CA2876164A1 - Adsorbants magnetiques, procedes pour fabriquer un adsorbant magnetique, et procedes d'elimination de contaminants de flux de fluide - Google Patents
Adsorbants magnetiques, procedes pour fabriquer un adsorbant magnetique, et procedes d'elimination de contaminants de flux de fluide Download PDFInfo
- Publication number
- CA2876164A1 CA2876164A1 CA2876164A CA2876164A CA2876164A1 CA 2876164 A1 CA2876164 A1 CA 2876164A1 CA 2876164 A CA2876164 A CA 2876164A CA 2876164 A CA2876164 A CA 2876164A CA 2876164 A1 CA2876164 A1 CA 2876164A1
- Authority
- CA
- Canada
- Prior art keywords
- adsorbent
- magnetic
- activated carbon
- iron oxide
- magnetic adsorbent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000003463 adsorbent Substances 0.000 title claims abstract description 168
- 238000000034 method Methods 0.000 title claims description 53
- 238000004519 manufacturing process Methods 0.000 title claims description 15
- 239000000356 contaminant Substances 0.000 title description 15
- 239000012530 fluid Substances 0.000 title description 14
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 196
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims abstract description 68
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 claims description 62
- 229910052753 mercury Inorganic materials 0.000 claims description 60
- 239000012717 electrostatic precipitator Substances 0.000 claims description 32
- 239000000654 additive Substances 0.000 claims description 30
- 239000002245 particle Substances 0.000 claims description 30
- 239000000696 magnetic material Substances 0.000 claims description 27
- 239000010881 fly ash Substances 0.000 claims description 23
- 238000002347 injection Methods 0.000 claims description 22
- 239000007924 injection Substances 0.000 claims description 22
- 238000002156 mixing Methods 0.000 claims description 13
- 230000000996 additive effect Effects 0.000 claims description 12
- 239000011941 photocatalyst Substances 0.000 claims description 12
- 238000002513 implantation Methods 0.000 claims description 11
- 238000011084 recovery Methods 0.000 claims description 10
- 238000003801 milling Methods 0.000 claims description 9
- 239000011230 binding agent Substances 0.000 claims description 8
- 238000000227 grinding Methods 0.000 claims description 7
- 229910052736 halogen Inorganic materials 0.000 claims description 7
- 150000002367 halogens Chemical class 0.000 claims description 7
- 230000000694 effects Effects 0.000 claims description 4
- 238000011282 treatment Methods 0.000 claims description 4
- 238000010531 catalytic reduction reaction Methods 0.000 claims description 3
- 239000002250 absorbent Substances 0.000 claims 4
- 230000002745 absorbent Effects 0.000 claims 4
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N titanium dioxide Inorganic materials O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 43
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical group [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 37
- SZVJSHCCFOBDDC-UHFFFAOYSA-N iron(II,III) oxide Inorganic materials O=[Fe]O[Fe]O[Fe]=O SZVJSHCCFOBDDC-UHFFFAOYSA-N 0.000 description 36
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 22
- 239000003546 flue gas Substances 0.000 description 22
- 239000002131 composite material Substances 0.000 description 20
- 239000000463 material Substances 0.000 description 20
- 229910052742 iron Chemical group 0.000 description 18
- 235000013980 iron oxide Nutrition 0.000 description 18
- 238000002149 energy-dispersive X-ray emission spectroscopy Methods 0.000 description 17
- 239000000047 product Substances 0.000 description 16
- 239000002594 sorbent Substances 0.000 description 14
- JHJLBTNAGRQEKS-UHFFFAOYSA-M sodium bromide Chemical compound [Na+].[Br-] JHJLBTNAGRQEKS-UHFFFAOYSA-M 0.000 description 12
- 230000001590 oxidative effect Effects 0.000 description 9
- 238000001878 scanning electron micrograph Methods 0.000 description 9
- 229910052799 carbon Inorganic materials 0.000 description 8
