CA2428029A1 - Air injection for nitrogen oxide reduction and improved product quality - Google Patents
Air injection for nitrogen oxide reduction and improved product quality Download PDFInfo
- Publication number
- CA2428029A1 CA2428029A1 CA002428029A CA2428029A CA2428029A1 CA 2428029 A1 CA2428029 A1 CA 2428029A1 CA 002428029 A CA002428029 A CA 002428029A CA 2428029 A CA2428029 A CA 2428029A CA 2428029 A1 CA2428029 A1 CA 2428029A1
- Authority
- CA
- Canada
- Prior art keywords
- rotary kiln
- burner
- nitrogen oxide
- combustible fuel
- combustion air
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- MWUXSHHQAYIFBG-UHFFFAOYSA-N Nitric oxide Chemical compound O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 title abstract 6
- 238000002347 injection Methods 0.000 title 1
- 239000007924 injection Substances 0.000 title 1
- 238000002485 combustion reaction Methods 0.000 abstract 3
- 239000000446 fuel Substances 0.000 abstract 3
- 239000000463 material Substances 0.000 abstract 3
- 238000001354 calcination Methods 0.000 abstract 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 abstract 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 1
- 230000002950 deficient Effects 0.000 abstract 1
- 229910052760 oxygen Inorganic materials 0.000 abstract 1
- 239000001301 oxygen Substances 0.000 abstract 1
- 229910052717 sulfur Inorganic materials 0.000 abstract 1
- 239000011593 sulfur Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B7/00—Hydraulic cements
- C04B7/36—Manufacture of hydraulic cements in general
- C04B7/364—Avoiding environmental pollution during cement-manufacturing
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F27—FURNACES; KILNS; OVENS; RETORTS
- F27B—FURNACES, KILNS, OVENS OR RETORTS IN GENERAL; OPEN SINTERING OR LIKE APPARATUS
- F27B7/00—Rotary-drum furnaces, i.e. horizontal or slightly inclined
- F27B7/20—Details, accessories or equipment specially adapted for rotary-drum furnaces
- F27B7/36—Arrangements of air or gas supply devices
- F27B7/362—Introducing gas into the drum axially or through the wall
- F27B2007/367—Introducing gas into the drum axially or through the wall transversally through the wall of the drum
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F27—FURNACES; KILNS; OVENS; RETORTS
- F27B—FURNACES, KILNS, OVENS OR RETORTS IN GENERAL; OPEN SINTERING OR LIKE APPARATUS
- F27B7/00—Rotary-drum furnaces, i.e. horizontal or slightly inclined
- F27B7/20—Details, accessories or equipment specially adapted for rotary-drum furnaces
- F27B7/2016—Arrangements of preheating devices for the charge
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F27—FURNACES; KILNS; OVENS; RETORTS
- F27B—FURNACES, KILNS, OVENS OR RETORTS IN GENERAL; OPEN SINTERING OR LIKE APPARATUS
- F27B7/00—Rotary-drum furnaces, i.e. horizontal or slightly inclined
- F27B7/20—Details, accessories or equipment specially adapted for rotary-drum furnaces
- F27B7/42—Arrangement of controlling, monitoring, alarm or like devices
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Ecology (AREA)
- Health & Medical Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- Environmental Sciences (AREA)
- Public Health (AREA)
- Biodiversity & Conservation Biology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Muffle Furnaces And Rotary Kilns (AREA)
- Furnace Details (AREA)
- Feeding, Discharge, Calcimining, Fusing, And Gas-Generation Devices (AREA)
Abstract
A calcining system (10) is operated in a substoichiometric mode for reducing nitrogen oxide generation and removing sulfur from materials (26) to be processed by creating an oxygen deficient atmosphere. The calcining system (10) includes a rotary kiln (14) rotating on a slightly inclined horizontal axis. The rotary kiln (14) has a feed end (22) introducing material (26) to be processed and a discharge end (24). A preheating/precalcining device (12) is positioned adjacent the feed end (22) such that the material (26) passes through the device (12) prior to entering the rotary kiln (14). A stationary hood (16) surrounds the discharge end (24). A burner (18) is supported by the stationary hood (16). The burner (18) introduces combustible fuel (38) and combustion air (40) into the rotary kiln (14) through the discharge end (24) and operates in a substoichiometric mode. At least on air nozzle (44) is located along the length of the rotary kiln (14). The air nozzle (44) injects combustion air (40) into the rotary kiln (14). The combustion air (40C) introduced by the air nozzle (44) completely combusts the combustible fuel (38) introduced by the burner (18) before the combustible fuel (38) exits the feed end (24).
