode layer.Present embodiment all stackedly on the two sides of negative electrode layer 1 is formed with metal nano-particle layer, as the above analysis, because the work function value of metal nanoparticle in metal nano-particle layer is lower than the work function value of negative electrode layer 1, therefore, negative electrode layer 1 chemical stabilization, metal nanoparticle in metal nano-particle layer is chemically active, and present embodiment is by stacked for metal nano-particle layer negative electrode layer 1 two sides that is arranged on, thus effectively will be layered on negative electrode layer 1 near the metal nano-particle layer 2 of photosensitive layer 3 one side and oxygen-barrier, effectively protect metal nano-particle layer 2 not oxidized, make the functional stable of metal nano-particle layer 2, be layered in the surface that is to say exposure metal nano-particle layer 2 ' in an atmosphere on negative electrode layer 1 another side As time goes on, to be slowly oxidized, thus the functional stabilization of metal nano-particle layer 2 ' is decreased, but the solar cell integrated performance of individual layer do not affected in present embodiment.In order to prevent metal nano-particle layer 2 ' oxidized, last layer anti-oxidation protection rete can be coated with at metal nano-particle layer 2 ' outer surface.
Refer to Fig. 3, the structural representation of the third execution mode of individual layer solar cell of the display embodiment of the present invention.In present embodiment, this individual layer solar cell comprises transparent insulating substrate 5 and on transparent insulating substrate 5, stacks gradually the transparent anode electrode layer 4 of formation, photosensitive layer 3, negative electrode layer 1 and metal nano-particle layer 2 ', and wherein the material of metal nano-particle layer 2 ' is the same with the material of the metal nano-particle layer 2 in above-mentioned two kinds of execution modes.This execution mode is laminated with metal nano-particle layer 2 ' in the one side of the negative electrode layer 1 deviating from photosensitive layer 3, that is to say outer surface metal nano-particle layer 2 ' being layered in negative electrode layer 1, as the above analysis, because the work function value of metal nanoparticle in metal nano-particle layer 2 ' is lower than the work function value of negative electrode layer 1, therefore, negative electrode layer 1 chemical stabilization, metal nanoparticle in metal nano-particle layer is chemically active, easily oxidized, but present embodiment negative electrode layer 1 can not effectively protect metal nano-particle layer 2 ' not oxidized, make to expose metal nano-particle layer 2 ' in an atmosphere As time goes on, the metal nanoparticle on its surface will be slowly oxidized, thus the functional stabilization of metal nano-particle layer 2 ' is decreased, thus cause the solar cell integrated performance of the individual layer in present embodiment also to decline to some extent.But the oxidized metal nanoparticle on metal nano-particle layer 2 ' surface will play the effect of protective layer; the interior metal nano particle of the close negative electrode layer 1 of metal nano-particle layer 2 ' is played to the effect of isolating oxygen; make metal nano-particle layer 2 ' not oxidized near the interior metal nano particle of negative electrode layer 1, the functional of metal nano-particle layer 2 ' is tended towards stability.Thus the solar cell integrated performance of the individual layer of present embodiment is also tended towards stability.In order to prevent metal nano-particle layer 2 ' oxidized, last layer anti-oxidation protection rete can be coated with at metal nano-particle layer 2 ' outer surface.
Claims (7)
1. an individual layer solar cell, it is characterized in that: comprise transparent insulating substrate, transparent insulating substrate stacks gradually the transparent anode electrode layer of formation, photosensitive layer, negative electrode layer and organic protection layer, described negative electrode layer at least one side is formed with metal nano-particle layer, in described metal nano-particle layer, the work function value of metal nanoparticle is lower than the work function value of negative electrode layer, described negative electrode layer is by individual layer, double-deck or multi-layer graphene film is formed, thickness is 0.5-10nm, the thickness of described photosensitive layer is 100-1000nm, the part do not covered by rear-face contact part at the basalis back side and rear-face contact part are formed with the second passivation layer, the refractive index of described second passivating film is more than 2.6.