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 7
- 230000008901 benefit Effects 0.000 description 7
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 7
- 238000011068 loading method Methods 0.000 description 7
- 238000001179 sorption measurement Methods 0.000 description 7
- 238000009826 distribution Methods 0.000 description 6
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- AMXOYNBUYSYVKV-UHFFFAOYSA-M lithium bromide Chemical compound [Li+].[Br-] AMXOYNBUYSYVKV-UHFFFAOYSA-M 0.000 description 4
- IOLCXVTUBQKXJR-UHFFFAOYSA-M potassium bromide Chemical compound [K+].[Br-] IOLCXVTUBQKXJR-UHFFFAOYSA-M 0.000 description 4
- 241000251468 Actinopterygii Species 0.000 description 3
- -1 V02 Inorganic materials 0.000 description 3
- 238000011021 bench scale process Methods 0.000 description 3
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- 229910052595 hematite Inorganic materials 0.000 description 3
- 239000011019 hematite Substances 0.000 description 3
- LIKBJVNGSGBSGK-UHFFFAOYSA-N iron(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Fe+3].[Fe+3] LIKBJVNGSGBSGK-UHFFFAOYSA-N 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- 238000007704 wet chemistry method Methods 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 229910013470 LiC1 Inorganic materials 0.000 description 2
- 108091006629 SLC13A2 Proteins 0.000 description 2
- BUGBHKTXTAQXES-UHFFFAOYSA-N Selenium Chemical compound [Se] BUGBHKTXTAQXES-UHFFFAOYSA-N 0.000 description 2
- 229910021536 Zeolite Inorganic materials 0.000 description 2
- 230000004913 activation Effects 0.000 description 2
- 229910052783 alkali metal Inorganic materials 0.000 description 2
- 150000001340 alkali metals Chemical class 0.000 description 2
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 2
- 150000001342 alkaline earth metals Chemical class 0.000 description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 2
- SWLVFNYSXGMGBS-UHFFFAOYSA-N ammonium bromide Chemical compound [NH4+].[Br-] SWLVFNYSXGMGBS-UHFFFAOYSA-N 0.000 description 2
- 229910052785 arsenic Inorganic materials 0.000 description 2
- RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 description 2
- 238000000498 ball milling Methods 0.000 description 2
- 239000002585 base Substances 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- 150000001721 carbon Chemical class 0.000 description 2
- 238000006477 desulfuration reaction Methods 0.000 description 2
- 230000023556 desulfurization Effects 0.000 description 2
- 229910001873 dinitrogen Inorganic materials 0.000 description 2
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- 239000012467 final product Substances 0.000 description 2
- 229910052598 goethite Inorganic materials 0.000 description 2
- 150000004820 halides Chemical class 0.000 description 2
- 231100001244 hazardous air pollutant Toxicity 0.000 description 2
- AEIXRCIKZIZYPM-UHFFFAOYSA-M hydroxy(oxo)iron Chemical compound [O][Fe]O AEIXRCIKZIZYPM-UHFFFAOYSA-M 0.000 description 2
- 238000009434 installation Methods 0.000 description 2
- 239000007800 oxidant agent Substances 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 239000002243 precursor Substances 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
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- 230000001105 regulatory effect Effects 0.000 description 2
- 229910052711 selenium Inorganic materials 0.000 description 2
- 239000011669 selenium Substances 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- 238000011144 upstream manufacturing Methods 0.000 description 2
- 239000010457 zeolite Substances 0.000 description 2
- WTCCANMBFQWZMY-UHFFFAOYSA-N 3-[4-(bromomethyl)phenyl]-7-(diethylamino)chromen-2-one Chemical compound O=C1OC2=CC(N(CC)CC)=CC=C2C=C1C1=CC=C(CBr)C=C1 WTCCANMBFQWZMY-UHFFFAOYSA-N 0.000 description 1
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 1
- 206010010904 Convulsion Diseases 0.000 description 1
- 235000016936 Dendrocalamus strictus Nutrition 0.000 description 1
