CA2323913A1 - Procede de transformation d'hydrocarbures et catalyseurs utilises dans ledit procede - Google Patents
Procede de transformation d'hydrocarbures et catalyseurs utilises dans ledit procede Download PDFInfo
- Publication number
- CA2323913A1 CA2323913A1 CA002323913A CA2323913A CA2323913A1 CA 2323913 A1 CA2323913 A1 CA 2323913A1 CA 002323913 A CA002323913 A CA 002323913A CA 2323913 A CA2323913 A CA 2323913A CA 2323913 A1 CA2323913 A1 CA 2323913A1
- Authority
- CA
- Canada
- Prior art keywords
- catalyst
- palladium
- platinum
- boiling point
- process according
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
- 239000003054 catalyst Substances 0.000 title claims abstract description 146
- 238000000034 method Methods 0.000 title claims abstract description 70
- 230000008569 process Effects 0.000 title claims abstract description 62
- 238000006243 chemical reaction Methods 0.000 title description 22
- 229930195733 hydrocarbon Natural products 0.000 title description 4
- 150000002430 hydrocarbons Chemical class 0.000 title description 4
- 239000004215 Carbon black (E152) Substances 0.000 title description 3
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 claims abstract description 102
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims abstract description 72
- 229910052763 palladium Inorganic materials 0.000 claims abstract description 57
- 238000004517 catalytic hydrocracking Methods 0.000 claims abstract description 40
- 238000005984 hydrogenation reaction Methods 0.000 claims abstract description 37
- 239000003921 oil Substances 0.000 claims abstract description 35
- 229910052697 platinum Inorganic materials 0.000 claims abstract description 35
- 238000009835 boiling Methods 0.000 claims abstract description 34
- 238000005336 cracking Methods 0.000 claims abstract description 26
- 239000011230 binding agent Substances 0.000 claims abstract description 16
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 33
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 22
- 239000010457 zeolite Substances 0.000 claims description 21
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 18
- 229910021536 Zeolite Inorganic materials 0.000 claims description 17
- 229910052757 nitrogen Inorganic materials 0.000 claims description 11
- 239000000956 alloy Substances 0.000 claims description 6
- 229910045601 alloy Inorganic materials 0.000 claims description 6
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 44
- 229910052717 sulfur Inorganic materials 0.000 description 44
- 239000011593 sulfur Substances 0.000 description 44
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 27
- 239000000463 material Substances 0.000 description 18
- 239000000047 product Substances 0.000 description 18
- 239000010953 base metal Substances 0.000 description 13
- 239000000377 silicon dioxide Substances 0.000 description 13
- 239000000446 fuel Substances 0.000 description 12
- 229910052751 metal Inorganic materials 0.000 description 12
- 239000002184 metal Substances 0.000 description 12
- 239000002253 acid Substances 0.000 description 11
- 239000001257 hydrogen Substances 0.000 description 11
- 229910052739 hydrogen Inorganic materials 0.000 description 11
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 10
- 229910000510 noble metal Inorganic materials 0.000 description 10
- 238000012360 testing method Methods 0.000 description 10
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 8
- 239000002245 particle Substances 0.000 description 8
- 239000011148 porous material Substances 0.000 description 8
- 238000009826 distribution Methods 0.000 description 6
- 230000000694 effects Effects 0.000 description 6
- 238000005470 impregnation Methods 0.000 description 6
- 238000004519 manufacturing process Methods 0.000 description 5
- 150000002739 metals Chemical class 0.000 description 5
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 4
- 239000010941 cobalt Substances 0.000 description 4
- 229910017052 cobalt Inorganic materials 0.000 description 4
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 4
- 239000010687 lubricating oil Substances 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- 229910052750 molybdenum Inorganic materials 0.000 description 4
- 239000011733 molybdenum Substances 0.000 description 4
- 229910052759 nickel Inorganic materials 0.000 description 4
- 239000003208 petroleum Substances 0.000 description 4
- 150000003839 salts Chemical class 0.000 description 4
- 125000003118 aryl group Chemical group 0.000 description 3
- 230000001174 ascending effect Effects 0.000 description 3