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US25212100P | 2000-11-20 | 2000-11-20 | |
| US60/252,121 | 2000-11-20 | ||
| US09/918,269 US6474984B2 (en) | 2000-11-20 | 2001-07-30 | Air injection for nitrogen oxide reduction and improved product quality |
| US09/918,269 | 2001-07-30 | ||
| PCT/US2001/043648 WO2002042701A1 (en) | 2000-11-20 | 2001-11-14 | Air injection for nitrogen oxide reduction and improved product quality |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CA2428029A1 true CA2428029A1 (en) | 2002-05-30 |
| CA2428029C CA2428029C (en) | 2009-05-26 |
Family
ID=26942061
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA002428029A Expired - Fee Related CA2428029C (en) | 2000-11-20 | 2001-11-14 | Air injection for nitrogen oxide reduction and improved product quality |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US6474984B2 (en) |
| EP (1) | EP1342042A4 (en) |
| AU (2) | AU2002225689B2 (en) |
| CA (1) | CA2428029C (en) |
| WO (1) | WO2002042701A1 (en) |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7229281B2 (en) * | 2000-09-11 | 2007-06-12 | Cadence Environmental Energy, Inc. | Method of mixing high temperature gases in mineral processing kilns |
| US6672865B2 (en) * | 2000-09-11 | 2004-01-06 | Cadence Enviromental Energy, Inc. | Method of mixing high temperature gases in mineral processing kilns |
| DE10317307B4 (en) * | 2003-04-14 | 2007-11-15 | Rheinkalk Gmbh | Device and method for burning limestone or dolomite |
| EP1993708A4 (en) * | 2006-01-09 | 2010-10-13 | Cadence Environmental Energy | Method and apparatus for reducing nox emissions in rotary kilns by sncr |
| US9250018B2 (en) * | 2009-11-06 | 2016-02-02 | Fives North American Combustion, Inc. | Apparatus and methods for achieving low NOx in a grate-kiln pelletizing furnace |
| CA2827930A1 (en) * | 2011-03-16 | 2012-09-20 | Hanwha Chemical Corporation | Method for calcining electrode materials using a rotary kiln |
| US10046977B2 (en) | 2013-07-05 | 2018-08-14 | Outotec (Finland) Oy | Process and plant for purifying red mud |
| CN103776262B (en) * | 2014-01-28 | 2015-05-13 | 北京汉能清源科技有限公司 | Real-time adjustment method and device for combustion conditions of rotary cement kiln |
| CN104634097A (en) * | 2014-12-26 | 2015-05-20 | 中国建筑材料科学研究总院 | Method and system for reducing nitrogen oxide in rotary kiln |
| CN111306933A (en) * | 2020-02-24 | 2020-06-19 | 沈忠东 | Staged combustion method for saving coal and reducing nitrogen during combustion of rotary cement kiln |
Family Cites Families (42)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US1121906A (en) | 1914-04-25 | 1914-12-22 | George F Downs | Rotary furnace or kiln. |
| US2813822A (en) | 1952-11-24 | 1957-11-19 | Collier Carbon & Chemical Co | Apparatus and method for calcining petroleum coke, coal and similar substances containing volatile combustible material |
| US3087790A (en) | 1959-09-04 | 1963-04-30 | Iowa State College Res Found | Reductive decomposition of calcium sulfate |
| US3584850A (en) | 1969-07-02 | 1971-06-15 | United States Steel Corp | Rotary kiln for shock sintering |
| US3633894A (en) | 1970-01-12 | 1972-01-11 | Bethlehem Steel Corp | Method of making calcined minerals with reduced sulfur content |
| US3661370A (en) | 1970-12-24 | 1972-05-09 | Allis Chalmers Mfg Co | Gas delivery manifold and processed material discharge assembly for rotary kiln |
| US3945624A (en) | 1972-10-31 | 1976-03-23 | Allis-Chalmers Corporation | Reduction kiln having a controllable distribution system |
| US3794483A (en) | 1972-10-31 | 1974-02-26 | Allis Chalmers | Process for delivering fuel and air to a rotary reduction kiln |
| US3847538A (en) | 1972-10-31 | 1974-11-12 | Allis Chalmers | Reduction kiln having distribution system |
| US3751220A (en) | 1972-11-24 | 1973-08-07 | Allis Chalmers | Fluid delivery system for rotary kiln |
| US3888621A (en) | 1974-04-12 | 1975-06-10 | Alcan Res & Dev | Monitoring and controlling kiln operation in calcination of coke |
| US3966560A (en) | 1974-05-06 | 1976-06-29 | Alcan Research And Development Limited | Method of calcining coke in a rotary kiln |
| US4065320A (en) | 1975-05-13 | 1977-12-27 | Allis-Chalmers Corporation | System for handling high sulfur materials |
| US4053356A (en) | 1975-08-08 | 1977-10-11 | Westinghouse Electric Corporation | Guide device |
| US4070149A (en) | 1976-07-23 | 1978-01-24 | Allis-Chalmers Corporation | Controllable distribution system for rotary kiln |