- 239000012692 Fe precursor Substances 0.000 description 1
- JJWSNOOGIUMOEE-UHFFFAOYSA-N Monomethylmercury Chemical compound [Hg]C JJWSNOOGIUMOEE-UHFFFAOYSA-N 0.000 description 1
- 235000011941 Tilia x europaea Nutrition 0.000 description 1
- 206010044565 Tremor Diseases 0.000 description 1
- 238000005411 Van der Waals force Methods 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- 230000000274 adsorptive effect Effects 0.000 description 1
- 231100001245 air toxic agent Toxicity 0.000 description 1
- 239000002956 ash Substances 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000002802 bituminous coal Substances 0.000 description 1
- 239000008280 blood Substances 0.000 description 1
- 210000004369 blood Anatomy 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- 210000004556 brain Anatomy 0.000 description 1
- 239000004568 cement Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
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- 230000001276 controlling effect Effects 0.000 description 1
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- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
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- 230000005284 excitation Effects 0.000 description 1
- 230000005281 excited state Effects 0.000 description 1
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- 239000000499 gel Substances 0.000 description 1
- 150000002366 halogen compounds Chemical class 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- TUJKJAMUKRIRHC-UHFFFAOYSA-N hydroxyl Chemical compound [OH] TUJKJAMUKRIRHC-UHFFFAOYSA-N 0.000 description 1
- VBMVTYDPPZVILR-UHFFFAOYSA-N iron(2+);oxygen(2-) Chemical group [O-2].[Fe+2] VBMVTYDPPZVILR-UHFFFAOYSA-N 0.000 description 1
- 239000004571 lime Substances 0.000 description 1
- 239000006249 magnetic particle Substances 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 238000012544 monitoring process Methods 0.000 description 1
- 230000000926 neurological effect Effects 0.000 description 1
- 239000011368 organic material Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- JTJMJGYZQZDUJJ-UHFFFAOYSA-N phencyclidine Chemical class C1CCCCN1C1(C=2C=CC=CC=2)CCCCC1 JTJMJGYZQZDUJJ-UHFFFAOYSA-N 0.000 description 1
- 238000000053 physical method Methods 0.000 description 1
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- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
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Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
- B01D53/06—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with moving adsorbents, e.g. rotating beds
- B01D53/10—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with moving adsorbents, e.g. rotating beds with dispersed adsorbents
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/64—Heavy metals or compounds thereof, e.g. mercury
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/81—Solid phase processes
- B01D53/83—Solid phase processes with moving reactants
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/06—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising oxides or hydroxides of metals not provided for in group B01J20/04
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/20—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising free carbon; comprising carbon obtained by carbonising processes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
- B01J20/28002—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their physical properties
- B01J20/28009—Magnetic properties
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
- B01J20/28054—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their surface properties or porosity
- B01J20/28057—Surface area, e.g. B.E.T specific surface area
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/30—Processes for preparing, regenerating, or reactivating
- B01J20/3021—Milling, crushing or grinding
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/30—Processes for preparing, regenerating, or reactivating
