CN104428475B - For forming the panel of floor covering, the method for manufacturing this panel and the particulate matter for the panel - Google Patents
For forming the panel of floor covering, the method for manufacturing this panel and the particulate matter for the panel Download PDFInfo
- Publication number
- CN104428475B CN104428475B CN201380036382.7A CN201380036382A CN104428475B CN 104428475 B CN104428475 B CN 104428475B CN 201380036382 A CN201380036382 A CN 201380036382A CN 104428475 B CN104428475 B CN 104428475B
- Authority
- CN
- China
- Prior art keywords
- thermoplastic material
- layer
- panel
- glass fibers
- individual glass
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04F—FINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
- E04F15/00—Flooring
- E04F15/02—Flooring or floor layers composed of a number of similar elements
- E04F15/10—Flooring or floor layers composed of a number of similar elements of other materials, e.g. fibrous or chipped materials, organic plastics, magnesite tiles, hardboard, or with a top layer of other materials
- E04F15/107—Flooring or floor layers composed of a number of similar elements of other materials, e.g. fibrous or chipped materials, organic plastics, magnesite tiles, hardboard, or with a top layer of other materials composed of several layers, e.g. sandwich panels
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27N—MANUFACTURE BY DRY PROCESSES OF ARTICLES, WITH OR WITHOUT ORGANIC BINDING AGENTS, MADE FROM PARTICLES OR FIBRES CONSISTING OF WOOD OR OTHER LIGNOCELLULOSIC OR LIKE ORGANIC MATERIAL
- B27N3/00—Manufacture of substantially flat articles, e.g. boards, from particles or fibres
- B27N3/06—Making particle boards or fibreboards, with preformed covering layers, the particles or fibres being compressed with the layers to a board in one single pressing operation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C43/00—Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor
- B29C43/006—Pressing and sintering powders, granules or fibres
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C43/00—Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor
- B29C43/22—Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor of articles of indefinite length
- B29C43/30—Making multilayered or multicoloured articles
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C43/00—Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor
- B29C43/22—Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor of articles of indefinite length
- B29C43/30—Making multilayered or multicoloured articles
- B29C43/305—Making multilayered articles
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C43/00—Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor
- B29C43/32—Component parts, details or accessories; Auxiliary operations
- B29C43/44—Compression means for making articles of indefinite length
- B29C43/48—Endless belts
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C70/00—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
- B29C70/003—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts characterised by the matrix material, e.g. material composition or physical properties
- B29C70/0035—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts characterised by the matrix material, e.g. material composition or physical properties comprising two or more matrix materials
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C70/00—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
- B29C70/04—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
- B29C70/06—Fibrous reinforcements only
- B29C70/08—Fibrous reinforcements only comprising combinations of different forms of fibrous reinforcements incorporated in matrix material, forming one or more layers, and with or without non-reinforced layers
- B29C70/081—Combinations of fibres of continuous or substantial length and short fibres
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C70/00—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
- B29C70/04—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
- B29C70/28—Shaping operations therefor
- B29C70/40—Shaping or impregnating by compression not applied
- B29C70/50—Shaping or impregnating by compression not applied for producing articles of indefinite length, e.g. prepregs, sheet moulding compounds [SMC] or cross moulding compounds [XMC]
- B29C70/504—Shaping or impregnating by compression not applied for producing articles of indefinite length, e.g. prepregs, sheet moulding compounds [SMC] or cross moulding compounds [XMC] using rollers or pressure bands
- B29C70/506—Shaping or impregnating by compression not applied for producing articles of indefinite length, e.g. prepregs, sheet moulding compounds [SMC] or cross moulding compounds [XMC] using rollers or pressure bands and impregnating by melting a solid material, e.g. sheet, powder, fibres
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/12—Layered products comprising a layer of synthetic resin next to a fibrous or filamentary layer
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/30—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
- B32B27/304—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers comprising vinyl halide (co)polymers, e.g. PVC, PVDC, PVF, PVDF
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
- B32B37/10—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the pressing technique, e.g. using action of vacuum or fluid pressure
- B32B37/1027—Pressing using at least one press band
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
- B32B37/14—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers
- B32B37/24—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers with at least one layer not being coherent before laminating, e.g. made up from granular material sprinkled onto a substrate
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B38/00—Ancillary operations in connection with laminating processes
- B32B38/14—Printing or colouring
- B32B38/145—Printing
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
- B32B5/02—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
- B32B5/024—Woven fabric
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/0002—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate
- D06N3/0015—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate using fibres of specified chemical or physical nature, e.g. natural silk
- D06N3/0022—Glass fibres
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- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04F—FINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
- E04F15/00—Flooring
- E04F15/02—Flooring or floor layers composed of a number of similar elements
- E04F15/02038—Flooring or floor layers composed of a number of similar elements characterised by tongue and groove connections between neighbouring flooring elements
-
- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04F—FINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
- E04F15/00—Flooring
- E04F15/02—Flooring or floor layers composed of a number of similar elements
- E04F15/08—Flooring or floor layers composed of a number of similar elements only of stone or stone-like material, e.g. ceramics, concrete; of glass or with a top layer of stone or stone-like material, e.g. ceramics, concrete or glass
-
- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04F—FINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
- E04F15/00—Flooring
- E04F15/02—Flooring or floor layers composed of a number of similar elements
- E04F15/10—Flooring or floor layers composed of a number of similar elements of other materials, e.g. fibrous or chipped materials, organic plastics, magnesite tiles, hardboard, or with a top layer of other materials
- E04F15/102—Flooring or floor layers composed of a number of similar elements of other materials, e.g. fibrous or chipped materials, organic plastics, magnesite tiles, hardboard, or with a top layer of other materials of fibrous or chipped materials, e.g. bonded with synthetic resins
-
- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04F—FINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
- E04F15/00—Flooring
- E04F15/02—Flooring or floor layers composed of a number of similar elements
- E04F15/10—Flooring or floor layers composed of a number of similar elements of other materials, e.g. fibrous or chipped materials, organic plastics, magnesite tiles, hardboard, or with a top layer of other materials
- E04F15/105—Flooring or floor layers composed of a number of similar elements of other materials, e.g. fibrous or chipped materials, organic plastics, magnesite tiles, hardboard, or with a top layer of other materials of organic plastics with or without reinforcements or filling materials
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C43/00—Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor
- B29C43/32—Component parts, details or accessories; Auxiliary operations
- B29C43/44—Compression means for making articles of indefinite length
- B29C43/48—Endless belts
- B29C2043/483—Endless belts cooperating with a second endless belt, i.e. double band presses
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2101/00—Use of unspecified macromolecular compounds as moulding material
- B29K2101/12—Thermoplastic materials
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2309/00—Use of inorganic materials not provided for in groups B29K2303/00 - B29K2307/00, as reinforcement
- B29K2309/08—Glass
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29L—INDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
- B29L2031/00—Other particular articles
- B29L2031/732—Floor coverings
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2305/00—Condition, form or state of the layers or laminate
- B32B2305/08—Reinforcements
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2305/00—Condition, form or state of the layers or laminate
- B32B2305/10—Fibres of continuous length
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B32B2305/00—Condition, form or state of the layers or laminate
- B32B2305/22—Fibres of short length
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2305/00—Condition, form or state of the layers or laminate
- B32B2305/30—Fillers, e.g. particles, powders, beads, flakes, spheres, chips
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/40—Properties of the layers or laminate having particular optical properties
- B32B2307/412—Transparent
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/40—Properties of the layers or laminate having particular optical properties
- B32B2307/414—Translucent
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
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- B32B2307/00—Properties of the layers or laminate
- B32B2307/70—Other properties
- B32B2307/724—Permeability to gases, adsorption
- B32B2307/7242—Non-permeable
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B32B2307/00—Properties of the layers or laminate
- B32B2307/70—Other properties
- B32B2307/732—Dimensional properties
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-
- B—PERFORMING OPERATIONS; TRANSPORTING
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- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2309/00—Parameters for the laminating or treatment process; Apparatus details
- B32B2309/08—Dimensions, e.g. volume
- B32B2309/10—Dimensions, e.g. volume linear, e.g. length, distance, width
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- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
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-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
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- B32B2315/00—Other materials containing non-metallic inorganic compounds not provided for in groups B32B2311/00 - B32B2313/04
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- B32B2315/085—Glass fiber cloth or fabric
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B32B2471/00—Floor coverings
-
- B—PERFORMING OPERATIONS; TRANSPORTING
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- B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
- B32B37/0007—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding involving treatment or provisions in order to avoid deformation or air inclusion, e.g. to improve surface quality
- B32B37/0015—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding involving treatment or provisions in order to avoid deformation or air inclusion, e.g. to improve surface quality to avoid warp or curl
-
- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04F—FINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
- E04F2201/00—Joining sheets or plates or panels
- E04F2201/01—Joining sheets, plates or panels with edges in abutting relationship
- E04F2201/0153—Joining sheets, plates or panels with edges in abutting relationship by rotating the sheets, plates or panels around an axis which is parallel to the abutting edges, possibly combined with a sliding movement
-
- E—FIXED CONSTRUCTIONS
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- E04F2201/00—Joining sheets or plates or panels
- E04F2201/01—Joining sheets, plates or panels with edges in abutting relationship
- E04F2201/0153—Joining sheets, plates or panels with edges in abutting relationship by rotating the sheets, plates or panels around an axis which is parallel to the abutting edges, possibly combined with a sliding movement
- E04F2201/0161—Joining sheets, plates or panels with edges in abutting relationship by rotating the sheets, plates or panels around an axis which is parallel to the abutting edges, possibly combined with a sliding movement with snap action of the edge connectors
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- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04F—FINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
- E04F2201/00—Joining sheets or plates or panels
- E04F2201/02—Non-undercut connections, e.g. tongue and groove connections
- E04F2201/023—Non-undercut connections, e.g. tongue and groove connections with a continuous tongue or groove
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
- Y10T428/24802—Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.]