| DE2719348C3 (en) | 1977-04-30 | 1983-04-28 | Metallgesellschaft Ag, 6000 Frankfurt | Process for the production of quick lime with a low sulfur content |
| DE2719347B2 (en) | 1977-04-30 | 1980-11-13 | Metallgesellschaft Ag, 6000 Frankfurt | Process for burning lime with solid carbonaceous fuel in a rotary kiln |
| US4340359A (en) | 1979-02-01 | 1982-07-20 | Holger Struckmann | Apparatus and method of heating particulate material |
| US4273314A (en) | 1979-06-22 | 1981-06-16 | The Direct Reduction Corporation | Direct reduction rotary kiln with improved air injection |
| US4330325A (en) | 1979-06-22 | 1982-05-18 | The Direct Reduction Corporation | Direct reduction rotary kiln with improved air injection |
| DE3012866A1 (en) | 1980-04-02 | 1981-10-08 | Metallgesellschaft Ag, 6000 Frankfurt | METHOD FOR BURNING LIME IN THE TURNTABLE |
| JPS5822881A (en) | 1981-08-03 | 1983-02-10 | 川崎重工業株式会社 | Rotary kiln and direct reduction method of metallic oxide using said kiln |
| US4402273A (en) | 1982-03-01 | 1983-09-06 | Ari Technologies, Inc. | Reduction of nitrogen oxide emissions from calciners |
| US4389242A (en) | 1982-03-18 | 1983-06-21 | The Direct Reduction Corporation | Interior arrangement for direct reduction rotary kilns and method |
| DE3545955C1 (en) * | 1985-12-23 | 1987-07-09 | Berlin Consult Gmbh | Installation for low NOx solids combustion in cement manufacture |
| US5224433A (en) | 1988-11-23 | 1993-07-06 | Cadence Chemical Resources, Inc. | Waste fuel delivery to long kilns |
| US5100314A (en) | 1989-07-14 | 1992-03-31 | Svedala Industries, Inc. | Apparatus and process for direct reduction of materials in a kiln |
| US5076838A (en) | 1989-07-14 | 1991-12-31 | Svedala Industries, Inc. | Process for direct reduction of materials in a kiln |
| DE3925475A1 (en) * | 1989-08-01 | 1991-02-07 | Krupp Polysius Ag | METHOD FOR THE HEAT TREATMENT OF FINE GRAIN GOODS |
| US4957050A (en) | 1989-09-05 | 1990-09-18 | Union Carbide Corporation | Combustion process having improved temperature distribution |
| US5031549A (en) | 1990-10-04 | 1991-07-16 | Westinghouse Electric Corp. | Method of introducing air into a rotary combustor |
| JPH07509688A (en) | 1992-07-14 | 1995-10-26 | アッシュ グローブ セメント カンパニー | Improved method for producing cement in long kilns |
| US5248330A (en) | 1992-12-24 | 1993-09-28 | Suedala, Inc. | Method of pyroprocessing mineral ore material |
| DE4334795A1 (en) | 1993-10-13 | 1995-04-20 | Bayer Ag | Device for gassing a rotary kiln |
| US5632616A (en) | 1994-11-28 | 1997-05-27 | Cadence Environmental Energy, Inc. | Method and apparatus for injecting air into long cement kilns |
| DE19513203A1 (en) | 1995-04-11 | 1996-10-17 | Bayer Ag | Fumigation device for rotary kilns |
| US5755818A (en) * | 1995-06-13 | 1998-05-26 | Praxair Technology, Inc. | Staged combustion method |
| US5908291A (en) | 1998-05-01 | 1999-06-01 | Harper International Corp. | Continuous cross-flow rotary kiln |
| TW430734B (en) | 1998-08-05 | 2001-04-21 | Cadence Environmental Energy | Apparatus and method for providing fuel modules to a preheater/precalciner kiln |
| DE19854582B4 (en) * | 1998-11-25 | 2007-11-22 | Khd Humboldt Wedag Gmbh | Process for the thermal treatment of cement raw meal |
| US6116896A (en) * | 1999-09-15 | 2000-09-12 | Air Liquide America Inc. | System and method for oxidant injection in rotary kilns |
| US6221127B1 (en) | 1999-11-10 | 2001-04-24 | Svedala Industries, Inc. | Method of pyroprocessing mineral ore material for reducing combustion NOx |
-
2001
- 2001-07-30 US US09/918,269 patent/US6474984B2/en not_active Expired - Lifetime
- 2001-11-14 EP EP01995180A patent/EP1342042A4/en not_active Withdrawn
- 2001-11-14 AU AU2002225689A patent/AU2002225689B2/en not_active Ceased
- 2001-11-14 WO PCT/US2001/043648 patent/WO2002042701A1/en not_active Ceased
- 2001-11-14 CA CA002428029A patent/CA2428029C/en not_active Expired - Fee Related
- 2001-11-14 AU AU2568902A patent/AU2568902A/en active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| AU2568902A (en) | 2002-06-03 |
| WO2002042701A1 (en) | 2002-05-30 |
| CA2428029C (en) | 2009-05-26 |
| EP1342042A4 (en) | 2006-12-06 |
| US6474984B2 (en) | 2002-11-05 |
| US20020061489A1 (en) | 2002-05-23 |
| AU2002225689B2 (en) | 2006-03-16 |
| EP1342042A1 (en) | 2003-09-10 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| EEER | Examination request | ||
| MKLA | Lapsed |
Effective date: 20171114 |