- B01J20/3085—Chemical treatments not covered by groups B01J20/3007 - B01J20/3078
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2251/00—Reactants
- B01D2251/10—Oxidants
- B01D2251/108—Halogens or halogen compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
- B01D2253/10—Inorganic adsorbents
- B01D2253/102—Carbon
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2255/00—Catalysts
- B01D2255/20—Metals or compounds thereof
- B01D2255/207—Transition metals
- B01D2255/20707—Titanium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2255/00—Catalysts
- B01D2255/80—Type of catalytic reaction
- B01D2255/802—Photocatalytic
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/60—Heavy metals or heavy metal compounds
- B01D2257/602—Mercury or mercury compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2258/00—Sources of waste gases
- B01D2258/02—Other waste gases
- B01D2258/0283—Flue gases
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2259/00—Type of treatment
- B01D2259/80—Employing electric, magnetic, electromagnetic or wave energy, or particle radiation
- B01D2259/814—Magnetic fields
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Analytical Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Environmental & Geological Engineering (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Biomedical Technology (AREA)
- Health & Medical Sciences (AREA)
- Inorganic Chemistry (AREA)
- Dispersion Chemistry (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
- Treating Waste Gases (AREA)
- Electrostatic Separation (AREA)
- Compounds Of Iron (AREA)
Abstract
La présente invention concerne un adsorbant magnétique qui comprend un adsorbant et de l'oxyde de fer implanté sur une surface de l'adsorbant, la surface totale de l'adsorbant magnétique n'étant pas sensiblement inférieure à une surface totale de l'adsorbant. Éventuellement, l'adsorbant est du charbon actif.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201261660475P | 2012-06-15 | 2012-06-15 | |
| US61/660,475 | 2012-06-15 | ||
| PCT/US2013/026863 WO2013187940A1 (fr) | 2012-06-15 | 2013-02-20 | Adsorbants magnétiques, procédés pour fabriquer un adsorbant magnétique, et procédés d'élimination de contaminants de flux de fluide |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CA2876164A1 true CA2876164A1 (fr) | 2013-12-19 |
| CA2876164C CA2876164C (fr) | 2021-06-08 |
Family
ID=49758587
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA2876164A Expired - Fee Related CA2876164C (fr) | 2012-06-15 | 2013-02-20 | Adsorbants magnetiques, procedes pour fabriquer un adsorbant magnetique, et procedes d'elimination de contaminants de flux de fluide |
Country Status (6)
| Country | Link |
|---|---|
| EP (1) | EP2861322A4 (fr) |
| JP (1) | JP2015526274A (fr) |
| CN (1) | CN104812464A (fr) |
| AU (2) | AU2013274862A1 (fr) |
| CA (1) | CA2876164C (fr) |
| WO (1) | WO2013187940A1 (fr) |
Families Citing this family (27)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US9388355B2 (en) | 2011-04-15 | 2016-07-12 | Biogenic Reagents Ventures, Llc | Process for producing high-carbon biogenic reagents |
| DK2847127T3 (da) | 2012-05-07 | 2020-10-26 | Carbon Tech Holdings Llc | Kontinuerlig fremgangsmåde til fremstilling af biogent aktivt kul |
| WO2015061701A1 (fr) | 2013-10-24 | 2015-04-30 | Biogenic Reagent Ventures, Llc | Procédés et appareil pour produire du charbon actif à partir de biomasse par le biais d'intermédiaires de cendre carbonisée |
| HRP20220257T1 (hr) | 2014-01-16 | 2022-04-29 | Carbon Technology Holdings, LLC | Ugljično mikro-postrojenje |
| US20150239743A1 (en) | 2014-02-24 | 2015-08-27 | Biogenic Reagent Ventures, Llc | Highly mesoporous activated carbon |
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| CN106693591A (zh) * | 2016-12-27 | 2017-05-24 | 盐城工学院 | 一种波形变速管道凝并器 |
| CN106731388A (zh) * | 2016-12-27 | 2017-05-31 | 盐城工学院 | 一种角型管道式超细颗粒凝并器 |
| CN106622661B (zh) * | 2016-12-27 | 2019-02-01 | 盐城工学院 | 一种交汇式波形变速管道凝并器 |
