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CH684796A5 - Method of protection for ensuring the longevity of concrete structures - Google Patents

Method of protection for ensuring the longevity of concrete structures Download PDF

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Publication number
CH684796A5
CH684796A5 CH190492A CH190492A CH684796A5 CH 684796 A5 CH684796 A5 CH 684796A5 CH 190492 A CH190492 A CH 190492A CH 190492 A CH190492 A CH 190492A CH 684796 A5 CH684796 A5 CH 684796A5
Authority
CH
Switzerland
Prior art keywords
concrete
impregnation
solution
protection
impregnating
Prior art date
Application number
CH190492A
Other languages
French (fr)
Inventor
Philippe Sarrasin
Original Assignee
Sarrasin Ingenieurs S A
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sarrasin Ingenieurs S A filed Critical Sarrasin Ingenieurs S A
Priority to CH190492A priority Critical patent/CH684796A5/en
Publication of CH684796A5 publication Critical patent/CH684796A5/en

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Classifications

    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/009After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone characterised by the material treated
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/45Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
    • C04B41/50Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
    • C04B41/5018Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials with fluorine compounds
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/45Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
    • C04B41/50Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
    • C04B41/5076Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials with masses bonded by inorganic cements
    • C04B41/5089Silica sols, alkyl, ammonium or alkali metal silicate cements
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/60After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only artificial stone
    • C04B41/61Coating or impregnation
    • C04B41/65Coating or impregnation with inorganic materials
    • C04B41/66Fluorides, e.g. ocratation
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/60After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only artificial stone
    • C04B41/61Coating or impregnation
    • C04B41/65Coating or impregnation with inorganic materials
    • C04B41/68Silicic acid; Silicates
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/20Resistance against chemical, physical or biological attack

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Aftertreatments Of Artificial And Natural Stones (AREA)

Abstract

A process for protection intended to ensure the longevity of structures made of concrete, by an economical impregnation system which is easy to produce, controllable and renewable, improving especially the hardness and the leaktightness of surface mortars with the aid of hydrofluoric acid salts or of alkali metal silicates etc.

Description

1 1

CH 684 796 A5 CH 684 796 A5

2 2

Description Description

Les dégradations des constructions en béton armé conduisent souvent à de très coûteux assainissements. The deterioration of reinforced concrete constructions often leads to very costly remediation.

Sans parler des effets destructeurs de certains agents agressifs spécifiques, la simple exposition aux agents climatiques ordinaires suffit à provoquer des phénomènes de corrosion des armatures lorsque celles-ci ne sont pas suffisamment protégées. La couverture basique du béton original peut être amoindrie par la carbonatation. La chaux libre contenue dans le ciment portland ordinaire disparaît alors progressivement et, à terme, les armatures sont exposées à la rouille comme tout fer non protégé. Le béton carbonaté devient aussi de plus en plus poreux et, par là même, de plus en plus sensible aux agressions du milieu ambiant. Without speaking about the destructive effects of certain specific aggressive agents, the simple exposure to ordinary climatic agents is enough to cause corrosion phenomena of the reinforcements when these are not sufficiently protected. The basic cover of the original concrete can be reduced by carbonation. The free lime contained in ordinary portland cement then gradually disappears and, in the long term, the reinforcements are exposed to rust like any unprotected iron. Carbonated concrete also becomes more and more porous and, by the same token, more and more sensitive to attacks from the surrounding environment.

Ce phénomène peut être rapide si la couverture de béton sur les fers est faible, si le béton n'est pas très compact ou si les sollicitations du milieu sont très contraignantes. This phenomenon can be rapid if the concrete cover on the irons is weak, if the concrete is not very compact or if the stresses of the medium are very restrictive.

Il importe donc d'assurer la LONGEVITE de la construction en béton. Comme on ne peut pratiquement souvent pas garantir la qualité et la constance de l'exécution en tous points de la construction et comme l'on n'est - la plupart du temps - pas maître des caractéristiques du milieu environnant, on tend de plus en plus à protéger la surface du béton par des enduits ou peintures diverses, voire par des isolations ou des bardages. It is therefore important to ensure LONGEVITY in concrete construction. As one can practically often not guarantee the quality and the constancy of the execution in all points of the construction and as one is - most of the time - not master of the characteristics of the surrounding environment, one tends more and more more to protect the surface of the concrete by various plasters or paints, even by insulations or cladding.

La plupart de ces procédés sont très coûteux. Certains d'entre eux sont encore mal connus et leur durabilité demeure sujette à caution. D'autres enfin, en dissimulant le parement du béton, ne permettent pas de surveiller de manière suivie l'état de la structure elle-même. Most of these methods are very expensive. Some of them are still poorly understood and their durability remains questionable. Others, by concealing the concrete facing, do not allow monitoring the condition of the structure itself.

