CA2514790A1 - Systeme de lubrification pour formage a froid, et methode et composition connexes - Google Patents

Systeme de lubrification pour formage a froid, et methode et composition connexes Download PDF

Info

Publication number: CA2514790A1
Authority: CA; Canada
Prior art keywords: phosphate; coating; article; calcium; lubricant
Prior art date: 2004-09-21
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Abandoned

Application number

CA002514790A

Other languages

English (en)

Inventor

Richard Church

William C. Russell

Paul Kulongowski

Kenneth J. Hacias

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Henkel AG and Co KGaA

Original Assignee

Henkel AG and Co KGaA

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

2004-09-21

Filing date

2005-08-03

Publication date

2006-03-21

2005-08-03 Application filed by Henkel AG and Co KGaA filed Critical Henkel AG and Co KGaA

2006-03-21 Publication of CA2514790A1 publication Critical patent/CA2514790A1/fr

Status Abandoned legal-status Critical Current

Links

238000000034 method Methods 0.000 title claims abstract description 100
230000008569 process Effects 0.000 title claims abstract description 95
239000000314 lubricant Substances 0.000 title claims abstract description 80
239000000203 mixture Substances 0.000 title claims description 33
229910019142 PO4 Inorganic materials 0.000 claims abstract description 196
239000010452 phosphate Substances 0.000 claims abstract description 195
238000000576 coating method Methods 0.000 claims abstract description 184
NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims abstract description 180
239000011248 coating agent Substances 0.000 claims abstract description 143
239000011575 calcium Substances 0.000 claims abstract description 100
229910052791 calcium Inorganic materials 0.000 claims abstract description 93
229910052751 metal Inorganic materials 0.000 claims abstract description 60
239000002184 metal Substances 0.000 claims abstract description 60
AVXURJPOCDRRFD-UHFFFAOYSA-N Hydroxylamine Chemical compound ON AVXURJPOCDRRFD-UHFFFAOYSA-N 0.000 claims abstract description 30
-1 calcium modified zinc Chemical class 0.000 claims abstract description 26
OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 89
230000003750 conditioning effect Effects 0.000 claims description 37
239000011701 zinc Substances 0.000 claims description 36
235000014113 dietary fatty acids Nutrition 0.000 claims description 31
239000000194 fatty acid Substances 0.000 claims description 31
229930195729 fatty acid Natural products 0.000 claims description 31
229910052725 zinc Inorganic materials 0.000 claims description 30
HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 29
239000013078 crystal Substances 0.000 claims description 26
150000004665 fatty acids Chemical class 0.000 claims description 19
239000000344 soap Substances 0.000 claims description 19
239000010953 base metal Substances 0.000 claims description 18
230000001050 lubricating effect Effects 0.000 claims description 18
230000002378 acidificating effect Effects 0.000 claims description 16
238000004519 manufacturing process Methods 0.000 claims description 13
RYYKJJJTJZKILX-UHFFFAOYSA-M sodium octadecanoate Chemical compound [Na+].CCCCCCCCCCCCCCCCCC([O-])=O RYYKJJJTJZKILX-UHFFFAOYSA-M 0.000 claims description 13
239000007795 chemical reaction product Substances 0.000 claims description 12
LRXTYHSAJDENHV-UHFFFAOYSA-H zinc phosphate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O LRXTYHSAJDENHV-UHFFFAOYSA-H 0.000 claims description 12
229910000165 zinc phosphate Inorganic materials 0.000 claims description 12
PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 claims description 10
239000011572 manganese Substances 0.000 claims description 10
229910052748 manganese Inorganic materials 0.000 claims description 10
239000004094 surface-active agent Substances 0.000 claims description 8
230000001143 conditioned effect Effects 0.000 claims description 7
238000002360 preparation method Methods 0.000 claims description 7
238000007746 phosphate conversion coating Methods 0.000 claims description 6
238000007739 conversion coating Methods 0.000 claims description 5
150000003609 titanium compounds Chemical class 0.000 claims description 5
239000006185 dispersion Substances 0.000 claims description 4
238000001035 drying Methods 0.000 claims description 4
229940114930 potassium stearate Drugs 0.000 claims description 4
ANBFRLKBEIFNQU-UHFFFAOYSA-M potassium;octadecanoate Chemical compound [K+].CCCCCCCCCCCCCCCCCC([O-])=O ANBFRLKBEIFNQU-UHFFFAOYSA-M 0.000 claims description 4
CPSYWNLKRDURMG-UHFFFAOYSA-L hydron;manganese(2+);phosphate Chemical compound [Mn+2].OP([O-])([O-])=O CPSYWNLKRDURMG-UHFFFAOYSA-L 0.000 claims description 2