| CN106621682A (zh) * | 2016-12-27 | 2017-05-10 | 盐城工学院 | 一种波形变速超细颗粒凝并箱 |
| CN106731436A (zh) * | 2016-12-27 | 2017-05-31 | 盐城工学院 | 一种流线型管道式超细颗粒凝并器 |
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| CN106731432A (zh) * | 2016-12-27 | 2017-05-31 | 盐城工学院 | 组合型管式凝并器 |
| CN106731392A (zh) * | 2016-12-27 | 2017-05-31 | 盐城工学院 | 一种新型超细颗粒凝并器 |
| CN107138272B (zh) * | 2017-04-24 | 2019-08-13 | 航天凯天环保科技股份有限公司 | 一种喷涂废气磁化净化方法及装置 |
| CN107930390B (zh) * | 2017-12-15 | 2021-05-28 | 中南大学 | 一种光催化氧化烟气中单质汞的方法 |
| MX2020013421A (es) | 2018-06-14 | 2021-03-29 | Carbon Tech Holdings Llc | Composiciones de dióxido de silicio de carbono poroso biogénico, métodos de elaboracion y uso de estas. |
| CN109738579A (zh) * | 2018-11-13 | 2019-05-10 | 中国航天员科研训练中心 | 一种基于渗透管的标准气体发生装置 |
| CN109761331B (zh) * | 2019-03-06 | 2021-07-06 | 青岛洛克环保科技有限公司 | 一种磁性污水处理剂及其制备方法 |
| CA3194777A1 (fr) | 2020-09-25 | 2022-03-31 | Carbon Technology Holdings, LLC | Bioreduction de minerais metalliques integres a la pyrolyse de biomasse |
| CN112480976B (zh) * | 2020-12-29 | 2023-01-17 | 昆明理工大学 | 一种高炉煤气干法深度净化的方法 |
| JP2024508270A (ja) | 2021-02-18 | 2024-02-26 | カーボン テクノロジー ホールディングス, エルエルシー | カーボンネガティブ冶金製品 |
| WO2022232311A1 (fr) | 2021-04-27 | 2022-11-03 | Carbon Technology Holdings, LLC | Compositions de biocarbone avec carbone fixe optimisé et leurs procédés de production |
| JP2024525574A (ja) | 2021-07-09 | 2024-07-12 | カーボン テクノロジー ホールディングス, エルエルシー | 高い固定炭素含有量及び最適化された反応性を有するバイオカーボンペレットを製造するためのプロセス、並びにこれから得られるバイオカーボンペレット |
| KR20240101647A (ko) | 2021-11-12 | 2024-07-02 | 카본 테크놀로지 홀딩스, 엘엘씨 | 최적화된 조성 파라미터를 갖는 바이오카본 조성물 및 이를 제조하는 공정 |
| CN113998771B (zh) * | 2021-12-30 | 2022-03-25 | 生态环境部华南环境科学研究所 | 一种TPhP的降解方法、生物炭-无机矿物复合体材料及其制备方法 |
| MA58992B1 (fr) * | 2022-12-21 | 2024-09-30 | Mascir (Moroccan Foundation For Advanced Science, Innovation & Research) | Charbon actif magnétique et photocatalytique pour la dépollution des eaux usées et son procédé de fabrication |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4554088A (en) * | 1983-05-12 | 1985-11-19 | Advanced Magnetics Inc. | Magnetic particles for use in separations |
| JPH08504665A (ja) * | 1992-12-18 | 1996-05-21 | ジ ユニバシティー オブ ウエスタン オーストラリア | 有毒物質の処理方法 |
| US5672323A (en) * | 1995-01-26 | 1997-09-30 | The Babcock & Wilcox Company | Activated carbon flue gas desulfurization systems for mercury removal |
| AU745172B2 (en) * | 1997-08-21 | 2002-03-14 | Lg Electronics Inc. | Electrostatic precipitator |
| WO2000038831A1 (fr) * | 1998-12-31 | 2000-07-06 | Hexablock, Inc. | Magneto-absorbant |
| US7429330B2 (en) * | 2001-08-27 | 2008-09-30 | Calgon Carbon Corporation | Method for removing contaminants from fluid streams |
| US20060076229A1 (en) * | 2003-01-13 | 2006-04-13 | Mazyck David W | Magnetic activated carbon and the removal of contaminants from a fluid streams |
| US7713503B2 (en) * | 2006-09-12 | 2010-05-11 | General Electric Company | Sorbents and sorbent composition for mercury removal |
| US7722843B1 (en) * | 2006-11-24 | 2010-05-25 | Srivats Srinivasachar | System and method for sequestration and separation of mercury in combustion exhaust gas aqueous scrubber systems |
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2013
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- 2013-02-20 AU AU2013274862A patent/AU2013274862A1/en not_active Abandoned
- 2013-02-20 EP EP13804938.2A patent/EP2861322A4/fr not_active Withdrawn
- 2013-02-20 JP JP2015517233A patent/JP2015526274A/ja active Pending
- 2013-02-20 WO PCT/US2013/026863 patent/WO2013187940A1/fr not_active Ceased
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2018
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|---|---|
| WO2013187940A1 (fr) | 2013-12-19 |
| EP2861322A1 (fr) | 2015-04-22 |
| AU2013274862A1 (en) | 2015-01-15 |
| EP2861322A4 (fr) | 2016-03-02 |
| AU2018203359B2 (en) | 2019-12-05 |
| CN104812464A (zh) | 2015-07-29 |
| CA2876164C (fr) | 2021-06-08 |
| JP2015526274A (ja) | 2015-09-10 |
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