La présente invention permet d'améliorer sensiblement la qualité de la surface des bétons en créant un parement renforcé, résistant beaucoup mieux aux agressions du milieu extérieur. Elle offre en outre l'avantage: The present invention makes it possible to appreciably improve the quality of the surface of concrete by creating a reinforced facing, much better resistant to attack by the external environment. It also offers the advantage:

- d'être très économique - to be very economical

- de pouvoir être appliquée facilement - to be easy to apply

- de permettre une surveillance constante des surfaces traitées laissées apparentes - to allow constant monitoring of the treated surfaces left visible

- de pouvoir être renouvelée à terme, lorsque cela devient nécessaire (en général une dizaine d'années, dans des conditions normales, à l'extérieur). - to be able to be renewed in the long term, when it becomes necessary (generally around ten years, under normal conditions, outside).

Selon la présente invention, on procède, après préparation du support, à une imprégnation transparente, en plusieurs phases successives (3 en général), distantes de 24 heures si possible, de la surface de béton à protéger par une solution (à 1/3 environ) de sels d'acides fluorhydriques ou sels fluosiliciques de magnésie MgSiF6 ou de silicates alcalins (verre soluble 38° Bé). Le parement ainsi traité doit être rincé à l'eau claire après les premières applications et lavé à grande eau (mais sans pression) après la dernière. According to the present invention, after preparation of the support, a transparent impregnation is carried out, in several successive phases (3 in general), 24 hours apart if possible, from the concrete surface to be protected by a solution (1/3 approximately) of hydrofluoric acid salts or fluosilicic salts of magnesia MgSiF6 or of alkali silicates (water glass 38 ° Bé). The siding thus treated must be rinsed with clean water after the first applications and washed with plenty of water (but without pressure) after the last.

Les recherches et les expériences du Professeur Sarrasin ont montré que la combinaison de l'imprégnation préconisée et des mortiers forme une couche en surface du béton pratiquement insoluble, de grande dureté et présentant une très bonne résistance aux agressions chimiques courantes. Professor Sarrasin's research and experience have shown that the combination of the recommended impregnation and mortars forms a surface layer of practically insoluble concrete, of great hardness and with very good resistance to common chemical attack.

Ce procédé convient pour protéger des parements extérieurs comme pour améliorer l'étanchéité du béton et la résistance aux lessives, acides ou huiles, des dalles de plancher, par exemple. Dans ce dernier cas, on peut enregistrer aisément la consommation très faible du produit d'imprégnation, qui doit être, pour un support en bon état, de 0,12 à 0,25 litre par m2. This process is suitable for protecting exterior siding as for improving the waterproofness of concrete and the resistance to detergents, acids or oils, for example floor slabs. In the latter case, one can easily record the very low consumption of the impregnation product, which must be, for a support in good condition, from 0.12 to 0.25 liters per m2.

Les surfaces de béton neuves doivent être traitées le plus tôt possible après la prise du béton. Les surfaces anciennes ou sales doivent être nettoyées à fond, puis rincées à l'eau froide et bien séchées avant le traitement. New concrete surfaces should be treated as soon as possible after setting the concrete. Old or dirty surfaces should be cleaned thoroughly, then rinsed in cold water and thoroughly dried before treatment.

Avant l'imprégnation, on brossera soigneusement toutes les surfaces à traiter et on les lavera à grande eau pour éliminer la poussière qui empêcherait la pénétration de l'imprégnation et nuirait à l'adhérence entre la solution et le béton. Before impregnation, all the surfaces to be treated will be carefully brushed and washed with plenty of water to remove the dust which would prevent the penetration of the impregnation and adversely affect the adhesion between the solution and the concrete.

L'imprégnation peut être aisément réalisée par un personnel soigneux, mais sans qualifications particulières, à l'aide de brosses ou de pinceaux, par exemple. On peut aussi envisager d'autres modes d'application, faisant appel à des techniques de projection, si l'importance des surfaces à traiter le justifie. Impregnation can be easily carried out by careful personnel, but without any particular qualifications, using brushes or paintbrushes, for example. We can also consider other modes of application, using projection techniques, if the size of the surfaces to be treated justifies it.

Pendant le traitement, les opérateurs devront porter des vêtements protecteurs et en tout cas des lunettes adéquates. Les fenêtres ou ouvertures non traitées seront masquées ou enduites d'un film gras permettant le nettoyage ultérieur. During treatment, operators must wear protective clothing and in any case suitable glasses. Untreated windows or openings will be masked or coated with a greasy film allowing subsequent cleaning.