- 239000007795 chemical reaction product Substances 0.000 description 3
- 238000000975 co-precipitation Methods 0.000 description 3
- 230000007423 decrease Effects 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- 239000007789 gas Substances 0.000 description 3
- 229910052809 inorganic oxide Inorganic materials 0.000 description 3
- 239000003350 kerosene Substances 0.000 description 3
- 239000000779 smoke Substances 0.000 description 3
- 150000003464 sulfur compounds Chemical class 0.000 description 3
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 3
- 229910052721 tungsten Inorganic materials 0.000 description 3
- 239000010937 tungsten Substances 0.000 description 3
- 241000640882 Condea Species 0.000 description 2
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 2
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 2
- 150000003863 ammonium salts Chemical class 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 238000001354 calcination Methods 0.000 description 2
- 230000003247 decreasing effect Effects 0.000 description 2
- 238000000151 deposition Methods 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 230000018109 developmental process Effects 0.000 description 2
- JRTYPQGPARWINR-UHFFFAOYSA-N palladium platinum Chemical compound [Pd].[Pt] JRTYPQGPARWINR-UHFFFAOYSA-N 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 238000005292 vacuum distillation Methods 0.000 description 2
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical class OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- 241000282326 Felis catus Species 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical class Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 1
- 229910002651 NO3 Inorganic materials 0.000 description 1
- 150000001242 acetic acid derivatives Chemical class 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 150000001345 alkine derivatives Chemical class 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229910000323 aluminium silicate Inorganic materials 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- DVARTQFDIMZBAA-UHFFFAOYSA-O ammonium nitrate Chemical compound [NH4+].[O-][N+]([O-])=O DVARTQFDIMZBAA-UHFFFAOYSA-O 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- AQBOUNVXZQRXNP-UHFFFAOYSA-L azane;dichloropalladium Chemical compound N.N.N.N.Cl[Pd]Cl AQBOUNVXZQRXNP-UHFFFAOYSA-L 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- 150000001734 carboxylic acid salts Chemical class 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 239000010779 crude oil Substances 0.000 description 1
- 229910002026 crystalline silica Inorganic materials 0.000 description 1
- 230000001627 detrimental effect Effects 0.000 description 1
- 150000001993 dienes Chemical class 0.000 description 1
- 239000002283 diesel fuel Substances 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 238000011067 equilibration Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 150000004675 formic acid derivatives Chemical class 0.000 description 1
- 238000005194 fractionation Methods 0.000 description 1
- 239000007792 gaseous phase Substances 0.000 description 1
- 239000003502 gasoline Substances 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 125000005842 heteroatom Chemical group 0.000 description 1
- 235000011167 hydrochloric acid Nutrition 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 238000005342 ion exchange Methods 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 239000012263 liquid product Substances 0.000 description 1
- 230000001050 lubricating effect Effects 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 150000002823 nitrates Chemical class 0.000 description 1
- 150000002940 palladium Chemical class 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- 238000001935 peptisation Methods 0.000 description 1
- -1 platinum group metals Chemical class 0.000 description 1
- 231100000572 poisoning Toxicity 0.000 description 1
- 230000000607 poisoning effect Effects 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 239000011819 refractory material Substances 0.000 description 1
- 102200082820 rs33960931 Human genes 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 150000003568 thioethers Chemical class 0.000 description 1
- 239000013585 weight reducing agent Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G47/00—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions
- C10G47/02—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used
- C10G47/10—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used with catalysts deposited on a carrier