- Y10T428/24851—Intermediate layer is discontinuous or differential
- Y10T428/24868—Translucent outer layer
Landscapes
- Engineering & Computer Science (AREA)
- Architecture (AREA)
- Mechanical Engineering (AREA)
- Civil Engineering (AREA)
- Structural Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Composite Materials (AREA)
- Life Sciences & Earth Sciences (AREA)
- Physics & Mathematics (AREA)
- Textile Engineering (AREA)
- Fluid Mechanics (AREA)
- Manufacturing & Machinery (AREA)
- Wood Science & Technology (AREA)
- Forests & Forestry (AREA)
- Mathematical Physics (AREA)
- Ceramic Engineering (AREA)
- Laminated Bodies (AREA)
- Floor Finish (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Description
技术领域technical field
本发明涉及用于形成地板覆盖物的面板、用于制造这种面板的方法和用于所述面板的颗粒物。The present invention relates to a panel for forming a floor covering, a method for manufacturing such a panel and a granulate for said panel.
更具体地,本发明涉及包括至少一层热塑性材料的层、尤其是热塑性材料的基板层的面板。而且,这种面板还可以最所述层包括具有印刷装饰层的至少一个顶层和半透明和透明的耐磨层。More specifically, the invention relates to panels comprising at least one layer of thermoplastic material, in particular a substrate layer of thermoplastic material. Furthermore, such a panel may also comprise at least one top layer with a printed decorative layer and a translucent and transparent wear layer as said layers.
本发明尤其涉及这种类型的面板,即,在两个或更多个相对边缘上,包括联接装置或联接部,两块这种地板面板可以借助所述联接装置或联接部在所述边缘处联接,使其在垂直于相应边缘的水平方向上并且在地板面板的平面中以及在垂直于地板面板的平面的竖向方向上相互锁定。这种地板面板可以用于构成所谓的浮动地板覆盖物,其中地板面板在其边缘处连接至彼此,但自由地铺设在下部表面上。The invention relates in particular to panels of the type comprising, on two or more opposite edges, coupling means or portions by means of which two such floor panels can be connected at said edges. Coupling such that they are interlocked in a horizontal direction perpendicular to the respective edges and in the plane of the floor panels as well as in a vertical direction perpendicular to the plane of the floor panels. Such floor panels can be used to construct so-called floating floor coverings, wherein the floor panels are connected to each other at their edges, but lie freely on the underlying surface.
背景技术Background technique
例如从EP 1938963、EP 2339092A1和WO 2010/023042已知这种面板。从这些文献已知乙烯基地板面板用于形成浮动地板覆盖物。这种乙烯基地板面板大部分具有3至5毫米的厚度并且具有高材料密度。面板的相应芯部由例如可以包括填料的软PVC的热塑性材料的一个或多个层构成。在印刷部上设有透明热塑性层并且可以设有表面漆层。根据EP2339092A1,可以施加在玻璃纤维基础上的加强层。Such panels are known, for example, from EP 1938963, EP 2339092A1 and WO 2010/023042. From these documents vinyl floor panels are known for forming floating floor coverings. Such vinyl floor panels mostly have a thickness of 3 to 5 mm and have a high material density. The respective cores of the panels consist of one or more layers of thermoplastic material such as soft PVC which may include fillers. A transparent thermoplastic layer and possibly a surface lacquer layer are provided on the printed part. According to EP2339092A1 a reinforcement layer on a fiberglass base can be applied.
现有技术的面板的缺点在于在温度影响下,它们经受较强的收缩和膨胀。收缩和膨胀会导致地板覆盖物或各面板向上推起,例如以相互释放联接部,或者导致这样的现象,即,各板形部件将漂离,由此会产生间隙。现有技术的面板的特征使得已经由于例如在房间窗户处入射阳光的加热而出现问题。A disadvantage of prior art panels is that they are subject to strong shrinkage and expansion under the influence of temperature. Shrinkage and expansion can lead to the floor covering or the panels being pushed upwards, for example to release the joints from one another, or to the phenomenon that the plate-shaped parts will float away, whereby gaps are created. The characteristics of the panels of the prior art are such that problems arise already due to heating eg by incident sunlight at a room window.
从WO 2012/004701已知施加玻璃纤维层或嵌入型材来增大这种面板的尺寸稳定性。尤其在此已经解决了面板的弯曲硬度。From WO 2012/004701 it is known to apply glass fiber layers or embedded profiles to increase the dimensional stability of such panels. In particular the bending stiffness of the panels has been addressed here.