Claims (8)

RevendicationsClaims 1. Procédé de protection des surfaces de béton, améliorant l'étanchéité, la dureté superficielle et la résistance aux agressions climatiques et chimiques, caractérisé en ce que la protection est obtenue par l'imprégnation du béton par une solution de sels de l'acide fluorhydrique.1. A method of protecting concrete surfaces, improving sealing, surface hardness and resistance to climatic and chemical attack, characterized in that protection is obtained by impregnating the concrete with a solution of acid salts hydrofluoric. 2. Procédé selon la revendication 1, caractérisé en ce que la protection est obtenue par l'imprégnation du béton par une solution de sels fluosiliciques de magnésie de formule MgSiF6.2. Method according to claim 1, characterized in that the protection is obtained by impregnating the concrete with a solution of fluosilicon salts of magnesia of formula MgSiF6. 3. Procédé de protection des surfaces de béton, améliorant l'étanchéité, la dureté superficielle et la résistance aux agressions climatiques et chimiques, caractérisé en ce que la protection est obtenue par l'imprégnation du béton par une solution de silicates alcalins, verre soluble 38° Be.3. Method for protecting concrete surfaces, improving sealing, surface hardness and resistance to climatic and chemical attack, characterized in that protection is obtained by impregnating the concrete with a solution of alkali silicates, soluble glass 38 ° Be. 4. Procédé selon l'une des revendications précédentes, caractérisé en ce que l'imprégnation est exécutée en 2 ou 3 phases successives, distantes, de préférence, de 24 heures.4. Method according to one of the preceding claims, characterized in that the impregnation is carried out in 2 or 3 successive phases, preferably 24 hours apart. 5. Procédé selon l'une des revendications précédentes, caractérisé en ce que l'imprégnation est précédée d'une préparation du support par brossage, lavage et séchage.5. Method according to one of the preceding claims, characterized in that the impregnation is preceded by a preparation of the support by brushing, washing and drying. 6. Procédé selon l'une des revendications précédentes, caractérisé en ce que l'imprégnation est suivie d'un rinçage à exécuter juste avant son séchage complet.6. Method according to one of the preceding claims, characterized in that the impregnation is followed by a rinsing to be carried out just before its complete drying. 7. Procédé selon l'une des revendications précé-7. Method according to one of the preceding claims - 55 1010 1515 2020 2525 3030 3535 4040 4545 5050 5555 6060 6565 22 33 CH 684 796 A5CH 684 796 A5 dentes, caractérisé en ce que la solution se fait dans une proportion voisine de 1 (sels): 3 (eau).teeth, characterized in that the solution is made in a proportion close to 1 (salts): 3 (water). 8. Procédé selon l'une des revendications précédentes, caractérisé en ce que la quantité de solution à appliquer sur une surface plane est de 0,12 à 0,25 litre par m2, pour chaque imprégnation.8. Method according to one of the preceding claims, characterized in that the amount of solution to be applied to a flat surface is 0.12 to 0.25 liters per m2, for each impregnation. 55 1010 1515 2020 2525 3030 3535 4040 4545 5050 5555 6060 6565 33
CH190492A 1992-06-17 1992-06-17 Method of protection for ensuring the longevity of concrete structures CH684796A5 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CH190492A CH684796A5 (en) 1992-06-17 1992-06-17 Method of protection for ensuring the longevity of concrete structures

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CH190492A CH684796A5 (en) 1992-06-17 1992-06-17 Method of protection for ensuring the longevity of concrete structures

Publications (1)

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CH684796A5 true CH684796A5 (en) 1994-12-30

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1996038396A1 (en) * 1995-06-02 1996-12-05 Stonetec Anstalt/Stonetec Establishment Agent for impregnating stone and shaped stonework or for the production of modelable compounds and compounds containing said agent and mineral solids
RU2461533C1 (en) * 2011-04-22 2012-09-20 Государственное образовательное учреждение высшего профессионального образования "Мордовский государственный университет им. Н.П. Огарева" Composition for saturating concrete and reinforced concrete articles

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1996038396A1 (en) * 1995-06-02 1996-12-05 Stonetec Anstalt/Stonetec Establishment Agent for impregnating stone and shaped stonework or for the production of modelable compounds and compounds containing said agent and mineral solids
RU2461533C1 (en) * 2011-04-22 2012-09-20 Государственное образовательное учреждение высшего профессионального образования "Мордовский государственный университет им. Н.П. Огарева" Composition for saturating concrete and reinforced concrete articles

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