229910000398 iron phosphate Inorganic materials 0.000 claims description 2
WBJZTOZJJYAKHQ-UHFFFAOYSA-K iron(3+) phosphate Chemical compound [Fe+3].[O-]P([O-])([O-])=O WBJZTOZJJYAKHQ-UHFFFAOYSA-K 0.000 claims description 2
229910000159 nickel phosphate Inorganic materials 0.000 claims description 2
JOCJYBPHESYFOK-UHFFFAOYSA-K nickel(3+);phosphate Chemical compound [Ni+3].[O-]P([O-])([O-])=O JOCJYBPHESYFOK-UHFFFAOYSA-K 0.000 claims description 2
238000011282 treatment Methods 0.000 abstract description 15
CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 abstract description 11
235000021317 phosphate Nutrition 0.000 description 179
239000000243 solution Substances 0.000 description 65
230000000052 comparative effect Effects 0.000 description 30
239000002253 acid Substances 0.000 description 25
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 23
235000021110 pickles Nutrition 0.000 description 19
239000010936 titanium Substances 0.000 description 18
229910052719 titanium Inorganic materials 0.000 description 17
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 16
RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 15
239000000956 alloy Substances 0.000 description 15
229910045601 alloy Inorganic materials 0.000 description 15
238000001228 spectrum Methods 0.000 description 13
230000006872 improvement Effects 0.000 description 11
229910001463 metal phosphate Inorganic materials 0.000 description 10
229910000831 Steel Inorganic materials 0.000 description 9
230000008901 benefit Effects 0.000 description 9
239000012141 concentrate Substances 0.000 description 9
239000010959 steel Substances 0.000 description 9
PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 8
230000003213 activating effect Effects 0.000 description 8
229910052742 iron Inorganic materials 0.000 description 8
239000000047 product Substances 0.000 description 8
238000004876 x-ray fluorescence Methods 0.000 description 8
238000011109 contamination Methods 0.000 description 7
238000004846 x-ray emission Methods 0.000 description 7
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 6
238000007792 addition Methods 0.000 description 6
230000002860 competitive effect Effects 0.000 description 6
150000003608 titanium Chemical class 0.000 description 6
230000015572 biosynthetic process Effects 0.000 description 5
230000000694 effects Effects 0.000 description 5
238000007654 immersion Methods 0.000 description 5
238000005461 lubrication Methods 0.000 description 5
125000002467 phosphate group Chemical group [H]OP(=O)(O[H])O[*] 0.000 description 5
NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 4
CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 4
239000003788 bath preparation Substances 0.000 description 4
238000002149 energy-dispersive X-ray emission spectroscopy Methods 0.000 description 4
230000004048 modification Effects 0.000 description 4
238000012986 modification Methods 0.000 description 4
229910052759 nickel Inorganic materials 0.000 description 4
OOQVQSGLNPBFNY-UHFFFAOYSA-N octadecaneperoxoic acid;zinc Chemical compound [Zn].CCCCCCCCCCCCCCCCCC(=O)OO OOQVQSGLNPBFNY-UHFFFAOYSA-N 0.000 description 4
QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 4
238000005554 pickling Methods 0.000 description 4
239000000126 substance Substances 0.000 description 4
QAOWNCQODCNURD-UHFFFAOYSA-N sulfuric acid Substances OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 4
229910002651 NO3 Inorganic materials 0.000 description 3
GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 3
KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
230000001464 adherent effect Effects 0.000 description 3
239000002280 amphoteric surfactant Substances 0.000 description 3
239000000356 contaminant Substances 0.000 description 3
229910001448 ferrous ion Inorganic materials 0.000 description 3
WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 3
KBJMLQFLOWQJNF-UHFFFAOYSA-N nickel(ii) nitrate Chemical compound [Ni+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O KBJMLQFLOWQJNF-UHFFFAOYSA-N 0.000 description 3
229910017604 nitric acid Inorganic materials 0.000 description 3
229910000029 sodium carbonate Inorganic materials 0.000 description 3
239000007787 solid Substances 0.000 description 3
239000000758 substrate Substances 0.000 description 3
239000012224 working solution Substances 0.000 description 3
239000011787 zinc oxide Substances 0.000 description 3
XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 description 3
RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
VTLYFUHAOXGGBS-UHFFFAOYSA-N Fe3+ Chemical compound [Fe+3] VTLYFUHAOXGGBS-UHFFFAOYSA-N 0.000 description 2
NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
230000032683 aging Effects 0.000 description 2