US 6306318描述了用于再循环废弃地毯的方法,其中,从基于废弃地毯和新的软PVC的再循环物料的熔融混合物开始,借助注射成型方法生产最小厚度为大约5毫米的柔性地板砖。所述混合物包括重量百分比最大为5的塑化剂的量,所获得的地板砖横过其厚度具有均匀的成分并且包括重量百分比为10至20的未熔化聚酰胺或聚酯地毯纤维,所述地毯纤维横过这些地板砖的厚度均匀分布。所述纤维提供耐磨表面。作为废弃地毯的再循环物料的替代物,也可以应用玻璃纤维强化的合成材料(英文:玻璃纤维)的再循环物料。在地毯的情况下,其以大约3.2毫米或更大的地毯纤维开始,其中尽可能避免在处理期间长度的减小。但可以预期在注射成型之前使地毯破碎并在挤压机中对其进行处理实际上将导致现有纤维缩短。不清楚当从玻璃纤维加强合成材料的再循环开始时玻璃纤维的长度将是多少。而且不清楚多少玻璃纤维已经合并到地板砖基体中以及应用了何种玻璃纤维。所得到的地板砖较硬并且柔性不足。这会导致在使用期间冲击噪音的问题以及不能适应不平坦的下部表面的问题。注射成型的地板砖包括沿着边缘的联接装置,但这些联接装置并不提供沿竖向方向的锁定。而且,尤其在软热塑性材料的情况下,注射成型的精度较差。该方法是耗时的,并且地板砖的耐磨侧的外观几乎不可能变化。这种地板砖可能仍随着温度变化而具有较大的尺寸变化。US 6306318 describes a method for recycling waste carpets in which, starting from a molten mixture of recycled material based on waste carpets and new soft PVC, flexible floor tiles with a minimum thickness of about 5 mm are produced by means of injection molding methods. Said mixture comprises an amount of plasticizer in a maximum of 5 weight percent, the floor tile obtained has a uniform composition across its thickness and comprises 10 to 20 weight percent of unmelted polyamide or polyester carpet fibers, said The carpet fibers are evenly distributed across the thickness of these floor tiles. The fibers provide a wear resistant surface. As an alternative to the recycled material of waste carpet, it is also possible to use the recycled material of glass-fibre-reinforced synthetic material (English: glass fibres). In the case of carpets, this starts with carpet fibers of about 3.2 mm or larger, wherein a reduction in length during processing is avoided as much as possible. But it can be expected that breaking up the carpet before injection molding and processing it in the extruder will actually result in shortening of the existing fibers. It is not clear what the length of the glass fibers will be when starting from the recycling of glass fiber reinforced composites. It is also unclear how much glass fiber has been incorporated into the floor tile matrix and what kind of glass fiber is applied. The resulting floor tiles are relatively hard and not sufficiently flexible. This can lead to problems with impact noise during use and problems with uneven lower surfaces. Injection molded floor tiles include couplings along the edges, but these do not provide locking in the vertical direction. Furthermore, especially in the case of soft thermoplastic materials, the precision of injection molding is poor. This method is time consuming and it is almost impossible to change the appearance of the wear side of the floor tile. Such floor tiles may still have large dimensional changes with temperature changes.
GB 1248060作为与US 6306318类似的替代方法描述了通过一种方法制造加强热塑性材料的可行方案,在所述方法中,连续的纤维层与热塑性颗粒物层交替地层叠并被挤压。这样,避免了在挤压机中现有纤维的破碎。根据示例,硬PVC可用作热塑性材料。GB 1248060 describes, as an alternative similar to US 6306318, a possible solution for manufacturing reinforced thermoplastic materials by a process in which successive layers of fibers are alternately laminated with layers of thermoplastic particles and extruded. In this way, breakage of existing fibers in the extruder is avoided. According to an example, rigid PVC can be used as thermoplastic material.
发明内容Contents of the invention
本发明涉及一种可替代面板,其首先用作用于形成浮动地板覆盖物的地板面板。根据本发明的各优选实施例,还提供用于解决现有技术面板的问题的方案。The present invention relates to a replaceable panel, firstly used as a floor panel for forming a floating floor covering. According to preferred embodiments of the present invention, solutions for solving the problems of prior art panels are also provided.
为此,本发明根据其第一独立方面涉及一种用于形成地板覆盖物的面板,其中该面板包括由热塑性材料构成的至少一层,其特征在于,所述层还包括优选地长度大于1mm的独立纤维。“独立纤维”意味着它们不形成诸如玻璃纤维布的层或预制层的一部分,而是例如在热塑性材料内均匀或不均匀地自由分布。发明人已经发现使用这种松散或独立的纤维可以在主要程度上有助于面板的尺寸稳定性,并且继而尤其可以限制膨胀或收缩的程度。通常,这种独立纤维嵌入在热塑性材料中看起来比例如玻璃纤维布更好。而且与这种玻璃纤维网(无纺布)或玻璃纤维布(纺织)相比,所述独立纤维可以在热塑性材料的较大厚度上有效,从而可以在较大程度上避免通过在这种玻璃纤维布上移开而产生收缩或膨胀。To this end, the invention according to its first independent aspect relates to a panel for forming a floor covering, wherein the panel comprises at least one layer of thermoplastic material, characterized in that said layer also comprises independent fibers. "Independent fibers" means that they do not form part of a layer such as glass fiber cloth or a prefabricated layer, but are distributed freely, eg, uniformly or inhomogeneously within the thermoplastic material. The inventors have found that the use of such loose or individual fibers can contribute substantially to the dimensional stability of the panel, and in turn limit the degree of expansion or contraction among other things. Typically, such individual fibers look better embedded in thermoplastic materials than, for example, fiberglass cloth. Moreover, compared with such glass fiber mesh (non-woven fabric) or glass fiber cloth (woven), the independent fibers can be effective on a larger thickness of thermoplastic material, so that the passage through the glass fiber can be avoided to a large extent. Shrinkage or expansion occurs when the fiber cloth is removed.
优选地,相应纤维的平均长度为3毫米或更大。已借助平均长度为大约4.5毫米的纤维获得了良好的效果。优选地,配件厂的短于10毫米或者甚至短于6毫米。Preferably, the average length of the respective fibers is 3 mm or greater. Good results have been obtained with fibers having an average length of about 4.5 mm. Preferably, the accessory factory is shorter than 10 mm or even shorter than 6 mm.
优选地,相应的层所包括的相应纤维的重量百分比在1与25之间,并且重量百分比更好是在5与15之间,而不包括诸如白垩的其它可能的纤维。Preferably, the respective layers comprise respective fibers in a weight percent between 1 and 25, and better still between 5 and 15 weight percent, excluding other possible fibers such as chalk.
优选地,玻璃纤维用于所述纤维。优选地选择例如在DIN 1259中定义的E玻璃。根据替代方案,可以应用钢纤维或其它纤维,诸如碳纤维、芳族聚酰胺纤维或聚乙烯纤维。Preferably glass fibers are used for the fibers. E-glass as defined in DIN 1259, for example, is preferably selected. According to an alternative, steel fibers or other fibers such as carbon, aramid or polyethylene fibers may be applied.
优选地,应用防潮纤维,并且因而没有纤维素纤维,除非它们例如用乙酰化作用涂覆或处理,以便使其至少在一定程度上防潮。Preferably, moisture-resistant fibers are applied, and thus no cellulose fibers, unless they are coated or treated, for example with acetylation, in order to render them at least somewhat moisture-resistant.
优选地,例如玻璃纤维的纤维的平均直径在1微米与100微米之间或者更好在3微米与30微米之间,其中在各种试验中,在5微米与25微米之间的范围已被证明是最好的。Preferably, the average diameter of the fibers, such as glass fibers, is between 1 micron and 100 microns or better still between 3 microns and 30 microns, wherein in various tests the range between 5 microns and 25 microns has been Proven to be the best.
优选地,所述纤维设有涂层或被处理以提高到热塑性材料的附着性。优选地,纤维的表面用诸如硅烷的耦合剂处理。Preferably, the fibers are provided with a coating or treated to improve adhesion to thermoplastic materials. Preferably, the surface of the fibers is treated with a coupling agent such as silane.
优选地,所述纤维的热膨胀系数小于其所处于其中的热塑性材料的热膨胀系数,并且/或者杨氏模量高于其所处于其中的热塑性材料的杨氏模量。Preferably, the fiber has a coefficient of thermal expansion smaller than that of the thermoplastic material in which it is located and/or a Young's modulus higher than that of the thermoplastic material in which it is located.
优选地,所应用的纤维的杨氏模量大于40GPa,更好是大于60GPa。Preferably, the applied fibers have a Young's modulus greater than 40 GPa, more preferably greater than 60 GPa.