2. individual layer solar cell according to claim 1, is characterized in that: in described metal nano-particle layer, metal nanoparticle is at least one metal nanoparticle in lithium, caesium, potassium, sodium.
3. individual layer solar cell according to claim 1, is characterized in that: in described metal nano-particle layer, the work function value of metal nanoparticle is 4.3-2eV, and the thickness of described metal nano-particle layer is 0.5-1nm.
4. individual layer solar cell according to claim 1, is characterized in that: the material of described transparent insulating substrate is quartz glass, silicate glass, vagcor, soda-lime glass, polyvinyl chloride, Merlon or polyester;
The conductive film of described transparent anode electrode layer to be material be tin indium oxide, zinc oxide aluminum, zinc-gallium oxide, indium zinc oxide, gold, aluminium, silver or carbon nano-tube;
The material of described photosensitive layer is phthalocyanine dye, pentacene, porphyrin compound, cyanine dyes, fullerene, PTCDA, Pe, Pe derivative, CdSe, CdS, CdTe, TiO2, ZnO, PbS, SnO2;
The thickness of described transparent insulating substrate is 1.1-1.5mm;
The thickness of described transparent anode electrode layer is 80-120nm.
5. an individual layer preparation method of solar battery, it comprises the steps:
Prepare transparent insulating substrate;
The wherein one side of described transparent insulating substrate forms transparent anode electrode layer;
Transparent anode electrode layer deposits light-sensitive material, forms photosensitive layer;
Deposit stacked metal nano-particle layer and cathode layer on a photoresist layer, thus obtain described individual layer solar cell, wherein, at least one face of described negative electrode layer is laminated with metal nano-particle layer;
Wherein, in described metal nano-particle layer the work function value of metal nanoparticle lower than the work function value of negative electrode layer;
Described stacked metal nano-particle layer and the cathode layer of depositing on a photoresist layer is by following three kinds of forming step, any one realizes:
First depositing metallic nanoparticles on a photoresist layer, forms metal nano-particle layer, then forms negative electrode layer by the individual layer be immersed in FeCl3 solution, bilayer or multi-layer graphene film transfer to metal nano-particle layer;
Or, first by the individual layer, bilayer or the multi-layer graphene film transfer that are immersed in FeCl3 solution on photosensitive layer, then on graphene film depositing metallic nanoparticles, form metal nano-particle layer;
Or, first depositing metallic nanoparticles on a photoresist layer, form metal nano-particle layer, again by the individual layer, bilayer or the multi-layer graphene film transfer that are immersed in FeCl3 solution in metal nano-particle layer, form negative electrode layer, then depositing metallic nanoparticles on negative electrode layer, forms another metal nano-particle layer.
6. individual layer preparation method of solar battery according to claim 5, is characterized in that: in described metal nano-particle layer, metal nanoparticle is at least one metal nanoparticle in lithium, caesium, potassium, sodium.
7. individual layer preparation method of solar battery according to claim 1, is characterized in that: in described metal nano-particle layer, the work function value of metal nanoparticle is 4.3-2eV, and the thickness of described metal nano-particle layer is 0.5-1nm.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410677719.9A CN104485422A (en) | 2014-11-21 | 2014-11-21 | Single-layer solar battery and preparing method of single-layer solar battery |
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| CN105207604A (en) * | 2015-10-28 | 2015-12-30 | 蒋安为 | Long-wave ultraviolet power generation device |
| CN106410040A (en) * | 2016-11-16 | 2017-02-15 | 太原理工大学 | Upright bulk hetero-junction organic solar cell doped with metal nanoparticles and making method thereof |
| WO2018152731A1 (en) * | 2017-02-23 | 2018-08-30 | 海门黄海创业园服务有限公司 | Cds/cdte solar cell structure |
| CN111243866A (en) * | 2020-01-20 | 2020-06-05 | 南京信息工程大学 | Double-dye co-sensitive solar cell |
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| CN111243866B (en) * | 2020-01-20 | 2021-11-12 | 南京信息工程大学 | Double-dye co-sensitive solar cell |
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