239000007864 aqueous solution Substances 0.000 description 2
ZCCIPPOKBCJFDN-UHFFFAOYSA-N calcium nitrate Chemical compound [Ca+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O ZCCIPPOKBCJFDN-UHFFFAOYSA-N 0.000 description 2
239000001506 calcium phosphate Substances 0.000 description 2
229910000389 calcium phosphate Inorganic materials 0.000 description 2
235000011010 calcium phosphates Nutrition 0.000 description 2
CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical class [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 description 2
239000008199 coating composition Substances 0.000 description 2
150000001875 compounds Chemical class 0.000 description 2
238000007796 conventional method Methods 0.000 description 2
239000010949 copper Substances 0.000 description 2
229910052802 copper Inorganic materials 0.000 description 2
238000005260 corrosion Methods 0.000 description 2
230000007797 corrosion Effects 0.000 description 2
238000011161 development Methods 0.000 description 2
230000018109 developmental process Effects 0.000 description 2
238000009826 distribution Methods 0.000 description 2
239000000428 dust Substances 0.000 description 2
150000002500 ions Chemical class 0.000 description 2
150000002739 metals Chemical class 0.000 description 2
239000003973 paint Substances 0.000 description 2
239000002245 particle Substances 0.000 description 2
150000003013 phosphoric acid derivatives Chemical class 0.000 description 2
238000012545 processing Methods 0.000 description 2
238000001953 recrystallisation Methods 0.000 description 2
235000017550 sodium carbonate Nutrition 0.000 description 2
235000011121 sodium hydroxide Nutrition 0.000 description 2
239000007921 spray Substances 0.000 description 2
229940114926 stearate Drugs 0.000 description 2
QORWJWZARLRLPR-UHFFFAOYSA-H tricalcium bis(phosphate) Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O QORWJWZARLRLPR-UHFFFAOYSA-H 0.000 description 2
ZNBNBTIDJSKEAM-UHFFFAOYSA-N 4-[7-hydroxy-2-[5-[5-[6-hydroxy-6-(hydroxymethyl)-3,5-dimethyloxan-2-yl]-3-methyloxolan-2-yl]-5-methyloxolan-2-yl]-2,8-dimethyl-1,10-dioxaspiro[4.5]decan-9-yl]-2-methyl-3-propanoyloxypentanoic acid Chemical compound C1C(O)C(C)C(C(C)C(OC(=O)CC)C(C)C(O)=O)OC11OC(C)(C2OC(C)(CC2)C2C(CC(O2)C2C(CC(C)C(O)(CO)O2)C)C)CC1 ZNBNBTIDJSKEAM-UHFFFAOYSA-N 0.000 description 1
OCKGFTQIICXDQW-ZEQRLZLVSA-N 5-[(1r)-1-hydroxy-2-[4-[(2r)-2-hydroxy-2-(4-methyl-1-oxo-3h-2-benzofuran-5-yl)ethyl]piperazin-1-yl]ethyl]-4-methyl-3h-2-benzofuran-1-one Chemical compound C1=C2C(=O)OCC2=C(C)C([C@@H](O)CN2CCN(CC2)C[C@H](O)C2=CC=C3C(=O)OCC3=C2C)=C1 OCKGFTQIICXDQW-ZEQRLZLVSA-N 0.000 description 1
BHPQYMZQTOCNFJ-UHFFFAOYSA-N Calcium cation Chemical compound [Ca+2] BHPQYMZQTOCNFJ-UHFFFAOYSA-N 0.000 description 1
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 description 1
229910003638 H2SiF6 Inorganic materials 0.000 description 1
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
241000282337 Nasua nasua Species 0.000 description 1
IOVCWXUNBOPUCH-UHFFFAOYSA-M Nitrite anion Chemical compound [O-]N=O IOVCWXUNBOPUCH-UHFFFAOYSA-M 0.000 description 1
XOJVVFBFDXDTEG-UHFFFAOYSA-N Norphytane Natural products CC(C)CCCC(C)CCCC(C)CCCC(C)C XOJVVFBFDXDTEG-UHFFFAOYSA-N 0.000 description 1
QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
241000276425 Xiphophorus maculatus Species 0.000 description 1
229910009378 Zn Ca Inorganic materials 0.000 description 1
RFFPTVDUMCWFTA-UHFFFAOYSA-H [Na+].[Na+].[Ti+4].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O Chemical compound [Na+].[Na+].[Ti+4].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O RFFPTVDUMCWFTA-UHFFFAOYSA-H 0.000 description 1
230000002411 adverse Effects 0.000 description 1
239000012670 alkaline solution Substances 0.000 description 1
229910000147 aluminium phosphate Inorganic materials 0.000 description 1
238000004458 analytical method Methods 0.000 description 1
239000011260 aqueous acid Substances 0.000 description 1
229910021538 borax Inorganic materials 0.000 description 1
229910001424 calcium ion Inorganic materials 0.000 description 1
235000013539 calcium stearate Nutrition 0.000 description 1
239000008116 calcium stearate Substances 0.000 description 1
229910052799 carbon Inorganic materials 0.000 description 1
238000001311 chemical methods and process Methods 0.000 description 1
238000006243 chemical reaction Methods 0.000 description 1
238000004140 cleaning Methods 0.000 description 1
239000010941 cobalt Substances 0.000 description 1
229910017052 cobalt Inorganic materials 0.000 description 1
GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
238000000641 cold extrusion Methods 0.000 description 1
238000010960 commercial process Methods 0.000 description 1