优选地,所应用的纤维的热膨胀系数小于30μm/mK并且更好的是小于5μm/mK。Preferably, the fibers used have a coefficient of thermal expansion of less than 30 μm/mK and better still less than 5 μm/mK.
优选地,所述热塑性材料涉及聚氯乙稀,优选地半刚性或甚至是软的聚氯乙稀(PVC),即具有塑化剂的PVC,例如PVC中塑化剂的重量百分比大于百分之20或大于百分之30。清楚的是代替PVC的使用,还可以应用聚丙烯(PP)、聚乙烯(PET)或聚氨酯(PUR)。Preferably, said thermoplastic material relates to polyvinyl chloride, preferably semi-rigid or even soft polyvinyl chloride (PVC), ie PVC with a plasticizer, for example with a weight percentage of plasticizer in PVC greater than % 20 or more than 30 percent. It is clear that instead of using PVC, polypropylene (PP), polyethylene (PET) or polyurethane (PUR) can also be used.
优选地,本发明的面板还包括在所述层上方的至少印刷装饰层和设置在其上面的半透明或透明的耐磨层。所述装饰层可以由在合成材料膜上进行印刷而形成,例如印刷的PVC膜、PU膜、PP膜、PET膜。在PP膜的情况下,这可以例如涉及定向聚丙烯膜。耐磨层优选地也包括热塑性材料,诸如PVC、PU、PP或PET。优选地,透明热塑性耐磨层没有固体添加剂,例如用于增强耐磨性的陶瓷颗粒物,但这种颗粒物并不被排除在外。但发明人已经发现为了获得良好的透明度而将其省略,同时仍保持可接受的耐磨性,即,根据EN 13329测量,耐磨性可以与AC2或AC3级的层叠面板相比或更好。耐磨层的厚度是最小0.15毫米,并且更好是最小0.3毫米,但优选地小于1毫米,其中0.2至0.4毫米是较好的值。借助该较好的值,通过耐磨层自身的热塑性材料,因而不考虑可能的固体添加剂,对于住宅应用就已经可以获得足够的耐磨性。因此例如可以在附件E的EN 13329中描述的挺度测试中获得2000或更高的IP值(初始磨损点)。Preferably, the panel of the invention further comprises at least a printed decorative layer above said layer and a translucent or transparent wear layer disposed thereon. The decorative layer may be formed by printing on a film of synthetic material, such as printed PVC film, PU film, PP film, PET film. In the case of PP films, this may for example involve oriented polypropylene films. The wear layer preferably also comprises a thermoplastic material, such as PVC, PU, PP or PET. Preferably, the transparent thermoplastic wear layer is free of solid additives, such as ceramic particles for enhanced wear resistance, but such particles are not excluded. The inventors have however found that it is omitted in order to obtain good transparency while still maintaining acceptable abrasion resistance, ie comparable or better than AC2 or AC3 class laminate panels as measured according to EN 13329. The thickness of the wear layer is at least 0.15 mm, and better at least 0.3 mm, but preferably less than 1 mm, with 0.2 to 0.4 mm being preferred values. With this better value, sufficient wear resistance for residential applications can already be achieved by the thermoplastic material of the wear layer itself, thus disregarding possible solid additives. Thus for example an IP value of 2000 or higher (point of initial wear) can be obtained in the stiffness test described in Annex E of EN 13329.
根据替代方案,印刷装饰或印刷可以设置在耐磨层的下侧上。According to an alternative, a printed decoration or printing can be provided on the underside of the wear layer.
优选地,所述热塑性层还包括至少玻璃纤维布或玻璃纤维网。优选地,其在此涉及所谓的“无纺布”,即,玻璃纤维网。发明人已经发现最好买入在热塑性材料中的玻璃纤维网可以被定向,并且因此可以更高效地加工玻璃纤维。Preferably, the thermoplastic layer further comprises at least glass fiber cloth or glass fiber mesh. Preferably, this is a so-called "nonwoven", ie a glass fiber web. The inventors have discovered that glass fiber webs that are best purchased in thermoplastic materials can be oriented and thus the glass fibers can be processed more efficiently.
优选地,根据本发明包括独立纤维的热塑性层涉及基板层,即,在顶层下面延伸的层。优选地,这种层位于面板厚度的至少中间。这样,限制或排除了随温度变化的可能的弯曲效应。Preferably, the thermoplastic layer comprising individual fibers according to the invention relates to the substrate layer, ie the layer extending below the top layer. Preferably, such a layer is located at least in the middle of the thickness of the panel. In this way, possible bending effects as a function of temperature are limited or excluded.
面板的基板可以通过各种可能的方式构成。下文总结了非排他性的一些可行方案。The substrate of the panel can be constructed in various possible ways. Some non-exclusive possible options are summarized below.
根据第一可行方案,面板包括基于热塑性材料的至少两个这种层。这些层可以直接位于彼此之上或者可以通过诸如玻璃纤维布或玻璃纤维网的一个或多个中间层分开。根据该第一可行方案,面板的厚度优选地由这些层形成百分之40或更多,或者甚至一半或更多。换言之,面板的基板,因而位于装饰下面的层,基本可以由具有热塑性材料和独立纤维的这种层形成。明显的是这样可以通过有利方式减小随温度变化膨胀或收缩的程度。According to a first possibility, the panel comprises at least two such layers based on thermoplastic material. The layers may lie directly on top of each other or may be separated by one or more intermediate layers such as fiberglass cloth or mesh. According to this first possibility, the thickness of the panel is preferably formed by these layers by 40 percent or more, or even by half or more. In other words, the substrate of the panel, and thus the layer underlying the decoration, can essentially be formed of such a layer with thermoplastic material and individual fibers. It is clear that this advantageously reduces the degree of expansion or contraction with temperature changes.
根据第二可行方案,所述面板进包括基于热塑性材料和纤维的一个这种层。这种层位于面板和/或基板的厚度的至少中间。相应层优选地形成面板和/或基板的厚度的至少百分之10并且更好是至少百分之50。基板的厚度的其余部分继而可以由可以不必包括纤维的热塑性材料层形成,和/或由一个或多个玻璃纤维布或玻璃纤维网形成。不排除相应层形成多于百分之80或者甚至是整个基板。According to a second possibility, said panel further comprises one such layer based on thermoplastic material and fibres. Such a layer is located at least in the middle of the thickness of the panel and/or substrate. The respective layers preferably form at least 10 percent and better at least 50 percent of the thickness of the panel and/or substrate. The remainder of the thickness of the substrate may then be formed from a layer of thermoplastic material which may not necessarily include fibres, and/or from one or more glass fiber cloths or meshes. It is not excluded that the corresponding layer forms more than 80 percent or even the entire substrate.
优选地,基板厚度是1.3至10毫米。整个地板面板的厚度优选地是在2至6毫米之间。优选地,基板形成地板面板的厚度的至少二分之一。Preferably, the substrate thickness is 1.3 to 10 mm. The thickness of the entire floor panel is preferably between 2 and 6 mm. Preferably, the base plate forms at least half of the thickness of the floor panel.
在基板下侧上,可以设有相对层或衬垫层,优选地是蒸气密封层。这种相对层或衬垫层优选地由热塑性合成材料层构成。相对层的厚度优选地对应于包括可能的背衬层的顶层的厚度,但优选地较薄。相对层优选地用作平衡层,以便可以获得平衡的夹层结构,即,面板没有翘曲或翘曲最小。On the underside of the substrate, an opposing layer or backing layer, preferably a vapor-tight layer, may be provided. This counter layer or backing layer preferably consists of a layer of thermoplastic synthetic material. The thickness of the opposite layer preferably corresponds to the thickness of the top layer including a possible backing layer, but is preferably thinner. The opposite layer is preferably used as a balancing layer, so that a balanced sandwich structure can be obtained, ie no or minimal warping of the panels.