- C10G47/12—Inorganic carriers
- C10G47/14—Inorganic carriers the catalyst containing platinum group metals or compounds thereof
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G47/00—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions
- C10G47/02—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used
- C10G47/10—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used with catalysts deposited on a carrier
- C10G47/12—Inorganic carriers
- C10G47/16—Crystalline alumino-silicate carriers
- C10G47/18—Crystalline alumino-silicate carriers the catalyst containing platinum group metals or compounds thereof
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Inorganic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Crystallography & Structural Chemistry (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Catalysts (AREA)
Abstract
L'invention concerne un procédé utile pour transformer des huiles hydrocarbonées en des produits présentant une masse moléculaire moyenne et un point d'ébullition moyen inférieurs. Ledit procédé consiste à mettre les huiles hydrocarbonées au contact d'un catalyseur comprenant un composant de craquage, un liant, un premier composant d'hydrogénation constitué de palladium et un second composant d'hydrogénation constitué de platine, le rapport molaire palladium/platine étant compris entre 10:1 et 1:10, dans des conditions d'hydrocraquage suffisantes pour transformer au moins 30 % environ des huiles hydrocarbonées, qui bouillent au-dessus de 700 ·F, en des composants de distillat moyen, ayant un point d'ébullition inférieur à 700 ·F.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US7802298P | 1998-03-14 | 1998-03-14 | |
| US60/078,022 | 1998-03-14 | ||
| PCT/US1999/004655 WO1999047625A1 (fr) | 1998-03-14 | 1999-03-11 | Procede de transformation d'hydrocarbures et catalyseurs utilises dans ledit procede |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA2323913A1 true CA2323913A1 (fr) | 1999-09-23 |
Family
ID=22141446
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA002323913A Abandoned CA2323913A1 (fr) | 1998-03-14 | 1999-03-11 | Procede de transformation d'hydrocarbures et catalyseurs utilises dans ledit procede |
Country Status (9)
| Country | Link |
|---|---|
| EP (1) | EP1064342A1 (fr) |
| JP (1) | JP2002506918A (fr) |
| AU (1) | AU3067199A (fr) |
| BR (1) | BR9908751A (fr) |
| CA (1) | CA2323913A1 (fr) |
| EA (1) | EA200000944A1 (fr) |
| HU (1) | HUP0101008A3 (fr) |
| PL (1) | PL342894A1 (fr) |
| WO (1) | WO1999047625A1 (fr) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101760235B (zh) * | 2008-12-25 | 2013-03-06 | 中国石油化工股份有限公司 | 一种重质原油加氢裂化的方法 |
| CN104549243B (zh) * | 2013-10-28 | 2017-05-24 | 中国石油化工股份有限公司 | 负载型催化剂及其制备方法和应用以及制备5,6‑二氨基苯并咪唑酮的方法 |
| EP3353265B8 (fr) | 2015-09-22 | 2024-12-04 | BASF Corporation | Système catalytique tolérant le soufre |
| CN117120160A (zh) * | 2021-03-23 | 2023-11-24 | 雪佛龙美国公司 | 铂-钯双金属加氢裂化催化剂 |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3427243A (en) * | 1967-05-08 | 1969-02-11 | Union Oil Co | Hydrocracking process |
| US4429053A (en) * | 1981-12-04 | 1984-01-31 | Union Oil Company Of California | Rare earth-containing Y zeolite compositions |
| DK0519573T3 (da) * | 1991-06-21 | 1995-07-03 | Shell Int Research | Hydrogenerings-katalysator og fremgangsmåde |
| US5147526A (en) * | 1991-10-01 | 1992-09-15 | Amoco Corporation | Distillate hydrogenation |
| MY107780A (en) * | 1992-09-08 | 1996-06-15 | Shell Int Research | Hydroconversion catalyst |
-
1999
- 1999-03-11 EP EP99912256A patent/EP1064342A1/fr not_active Withdrawn
- 1999-03-11 EA EA200000944A patent/EA200000944A1/ru unknown
- 1999-03-11 PL PL99342894A patent/PL342894A1/xx unknown
- 1999-03-11 AU AU30671/99A patent/AU3067199A/en not_active Abandoned
- 1999-03-11 JP JP2000536808A patent/JP2002506918A/ja active Pending
- 1999-03-11 CA CA002323913A patent/CA2323913A1/fr not_active Abandoned
- 1999-03-11 WO PCT/US1999/004655 patent/WO1999047625A1/fr not_active Ceased
- 1999-03-11 HU HU0101008A patent/HUP0101008A3/hu unknown
- 1999-03-11 BR BR9908751-0A patent/BR9908751A/pt not_active Application Discontinuation
Also Published As
| Publication number | Publication date |
|---|---|
| HUP0101008A3 (en) | 2002-10-28 |
| EP1064342A1 (fr) | 2001-01-03 |
| JP2002506918A (ja) | 2002-03-05 |
| HUP0101008A2 (hu) | 2001-07-30 |
| AU3067199A (en) | 1999-10-11 |
| EA200000944A1 (ru) | 2001-02-26 |
| BR9908751A (pt) | 2000-11-28 |
| WO1999047625A1 (fr) | 1999-09-23 |
| PL342894A1 (en) | 2001-07-16 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FZDE | Discontinued |