239000000470 constituent Substances 0.000 description 1
230000007423 decrease Effects 0.000 description 1
238000001514 detection method Methods 0.000 description 1
239000000839 emulsion Substances 0.000 description 1
LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 1
229910001447 ferric ion Inorganic materials 0.000 description 1
238000005187 foaming Methods 0.000 description 1
230000005484 gravity Effects 0.000 description 1
WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
229910000378 hydroxylammonium sulfate Inorganic materials 0.000 description 1
239000003112 inhibitor Substances 0.000 description 1
SURQXAFEQWPFPV-UHFFFAOYSA-L iron(2+) sulfate heptahydrate Chemical compound O.O.O.O.O.O.O.[Fe+2].[O-]S([O-])(=O)=O SURQXAFEQWPFPV-UHFFFAOYSA-L 0.000 description 1
JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
230000001788 irregular Effects 0.000 description 1
239000007788 liquid Substances 0.000 description 1
229910021645 metal ion Inorganic materials 0.000 description 1
230000003472 neutralizing effect Effects 0.000 description 1
239000003921 oil Substances 0.000 description 1
235000019198 oils Nutrition 0.000 description 1
238000010422 painting Methods 0.000 description 1
235000011118 potassium hydroxide Nutrition 0.000 description 1
238000002203 pretreatment Methods 0.000 description 1
230000009257 reactivity Effects 0.000 description 1
230000009467 reduction Effects 0.000 description 1
238000007761 roller coating Methods 0.000 description 1
150000003839 salts Chemical class 0.000 description 1
238000006748 scratching Methods 0.000 description 1
230000002393 scratching effect Effects 0.000 description 1
239000010802 sludge Substances 0.000 description 1
229910052708 sodium Inorganic materials 0.000 description 1
239000011734 sodium Substances 0.000 description 1
239000004328 sodium tetraborate Substances 0.000 description 1
235000010339 sodium tetraborate Nutrition 0.000 description 1
238000005507 spraying Methods 0.000 description 1
238000005482 strain hardening Methods 0.000 description 1
ZEFWRWWINDLIIV-UHFFFAOYSA-N tetrafluorosilane;dihydrofluoride Chemical compound F.F.F[Si](F)(F)F ZEFWRWWINDLIIV-UHFFFAOYSA-N 0.000 description 1
238000003466 welding Methods 0.000 description 1
238000007704 wet chemistry method Methods 0.000 description 1
239000000080 wetting agent Substances 0.000 description 1
238000005491 wire drawing Methods 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M129/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing oxygen
- C10M129/02—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing oxygen having a carbon chain of less than 30 atoms
- C10M129/26—Carboxylic acids; Salts thereof
- C10M129/28—Carboxylic acids; Salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
- C10M129/38—Carboxylic acids; Salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having 8 or more carbon atoms
- C10M129/40—Carboxylic acids; Salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having 8 or more carbon atoms monocarboxylic
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
- C23C22/06—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
- C23C22/07—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing phosphates
- C23C22/08—Orthophosphates
- C23C22/12—Orthophosphates containing zinc cations
- C23C22/13—Orthophosphates containing zinc cations containing also nitrate or nitrite anions
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/78—Pretreatment of the material to be coated
- C23C22/80—Pretreatment of the material to be coated with solutions containing titanium or zirconium compounds
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/10—Carboxylix acids; Neutral salts thereof
- C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
- C10M2207/125—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids
- C10M2207/126—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids monocarboxylic
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/243—Cold working
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/244—Metal working of specific metals
- C10N2040/246—Iron or steel
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2050/00—Form in which the lubricant is applied to the material being lubricated
- C10N2050/015—Dispersions of solid lubricants
- C10N2050/02—Dispersions of solid lubricants dissolved or suspended in a carrier which subsequently evaporates to leave a lubricant coating
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2050/00—Form in which the lubricant is applied to the material being lubricated
- C10N2050/023—Multi-layer lubricant coatings
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2080/00—Special pretreatment of the material to be lubricated, e.g. phosphatising or chromatising of a metal