优选地,根据本发明包括独立纤维的层的热塑性材料还包括填料,诸如石灰石。Preferably, the thermoplastic material comprising a layer of individual fibers according to the invention also comprises a filler, such as limestone.
漆层可以用作面板的最下层。在此,这可以涉及UV或电子束硬化的漆层或PU漆层。A layer of lacquer can be used as the lowest layer of the panel. In this case, this can be a UV- or electron beam-cured lacquer layer or a PU varnish layer.
优选地,应用本发明的地板面板在各边缘处设有机械联接装置,允许将两块这种地板面板联接至彼此,以便在垂直于联接边缘的水平方向上并且在面板的平面中以及在垂直于所联接的面板的平面的竖向方向上产生锁定。优选地,所述联接装置还具有以下特征中的一个或两个或多个的组合:Preferably, the floor panels to which the invention is applied are provided at each edge with mechanical coupling means allowing to couple two such floor panels to each other so that in the horizontal direction perpendicular to the joint edges and in the plane of the panels and in the vertical The locking takes place in the vertical direction of the plane of the joined panels. Preferably, the coupling device also has one or a combination of two or more of the following features:
-所述机械联接装置或联接部基本实现为舌部和由上唇和下唇界定的槽,其中该舌部和槽基本用于沿所述竖向方向锁定,并且其中舌部和槽设有基本用于沿所述水平方向锁定的额外锁定部。优选地,锁定部包括在舌部的下侧上的凸起和在下部槽唇中的凹槽。这种联接装置和锁定部例如从WO 97/47834已知;- said mechanical coupling means or coupling is substantially realized as a tongue and a groove delimited by an upper lip and a lower lip, wherein the tongue and groove are substantially intended for locking in said vertical direction, and wherein the tongue and groove are provided with substantially Additional locking part for locking in said horizontal direction. Preferably, the locking portion comprises a protrusion on the underside of the tongue and a groove in the lower lip. Such coupling means and locks are known for example from WO 97/47834;
-所述机械联接装置或联接部将所联接到地板面板压靠在彼此上,例如是由于这些机械联接装置设有从EP 1026341已知的所谓的预紧装置。使得地板面板压靠在彼此上或朝向彼此压靠的张力可以例如借助下唇与上述特征相组合而获得,所述下唇在联接位置向外弯曲并且当试图弹回时压靠在舌部的下侧上;- said mechanical couplings or couplings press the coupled floor panels against each other, for example due to the fact that these mechanical couplings are provided with so-called pretensioning devices known from EP 1026341 . The tension that causes the floor panels to press against each other or towards each other can be obtained, for example, by means of a lower lip in combination with the above-mentioned features, which bends outwards in the coupling position and presses against the tongue when trying to spring back. on the lower side;
-所述机械联接装置允许借助面板朝向彼此地水平移动或准水平移动而进行联接;- said mechanical coupling means allow coupling by means of a horizontal or quasi-horizontal movement of the panels towards each other;
-所述机械联接装置允许借助沿着相应边缘的转动W而进行联接;- said mechanical coupling means allow coupling by means of a rotation W along the respective edge;
-所述机械联接装置允许借助凸出联接部向下运动到凹入联接部中而进行联接,所述凸出联接部例如具有舌部,所述凹入联接部例如具有槽。借助这种面板,具有随着面板的膨胀或向上挤压而使连接释放的高风险,这是因为在这种情况下沿竖向方向的锁定会变弱;- The mechanical coupling means allow coupling by means of a downward movement of a male coupling part, for example with a tongue, into a female coupling part, for example with a groove. With such panels, there is a high risk of the connection being released as the panel expands or is squeezed upwards, since in this case the locking in the vertical direction is weakened;
-所述机械联接装置或至少所述上边缘借助旋转铣刀的铣削操作而实现。- said mechanical coupling means or at least said upper edge is realized by means of a milling operation of a rotary milling cutter.
优选地,所述联接装置基本在所述基板中实现,尤其是在根据本发明包括松散纤维的所述层中实现。优选地,所述联接装置借助旋转铣刀的铣削操作而提供。优选地,本发明的地板面板涉及长方形或正方形的矩形面板,其设有在两对相对边缘上的机械联接装置。Preferably, said coupling means are realized substantially in said substrate, in particular in said layer comprising loose fibers according to the invention. Preferably, said coupling means are provided by means of a milling operation of a rotary milling cutter. Preferably, the floor panels of the present invention relate to rectangular or square rectangular panels provided with mechanical coupling means on two pairs of opposite edges.
设有联接装置的面板的厚度优选地是2.5毫米,更好是3毫米。由于所述独立纤维的存在,也可以在4毫米或更薄的面板中提供可靠的联接装置。由于所获得的面板尺寸稳定性较高,因此联接装置应力较小并且可以做得更小。The thickness of the panels provided with the coupling means is preferably 2.5 mm, better 3 mm. Thanks to the presence of said individual fibers, reliable coupling means can also be provided in panels of 4 mm or less. Due to the higher dimensional stability of the panels obtained, the coupling means are less stressed and can be made smaller.
本发明可以用于在其边缘处没有联接装置的面板,其中这些面板继而用于以其下侧粘合至下部表面。这种面板的厚度优选地小于4毫米,但优选地大于1.5毫米。The invention can be used for panels without coupling means at their edges, wherein these panels are then intended to be glued with their undersides to a lower surface. The thickness of such panels is preferably less than 4 mm, but preferably greater than 1.5 mm.
本发明的面板的宽度优选地是8厘米或更大。尤其优选的尺寸是宽度在14与22厘米之间并且长度在118与220厘米之间。清楚的是这涉及面板形部件并且因而不涉及墙到墙的地板覆盖物。但面板形部件不必是刚性的,而可以是能卷起的。本发明尤其涉及厚板形式或板砖形式的所谓的LVT(豪华乙烯基板砖)。The width of the panels of the invention is preferably 8 cm or more. Particularly preferred dimensions are widths between 14 and 22 centimeters and lengths between 118 and 220 centimeters. It is clear that this concerns panel-shaped parts and thus not wall-to-wall floor coverings. However, the panel-shaped member need not be rigid, but may be rollable. The invention relates in particular to so-called LVT (luxury vinyl tiles) in the form of slabs or tiles.
当在具有重量百分比为20的塑化剂的软PVC中使用长度为3.2毫米的独立E玻璃纤维时,发明人已经发现,从20℃加热到120℃,仅膨胀0.05%,而对于没有应用独立纤维的类似样品,膨胀了0.35%。对于冷却而言,也发现了类似的收缩值。When using individual E-glass fibers with a length of 3.2 mm in soft PVC with 20 weight percent plasticizer, the inventors have found that heating from 20°C to 120°C expands only 0.05%, whereas for no application independent A similar sample of fiber was expanded by 0.35%. Similar shrinkage values were also found for cooling.
根据独立的第二方面,本发明还涉及可以用于制造面板的方法,所述面板具有本发明的第一方面或其优选实施例的特征,但也可以更广泛地应用。为此,本发明设计一种用于制造面板的方法,其中所述方法至少包括形成热塑性材料的层的步骤,其特征在于,所形成的层包括优选地长度大于1毫米的独立纤维。According to an independent second aspect, the present invention also relates to a method which may be used for the manufacture of panels having the features of the first aspect of the invention or preferred embodiments thereof, but which may also be applied more generally. To this end, the invention contemplates a method for the manufacture of panels, wherein said method comprises at least the step of forming a layer of thermoplastic material, characterized in that the formed layer comprises individual fibers preferably having a length greater than 1 mm.