Landscapes

Chemical & Material Sciences (AREA)
General Chemical & Material Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Organic Chemistry (AREA)
Engineering & Computer Science (AREA)
Materials Engineering (AREA)
Mechanical Engineering (AREA)
Metallurgy (AREA)
Oil, Petroleum & Natural Gas (AREA)
Lubricants (AREA)
Chemical Treatment Of Metals (AREA)

CA002514790A 2004-09-21 2005-08-03 Systeme de lubrification pour formage a froid, et methode et composition connexes Abandoned CA2514790A1 (fr)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
US61213404P	2004-09-21	2004-09-21
US60/612,134		2004-09-21

Publications (1)

Publication Number	Publication Date
CA2514790A1 true CA2514790A1 (fr)	2006-03-21

Family

ID=36096938

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA002514790A Abandoned CA2514790A1 (fr)	2004-09-21	2005-08-03	Systeme de lubrification pour formage a froid, et methode et composition connexes

Country Status (2)

Country	Link
US (1)	US20060060265A1 (fr)
CA (1)	CA2514790A1 (fr)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US20080283152A1 (en) *	2007-05-17	2008-11-20	Jeffrey Allen Greene	Rinse conditioner bath for treating a substrate and associated method
CN103604392B (zh) *	2013-11-26	2016-09-14	洛阳Lyc轴承有限公司	一种磷化膜深度的测定方法
JP6515389B2 (ja) *	2015-10-09	2019-05-22	日本製鉄株式会社	摺動部材及びその製造方法
EP3504356B1 (fr)	2016-08-24	2024-08-21	PPG Industries Ohio, Inc.	Composition alcaline pour les traitements des surfaces métalliques