根据尤其优选的实施例,所述层形成在所述热塑性材料的颗粒物的基础上。优选地,颗粒物的颗粒包括重量百分比为至少50或重量百分比为60至80的填料,诸如白垩。该颗粒物例如可以散布或通过其他方式沉积在下部表面上,然后所述颗粒物借助优选的加热的挤压处理合并成热塑性层。根据最优选的实施例,颗粒物沉积或者可以散布在输送装置上,并且在连续挤压装置的带之间被引导,在此进行合并或至少开始合并。根据该具体的优选实施例,为此可以应用诸如从WO 2012/016916得知的装置。优选地,所述颗粒物的平均颗粒物尺寸是1至3毫米,或者是大约2毫米。根据具体实施例,使用所谓的微颗粒物或平均颗粒物尺寸小于1毫米的颗粒物,例如大约800微米的颗粒物。可以应用小于350微米的颗粒物,或者甚至更好是100微米和小于100微米的颗粒物。这种小颗粒物优选地不是仅通过破碎较大颗粒物而获得,而是通过凝固热塑性材料而获得。凝固因而将例如通过在液体中淬火(英文:quenching)而进行。用于形成颗粒物的该特定技术使得所获得的颗粒物的颗粒物形状更接近球形。通过利用可以通过凝固获得的小于1毫米的颗粒物或微颗粒物,可以获得相应热塑性层的更均匀的成分。本发明的独立纤维当位于基于这种颗粒物的层中时将具有更好的效果。According to a particularly preferred embodiment, said layer is formed on the basis of particles of said thermoplastic material. Preferably, the particles of the particulate matter comprise at least 50 weight percent or 60 to 80 weight percent filler, such as chalk. The particles can, for example, be dispersed or otherwise deposited on the lower surface, whereupon said particles are consolidated into a thermoplastic layer by means of a preferably heated extrusion process. According to the most preferred embodiment, the particle deposits can either be spread on the conveying device and guided between the belts of the continuous pressing device, where the consolidation takes place or at least begins to consolidate. According to this particular preferred embodiment, a device such as is known from WO 2012/016916 can be applied for this purpose. Preferably, the particles have an average particle size of 1 to 3 mm, or approximately 2 mm. According to a particular embodiment, so-called microparticles or particles with an average particle size of less than 1 millimeter, for example particles of about 800 micrometers, are used. Particles smaller than 350 microns, or even better, 100 microns and smaller, may be used. Such small particles are preferably obtained not only by crushing larger particles, but by solidifying the thermoplastic material. Solidification will thus take place, for example, by quenching in the liquid. This particular technique for forming the granules results in a more spherical granule shape of the obtained granules. A more homogeneous composition of the corresponding thermoplastic layer can be obtained by using particles or microparticles of less than 1 mm which can be obtained by coagulation. The individual fibers of the present invention will be more effective when located in such particulate based layers.
所述独立纤维也可以被散布或合并在所散布的颗粒物的颗粒中。The individual fibers may also be interspersed or incorporated within particles of the interspersed particulate matter.
当最终层不包括任何独立纤维时,使用上述微颗粒物也是具有优点的。因此,本发明根据具体独立方面还涉及用于制造面板的方法,该方法至少包括形成热塑性材料的层的步骤,其特征在于,所述层基于所述热塑性材料的散布颗粒物而形成并且所述颗粒物的平均颗粒物尺寸小于1mm,并且更好是小于350微米或更小,或者是100微米或更小。优选地,所述平均颗粒物尺寸大于25微米,以便避免颗粒物结块并且保持颗粒物良好的流动性。清楚的是这种方法具有优选实施例,其对应于所述第二方面的方法的优选实施例,而不必应用独立纤维。清楚的是优选地将软PVC用作热塑性材料,并且相应的热塑性层优选地包括填料,诸如白垩或石灰。这些填料可以或可以不经由相应的颗粒物来提供。优选地,所述颗粒物包括多于百分之50重量的填料或者更好百分之60与80之间重量的填料,例如大约百分之70或72重量的填料。通过应用高填充的颗粒物,可以实现填料在层中较好的分布,并且获得平稳的制造过程。还清楚的是该方法可以用于制造与所述第一方面或其优选实施例类似的地板面板,而不必应用所述独立纤维。The use of such microparticles is also advantageous when the final layer does not comprise any individual fibers. Therefore, the present invention also relates, according to a specific independent aspect, to a method for manufacturing panels comprising at least the step of forming a layer of thermoplastic material, characterized in that said layer is formed on the basis of dispersed particles of said thermoplastic material and said particles The average particle size is less than 1 mm, and more preferably less than 350 microns or less, or 100 microns or less. Preferably, the average particle size is greater than 25 microns, so as to avoid particle agglomeration and maintain good fluidity of the particles. It is clear that this method has preferred embodiments which correspond to the preferred embodiments of the method of said second aspect without necessarily applying individual fibers. It is clear that soft PVC is preferably used as thermoplastic material and that the corresponding thermoplastic layer preferably comprises fillers such as chalk or lime. These fillers may or may not be provided via corresponding particulates. Preferably, the particulate matter comprises more than 50% by weight filler or better still between 60 and 80% by weight filler, such as about 70 or 72% by weight filler. By using highly filled particles, a better distribution of the filler in the layer can be achieved and a smooth manufacturing process can be achieved. It is also clear that the method can be used to manufacture floor panels similar to said first aspect or its preferred embodiments without having to apply said individual fibers.
根据第二方面的另一个实施例,所述层基于挤压的热塑性材料而形成。在此这可以涉及例如借助所谓的Banbury混合器(Kobe Steel公司)获得到材料,其中相应热塑性材料的颗粒物被揉制,其中例如在至少一套辊之间处被揉制的材料被挤压成层。在此,产生纤维在混合期间被破碎的风险。According to another embodiment of the second aspect, said layer is formed based on extruded thermoplastic material. This can involve, for example, obtaining the material by means of a so-called Banbury mixer (Kobe Steel company), in which granules of the corresponding thermoplastic material are kneaded, wherein the kneaded material is extruded, for example, between at least one set of rollers Floor. Here, the risk arises that the fibers are broken during mixing.
还根据上述两个尤其优选的实施例,所述颗粒物还优选地包括所述独立纤维的至少一部分,优选地是玻璃纤维。Also according to the above two particularly preferred embodiments, said particulate matter also preferably comprises at least a portion of said individual fibers, preferably glass fibres.
明显的是在上述步骤中所获得的层必须与在所述层中或不在所述层中的其他材料一起处理,以形成最终面板。还可以首先获得板材或片材,由此通过将其细分而获得多块这种面板。It is obvious that the layer obtained in the above steps must be processed together with other materials, whether present in said layer or not, in order to form the final panel. It is also possible to first obtain a board or sheet, whereby by subdividing it a plurality of such panels is obtained.
通常可以通过多种方式处理相应的层。根据第一可行方案,借助加热并挤压,相应的层至少在表面处与诸如印刷装饰膜和/或耐磨层和/或另一基层的一个或多个其它热塑性层熔合到一起。根据第二可行方案,一个或多个其它材料层、尤其是一个或多个其它基层通过对其压延或以其他方式将其提供在已形成的层上而以液体形式或膏形式提供。根据第三可行方案,根据本发明包括纤维的层设置在已形成的其它层上,例如在玻璃纤维网上或在玻璃纤维布上,和/或在另一个已形成的基板层上。The corresponding layer can usually be handled in several ways. According to a first possibility, the respective layer is fused together at least at the surface with one or more other thermoplastic layers, such as a printed decorative film and/or a wear layer and/or a further base layer, by means of heating and pressing. According to a second possibility, one or more further material layers, in particular one or more further base layers, are provided in liquid form or in paste form by calendering them or otherwise providing them on an already formed layer. According to a third possibility, the layer comprising fibers according to the invention is arranged on other already formed layers, for example on a glass fiber mesh or on a glass fiber cloth, and/or on another already formed substrate layer.
优选地,本发明的方法包括在相应的层中提供玻璃纤维层的步骤,优选地是玻璃纤维网或“无纺布”。Preferably, the method of the invention comprises the step of providing a layer of glass fibres, preferably a glass fiber mesh or "nonwoven", in a corresponding layer.
应注意,透明耐磨层当施加时优选地没有诸如玻璃纤维的纤维。当利用装饰膜时,其也优选地没有这种独立纤维,无论是否是层的形式。对于装饰膜,优选地应用印刷硬PVC膜,即,没有或几乎没有塑化剂的PVC膜。使用硬PVC膜会得到高质量的印刷,这是因为在印刷期间较少经受尺寸变化。当在印刷期间借助供热进行一个或多个干燥处理时,这是尤其有利的,当用水基着色墨水时将是这种情况。对于透明耐磨层,可以使用软PVC层,例如具有重量百分比为12或更多的塑化剂。It should be noted that the transparent wear layer is preferably free of fibers such as glass fibers when applied. When a decorative film is utilized, it is also preferably free of such individual fibers, whether in the form of a layer or not. For decorative films, preferably printed rigid PVC films are applied, ie PVC films with no or little plasticizer. The use of a rigid PVC film results in high quality printing, since it is less subject to dimensional changes during printing. This is particularly advantageous when one or more drying processes are carried out by means of heat supply during printing, as will be the case with water-based pigmented inks. For the transparent wear layer, a soft PVC layer can be used, for example with 12 weight percent or more of plasticizer.
根据第三独立方面,本发明还涉及可以应用于所述第二方面和/或其优选实施例的方法的材料。为此,本发明涉及用于形成热塑性材料的颗粒物,其中该颗粒物除了相应热塑性材料之外还包括玻璃纤维,该玻璃纤维的平均长度优选地大于1mm,并且更好是3毫米或更长。所述颗粒物可以包括填料,诸如石灰或白垩。在这种情况下,所述颗粒物优选地包括重量百分比为至少50或从60至80的填料,诸如白垩。According to a third independent aspect, the invention also relates to a material that can be applied to the method of said second aspect and/or its preferred embodiments. To this end, the present invention relates to a granulate for forming a thermoplastic material, wherein the granulate comprises, besides the corresponding thermoplastic material, glass fibers, the average length of which glass fibers is preferably greater than 1 mm, and better still 3 mm or more. The particulate matter may include fillers such as lime or chalk. In this case, the particulate matter preferably comprises at least 50 or from 60 to 80 weight percent filler, such as chalk.
清楚的是热塑性材料还可以具有在第一方面中陈述的成分。优选地,热塑性材料涉及用于形成半刚性或软PVC的原料。优选地,该PVC包括塑化剂的量的重量百分比大于12,例如20或更大的重量百分比。It is clear that the thermoplastic material can also have the composition stated in the first aspect. Preferably, the thermoplastic material relates to the raw material used to form semi-rigid or soft PVC. Preferably, the PVC comprises plasticizer in an amount greater than 12 weight percent, such as 20 or more weight percent.
应理解,根据本发明,“基板”意味着地板面板自身的内层,其可以由单层或多层构成,但其中相应的层的总厚度优选地大于所述面板总厚度的一半,并且/或者其中所述相应层的总重量优选地大于所述地板的总重量的一半。优选地,可能的联接装置的轮廓基本或完全在基板中实现。It will be understood that, according to the present invention, "substrate" means the inner layer of the floor panel itself, which may consist of a single layer or multiple layers, but wherein the total thickness of the respective layers is preferably greater than half the total thickness of said panel, and/ Or wherein the total weight of said respective layers is preferably more than half of the total weight of said floor. Preferably, the contours of possible coupling means are substantially or completely realized in the base plate.
而且,应理解,“纤维”意味着长形颗粒物。优选地,这种纤维的长度至少是其平均直径的一百倍。优选地,这涉及具有圆形或大致圆形横截面的纤维。Also, it should be understood that "fiber" means elongated particles. Preferably, the length of such fibers is at least one hundred times their average diameter. Preferably, this involves fibers having a circular or approximately circular cross-section.
附图说明Description of drawings
为了较好地示出本发明的特征,下文将参照附图描述作为非限制性示例的一些优选实施例,其中:In order to better illustrate the characteristics of the invention, some preferred embodiments will be described below as non-limiting examples with reference to the accompanying drawings, in which:
图1示出具有本发明的特征的面板;Figure 1 shows a panel with the features of the invention;
图2以较大比例示出按照图1中的线II-II的横截面;Figure 2 shows a cross-section according to line II-II in Figure 1 on a larger scale;
图3示意性地示出在具有所述第二方面的特征的方法中的一些步骤。Figure 3 schematically illustrates some steps in a method having features of said second aspect.
具体实施方式detailed description
图1示出矩形和长方形地板面板1,其具有一对长边2-3和一对短边4-5。Figure 1 shows a rectangular and oblong floor panel 1 having a pair of long sides 2-3 and a pair of short sides 4-5.
图2示出相应的地板面板1由各层6-7-8-9-10构成。Figure 2 shows that a corresponding floor panel 1 is made up of layers 6-7-8-9-10.
基板11由热塑性材料的层9形成,所述热塑性材料在这种情况下是软PVC,其包括诸如玻璃纤维的独立纤维。相应的基板层9还包括内嵌的玻璃纤维网12。在相应的层9上设有顶层13,其包括印刷装饰层7和基于热塑性材料的透明耐磨层6。顶层13还包括位于装饰膜7下面的背衬层8。在该示例中,背衬层8、装饰膜7和耐磨层6是基于聚氯乙稀制成的。优选地,装饰膜7制成为印刷硬PVC膜,而耐磨层6和可能的可选背衬层8优选地基于软PVC实现,即,具有重量百分比为12或更多的塑化剂的量。The substrate 11 is formed by a layer 9 of thermoplastic material, in this case soft PVC, comprising individual fibers such as glass fibres. The corresponding substrate layer 9 also includes an embedded glass fiber mesh 12 . On the corresponding layer 9 there is provided a top layer 13 comprising a printed decoration layer 7 and a transparent wear layer 6 based on a thermoplastic material. The top layer 13 also includes a backing layer 8 located below the decorative film 7 . In this example, the backing layer 8 , the decorative film 7 and the wear layer 6 are based on polyvinyl chloride. Preferably, the decorative film 7 is made as a printed hard PVC film, while the wear layer 6 and possible optional backing layer 8 are preferably realized based on soft PVC, i.e. with an amount of plasticizer of 12 weight percent or more .
在该示例中,装饰膜7设有带木纹图案14的印刷部,其中每块面板1每次都提供单个木板的图像。In this example, the decorative film 7 is provided with a print with a wood grain pattern 14, wherein each panel 1 provides an image of a single wood board at a time.
在基板11的下侧15上,设有也基于软PVC的相对层10。On the underside 15 of the substrate 11 there is provided an opposing layer 10 also based on soft PVC.
图2示出所述层9至少在基板11的厚度T的中间中。在这种情况下,相应的层9形成整个基板11。FIG. 2 shows that said layer 9 is at least in the middle of the thickness T of the substrate 11 . In this case, the corresponding layer 9 forms the entire substrate 11 .
图2还示出包括独立纤维的相应的层9构成面板1的厚度T的至少百分之40并且在此甚至大于该厚度的一半。FIG. 2 also shows that the respective layer 9 comprising individual fibers constitutes at least 40 percent and here even more than half of the thickness T of the panel 1 .