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JPS6020463B2 (ja) *	1982-06-04	1985-05-22	日本パ−カライジング株式会社	鉄鋼材の冷間加工潤滑処理方法
US4865653A (en) *	1987-10-30	1989-09-12	Henkel Corporation	Zinc phosphate coating process
US6214132B1 (en) *	1997-03-07	2001-04-10	Henkel Corporation	Conditioning metal surfaces prior to phosphate conversion coating
JP2000119862A (ja) *	1998-10-07	2000-04-25	Nippon Parkerizing Co Ltd	鉄鋼の冷間塑性加工用潤滑処理方法

2005
- 2005-08-03 US US11/195,917 patent/US20060060265A1/en not_active Abandoned
- 2005-08-03 CA CA002514790A patent/CA2514790A1/fr not_active Abandoned

Also Published As

Publication number	Publication date
US20060060265A1 (en)	2006-03-23

Publication	Publication Date	Title
JP2806531B2 (ja)	1998-09-30	鉄又は鉄合金材料の表面処理用リン酸亜鉛系水溶液及び処理方法
US9228088B2 (en)	2016-01-05	Composition for the alkaline passivation of zinc surfaces
CN113278957B (zh)	2024-04-16	制备用于冷成型的金属成型体的方法
MXPA97003675A (en)	1997-08-01	Compositions of zinc phosphate pararecubriment containing ox accelerators
US5160551A (en)	1992-11-03	Activator for use in phosphating processes
AU2004241000B2 (en)	2009-05-14	Method and solution for coating metal surfaces with a phosphating solution containing water peroxide, produced metal object and use of said object
US6361623B1 (en)	2002-03-26	Method for phosphatizing iron and steel
JPS61157684A (ja)	1986-07-17	鉄系金属の冷間加工用潤滑処理方法
CA1313994C (fr)	1993-03-02	Methode d'etirage de tige de fer ou d'acier
JP2000144445A (ja)	2000-05-26	金属材料のアルカリ脱脂処理液およびその使用方法
US6231688B1 (en)	2001-05-15	Composition and process for zinc phosphate conversion coating
US20060237099A1 (en)	2006-10-26	Method for coating metal bodies with a phosphating solution and phosphating solution
US20060060265A1 (en)	2006-03-23	Lubricant system for cold forming, process and composition therefor
JP2015190046A (ja)	2015-11-02	耐食性及び加工性に優れた皮膜を有する鋼線材及びその製造方法
KR101798804B1 (ko)	2017-11-16	소성 가공용 비인 화성 처리제, 처리액, 화성 피막 및 화성 피막을 갖는 금속 재료
JP7329472B2 (ja)	2023-08-18	スケールおよび／またはカーボン除去方法、および金属材の製造方法
WO1998024947A1 (fr)	1998-06-11	Compositions de phosphatation du fer a poids de couche eleve
US5234509A (en)	1993-08-10	Cold deformation process employing improved lubrication coating
JP4031213B2 (ja)	2008-01-09	皮膜形成剤及び皮膜
US3726720A (en)	1973-04-10	Metal conditioning compositions
US5888315A (en)	1999-03-30	Composition and process for forming an underpaint coating on metals
JP2000087253A (ja)	2000-03-28	油分付着鋼材の脱脂兼リン酸亜鉛化成処理液
WO2000014301A1 (fr)	2000-03-16	Composition liquide alcaline et procede de degraissage des pieces metalliques
CN117025000A (zh)	2023-11-10	提升镀锌钢板表面加工性能的环保水基改性处理剂及应用
JP2001295063A (ja)	2001-10-26	非鉄金属材料およびめっき鋼板へのりん酸塩被膜の形成方法

Legal Events

Date	Code	Title	Description
2011-08-03	FZDE	Dead