而且,该示例的面板1设有在相对边缘2-3上的机械联接装置或联接部16。图2示出至少一对长边缘2-3上的机械联接装置16允许两块这种地板面板1联接至彼此,使得在与所联接的面板1的平面垂直的竖向方向V1上以及在与所联接的边缘2-3垂直的水平方向H1上和在面板1的平面中产生锁定。所示联接装置16的特征在于其基本实现为由上唇19和下唇20界定的槽18和舌部17,其中所述舌部17和槽18基本用于沿所述竖向方向V1进行锁定,并且其中所述舌部17和槽18设有额外的锁定部21-22,基本用于沿所述水平方向H1进行锁定。在这种情况下,锁定部包括在舌部17下侧上的凸起21和在下唇20中的与其配合的凹槽22。Furthermore, the panel 1 of this example is provided with mechanical coupling means or couplings 16 on opposite edges 2-3. Figure 2 shows that mechanical coupling means 16 on at least one pair of long edges 2-3 allow two such floor panels 1 to be coupled to each other such that in a vertical direction V1 perpendicular to the plane of the coupled panels 1 and in a The joined edges 2 - 3 are locked in the vertical horizontal direction H1 and in the plane of the panel 1 . The coupling device 16 shown is characterized in that it is substantially realized as a groove 18 delimited by an upper lip 19 and a lower lip 20 and a tongue 17, wherein said tongue 17 and groove 18 are substantially intended for locking in said vertical direction V1, And wherein said tongue portion 17 and groove 18 are provided with additional locking portions 21-22, basically for locking along said horizontal direction H1. In this case, the locking portion comprises a protrusion 21 on the underside of the tongue 17 and a cooperating groove 22 in the lower lip 20 .
在此示出的联接装置16允许至少通过沿相应边缘2-3的转动W而进行联接。The coupling device 16 shown here allows coupling at least by turning W along the respective edge 2 - 3 .
机械联接装置16基本在层9中实现,其根据本发明包括独立纤维。在该示例中,它们通过铣削处理提供,例如通过旋转刀具提供。The mechanical coupling means 16 are substantially realized in the layer 9, which according to the invention comprises individual fibers. In this example, they are provided by a milling process, for example by a rotating tool.
图3示出用于制造图1和2的面板的方法的一些步骤。更具体地,所述步骤示出为用热塑性材料形成所述层9,其根据本发明包括独立纤维。FIG. 3 shows some steps of a method for manufacturing the panel of FIGS. 1 and 2 . More specifically, said steps are shown for forming said layer 9 from a thermoplastic material comprising individual fibers according to the invention.
在图3的示例中,相应层9基于相应的热塑性材料的颗粒物23形成。在此,这涉及具有所述第三方面的特征的颗粒物23,其中所述颗粒物也包括玻璃纤维。In the example of FIG. 3 , the respective layer 9 is formed based on particles 23 of a respective thermoplastic material. In this case, this is a granulate 23 having the features of the third aspect, wherein the granulate also comprises glass fibers.
图3示出颗粒物23开始在输送装置25上分别借助散布装置24沉积,然后在连续挤压装置17的带26之间被合并。在此,颗粒物23沿着一个或多个加热装置28被传送并且其可以在积压处理之后或在积压处理结束时再次被冷却。通过冷却,获得了挤压的板材、片材或层可以较快用于进一步处理。FIG. 3 shows that the particles 23 are initially deposited on the conveying device 25 by means of the spreading device 24 and then merged between the belts 26 of the continuous pressing device 17 . In this case, the particulate matter 23 is conveyed along one or more heating devices 28 and it can be cooled again after the stacking process or at the end of the stacking process. By cooling, the extruded plates, sheets or layers obtained are relatively quickly available for further processing.
图3还示出可以与挤压同时地通过在挤压处理中在颗粒物23上或颗粒物之间设置另一层而将其施加或插入,在这种情况下,所述另一层是玻璃纤维层12。这可以如上所述涉及例如玻璃纤维层12或背衬层8、装饰膜7或耐磨层6。其还可以涉及已经层压在一起的组合层,例如已经完全或部分地复合的顶层3,其例如包括至少装饰膜7和耐磨层6,或者至少背衬层8和装饰膜7;或者背衬层8、装饰膜7以及背衬层6。优选地在积压处理之后提供可能的表面漆层。这在此未示出。根据另一个未示出的可行方案,在颗粒物23已经至少部分地被挤压、优选地已经被至少积压成粘着整体之后,设置至少装饰膜7或耐磨层6或者可以是二者的组合。在后者情况下,基于颗粒物已经挤压的层优选地在其余层6-7设置在其上之前被研磨。为了提供装饰膜7和/或耐磨层6,优选地再次利用连续挤压装置。代替研磨处理,还可以例如借助塑溶胶进行调平。Figure 3 also shows that it can be applied or inserted simultaneously with the extrusion by placing another layer on or between the particles 23 during the extrusion process, in this case glass fiber Layer 12. This can involve, for example, the glass fiber layer 12 or the backing layer 8 , the decorative film 7 or the wear layer 6 as described above. It may also involve composite layers that have been laminated together, such as a top layer 3 that has been fully or partially composited, for example comprising at least a decorative film 7 and a wear layer 6, or at least a backing layer 8 and a decorative film 7; Lining layer 8 , decorative film 7 and backing layer 6 . A possible surface lacquer layer is preferably provided after the backlog treatment. This is not shown here. According to another possibility not shown, after the particles 23 have been at least partially compressed, preferably at least packed into a cohesive whole, at least the decorative film 7 or the wear-resistant layer 6 is provided or may be a combination of both. In the latter case, the already extruded layer based on particulate matter is preferably ground before the remaining layers 6 - 7 are placed thereon. In order to provide the decorative film 7 and/or the wear layer 6, preferably a continuous extrusion device is again used. Instead of grinding, it is also possible, for example, to carry out leveling with the aid of plastisols.
本发明不限于在此所述的实施例;相反,这种面板、方法和颗粒物可以根据各种变型而实现,而不脱离本发明的范围。而且,所述面板代替作为地板面板也可以实现为墙壁面板或天花板面板或者甚至是家具面板。The invention is not limited to the embodiments described here; rather, such panels, methods and granules can be realized according to various modifications without departing from the scope of the invention. Furthermore, instead of being a floor panel, the panel can also be realized as a wall or ceiling panel or even as a furniture panel.
Claims (14)
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| BE2012/0370 | 2012-06-01 | ||
| BE201200370A BE1020739A3 (en) | 2012-06-01 | 2012-06-01 | PANEL FOR FORMING A FLOOR COATING, METHOD FOR MANUFACTURING SUCH PANELS AND GRANULATE USED HEREIN. |
| BE2012/0474 | 2012-07-06 | ||
| BE201200474A BE1020722A3 (en) | 2012-06-01 | 2012-07-06 | PANEL FOR FORMING A FLOOR COVERING AND METHOD FOR MANUFACTURING SUCH PANELS. |
| PCT/IB2013/054480 WO2013179260A1 (en) | 2012-06-01 | 2013-05-30 | Panel for forming a floor covering, method for manufacturing such panels and granulate applied herewith. |
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| CN104428475A CN104428475A (en) | 2015-03-18 |
| CN104428475B true CN104428475B (en) | 2017-07-04 |
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| CN201380036383.1A Active CN104619936B (en) | 2012-06-01 | 2013-05-30 | Panel for forming a floor covering and method for manufacturing such a panel |
| CN201810130912.9A Active CN108222413B (en) | 2012-06-01 | 2013-05-30 | Panels for forming floor coverings |
| CN201380036382.7A Active CN104428475B (en) | 2012-06-01 | 2013-05-30 | For forming the panel of floor covering, the method for manufacturing this panel and the particulate matter for the panel |
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| CN201380036383.1A Active CN104619936B (en) | 2012-06-01 | 2013-05-30 | Panel for forming a floor covering and method for manufacturing such a panel |
| CN201810130912.9A Active CN108222413B (en) | 2012-06-01 | 2013-05-30 | Panels for forming floor coverings |
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| PT (3) | PT3351703T (en) |
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